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Artigos de revistas sobre o assunto "(AIGa)N quantum dots"

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Barettin, Daniele, Alexei V. Sakharov, Andrey F. Tsatsulnikov, Andrey E. Nikolaev e Nikolay Cherkashin. "Electromechanically Coupled III-N Quantum Dots". Nanomaterials 13, n.º 2 (5 de janeiro de 2023): 241. http://dx.doi.org/10.3390/nano13020241.

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We exploit the three-dimensional (3D) character of the strain field created around InGaN islands formed within the multilayer structures spaced by a less than 1-nm-thick GaN layer for the creation of spatially correlated electronically coupled quantum dots (QDs). The laterally inhomogeneous vertical out-diffusion of In atoms during growth interruption is the basic mechanism for the formation of InGaN islands within as-deposited 2D layers. An anisotropic 3D strain field created in the first layer is sufficient to justify the vertical correlation of the islands formed in the upper layers spaced by a sufficiently thin GaN layer. When the thickness of a GaN spacer exceeds 1 nm, QDs from different layers under the same growth conditions emit independently and in the same wavelength range. When extremely thin (less than 1 nm), a GaN spacer is formed solely by applying short GI, and a double wavelength emission in the blue and green spectral ranges evidences the electromechanical coupling. With k→·p→ calculations including electromechanical fields, we model the optoelectronic properties of a structure with three InGaN lens-shaped QDs embedded in a GaN matrix, with three different configurations of In content. The profiles of the band structures are strongly dependent on the In content arrangement, and the quantum-confined Stark effect is significantly reduced in a structure with an increasing gradient of In content from the top to the bottom QD. This configuration exhibits carrier tunneling through the QDs, an increase of wave functions overlap, and evidence emerges of three distinct peaks in the spectral range.
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Huault, Thomas, Julien Brault, Franck Natali, Benjamin Damilano, Denis Lefebvre, Rabih Tauk, Mathieu Leroux e Jean Massies. "GaN/Al0.5 Ga0.5 N quantum dots and quantum dashes". physica status solidi (b) 246, n.º 4 (15 de janeiro de 2009): 842–45. http://dx.doi.org/10.1002/pssb.200880614.

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Roy, Santanu, Christopher Tuinenga, Fadzai Fungura, Pinar Dagtepe, Viktor Chikan e Jacek Jasinski. "Progress toward Producing n-Type CdSe Quantum Dots: Tin and Indium Doped CdSe Quantum Dots". Journal of Physical Chemistry C 113, n.º 30 (julho de 2009): 13008–15. http://dx.doi.org/10.1021/jp8113946.

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Gu, Siyong, Chien-Te Hsieh, Yasser Ashraf Gandomi, Jianlin Li, Xing Xing Yue e Jeng-Kuei Chang. "Tailoring fluorescence emissions, quantum yields, and white light emitting from nitrogen-doped graphene and carbon nitride quantum dots". Nanoscale 11, n.º 35 (2019): 16553–61. http://dx.doi.org/10.1039/c9nr05422g.

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Highly fluorescent N-doped graphene quantum dots (NGQDs) and graphitic carbon nitride quantum dots (CNQDs, g-C3N4) were synthesized using a solid-phase microwave-assisted (SPMA) technique.
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Jeong, Kwang Seob, Zhiyou Deng, Sean Keuleyan, Heng Liu e Philippe Guyot-Sionnest. "Air-Stable n-Doped Colloidal HgS Quantum Dots". Journal of Physical Chemistry Letters 5, n.º 7 (19 de março de 2014): 1139–43. http://dx.doi.org/10.1021/jz500436x.

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McCarthy, S. A., J. B. Wang e P. C. Abbott. "Electronic structure calculation for N-electron quantum dots". Computer Physics Communications 141, n.º 1 (novembro de 2001): 175–204. http://dx.doi.org/10.1016/s0010-4655(01)00401-5.

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Naik, M. Jaya Prakash, Sourajit Mohanta, Peetam Mandal e Mitali Saha. "N-Doped Graphene Quantum Dots Using Different Bases". International Journal of Nanoscience 18, n.º 01 (24 de janeiro de 2019): 1850017. http://dx.doi.org/10.1142/s0219581x18500175.

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Photoluminescent graphene quantum dots (GQDs) have received tremendous attention due to their sui generis chemical, electronic and optical properties but fabricating the pristine quality of GQD is extremely challenging. Herein, we have reported the pyrolysis of citric acid which in the presence of different bases viz. triethylamine, ammonium hydroxide and urea, produced N-doped GQDs at different pH. The effect of different pH has been studied in detail to optimize the formation conditions of the GQD. Ultraviolet–visible (UV–Vis) spectroscopy and normalized fluorescence spectra were applied to analyze the optical properties of the GQD. The mean particle size was analyzed by a particle size analyzer (dynamic light dispersion).
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Shiralizadeh Dezfuli, Amin, Elmira Kohan, Sepand Tehrani Fateh, Neda Alimirzaei, Hamidreza Arzaghi e Michael R. Hamblin. "Organic dots (O-dots) for theranostic applications: preparation and surface engineering". RSC Advances 11, n.º 4 (2021): 2253–91. http://dx.doi.org/10.1039/d0ra08041a.

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Organic dots is a term used to represent materials including graphene quantum dots and carbon quantum dots because they rely on the presence of other atoms (O, H, and N) for their photoluminescence or fluorescence properties. Cargo delivery, bio-imaging, photodynamic therapy and photothermal therapy are major biomedical applications of organic dots.
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Mansur, Herman S., Alexandra A. P. Mansur, Elisabete Curti e Mauro V. De Almeida. "Bioconjugation of quantum-dots with chitosan and N,N,N-trimethyl chitosan". Carbohydrate Polymers 90, n.º 1 (setembro de 2012): 189–96. http://dx.doi.org/10.1016/j.carbpol.2012.05.022.

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Zhang, Lin Lin, Jia Huan Wu, Chun Hui Shi e Yu Guang Lv. "Preparation of Cadmium Telluride Quantum Dots Modified by Thioglycolic Acid". Key Engineering Materials 915 (29 de março de 2022): 95–100. http://dx.doi.org/10.4028/p-m485h7.

