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Artykuły w czasopismach na temat „Nickel sulfide”

Autor: Grafiati

Data publikacji: 4 czerwca 2021

Data aktualizacji: 3 lutego 2022

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1

Wilkin, Richard T., i David A. Rogers. "Nickel sulfide formation at low temperature: initial precipitates, solubility and transformation products". Environmental Chemistry 7, nr 6 (2010): 514. http://dx.doi.org/10.1071/en10076.

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Environmental context Remediation technologies often rely on manipulation of redox conditions or natural redox processes to favour microbial sulfate-reduction and mineral sulfide formation for treatment of inorganic contaminants in groundwater, including nickel. However, few data are available on the structural properties, solubility and mineral transformation processes involving nickel sulfides. These data are needed in order to constrain the long term performance of groundwater remediation efforts. Abstract The formation of nickel sulfides has been examined experimentally over the temperature range from 25 to 60°C. At all conditions studied, hexagonal (α-NiS) was the initial precipitate from solution containing Ni2+ and dissolved sulfide. Freshly precipitated nickel sulfide possesses significant residual Ni–O coordination as revealed by X-ray absorption spectroscopy. With progressive aging, residual Ni–O coordination is replaced by Ni–S coordination. The formation of millerite (β-NiS, rhombohedral) was not detected in any of the synthesis experiments. In the presence of elemental sulfur, hexagonal NiS converted to polydymite (Ni3S4) and vaesite (NiS2). Thus, conversion of nickel monosulfide to thiospinel and disulfide structures appears to be redox dependent, analogous to aging and transformation processes of iron sulfides. In the absence of elemental sulfur or with only hydrogen sulfide or bisulfide present, transformation of hexagonal NiS was not observed after 1680 h at 60°C. Low-pH solubility experiments yielded a solubility product for hexagonal NiS of log Ks0 = –2.69 ± 0.26. Solubility data at pH > 3 suggest that Ni–bisulfide complexation is important in controlling the solubility of Ni in sulfidic solutions.

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2

Selivanov, Evgeny N., O. V. Nechvoglod i R. I. Gulyaeva. "Thermal Expansion of Copper and Nickel Sulfides and their Alloys". Defect and Diffusion Forum 334-335 (luty 2013): 55–59. http://dx.doi.org/10.4028/www.scientific.net/ddf.334-335.55.

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Thermal expansion coefficients of metal sulfides and their alloys are important for technological processes calculations of sulfide processing materials, for example, the crystallization equipment of nickel and copper-nickel converter matte. The synthesized copper and nickel monosulfide, and nickel and copper-nickel matte have been used as the initial samples. Dilatometric analysis was carried out by dilatometer (Linseis L78 RITA). Differences in the values measured are accounted for by the synthesis samples facilities, the coexistence of several non-stoichiometric sulfide phases and interaction during heating. In the temperature 20-500°C range the coefficients of thermal expansion (α) for the sulfides of copper, nickel and their alloys are changed from 10.4 to 20.610-6 1/K. Changes in the value α are accounted for by phase transitions in sulfide samples at their heating. Considering the properties of the phase components are an additive it is shown the thermal expansion coefficient complex sulfide-metal alloys is possible to calculate.

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3

Zhang, Ya Hui, Xi Cheng i Qing Wang. "A Low Temperature Precursor Sulfuration Route to Metal Sulfides Nanomaterials". Advanced Materials Research 148-149 (październik 2010): 1404–7. http://dx.doi.org/10.4028/www.scientific.net/amr.148-149.1404.

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A low-temperature precursor sulfuration route has been established to prepare metal sulfides with different nanostructures during the synthesis of nickel sulfide. The advantages of the low-temperature precursor sulfuration route were testified by the synthesis of different metal sulfides ( lead sulfide, zinc sulfide and cobalt sulfide). It offers a novel path to the preparation of other metal sulfides.

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4

Nechvoglod, Olga V., i Alena G. Upolovnikova. "The study of the phase composition of the products of electrochemical oxidation of sulfide granules of the system Cu1.96S–Ni3S2–Cu–Ni". Butlerov Communications 57, nr 3 (31.03.2019): 149–54. http://dx.doi.org/10.37952/roi-jbc-01/19-57-3-149.

