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Artykuły w czasopismach na temat "Supramolecular coordination polymers"

1

Jiang, Qian, Nicolas Desbois, Shifa Wang, and Claude P. Gros. "Recent developments in dipyrrin based metal complexes: Self-assembled nanoarchitectures and materials applications." Journal of Porphyrins and Phthalocyanines 24, no. 05n07 (2020): 646–61. http://dx.doi.org/10.1142/s1088424620300025.

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While dipyrrin-boron complexes (BODIPYs) and their derivatives have attracted much attention, dipyrrin-based metal complexes recently appeared as a novel luminescent material. So far, dipyrrin-metal complexes have been regarded as non-luminescent or weakly luminescent. Interestingly, introduction of steric hindrance at the meso-position and the development of heteroleptic complexes with proper frontier orbital ordering are two recent strategies that have been developed to improve their luminescent ability. Compared with BODIPYs, one of the distinctive advantages of dipyrrin-metal complexes is that they can form a series of self-assembled supramolecules and polymer assemblies via facile coordination reactions. In recent times, several supramolecular, coordination polymers and Metal-Organic Frameworks (MOFs) have been developed, [Formula: see text] by spontaneous coordination reactions between dipyrrin ligands and metal ions. As a novel luminescent material, dipyrrin-metal complexes have been applied in many fields. This review article summarizes recent developments in dipyrrin-metal complexes from the viewpoint of the improvement of luminescent ability, the formation of supramolecular and coordination polymers and their potential applications.
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Zhang, Jie-Peng, Xiao-Chun Huang, and Xiao-Ming Chen. "Supramolecular isomerism in coordination polymers." Chemical Society Reviews 38, no. 8 (2009): 2385. http://dx.doi.org/10.1039/b900317g.

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Nath, J. K. "Syntheses, Structural Insight and HirshFeld Surface Analysis of Two Heteroleptic Coordination Polymer of Cu(II)." Журнал структурной химии 64, no. 9 (2023): 116489. http://dx.doi.org/10.26902/jsc_id116489.

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Using a solvothermal method, we have synthesized two coordination polymers of Cu(II). One is a 1D polymer {[Cu(bpy)(NDC)(H 2 O)].2H 2 O} n (1, 1D) formed with 1,8-naphthalene dicarboxylic acid (H 2 NDC) and 2,2′ -bipyridine (bpy) as an auxiliary ligand, while the other is a 2D polymer {[Cu 3 (TMA)(Imd) 3 ].5H 2 O.2DMF} n (2, 2D) formed with trimellitic acid (H 3TMA) and imidazole (Imd) as an auxiliary ligand. Both coordination polymers 1 and 2 were formed through an in situ hydrolytic ring opening reaction of 1,8-naphthalic anhydride and trimelitic anhydride with bipyridine and imidazole ligands, respectively. The asymmetric unit of polymer 1 contains asymmetric η 1 binding mode (one of the carboxylate) linking distorted square-pyramidal [Cu(NDC)(bpy)(H 2 O)] 2+ coordination units. The syn-syn-η 1 :η 1 linear polymer conformation exist in the 1D coordination polymer with adjacent Cu…Cu distance is 6.849Å. A chain of cyclic tetrameric water clusters is present between the stacked layers of the 3D supramolecular structure. The formation of the 3D supramolecular structure is guided by various weak interactions such as OH…O, CH…O, CH…π and π…π interactions. The coordination polymers 2 forms 3D supramolecular architecture guided by various weak interactions such as OH…O, CH…O and NH…O interactions. The crystal structures of both coordination polymers have been determined using single crystal X-ray diffraction and their structural features are described.
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Harada, Akira, and Akihito Hashidzume. "Supramolecular Polymers Based on Cyclodextrins and Their Derivatives." Australian Journal of Chemistry 63, no. 4 (2010): 599. http://dx.doi.org/10.1071/ch09609.

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Since Lehn introduced the concept in the 1990s, supramolecular polymers have been developed rapidly by several research groups. Supramolecular polymers should be key materials for establishment of a sustainable society. This short review describes briefly hydrogen-bonded and coordination supramolecular polymers, and then reviews our research on cyclodextrin-based supramolecular polymers.
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Tzeng, Biing-Chiau, and Hsien-Te Yeh. "Self-Assembly of a Cd2+Compound with 4-Pyridylthioacetic Acid: Structural and Luminescence Properties." Zeitschrift für Naturforschung B 59, no. 11-12 (2004): 1320–24. http://dx.doi.org/10.1515/znb-2004-11-1251.

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Abstract An interesting 3-D supramolecular architecture has been constructed through O-H・ ・ ・O and S・ ・ ・S weak interactions based on a neutral 1-D coordination polymer, [Cd(pyta)2(H2O)]n (pyta = pyridylthiocarboxylate), by self-assembly of the Cd2+ion and Hpyta ligand. This supramolecular approach is achieved in combination of coordinative bonds, O-H・ ・ ・O and S・ ・ ・S interactions. The tetragonal unit of 1-D coordination polymers forms a 1-D channel structure with a dimension of 5.35×6.86 Å2in the solid state, leading to the formation of zeolite-like materials. In combination with the zeolitelike nature of the title compound as well as its luminescence behavior, it is expected to find useful applications in luminescence sensing for VOCs (volatile organic compounds).
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Abbas Omran, Khalida. "The Construct and Interpretation of Chelated Coordination Polymers and Their Use in Nanomaterials Research." Journal of Environmental and Public Health 2022 (August 10, 2022): 1–13. http://dx.doi.org/10.1155/2022/3937375.

