Rozprawy doktorskie na temat „WASTE PLASTIC MATERIAL”

Extensive quantities of apple pomace are generated annually but disposal of this waste is still much disputed. In EU alone, 500 000 tons are produced every year. Without further treatment, the acidic character of apples with their high sugar and low protein content makes the pomace unsuitable for landfilling and animal feedstock. However, further treatment is usually not economically feasible. This study addresses this issue by introducing a new approach for the apple pomace to produce sustainable materials.  The high content of sugars in apple pomace which can be reshaped and reformed at higher temperatures makes the waste material suitable for plastic production. Other components found in apple pomace are 5 % proteins and 1.5 % fats. Fibers are abundant, dietary fibers amounts for more than half (55 %) the original apple pomace weight. Phenols, sorbitol and acids can be found in minor mount, 2 % or less. The apple pomace itself is a mixture of mostly pulp and peel which corresponds to 9/10 of the total mass. Whereas seeds, seed core and stalk are the remaining 1/10. The possibilities of utilizing apple pomace to produce biofilms and 3D shapes have been investigated. The effects of introducing orange pomace, another waste material produced in extensive quantities, to apple pomace samples has also been studied.  Two methods were used to produce bioplastic materials; solution casting and compression molding. Glycerol was used as a plasticizer. Apple pomace, either washed or not washed, was oven-dried and milled into a fine powder. Using compression molding, plates or cups of the two powders with different amounts of glycerol were prepared. Mixtures of apple pomace and orange pomace, with or without glycerol, were prepared in the same way. The apple pomace was also used in a film casting method to produce plastic films. Applying laser cutting to the plates and plastic films, dog-bone specimens were created whose mechanical properties were analysed using a universal testing machine.  Highest values in terms of tensile strength and elongation at max was reached with bioplastics produced from solution casting where the values varied in the range 3.3 – 16 MPa and 11 – 55 % respectively. The compression molding approach resulted in tensile strength values in the range 0.94 – 5.9 MPa whereas the elongation at max was in the range 0.30 – 1.9 %. A possible application for this material could be disposable tableware which does not require high mechanical strength.  It was shown that it is possible to produce 3D structures and plastic films from apple pomace. Washed apple pomace with glycerol has similar properties as not washed apple pomace without the plasticizer. Adding orange pomace to apple pomace samples increases the tensile strength at the expense of the elongation at max. The pressing conditions and powder size greatly effects the mechanical properties, where a larger powder size lower the values for the mechanical properties. This new approach paves the way for a new utilization of apple pomace to replace some petroleum-based materials and at the same time solve the disposal problem of apple pomace.

One of the most promising technologies for plastic waste valorization in the frame of a circular economy is gasification. Gasification of plastic waste allows to produce a syngas which can be further processed to produce chemicals. In this thesis, a plastic waste-to-methanol route is investigated. After evaluating the plastic waste mass potential available in the Netherlands for gasification through Material Flow Analysis, a waste-to-methanol process is modeled based on literature review and Aspen Plus simulations. Finally, a Life Cycle Assessment (LCA) is performed with the aid of the software SimaPro and specifically focusing on global warming potential (GWP) and cumulative fossil energy demand (CFED). The obtained results are compared with the environmental performance of a traditional natural gas-to-methanol route. This case study shows that 270 kt of plastic waste would be available for gasification in the Netherlands in an optimistic scenario. The modeling of the plastic waste-to-methanol process proves the feasibility of synthesizing pure methanol from a waste-sourced syngas. The results from the LCA indicate that the plastic waste-to-methanol process is associated to a global warming potential equal to almost 3.75 tonnes of CO2 equivalent and responsible for the consumption of about 37.41 GJ of primary energy derived from fossil resources. The waste-to-methanol process is responsible for six times greater GHG emissions than methanol produced from steam reforming of natural gas, and it consumes an additional 11.0% of primary fossil energy. Different sensitivity analyses were carried out to test the robustness of the results. All scenarios confirmed a higher GWP associated to the waste-to-methanol process, which therefore has, for the foreseeable future, rather limited practical relevance since there is no environmental convenience relative to a standard fossil-based methanol production.

Sustainable development is vital in order for Thailand to continue to develop as in previous years. However, sustainable development cannot be achieved if the amount of macroplastic littering into the oceans does not decrease. In order to facilitate future decision making regarding this issue, this report aims to identify which human activities that contribute the most to the present macroplastic waste items on Thai shorelines. This identification was performed through a simplified material flow analysis based on observations and simple calculations on the island Koh Chang in Ranong. A comparative study was performed on the dissimilar island Koh Larn in Pattaya in order to eliminate any error factors caused by the specific environment on Koh Chang. It was deduced that Grocery Consumption, Fishing and Dining were the Key Activities on the two islands that contributed to the present macroplastic waste. Tourism was also shown to be a great contributor. The study did not find any signs of a current Rate of Accumulation on Koh Chang. However, there were always macroplastic waste items present in the sampling areas which implies that they might pose a threat to the ecosystems. Further research is needed in order to find a suitable solution for this problem.
En hållbar utveckling är central för att Thailand ska kunna fortsätta utvecklas på samma sätt som skett de senaste åren. Hållbar utveckling kan dock inte uppnås om mängden makroplaster som hamnar i haven inte minskar. För att underlätta framtida beslutsfattande ämnar denna rapport att identifiera de mänskliga aktiviteter som i störst utsträckning bidrar till de makroplastföremål som går att finna på thailändska kuststräckor. Denna identifiering utfördes genom en simplifierad materialflödesanalys som baserades på observationer och simpla beräkningar på ön Koh Chang i Ranong. En jämförande studie utfördes på den annorlunda ön Koh Larn i Pattaya för att eliminera felfaktorer som kan ha uppstått på grund av Koh Changs specifika förutsättningar. Studien visade att Livsmedelskonsumption, Fiske, och Restaurangbesök var de Nyckelaktiviteter som bidrog till det befintliga makroplastavfallet. Turism visade sig också vara en stor bidragare till makroplastavfall. Studien kunde inte visa på någon Ackumuleringsgrad på Koh Chang. Trots detta fanns alltid makroplastföremål närvarande i provtagningsområdena på Koh Chang, vilket antyder att dessa föremål skulle kunna innebära ett hot mot ekosystemen. Vidare efterforskningar krävs för att hitta en passande lösning på problemet.

