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Artigos de revistas sobre o tema "Cinétique de transition de phase"

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Publicado: 25 de maio de 2024

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1

Delmastro, A., A. Bachiorrini e M. Murat. "Desordre a courte distance dans les phases transitoires resultant de l'activation thermique des montmorillonites". Clay Minerals 24, n.º 1 (março de 1989): 43–52. http://dx.doi.org/10.1180/claymin.1989.024.1.04.

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RésuméDes phases transitoires ont été préparées par activation thermique de deux montmorillonites, l'une calcique et l'autre sodique, dans le domaine de température 650–950°C, puis étudiées par spectroscopie infrarouge. Le coefficient de désordre à courte distance, défini à partir de l'élargissement et l'intensité de certaines bandes caracteristiques, présente ses valeurs maximales avec les phases transitoires obtenues à 800°C et 820–850°C respectivement pour la couche de silice et la couche d'alumine. Ce résultat a pu être corrélé à plusieurs données expérimentales concernant la cinétique de dissolution de ces phases transitoires dans l'acide fluorhydrique dilué ou dans des solutions saturées d'hydroxyde de calcium. En outre, l'accroissement particulièrement marqué du désordre à courte distance mis en évidence au niveau de la transition V→IV de la coordinance de l'aluminium, confirme l'hypothèses émise antérieurement par d'autres auteurs pour expliquer le troisième effet endothermique de faible intensité observé sur les courbes ATD des montmorillonites entre 800° et 900°C.

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2

Siméone, D., J. L. Béchade e D. Gosset. "Mise en évidence de la transition de phase de la zircone monoclinique implantée par des ions Bi et O de faible énergie cinétique". Le Journal de Physique IV 11, PR1 (abril de 2001): Pr1–165—Pr1–174. http://dx.doi.org/10.1051/jp4:2001116.

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3

Lemaire, J., M. Niclause e M. Dzierzynski. "Cinétique D'Oxydation Photochimique de L'Heptaldéhyde en Phase Liquide". Bulletin des Sociétés Chimiques Belges 71, n.º 11-12 (2 de setembro de 2010): 780. http://dx.doi.org/10.1002/bscb.19620711128.

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4

Boussofara, M., M. Hamdi, F. Klaai, M. Boussofara, M. Hamdi, F. Klaai e B. Jeribi. "Cinétique de la procalcitonémie durant la phase aiguë d’un traumatisme grave". Annales Françaises d'Anesthésie et de Réanimation 33 (setembro de 2014): A174. http://dx.doi.org/10.1016/j.annfar.2014.07.292.

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5

Rakovan, John. "Phase Transition". Rocks & Minerals 81, n.º 6 (janeiro de 2006): 467–69. http://dx.doi.org/10.3200/rmin.81.6.467-469.

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6

Rothman, Tony. "Phase Transition". Scientific American 259, n.º 3 (setembro de 1988): 30–31. http://dx.doi.org/10.1038/scientificamerican0988-30.

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7

Matte, Denise, Bernard Solastiouk, André Merlin e Xavier Deglise. "Étude cinétique de la N-chloration de l'acide cyanurique en phase aqueuse". Canadian Journal of Chemistry 68, n.º 2 (1 de fevereiro de 1990): 307–13. http://dx.doi.org/10.1139/v90-043.

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A complete kinetic study of the N-chlorination, in basic aqueous medium, of cyanuric acid by the stopflow spectrophotometric method is presented. Our experimental results can be interpreted by two pairs of kinetically indistinguishable mechanisms.[Formula: see text]or[Formula: see text]and[Formula: see text]or[Formula: see text]The rate constants and their corresponding activation energies were determined in the limiting case where one of the elementary steps in each pair is involved alone in the kinetics of reaction.[Formula: see text]The rate constants for hydrolysis of the monochlorinated cyanuric acid derivatives were derived from our experimental values. Keywords: kinetics, N-chlorination, 1,3,5-triazine-2,4,6-trione, aqueous medium, stopped flow.

