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Artigos de revistas sobre o tema "All-solid batteries"

Autor: Grafiati

Publicado: 8 de fevereiro de 2025

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1

HAYASHI, Akitoshi, e Atsushi SAKUDA. "Development of All-solid-state Batteries". Journal of The Institute of Electrical Engineers of Japan 141, n.º 9 (1 de setembro de 2021): 579–82. http://dx.doi.org/10.1541/ieejjournal.141.579.

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2

Notten, Peter H. L. "3D-integrated all-solid-state batteries". Europhysics News 42, n.º 3 (maio de 2011): 24–29. http://dx.doi.org/10.1051/epn/2011303.

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3

Bhardwaj, Ravindra Kumar, e David Zitoun. "Recent Progress in Solid Electrolytes for All-Solid-State Metal(Li/Na)–Sulfur Batteries". Batteries 9, n.º 2 (3 de fevereiro de 2023): 110. http://dx.doi.org/10.3390/batteries9020110.

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Metal–sulfur batteries, especially lithium/sodium–sulfur (Li/Na-S) batteries, have attracted widespread attention for large-scale energy application due to their superior theoretical energy density, low cost of sulfur compared to conventional lithium-ion battery (LIBs) cathodes and environmental sustainability. Despite these advantages, metal–sulfur batteries face many fundamental challenges which have put them on the back foot. The use of ether-based liquid electrolyte has brought metal–sulfur batteries to a critical stage by causing intermediate polysulfide dissolution which results in poor cycling life and safety concerns. Replacement of the ether-based liquid electrolyte by a solid electrolyte (SEs) has overcome these challenges to a large extent. This review describes the recent development and progress of solid electrolytes for all-solid-state Li/Na-S batteries. This article begins with a basic introduction to metal–sulfur batteries and explains their challenges. We will discuss the drawbacks of the using liquid organic electrolytes and the advantages of replacing liquid electrolytes with solid electrolytes. This article will also explain the fundamental requirements of solid electrolytes in meeting the practical applications of all solid-state metal–sulfur batteries, as well as the electrode–electrolyte interfaces of all solid-state Li/Na-S batteries.

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4

Amaresh, S., K. Karthikeyan, K. J. Kim, Y. G. Lee e Y. S. Lee. "Aluminum based sulfide solid lithium ionic conductors for all solid state batteries". Nanoscale 6, n.º 12 (2014): 6661–67. http://dx.doi.org/10.1039/c4nr00804a.

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The ionic conductivity of a Li–Al–Ge–P–S based thio-LISICON solid electrolyte is equivalent to that of a conventional organic liquid electrolyte used in lithium secondary batteries. The usage of aluminum brings down the cost of the solid electrolyte making it suitable for commercial solid state batteries.

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5

HAYASHI, Akitoshi, Atsushi SAKUDA e Masahiro TATSUMISAGO. "Development of Solid Electrolytes for All-Solid-State Batteries". NIPPON GOMU KYOKAISHI 92, n.º 11 (2019): 430–34. http://dx.doi.org/10.2324/gomu.92.430.

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6

Dirican, Mahmut, Chaoyi Yan, Pei Zhu e Xiangwu Zhang. "Composite solid electrolytes for all-solid-state lithium batteries". Materials Science and Engineering: R: Reports 136 (abril de 2019): 27–46. http://dx.doi.org/10.1016/j.mser.2018.10.004.

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7

Smdani, Gulam, Md Wahidul Hasan, Amir Abdul Razzaq e Weibing Xing. "A Novel Solid State Polymer Electrolyte for All Solid State Lithium Batteries". ECS Meeting Abstracts MA2024-01, n.º 1 (9 de agosto de 2024): 113. http://dx.doi.org/10.1149/ma2024-011113mtgabs.

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All-solid-state lithium batteries (ASSLBs) have gained enormous interest due to their potential high energy density, high performance, and inherent safety characteristics for advanced energy storage systems.1 Currently, solid-state ceramic (inorganic) electrolytes (SSCEs), solid-state polymer electrolytes (SSPEs), and a combination of the two (e.g., SSCE fillers in SSPEs) are being developed for ASSLBs.2 Although SSCEs have high ionic conductivity and high electrochemical stability,3 they experience some significant drawbacks, such as poor electrolyte/electrode interfacial properties and poor mechanical characteristics (brittle, fragile),4 which can hinder their adoption to commercialization. Typically, SSCE-based ASSLBs require high cell stack pressures exerted by heavy fixtures for regular operations, which can reduce the energy density of the overall battery packages.5 One promising solution to circumvent the aforementioned issues of SSCE-based ASSLBs is to develop SSPE-based AASLBs, since SSPEs can provide inherently good interfacial contacts with the electrodes that do not require high cell stack pressures. In addition, SSPEs are advantageous in making flexible batteries due to their elastic nature.6 In this study, a novel method was developed to prepare a high-performance SSPE-based ASSLB, where a π-conjugated polymer was incorporated into a baseline polymer backbone, resulting in an improvement in ionic conductivity, thermal stability, and electrochemical stability. The novel SSPE demonstrated a superior electrochemical performance than the baseline when used in ASSLBs. The strategy developed in this study may lead to a new direction for the research and development of next-generation SSPE-based ASSLBs. References: (1) Chiu, K.-C.; Chang, J.-K.; Su, Y.-S. Recent Configurational Advances for Solid-State Lithium Batteries Featuring Conversion-Type Cathodes. Molecules 2023, 28 (12), 4579. (2) Chen, A.; Qu, C.; Shi, Y.; Shi, F. Manufacturing strategies for solid electrolyte in batteries. Frontiers in Energy Research 2020, 8, 571440. (3) Li, S.; Zhang, S. Q.; Shen, L.; Liu, Q.; Ma, J. B.; Lv, W.; He, Y. B.; Yang, Q. H. Progress and perspective of ceramic/polymer composite solid electrolytes for lithium batteries. Advanced Science 2020, 7 (5), 1903088. (4) Yu, X.; Manthiram, A. A review of composite polymer-ceramic electrolytes for lithium batteries. Energy Storage Materials 2021, 34, 282-300. (5) Hayashi, A.; Sakuda, A.; Tatsumisago, M. Development of sulfide solid electrolytes and interface formation processes for bulk-type all-solid-state Li and Na batteries. Frontiers in Energy Research 2016, 4, 25. (6) Jiang, Y.; Yan, X.; Ma, Z.; Mei, P.; Xiao, W.; You, Q.; Zhang, Y. Development of the PEO based solid polymer electrolytes for all-solid state lithium ion batteries. Polymers 2018, 10 (11), 1237. Acknowledgment This work was supported by the Larry and Linda Pearson Endowed Chair at the Department of Mechanical Engineering, South Dakoda School of Mines and Technology and by the South Dakota Governor’s Research Center for Electrochemical Energy Storage.