Modernization has brought about steady increase in the consumption of goods and services by human societies across the globe, which mostly driven by both population growth and the change of individual living standards. This, of course, leads to an ever-increasing waste production that ends up in landfills and very often as a source of pollution on natural ecosystems, especially in the low and middle-income countries where waste management is almost inexistent. The management of waste streams is a huge challenge for developed countries as well, where societal and environmental impacts are visible despite massive investments in waste management. One of the most problematic waste materials is plastic, which can remain in nature for over 100 years without degradation, leading to serious environmental concerns. As one of the most significant innovations of the 20th century, plastic is a widely used and cost-effective material for many applications. After their useful lifetimes, their management is problematic. Thus, robust and innovative approaches of managing such waste material are needed in order to mitigate the problem. One of the innovative approaches of tackling the menace cause by plastic waste is through its incorporation into the construction materials. This thesis seeks to address this problem by exploring the use of melted plastic wastes (High Density Poly Ethylene, HDPE and Low Density Poly Ethylene, LDPE) as binder in developing new construction materials (mortar with melted plastic as the only binder, MPB and Plastic Waste Crete, PWC) as an alternative to partially replace traditional concrete and mortar, or finding other engineering uses for this type of waste. Worldwide, about 190 m3 of concrete is poured every second, which translates to 6 billion m3 per year and making it, one of the most widely used manufactured materials. However, the production of concrete requires water and cement. Cement is expensive, and its production contributes to the emission of environmentally polluting gases. Replacing this binding element with recycled plastic derivatives would have significant economic and environmental benefits. In addition to the elimination of cement cost, this will result in water savings, which is especially important for areas without fresh water scarcity. Some researchers have used plastics in concrete and mortars as additives and/or replacement for fine and coarse aggregates. In addition, different types of plastics have been used in bitumen as an additive to reduce construction cost and improve sustainability by adding value to wastes materials. However, there is paucity of technical information about the use of the melted HDPE and LDPE plastic wastes as the only binding phase in concrete- or mortar-like materials. Moreover, many parameters such as preparation conditions, field variables, constituent elements, and final applications have impacts on the performance of construction materials Thus, the key objective of this PhD research is to develop the mortar with plastic binder (MPB) and PlasticWasteCrete (PWC) by using molten HDPE and LDPE plastic wastes as the only binder as well as to investigate the engineering properties of these new types of construction materials. The plastic contents of 45%, 50%, 60% and 65% and HDPE to LDPE ratios of 40/60, 50/50, and 60/40 were selected for the experimental tests. Clean river sand was used as the only aggregate for the MPB, while both sand and gravel were used for the PWC. Various tests were then performed on prepared MPB and PWC samples at different curing times from early to advanced ages to assess their engineering properties. These tests were conducted in accordance with the ASTM standards to evaluate the mechanical properties (compressive strength and splitting tensile strength), permeability and density of the MPB and PWC materials. Additional tests were carried out to analyze the products at the microstructural level (optical microscope, SEM, MIP and thermogravimetric analysis) to gain an insight into the microstructural properties of the developed materials and how that affect their engineering properties. The compressive strength tests revealed the optimal plastic content for the MPB and PWC with the best strength performance. The average compressive strength values for various optimal formulations after 28 days were found to be in the range of 9 to 18 MPa. The splitting tensile strength for the new materials from 1 to 28 days of curing time, were found to be between 1 and 5 MPa. The average hardened density of the MPB and PWC is about 2 g/cm3, which makes them lightweight material according to RILEM classification. In addition, various absorption tests (capillary and immersion) were performed on different MPB and PWC samples, and the obtained results showed that they are porous materials having lower rate of absorption than the traditional cementitious materials (mortar, concrete). This observation was supported by the results from both MIP and SEM analyses. Finally, thermogravimetric analysis provided interesting details on the thermal decomposition of the new materials, with significant changes or mass loss for these products being observed only at temperatures higher than 300°C. The findings from this study suggest MPB and PWC made with melted plastic waste as the only binder have a promising potentials for use in construction. The research conducted in this PhD study offers a good understanding of the engineering properties of the materials as well as the optimal formulations that yield best performance in terms of strength and durability. In summary, it provides useful technical information and tools on the MPB and PWC that will contribute in setting guidelines on the optimal applications of these products in the field of construction in order to have safe, durable and cost-effective structures. Résumé Avec la modernisation de nos sociétés, les habitudes ont considérablement changé, ainsi, on observe une forte consommation des biens et services, due à l’augmentation de la population et l’amélioration de leurs conditions de vie. Ce qui conduit à une augmentation considérable des quantités des déchets qui terminent leurs cycles au niveau des décharges ou dans les océans/fleuves devenant ainsi une source de source de pollution des écosystèmes naturels, surtout dans les pays à revenu faible et intermédiaire avec des systèmes défaillants ou moins performants de gestion des déchets. La gestion des flux de déchets est aussi un défi pour certains pays développés, où les impacts sociaux et environnementaux sont visibles en dépit des investissements massifs dans ce secteur. Parmi ces déchets, nous avons les plastiques, l’une des innovations du 20e siècle avec des qualités versatiles et coût faible, se trouve partout dans nos vies quotidiennes. Après leur utilisation, les plastiques deviennent des déchets qui peuvent rester dans la nature plus de 100 ans sans aucune dégradation, avec des conséquences néfastes sur l’Homme et l’environnement. Ainsi, une approche robuste et innovante de gestion de ces déchets est nécessaire afin d'atténuer leurs impacts. L'une des approches innovantes pour réduire l’impact causé par les déchets plastiques consiste à les incorporer dans les matériaux de construction. Ainsi, le problème est abordé dans cette thèse en développant des technologies permettant de recycler les plastiques fondus comme liant dans les nouveaux matériaux de construction (MPB et PWC), afin d’offrir une alternative pour remplacer partiellement le béton / mortier traditionnel. Le béton est l’un des matériaux les plus utilisés au monde, avec environ 190 m3 coulés chaque seconde, correspondant à 6 milliards de m3 par an. Cependant, la production de béton nécessite de l'eau et du ciment. Le ciment coûte cher et sa production contribue à l'émission de gaz polluants l'environnement. Le remplacement d'une partie du béton traditionnel par un matériau à base des déchets plastique aura des avantages économiques, sociaux et environnementaux importants. Allant dans ce sens, certains chercheurs ont utilisé les plastiques dans le béton et le mortier comme additifs et / ou substituts des matériaux granulaires tels que le sable et le gravier. Aussi, différents types de plastiques ont été utilisé dans le bitume comme additif pour réduire les coûts de construction et améliorer la durabilité, ainsi contribuer à donner de la valeur aux déchets. Cependant, jusqu'à présent, il existe peu d’informations techniques sur l'utilisation de déchets plastiques (HDPE et LDPE) fondus comme seuls liants pour développer de nouveaux types de matériaux de construction. En plus, plusieurs facteurs (les conditions de préparation, les éléments constitutifs, les applications finales, etc.) ont un impact sur les caractéristiques des matériaux de construction. Ainsi, l'objectif de cette recherche doctorale est de développer des nouveaux matériaux de construction (MPB et PWC) en utilisant les déchets plastiques fondus (HDPE et LDPE) comme seul liant, puis déterminer les propriétés caractéristiques de ces matériaux afin de trouver la formulation optimale conduisant à la meilleure résistance. En plus de l'élimination du coût du ciment, cette technologie permet aussi de faire des économies d'eau, bénéfique surtout pour les zones avec des difficultés d'accès à l’eau potable. Cela contribuera à la réduction des coûts de la construction en utilisant les produits innovants comme alternative au béton / mortier conventionnel. Un vaste programme expérimental, comprenant des tests à petite et grande échelle, a été développé afin d'atteindre les objectifs de cette étude de doctorat. La campagne expérimentale a comporté différentes étapes comprenant la sélection des matériaux, la détermination de la formulation optimale et les conditions appropriées pour la préparation des matériaux susmentionnés. Par la suite, pour une meilleure compréhension du comportement technique et des propriétés du produit final, divers tests ont été effectué sur les matériaux préparés à différents temps de durcissement. Ces tests ont été menés conformément aux normes ASTM pour évaluer les propriétés mécaniques (résistance à la compression et à la traction), la perméabilité et la densité des nouveaux matériaux. Les expériences ont été approfondies en analysant les produits au niveau microstructural (microscope optique, SEM, MIP et analyse thermique) pour avoir un aperçu des propriétés microstructurales des matériaux développés et essayer de comprendre les relations avec leur comportement mécanique. Les essais de compression ont permis de trouver la teneur en plastique optimale pour les matériaux (MPB et PWC) avec les meilleures valeurs de résistance. Les résistances moyennes à la compression à 28 jours pour diverses formulations étaient comprises entre 9 et 18 MPa. La résistance à la traction par fendage des nouveaux matériaux entre 1 et 28 jours se situait entre 1 et 5 MPa. La densité moyenne du béton et mortier écologique est proche de 2 g / cm3, ils peuvent donc être considérés comme des matériaux légers selon la classification RILEM. De plus, divers tests d'absorption (capillaire et par immersion) ont été réalisé sur différents échantillons de MPB et PWC, les résultats obtenus ont montré qu'il s'agit de matériaux poreux ayant un taux d'absorption plus faible que les matériaux traditionnels contenant du ciment. Plusieurs analyses microstructurales ont été réalisées sur différents échantillons des nouveaux produits (MPB et PWC) et les matériaux cimentaires traditionnels ont été utilisés pour renforcer notre compréhension. Enfin, l'analyse thermique a fourni des détails intéressants sur la décomposition thermique de ces nouveaux matériaux ; des changements significatifs avec une perte de masse considérable ont été observés seulement pour des températures supérieures à 300 ° C. Les résultats de ces essais permettent d'acquérir une bonne compréhension des propriétés techniques des nouveaux matériaux (MPB et PWC) ainsi que de déterminer les teneurs optimales en plastique conduisant aux meilleures performances en termes de résistance et de durabilité. Ainsi, les recherches menées dans cette étude de doctorat fournissent des informations techniques et des outils utiles sur le MPB et le PWC; et contribueront à installer des bases pour guider les applications optimales de ces nouveaux produits dans le domaine de la construction afin d'avoir des structures sûres, durables et rentables.

