Gotowa bibliografia na temat „Self desiccation”

This paper focuses on the impact which polypropylene fiber (PF) has on the self-desiccation effect at early age of high performance concrete (HPC). The experimental results indicate that PF has little influence on the Internal Relative Humidity (IRH) caused by self-desiccation effect of concrete, but can reduce early aged self-desiccation shrinkage of concrete. With the PF dosage increasing, the values of early self-desiccation shrinkage of HPC decrease first and then increase. In the experimental conditions, the value of self-desiccation shrinkage of concrete with 0.6Kg/m3 PF is the lowest one.

High early strength (HES) concrete patching materials are increasingly used to repair damaged pavements. The use of HES concrete enables the repaired pavement to be opened to traffic shortly after the repair has been installed; for example, opening pavements to traffic 4–6 h after the concrete is placed is becoming more common. HES concrete mixtures are typically designed with a low water-to-cement ratio and a high cement content; they contain accelerating admixtures and limited supplementary cementitious materials. As a result, these HES patches may be susceptible to self-desiccation, causing autogenous shrinkage and early age cracking. Self-desiccation can lead to reduced hydration, limited strength gain, and overestimation of strength development in maturity-based predictions. The objectives of this study are threefold. First, the paper will illustrate how self-desiccation can lead to the premature cessation of hydration and increased potential for shrinkage cracking. Second, the paper will illustrate how maturity-based predictions can be modified to account for self-desiccation. Third, internal curing is discussed as a way to mitigate self-desiccation and shrinkage ultimately improving the performance of HES concrete patching materials.

The internal relative humidity (RH) plays a crucial role in most of the concrete properties. Self-desiccation caused by continuous cement hydration is a major factor affecting the RH of concrete. This paper investigates the relationship between RH and microstructure for cementitious systems in the case of self-desiccation. A series of paste specimens prepared with different binder and water-binder-ratio (w/b) were cured under sealed conditions from 1 day to 1.5 years. The RH and microstructure of the paste specimens were measured. The microstructure characteristics under study include porosity, pore size, evaporable and non-evaporable water content. The results reveal that the RH of cementitious system drops to a great extent in the first 105 days’ hydration and decreases slowly afterwards. The blended materials such as fly ash, slag or limestone powder have different influences on the RH. A mathematical model between RH and the average pore diameter is proposed for cementitious systems under self-desiccation, regardless of age, w/b or cement type.

Hoje em dia, o desenvolvimento dos superplastificantes permite a produção de betões com menor razão água/cimento. Ao usar razões água/cimento mais baixas, os materiais científicos apresentam maior tendência para fissurar devido à retracção autogénea. Este trabalho apresenta um estudo sobre a utilização de polímeros superabsorventes (SAP) no controlo da retracção. O uso de SAPs em materiais comentícios atenua a retracção autogénea pois estes produtos permitem o fornecimento interno de água. Estes produtos podem também afectar outras propriedades, afectando as características mecânicas e a trabalhabilidade. Para análise do efeito dos SAP foram estudadas argamassas com várias concentrações deste produto, tendo como referência argamassas semelhantes sem SAP, determinando-se as retracções autogénea e total, a resistência à compressão e o módulo de elasticidade. Além de SAP, foi também utilizado um agregado leve, um outro tipo de introdutor de água, para comparação com os polímeros em estudo. /ABSTRACT: This work presents a study on the use of superabsorbent polymers (SAP) in the control of shrinkage. The use of SAPs in cementitious materials reduces the autogenous shrinkage because these products enable the internal supply of water. These materials can also affect other properties such as mechanical properties and workability. To analyze the effect of SAP, mortars containing various concentrations of this product were studied, in comparison with reference mortars without SAP. The tests performed were autogenous and total shrinkage, compressive strength and modulus of elasticity. Besides SAP, it was also used a lightweight aggregate, another type of internal supply of water, for comparison with the polymers under study.