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8

Hatzell, Kelsey. "Chemo-Mechanics in All Solid State Composite Cathodes". ECS Meeting Abstracts MA2022-02, n.º 4 (9 de outubro de 2022): 469. http://dx.doi.org/10.1149/ma2022-024469mtgabs.

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Decarbonization of transportation systems will require a suite of battery technologies depending on the mode and scale. Solid state batteries are an energy dense and non-flammable alternative to conventional batteries and is currently being explored for passenger vehicles and portable electronics1,2. While there is considerable interest in understanding lithium metal anodes for solid state batteries, many significant challenges still exist in solid state cathodes. Solid state cathodes are composites and usually include a combination of active material, solid electrolyte and binder3. The composition, microstructure, and properties of the cathode has significant implications for rate performance, energy density, and lifetime of these systems. Here we examine composite solid state cathodes comprised of argyrodite Li6PS5Cl and LiNi0.8Co0.1Mn0.1O2. We examine how composition and structure influences performance with a specific lens on understanding how chemo-mechanical transformations and buried solid-solid interfaces evolved during cycle operation. In addition we show how external operating conditions (temperature/pressure) influence stress generation in these systems. In this talk we will discuss how we combine novel bench-top experiments with advanced operando x-ray characterization tools to quantify stress and correlate it to structure. [1]Shen, F., Dixit, M. B., Zaman, W., Hortance, N., Rogers, B., & Hatzell, K. B. (2019). Composite electrode ink formulation for all solid-state batteries. Journal of The Electrochemical Society, 166(14), A3182. [2]Hatzell, K. B., & Zheng, Y. (2021). Prospects on large-scale manufacturing of solid state batteries. MRS Energy & Sustainability, 8(1), 33-39. [3]Ren, Y., Hortance, N., & Hatzell, K. (2022). Mitigating Chemo-Mechanical Failure in Li-S Solid State Batteries with Compliant Cathodes. Journal of The Electrochemical Society.

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9

Chen, Zonghai. "(Invited) Formation of Solid/Solid Interface for All Solid State Batteries". ECS Meeting Abstracts MA2020-01, n.º 2 (1 de maio de 2020): 290. http://dx.doi.org/10.1149/ma2020-012290mtgabs.

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10

Sun, Zhouting, Mingyi Liu, Yong Zhu, Ruochen Xu, Zhiqiang Chen, Peng Zhang, Zeyu Lu, Pengcheng Wang e Chengrui Wang. "Issues Concerning Interfaces with Inorganic Solid Electrolytes in All-Solid-State Lithium Metal Batteries". Sustainability 14, n.º 15 (25 de julho de 2022): 9090. http://dx.doi.org/10.3390/su14159090.

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All-solid-state batteries have attracted wide attention for high-performance and safe batteries. The combination of solid electrolytes and lithium metal anodes makes high-energy batteries practical for next-generation high-performance devices. However, when a solid electrolyte replaces the liquid electrolyte, many different interface/interphase issues have arisen from the contact with electrodes. Poor wettability and unstable chemical/electrochemical reaction at the interfaces with lithium metal anodes will lead to poor lithium diffusion kinetics and combustion of fresh lithium and active materials in the electrolyte. Element cross-diffusion and charge layer formation at the interfaces with cathodes also impede the lithium ionic conductivity and increase the charge transfer resistance. The abovementioned interface issues hinder the electrochemical performance of all-solid-state lithium metal batteries. This review demonstrates the formation and mechanism of these interface issues between solid electrolytes and anodes/cathodes. Aiming to address the problems, we review and propose modification strategies to weaken interface resistance and improve the electrochemical performance of all-solid-state lithium metal batteries.

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11

Thangadurai, Venkataraman. "(Invited) Garnet Solid Electrolytes for Advanced All-Solid-State Li Metal Batteries". ECS Meeting Abstracts MA2022-02, n.º 47 (9 de outubro de 2022): 1759. http://dx.doi.org/10.1149/ma2022-02471759mtgabs.

