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1

Kumpulainen, Tatu, i Alexandre Fürstenberg. "SCS Photochemistry Section Meeting Fribourg, June 14, 2019". CHIMIA International Journal for Chemistry 73, nr 10 (30.10.2019): 840. http://dx.doi.org/10.2533/chimia.2019.840.

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On June 14, 2019, nearly 50 photochemists from all over Switzerland and beyond gathered together at the Haute Ecole d'Ingénierie et d'Architecture in Fribourg (HEIA-FR) for the annual SCS Photochemistry Section meeting to discuss their latest findings in the field. The organizing committee consisting of the board of the SCS Photochemistry Section put together a program consisting of 3 invited talks, 9 oral communications and a poster session with 24 posters to revive this event which, they hope, will take place annually. In addition, the general assembly of the Section was held at the premise during the day.
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2

Burrows, Hugh D., i Artur J. M. Valente. "Preface". Pure and Applied Chemistry 85, nr 7 (1.01.2013): iv. http://dx.doi.org/10.1351/pac20138507iv.

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The XXIVth IUPAC Symposium on Photochemistry was held in the old university city of Coimbra, Portugal from 15 to 20 July 2012, and welcomed 640 participants from 53 countries presenting their research on this important area of chemistry. This series of meetings started in Strasbourg in July 1964 as the International Symposium on Organic Photochemistry, organized by George Hammond and J. Levisalles. Subsequent symposia have seen the meeting expand to embrace all areas of photochemistry. The program topics of the Coimbra symposium ranged from materials aspects of photochemistry through nanostructures and nanomaterials to mechanistic and synthetic aspects of organic photochemistry, photobiology, photomedicine and skin photochemistry, applied photochemistry, and photochemistry and cultural heritage.The symposium had 8 plenary lectures, 22 invited lectures, 105 oral communications, and more than 400 posters, confirming the vitality of this area of chemistry. It is difficult to pinpoint specific highlights, as these depend very much on one's personal interests, but one of the most important presentations was undoubtedly Tom Meyer's Porter Medal Lecture on metal-to-ligand charge-transfer states in polypyridylruthenium(II) complexes and related systems. An IUPAC Photochemistry Symposium was previously held in Portugal, in Lisbon, in 1986, and it is interesting to note that Prof. Meyer also gave a plenary lecture there addressing some of the fundamental photophysics of these systems [Pure Appl. Chem.58, 1193 (1986)]. It is refreshing to see how these have developed from pure science to practical applications.George Porter gave a plenary lecture at the Lisbon symposium in 1986 on the first nanoseconds of photosynthesis. Developments in instrumentation in the intervening 26 years now make interrogation of excited-state behavior on the femtosecond timescale relatively straightforward, and as various presentations in this volume and in the symposium demonstrate, are helping unravel the importance of early events in many photochemical and photobiological processes.In addition to the lectures and poster presentations, the program also included a number of awards for young photochemists and posters, and a variety of social activities, including canoeing on the local River Mondego.We believe that the scientific program has maintained the excellent tradition of the IUPAC Photochemistry Symposia in showing that this continues to be a vibrant, exciting interdisciplinary area of research. This issue of Pure and Applied Chemistry contains a number of the plenary and invited lectures from the symposium, which we feel mirror the current state of the art of photochemistry as a dynamic and important field of chemistry.Hugh D. BurrowsJ. Sérgio Seixas de MeloArtur J. M. ValenteConference Editors
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3

Coyle, Emma E., i Michael Oelgemöller. "Micro-photochemistry: photochemistry in microstructured reactors. The new photochemistry of the future?" Photochemical & Photobiological Sciences 7, nr 11 (2008): 1313. http://dx.doi.org/10.1039/b808778d.

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Liu, Wenbo, i Chao-Jun Li. "Recent Synthetic Applications of Catalyst-Free Photochemistry". Synlett 28, nr 20 (14.09.2017): 2714–54. http://dx.doi.org/10.1055/s-0036-1590900.