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A CdTe quantum dot modified with thioglycolic acid as stabilizer was prepared. The structure of CdTe quantum dots was characterized by IR, UV and fluorescence spectra, transmission electron microscopy (TEM) scanning and X-ray diffraction (XRD). The effects of reactants, temperature, time and PH on the luminescence properties of the quantum dots were investigated. It is found that the quantum dots have strong fluorescence intensity. The synthesized QDS have small and uniform particle size and high crystallinity. The optimum conditions were determined as follows: n (Cd2+): n (Te2-): n (TGA) = 2:1:4, heating temperature 140°C, reaction time 60min, pH 11.
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Teses / dissertações sobre o assunto "(AIGa)N quantum dots"

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Nikitskiy, Nikita. "Propriétés d'émetteurs ultra-violets à base d'hétérostructures quantiques et de métasurfaces (Al,Ga)N". Electronic Thesis or Diss., Université Côte d'Azur, 2024. http://www.theses.fr/2024COAZ5081.

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Les diodes électroluminescentes (LED) sont essentielles dans les technologies modernes, permettant une large gamme d'applications allant de l'éclairage à des usages spécialisés dans les domaines médicaux et environnementaux. Les LED ultra-violettes (UV), basées sur des hétérostructures à base d'alliages de nitrure d'aluminium et de gallium ((Al,Ga)N) avec des émetteurs quantiques, présentent un grand potentiel pour des applications telles que la stérilisation, la purification de l'eau et le diagnostic médical, grâce à leur efficacité énergétique, leur compacité et leur durée de vie plus longue par rapport aux lampes au mercure conventionnelles. Les systèmes à base d'(Al,Ga)N possèdent une bande interdite directe large et ajustable et est comprise entre 3.4 eV et 6.2 eV ce qui équivaut à une longueur d'onde d'émission de 365 nm et 200 nm respectivement. Cela fait rend particulièrement adaptés à l'émission de lumière sur un large spectre de longueurs d'onde dans la gamme UV, tandis que la capacité de dopage du matériau permet de réaliser des régions de type négatif (type n) et de type positif (type p), ce qui est nécessaire pour fabrication des LED. Malgré ces avantages, les LED UV basées sur l'(Al,Ga)N souffrent actuellement d'une efficacité quantique plus faible que à leurs homologues émettant dans le visible, en particulier en raison de la forte densité de défauts, des effets de polarisation de l'émission et de la faible extraction de la lumière. Cette thèse explore différentes voies permettant de remédier à ces problèmes. En particulier, l'utilisation de métasurfaces optiques, c'est-à-dire de réseaux de nanostructures, est envisagée pour améliorer l'émission des hétérostructures (Al,Ga)N. Le chapitre 1 présente l'état de l'art dans ce domaine ainsi que la motivation de ce travail. Le chapitre 2 offre une vue d'ensemble complète des propriétés fondamentales des matériaux (Al,Ga)N, notamment leurs caractéristiques cristallographiques et optiques. Il décrit également la croissance par épitaxie par jets moléculaires des boîtes quantiques (Al,Ga)N utilisées dans ce travail. Au chapitre 3, nous étudions expérimentalement l'influence de la relaxation mécanique des hétérostructures et de la qualité cristalline sur les propriétés optiques des boîtes quantiques émettant dans la gamme UV. Le chapitre 4 examine en profondeur la réponse photonique des matériaux (Al,Ga)N, offrant une analyse théorique et expérimentale des mécanismes d'interaction de la lumière et de la polarisation de l'émission. Enfin, le chapitre 5 traite de l'intégration des métasurfaces avec des émetteurs UV basés sur (Al,Ga)N pour améliorer le contrôle de l'émission et les performances globales du dispositif. L'utilisation de métasurfaces, capables de manipuler la lumière à l'échelle sub-longueur d'onde, est explorée comme une stratégie prometteuse pour augmenter l'extraction de la lumière en dirigeant et contrôlant l'émission dans la gamme UV
Light-emitting diodes (LEDs) are essential in modern technology, enabling a wide range of applications from general lighting to specialized uses in medical and environmental fields. Ultraviolet (UV) LEDs, based on heterostructures of aluminum gallium nitride alloys ((Al,Ga)N) with quantum emitters, hold significant promise for applications in sterilization, water purification, and medical diagnostics due to their energy efficiency, compact form, and longer lifespan compared to conventional mercury lamps.The(Al,Ga)N-based systems have a wide and tunable direct band gap ranging from 3.4 eV to 6.2 eV, which is equivalent to emission wavelengths of 365 nm and 200 nm, respectively. This makes them particularly suitable for light emission over a broad wavelength spectrum in the UV range, while the material doping capability supports both n-type and p-type doping regions, which is necessary for LED fabrication. Despite these advantages, UV LEDs based on (Al,Ga)N currently suffer from lower quantum efficiency compared to their visible-light counterparts, particularly due to high defect densities, emission polarization effects, and overall low light extraction.This work explores these challenges in more detail and also considers the possibility of improving the radiative characteristics of (Al,Ga)N heterostructures by embedding them into a metasurface. Chapter 1 introduces the state of the art in this topic and the motivation for this work. Chapter 2 presents a comprehensive overview of the fundamental properties of (Al,Ga)N materials, including their crystallographic and optical characteristics. It also describes the Molecular Beam Epitaxy growth of (Al,Ga)N quantum dots (QDs) used in this work. In Chapter 3, we experimentally investigate the influence of the mechanical relaxation of the heterostructures and the crystalline quality on the optical properties of the QDs emitting in the UV range. Chapter 4 delves into the photonic response of (Al,Ga)N materials, offering a theoretical and experimental analysis of light interaction mechanisms and emission polarization. Finally, Chapter 5 discusses the integration of metasurfaces with (Al,Ga)N-based UV emitters for improving emission control and overall device performance. The use of metasurfaces, which can manipulate light at the subwavelength scale, is explored as a promising strategy to increase light extraction efficiency by directing and controlling emission in the UV range
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Ferguson, A. "Electron transport in n-type SiGe double quantum dots". Thesis, University of Cambridge, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.598980.

