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Livros sobre o tema "Electron donor-acceptor complexes"

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1

E, Meador Willard, Chang C. Ken e United States. National Aeronautics and Space Administration. Scientific and Technical Information Division., eds. Initiation precursors and initiators in laser-induced copolymerization of styrene and maleic anhydride in acetone. [Washington, DC]: National Aeronautics and Space Administration, Office of Management, Scientific and Technical Information Division, 1990.

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2

1946-, Gokel George W., e Koga Kenji 1938-, eds. United States-Japan Seminar on Host-Guest Chemistry: Proceedings of the U.S.-Japan Seminar on Host-Guest Chemistry, Miami, Florida, U.S.A., 2-6 November 1987. Dordrecht: Kluwer Academic Publishers, 1989.

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3

Jaworska-Augustyniak, Anna. Fotochemiczne własności elektrono-donorowo-akceptorowych kompleksów ferrocenu, kobaltocenu i niklocenu. Poznań: Wydawn. Nauk. Uniwersytetu im. Adama Mickiewicza w Poznaniu, 1988.

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4

Kapinus, E. I. Fotonika molekuli͡a︡rnykh kompleksov. Kiev: Nauk. dumka, 1988.

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5

Drago, Russell S. Applications of electrostatic-covalent models in chemistry. Gainesville, FL (P.O. Box 13413, Gainesville 32604): Surfside Scientific Publishers, 1994.

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6

T, Pantelides Sokrates, ed. Deep centers in semiconductors: A state-of-the-art approach. 2a ed. Yverdon, Switzerland: Gordon and Breach Science Publishers, 1992.

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7

1939-, Vögtle F., e Weber E, eds. Host guest complex chemistry: Macrocycles : synthesis, structures, applications. Berlin: Springer, 1985.

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8

T, Pantelides Sokrates, ed. Deep centers in semiconductors: A state of the art approach. New York: Gordon and Breach, 1986.

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9

Pawlukojć, Andrzej. Badania widm oscylacyjnych, w obszarze niskich częstości, wybranych kompleksów molekularnych z przeniesieniem ładunku oraz ich składników metodą nieelastycznego rozpraszania neutronów termicznych. Warszawa: Instytut Chemii i Techniki Jądrowej, 2006.

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10

1908-, Gutmann Felix, ed. Charge transfer complexes in biological systems. New York: M. Dekker, 1997.

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11

Joshua, Jortner, Bixon M, Prigogine I e Rice Stuart Alan 1932-, eds. Electron transfer- from isolated molecules to biomolecules. New York: J. Wiley, 1999.

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12

Gutmann, Viktor. The Donor-Acceptor Approach to Molecular Interactions. Springer, 2012.

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13

Paulson, Basil Pavlatos. A study of electronic interactions in intramolecular charge transfer. 1993.

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14

Pantelides, Sokrates T. Deep Centers in Semiconductors: A State-of-the-Art Approach. 2a ed. CRC, 1992.

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15

(Editor), Joshua Jortner, e M. Bixon (Editor), eds. Advances in Chemical Physics, Electron TransferFrom Isolated Molecules to Biomolecules (Advances in Chemical Physics). Wiley-Interscience, 1999.

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16

(Editor), Joshua Jortner, e M. Bixon (Editor), eds. Advances in Chemical Physics, Electron TransferFrom Isolated Molecules to Biomolecules (Advances in Chemical Physics). Wiley-Interscience, 1999.

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17

Kirchman, David L. Processes in anoxic environments. Oxford University Press, 2018. http://dx.doi.org/10.1093/oso/9780198789406.003.0011.

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Resumo:
During organic material degradation in oxic environments, electrons from organic material, the electron donor, are transferred to oxygen, the electron acceptor, during aerobic respiration. Other compounds, such as nitrate, iron, sulfate, and carbon dioxide, take the place of oxygen during anaerobic respiration in anoxic environments. The order in which these compounds are used by bacteria and archaea (only a few eukaryotes are capable of anaerobic respiration) is set by thermodynamics. However, concentrations and chemical state also determine the relative importance of electron acceptors in organic carbon oxidation. Oxygen is most important in the biosphere, while sulfate dominates in marine systems, and carbon dioxide in environments with low sulfate concentrations. Nitrate respiration is important in the nitrogen cycle but not in organic material degradation because of low nitrate concentrations. Organic material is degraded and oxidized by a complex consortium of organisms, the anaerobic food chain, in which the by-products from physiological types of organisms becomes the starting material of another. The consortium consists of biopolymer hydrolysis, fermentation, hydrogen gas production, and the reduction of either sulfate or carbon dioxide. The by-product of sulfate reduction, sulfide and other reduced sulfur compounds, is oxidized back eventually to sulfate by either non-phototrophic, chemolithotrophic organisms or by phototrophic microbes. The by-product of another main form of anaerobic respiration, carbon dioxide reduction, is methane, which is produced only by specific archaea. Methane is degraded aerobically by bacteria and anaerobically by some archaea, sometimes in a consortium with sulfate-reducing bacteria. Cultivation-independent approaches focusing on 16S rRNA genes and a methane-related gene (mcrA) have been instrumental in understanding these consortia because the microbes remain uncultivated to date. The chapter ends with some discussion about the few eukaryotes able to reproduce without oxygen. In addition to their ecological roles, anaerobic protists provide clues about the evolution of primitive eukaryotes.
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