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Catalyst-free photochemistry provides numerous opportunities toward sustainable synthesis because catalyst separation can usually be avoided, which is consistent with green chemistry principles. Complementary to the well-reviewed photoredox chemistry, this review specifically summarizes the synthetic applications of photochemistry without external catalysts reported since 2000. The selected examples include both natural product synthesis and new methodology development. This review is arranged based on the type of chromophore. It is our hope that this review will inspire more synthetic chemists to embrace photochemistry into their research plans.1 Introduction2 Photochemistry of Olefins2.1 [2+2] Cycloaddition of Enones and Olefins2.2 Cycloaddition of Olefins without Carbonyl Groups2.3 Z/E Isomerization2.4 Cyclization2.5 Others3 Photochemistry of C=O3.1 The Paternò–Büchi Reaction3.2 The Yang Photoenolization3.3 The Norrish Type I Reaction3.4 The Norrish Type II Reaction3.5 Others4 Photochemistry of Nitrogen-Containing Functional Groups5 Photochemistry of Halogen-Containing Compounds6 Conclusion and Outlook
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Lemon, Christopher M. "Corrole photochemistry". Pure and Applied Chemistry 92, nr 12 (16.12.2020): 1901–19. http://dx.doi.org/10.1515/pac-2020-0703.

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AbstractThe rapid expansion of photoredox catalysis and artificial photosynthesis has garnered renewed interest in the field of photochemistry. While porphyrins have been widely utilized for a variety of photochemical applications, corrole photochemistry remains underexplored, despite an exponential growth in corrole chemistry. Indeed, less than 4% of all corrole-related publications have studied the photochemistry of these molecules. Since corroles exhibit chemical properties that are distinct from porphyrins and related macrocycles, it is likely that this divergence would also be observed in their photochemical properties. This review provides a comprehensive summary of the extant corrole photochemistry literature. Corroles primarily serve as photosensitizers that transfer energy or an electron to molecular oxygen to form singlet oxygen or superoxide, respectively. While both of these reactive oxygen species can be used to drive chemical reactions, they can also be exploited for photodynamic therapy to treat cancer and other diseases. Although direct photochemical activation of metal–ligand bonds has been less explored, corroles mediate a variety of transformations, particularly oxygen atom transfer reactions. Together, these examples illustrate the diversity of corrole photochemistry and suggest that there are many additional applications yet to be discovered.
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6

WASHIDA, Nobuaki. "Spectroscopic Measurements in Photochemistry. X. Atmospheric Photochemistry." Journal of the Spectroscopical Society of Japan 40, nr 4 (1991): 235–46. http://dx.doi.org/10.5111/bunkou.40.235.

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García, Hermenegildo. "Preface". Pure and Applied Chemistry 77, nr 6 (1.01.2005): iv. http://dx.doi.org/10.1351/pac20057706iv.