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This thesis presents an experimental investigation into the properties of highly doped (nphosphorous ~ 1.4 x 1019cm-3) n-type silicon-germanium double quantum dots. The structures are fabricated with a diameter of between 40nm and 70nm by means of electron beam lithography. Their electronic properties are then measured using a variety of cryogenic techniques, including a dilution refrigerator with a base temperature of 20mK. The main results from this investigation are described below. The ‘Coulomb Oscillations’ form a hexagonal lattice as the electrochemical potentials on the two dots are shifted by means of electrostatic gates. This indicates that the double dot is indeed a double well potential, and shows that the electron number on the dots can be independently altered. The elastrostatic gates are shown to have a wide degree of control over not just the electrochemical potential on the dots, but also the shape of the potential well. In this way, the two wells can be induced to coalesce; one of the wells can be merged into its nearby lead; or the coupling parameters between the dots and dots and leads can be altered. A supplementary piece of work, undertaken in collaboration with Paul Cain, is presented in appendix A. This describes an original scheme for quantum computation in which the ammonia molecule is used as the qubit. It is confined within a fullerene and placed on a crystal surface where gates and global microwave pulses manipulate, and interact it with other such encapsulated ammonia molecules. Finally, measurements is performed with an electrometer which has the ability to distinguish the polarisability of the ammonia molecule’s eigenstates.
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Yu, Kuan-Hung. "Optical Spectroscopy of GaN/Al(Ga)N Quantum Dots Grown by Molecular Beam Epitaxy". Thesis, Department of Physics, Chemistry and Biology, 2009. http://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-19821.

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GaN quantum dots grown by molecular beam epitaxy are examined by micro-photoluminescence. The exciton and biexciton emission are identified successfully by power-dependence measurement. With two different samples, it can be deduced that the linewidth of the peaks is narrower in the thicker deposited layer of GaN. The size of the GaN quantum dots is responsible for the binding energy of biexciton (EbXX); EbXX decreases with increasing size of GaN quantum dots. Under polarization studies, polar plot shows that emission is strongly linear polarized. In particular, the orientation of polarization vector is not related to any specific crystallography orientation. The polarization splitting of fine-structure is not able to resolve due to limited resolution of the system. The emission peaks can be detected up to 80 K. The curves of transition energy with respect to temperature are S-shaped. Strain effect and screening of electric field account for  blueshift of transition energy, whereas Varshni equation stands for redshifting. Both blueshifting and redshifting are compensated at temperature ranging from 4 K to 40 K.

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Bruce, Jocelyn Catherine. "Use of the N,N-dialkyl-N’-benzoyl(thio)selenoureas as single source precursors for the synthesis of semiconducting quantum dots". Thesis, Stellenbosch : Stellenbosch University, 2008. http://hdl.handle.net/10019.1/1205.

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Thesis (PhD (Chemistry and Polymer Science))--Stellenbosch University, 2008.
The successful preparation and structural characterization of a number of N,N-dialkyl-N’-benzoyl(thio)selenourea ligands is described; where the intermolecular interactions are characterized by the presence of Resonance Assisted Hydrogen Bonding (RAHB), π- π interactions between neighbouring benzene residues only being evident amongst the longer alkyl chain derivatives. The first structural characterization of an asymmetrically substituted N,N-dialkyl- N’-benzoylselenourea ligand reveals an increased stability of the Z isomer in the solid state, this being reflected by the sulfur analogue. Attempts to synthesise N,N-dicyclohexyl-N’-benzoylselenourea led to the isolation and structural characterization of a novel 1,3,5-oxaselenazine salt and dicyclohexylaminobenzoate. The first structural characterization of a “bipodal” N,N-dialkyl-N’-benzoylselenourea ligand, 3,3,3’,3’-tetrabutyl-1,1’- isophthaloylbis(selenourea), reveals RAHB in the crystal lattice similar to that exhibited by the “monopodal” analogue, N,N-dibutyl-N’-benzoylselenourea. The successful complexation of the N,N-dialkyl-N’-benzoyl(thio)selenourea ligands to a number of different transition metal ions is reported allowing the preparation of several potential single source precursors. Coordination through the O and Se/S donor atoms to Pd(II) results in the formation of square planar metal complexes, with a cis conformation, several of which could be structurally characterized. In particular, the first structural elucidation of an asymmetrically substituted N,N-dialkyl-N’-benzoylselenourea metal complex, cis-bis(N-benzyl-N-methyl-N’- benzoylselenoureato)palladium(II) indicates the increased stability of the EZ isomer in the solid state. Structural elucidation of the novel (N,N-diphenyl-N’-benzoylselenoureato)cadmium(II) reveals a bimetallic complex in the solid state, where the expected 2:1 ligand : metal ratio is maintained, and the two Cd(II) centres are 5 and 6 coordinated, with O and Se donor atoms. Multinuclear Nuclear Magnetic Resonance (NMR) Spectroscopy has been employed in the thorough characterisation of the potential single source precursors, 77Se NMR spectroscopy indicating a decreased shielding of the 77Se nucleus as the “hardness” of the central metal ion increases i.e. Pd(II) > Zn(II) > Cd(II). Use of 113Cd NMR spectroscopy indicates the preferential binding of N,N-diethyl-N’- benzoylselenourea to Cd(II) over that of its sulfur analogue, and initial studies suggest a form of chelate metathesis taking place in solution. 31P NMR spectroscopy is used to gain insight into the formation of cis-bis(N,N-diethyl-N’- benzoylselenoureato)Pt(II). Thermolysis of (N,N-diethyl-N’-benzoylselenoureato)cadmium(II) and its sulfur analogue led to the successful synthesis of CdSe and CdS quantum dots respectively, where thermolysis over a range of temperatures allows a degree of size control over the resulting nanoparticles. The effect of precursor alkyl chain length on nanoparticle morphology was investigated for both the N,N-dialkyl-N’-benzoylthio- and –selenoureas. A correlation between the two for the (N,N-dialkyl-N’-benzoylselenoureato)Cd(II) complexes is described and possible growth mechanisms are discussed. Preliminary investigations into the use of other N,N-dialkyl-N’-benzoyl(thio)selenourea metal complexes as single source precursors reveal that both (N,N-diethyl-N’-benzoylselenoureato)Zn(II) and its sulfur analogue show potential as single source precursors for the formation of ZnO and ZnS nanoparticles respectively. Initial studies into the use of N,N-dialkyl-N’-benzoyl(thio)selenourea metal complexes as single source precursors for the synthesis of core-shell nanoparticles is briefly described. The Aerosol Assisted Chemical Vapour Deposition (AACVD) of several N,N-dialkyl-N’-benzoyl(thio)selenourea metal complexes is reported, where both (N,N-diethyl-N’-benzoylselenoureato)Cd(II) and its sulfur analogue allow the deposition of crystalline CdSe and CdS respectively. The AACVD of (N,N-diethyl-N’- benzoylselenoureato)Zn(II) leads to the deposition of crystalline ZnSe, ZnS being deposited by (N,N-diethyl-N’-benzoylthioureato)Zn(II). The deposition of heazelwoodite (Ni3S2) with varying morphologies results from the AACVD of cis-bis(N,N-diethyl-N’-benzoylthioureato)Ni(II). Thermal annealing of the amorphous material deposited by the AACVD of cis-bis(N,N-diethyl-N’-benzoylthioureato)Pd(II), allows the formation of highly crystalline palladium. The deposition of metallic platinum using cis-bis(N,N-diethyl-N’-benzoylthioureato)Pt(II) is described as well as the deposition of crystalline Pd17Se15 from cis-bis(N,N-diethyl-N’-benzoylselenoureato)Pd(II). This, to the best of our knowledge, is the first time that AACVD has been performed, using the N,N-dialkyl-N’- benzoyl(thio)selenourea metal complexes as single source precursors, in addition, we believe it to be the first time that palladium selenide has been deposited using the AACVD technique.
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Menezes, Alan Silva de. "Estudo estrutural de nanossistemas semicondudores e semicondutores implantados por difração de raios-X de n-feixes". [s.n.], 2010. http://repositorio.unicamp.br/jspui/handle/REPOSIP/278200.