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These days, Li metal anode-based battery has been arisen as one of the key energy storage technologies due to its high theoretical energy density compared to conventional lithium and sodium ion-based batteries. The present Li-S batteries suffer due to Li dendrite formation and capacity decay due to polysulfide dissolution effect, because of organic electrolytes used in the current research. Solid state (ceramic) electrolytes are promising to prevent Li dendrite growth and polysulfide dissolution. Among different ceramic electrolytes garnet-type structure solid inorganic electrolytes are very promising because of its high lithium-ion conductivity and stability with elemental Li. However, the high interfacial resistance with the electrode is the major bottleneck for the practical use of ceramic electrolyte. Polymer and ceramic hybrid electrolytes exhibit low interfacial resistance. In this talk, we will present development of electrolytes for all-solid-state Li metal batteries.

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12

SAKUDA, Atsushi, Akitoshi HAYASHI e Masahiro TATSUMISAGO. "Metastable Materials for All-Solid-State Batteries". Electrochemistry 87, n.º 5 (5 de setembro de 2019): 247–50. http://dx.doi.org/10.5796/electrochemistry.19-h0002.

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13

Buissette, Valérie. "All-solid-state Batteries - Without Liquid Electrolyte". ATZextra worldwide 27, S1 (agosto de 2022): 34–37. http://dx.doi.org/10.1007/s40111-022-0325-2.

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14

Yang, Jing, Gaozhan Liu, Maxim Avdeev, Hongli Wan, Fudong Han, Lin Shen, Zheyi Zou et al. "Ultrastable All-Solid-State Sodium Rechargeable Batteries". ACS Energy Letters 5, n.º 9 (11 de agosto de 2020): 2835–41. http://dx.doi.org/10.1021/acsenergylett.0c01432.

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15

Danilov, D., R. A. H. Niessen e P. H. L. Notten. "Modeling All-Solid-State Li-Ion Batteries". Journal of The Electrochemical Society 158, n.º 3 (2011): A215. http://dx.doi.org/10.1149/1.3521414.

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16

Meng, Shirley. "Si Anode for All Solid State Batteries". ECS Meeting Abstracts MA2022-02, n.º 3 (9 de outubro de 2022): 249. http://dx.doi.org/10.1149/ma2022-023249mtgabs.

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The development of silicon anodes for lithium-ion batteries has been largely impeded by poor interfacial stability against liquid electrolytes. I will show how to enable the operation of a 99.9 weight % microsilicon anode by using the interface passivating properties of sulfide solid electrolytes. Advanced interface and bulk characterization, and quantification of interfacial components, showed that such an approach eliminates continuous interfacial growth and irreversible lithium losses. Microsilicon full cells were assembled and found to achieve high areal current density, wide operating temperature range, and high areal loadings for the different cells. The promising performance can be attributed to both the desirable interfacial property between microsilicon and sulfide electrolytes and the distinctive chemomechanical behavior of the lithium-silicon alloy. I will also discuss a few exciting future directions for nanosilicon with solid state electrolytes.

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17

Pandeeswari, Jayaraman, Gunamony Jenisha, Kumlachew Zelalem Walle e Masashi Kotobuki. "Recent Research Progress on All-Solid-State Mg Batteries". Batteries 9, n.º 12 (27 de novembro de 2023): 570. http://dx.doi.org/10.3390/batteries9120570.

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Current Li battery technology employs graphite anode and flammable organic liquid electrolytes. Thus, the current Li battery is always facing the problems of low energy density and safety. Additionally, the sustainable supply of Li due to the scarce abundance of Li sources is another problem. An all-solid-state Mg battery is expected to solve the problems owing to non-flammable solid-state electrolytes, high capacity/safety of divalent Mg metal anode and high abundance of Mg sources; therefore, solid-state electrolytes and all-solid-state Mg batteries have been researched intensively last two decades. However, the realization of all-solid-state Mg batteries is still far off. In this article, we review the recent research progress on all-solid-state Mg batteries so that researchers can pursue recent research trends of an all-solid-state Mg battery. At first, the solid-state electrolyte research is described briefly in the categories of inorganic, organic and inorganic/organic composite electrolytes. After that, the recent research progress of all-solid-state Mg batteries is summarized and analyzed. To help readers, we tabulate electrode materials, experimental conditions and performances of an all-solid-state Mg battery so that the readers can find the necessary information at a glance. In the last, challenges to realize the all-solid-state Mg batteries are visited.

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18

Lian, Peng-Jie, Bo-Sheng Zhao, Lian-Qi Zhang, Ning Xu, Meng-Tao Wu e Xue-Ping Gao. "Inorganic sulfide solid electrolytes for all-solid-state lithium secondary batteries". Journal of Materials Chemistry A 7, n.º 36 (2019): 20540–57. http://dx.doi.org/10.1039/c9ta04555d.

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19

Jung, Yun-Chae, Sang-Min Lee, Jeong-Hee Choi, Seung Soon Jang e Dong-Won Kim. "All Solid-State Lithium Batteries Assembled with Hybrid Solid Electrolytes". Journal of The Electrochemical Society 162, n.º 4 (2015): A704—A710. http://dx.doi.org/10.1149/2.0731504jes.

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20

Kim, Jun tae, Hyeon-ji Shin e Hun-Gi Jung. "Sulfide Solid Electrolyte Coated Cathode in All-Solid-State Batteries". ECS Meeting Abstracts MA2024-02, n.º 8 (22 de novembro de 2024): 1234. https://doi.org/10.1149/ma2024-0281234mtgabs.