Les marais de l'Ouest ont été gagnés sur les sédiments fluvio-marins par poldérisation débutée dès le moyen âge. Les aménagements hydrauliques avaient, initialement, des objectifs sanitaires et d'élevage. A partir des endiguements, ils ont divisé les territoires en marais mouillés et marais desséchés. Depuis les années 1970 le développement des cultures intensives de céréales a nécessité un rabaissement complémentaire de la nappe par drainage en partie pour augmenter la désalinisation de surface et limiter l’engorgement des sols. Néanmoins, ces territoires restent caractérisés par des nappes proches de la surface. En conséquence les profils hydriques vont être gouvernés par les conditions météorologiques y compris l'évapotranspiration, la pluviométrie, mais également par les remontées capillaires issues d'une nappe salée. D'autre par la nature argileuse des sols et ses propriétés de retrait conditionnent énormément le fonctionnement hydrodynamique et les évolutions de structure.La première partie du travail a été de suivre les évolutions des profils hydriques et de salinité en parcelles non drainées (prairies) et en parcelles drainées (Maïs, Blé, Tournesol). Ces suivis ont été complétés par les mesures des niveaux de nappes et par des mesures tensiométriques via des bougies poreuses implantées à différentes profondeurs. L'objectif final a été de calculer et modéliser les profils de réserve utile (RU) et de RU "résiduelle" utilisable par les plantes. Dans ces systèmes alimentés par les remontées capillaires, le réseau racinaire puise l'eau dans la zone non saturée de surface (vadose) puis dans la zone saturée sous-jacente. La teneur en eau caractéristique de l'interface zone non saturée - zone saturée a été déterminée par analogie entre les chemins d'état de la matrice argileuse le long de sa courbe de retrait et du sol le long de sa courbe de compaction. Les profils de RU résiduelle utilisable par les plantes ont été calculés à partir des profils de teneurs en eau puis comparés aux profils de RU obtenus via les données de station météorologique. Ces profils de RU résiduelle ont pu être écrits sous forme d'équation polynomiale du second degré puis modélisés. Dans cet environnement alimenté par les remontées capillaires, ces profils de RU résiduelles peuvent être modélisés à partir d'un paramètre facilement mesurable en surface qui prend en compte la structure du sol et les conditions météorologique : soit la teneur en eau à 10 cm de profondeur. Cette modélisation reste suffisamment réaliste pour être utilisée comme un outil prédictif face à la pédodiversité et/ou les rendements de culture.A ce travail s'ajoute deux études préliminaires : - les mesures des conductivités thermiques effectives de ces sols par la méthode du fil chaud et leurs modélisations dans les systèmes biphasés : eau - argile et air - argile, mais également pour les systèmes triphasés non saturés : eau - air - argile. Les perspectives sont la modélisation des transferts thermiques et hydriques dans le sol à partir de la surface, - et l'élaboration d'un protocole d'imprégnation-polymérisation des sols argileux humides par des résines de type HEMA. Cette imprégnation permet d'envisager la confection de lames minces dans le matériau argileux induré avec conservation de sa structure initiale humide. Les perspectives sont la pétrographie quantitative à l'interface racine - sol le long de profils verticaux dans les environnements argileux à degrés de saturation et structure évolutives
The coastal marshlands are territories generally reclaimed on primary fluvio-marine sediments. They result from hydraulic managements and/or polderization which may date from the Middle Ages. Historically these hydraulic managements were built for goals of wholesomeness, breeding and farming. They isolate two territories: the dried marshes and the wet marshes. For the intensive cereal crops the slow drying caused by land reclamation was recently improved by the drainage, in part for increase the depth of desalinization and decrease waterlogging. Nevertheless, these territories remain characterized by shallow ground water of initial salt water. Consequently, the hydric profiles are governed by the meteoric conditions including the Evapotranspiration, the rainfall, but also the capillarity rises from the salt groundwater. Moreover, the clay dominated nature of the soils and their drastic shrinkage properties govern the hydrodynamic functioning and the soil structure behavior.The first part of the work was the monitoring of the water content and salinity profiles in drained cereal crops and in undrained grasslands. These measurements have been completed by the ground water level and tensiometric monitoring. The final goal was the calculation and modeling of the available water capacity (AWC) and plant available water (PAW) profiles. In these systems mainly supplied by the capillarity rises, the root network gets water in the subsurface vadose zone and then in the deeper saturated groundwater zone. The water content characteristic of the interface between the vadose and saturated zone was determined by comparison between the clay material state paths along its shrinkage curve and along its compaction curve. The PAW profiles were calculated from the water content profiles and then compared to the AWC profiles. The PAW profiles have been equated as polynomial second degree equations. In these shallow groundwater environments the PAW profiles have been modeled taking into account an easy measurable surface parameter which includes the soil structure behavior and the meteoric conditions: i.e. the water content measured at 10 cm depth. The PAW modelling remains sufficiently realistic to be used as a tool for farming management. Two preliminary studies were added to this work: - the measurement of effective thermal conductivity of the clayey soils by the transient hot wire method, and the modeling of the effective thermal conductivity of biphasic air-clay and water-clay media, but also triphasic unsaturated air-water-clay media. The prospect is the modeling of thermal and hydric transfer from the surface to the depth. - and the elaboration of a protocol of impregnation - hardening for wet clay dominated soils by HEMA resins. This impregnation allows the making of thin sections in these clay materials with conservation of their initial wet structures. The prospective is the quantitative petrography at the root - clay matrix interface along vertical profiles in clayey soils at different degrees of saturation and different structures