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Photochemistry is a mature science. A characteristic hallmark of a consolidated scientific discipline is that it increasingly broadens its scope of interests from an initial central core toward the periphery where it interacts with other areas. Most of the current scientific research is characterized by an enriching multidisciplinarity, focusing on topics that combine backgrounds from different fields. In this way, the largest advances are taking place at the interphase between areas where different fields meet.This multidisciplinarity is, I believe, also a characteristic feature of the current situation for photochemistry. Thus, photochemistry was initially focused on the understanding and rationalization at a molecular level of the events occurring after light absorption by simple organic compounds. Molecular organic photochemistry constituted the core of this discipline, and it largely benefited from advances in the understanding of the electronic states provided by quantum mechanics. Later, photochemistry started to grow toward areas such as photobiology, photoinduced electron transfer, supramolecular photochemistry, and photochemistry in heterogeneous media, always expanding its sphere of interest.This context of increasing diversity in topics and specialization is reflected in this issue of Pure and Applied Chemistry. The contributors correspond to some of the plenary plus two invited lectures of the XXth IUPAC Symposium that was held 17ñ22 July in Granada, Spain. The program included plenary and invited lectures and oral contributions grouped in 13 sections covering femtochemistry, photochemistry of biomacromolecules, single-molecule photochemistry, and computational methods in photochemistry to nanotechnology, among others. These workshop titles give an idea of the breadth of themes that were included in this symposium. While it is obvious that the list of contributions correspond to different subdisciplines in photochemistry, all of them have a common scientific framework to rationalize the facts.The purpose of the symposium was to present an overview of the current status of some research fronts in photochemistry. This issue begins with the 2004 Porter Medal Lecture awarded jointly by the Asian, European, and Interamerican Photochemical Societies that was given to Prof. Graham Fleming (University of California, Berkeley) for his continued advances in photosynthesis. Prof. Flemingís studies have constituted a significant contribution to the understanding of the interplay between the structure of photosynthetic centers of green plants and the mechanism of energy migration toward the photosynthetic centers. These events take place in a very short time scale and are governed by the spatial arrangement of the constituents.Continuing with photobiology, the second article by Prof. Jean Cadet (Grenoble University) describes the type of photochemical damage and photoproducts arising from DNA UV irradiation. Knowledge of these processes is important for a better understanding of skin cancer and the possibilities for DNA repair. Closely related with DNA damage occurring upon irradiation, the article by Prof. Tetsuro Majima (Osaka University) provides an account of his excellent work on photosensitized oneelectron oxidation of DNA.The concept of "conical intersection", developed initially by Robb and Bernardi to rationalize the relaxation of excited states, led to the foundation of computational photochemistry, which has proved to be of general application to photochemical reactions. In this issue, Prof. Massimo Olivucci (University of Siena) shows that quantum chemical calculations can also be applied to photochemical reactions occurring in photobiology and, in particular, to the problem of vision. These calculations are characterized by the large number of atoms that are included and the fact that they have to estimate at a high calculation level and with high accuracy the energy of states differring in a few kcal mol-1.The next article corresponds to one of the two invited lectures included in this issue. The one given by Dr. Virginie Lhiaubet-Vallet (Technical University of Valencia) in the workshop Photophysical and Photochemical Approaches in the Control of Toxic and Therapeutic Activity of Drugs describes the enantioselective quenching of chiral drug excited states by biomolecules. Moving from photobiology to free radical polymerization with application in microlithography, the article by Prof. Tito Scaiano (University of Ottawa) reports among other probes an extremely elegant approach to detect the intermediacy of radicals in photochemical reactions based on a silent fluorescent molecular probe containing a free nitroxyl radical.Solar energy storage is a recurrent topic and a long-desired application of photochemistry. In her comprehensive contribution, Prof. Ana Moore (Arizona State University) summarizes the continued seminal contribution of her group to the achievement of an efficient solar energy storage system based on the photochemical generation of long-lived charge-separated states. Another possibility of solar energy storage consists of water splitting. In his article, Prof. Haruo Inoue (Tokyo Metropolitan University) deals with artificial photosynthetic methods based on the use of ruthenium porphyrins as photosensitizers for the two-electron oxidation of water with formation of dioxygen.Also in applied photochemistry, Prof. Luisa De Cola (University of Amsterdam) reports on intramolecular energy transfer in dinuclear metal complexes having a meta-phenylene linker. The systems described by Prof. De Cola have potential application in the field of light-emitting diodes, since most of the complexes described exhibit electroluminescence. The second invited lecture is by Dr. Alberto Credi (University of Bologna), one of Europeís most promising young photochemists. In his interesting article, the operation upon light excitation of a rotaxane molecular machine is described. A macro-ring acting as electron donor moiety in a charge-transfer complex is threaded in a dumbbell-shaped component having two viologen units with different redox potential. Light absorption produces the cyclic movement of the macro-ring from one viologen station to the other.The last two contributions fall within the more classic organic photochemistry realm. Prof. Axel Griesbeck (University of Cologne) describes the multigram synthesis of antimalarial peroxides using singlet-oxygen photosensitizers adsorbed or bonded to polymer matrices. The last contribution comes from Prof. Heinz Roth (University of Rutgers), who has worked during his entire career in the fields of organic photochemistry and radical ion chemistry. Prof. Roth has summarized his vast knowledge in radical ion chemistry, reviewing the mechanism of triplet formation arising from radical ion pair recombination. This mechanism for triplet formation is currently gaining a renewed interest owing to the potential applicability to the development of phosphors.I hope that the present selection will be appealing and attractive for a broad audience of readers interested in photochemistry and will give readers an idea of the state of the art of some current topics in this area.Hermenegildo GarcíaConference Editor
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8

Braslavsky, S. E. "Glossary of terms used in photochemistry, 3rd edition (IUPAC Recommendations 2006)". Pure and Applied Chemistry 79, nr 3 (1.01.2007): 293–465. http://dx.doi.org/10.1351/pac200779030293.