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Using a sulfide solid electrolyte, the all-solid-state batteries emerge as a promising candidate for next generation batteries, having significant advantages such as high lithium ionic conductivity and wide electrochemical stability window. These characteristics pave the way for the realization of elevated power and energy densities. Nonetheless, this cutting-edge technology is not without its hurdles; indeed, there are pressing issues that demand attention and refinement. In contrast to conventional lithium-ion batteries, which rely on organic liquid electrolytes with high wettability having uniform lithium ion transfer pathways within electrodes, the ASSBs encounter constraints in establishing solid-solid interfaces owing to its intrinsic solid nature. This limitation becomes particularly apparent during the cycling, wherein the fluctuating volume of the active material, prompted by the (de)intercalation of lithium ions, precipitates the degradation of the interface between active material and solid electrolyte within the composite electrode. This phenomenon leads up to loss of the lithium ionic pathway, precipitating a deterioration in cell performance The key point of this study lies in the endeavor to enhance battery performance through the application of a solid electrolyte coating onto the surface of the active material. By doing so, the aim is to preserve a uniform pathway for lithium ion transfer within the composite electrode. It is noteworthy that the solid electrolyte coating layer exerts profound influence on the electrochemical dynamics of the cell, important in adapting the formation of homogeneous lithium ionic pathway and the mitigation of void formation within the composite electrode. Thus, the main thrust of this research is to validate the formation of meticulously uniform solid electrolyte coating layer, depend upon the size of the solid electrolyte particles. In pursuit of this objective, a multifaceted approach was adopted. Through the utilization of liquid-phase process and a dispersant, the particle size of the solid electrolyte was deliberately manipulated, thereafter subjecting it to a dispersion process for the application of solid electrolyte coating. Intriguingly, it was observed that as the particle size of the solid electrolyte diminished, a more uniform solid electrolyte coating layer ensured, thereby engendering better electrochemical performance. Furthermore, it was corroborated that the lithium ionic pathway persevered even after long cycling, attributable to the presence of the solid electrolyte coating layer. Concomitantly, the incidence of undesirable side reactions was appreciably mitigated, with the homogeneous electrochemical reactions within composite electrode.

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Yang, Shuhao, e Guoying Chen. "Fundamental Understanding of Halide Solid Electrolytes for All-Solid-State Batteries". ECS Meeting Abstracts MA2024-01, n.º 2 (9 de agosto de 2024): 412. http://dx.doi.org/10.1149/ma2024-012412mtgabs.

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Due to their superior oxidative stability, high ionic conductivity and excellent chemical compatibility with uncoated 4 V-class cathode active materials, halide compounds, particularly those with a general formula of Li3MCl6 (M = Sc, Zr, In, Y, Er, and Yb etc.), have attracted much attention as solid electrolytes (SEs) for all-solid-state batteries (ASSBs).1,2 While a great deal of effort has been devoted to the discovery of new halide SEs,3–5 fundamental understanding of their properties, such as the mechanism of ionic conductivity, chemical stability, and the interfacial reactivities at the cathode and the anode are still lacking. Here we use Li3YCl6 (LYC) as an example to investigate the key parameters that impact their performances in ASSBs. Hopping frequency analysis is used to understand how synthesis methods and chemical compositions affect mobile carrier concentration and ionic conductivity in the Li–Y–Cl series.6 Synchrotron X-ray absorption (XAS) and diffraction (XRD) are used to investigate electrochemical and interfacial chemistry of LYC in full ASSB cells with an uncoated nickel-rich cathode, a Li metal anode or a lithium-metal alloy anode. Our strategies in developing halide SEs for higher capacity and high energy density ASSBs will be presented. References: (1) Manthiram, A.; Yu, X.; Wang, S. Lithium battery chemistries enabled by solid-state electrolytes. Nat. Rev. Mater. 2017, 2, 16103. (2) Janek, J.; Zeier, W. G.; Challenges in speeding up solid-state battery development. Nat. Energy 2023, 8, 230−240. (3) Combs, S. R.; Todd, P. K.; Gorai, P.; Maughan, A. E. Designing defects and diffusion through substitutions in metal halide solid electrolytes. J. Electrochem. Soc. 2022, 169, 040551. (4) Kwak, H.; Wang, S.; Park, J.; Liu, Y.; Kim, K. T.; Choi, Y.; Mo, Y.; Jung, Y. S. Emerging halide superionic conductors for all-solid-state batteries: design, synthesis, and practical applications. ACS Energy Lett. 2022, 7, 1776–1805. (5) Wang, C.; Liang, J.; Kim, J. T.; Sun, X. Prospects of halide-based all-solid-state batteries: from material design to practical application. Sci. Adv. 2022, 8, eadc9516. (6) Yang, S.; Kim, S. Y.; Chen, G. Halide superionic conductors for all-solid-state batteries: effects of synthesis and composition on lithium-ion conductivity. Submitted.

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Helms, Brett. "Design of Solid Electrolytes to Enable Direct Cathode Recycling in All-Solid-State Lithium Metal Batteries". ECS Meeting Abstracts MA2023-01, n.º 6 (28 de agosto de 2023): 1080. http://dx.doi.org/10.1149/ma2023-0161080mtgabs.

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All-solid-state lithium metal batteries are thought to be safer when used in electric vehicles with large powertrains. During the manufacturing of cathodes and separators from solid electrolytes, interphases generated between particulates at high pressure and temperature make deconstructing solid-state batteries exceedingly difficult. Here, I will describe a new approach for creating all-solid state batteries that are readily deconstructed and whereby all components of the battery can be dissociated from the other, enabling direct cathode recycling. Key to our design is the solid electrolyte, which assembled from ion-transporting components that may also be disassembled using a simple solvent-assisted process. Batteries featuring this solid electrolyte operate for hundreds of cycles at EV-relevant C-rates with both LFP and NMC cathodes, showing 80% capacity retention over that timeframe. More importantly, second-life batteries after direct cathode recycling indicate we can recovery 90% of the original capacity from the cathodes and sustain it for hundreds of additional cycles at those rates.

