Literatura científica selecionada sobre o tema "Dérivés benzyliques"
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Artigos de revistas sobre o assunto "Dérivés benzyliques"
Touet, Joël, Laurent Faveriel e Eric Brown. "Agents de dédoublement. 3. Ethers benzyliques du (R)-(−) et du (S)-(+)-2-aminobutan-1-ol, et leur utilisation dans le dédoublement de dérivés N-acylés de la phénylglycine et de la p-hydroxyphénylglycine". Tetrahedron 51, n.º 6 (fevereiro de 1995): 1709–20. http://dx.doi.org/10.1016/0040-4020(94)01037-z.
Texto completo da fonteTeses / dissertações sobre o assunto "Dérivés benzyliques"
Pierret, Alexandre. "Fonctionnalisation à distance par métallotropie de dérivés benzyliques". Electronic Thesis or Diss., Université de Lorraine, 2023. https://docnum.univ-lorraine.fr/ulprive/DDOC_T_2023_0032_PIERRET.pdf.
Texto completo da fonteThis thesis presents a development of the remote functionalization reaction by metallotropic rearrangement on benzyl derivatives. The work is based on the use of a single metal reagent, a lithium triorganozincate, which allows the formation of two bonds C(sp3)-C(sp2) and C(sp3)-C(sp3) on sites 5 atoms apart in a single operation. The first chapter focuses on benzyl derivatives with an iodine in position 4 of the aromatic ring. Novel reaction conditions based on the use of a bio-based solvent are proposed. They allow to reach an unprecedented synthetic scope for such a reaction from these substrates. The influence of the solvent is also discussed. The second chapter is devoted to the mechanistic study by DFT of each step composing the reaction sequence studied previously. Thus, the halogen/metal exchange, the 1,2-migration of ligand or the metallotropic rearrangement are investigated with careful consideration of the solvent of the reaction. An experimental contribution completes this study. Finally, the extension of this transformation to benzylic heteroaromatic derivatives, in particular thiophenes, is the subject of the last chapter of this thesis. The reported work defines an approach of remote functionalization where a same toolbox, composed of a unique platform (halogenated thiophene bearing a benzyl phosphate) and an organometallic reagent of the same nature (lithium organozincate), offers several synthetic opportunities according to the experimenter's desires
Mliki, Ahmed. "Action d'un pseudomonas sp sur des lignines de bois explosé et divers dérivés benzyliques". Grenoble 1, 1990. http://www.theses.fr/1990GRE10022.
Texto completo da fonteEr-Rhaimini, Abderrahman. "Hétérocycles azotes N-benziles : synthèse de dérivés N-benziles de l'adénine : étude de la photoélimination de substituants benzyliques". Angers, 1986. http://www.theses.fr/1986ANGE0002.
Texto completo da fonteMarquet, Bernard. "Electrofluoration en position benzylique". Lyon 1, 1990. http://www.theses.fr/1990LYO10196.
Texto completo da fonteBinay, Patrice. "Nouveaux modèles du NADH : réactivité et énantiosélectivité". Rouen, 1986. http://www.theses.fr/1986ROUES001.
Texto completo da fonte