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Orientador: Lisandro Pavie Cardoso
Tese (doutorado) - Universidade Estadual de Campinas, Instituto de Física Gleb Wataghin
Made available in DSpace on 2018-08-17T08:00:52Z (GMT). No. of bitstreams: 1 Menezes_AlanSilvade_D.pdf: 23119383 bytes, checksum: ab5e971a0c297e969fddfdd4a44a73a6 (MD5) Previous issue date: 2010
Resumo: Neste trabalho, a difração múltipla (DM) de raios-X associada com as vantagens da radiação síncrotron configura-se como uma microssonda de alta resolução e é utilizada para obter relevantes contribuições ao estudo das propriedades estruturais de materiais semicondutores, apresentem-se eles como nanosistemas epitaxiais ou implantados com íons. O estudo e detecção de reflexões híbridas (interação camada epitaxial/substrato) coerentes (CHR) negativas nas varreduras Renninger (RS) do substrato é uma das contribuições desta tese. O mapeamento ?:f da condição de difração da reflexão secundária (113)(111) mostra que a CHR negativa que aparece é, na realidade, a interferência destrutiva entre a reflexão secundária da rede da camada e a reflexão primária do substrato. Ressalta-se aqui importância da medida detalhada da condição de difração de reflexões secundárias adequadas da DM. O uso do caso especial da DM denominado difração Bragg-superfície (BSD), cuja reflexão secundária se propaga paralelamente à superfície dos monocristais ou interfaces nas heteroestruturas, quando envolve reflexões secundárias que são sensíveis à simetria da rede cristalina, constitui outra contribuição da tese. O pico na RS para o substrato (GaAs), que representa o caso de quatro-feixes (000)(004)(022)(022) e que se separa em dois picos na RS da camada GaInP por distorção tetragonal foi utilizado como uma nova ferramenta no estudo de deformações tetragonais, mesmo para camadas epitaxiais finas. Além disso, a presença de distorções ortorrômbicas ou até mesmo monoclínicas, pode ser investigada pela medida dos dois pares de picos secundários (022)(022) e (202)(202), também presentes na mesma RS da camada ternária. Outras contribuições desta tese estão na aplicação da DM no estudo de amostras de SiO2/Si(001) implantadas com íons Fe+, que passaram pelo processo de cristalização epitaxial induzida por feixe de íons (IBIEC) e, finalmente, por tratamento térmico. Mapeamentos ?:f do pico BSD (000)(002)(111) forneceram parâmetros de rede e tensões nas direções perpendiculares e paralelas com relação à superfície, para as regiões tensionadas provocadas por formação das nanopartículas da fase ?-FeSi2 produzidas por IBIEC. Para outro conjunto de amostras semelhantes exceto pela ausência do óxido a interessante formação de nanopartículas da fase ?-FeSi2 sob a forma de placas orientadas na amostra IBIEC, que foram observadas por microscopia e confirmadas por curvas de rocking (002) na condição de DM para os picos BSD (111) e (111) e mapeamentos ?:f, provocou tensões anisotrópicas no plano da superfície da amostra IBIEC. Formas esféricas das nanopartículas também detectadas por microscopia introduzem tensões isotrópicas e a caracterização estrutural das amostras foi realizada da mesma maneira mencionada acima. Medidas dos mapeamentos do espaço recíproco (RSM) com reflexões simétricas e assimétricas foram importante para confirmar os resultados obtidos por MD das amostras implantadas, por permitir observar a variação de composição lateral e periódica existente na camada de GaInP, assim como, por confirmar o efeito da altura dos pontos quânticos de InP sobre a camada ternária, no nível de tensão provocado por eles na camada de recobrimento desses pontos, ou seja, quanto maior a altura maior o nível de tensão na camada
Abstract: In this paper, X-ray multiple diffraction (MD) associated with the advantages of synchrotron radiation appears as a high-resolution microprobe and it is used to obtain relevant contributions to the study of structural properties of semiconductor materials, as they present themselves nanosystems epitaxial or implanted with ions. The study and detection of negative hybrid reflections (interaction epitaxial layer/substrate) coherent (CHR) in substrate Renninger scans (RS) is one of the contributions of this thesis. The ?:f mapping, i.e., the scanning of the (113)(111) secondary reflection diffraction condition shows that the CHR negative that appears is, in fact, the destructive interference between the layer secondary reflection and the substrate primary reflection. It is emphasized here the importance of a detailed measurement of the diffraction condition of adequate MD secondary reflections. The use of the MD special case named Bragg-Surface Diffraction (BSD), in which the secondary reflection propagates parallel to the single crystal surface or interfaces in heterostructures, when involves secondary reflections that are sensitive to the crystalline lattice symmetry, is another relevant contribution of this thesis. The substrate (GaAs) RS peak, which stands for the (000)(004)(022)(022) four-beam case that splits into two three-beam peaks GaInP layer RS by tetragonal distortion was used as a novel tool in the study of tetragonal distortions, even for thin epitaxial layers. Moreover, the presence of orthorhombic distortion or even monoclinic one, can be investigated by measuring the two pairs of secondary peaks (022)(022)and (202)(202) also present in the same ternary layer RS. Other thesis contributions are in the application of DM to the study of SiO2/Si(001) crystals implanted with Fe+, which were submitted to Ion Beam Induced Epitaxial Crystallization process (IBIEC) and then, annealed. ?:f mappings of the (000)(002)(111) BSD peak gave rise to perpendicular and in-plane lattice parameters and strains for the stressed regions provoked by the ?-FeSi2 nanoparticles formation provided by IBIEC. For another set of similar samples except for the absence of the oxide, the interesting formation of oriented plate-like ?-FeSi2 nanoparticles, that were observed by TEM and confirmed by (002) rocking curves obtained at MD condition for the BSD (111) and (1 peaks and the ?:f mappings that provided anisotropic in-plane strains in IBIEC sample. Nanoparticles spherical-like also detected by TEM induce isotropic strains and the samples structural characterization was obtained using the same above mentioned manner. Measurements of the reciprocal space mapping (RSM) using symmetric and asymmetric reflections were important to confirm the implanted crystal results obtained by MD by allowing to observe the periodic and lateral composition variation in the GaInP layer as well as, to confirm the effect of the height of InP quantum dots grown on the ternary layer in the strain degree they cause in the ternary cap layer, it means, the greater the height the greater the level of strain in the cap layer
Doutorado
Física da Matéria Condensada
Doutor em Ciências
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Jezequel, Julie. "Impact of psychotomimetic molecules on glutamatergic N-Methyl-D-Aspartate receptors surface trafficking". Thesis, Bordeaux, 2016. http://www.theses.fr/2016BORD0232/document.