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The crystallization rate of copper and nickel sulfides influences on the phase formation processes. The high crystallization rate (about 103 degrees/s), achieved through granulation of the sulfide copper-nickel melt, leads to the stabilization of non-stoichiometric phases, the formation of ultrafine structures, which are grains and partial dissolution of the metal component in the sulfide. The structure of the granules is formed by nickel sulfide (Cu1.96S) phases in the form of dendritic inclusions of 2-20 µm in size in the nickel sulfide phase (Ni3S2). According to the phase diagram of the state of Cu – Ni – S, a solid solution of Cu – Ni may be present in the composition of eutectic compounds with copper and nickel sulphides. The electrochemical oxidation of copper and nickel sulfides in a solution of sulfuric acid occurs through a series of successive phase transformations described in the work, during which the conversion of sulfides occurs in intermediate oxidation states oxidizing to the elemental state: Cu1.96S → Cu1.8S → Cu1.75S → CuS → S; Ni3S2 → NiS → S. The non-stoichiometric composition of compounds suggests the presence of excessive or deficient sulfur and metal contents in the crystal lattice, which can affect the mechanism and sequence of phase transformations during the electrochemical oxidation of sulfide granules. Dissolution occurs not only on the surface of the granules, but also along the grain boundaries. The leached areas form capillaries inside the granules, through which electrolyte enters the electrochemical reactions. Porous sulfur sulfide sludge forms on the surface of the granules. The phase composition of the sludge was studied. The main phase components of poorly soluble products are nickel granules Ni3+хS2–Cu2-хS.

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5

Hartmann, Nathaniel J., Guang Wu i Trevor W. Hayton. "Activation of CS2 by a “masked” terminal nickel sulfide". Dalton Transactions 45, nr 37 (2016): 14508–10. http://dx.doi.org/10.1039/c6dt00885b.

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Activation of carbon disulfide (CS₂) by “masked” terminal nickel sulfide, [K(18-crown-6)][(L^tBu)Ni(S)], gives a trithiocarbonate complex. This result confirms the nucleophilicity of the sulfide ligand and expands the scope of reactivity for late metal sulfides.

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6

Pan, Yuan, Yinjuan Chen, Xiao Li, Yunqi Liu i Chenguang Liu. "Nanostructured nickel sulfides: phase evolution, characterization and electrocatalytic properties for the hydrogen evolution reaction". RSC Advances 5, nr 127 (2015): 104740–49. http://dx.doi.org/10.1039/c5ra18737k.

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Nanostructured nickel sulfides with different phases were synthesized and their electrocatalytic activity for hydrogen evolution was investigated. β NiS exhibits the best catalytic activity among all the nickel sulfide catalysts.

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7

LU, PAI, i DONGFENG XUE. "EMULSION-ASSISTED SYNTHESIS OF NICKEL SULFIDE HIERARCHICAL ARCHITECTURES". Modern Physics Letters B 23, nr 31n32 (30.12.2009): 3843–49. http://dx.doi.org/10.1142/s0217984909021909.

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We herein demonstrated the preparation of nickel sulfide hierarchical architectures via an emulsion-assisted route in hydrothermal system. Scanning electron microscope images of the products at different reaction stages indicated that the construction of the nanostructured hierarchical nickel sulfide was accomplished through oriented attachment accompanied by an encapsulation procedure, and the as-obtained products exhibited uniform architectures assembled by various primary units (e.g. nanorods, nanosheets). In addition, the effect of different surfactants on the shape of nickel sulfide nanostructures was further studied. The results indicated that the hierarchical architectures can only be achieved with the assistance of anionic surfactant (e.g. sodium dodecyl sulfate). These as-prepared novel hierarchical nanostructures may be used in various areas, including industrial catalysis, and energy storage etc.

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8

Zhang, Ya Hui, i Qing Wang. "The New Progress of Nickel Sulfide Synthesis". Advanced Materials Research 366 (październik 2011): 318–21. http://dx.doi.org/10.4028/www.scientific.net/amr.366.318.

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Nickel sulfide has been the subject of considerable interest because of its potential applications in many fields. In this paper, the synthesis of nickel sulfide nanostructures is described. The Morphologies of as prepared nickel sulfide nanostructures are summarized. And the applications and prospects of nickel sulfide in this field also are analyzed.