El propósito de esta tesis doctoral fue evaluar la influencia de los diferentes procesos de gestión de residuos, tales como la valorización material, energética y biológica de dos poliésteres clave de la industria del embalaje: el actual no-renovable poli (tereftalato de etileno) (PET) y el potencial candidato para sustituirlo en un futuro próximo, la polilactida (PLA) de base renovable. Se utilizaron diversas plantas piloto para simular las condiciones de la degradación sufrida por PET y PLA en el reciclado mecánico, la pirólisis, la combustión y el enterramiento en suelo. Los cambios fueron monitorizados por calorimetría diferencial de barrido (DSC), análisis dinámico-mecánico-térmico (DMTA), análisis termogravimétrico (TGA), espectrometría infrarroja con transformada de Fourier (FTIR), espectroscopia de correlación 2D-IR para el análisis de gases (EGA), espectrometría de masas MALDI-TOF, microscopía electrónica de barrido (SEM), índice de fluidez de masa fundida (MFR), ensayos de tracción e impacto Charpy y viscosimetría. Se han propuesto, desarrollado y aplicado diversas estrategias y procedimientos analíticos para establecer parámetros fiables para ser utilizados como indicadores de la degradación y por tanto controlar la influencia de cada proceso de valorización en la calidad del material. El comportamiento de PET y PLA reciclados mecánicamente se evaluó en base a sus propiedades químicas, microestructurales, mecánicas y térmicas. Se observó una pérdida general de prestaciones de PET y PLA reprocesado una vez y dos veces, respectivamente. Además, las propiedades de los materiales reciclados de PLA fueron mejores en términos relativos a los productos reciclados de PET. Las descomposiciones térmica y termo-oxidativa causadas por los procesos de pirolisis y combustión se evaluaron sobre la estabilidad térmica, gases emitidos y cinéticas de descomposición. Se destaca el uso de la combustión controlada para ambos polímeros, ya que se necesita menos energía para iniciar la descomposición, y la mezcla de gases que se desprenden es más homogénea.
Badía Valiente, JD. (2011). Strategies and analytical procedures for a sustainable plastic waste management. An application to poly (ethylene terephthalate) and polylactide in the packaging sector [Tesis doctoral]. Editorial Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/12890
Palancia