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8

Matte, Denise, Bernard Solastiouk, André Merlin e Xavier Deglise. "Étude cinétique de la N-chloration de la succinimide en phase aqueuse". Canadian Journal of Chemistry 70, n.º 1 (1 de janeiro de 1992): 89–99. http://dx.doi.org/10.1139/v92-016.

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A kinetic study of the N-chlorination, in aqueous medium, of succinimide (SH) at low pH (<5) and at high pH (>9) is presented. We have derived the rate constants and activation energies of the processes involved. A stopped-flow spectrophotometric technique was used to study the kinetics. Without chloride ions, our experimental results can be interpreted by two kinetically indistinguishable mechanisms:[Formula: see text]The limiting values of the rate constants for the case in which only one process is involved in the kinetics of chlorination were evaluated: [Formula: see text]; [Formula: see text].In acid medium, in the presence of chloride ions, we observe a nucleophilic attack of the S− ion on molecular chlorine Cl2. This process is added to the two former processes. Keywords: kinetics, N-chlorination, succinimide, aqueous medium, stopped flow.

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9

Lepers, Romuald, A. X. Bigard, Christophe Hausswirth e Charles-Yannick Guézennec. "Modélisation de la transition natation-cyclisme en laboratoire, effet sur la cinétique du lactate". Les Cahiers de l'INSEP 20, n.º 1 (1997): 145. http://dx.doi.org/10.3406/insep.1997.1299.

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10

Vacquier, G., e A. Casalot. "Etude thermodynamique et cinétique du transport en phase vapeur de NbSe2 par l'iode". Journal of Crystal Growth 130, n.º 1-2 (maio de 1993): 259–68. http://dx.doi.org/10.1016/0022-0248(93)90860-y.

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11

Sherrill, Max D., e Walter L. Trikosko. "Josephson phase transition". Physical Review B 32, n.º 11 (1 de dezembro de 1985): 7590–93. http://dx.doi.org/10.1103/physrevb.32.7590.

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12

Norman, G. E. "Plasma Phase Transition". Contributions to Plasma Physics 41, n.º 2-3 (março de 2001): 127–30. http://dx.doi.org/10.1002/1521-3986(200103)41:2/3<127::aid-ctpp127>3.0.co;2-8.

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13

Yang, X. M., G. Zhang e Z. Song. "Phase transition in phase transition lines of quantum XY model". Journal of Physics: Condensed Matter 31, n.º 24 (2 de abril de 2019): 245401. http://dx.doi.org/10.1088/1361-648x/ab0f04.

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14

Vogin, Bernard, François Baronnet e Gérard Scacchi. "Étude chimique et cinétique de l'oxydation homogène en phase gazeuse d'alcanes légers. I. Isobutane". Canadian Journal of Chemistry 67, n.º 5 (1 de maio de 1989): 759–72. http://dx.doi.org/10.1139/v89-115.

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A literature survey on the homogeneous gas-phase oxidation of light alkanes shows that despite a rather high number of papers there are still, even in the case of isobutane, an important number of unresolved questions, which makes the writing of a reaction scheme rather difficult. To obtain more reliable experimental data, we have studied the homogeneous gas-phase oxidation of isobutane in a conventional static system, at 310 and 340 °C and subatmospheric pressure. This investigation is chiefly aimed at identifying and measuring the major primary products of the reaction. A chain radical scheme based on the primary products and on estimation of the rate constants of the elementary steps by the methods of Thermochemical Kinetics is put forward to interpret our experimental results. Two major reaction routes appear, one corresponding to the formation of isobutene and the other to the formation of isobutene oxide. The conclusions of the present investigation and suggestions for further developments are also mentioned. Keywords: oxidation, chemical kinetics, reaction mechanism, isobutane.

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15

Balbi, N., JH Balbi e B. Khoumeri. "Modélisation non linéaire du comportement cinétique d’une réaction de Diels-Alder en phase liquide". Journal de Chimie Physique 92 (1995): 37–46. http://dx.doi.org/10.1051/jcp/1995920037.