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Presently, an important step from basic research to practical applications is synthesizing nanostructured materials. Metal-organic structures, as well as coordination polymers, are a diverse group of materials with a wide range of potential and properties applications. It has been difficult to get these materials into commercial use because of many drawbacks. Polymers containing chelated units are described and assessed for their advancements and problems in preparation, properties, and structure. Here, a proposed approach based on designing coordination polymeric materials with chelated units using the metal-ligand approach (CPM-CU-MA) has been introduced for a columnar-layered plan, supramolecular components, and building levels. Nanocomposite materials can be formed through the thermal transformation of coordination polymers based on donor atoms. The polymeric metal chelates (PMCs) are categorized according to luminescent coordination polymer (LCoP) development. It is classified as macrocyclic intracomplex, polynuclear, and molecular according to its macrostructure. Supramolecular networks (SMNs) can be transformed into a coordination polymer by introducing cyclo-dehydrogenation of natural building blocks on a surface. The structure-property connections of LCPs can influence a framework of liquid crystal display (LCP) that has been given based on LC phase modulators with a large modulation depth and has useful applications in LC lens. In the spatial organization of PMCs, the main focus is on the commonalities and contrasts between higher- and lower-molecular-weight chelates based on molecularly imprinted sensors (MISs) and nanomaterial sensors for a wide range of uses. New functional nanoparticles based on the molecular components have exciting potential, as demonstrated by these findings based on parameters risk factors for human health, hazards reduction in the environment, lack of cost-effectiveness, environmental sustainability, and bioavailability of polymers with an overall performance of 95.3%.
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van der Gucht, J., N. A. M. Besseling, and H. P. van Leeuwen. "Supramolecular Coordination Polymers: Viscosimetry and Voltammetry." Journal of Physical Chemistry B 108, no. 8 (2004): 2531–39. http://dx.doi.org/10.1021/jp036865r.

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Wang, Yong-Tao, Gui-Mei Tang, and Da-Wei Qin. "Metal-Controlled Assembly Tuning Coordination Polymers with Flexible 2-(1H-imidazole-1-yl)acetic Acid (Hima)." Australian Journal of Chemistry 59, no. 9 (2006): 647. http://dx.doi.org/10.1071/ch06183.

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Three new inorganic–organic coordination polymers based on a versatile linking unit 2-(1H-imidazole-1-yl)acetate (Hima) and divalent Mn(ii), Ni(ii), and Cu(ii) ions, exhibiting two kinds of two dimensionalities with different topological structures, have been prepared in water medium and structurally characterized by single-crystal X-ray diffraction analysis. Reaction of MnCl2·4H2O and Ni(NO3)2·6H2O with Hima yielded neutral two-dimensional (2D) coordination polymers [M(ima)2]n, M = Mn(ii) 1, and Ni(ii) 2 with isostructural 2D coordination polymers possessing (3,6) topology structures, which further stack into three-dimensional (3D) supramolecular networks through C–H···O weak interactions. However, when Cu(NO3)2·4H2O was used, a neutral 2D coordination polymer [Cu(ima)2]n 3 consisting of rhombus units was generated, which showed a 3D supramolecular network through C–H···O weak interactions. Among these polymers, the building block ima anion exhibits different coordination modes. These results indicate that the versatile nature of this flexible ligand, together with the coordination preferences of the metal ions, plays a critical role in construction of these novel coordination polymers. Spectral and thermal properties of these new materials have also been investigated.
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Chen, Chun-Long, Bei-Sheng Kang, and Cheng-Yong Su. "Recent Advances in Supramolecular Design and Assembly of Silver(I) Coordination Polymers." Australian Journal of Chemistry 59, no. 1 (2006): 3. http://dx.doi.org/10.1071/ch05225.

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The supramolecular chemistry of Ag(i) coordination assemblies continues to attract attention due to their versatile structural diversity and potential physical and chemical functions. This article provides a short review of recent advances in the design and construction of Ag(i) coordination polymers with special emphasis on the Ag(i) ion coordination geometry, ligand functionality, and supramolecular interactions. The potential functions of Ag(i) coordination polymers are briefly summarized.
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10

Yuan, C., J. Chen, S. Yu, et al. "Protein-responsive assemblies from catechol–metal ion supramolecular coordination." Soft Matter 11, no. 11 (2015): 2243–50. http://dx.doi.org/10.1039/c4sm02528h.

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A synergistic strategy combining the driving forces of both catechol–metal ion coordination and polymer self-assembly can organize polymers into hybrid nanoassemblies with tunable morphologies and protein-triggered disassembly features.
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