The aim of the thesis was to show that it is possible to develop a sustainable product of a discarded material and provide a framework for how to do that. A great amount of discarded material is today put on landfill due to its low value and difficulties to use. But putting the waste on landfill is the least preferred way of handling it, especially when the resources in the world are not infinite. It is therefore of importance that we find another way of handling the discarded material, which is why this thesis was written.  During the work has a qoute by McDonough and Braungart (2002) been kept in mind, reminding us, as product designers,  of the responsibilty we have  for future generations well-being.  “How can we love the children of all species– not just our own – for all time?” – McDonough and Braungart. 2002. Remaking the way we want things, pp 168. This thesis consisted of three phases. In phase 1 the plastic WEEEBR (a recycled plastic blend from waste from electrical and electronic equipment) was evaluated and a suitable product for it was found. Phase 2 started with a market research trying to find a market opportunity for that product. Thereafter several concepts for the product was developed. The last phase, phase 3, analyzed and evaluated the two previous phases in order to summarize the process and develop a method for how to put requirements on future products.   Phase 1 and 2 are shortly described, thereafter follows the analysis of them. The proposed method are exemplified with concepts and results from phase 1 and 2. The result of the thesis was a method based on following 6 steps: Agree to the company’s vision Evaluate what available material you have Evaluate your technical possibilites with the material Highlight a market possibility Set product requirements Develop the concept This method is generic and shall be used as a guide when developing sustainable products. Developing sustainable products include thinking about what material you have. It is worth thinking about if the product shall be produced locally, with local material and also how the material should be handled after it is used and at last where it ends up.
Waste to Design
Closing the loop

Work with behind-go recycling waste with project on foundation firm applied in this branch. Next then by suggesting arrangement on recycling electric cable, development prises and processing price list.

The catalytic cracking of linear low density polyethylene (lldPE), polypropylene (PP) and plastic waste were investigated using commercial zeolites (ZSM-5, zeolite β, Mordenite, and USY), USY modified by ion-exchange, mixed catalyst (ZSM-5/ zeolite β, ZSM-5/USY), and nanocrystaline-ZSM-5. USY was modified by ion-exchange with ammonium salt at two different temperatures (298K and 353K) and for various reaction times. The cracking of PP and lldPE was performed using mixed catalysts and in addition a detailed study was carried out employing statistical design of response surface methodology to obtain the optimum reaction condition to produce maximum products. Nano crystalline ZSM-5 catalysts were prepared with/without the presence of alcohol (ethanol and isopropanol) and sodium and statistical analysis of completely random design was used to determine the effect of these constituents in the reaction mixture on the characteristics of ZSM-5 material and on their catalytic performance. The catalytic studies using commercial zeolites revealed that the zeolite β and mordenite produced higher liquid yield from lldPE and plastic waste, respectively. However, by using a modified USY, by ion-exchange at temperature 298K for 48hours, a further improvement to the liquid yield was achieved. Using a mixer of ZSM-5/ zeolite β it was possible to achieve very good conversions for both lldPE and PP with least amount of coke formation. Further studies on catalytic cracking of lldPE using nanocrystalline ZSM-5 indicate that the highest liquid yield that could be achieved was by using the material synthesised in the presence of alcohol and sodium in the starting solution. The effect of constituents in the starting gel mixture for ZSM-5 synthesis appears to influence surface area, acidity and particle size; however it appears that this does not affect the catalytic performance for cracking of lldPE. However the study suggest that control of external surface area and particle size is highly significant.

Thesis (PhD) - Swinburne University of Technology, Industrial Research Institute Swinburne - 2006.
A thesis submitted for the degree of Doctor of Philosophy, Industrial Research Institute Swinburne, Swinburne University of Technology - 2006. Typescript. "August 2006". Includes bibliographical references (p. 361-389).

Currently, using waste materials in civil and construction engineering is of great interest to researchers and industry. This study investigates the impact of using waste polyethylene terephthalate plastic and nano-silica to modify asphalt mixtures following Australian design guidelines and criteria; different types of asphalt mixtures, waste plastic types and contents, nano-silica size are used to investigate and determine the mechanical properties of the modified asphalt mixtures.

The society is striving to tackle the over-extraction of Earth’s resources due to the ongoing population rise. The increased needs of energy and material resources leads to a growing volume of materials waste, which include a variety of dangerous pollutants among them. Waste of electrical and electronic equipment poses a universal problem due to its vast quantities, responsible for environmental pollution and numerous diseases to humans and animals. The high demand in electrical and electronic equipment along with its short-life time due to its obsolescence, leads to the expansion of WEEE waste stream. Energy and material recovery from WEEE can minimize significantly the over extraction of precious metals and minerals along with fuels towards a more sustainable future. Currently, there are several ways to treat WEEE and recover material fractions along with energy, such as incineration and landfilling. Thermochemical treatment of WEEE offers the possibility to convert waste into energy and material simultaneously, in an environmentally friendlier way, resulting in a more sustainable waste management. In this research, pyrolysis is examined as a method for energy and material recovery from WEEE. Brominated plastics along with Polyethylene plastic mixtures have been acquired from Stena and Boliden AB separation processes respectively. Both materials are subjected to pyrolysis in a fixed bed and an auger reactor. The pyrolysis products show their strong relation to the pyrolysis temperature, the type of the reactor and the initial composition of the feedstock material. The carried-out experiments depict the upward trend of the gaseous products in favor of the oils as the pyrolysis temperature increase. The amount of solid residue remained almost at the same levels throughout the temperature range, meaning that no higher temperatures are needed in order to achieve higher decomposition rates of the tested material. Unreacted carbon and inorganic compounds end up in the solid residue that could be used as fuel in a combustion process. The metal fraction can be separated and recycled, as it possesses commercial value. Main oil compounds listed were, styrene, toluene, ethylbenzene, alpha methylstyrene benzene, phenol. Compounds such as benzene, indene and p-xylene were produced as the organic compounds were further decomposed during the experiments at the highest temperatures. Chlorine and bromine content must be separated in order to be a formidable fuel. The amount of combustible gases was increasing and their energy potential with the temperature rise. The gaseous fraction consists mainly of: H2, CO, CH4, CO2, C2H2, C2H4, C2H6, C3H6, C3H8. Both the gaseous and oil compounds can be used as fuels in a combustion process. The amount of halogens was measured at low levels within the product range, though their separation is important. Pyrolysis of WEEE is a promising method for energy and material recovery that can boost the sustainability of our society.
Samhället strävar efter att ta itu med överutvinningen av jordens resurser på grund av den pågåendebefolkningsökningen. De ökade behoven hos energi och materiella resurser leder till en ökandemängd materialavfall, vilket inkluderar en mängd farliga föroreningar bland dem. Avfall av elektriskoch elektronisk utrustning utgör ett universellt problem på grund av sin stora mängd, ansvarig förmiljöföroreningar och många sjukdomar hos människor och djur. Den stora efterfrågan på elektriskoch elektronisk utrustning tillsammans med den korta livslängden på grund av dess föryngring ledertill utvidgningen av WEEE-avfallsströmmen. Energi och materialåtervinning från WEEE kanbetydligt minska över-extraktion av ädelmetaller och mineraler tillsammans med bränslen mot en merhållbar framtid. För närvarande finns det flera sätt att behandla WEEE och återvinna materialfraktioner tillsammansmed energi, såsom förbränning och deponering. Termokemisk behandling av WEEE erbjudermöjlighet att omvandla avfall till energi och material samtidigt, på ett miljövänligare sätt, vilketresulterar i en mer hållbar avfallshantering.I denna forskning undersöks pyrolys som en metod för energi och materialåtervinning från WEEE.Bromerad plast tillsammans med polyetylenplastblandningar har förvärvats från Stena och BolidenAB separationsprocesser. Båda materialen utsätts för pyrolys i en fast bädd och en skruvreaktor.Pyrolysprodukterna visar deras starka förhållande till pyrolys-temperaturen, reaktortypen och denursprungliga sammansättningen av råmaterialet. De utförda experimenten visar den uppåtgåendetrenden hos de gasformiga produkterna till förmån för oljorna som pyrolystemperaturökningen.Mängden fast substans förblev nästan vid samma nivåer genom temperaturintervallet, vilket innebäratt inga högre temperaturer behövs för att uppnå högre sönderdelningshastigheter för det testadematerialet. Oreagerat kol och oorganiska föreningar hamnar i den fasta återstoden som kan användassom bränsle vid förbränningsprocessen. Metallfraktionen kan separeras och återvinnas, eftersom denhar kommersiellt värde. De angivna huvudolja-föreningarna var styren, toluen, etylbensen, alfa-metylstyrenbensen, fenol.Föreningar såsom bensen, inden och p-xylen framställdes när de organiska föreningarnasönderdelades vidare under försöken vid de högsta temperaturerna. Klor och brominnehåll måstesepareras för att vara ett formidabelt bränsle.Mängden brännbara gaser ökade och deras energipotential med temperaturökningen. Den gasformigafraktionen består huvudsakligen av: H2, CO, CH4, CO2, C2H2, C2H4, C2H6, C3H6, C3H8. Bådegasformiga och oljeföreningar kan användas som bränslen i en förbränningsprocess. Mängdenhalogener mättes vid låga halter inom produktsortimentet, fastän deras separation är viktig.Pyrolys av WEEE är en lovande metod för energi och materialåtervinning som kan öka vårt samhälleshållbarhet.