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23

Wang, Yao‐Yao, Wan‐Yue Diao, Chao‐Ying Fan, Xing‐Long Wu e Jing‐Ping Zhang. "Benign Recycling of Spent Batteries towards All‐Solid‐State Lithium Batteries". Chemistry – A European Journal 25, n.º 38 (6 de junho de 2019): 8975–81. http://dx.doi.org/10.1002/chem.201900845.

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24

Nagao, Kenji, Yuka Nagata, Atsushi Sakuda, Akitoshi Hayashi, Minako Deguchi, Chie Hotehama, Hirofumi Tsukasaki et al. "A reversible oxygen redox reaction in bulk-type all-solid-state batteries". Science Advances 6, n.º 25 (junho de 2020): eaax7236. http://dx.doi.org/10.1126/sciadv.aax7236.

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An all-solid-state lithium battery using inorganic solid electrolytes requires safety assurance and improved energy density, both of which are issues in large-scale applications of lithium-ion batteries. Utilization of high-capacity lithium-excess electrode materials is effective for the further increase in energy density. However, they have never been applied to all-solid-state batteries. Operational difficulty of all-solid-state batteries using them generally lies in the construction of the electrode-electrolyte interface. By the amorphization of Li2RuO3 as a lithium-excess model material with Li2SO4, here, we have first demonstrated a reversible oxygen redox reaction in all-solid-state batteries. Amorphous nature of the Li2RuO3-Li2SO4 matrix enables inclusion of active material with high conductivity and ductility for achieving favorable interfaces with charge transfer capabilities, leading to the stable operation of all-solid-state batteries.

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Reddy, Mogalahalli V., Christian M. Julien, Alain Mauger e Karim Zaghib. "Sulfide and Oxide Inorganic Solid Electrolytes for All-Solid-State Li Batteries: A Review". Nanomaterials 10, n.º 8 (15 de agosto de 2020): 1606. http://dx.doi.org/10.3390/nano10081606.

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Energy storage materials are finding increasing applications in our daily lives, for devices such as mobile phones and electric vehicles. Current commercial batteries use flammable liquid electrolytes, which are unsafe, toxic, and environmentally unfriendly with low chemical stability. Recently, solid electrolytes have been extensively studied as alternative electrolytes to address these shortcomings. Herein, we report the early history, synthesis and characterization, mechanical properties, and Li+ ion transport mechanisms of inorganic sulfide and oxide electrolytes. Furthermore, we highlight the importance of the fabrication technology and experimental conditions, such as the effects of pressure and operating parameters, on the electrochemical performance of all-solid-state Li batteries. In particular, we emphasize promising electrolyte systems based on sulfides and argyrodites, such as LiPS5Cl and β-Li3PS4, oxide electrolytes, bare and doped Li7La3Zr2O12 garnet, NASICON-type structures, and perovskite electrolyte materials. Moreover, we discuss the present and future challenges that all-solid-state batteries face for large-scale industrial applications.

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Kim, A.-yeon, Hun-Gi Jung, Hyeon-Ji Shin e Jun tae Kim. "Binderless Sheet-Type Oxide-Sulfide Composite Solid Electrolyte for All-Solid-State Batteries". ECS Meeting Abstracts MA2023-02, n.º 4 (22 de dezembro de 2023): 745. http://dx.doi.org/10.1149/ma2023-024745mtgabs.

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Lithium-ion batteries have been used as energy sources not only for small electronic devices but also for high-capacity and high-energy-density applications such as electric vehicles. However, the use of flammable organic liquid electrolytes in lithium-ion batteries has raised safety concerns in various applications. Therefore, solid-state batteries using flame-retardant inorganic materials are considered a more reasonable direction for future energy sources due to their high safety and high energy density. Solid electrolytes(SEs) are divided into oxide-based, sulfide-based, and polymer-based. Each solid electrolyte has its own advantages and disadvantages. Oxide-based solid electrolytes (e.g., Li7La3Zr2O12 (LLZO), Li3xLa2/3-xTiO3 (LLTO), Li1.3Al0.3Ti1.7(PO4)3 (LATP)) are air-stable and exhibit excellent electrochemical properties over a wide potential range. However, their high interfacial resistance may limit their practical application as batteries. Sulfide-based solid electrolytes (e.g., Li6PS5X (X=Cl, Br, I), Li10GeP2S12, (100-x)Li2S-xP2S5)) have high ionic conductivity, ductile properties, low interfacial resistance, and good room temperature workability. However, they are vulnerable to atmospheric instability, which can produce toxic gases such as H2S, and are relatively electrochemically unstable with Li metal. Polymer-based solid electrolytes, such as those made from polymers like PEO, PVDF, PAN, etc. that are compounded with other solid electrolytes (oxides, sulfides, etc.), offer the advantage of being able to form solid electrolyte membranes over large areas. But they have low ionic conductivity and weak mechanical properties of the polymer itself, limiting their practical application. To apply solid-state batteries to practical high-energy density energy storage devices such as electric vehicles, high ion conductivity, electrochemical stability, high mechanical properties, and large area formation of the electrolyte layer are essential. Solid electrolytes are mainly formed in powder form, and without a polymer binder, it is limited to apply as a film for large-capacity storage devices. Here, we fabricated a freestanding sheet-type Al-LLZO oxide-based solid electrolyte that forms a 3D network without a polymer material using an electrospinning method. In addition, we prepared a oxide-sulfide composite solid electrolyte membrane by impregnating LPSCl sulfide-based solid electrolyte into the Al-LLZO solid electrolyte sheet. As a result, This process removed the polymer and improved both the ionic conductivity and mechanical properties. Furthermore, it was possible to achieve both large-area and film characteristics without the need for a polymer.