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Les récepteurs glutamatergiques de type N-Méthyl-D-Aspartate (RNMDA) jouent un rôle majeur dans de nombreux processus physiologiques, et leur implication dans la physiopathologie de certains troubles neuropsychiatriques tels que la schizophrénie est suggérée par un robuste faisceau de données cliniques et précliniques. Cependant, les mécanismes cellulaires et moléculaires conduisant à une telle dérégulation des RNMDA restent inexpliqués. La diffusion membranaire, mécanisme de contrôle spatial et temporel de la distribution des RNMDA à la surface des neurones, constitue un puissant régulateur de la transmission synaptique. Mon projet de thèse repose ainsi sur l’hypothèse originale qu’une altération de la diffusion de surface des RNMDA jouerait un rôle central dans l’émergence de troubles psychotiques. Afin d‘explorer cette piste, j’ai étudié l’impact de molécules aux propriétés psychomimétiques (i.e induisant un état psychotique) sur la diffusion de surface des RNMDA. Les résultats obtenus au cours de ma thèse démontrent que des molécules psychomimétiques, aux modes d’action distincts (antagonistes du RNMDA et autoanticorps anti-RNMDA), perturbent la diffusion membranaire ainsi que la localisation synaptique des RNMDA, conduisant à terme à des défauts de transmission glutamatergique. Mon travail de thèse propose donc qu’un défaut de diffusion membranaire des RNMDA conduirait à des altérations fonctionnelles pouvant contribuer à l’émergence de troubles psychotiques. L’ensemble de mon travail apporte ainsi un regard nouveau sur la mécanistique des troubles psychotiques et ouvre la voie à de nouvelles pistes thérapeutiques
Glutamatergic N-Methyl-D-Aspartate receptors (NMDAR) play a key role in many physiological processes, and their implication in the pathophysiology of several neuropsychiatric disorders is now well established. Multiple lines of evidence converge towards a dysregulation of the NMDAR in psychotic disorders such as schizophrenia (SCZ). However, the molecular and cellular deficits underlying NMDAR dysfunction remain misunderstood. By tightly controlling NMDAR synaptic localization, surface trafficking represents a powerful regulator of synaptic transmission. Could an alteration of NMDAR surface trafficking underlie NMDAR dysfunction and contribute to the emergence of psychotic disorders? To tackle this question, my PhD project aimed at investigating the impact of different psychotomimetic molecules on NMDAR surface trafficking. In the first part of my project, I explored the impact of NMDAR autoantibodies (NMDAR-Ab) from SCZ and healthy subjects. My results revealed that NMDAR-Ab from SCZ patients rapidly disturb NMDAR synaptic trafficking and distribution, through a loss of NMDAR-EphrinB2 receptor interaction, eventually preventing the induction of synaptic plasticity. In the second part of my PhD project, I showed that psychotomimetic NMDAR antagonists also alter NMDAR synaptic mobility and localization. Downregulation of PSD proteins expression prevented NMDAR antagonists-induced deficits, suggesting that such alterations ensue from modifications of NMDAR intracellular interactions. Taken together, these results demonstrate that psychotomimetic molecules profoundly impact NMDAR surface trafficking, supporting a pathogenic role of this unsuspected process in the emergence of psychotic symptoms
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Pasquali, Valerio. "Fabrication and measurement of strain-free GaAs/AlAs quantum dot devices". Thesis, Paris 6, 2017. http://www.theses.fr/2017PA066631.