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Abstract: The second edition of the Glossary of Terms Used in Photochemistry [Pure Appl. Chem.68, 2223-2286 (1996); <http://www.iupac.org/publications/pac/1996/pdf/6812x2223.pdf>] has been both corrected and updated. Terms have been added related to molecular anisotropy, the use of polarized radiation, nonlinear optical phenomena, and the emerging field of computation of excited species. Some changes have been introduced in this "Glossary" regarding the terms related to radiation energy to make this collection fully compatible with internationally agreed-upon terms. Many links are included to various Web pages listing quantities relevant to the work of photochemists and scientists using photochemical tools.
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9

Baeyens, Robin, Thomas Konings, Olivia Venot, Ludmila Carone i Leen Decin. "Grid of pseudo-2D chemistry models for tidally locked exoplanets – II. The role of photochemistry". Monthly Notices of the Royal Astronomical Society 512, nr 4 (26.03.2022): 4877–92. http://dx.doi.org/10.1093/mnras/stac809.

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ABSTRACT Photochemistry is expected to change the chemical composition of the upper atmospheres of irradiated exoplanets through the dissociation of species, such as methane and ammonia, and the association of others, such as hydrogen cyanide. Although primarily the high altitude day side should be affected by photochemistry, it is still unclear how dynamical processes transport photochemical species throughout the atmosphere, and how these chemical disequilibrium effects scale with different parameters. In this work we investigate the influence of photochemistry in a 2D context, by synthesizing a grid of photochemical models across a large range of temperatures. We find that photochemistry can strongly change the atmospheric composition, even up to depths of several bar in cool exoplanets. We further identify a sweet spot for the photochemical production of hydrogen cyanide and acetylene, two important haze precursors, between effective temperatures of 800 and 1400 K. The night sides of most cool planets (Teff &lt; 1800 K) are shown to host photochemistry products, transported from the day side by horizontal advection. Synthetic transmission spectra are only marginally affected by photochemistry, but we suggest that observational studies probing higher altitudes, such as high-resolution spectroscopy, take photochemistry into account.
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10

Scandola, Franco. "Preface". Pure and Applied Chemistry 83, nr 4 (1.01.2011): iv. http://dx.doi.org/10.1351/pac20118304iv.

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Latest in a long series of successful conferences, the XXIIIrd IUPAC Symposium on Photochemistry was held in Ferrara, Italy on 11-16 July 2010. The conference venues were the Opera Theatre and the Estense Castle, in the historic center of the city. The contrasting mix of modern science and ancient environment was a special trait of the Ferrara symposium.The symposium was attended by over 500 delegates (including some 130 Ph.D. students) from 40 different countries. The scientific program consisted of 8 plenary lectures, 23 invited lectures, 97 selected oral presentations, as well as 354 posters. A highlight of the symposium was the presentation of the Porter Medal to Prof. David Phillips of Imperial College London, UK, in recognition of his outstanding contributions to several fields of photochemistry. The title of his lecture was “Targeted sensitizers for photodynamic therapy”.The wide variety of fields encompassed by modern photochemistry is reflected by the list of sessions held within the symposium: Electron and Energy Transfer, Molecular Switches and Machines, Organic Photochemistry, Inorganic Photochemistry, Photochromic Systems, Solar Energy, Supramolecular Photochemistry, Nanoparticles, Photocatalysis, Ultrafast Spectroscopy, Theoretical Photochemistry, Exciton and Charge Dynamics, Microscopy, Nanoscopic Systems, Singlet Oxygen and Phototherapy, Photobiology, Fluorescent Labels, Photoactive Materials, Applied Photochemistry, and Organized Media. Most of the topics discussed were characterized by a fertile combination of fundamental insight, advanced techniques, and practical application.This issue of Pure and Applied Chemistry collects a number of papers based on plenary and invited lectures delivered at the symposium. I hope that this collection will help illustrate modern photochemistry not only as a lively and exciting research field but also as a powerful resource toward the solution of important practical problems.Franco ScandolaConference Editor
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11

Kashyap, Akshay, Elamparuthi Ramasamy, Vijayakumar Ramalingam i Mahesh Pattabiraman. "Supramolecular Control of Singlet Oxygen Generation". Molecules 26, nr 9 (2.05.2021): 2673. http://dx.doi.org/10.3390/molecules26092673.