The awareness on raw material scarcity and environmental issues has globally stimulated interest into the re-design of products, processes or services, maximizing prevention, reuse and recycling rates. Within this context, plastic represents a key material. In particular, plastic packaging is a priority issue, accounting for the 40% of the European converters demand and about 60% of post-consumer plastic waste. Nowadays, less than 30% of collected plastic waste is recycled, while landfilling and incineration rates of plastic waste remain high, approximately 27% and 41% respectively. The EU Commission is currently hardly working on this issue: the recent EU Plastic Strategy sets very ambitious goals for plastics sustainability. This background topic is the key point of the master thesis. The study starts with mapping the best practices on plastic recycling and prevention, following the entire plastic packaging value chain. Adopting a multi-criteria perspective, legislative, economic and technical, technological and environmental framework of good practices and criticalities is outlined, in order to assess the current state of innovation on circular economy for plastics. The overview on levers and barriers for plastic circularity allows to design a new set of circular economy indicators suitable to be applied on plastic packaging sector. As good practices, eco-design principles are adopted in order to delineate an assessment tool able to identify plastic packaging sustainability and circularity. Moreover, the compliance with the regulatory framework and possible economic advantages are verified. Therefore, the final goal of the study is to identify practical suggestions which can be converted into a set of indicators for measuring plastic packaging circularity, delineating criticalities and possible improvements for boosting the sustainable transition of the entire sector.

This thesis presents the implementation and the optimization of a waste management system (WMS) in the Koinonia community (that is sited in the Chilanga district near Lusaka), showing the challenges that must be faced, implementing a WMS in a developing country. In the first part of the thesis it will be contextualized the waste management in the Zambian economy showing how a diversification involving the it could fit with the needs of the Nation. In the second part it will be treated the waste management hierarchy through the illustration of some European policies (like Circular Economy Package) and best practice (like WtE in Sweden). In the third part it will be analyzed the case of study Koinonia community where it has been spent three month. The object of the study was how to make the waste management system economical sustainable, the various issue regarding this subject are described by some reports wrote at the beginning of the experience and at the end. In addition, the chapter presents a study about the waste production in Chilanga and the data collected by means the interview with the waste aggregator present in the city. Concluding, it is showed a proposal of evolution of the waste management system which consist in install a phv (Photovoltaic) system that will feed an ecological island of low dimension.

Incineration of waste materials has become a common way to handle a worldwide increase of produced waste materials. The problem with waste as fuel is that the material is not homogeneous and include a mixture of fossils and renewables. The fossil part ends up in an emission of fossil carbon dioxide in a combustion process, which is included in the emissions trading system. However, since waste material varies a lot in composition depending on the time of the year, origins, etc. it is preferable to have a method for real-time measurement of the fossil share of combusted waste. No real-time measurement technologies are available today which is the reason to investigate if near-infrared (NIR) spectroscopy could be a potential solution. An artificial mixture of refused derived fuel has been used to investigate the possibilities of NIR for prediction of the fossil share in waste material. The fossil share is assumed to be equal to the content of plastic material with an origin of oil products. Mixtures with different plastic content are scanned by the NIR instrument to obtain individual absorption spectra. A Partial least square (PLS) regression model is created on measured spectra and known content of plastics. The best model for the prediction on new spectral data using one of four measured replicates is a PLS model preprocessed with Savitzky-Golay smoothing that gives an R-square value of 0,782. If the prediction is done, depending on a delimitated wavenumber interval and an average of all four replicates is the best model instead of a PLS model pre-processed with standard normal variate without seven outliers that have an R-square value of 0,81. R-square value is the coefficient of determination which has been used to figure out the best model. An R-square value above 0,65 are recommended for process modelling, where 1 is the highest possible value.