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9

Kim, Jong Seon, Gun Whan Lee, Ki Won Kim, Jou Hyen Ahn, Gyu Bong Cho, Ho Suk Ryu i Hyo Jun Ahn. "The Discharge Properties of Nickel Sulfide Thin Film Prepared from Sulfidation of Nickel Foil". Materials Science Forum 544-545 (maj 2007): 1073–76. http://dx.doi.org/10.4028/www.scientific.net/msf.544-545.1073.

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The nickel sulfide (Ni3S2) thin film could be prepared from Ni/S double layer, which was deposited on nickel foil using evaporation and sputtering. The nickel sulfide electrode was discharged and charged between 0.6V and 2.6V versus Li/Li+ at room temperature. The nickel sulfide film had the first discharge capacity of 270mAh/g, and two plateaus at 1.3V and 1.8V.

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10

Fortin, D., G. Southam i T. J. Beveridge. "Nickel sulfide, iron-nickel sulfide and iron sulfide precipitation by a newly isolated Desulfotomaculum species and its relation to nickel resistance". FEMS Microbiology Ecology 14, nr 2 (czerwiec 1994): 121–32. http://dx.doi.org/10.1111/j.1574-6941.1994.tb00099.x.

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11

Karbanee, Nazneen, Robert P. van Hille i Alison E. Lewis. "Controlled Nickel Sulfide Precipitation Using Gaseous Hydrogen Sulfide". Industrial & Engineering Chemistry Research 47, nr 5 (marzec 2008): 1596–602. http://dx.doi.org/10.1021/ie0711224.

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12

Wu, Kaili, Baochan Yang, Xixi Zhu, Wei Chen, Xiliang Luo, Zhenxue Liu, Xiao Zhang i Qingyun Liu. "Cobalt and nickel bimetallic sulfide nanoparticles immobilized on montmorillonite demonstrating peroxidase-like activity for H2O2 detection". New Journal of Chemistry 42, nr 23 (2018): 18749–58. http://dx.doi.org/10.1039/c8nj04647f.

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13

McDonald, Robbie G., Jian Li i Peter J. Austin. "High Temperature Pressure Oxidation of a Low-Grade Nickel Sulfide Concentrate with Control of the Residue Composition". Minerals 10, nr 3 (9.03.2020): 249. http://dx.doi.org/10.3390/min10030249.

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High temperature pressure oxidation of a low-grade nickel concentrate was examined to demonstrate the potential benefits and shortcomings of this approach. The high iron sulfide content ensured that acid generation was much greater than for higher grade concentrates. This results in the formation of basic iron sulfate phases and a significant amount of sulfuric acid. Kinetic sampling during pressure oxidation tests also demonstrated the transformation of sulfide minerals, including the oxidative transformations of pentlandite to violarite and then to vaesite, the latter phase not previously noted in studies of this kind. Finally, addition of a divalent metal sulfate buffer, here magnesium sulfate, mitigates the formation of basic iron sulfates but with greater generation of sulfuric acid in the leach liquor. Under the conditions employed in this study, this acid could be employed to leach other nickel-containing materials such as nickel laterites.

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14

Li, Guangshi, Xiaolu Xiong, Liping Wang, Lang Che, Lizhen Wei, Hongwei Cheng, Xingli Zou i in. "Sulfation Roasting of Nickel Oxide–Sulfide Mixed Ore Concentrate in the Presence of Ammonium Sulfate: Experimental and DFT Studies". Metals 9, nr 12 (25.11.2019): 1256. http://dx.doi.org/10.3390/met9121256.