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Singlet oxygen (1O2) is the excited state electronic isomer and a reactive form of molecular oxygen, which is most efficiently produced through the photosensitized excitation of ambient triplet oxygen. Photochemical singlet oxygen generation (SOG) has received tremendous attention historically, both for its practical application as well as for the fundamental aspects of its reactivity. Applications of singlet oxygen in medicine, wastewater treatment, microbial disinfection, and synthetic chemistry are the direct results of active past research into this reaction. Such advancements were achieved through design factors focused predominantly on the photosensitizer (PS), whose photoactivity is relegated to self-regulated structure and energetics in ground and excited states. However, the relatively new supramolecular approach of dictating molecular structure through non-bonding interactions has allowed photochemists to render otherwise inactive or less effective PSs as efficient 1O2 generators. This concise and first of its kind review aims to compile progress in SOG research achieved through supramolecular photochemistry in an effort to serve as a reference for future research in this direction. The aim of this review is to highlight the value in the supramolecular photochemistry approach to tapping the unexploited technological potential within this historic reaction.
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12

Shpol'skii, E. V. "Contemporary photochemistry". Uspekhi Fizicheskih Nauk 163, nr 4 (1993): 87. http://dx.doi.org/10.3367/ufnr.0163.199304h.0087.

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Zhu, X. "Surface Photochemistry". Annual Review of Physical Chemistry 45, nr 1 (październik 1994): 113–44. http://dx.doi.org/10.1146/annurev.pc.45.100194.000553.

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Neckers, Douglas C., i Xichen Cai. "Organic photochemistry". Annual Reports Section "B" (Organic Chemistry) 105 (2009): 380. http://dx.doi.org/10.1039/b905115p.

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Shpol'skiĭ, É. V. "Contemporary photochemistry". Physics-Uspekhi 36, nr 4 (30.04.1993): 295–310. http://dx.doi.org/10.1070/pu1993v036n04abeh002154.

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Glassgold, A. E. "CIRCUMSTELLAR PHOTOCHEMISTRY". Annual Review of Astronomy and Astrophysics 34, nr 1 (wrzesień 1996): 241–77. http://dx.doi.org/10.1146/annurev.astro.34.1.241.

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Smith-Freeman, L. A., W. P. Schroeder i C. Wittig. "AsH3Ultraviolet Photochemistry†". Journal of Physical Chemistry A 113, nr 10 (12.03.2009): 2158–64. http://dx.doi.org/10.1021/jp8094769.

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Steinmetz, Mark G. "Organosilane Photochemistry". Chemical Reviews 95, nr 5 (lipiec 1995): 1527–88. http://dx.doi.org/10.1021/cr00037a017.

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Hayden, Brian E. "Surface photochemistry". Journal of Electroanalytical Chemistry 433, nr 1-2 (sierpień 1997): 229. http://dx.doi.org/10.1016/s0022-0728(97)88941-3.

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Cı́rkva, Vladimı́r, Jana Kurfürstová, Jindřich Karban i Milan Hájek. "Microwave photochemistry". Journal of Photochemistry and Photobiology A: Chemistry 168, nr 3 (grudzień 2004): 197–204. http://dx.doi.org/10.1016/j.jphotochem.2004.05.028.

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Ramamurthy, V., i N. J. Turro. "Photochemistry: Introduction". Chemical Reviews 93, nr 1 (styczeń 1993): 1–2. http://dx.doi.org/10.1021/cr00017a600.

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Ramamurthy, V., i N. J. Turro. "Photochemistry: Introduction". Chemical Reviews 93, nr 2 (marzec 1993): 585–86. http://dx.doi.org/10.1021/cr00018a600.

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Lloyd, K. G., B. Roop, A. Campion i J. M. White. "Surface photochemistry". Surface Science 214, nr 1-2 (kwiecień 1989): 227–39. http://dx.doi.org/10.1016/0039-6028(89)90420-2.

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Lloyd, K. G., B. Roop, A. Campion i J. M. White. "Surface photochemistry". Surface Science Letters 214, nr 1-2 (kwiecień 1989): A256. http://dx.doi.org/10.1016/0167-2584(89)90050-9.

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Al-Ekabi, Hussain, i Paul De Mayo. "Surface photochemistry". Tetrahedron 42, nr 22 (styczeń 1986): 6277–84. http://dx.doi.org/10.1016/s0040-4020(01)88090-x.