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Dans cette thèse, nous nous intéressons à la croissance de boîtes quantiques par formation de nano-trous in-situ par « droplet-etching » ainsi qu’à la fabrication et caractérisation de dispositifs basés sur ces nanostructures. La thèse comporte sept chapitres. Le premier chapitre est une introduction au sujet et les méthodes expérimentales sont présentées dans le second chapitre. Les méthodes de fabrication ainsi que les résultats expérimentaux obtenus sont discutés dans le troisième chapitre.Nous montrons que l’utilisation in-situ de la méthode de droplet-etching permet de modifier localement l’épaisseur d’un puits quantique à modulation de dopage et créer des boîtes quantiques dans le puits où existe un gaz bidimensionnel d’électrons. Ces nanostructures constituent des diodes n-i Schottky que nous avons étudié. Les effets de ces boîtes quantiques non-contraintes et les fluctuations d’épaisseur à l’échelle nanométrique du puits quantique sur la mobilité du gaz bidimensionnel d’électrons sont discutés dans le quatrième chapitre et cinquième. Le sixième chapitre présente la fabrication d’une jonction p-n latérale basée sur l’échantillon de puits quantique avec des boîtes. Nous discutons les différentes étapes de fabrication et analysons leur influence sur le dispositif, ainsi que leurs propriétés optiques. En particulier, nous démontrons l’électroluminescence d’une boîte unique localisée dans une jonction p-n latérale. Finalement, le dernier chapitre conclue ce travail et en présente les perspectives
In this thesis the formation of quantum dots (QD) via in-situ droplet nanohole etching, the fabrication and characterization of devices based on these nanostructures is described. The thesis consists of seven chapters. In the first chapter an introduction is given to present the topic to the reader. In the second chapter the experimental methods are presented. In the third chapter, the fabrication method is described and the experimental results obtained in this project are discussed. It will be shown the use of in-situ droplet etching to locally modify the thickness of a modulation doped quantum well, to create QDs embedded in a quantum well(QW) where a two dimensional electorn gas (2DEG) is confined by modulation doping and the embedding of these nanostructures in a n-i-Schottky diode. The effect of these strain-free dots, and the related nanoscale thickness fluctuations of the quantum well, on the 2DEG mobility are discussed in the fourth and in particular in the fifth chapter. In the sixth chapter, the fabrication of a lateral p-n junction based on the QW sample with embedded QD is presented. Following describing the fabrication stages and analysing the influence of each stage on the device, the optical properties of the junction will be discussed. In particular, it will be shown the electroluminescence of a single dot located at lateral the p-n junction. Finally, in the last chapter the conclusion of this work and the future projects are presented
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8

Pasquali, Valerio. "Fabrication and measurement of strain-free GaAs/AlAs quantum dot devices". Electronic Thesis or Diss., Paris 6, 2017. http://www.theses.fr/2017PA066631.

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Dans cette thèse, nous nous intéressons à la croissance de boîtes quantiques par formation de nano-trous in-situ par « droplet-etching » ainsi qu’à la fabrication et caractérisation de dispositifs basés sur ces nanostructures. La thèse comporte sept chapitres. Le premier chapitre est une introduction au sujet et les méthodes expérimentales sont présentées dans le second chapitre. Les méthodes de fabrication ainsi que les résultats expérimentaux obtenus sont discutés dans le troisième chapitre.Nous montrons que l’utilisation in-situ de la méthode de droplet-etching permet de modifier localement l’épaisseur d’un puits quantique à modulation de dopage et créer des boîtes quantiques dans le puits où existe un gaz bidimensionnel d’électrons. Ces nanostructures constituent des diodes n-i Schottky que nous avons étudié. Les effets de ces boîtes quantiques non-contraintes et les fluctuations d’épaisseur à l’échelle nanométrique du puits quantique sur la mobilité du gaz bidimensionnel d’électrons sont discutés dans le quatrième chapitre et cinquième. Le sixième chapitre présente la fabrication d’une jonction p-n latérale basée sur l’échantillon de puits quantique avec des boîtes. Nous discutons les différentes étapes de fabrication et analysons leur influence sur le dispositif, ainsi que leurs propriétés optiques. En particulier, nous démontrons l’électroluminescence d’une boîte unique localisée dans une jonction p-n latérale. Finalement, le dernier chapitre conclue ce travail et en présente les perspectives
In this thesis the formation of quantum dots (QD) via in-situ droplet nanohole etching, the fabrication and characterization of devices based on these nanostructures is described. The thesis consists of seven chapters. In the first chapter an introduction is given to present the topic to the reader. In the second chapter the experimental methods are presented. In the third chapter, the fabrication method is described and the experimental results obtained in this project are discussed. It will be shown the use of in-situ droplet etching to locally modify the thickness of a modulation doped quantum well, to create QDs embedded in a quantum well(QW) where a two dimensional electorn gas (2DEG) is confined by modulation doping and the embedding of these nanostructures in a n-i-Schottky diode. The effect of these strain-free dots, and the related nanoscale thickness fluctuations of the quantum well, on the 2DEG mobility are discussed in the fourth and in particular in the fifth chapter. In the sixth chapter, the fabrication of a lateral p-n junction based on the QW sample with embedded QD is presented. Following describing the fabrication stages and analysing the influence of each stage on the device, the optical properties of the junction will be discussed. In particular, it will be shown the electroluminescence of a single dot located at lateral the p-n junction. Finally, in the last chapter the conclusion of this work and the future projects are presented
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Tao, Zhi. "Photodétection dans une large gamme de longueur d’onde : phototransistor CdSe QDs/RGO sur des nanofils de ZnO dans la gamme UV-Vis, PbS QDs avec un transistor organique C60 de type N imprimé dans la gamme proche IR". Thesis, Rennes 1, 2019. http://www.theses.fr/2019REN1S087.

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La détection de lumière dans une large gamme de longueur d’onde allant de l’UV au proche infrarouge est réalisée avec une sensibilité importante en utilisant l’effet d’amplification amené par un transistor à effet de champ et la capacité de détection dans une grande gamme de longueur d’onde amenée par des nanoparticules de CdSe et de PbS de diamètres différents. Dans une première partie, un FET utilisant une couche active de nanofils de ZnO est fabriqué. La détection de lumière UV-Vis est assurée en enrobant ces nanofils par un mélange de nanoparticules de CdSe et d’oxyde de graphène. L’oxyde de graphène assure une bonne transition des électrons crées par la lumière dans le CdSe vers le ZnO. La photo-réponse obtenue, supérieure à 104 A/W à 350 nm, a été multipliée par un facteur 100 dans la gamme 200-500nm en utilisant l’oxyde de graphène. Dans une seconde partie, la détection de lumière infrarouge a été assurée par des nanoparticules de PbS incorporées dans un transistor organique de type N utilisant du C60 comme couche active. Les électrodes en argent de ce transistor et son isolant de grille en photorésine SU8 sont déposés par impression. Les nanoparticules sont déposées en solution à l’interface entre le semiconducteur et l’isolant de grille. Ce phototransistor incorporé dans un inverseur a montré l’apparition d’un signal de sortie de 2V dû à l’application d’une lumière de 1050 nm de longueur d’onde et de 250 µw/cm2 de puissance
Detection of light in large wavelength range, from the UV to NIR, is got with high sensitivity by using the amplification of a field effect transistor and the ability of light detection in large range by CdSe and PbS quantum dots with different diameters. In the first part, a FET with ZnO nanowires active layer is fabricated. The light detection in UV-Vis range is insured thanks to CdSe QDs/RGO (Reduced Graphene Oxide) fragments decorating the surface of the ZnO nanowires RGO insures good transfer of photo-electrons induced by the light into the CdSe QDs towards ZnO. The responsivity, higher than 104 A/W at 350 nm, has been improved by 100 in 200-500 nm range by using RGO. In the second part, IR light detection has been insured by using PbS QDs embedded in N-type Organic FET using C60 film as active layer. Silver electrodes of this transistor and its SU8 photoresist gate insulator have been printed. QDs have been deposited in solution at the interface between the semiconducting layer and the gate insulator. This phototransistor has been used in an inverter. The output voltage of the inverter change by 2V under lighting with 1050 nm wavelength and 250 µW/cm2 power
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Pruvost, Née Dequidt Caroline. "Etude de la dynamique des adhésions neuronales N-cadhérine et L1 dans la croissance axonale et la synaptogenèse". Phd thesis, Université Victor Segalen - Bordeaux II, 2007. http://tel.archives-ouvertes.fr/tel-00164823.