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Lim, Jungwoo, Rory Powell e Laurence J. Hardwick. "Gas Evolution from Sulfide-Based All-Solid-State Batteries". ECS Meeting Abstracts MA2022-01, n.º 2 (7 de julho de 2022): 231. http://dx.doi.org/10.1149/ma2022-012231mtgabs.

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The demand for high-performance batteries for electrical vehicles (EV) and large-scale energy storage systems have accelerated the development of all-solid-state batteries. Switching from organic liquid electrolyte to solid electrolyte (SE) ensures, not only the high energy density (Wh/L), but also an intrinsic improvement to safety from the removal of flammable solvent in the liquid electrolyte. However, for the development of all-solid-state batteries, still many problems exist toward commercialisation. One challenge is their chemical/electrochemical stability. In case of Li6PS5Cl argyrodite, their electrochemical decomposition was proposed as following reaction. [1] Li6PS5Cl → Li4PS5Cl + 2Li+ + 2e → Li3PS4 + Sx + LiCl → P2Sx + Sx + LiCl + 3Li+ + 3e (1) However, this proposed reaction is bulk electrochemical decomposition of argyrodite. To understand the decomposition in actual cell, layered oxide cathode/argyrodite composite were analysed by in situ Raman microscopy, X-ray photoelectron spectroscopy and Time-of-flight secondary ion mass spectrometry. [2, 3] This research reports actual solid decomposition product formed by active material and solid electrolyte such as POx or (S2)2- compound. Not only for solid decomposition product, but also gaseous decomposition product can be generated from the interface between cathode materials and SE. Previously, much work has demonstrated that O2 and CO2 gases are released from the positive electrode material within the lithium-ion cell. [4] These exothermic surface reactions are important not only for cell swelling in the long-term usage, but also for cell combustion. However, the gas releasing behaviour of positive electrode mixture in all-solid-state batteries are still not well recognised. In this research, we focused on the gas releasing behaviour of all-solid-state batteries. LiNi0.6Mn0.2Co0.2O2 was selected for cathode materials in this research. For the solid electrolyte itself and LiNi0.6Mn0.2Co0.2O2/SE mixture were analysed by Differential Electrochemical Mass Spectroscopy (DEMS). Furthermore, to understand the importance of surface chemistry, air stored LiNi0.6Mn0.2Co0.2O2 and Al2O3 coated LiNi0.6Mn0.2Co0.2O2were prepared. Since air contamination (H2O and CO2) is detrimental for Ni-rich cathode and battery [5], we propose role of surface chemistry in all-solid-state batteries by comparing different LiNi0.6Mn0.2Co0.2O2 composites. As shown in Figure 1, CO2 and O2 gas evolution is observed within an all-solid-state cell as it is charged up to 5 V, with evolution beginning at ca. 4 V highlighting the requirement of stabilising interfaces even when a solid-state electrolyte is used. Figure 1. Comparison of O2 and CO2 gas evolution from (a) Li6PS5Cl and (b) LiNi0.6Mn0.2Co0.2O2/ Li6PS5Cl composite when charged to 5 V vs. Li/Li+. [1] L. Zhou, N. Minafara, W. G. Zeier, L. F. Nazar, Innovative Approaches to Li-Argyrodite Solid Electrolytes for All-Solid-State Lithium Batteries, Acc. Chem. Res., 54, (2021) 2717–2728 [2] Y. Zhou, C. Doerrer, J. Kasemchainan, P. G. Bruce, M. Pasta, L. J. Hardwick, Observation of Interfacial Degradation of Li6PS5Cl against Lithium Metal and LiCoO2 via In Situ Electrochemical Raman Microscopy, Batter. & Supercaps, 3, (2020) 647 –652 [3] F. Walther, R. Koerver, T. Fuchs, S. Ohno, J. Sann, M. Rohnke, W. G. Zeier, J. Janek, Visualization of the Interfacial Decomposition of Composite Cathodes in Argyrodite-Based All-Solid-State Batteries Using Time-of-Flight Secondary-Ion Mass Spectrometry, Chem. Mater, 31, (2019), 3745-3755 [4]S. Shariﬁ-Asl, J. Lu, K. Amine, R. Shahbazian-Yassar, Oxygen Release Degradation in Li-Ion Battery Cathode Materials: Mechanisms and Mitigating Approaches, Adv. Energy Mater., 9, (2019) 1900551 [5] H. Kim, A. Choi, S. W. Doo, J. Lim, Y. Kim, K. T. Lee, Role of Na+ in the cation disorder of [Li1-xNax] NiO2 as a cathode for lithium-ion batteries, J. Electrochem. Soc., 165, (2018), A201 Figure 1

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Zhang, Shumin, Feipeng Zhao e Xueliang Andy Sun. "Interface Engineering Via Fluorinated Solid Electrolytes for All-Solid-State Li Batteries". ECS Meeting Abstracts MA2022-01, n.º 2 (7 de julho de 2022): 159. http://dx.doi.org/10.1149/ma2022-012159mtgabs.