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Balzani, Vicenzo. "Supramolecular photochemistry". Tetrahedron 48, nr 48 (listopad 1992): 10443–514. http://dx.doi.org/10.1016/s0040-4020(01)88348-4.

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von Zelewsky, Alex. "Supramolecular photochemistry". Inorganica Chimica Acta 209, nr 1 (lipiec 1993): 111. http://dx.doi.org/10.1016/s0020-1693(00)84990-7.

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Truscott, T. G. "Bioorganic Photochemistry". Journal of Photochemistry and Photobiology A: Chemistry 59, nr 1 (czerwiec 1991): 131. http://dx.doi.org/10.1016/1010-6030(91)87077-9.

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Ho, W. "Surface photochemistry". Surface Science 299-300 (styczeń 1994): 996–1007. http://dx.doi.org/10.1016/0039-6028(94)90712-9.

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Bochu, Christophe, Axel Couture, Pierre Grandclaudon i Alain Lablache-Combier. "Dienamide photochemistry". Journal of the Chemical Society, Chemical Communications, nr 11 (1986): 839. http://dx.doi.org/10.1039/c39860000839.

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Morandeira, Ana, Alexandre Fürstenberg, Olivier Nicolet, Stéphane Pages, Bernhard Lang i Eric Vauthey. "Ultrafast Photochemistry". CHIMIA International Journal for Chemistry 56, nr 12 (1.12.2002): 690–94. http://dx.doi.org/10.2533/000942902777679849.

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Balzani, Vincenzo. "Supramolecular photochemistry". Pure and Applied Chemistry 62, nr 6 (1.01.1990): 1099–102. http://dx.doi.org/10.1351/pac199062061099.

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Bruce, James. "Organic photochemistry". Annual Reports Section "B" (Organic Chemistry) 103 (2007): 370. http://dx.doi.org/10.1039/b617918p.

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Neckers, Douglas C. "Organic photochemistry". Annual Reports Section "B" (Organic Chemistry) 104 (2008): 349. http://dx.doi.org/10.1039/b717026m.

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Dünkel, Lothar. "Supramolecular Photochemistry". Zeitschrift für Physikalische Chemie 175, Part_1 (styczeń 1992): 125. http://dx.doi.org/10.1524/zpch.1992.175.part_1.125.

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Hennig, H. "Surface Photochemistry". Zeitschrift für Physikalische Chemie 198, Part_1_2 (styczeń 1997): 278–79. http://dx.doi.org/10.1524/zpch.1997.198.part_1_2.278a.

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Dünkel, L. "Surface Photochemistry". Zeitschrift für Physikalische Chemie 202, Part_1_2 (styczeń 1997): 303–5. http://dx.doi.org/10.1524/zpch.1997.202.part_1_2.303a.

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Coohill, Thomas P. "Photobiology/Photochemistry". International Journal of Toxicology 17, nr 5 (sierpień 1998): 559–65. http://dx.doi.org/10.1080/109158198226062.

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Exposure of living organisms to non-ionizing electromagnetic radiation (here confined to the visible and part of the ultraviolet, 200-800 nm) can cause a toxic reaction. The details of the exposure, both in intensity and wavelength composition, will determine the degree of effect. If absorbing chromophores, both endogenous and exogenous, are present, additional response can be elicited. Whether the radiation reaches a sensitive target will depend upon the depth of penetration and the opacity of the cell or tissue. The final effect will be determined by the initial photoproducts produced, the subsequent reactions they cause, and the amount of repair of damage by cellular processes. In some cases it is possible to predict the complete response; in others it is variable.
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Coyle, John. "Organic Photochemistry". Journal of Photochemistry 40, nr 1 (wrzesień 1987): 190–91. http://dx.doi.org/10.1016/0047-2670(87)87056-9.

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Suslick, K. S., i R. A. Watson. "Metalloporphyrin photochemistry". Journal of Inorganic Biochemistry 36, nr 3-4 (sierpień 1989): 318. http://dx.doi.org/10.1016/0162-0134(89)84501-5.

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Sanders, J. K. M. "Supramolecular photochemistry". Journal of Inclusion Phenomena and Molecular Recognition in Chemistry 13, nr 1 (maj 1992): 105–6. http://dx.doi.org/10.1007/bf01076677.

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