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16

Avedillo, Maria J., Jose Maria Quintana e Juan Nunez. "Phase Transition Device for Phase Storing". IEEE Transactions on Nanotechnology 19 (2020): 107–12. http://dx.doi.org/10.1109/tnano.2020.2965243.

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17

Kamegashira, N., A. Shimono, H. W. Xu, H. Satoh, K. Hayashi e T. Kikuchi. "Phase transition of the Ca1.5Nd0.5MnO4 phase". Materials Chemistry and Physics 26, n.º 5 (dezembro de 1990): 483–92. http://dx.doi.org/10.1016/0254-0584(90)90058-i.

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18

Aihara, Masaki. "Ultrafast Photoinduced Phase Transition". JPSJ News and Comments 5 (12 de janeiro de 2008): 07. http://dx.doi.org/10.7566/jpsjnc.5.07.

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19

Sirma, K. K., J. R. Faith, K. M. Khanna e L. S. Chelimo. "PHASE TRANSITION IN SUPERCONDUCTORS." International Journal of Advanced Research 4, n.º 9 (30 de setembro de 2016): 1952–55. http://dx.doi.org/10.21474/ijar01/1678.

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20

Widyan, Hatem. "Phase Transition in Potential". American Journal of Applied Sciences 3, n.º 7 (1 de julho de 2006): 1939–47. http://dx.doi.org/10.3844/ajassp.2006.1939.1947.

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21

Gadway, Bryce. "A shaking phase transition". Nature Physics 18, n.º 3 (março de 2022): 231–32. http://dx.doi.org/10.1038/s41567-022-01543-w.

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22

Sirma., K. K., J. R. Faith. e W. K. Cheruiyot. "PHASE TRANSITION IN AND ." International Journal of Advanced Research 5, n.º 1 (31 de janeiro de 2017): 2636–39. http://dx.doi.org/10.21474/ijar01/3054.

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23

Murao, Tsuyoshi. "Phase transition at surface." Bulletin of the Japan Institute of Metals 25, n.º 11 (1986): 906–13. http://dx.doi.org/10.2320/materia1962.25.906.

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24

Singh, Max Diamond, e Orestis Terzidis. "Introducing Innovation Phase Transition". International Journal of Innovation Science 7, n.º 4 (dezembro de 2015): 249–62. http://dx.doi.org/10.1260/1757-2223.7.4.249.

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25

Zhang, Jian, Alexander Wölfel, Liang Li e Sander van Smaalen. "Phase transition in FeOCl". Acta Crystallographica Section A Foundations of Crystallography 66, a1 (29 de agosto de 2010): s206. http://dx.doi.org/10.1107/s0108767310095358.

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26

Murakami, Akihiro, Takashi Sakuma, Haruyuki Takahashi e Yoshito Onoda. "Phase Transition ofCuxAg1-xBrTe". Journal of the Physical Society of Japan 67, n.º 2 (15 de fevereiro de 1998): 502–4. http://dx.doi.org/10.1143/jpsj.67.502.

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27

Singh, Max Diamond, e Orestis Terzidis. "Introducing Innovation Phase Transition". International Journal of Innovation Science 7, n.º 4 (1 de dezembro de 2015): 249–62. http://dx.doi.org/10.1108/ijis-07-04-2015-b003.

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Innovation diffusion points toward how innovations spread into the market after launch. This paper investigates diffusion dynamics at market entry time and proposes a new evolution pattern at the intersection between inventions and innovations. With this in mind, we initially prove that patent filings correlate with new product introductions in the U.S. spine market. Then we test our new theory supposing that certain patent filing threshold numbers accelerate strong economic returns in terms of innovations. We find that firms hitting certain patent filing thresholds significantly increase their product launches in the mentioned market. Moreover, the results seem to indicate that economic returns of inventions may be measured substantially. Thus, this paper suggests a new research area by utilizing our proposed concept about an Innovation Outcome Trigger Value (IOTV). Furthermore, the implications may also be interesting for practitioners, since we empirically prove that inventive activities turn out to be worthwhile, indeed.