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Solid electrolytes (SEs) are vital for all-solid-state batteries (ASSBs) since they replace the flammable liquid electrolytes to make the ASSBs safer and compacter.1 In order to boost the energy density of ASSBs, a practical SE is not only expected possessing high ionic conductivity, but also good compatibility with both cathode and anode to allow the use of high-voltage cathode and Li metal.2, 3 However, most of the developed SEs show limitations on directly contact with either high-voltage cathode materials or Li metal. As such, SE modification is required to address the interfacial issues between SE and electrodes. In this work, fluorinated sulfide- and halide-based SEs are proposed to stabilize the SE/Li metal and SE/high-voltage cathode interfaces, respectively. Our results firstly show that fluorinated argyrodite Li6PS5Cl (LPSCl) can enhance the interfacial stability toward the Li metal anode.4 The in-situ formed interface between Li and LPSCl1−xFx are of highly fluorinated and condense, which enables ultrastable Li plating/stripping behavior over 250 hrs at a high current density of 6.37 mA cm−2 and a cutoff capacity of 5 mAh cm−2. The Li metal treated by the LPSCl1−xFx SE is then demonstrated to deliver good durability and rate capability in full cells. Other than anode side improvement, F is introduced into a superionic conductor Li3InCl6 to widen the oxidation limit to over 6 V (vs. Li/Li+).5 Both experimental and computational results identify that F-containing passivating interphases are generated to contribute to the enhanced oxidation stability of Li3InCl6-xFx and stabilization the surface of cathodes at high cut-off voltages. The optimized composition Li3InCl4.8F1.2 is directly matched with bare high-voltage LiCoO2, enabling ASSBs to stably operate at room temperature at a cut-off voltage of 4.8 V (vs Li/Li+). Our studies provide a new strategy of interface engineering by introducing F in SEs, realizing the good compatibility between SE and electrodes and opening up the applications of ASSBs. Re ferences Manthiram, A., Yu, X. W., Wang, S. F. Lithium battery chemistries enabled by solid-state electrolytes. Nat. Rev . Mater. 2, 1-16 (2017). Wang, C. H., Liang, J. W., Zhao, Y., Zheng, M. T., Li, X. N., Sun, X. L. All-solid-state lithium batteries enabled by sulfide electrolytes: from fundamental research to practical engineering design. Energy Environ. Sci. 14, 2577-2619 (2021). Li, J. C., Ma, C., Chi, M. F., Liang, C. D., Dudney, N. J. Solid Electrolyte: the Key for High-Voltage Lithium Batteries. Adv. Energy Mater. 5, 1401408 (2015). Zhao, F. P., et al. Ultrastable Anode Interface Achieved by Fluorinating Electrolytes for All-Solid-State Li Metal Batteries. ACS Energy Lett. 5, 1035-1043 (2020). Zhang, S. M., et al. Advanced High-Voltage All-Solid-State Li-Ion Batteries Enabled by a Dual-Halogen Solid Electrolyte. Adv. Energy Mater. 11, 2100836 (2021).

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Sakuda, Atsushi. "Favorable composite electrodes for all-solid-state batteries". Journal of the Ceramic Society of Japan 126, n.º 9 (1 de setembro de 2018): 675–83. http://dx.doi.org/10.2109/jcersj2.18114.

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Huang, Yonglin, Bowen Shao e Fudong Han. "Interfacial challenges in all-solid-state lithium batteries". Current Opinion in Electrochemistry 33 (junho de 2022): 100933. http://dx.doi.org/10.1016/j.coelec.2021.100933.

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Kasemchainan, Jitti, e Peter G. Bruce. "All-Solid-State Batteries and their Remaining Challenges". Johnson Matthey Technology Review 62, n.º 2 (1 de abril de 2018): 177–80. http://dx.doi.org/10.1595/205651318x696747.

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Hiralal, Pritesh, Shinji Imaizumi, Husnu Emrah Unalan, Hidetoshi Matsumoto, Mie Minagawa, Markku Rouvala, Akihiko Tanioka e Gehan A. J. Amaratunga. "Nanomaterial-Enhanced All-Solid Flexible Zinc−Carbon Batteries". ACS Nano 4, n.º 5 (23 de abril de 2010): 2730–34. http://dx.doi.org/10.1021/nn901391q.

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Braun, P., C. Uhlmann, M. Weiss, A. Weber e E. Ivers-Tiffée. "Assessment of all-solid-state lithium-ion batteries". Journal of Power Sources 393 (julho de 2018): 119–27. http://dx.doi.org/10.1016/j.jpowsour.2018.04.111.

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Azhari, Luqman, Sungyool Bong, Xiaotu Ma e Yan Wang. "Recycling for All Solid-State Lithium-Ion Batteries". Matter 3, n.º 6 (dezembro de 2020): 1845–61. http://dx.doi.org/10.1016/j.matt.2020.10.027.

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Casalbore-Miceli, G., G. Giro, G. Beggiato, P. G. Di Marco e A. Geri. "All-solid-state batteries based on conducting polymers". Synthetic Metals 41, n.º 3 (maio de 1991): 1119–22. http://dx.doi.org/10.1016/0379-6779(91)91566-s.

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Kim, Youngki, Xianke Lin, Armin Abbasalinejad, Sun Ung Kim e Seung Hyun Chung. "On state estimation of all solid-state batteries". Electrochimica Acta 317 (setembro de 2019): 663–72. http://dx.doi.org/10.1016/j.electacta.2019.06.023.