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Sulfation roasting, a common activation technique, is a potential method for cleaner production of nickel from complex low-grade ores. In this study, nickel oxide–sulfide mixed ore concentrate was roasted with the addition of ammonium sulfate under a static air atmosphere, and the roasted products were leached by water, in order to evaluate the extraction of metals. The ammonium sulfate activation roasting was investigated thoroughly and systematically by thermogravimetry–differential scanning calorimetry, X-ray diffraction, and scanning electron microscopy. Particularly, the interface sulfation behavior and path were studied by the density functional theory (DFT) method. The results showed that a large amount of nonferrous metal sulfate (70% Ni, 89% Co, and 90% Cu) was generated, while iron was almost entirely transformed into iron oxide under appropriate roasting conditions of adding ammonium sulfate at a mass ratio of 200%, heating to 650 °C at 10 °C/min, and holding for 120 min. It was found that activation of ammonium sulfate can take two different paths: one in which ammonium sulfate directly reacts with raw ores below 500 °C and the other in which the SO2 decomposed from sulfates (ammonium sulfate, intermediate ammonium ferric sulfate, and ferric sulfate) reacts with the intermediate metal sulfides (NiS and Cu2S). The interface sulfation mechanism of NiS and Cu2S was investigated deeply by DFT method, which showed that there are two paths of sulfation for NiS or Cu2S, and both of them are thermodynamically favored. Thus, a thorough and systematic investigation of ammonium sulfate activation roasting of nickel oxide–sulfide mixed ore is provided; this might be a potential basis for future industrial applications of ammonium sulfate activation roasting techniques in complex mineral metallurgy.

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15

McDonald, Robbie G., i Jian Li. "The High Temperature Co-Processing of Nickel Sulfide and Nickel Laterite Sources". Minerals 10, nr 4 (14.04.2020): 351. http://dx.doi.org/10.3390/min10040351.

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The pressure oxidation of low-grade nickel sulfide concentrate with high iron sulfides content generates significant amounts of sulfuric acid that must be neutralized. This acid can be utilized to leach metal values from ores such as nickel laterites. The present study demonstrates the use of a low-grade nickel concentrate generated from Poseidon Nickel Mt Windarra ore to enable additional nickel and cobalt extraction from a Bulong Nickel Operation nickel laterite blend. The co-processing of these materials at 250 °C, with oxygen overpressure, using total pulp densities of 30% or 40% w/w, and a range of nickel concentrate to nickel laterite mass ratios between 0.30–0.53, yielded base metal extractions of 95% or greater. The final free acid range was between 21.5–58.5 g/L, which indicates that enough in situ sulfuric acid was generated during co-processing. The acid was shown from mineralogical analysis to be efficiently utilized to dissolve the laterite ore, which indicates that the primary iron hydrolysis product was hematite, while the aluminum-rich sodium alunite/jarosite phase that formed hosts approximately 5% of the hydrolyzed iron.

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16

Liu, Shanqi, Yongbing Li, Yiwen Ju, Jie Liu, Jianming Liu i Yaolin Shi. "Equilibrium nickel isotope fractionation in nickel sulfide minerals". Geochimica et Cosmochimica Acta 222 (luty 2018): 1–16. http://dx.doi.org/10.1016/j.gca.2017.10.018.

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17

RAMASAMY, KARTHIK, WEERAKANYA MANEEPRAKORN, NASIR IQBAL, MOHAMMAD AZAD MALIK i PAUL O'BRIEN. "COBALT(II)/NICKEL(II) COMPLEXES OF DITHIOACETYLACETONE [M(SacSac)2](M = Co, Ni) AS SINGLE SOURCE PRECURSORS FOR COBALT/NICKEL SULFIDE NANOSTRUCTURES". International Journal of Nanoscience 10, nr 04n05 (sierpień 2011): 815–22. http://dx.doi.org/10.1142/s0219581x11009234.

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Cobalt(II)/Nickel(II) complexes of 4-thiopent-3-ene-2-thione (SacSac), [ M(SacSac) 2]( M = Co, Ni ) have been used as single source precursors (SSPs) for the preparation of cobalt/nickel sulfide thin films by aerosol-assisted chemical vapor deposition (AACVD). Cobalt or nickel sulfide nanoparticles were grown by thermal decomposition of the precursor in hot trioctylphosphine oxide (TOPO) or hexadecylamine (HDA). XRD analysis showed that all samples of cobalt or nickel sulfide are of the sulfur deficient phases ( Ni9S8, Co9S8, Ni7S6 , or Ni3S2 ). SEM and TEM analysis showed that nickel sulfide formed nanowires, nanorods and spheres; cobalt sulfide formed plate like structures and spheres. The chemical compositions of the nanoparticles can be controlled by varying temperature or the capping agents.

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18

Nechvoglod, O. V., Evgeny N. Selivanov i S. V. Mamyachenkov. "Effect of Structure on the Electrochemical Oxidation Rate of Copper and Nickel Sulfides". Defect and Diffusion Forum 326-328 (kwiecień 2012): 383–87. http://dx.doi.org/10.4028/www.scientific.net/ddf.326-328.383.