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior - CAPES
Gypsum is a building material older than is known. Some of their properties they confer advantages such as fire resistance, thermal and acoustic insulation. By virtue of being a ligand less aggressive environment than Portland cement, its use should be encouraged and new applications studied. This work aims to study the physical-mechanical and thermal composite gypsum with the addition of vermiculite and waste of the footwear industry (EVA). The development of these composites has as its purpose the production of elements of thermal protection coating on walls. In the initial stage were investigated physical and mechanical properties of these composites. To determine the influence of levels of EVA and vermiculite, and ratio water/plaster in the physical and mechanical properties of composites in the fresh and hardened were incorporated into five different percentages of the materials with the three ratios water/plaster. A basic composition of each composite was determined by multivariate analysis. Then the composite was optimized its matrix modified with the partial replacement of gypsum by ceramic waste and lime and studied its physical and mechanical properties as well as aspects related to durability. Finally they were certain the thermal properties of composites with waste gypsum and gypsumvermiculite waste-EVA and proposed a constructive element for use in masonry lining and examined its thermal performance. The results indicated that the incorporation of ceramic waste and lime into matrix gypsum of the composites improved their optimized mechanical properties and their performance in relation to water by surface treatment. The theoretical study has shown that proposed plates reduce the heat load incident on mansory.
O gesso é um dos materiais de construção mais antigos que se tem conhecimento. Algumas de suas propriedades lhe confere vantagens como, resistência ao fogo, isolamentos térmico e acústico. Em virtude de ser um ligante menos agressivo ao ambiente que o cimento Portland, seu uso deve ser incentivado e novas aplicações estudadas. Este trabalho teve como objetivo estudar as propriedades físico-mecânicas e térmicas de compósitos à base de gesso com a incorporação de vermiculita e de resíduos da indústria de calçados (EVA). O desenvolvimento destes compósitos tem como propósito a produção de elementos de revestimento para proteção térmica de alvenarias. Na etapa inicial foram pesquisadas as propriedades físicas e mecânicas desses compósitos. Para determinar a influência dos teores de resíduo de EVA e vermiculita e da relação água/gesso nas propriedades físicomecânicas dos compósitos no estado fresco e endurecido foram incorporados cinco percentuais diferentes dos materiais com três relações água/gesso. Uma composição básica de cada compósito foi determinada através de análise estatística multivariada. Em seguida o compósito otimizado teve sua matriz modificada com a substituição parcial do gesso por resíduo cerâmico e cal e estudadas suas propriedades físico-mecânicas, bem como aspectos relacionados à durabilidade. Finalmente foram determinadas as propriedades térmicas do gesso e do compósito gesso com vermiculita e gesso com EVA e proposto um elemento construtivo para aplicação em revestimento interno de alvenarias bem como analisado teoricamente seu desempenho térmico. Os resultados deste trabalho indicaram que a incorporação de resíduo cerâmico e cal à matriz de gesso dos compósitos otimizados melhoraram suas propriedades mecânicas bem como seu desempenho em relação à água mediante o tratamento superficial. O estudo teórico demonstrou que as placas propostas reduzem a carga térmica incidente em alvenarias.

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A reciclagem de refugos é um processo estratégico que viabiliza a expansão do mercado de plásticos, podendo gerar novos produtos. A obtenção de blendas poliméricas é uma alternativa nesse processo, já que é conhecida a perda de propriedades mecânicas dos termoplásticos nas etapas de reprocessamento. Neste trabalho, o polietileno de alta densidade (PEAD) reciclado teve adições de borracha do monômero etileno-propileno-dieno (EPDM) puro em baixos teores (1 %, 5 % e 10 %), cujo objetivo foi formar blendas miscíveis e um produto final mais resistente ao impacto. O PEAD foi submetido a quatro ciclos de moagem, extrusão e injeção (reprocessamento) e misturado ao EPDM puro por extrusão sem o uso de qualquer aditivo. Os grânulos da blenda formada foram usados para confeccionar os corpos-de-prova por injeção para seu uso nas distintas metodologias analíticas. O processo de irradiação gama foi aplicado nas doses de 50 kGy e 100 kGy e os parâmetros físico-químicos e mecânicos dessas amostras foram comparados aos das não irradiadas. Tanto as blendas irradiadas como as não irradiadas mostraramse visualmente e microscopicamente homogêneas, indicando a compatibilidade da mistura, que também é verificada por seu comportamento térmico. Os parâmetros mecânicos provenientes dos ensaios de tração e flexão, foram semelhantes nas amostras do termoplástico virgem e do reciclado; o processo de irradiação nas blendas gerou sua reticulação, sendo esta verificada não só pelo aumento dos valores desses parâmetros como também pelo aumento da fração gel. A resistência ao impacto aumentou cerca de duas vezes e meia nas amostras com maior teor de EPDM e cerca de 6 a 7 vezes nestas mesmas amostras irradiadas a 50 kGy e 100 kGy respectivamente. O novo material obtido tem fortes indicativos para a sua utilização na pequena e média indústria de plástico, uma vez que já com 1 % de EPDM apresentam melhores características mecânicas em relação ao termoplástico reciclado quatro vezes e essas características foram incrementadas após o processo de irradiação gama.
Dissertação (Mestrado em Tecnologia Nuclear)
IPEN/D
Instituto de Pesquisas Energéticas e Nucleares - IPEN-CNEN/SP

This master thesis deals with the current situation of waste management of material usable municipal waste with focus on various fractions of plastics. The theoretical part summarises the legislation of waste treatment, also contains an analysis of the current situation of waste management in the Czech Republic and comparison the situation in the European Union. In the next part of thesis are described basic fractions of plastics and their properties. There are mentioned the current problems with plastics processing and the risks of leakage to the environment. Furthermore, a complex chain of plastic waste reprocessing is described, since the inception of plastics waste to the manufacture of products made from recycled plastics. The most attention is paid to the discription of recycling plant, where the output material from sorting lines is reprocessed into a secondary material in the form of flakes or granules. Also this part is focused on the technology of recycling line and the individual devices are described. In the practical part of the thesis is created techno-economic model of recycling line with the aim of its use for balance calculations of recycling and also economic evaluation. As a part of the model was made a market research of secondary raw materials with a focus on price development. Subsequetly, sensitivity analyzes of selected parameters are applied to the model and the impact of scenarios on the economic results are evaluated.