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Kato, Yuki, Shinya Shiotani, Keisuke Morita, Kota Suzuki, Masaaki Hirayama e Ryoji Kanno. "All-Solid-State Batteries with Thick Electrode Configurations". Journal of Physical Chemistry Letters 9, n.º 3 (22 de janeiro de 2018): 607–13. http://dx.doi.org/10.1021/acs.jpclett.7b02880.

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Qu, Hang, Xin Lu e Maksim Skorobogatiy. "All-Solid Flexible Fiber-Shaped Lithium Ion Batteries". Journal of The Electrochemical Society 165, n.º 3 (2018): A688—A695. http://dx.doi.org/10.1149/2.1001803jes.

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Liao, Jared, Joel Kirner e Feng Zhao. "Mitigating Interfacial Issues in All-Solid-State Batteries". ECS Meeting Abstracts MA2020-02, n.º 5 (23 de novembro de 2020): 952. http://dx.doi.org/10.1149/ma2020-025952mtgabs.

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Battaglia, Corsin. "(Invited) Interface Stability in All-Solid-State Batteries". ECS Meeting Abstracts MA2020-02, n.º 5 (23 de novembro de 2020): 965. http://dx.doi.org/10.1149/ma2020-025965mtgabs.

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Kim, Se‐Hee, Jung‐Hui Kim, Sung‐Ju Cho e Sang‐Young Lee. "All‐Solid‐State Printed Bipolar Li–S Batteries". Advanced Energy Materials 9, n.º 40 (5 de setembro de 2019): 1901841. http://dx.doi.org/10.1002/aenm.201901841.

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Notten, P. H. L., F. Roozeboom, R. A. H. Niessen e L. Baggetto. "3-D Integrated All-Solid-State Rechargeable Batteries". Advanced Materials 19, n.º 24 (17 de dezembro de 2007): 4564–67. http://dx.doi.org/10.1002/adma.200702398.

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Asano, Tetsuya, Masashi Sakaida, Akihiro Sakai, Akinobu Miyazaki e Shinya Hasegawa. "(Invited) Solid Halide Electrolytes for All-Solid-State Lithium Ion Batteries". ECS Meeting Abstracts MA2020-01, n.º 2 (1 de maio de 2020): 270. http://dx.doi.org/10.1149/ma2020-012270mtgabs.

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Zheng, Feng, Masashi Kotobuki, Shufeng Song, Man On Lai e Li Lu. "Review on solid electrolytes for all-solid-state lithium-ion batteries". Journal of Power Sources 389 (junho de 2018): 198–213. http://dx.doi.org/10.1016/j.jpowsour.2018.04.022.

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Trevey, James E., Jeremy R. Gilsdorf, Sean W. Miller e Se-Hee Lee. "Li2S–Li2O–P2S5 solid electrolyte for all-solid-state lithium batteries". Solid State Ionics 214 (abril de 2012): 25–30. http://dx.doi.org/10.1016/j.ssi.2012.02.034.

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Hiraoka, Koji, Masaki Kato, Takeshi Kobayashi e Shiro Seki. "Polyether/Na3Zr2Si2PO12 Composite Solid Electrolytes for All-Solid-State Sodium Batteries". Journal of Physical Chemistry C 124, n.º 40 (10 de setembro de 2020): 21948–56. http://dx.doi.org/10.1021/acs.jpcc.0c05334.

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Rao, R. P., e S. Adams. "Studies of lithium argyrodite solid electrolytes for all-solid-state batteries". physica status solidi (a) 208, n.º 8 (30 de junho de 2011): 1804–7. http://dx.doi.org/10.1002/pssa.201001117.

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Kim, Jae-Kwang, Johan Scheers, Tae Joo Park e Youngsik Kim. "Superior Ion-Conducting Hybrid Solid Electrolyte for All-Solid-State Batteries". ChemSusChem 8, n.º 4 (13 de novembro de 2014): 636–41. http://dx.doi.org/10.1002/cssc.201402969.

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Zheng, Mingyuan, Xin Li, Jianwei Sun, Xinlu Wang, Guixia Liu, Wensheng Yu, Xiangting Dong e Jinxian Wang. "Research progress on chloride solid electrolytes for all-solid-state batteries". Journal of Power Sources 595 (março de 2024): 234051. http://dx.doi.org/10.1016/j.jpowsour.2024.234051.

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Zhang, Jiarui. "Research Progress of Thin Film Structures of All-Solid-State Lithium-Ion Battery". Highlights in Science, Engineering and Technology 83 (27 de fevereiro de 2024): 548–52. http://dx.doi.org/10.54097/g2mbv453.

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The need for portable power sources has increased quickly with the advent of the electronic information era. Due to the significant benefits of lithium-ion batteries' high voltage, high capacity, and extended cycle life, these batteries have a wide range of potential applications in a variety of industries, including portable electronic gadgets, electric vehicles, and space technology. Lithium-ion batteries may cause safety issues such as thermal runaway under harsh conditions. By employing solid electrolytes in the thin layer of all-solid-state lithium batteries (TFLIBs) instead of organic liquid electrolytes, the safety issues with current commercial lithium-ion batteries may be effectively remedied. They outperform bulk solid-state lithium batteries, which has made the industry pay close attention to them. Because they directly affect the charge-discharge rate, cycle life, self-discharge, safety, and high and low-temperature performance of thin film batteries, electrolyte thin films play a crucial role in TFLIBs. This paper reviews three innovative thin film structures, their different benefits and drawbacks, the most current research on them, and projections for their future development to serve as a reference for future research on lithium-ion batteries.

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