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Synthesized samples were crystallized at 10 - 1000 K/sec (νcooling) to study the effect of sulfides structure on the electrochemical oxidation rates. The methods of X-ray, optical and electronic microscopy are used to analyze the phase composition, and the methods of voltamperometry and chronoamperometry are used to study the laws of electrochemical oxidation. Slow cooling of the samples with sulfide phase (Cu1,96S, Ni3S2) leads to crystallization of the metal (Ni, Cu). High cooling rate leads to crystallization of non-equilibrium phases, increasing of proportion of the sulfide phase and decreasing of metallic component up to complete disappearance. It is shown that electrochemical oxidation of copper and nickel sulfides proceeds stepwise: Me2S Me2-XS Me1+XS MeS Me2+ + S. Experiments have revealed the rates of electrochemical oxidation of granular sulfides that exceed the rates established for the slowly cooled samples. The rates of the electrochemical oxidation of Ni3S2 at potential of 1500 mV are 8.810-8 g/sec·mm2 (at vcooling = 10 К/sec) and 1.310-7 g/sec·mm2 (at νcooling = 1000 К/sec). The rates of the electrochemical oxidation of Cu2S at potential of 1000 mV are 2.810-8 g/sec·mm2 (at νcooling = 10 К/sec) and 4.310-8 g/sec·mm2 (at νcooling = 1000 К/sec). It is found that the forming of a passivation layer effects the rate of the electrochemical oxidation of copper sulfide and nickel sulfide. Non-equilibrium phase composition and refinement provide greater reactivity of sulfides in the conditions of anodic polarization. The oxidation and passivation of metallic phase along with sulfide phases proceed from the surface of Me2S Me alloys. As for the samples crystallized at 1000 K/sec only anodic oxidation of sulfides occurs due to a lack of metallic phase. The compositions of passivation films and potentials providing the extraction of sulfur in the elemental state from the sulfides crystallized at high rates were determined.

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19

Luganov, Vladimir, Brajendra Mishra, Saule Baimakhanova i Rinat Akpanbayev. "Chemical Enrichment of Nickel Sulfide". International Journal of Nonferrous Metallurgy 05, nr 01 (2016): 1–8. http://dx.doi.org/10.4236/ijnm.2016.51001.

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Lacroix, M., M. Vrinat i M. Breysse. "Unsupported nickel tungsten sulfide catalysts". Applied Catalysis 21, nr 1 (luty 1986): 73–83. http://dx.doi.org/10.1016/s0166-9834(00)81329-9.

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21

Holcomb, Gordon R., i Stephen D. Cramer. "Nickel sulfide hollow whisker formation". Materials Characterization 38, nr 2 (luty 1997): 67–73. http://dx.doi.org/10.1016/s1044-5803(97)80025-3.

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Didik, V. A., V. V. Kaminskiĭ, E. A. Skoryatina, V. P. Usacheva, N. V. Sharenkova i A. V. Golubkov. "Nickel diffusion in samarium sulfide". Technical Physics Letters 32, nr 7 (lipiec 2006): 555–57. http://dx.doi.org/10.1134/s1063785006070017.

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23

Himstedt, Rasmus, Dominik Hinrichs i Dirk Dorfs. "Extinction Coefficient of Plasmonic Nickel Sulfide Nanocrystals and Gold-Nickel Sulfide Core-Shell Nanoparticles". Zeitschrift für Physikalische Chemie 233, nr 1 (19.12.2018): 3–14. http://dx.doi.org/10.1515/zpch-2018-1165.

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Abstract In the presented work, the molar extinction coefficient of plasmonic heazlewoodite (Ni3S2) nanoparticles and Au-Ni3S2 core-shell nanoparticles is determined for the first time. The results are compared to analogously determined extinction coefficients of pure Au nanocrystals (NCs), which themselves correlate very well with existing literature on the subject. The measured extinction coefficients at the localized surface plasmon resonance (LSPR) maximum wavelength of nickel sulfide particles are similar to the values of equally sized Au NCs. Therefore, considering the lower cost of the heazlewoodite material, it could be a reasonable alternative for optical applications of nanoparticles showing a LSPR in the visible regime of the electromagnetic spectrum. Furthermore, this study shows, that by growing a Ni3S2 shell onto a pure Au nanocrystal a highly tuneable optical material with variable LSPR frequency and molar extinction coefficient is obtained.