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Lors des processus développementaux d'élongation axonale et de synaptogenèse, les protéines d'adhésion telles les cadhérines ou les Ig-CAM jouent des rôles fondamentaux en permettant la formation de contacts entre neurones. Pour étudier la dynamique de ces contacts et leurs rôles dans ces processus, nous avons mis en œuvre des techniques d'imagerie sur des neurones primaires d'hippocampe (clivage thrombine, FRAP, pinces optiques, quantum-dots), ceux-ci étant associés à un système semi-artificiel de microsphères recouvertes de protéines d'adhésion purifiées (N-cadhérine et L1). En utilisant une construction L1 portant une étiquette GFP extracellulaire clivable à la thrombine, j'ai pu précisé l'implication des processus de diffusion membranaire et d'exo- endocytose dans la dynamique des contacts L1-dépendants et obtenir des données quantitatives relatives à l'interaction homophile L1. J'ai également contribué à caractériser la liaison extracellulaire entre N-cadhérine et GluR2, sous-unité des récepteurs AMPA, et l'influence de l'expression de la N-cadhérine sur la mobilité de GluR2. L'interaction entre ces deux protéines pourrait être impliquée dans la formation et/ou la maturation des synapses.
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Capítulos de livros sobre o assunto "(AIGa)N quantum dots"

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Veljković, Dj, M. Tadić e F. M. Peeters. "Intersublevel Absorption in Stacked n-Type Doped Self-Assembled Quantum Dots". In Materials Science Forum, 37–42. Stafa: Trans Tech Publications Ltd., 2005. http://dx.doi.org/10.4028/0-87849-971-7.37.

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Liu, Quanlin, e Ting Wang. "Tuning Luminescence by Varying the O/N or Al/Si Ratio in Some Eu-Doped Nitride Phosphors". In Phosphors, Up Conversion Nano Particles, Quantum Dots and Their Applications, 343–70. Berlin, Heidelberg: Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-662-52771-9_11.

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Grushevskaya, H. V., G. G. Krylov, S. P. Kruchinin e B. Vlahovic. "Graphene Quantum Dots, Graphene Non-circular n–p–n-Junctions: Quasi-relativistic Pseudo Wave and Potentials". In NATO Science for Peace and Security Series A: Chemistry and Biology, 47–58. Dordrecht: Springer Netherlands, 2018. http://dx.doi.org/10.1007/978-94-024-1304-5_4.

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Hiu, Jia Shen, Sue Jiun Phang, Jiale Lee, Voon-Loong Wong e Lling-Lling Tan. "B-doped Carbon Quantum Dots Anchored n/n-Junctioned Graphitic Carbon Nitride (g-C3N4) for CO2 Photoreduction". In Environmental Science and Engineering, 151–57. Singapore: Springer Nature Singapore, 2024. http://dx.doi.org/10.1007/978-981-97-0372-2_14.

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Viscusi, Gianluca, Stefania Mottola, Hebat-Allah S. Tohamy, Giuliana Gorrasi e Iolanda De Marco. "Design of Cellulose Acetate Electrospun Membranes Loaded with N-doped Carbon Quantum Dots for Water Remediation". In Lecture Notes in Civil Engineering, 133–37. Cham: Springer Nature Switzerland, 2024. http://dx.doi.org/10.1007/978-3-031-63357-7_22.

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Dagher, Sawsan, Yousef Haik, Ahmad Ayesh e Nacer Tit. "Heterojunction Solar Cell Based on p-type PbS Quantum Dots and Two n-type Nanocrystals CdS and ZnO". In ICREGA’14 - Renewable Energy: Generation and Applications, 535–45. Cham: Springer International Publishing, 2014. http://dx.doi.org/10.1007/978-3-319-05708-8_43.

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John, Bony K., Neenamol John e Beena Mathew. "Microwave Assisted Synthesis of N,S-Doped Carbon Quantum Dots as a Fluorescent Sensor for Silver(I) Ions". In Recent Advances in Nanomaterials, 177–83. Singapore: Springer Nature Singapore, 2023. http://dx.doi.org/10.1007/978-981-99-4878-9_24.

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Pomorski, Krzysztof. "Analytical Solutions for N-Electron Interacting System Confined in Graph of Coupled Electrostatic Semiconductor and Superconducting Quantum Dots in Tight-Binding Model with Focus on Quantum Information Processing". In Springer Proceedings in Physics, 67–165. Cham: Springer International Publishing, 2023. http://dx.doi.org/10.1007/978-3-031-18096-5_7.

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Ghosal, A., C. J. Unirigar, H. Jiang, D. Ullmo e H. U. Baranger. "Interaction effects in the mesoscopic regime: A quantum :rvionte Carlo study of irregular quantum dots". In Quantum Monte Carlo, 154. Oxford University PressNew York, NY, 2007. http://dx.doi.org/10.1093/oso/9780195310108.003.00158.