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In the present work it was developed originals alternatives of enveronmentally safe and economically viable destination of thermoset plastic residue from a button factory, which at presnte stores such residue tempor and in a way that is inconvenient to the atmosphere, a waiting safe solutions. As the residue is not recycleab and its burning leberates strongly aggressive gases, safe alternatives were researched. Inicially, ghe residue in incineration was performed in cement ovens with precise control ofe emission of gases, but it was proved inviable due to its low calorific power, as well as the liberation of free lead in the ashes. An original and feasible option was the residue confinemente in soil-ciment blocks, lohich resulted in blocks highly resistant to simple compression with structural block, and also a significant increase in thermal resistence. Was got up other options of original and important composites as: making of blocks for pr?-moulded flagstone, internal coating of walls with plaster being obtained good texture results, replenish of ceramic blocks and blocks with cement, also implying in increase of thermal resistance. Besides these original and scientific contributions, the it was technologically contribution of defreadation with suggestions of the material using torch of thermal plasm; for this was projected, built, characterized and tested a torch to it shapes it being obtained exciting results for the development of this technology come back for ending destruction from all the types of inconvenient garbage to the atmosphere
No presente trabalho desenvolveram-se alternativas originais de encaminhamento ambientalmente seguro e economicamente vi?vel de res?duo pl?stico termofixo de uma f?brica de bot?es que, no momento, estoca esse res?duo de forma tempor?ria e inconveniente ao ambiente, aguardando solu??es mais seguras. Como o res?duo n?o ? recicl?vel e sua queima libera gases fortemente agressivos ? vida, pesquisaram-se alternativas seguras e vi?veis, tanto do ponto de vista t?cnico como econ?mico. Inicialmente considerou-se a incinera??o do res?duo em fornos de cimento com controle de emiss?o de gases; mas, concluiu-se que a op??o era invi?vel pelo fato do res?duo apresentar baixo poder calor?fico e de sua incinera??o resultar na libera??o de chumbo em cinzas. Pesquisou-se, depois, a possibilidade de decomposi??o do material por meio do uso de tocha de plasma t?rmico. Para isto projetou-se, construiu-se e testou-se uma tocha de plasma para termodecomposi??o, adaptada para utilizar ar ? press?o ambiente como g?s indutor, em substitui??o ao arg?nio, comumente utilizado em tochas de baixa pot?ncia. Os resultados demonstraram a viabilidade t?cnica da proposta; contudo, do ponto de vista econ?mico, os resultados n?o foram positivos. Em seguida, considerou-se o confinamento em blocos de solo-cimento. Foram produzidos blocos que apresentaram resist?ncia ? compress?o simples equivalente a de blocos portantes tipo C e aumento da resist?ncia t?rmica em rela??o ao bloco do mesmo tipo sem adi??o de res?duo. Levantaram-se outras op??es de comp?sitos originais e importantes como: blocos para laje pr?-moldada; revestimento interno de alvenaria com gesso; enchimento de blocos cer?micos e blocos com argamassa de cimento. Al?m do aumento da resist?ncia t?rmica, os comp?sitos desenvolvidos utilizaram menos cimento em sua composi??o, implicando em redu??o de custos sem comprometimento da resist?ncia mec?nica

Depuis une quarantaine d’années, les déchets ménagers et leur gestion sont assimilés à un enjeu écologique global. Alors que se popularisent les discours défendant une conception durable du développement, nos poubelles se multiplient. Qu’aspirons-nous à préserver lorsque, l’enjeu planétaire invoqué, un gouffre intermédiaire se dessine et nous invite à interroger ce lien communément admis entre déchets et pratiques de protection de l’environnement. Notre thèse consiste à affirmer que, sous couvert de leur « environnementalisation », et malgré l’inflation du temps et de l’espace qui leur sont consacrés, les déchets restent marqués par l’oubli des enjeux sociaux, techniques, matériels qui les caractérisent. Cet aveuglement, individuel et collectif, neutralise toute possibilité de penser le déchet comme indice : il voile sa fonction mémorielle et le condamne à n’être appréhendé que comme ce qui doit disparaître, que comme quantité de matière à contrôler, à éliminer. Le déchet durable est l’oxymore qui vise à problématiser cette multiplicité des modes de présence du déchet aujourd’hui. S’inspirant des figures du chiffonnier ou de l’archéologue, notre enquête socio-anthropologique s’applique à suivre ces déchets ménagers, depuis d’incertains océans de plastique jusqu’à quelques lombricomposteurs parisiens. A partir de cette confrontation à la matérialité, aux territoires et aux pratiques du déchu, il s’agit d’affirmer que là où la présence irrévocable des déchets est décrite comme un problème, la question de notre présence aux déchets se pose inévitablement
Over the past forty years, household waste and its management have been assimilated to a global environmental issue. While sustainable development is becoming a pressing issue, the number of our garbage bins is increasing. So what is it that we aim to preserve when we are dutifully sorting out our garbage? Between the very local gesture of discarding and the global environmental issue, there is a tremendous gap. The link between everyday practices of waste and environmental issues is so underdetermined that it has to be analysed. The main claim of this dissertation is that despite a growing concern with environment and the increasing time and space devoted to waste management, we remain unaware of the social, technological and material issues at stake. Because of this individual and collective blindness waste is not seen as a clue: as its memorial function is neglected waste is still perceived as what has to disappear, as a material quantity that has to be controlled and eliminated. The en-durable waste is an oxymoron that leads to further investigate the multiple modes of presence of waste in today’s life. Inspired by the personae of the ragman and of the archaeologist, this socio-anthropological investigation follows household waste from uncertain oceans of plastic to few Parisian vermicompost bins. Based on this confrontation to the materiality of waste, to the territories and to practices of wasting, this dissertation claims that where the unavoidable presence of waste is described as a problem, it is question of our presence to waste that is at stake

Stabilization of soil is an effective and reliable method for improvement of strength, stability and bearing capacity of soils. Soil stabilization can be done in number of ways. But the stabilization using waste plastic strips is an economic method since the stabilizer used here is waste plastic materials, which is easily available and cheap. The primary objective of this project is to improve the shear strength and stability of soil using plastic cover wastes. This report presents the various tests conducted on fiber reinforced soil with varying fiber content and their results are analyzed such that it can be used in the fields. Maximum Dry Density (MDD), Optimum Moisture Content (OMC), California Bearing Ratio (CBR) and shear strength parameters (cohesion C and angle of internal friction Φ) of soil were examined. The plastic strips were added in different proportions by dry weight (0.25%, 0.5%, 1% and 1.5%) of the soil. Results conclude that, there is significant improvement in the strength of soil due to increase in cohesion. However cohesion is improved but no large variation in angle of internal friction. MDD of soil increases up to 0.5 % of plastic waste as stabilizer, but demand of water decreases as plastic does not absorb water. CBR value increased up to 1% of plastic waste as stabilizer. This could be effective method of disposal of plastic waste with respect to environmental concern.

No
Methods of recycling unplasticized polyvinyl chloride (uPVC) window frame waste were investigated. The quality of untreated granular waste was compared to that of waste treated by a range of contaminant removal processes including melt filtration and dissolution. Processability of each recyclate was evaluated by using a highly instrumented single screw extruder that enabled melt viscosity and process variation to be monitored in real time. Product quality measurements such as mechanical properties and surface defects were made on extruded strip, and the nature of the stabilizers present was determined. The mechanical properties of recyclates were found to be comparable to or better than those of virgin material in all cases and conformed to industry standards for window profile. Contaminant removal stages significantly reduced the amount of large surface defects detected in extrudate. Processability was comparable to that of virgin compounds, but melt viscosity varied among different batches of recyclate, depending on the source and composition of the original PVC formulation.