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24

Ghezelbash, Ali, i Brian A. Korgel. "Nickel Sulfide and Copper Sulfide Nanocrystal Synthesis and Polymorphism". Langmuir 21, nr 21 (październik 2005): 9451–56. http://dx.doi.org/10.1021/la051196p.

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Kang, Jinhyeon, i Sanggyu Yim. "Enhanced cycle stability of a NiCo 2 S 4 nanostructured electrode for supercapacitors fabricated by the alternate-dip-coating method". Royal Society Open Science 5, nr 8 (sierpień 2018): 180506. http://dx.doi.org/10.1098/rsos.180506.

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Nanostructured nickel cobalt sulfide (NiCo 2 S 4 ) electrodes are successfully fabricated using a simple alternate-dip-coating method. The process involves dipping a TiO 2 nanoparticles-covered substrate in a nickel/cobalt precursor solution and sulfur precursor solution alternately at room temperature. The fabricated bimetallic sulfide electrode exhibits a synergetic improvement compensating for the disadvantages of the two single metal sulfide electrodes, i.e. the poor cycle stability of the nickel sulfide electrode and the low specific capacitance ( C sp ) of the cobalt sulfide electrode. The two capacitive properties are optimized by adjusting the ratio of nickel and cobalt concentrations in the metal precursor solution, reaching a C sp of 516 F g −1 at a current density of 1 mA cm −2 , with its retention being 99.9% even after 2000 galvanostatic charge–discharge cycles.

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Wang, Fanmao, Feng Liu, Richard Elliott, Sabereh Rezaei, Leili Tafaghodi Khajavi i Mansoor Barati. "Solid State Extraction of Nickel from Nickel Sulfide Concentrates". Journal of Alloys and Compounds 822 (maj 2020): 153582. http://dx.doi.org/10.1016/j.jallcom.2019.153582.

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Gole, Ajay V., i Shivram S. Garje. "Preparation of Nickel Sulfide Thin Films and Nanocrystallites Using Nickel Furfuraldehyde Thiosemicarbazone as Single-Source Precursor". Advanced Materials Research 383-390 (listopad 2011): 3828–34. http://dx.doi.org/10.4028/www.scientific.net/amr.383-390.3828.

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Nickel furfuraldehyde thiosemcarbabazone adduct of the type, NiCl2(L)2(L = furfuraldehyde thiosemicarbazone) was synthesized by the reaction between nickel dichloride hexahydrate and furfuraldehyde thiosemicarbazone in 1:2 stoichiometry. The resulting compound was characterised by elemental analysis, IR,1H and13C{1H} NMR spectral data. It was further used as a single-source precursor for the deposition of nickel sulfide thin films by aerosol assisted chemical vapour deposition (AACVD) technique and the nickel sulfide nanocrystallites by pyrolysis and solvothermal decomposition methods. The thin films obtained were characterised by powder X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive analysis by X-rays (EDAX) and atomic force microscopy (AFM). The nanocrystallites obtained were also characterized by XRD, EDAX as well as transmission electron microscopy (TEM). The SEM images of the thin films show formation of different morphologies of nickel sulfide, i.e. nanoball-like, nanowires to flower-like depending on the growth temperature. The mechanism for the variation of the morphology with the growth temperature has been proposed. The XRD of the nanocrystallites obtained matches with the hexagonal phase of nickel sulfide and the TEM images show formation of 10-50 nm spherical nano-crystals.

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Sung, Kiwhan, Sang Hyun Lee, Taek-Mo Chung i Chang Gyoun Kim. "A Facile Route to Nano-Sized Nickel Sulfide via Thermolysis of Nickel Alkanethiolate". Journal of Nanoscience and Nanotechnology 8, nr 9 (1.09.2008): 4873–76. http://dx.doi.org/10.1166/jnn.2008.ic57.