When colloidal droplets evaporate, material is often deposited at the periphery in a coffee-ring pattern. An understanding of colloidal transport and deposition in evaporating droplets is critical for optimization of many medical diagnostic devices and printing processes. This phenomenon can also be used for nanoparticle self-assembly, containerless materials processing, and manufacturing of flexible electronics. The forces affecting colloidal transport can be categorized as (i) convective effects, (ii) particle diffusion, and (iii) boundary effects. Knowledge of fluid flow in an evaporating droplet is required to understand particle transport when convection effects dominate over particle diffusion. The evaporative radial flow identified by Deegan et al. [1] is the result of contact line pinning and high evaporation flux at the contact line. Hu and Larson later identified that dominance of thermal Marangoni recirculation within the droplet can suppress ring formations by convecting particles to the center of the deposition. Bhardwaj et al. [2] demonstrated that van der Walls and electrostatic forces can dominate colloidal transport and capture particles on the substrate to form uniform depositions. These effects are represented by the Derjaguin, Verwey, and Overbeek (DLVO) force. This force can attract or repel particles from the surface or other particles when they are separated by less than the Debye length. Attractive DLVO forces result in uniform depositions when they dominate over the evaporative and Marangoni flows in evaporating droplets. Particle capture on the substrate has also been achieved by antibodies-antigen reactions, or by leveraging magnetic and electrophoretic forces. Particles can also be captured on the interface of evaporating droplets. Li et al. [3] observed uniform colloidal monolayers when water droplets were evaporated at elevated temperatures. They argued that particles were being captured on the interface in these cases as the particle diffusion rate was smaller than the velocity of the collapsing interface. This work will find a low cost method for electrowetting assisted deposition and examine how electric fields can disrupt the interplay between convection, diffusion, and interface trapping in evaporating colloidal droplets. Application of AC and DC electric fields has the potential to suppress the coffee-ring effect by independently controlling the shape of the fluid interface, the contact angle hysteresis, and the motion of particles suspended in the droplet. This investigation will compare the interfacial evolution and deposition patterns left by evaporating protein laden droplets under AC and DC fields to examine their suitability for medical diagnostic applications.