Natural Fibre Composites (NFCs) offer new opportunities to mitigate negative impact of engineering activities on the environment. Due to their lost cost, light weight and environmental benefits, they find applications in building, furniture and automotive industry. This study seeks to improve mechanical properties of composites made from waste recyclable plastics and natural fibres from agricultural byproduct sources such as Agave americana leaves, corn, wheat and seed flax straws. The approach used is a holistic one which includes investigating the availability and properties of natural fibres and their composites with waste plastic for use in Canada and Lesotho, a small country in Southern Africa. The social and environmental implications of using these materials are also investigated. In both Lesotho and Canada, there are enough raw materials which can be used in NFCs if the necessary environment is developed. The unique microstructural and interfacial behaviour of Agave americana fibres were investigated and their possible impact on the composites forecasted. Composites made with a variety of underutilized natural fibres: Agave americana, corn, seed flax and wheat were also manufactured and tested. The addition of natural fibres and milled straw to the waste plastic improved mainly the tensile and flexural moduli of the composites. The environmental properties of NFCs were also analyzed through a case study using Life Cycle Assessment (LCA) as tool. The results suggest that NFCs could be seen as a more environmentally friendly alternative than conventional composites.
Thesis (Ph.D, Chemical Engineering) -- Queen's University, 2008-12-03 12:32:23.095

碩士
龍華科技大學
工程技術研究所
95
Experiment studies of material synthesis with decomposition of waste plastic using a 13.56 MHz RF H2O plasma have been carried out. Polyethylene(PE) powders were heated using an externally applied electrical current up to approximately 450℃ for vaporizing and mixing into the discharge for decomposition. In this study, the plasma pressure and the electrode distance will be changed. Then, the electron density and electron temperature will be measured by single probe method. The radical species in plasma were measured by an optical spectroscope and the reaction products were analyzed using the gas-chromatograph with the mass-spectrometer. Experiment results show that ：(1) PE powder was effectively decomposed in H2O plasma to form various kinds of radicals such as CH, CO, and C2. (2) Reaction products collected by a cold trap downstream of the gas flow were quite different to those obtained in the experiment using 2.45GHz microwave discharge. (3) The category and proportions of the reaction products are varied under different chamber pressures and different electrode distance.

The contribution aims to evaluate the effect of a cellulose-based bio-plastic waste (cellulose acetate) on the current Italian Municipal Solid Waste (MSW) management system. Three main scenarios were proposed, assuming the collection of cellulose acetate waste with organic, plastic and mixed waste streams respectively. The treatment routes of organic, plastic and mixed waste were considered as a combined anaerobic digestion and composting process, mechanical sorting and recycling and mechanical-biological treatment followed by incineration, respectively. For the scope, experimental activities have been carried out in order to estimate the performance of each treatment from a technical point of view, described as performance of the process and performance of the outputs. Based on the technical results, environmental and economic assessments have been carried out in order to evaluate the carbon footprint and the total cost of the whole waste management system for each scenario. From each evaluation, three indices were calculated and combined through a multi-criteria decision analysis to identify the preference of the different scenarios according to four decision-makers. Results have revealed how, despite the presence of cellulose acetate resulted in no effect or small improvement in the process for organic and plastic treatment, the outputs were strongly affected by the presence of bio-plastic. On the other hand, during mixed waste treatment, cellulose acetate did not influence the process as well as the output was slightly improved. These achievements were applicable also to environmental and economic analysis. Both evaluations revealed that cellulose acetate performed worst when handled with organic waste, while the treatment of plastic and mixed waste with cellulose acetate gave similar and better results. The main reason for this result was the non-conformity of compost quality when treating cellulose acetate with organic waste, which limited the use of compost in agriculture. These results were combined through the multi-criteria decision analysis approach, which showed a reference for the treatment of cellulose acetate with mixed waste, while the one in organic one was significantly low. Finally, the contribution suggests the necessity to upgrade the current organic waste management system to increase the performance of bio-plastic waste treatment, which is the strategy pursued by Italy.

碩士
萬能科技大學
材料科學與工程研究所在職專班
101
The aim of this work is the production of CB/waste PET, CB/waste PLA and waste PLA/waste PET composites from carbon blank (CB), waste polyethylene terephthalate (PET) and waste polylactide (PLA) by means of a melt blending method using a barbender. Further, to increase the electromagnetic shielding property of those composites, the CB is studied as an alternative to waste PET and waste PLA. Systematically investigations of the electromagnetic shielding property of the ratio of CB on the electromagnetic interference shielding effectiveness (SE) of the CB/waste PET, CB/waste PLA blends and the ratio of waste PLA on the electromagnetic interference shielding effectiveness (SE) of the waste PLA/waste PET blends are reported. Meanwhile, the thermal properties of blends have been studied to evaluate the thermal stability and feasibility use in electromagnetic shielding materials. As the result of EMI tests, the SE values of CB5/waste PET specimens meet the commercial grade shell material of 2G, 3G mobile phone needs as the CB5 contents of CB5/waste PET specimens reach 10 wt.% and the CB5 contents of CB5/waste PLA specimens reach 6 wt.%. In addition, the CB5/waste PET specimens exhibits highest electromagnetic shielding effect for the 2400MHz wireless router or 2450MHz microwave housing products needs as the CB5 contents of CB5/waste PET specimens reach 15 wt.% and the CB5 contents of CB5/waste PLA specimens reach 6 wt.%. Apply the CB5/waste PET specimens to the shell material of 3001MHz VHF wireless microphone and 5810MHz wireless phone, that SE value is highest at CB5 contents equal to 20 wt.% and the CB5 contents of CB5/waste PLA specimens reach 20 wt.%. For application of CB5/waste PET specimens and CB5/waste PLA specimens in 6000 MHz computer shell, the optimal CB5 contents are 8 wt. % and 6 wt. %. Especially, the SE value of CB5/waste PLA specimens is 48.4 dB, beyond grade of industrial products. However, waste PLA and waste PET are difficult to processing to prepare a uniform waste PLA/waste PET blends and anti-electromagnetic wave material. Overall, CB blend with waste PET or waste PLA is a valuable technology for resource of waste PET and waste PLA. Manufacture of EMI Shielding material by recycling PET and PLA not only expand the use of PET and PLA, but also reduce the processing load on waste PET and waste PLA.