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Nano-sized nickel sulfides were synthesized by the thermolysis of nickel alkanethiolates in the presence of coordinating ligands. Nickel alkanethiolates were synthesized by the reaction of the square planar nickel 1-dimethylamino-2-methyl-2-propanolate [Ni(dmamp)2] with various n-alkanethiols. The effect of ligands in the reaction system has been investigated to control the size and shape of nano-sized nickel sulfides. TEM images show that the products are nano-sized nickel sulfides in rod and plate shapes. Nickel alkanethiolates and nano-sized nickel sulfides have been characterized by means of X-ray diffraction and transmission electron microscopy.

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Aso, Keigo, Akitoshi Hayashi i Masahiro Tatsumisago. "Preparation conditions of NiS active material in high-boiling solvents for all-solid-state lithium secondary batteries". New J. Chem. 38, nr 4 (2014): 1731–37. http://dx.doi.org/10.1039/c3nj01432k.

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The formation mechanism of nickel sulfide was investigated by changing reaction conditions, examining intermediates, and verifying the effects of capping ability of a coordinating solvent on crystal phases of nickel sulfide.

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Kobayashi, Hiroshi, Hirofumi Shoji, Satoshi Asano i Masaki Imamura. "Chlorine Leaching Mechanism of Nickel Sulfide". Journal of the Japan Institute of Metals 80, nr 11 (2016): 713–18. http://dx.doi.org/10.2320/jinstmet.j2016019.

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Craig, B. D., J. K. Brownlee i T. V. Bruno. "Sulfide Stress Cracking of Nickel Steels". CORROSION 48, nr 2 (luty 1992): 90–97. http://dx.doi.org/10.5006/1.3299824.

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Tanabe, Teruo, Tsuyoshi Mitarai, Zenjiro Asaki i Yoshio Kondo. "Oxidation of Mixed Nickel-Cobalt Sulfide". Journal of the Japan Institute of Metals 49, nr 8 (1985): 633–39. http://dx.doi.org/10.2320/jinstmet1952.49.8_633.

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Tanabe, Teruo, Makoto Ogawa, Zenjiro Asaki i Yoshio Kondo. "Oxidation of Mixed Nickel-Iron Sulfide". Journal of the Japan Institute of Metals 50, nr 2 (1986): 192–200. http://dx.doi.org/10.2320/jinstmet1952.50.2_192.

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Tanabe, Teruo, Tsuyoshi Mitarai, Zenjiro Asaki i Yoshio Kondo. "Oxidation of Mixed Nickel-Cobalt Sulfide". Transactions of the Japan Institute of Metals 28, nr 4 (1987): 299–306. http://dx.doi.org/10.2320/matertrans1960.28.299.

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Tanabe, Teruo, Makoto Ogawa, Zenjiro Asaki i Yoshio Kondo. "Oxidation of Mixed Nickel-Iron Sulfide". Transactions of the Japan Institute of Metals 28, nr 6 (1987): 487–97. http://dx.doi.org/10.2320/matertrans1960.28.487.

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Bishop, D. W., P. S. Thomas i A. S. Ray. "Raman spectra of nickel(II) sulfide". Materials Research Bulletin 33, nr 9 (wrzesień 1998): 1303–6. http://dx.doi.org/10.1016/s0025-5408(98)00121-4.

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Wang, Yan, i Huan Pang. "Nickel‐Based Sulfide Materials for Batteries". ChemistrySelect 3, nr 45 (5.12.2018): 12967–86. http://dx.doi.org/10.1002/slct.201802348.

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You, Bo, i Yujie Sun. "Hierarchically Porous Nickel Sulfide Multifunctional Superstructures". Advanced Energy Materials 6, nr 7 (18.01.2016): 1502333. http://dx.doi.org/10.1002/aenm.201502333.

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Cheng, Zhe, Harry Abernathy i Meilin Liu. "Raman Spectroscopy of Nickel Sulfide Ni3S2". Journal of Physical Chemistry C 111, nr 49 (grudzień 2007): 17997–8000. http://dx.doi.org/10.1021/jp0770209.

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Huang, Shanshan, Elisa Lopez-Capel, David A. C. Manning i David Rickard. "The composition of nanoparticulate nickel sulfide". Chemical Geology 277, nr 3-4 (październik 2010): 207–13. http://dx.doi.org/10.1016/j.chemgeo.2010.08.001.