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28

GLEISER, MARCELO, e EDWARD W. KOLB. "THE ELECTROWEAK PHASE TRANSITION". International Journal of Modern Physics C 03, n.º 05 (outubro de 1992): 773–81. http://dx.doi.org/10.1142/s0129183192000464.

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The phase transition associated with the standard electroweak model is very weakly first order. The weakness of the transition means that around the critical temperature the finite-temperature Higgs mass is much less than the critical temperature. This leads to infrared problems in the calculation of the parameters of the potential. Therefore, theories of electroweak baryogenesis, which depend on the details of the transition, must be calculated with care.

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29

Wanless, Erica J., Tim W. Davey e William A. Ducker. "Surface Aggregate Phase Transition". Langmuir 13, n.º 16 (agosto de 1997): 4223–28. http://dx.doi.org/10.1021/la970146k.

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30

Shimizu, Fuminao, Toshihisa Yamaguchi, Tadashi Kurihama e Masaaki Takashige. "Phase Transition of Cs2FeI4". Ferroelectrics 384, n.º 1 (25 de junho de 2009): 93–97. http://dx.doi.org/10.1080/00150190902892964.

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31

Dhar, S. K., P. Manfrinetti, M. L. Fornasini e P. Bonville. "Phase transition in YbAl3C3". European Physical Journal B 63, n.º 2 (maio de 2008): 187–92. http://dx.doi.org/10.1140/epjb/e2008-00241-7.

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32

YAO, YAO, YU-ZHONG ZHANG, HUNPYO LEE, HARALD O. JESCHKE, ROSER VALENTÍ, HAI-QING LIN e CHANG-QIN WU. "ORBITAL SELECTIVE PHASE TRANSITION". Modern Physics Letters B 27, n.º 20 (agosto de 2013): 1330015. http://dx.doi.org/10.1142/s0217984913300159.

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In this paper, we review theoretical investigations on the origin of the orbital selective phase where localized and itinerant electrons coexist in the d shell at intermediate strength of the on-site Coulomb interactions between electrons. In particular, the effect of spatial fluctuations on the phase diagram of the two-orbital Hubbard model with unequal bandwidths is discussed. And different band dispersions in different orbitals as well as different magnetically ordered states in different orbitals which are responsible for orbital selective phase transitions are emphasized. This is due to the fact that these two mechanisms are independent of the Hund's rule coupling, and are completely distinct from other well-known mechanisms like orbitals of unequal bandwidths and orbitals with different degeneracies. Moreover, crystal field splitting is not required in these two recently proposed mechanisms.

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33

Troyanchuk, I. O., D. A. Efimov, N. V. Samsonenko, E. F. Shapovalova e H. Szymczak. "Phase transition in perovskites". Journal of Physics: Condensed Matter 10, n.º 36 (14 de setembro de 1998): 7957–66. http://dx.doi.org/10.1088/0953-8984/10/36/006.

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34

Agterberg, D. F., e M. B. Walker. "Anomalous phase transition inURu2Si2". Physical Review B 50, n.º 1 (1 de julho de 1994): 563–66. http://dx.doi.org/10.1103/physrevb.50.563.

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35

Saito, Shozaburo. "Phase Transition and Equilibrium". Journal of Chemical Engineering of Japan 22, n.º 3 (1989): 215–28. http://dx.doi.org/10.1252/jcej.22.215.

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36

Dézsi, I., Cs Fetzer, Á. Gombkötő, I. Szűcs, J. Gubicza e T. Ungár. "Phase transition in nanomagnetite". Journal of Applied Physics 103, n.º 10 (15 de maio de 2008): 104312. http://dx.doi.org/10.1063/1.2937252.