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Abstract The paper reported the extension of earlier QMC calculations for small symmetric quantum dots to large irregular dots, i.e., from the microscopic to the mesoscopic regime. For a large number N of electrons in a sufficiently irregular confining potential the motion of the electrons may be expected to- be chaotic, and mesoscopic fluctuations may result from electron interaction and interference effects. Studies using density functional theory (DFT) and the random phase approximation (RPA) have met with only limited success in treating these systems. This fixed-node diffusion QMC study was much more successful. The systems treated were two-dimensional quantum dots containing 10-30 electrons confined by a potential energy of the type culations were carried out for dots formed by six different sets of constants. Each of these was investigated with each number of electrons N and the total spin S given by S = 0, 1, and 2 for even N and S = 1/2, 3/2, and 5/2 for odd N in order to determine the ground-state energies and spins. Multi-determinant trial wavefunctions with simple Jastrow functions were assembled from Kohn-Sham orbitals, and coefficients for the determinants were optimized. Both VQMC and fixed-node DQMC calculations produced energies with statistical errors small compared to singleelectron energy-level spacings.
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Pederiva, F., C. J. Umrigar e E. Lipparini. "Diffusion Monte Carlo study of circular quantum dots". In Quantum Monte Carlo, 128. Oxford University PressNew York, NY, 2007. http://dx.doi.org/10.1093/oso/9780195310108.003.00131.

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Abstract Several QMC calculations had earlier treated quantum dots of various shapes and sizes by either variational or diffusion methods. This study extended much farther, with ground and low-lying excited states for circular two-dimensional dots with 2 to 13 electrons. The method was fixed-node diffusion QMC with importance sampling. Comparisons were made with Hartree-Fock and density functional calculations at the LSDA level. The system treated was a standard circular quantum dot with N electrons confined in two dimensions by a parabolic potential V = ½kr2 centered at the origin. The masses, dielectric constants, and the potential energy constants were specified as those for a GaAs crystal. Atomic units were replaced by effective atomic units. Anti-symmetry rules were the same as for atomic systems. Trial functions were expressed for each case as sums of one to five Slater determinants from density functional calculations, along with elaborate generalized Jastrow functions. The coefficients required for satisfying cusp conditions were different from those usually found for three-dimensional problems. A total of 23 cases with different numbers of electrons and L, S eigenstates were treated. The first version of the paper contained a few errors. Corrected results (also with lower uncertainties) were reported in a second version.0 In all cases the diffusion QMC energies were lower than the variational QMC energies, which were in turn lower than the HF energies. Fixed-node error was expected to be small. The differences from LSDA density functional energies were small but not negligible.
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Trabalhos de conferências sobre o assunto "(AIGa)N quantum dots"

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Mishra, Pawan, Lydia Jarvis, Chris Hodges, Sara-Jayne Gillgrass, Richard Forrest, Dagmar Butkovicova, Craig P. Allford et al. "Achieving InAs Quantum Dot Laser Operation at and Beyond 150 °C". In CLEO: Applications and Technology, ATh3O.2. Washington, D.C.: Optica Publishing Group, 2024. http://dx.doi.org/10.1364/cleo_at.2024.ath3o.2.

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We achieved InAs quantum dot-based laser operation up to 170 °C by adopting a codoped active region, including p-modulation doping and direct n-type doping in the InAs quantum dots, without resorting to high-reflectivity facet-coatings.
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2

NOMURA, S., e T. IITAKA. "ORDER-N ELECTRONIC STRUCTURE CALCULATION OF n-TYPE GaAs QUANTUM DOTS". In Proceedings of the International Symposium. WORLD SCIENTIFIC, 2008. http://dx.doi.org/10.1142/9789812814623_0031.

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Nomura, S., e T. Iitaka. "Order-N electronic structure calculation of n-type GaAs quantum dots". In PHYSICS OF SEMICONDUCTORS: 28th International Conference on the Physics of Semiconductors - ICPS 2006. AIP, 2007. http://dx.doi.org/10.1063/1.2730175.

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Arabzadeh Nosratabad, Neda, Zhicheng Jin, Liang Du e Hedi Mattoussi. "N-Heterocyclic carbene-stabilized gold nanoparticles and luminescent quantum dots". In Colloidal Nanoparticles for Biomedical Applications XVII, editado por Marek Osiński e Antonios G. Kanaras. SPIE, 2022. http://dx.doi.org/10.1117/12.2610485.

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Bai-sheng, CHEN. "Quantum Dots Tracking with N-Memory Cluster Indexed SMC-PHD filter". In 2020 International Conference on Computer Engineering and Application (ICCEA). IEEE, 2020. http://dx.doi.org/10.1109/iccea50009.2020.00091.

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Zhai, Liang, Giang N. Nguyen, Matthias C. Löbl, Clemens Spinnler, Alisa Javadi, Julian Ritzmann, Andreas D. Wieck, Arne Ludwig e Richard J. Warburton. "Low-noise GaAs quantum dots in a p-i-n diode". In CLEO: QELS_Fundamental Science. Washington, D.C.: OSA, 2021. http://dx.doi.org/10.1364/cleo_qels.2021.fw4i.1.

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Dvurechenskii, A. V., Ivan A. Ryazantsev, Anatolii P. Kovchavsev, Georgii L. Kuryshev, Alexander I. Nikivorov e Oleg P. Pchelyakov. "Photoconductivity gain by Si(Ge) p-n junction containing quantum dots". In SPIE Proceedings, editado por Anatoly M. Filachev e Alexander I. Dirochka. SPIE, 2003. http://dx.doi.org/10.1117/12.517308.

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Geiregat, Pieter, Ashley Stingel, Jari Leemans e Poul Petersen. "Broadband and Ultrafast Infrared Spectroscopy of n-doped HgSe Quantum Dots". In nanoGe Spring Meeting 2022. València: Fundació Scito, 2022. http://dx.doi.org/10.29363/nanoge.nsm.2022.063.

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Lin, Yi-Hsien, e Jean-Fu Kiang. "Efficiency improvement of p-i-n solar cell by embedding quantum-dots". In 2014 USNC-URSI Radio Science Meeting (Joint with AP-S Symposium). IEEE, 2014. http://dx.doi.org/10.1109/usnc-ursi.2014.6955517.

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Sanchez-Mondragon, Jose Javier, Adalberto Alejo-Molina, Sergio Sanchez-Sanchez e Miguel Torres-Cisneros. "Comparison of the Dicke model and the Hamiltonian for n quantum dots". In Integrated Optoelectronic Devices 2005, editado por Diana L. Huffaker e Pallab K. Bhattacharya. SPIE, 2005. http://dx.doi.org/10.1117/12.591222.

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