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37

Oliveira, M. A. S., R. L. Moreira e J. Y. Gesland. "Phase transition sequence ofLi3ThF7crystals". Physical Review B 56, n.º 13 (1 de outubro de 1997): 7755–58. http://dx.doi.org/10.1103/physrevb.56.7755.

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38

Kapusta, Joseph I., e Ajit M. Srivastava. "Proximal chiral phase transition". Physical Review D 50, n.º 8 (15 de outubro de 1994): 5379–88. http://dx.doi.org/10.1103/physrevd.50.5379.

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39

Iwata, Makoto, Tomonari Taguchi, Yoshihiro Ishibashi, Hirohumi Kasatani e Hikaru Terauchi. "Phase Transition inC3H7NH3H2PO4Single Crystal". Journal of the Physical Society of Japan 65, n.º 5 (15 de maio de 1996): 1459–63. http://dx.doi.org/10.1143/jpsj.65.1459.

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40

Matsuo, Yasumitsu, Junko Hatori, Katsumi Irokawa, Masaru Komukae, Toshio Osaka e Yasuharu Makita. "Ferroelastic Phase Transition inTl2SeO4". Journal of the Physical Society of Japan 65, n.º 12 (15 de dezembro de 1996): 3931–34. http://dx.doi.org/10.1143/jpsj.65.3931.

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41

Samuel, Stuart. "The earliest phase transition?" Nuclear Physics B 585, n.º 3 (outubro de 2000): 715–21. http://dx.doi.org/10.1016/s0550-3213(00)00431-4.

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42

Schäfer, Thomas. "The chiral phase transition". Nuclear Physics A 610 (dezembro de 1996): 13–25. http://dx.doi.org/10.1016/s0375-9474(96)00339-9.

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43

Gent, Ian P., e Toby Walsh. "The TSP phase transition". Artificial Intelligence 88, n.º 1-2 (dezembro de 1996): 349–58. http://dx.doi.org/10.1016/s0004-3702(96)00030-6.

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44

Bourson, P., A. Ndtoungou, J. Bouillot, J. L. Soubeyroux e D. Durand. "Phase transition of RbCN". Physica B: Condensed Matter 180-181 (junho de 1992): 351–53. http://dx.doi.org/10.1016/0921-4526(92)90756-i.

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45

Salker, A. V., H. V. Keer, E. B. Mirza e V. V. Deshpande. "Phase transition in V5O9". Journal of Solid State Chemistry 60, n.º 1 (novembro de 1985): 135–38. http://dx.doi.org/10.1016/0022-4596(85)90175-6.

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46

Duong-van, Minh. "Phase transition of multifractals". Nuclear Physics B - Proceedings Supplements 2 (novembro de 1987): 521–25. http://dx.doi.org/10.1016/0920-5632(87)90039-9.

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47

Tamaki, Shigeru. "Phase transition in liquids". Phase Transitions 66, n.º 1-4 (setembro de 1998): 167–257. http://dx.doi.org/10.1080/01411599808222125.

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48

TRIMPER, STEFFEN. "KINETIC INDUCED PHASE TRANSITION". International Journal of Modern Physics B 13, n.º 20 (10 de agosto de 1999): 2637–44. http://dx.doi.org/10.1142/s0217979299002563.

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An Ising model with local Glauber dynamics is studied under the influence of additional kinetic restrictions for the spin-flip rates depending on the orientation of neighboring spins. Even when the static interaction between the spins is completely eliminated and only an external field is taken into account the system offers a phase transition at a finite value of the applied field. The transition is realized due to a competition between the activation processes driven by the field and the dynamical rules for the spin-flips. The result is based on a master equation approach in a quantum formulation.

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49

Browning, Nigel D. "Phase transition singled out". Nature Chemistry 5, n.º 5 (23 de abril de 2013): 363–64. http://dx.doi.org/10.1038/nchem.1632.

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50

Xu, Ke, e Wei Li. "The SAT phase transition". Science in China Series E: Technological Sciences 42, n.º 5 (outubro de 1999): 494–501. http://dx.doi.org/10.1007/bf02917402.

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