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Gu, Yong-Pan, Ying Zhang, Meng-Yao Wang, Yu-Xin Huang, Zi-Yi Zhang, Shao-Hong Wei i Wei-Min Du. "High-Performance Solid-State Hybrid Supercapacitors Based on One-Dimensional Nickel Sulfide Nano-Arrays and Commercial Activated Carbon". Science of Advanced Materials 12, nr 6 (1.06.2020): 899–907. http://dx.doi.org/10.1166/sam.2020.3729.

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Nano-materials with ordered structures exhibit the valuable application in the domain of supercapacitors due to the internal structural advantages. Herein, one-dimensional nickel sulfide nano-arrays were prepared by a one-pot solvothermal method. When applied as the binder-free electrodes of supercapacitors, one-dimensional nickel sulfide nano-arrays can achieve superior electrochemical properties. It is particularly important that solidstate hybrid supercapacitors based on one-dimensional nickel sulfide nano-arrays and commercial activated carbon can achieve the areal energy density of 0.355 mWh cm–2 and stable voltage window of 0–1.6 V. In the meantime, the current hybrid supercapacitors can deliver the outstanding working lifetimes and the higher practical value. Such exciting results demonstrates that one-dimensional nickel sulfide nano-arrays have the wide application prospects in the field of small, lightweight, and mobile electronic products.

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42

Stepanov, V. A., V. Ye Kungurova i I. A. Koidan. "Металлогения Камчатского срединного массива". Bulletin of the North-East Science Center, nr 4 (28.12.2020): 39–54. http://dx.doi.org/10.34078/1814-0998-2020-4-39-54.

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The article describes the ore bearance of three stages of reflected activation of the Kamchatka middle massif: Late Cretaceous, Eocene, and Miocene. In the first stage, gold mineralization of the gold-quartz and gold-sulfide-quartz formations was formed; in the second - sulfide platinoid-copper-nickel; in the third - gold-copper-molybdenum-porphyry. The relationship of gold, sulfide platinoid-copper-nickel and gold-copper-molybdenum-porphyry mineralization with certain igneous rock complexes - (Kola, Dukuk and Lavkin) is shown. The mining of nickel, copper from the Shanuch deposit and gold from placers has been noted.

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Le Vaillant, Margaux, Stephen J. Barnes, James E. Mungall i Emma L. Mungall. "Role of degassing of the Noril’sk nickel deposits in the Permian–Triassic mass extinction event". Proceedings of the National Academy of Sciences 114, nr 10 (21.02.2017): 2485–90. http://dx.doi.org/10.1073/pnas.1611086114.

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The largest mass extinction event in Earth's history marks the boundary between the Permian and Triassic Periods at circa 252 Ma and has been linked with the eruption of the basaltic Siberian Traps large igneous province (SLIP). One of the kill mechanisms that has been suggested is a biogenic methane burst triggered by the release of vast amounts of nickel into the atmosphere. A proposed Ni source lies within the huge Noril’sk nickel ore deposits, which formed in magmatic conduits widely believed to have fed the eruption of the SLIP basalts. However, nickel is a nonvolatile element, assumed to be largely sequestered at depth in dense sulfide liquids that formed the orebodies, preventing its release into the atmosphere and oceans. Flotation of sulfide liquid droplets by surface attachment to gas bubbles has been suggested as a mechanism to overcome this problem and allow introduction of Ni into the atmosphere during eruption of the SLIP lavas. Here we use 2D and 3D X-ray imagery on Noril’sk nickel sulfide, combined with simple thermodynamic models, to show that the Noril’sk ores were degassing while they were forming. Consequent “bubble riding” by sulfide droplets, followed by degassing of the shallow, sulfide-saturated, and exceptionally volatile and Cl-rich SLIP lavas, permitted a massive release of nickel-rich volcanic gas and subsequent global dispersal of nickel released from this gas as aerosol particles.

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Sathiyaraj, Ethiraj, Govindasamy Gurumoorthy i Subbiah Thirumaran. "Nickel(ii) dithiocarbamate complexes containing the pyrrole moiety for sensing anions and synthesis of nickel sulfide and nickel oxide nanoparticles". New Journal of Chemistry 39, nr 7 (2015): 5336–49. http://dx.doi.org/10.1039/c4nj02250e.

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Rare anagostic interaction is observed in (N-(pyrrol-2-ylmethyl)-N-furfuryldithiocarbamato-S,S′)(thiocyanato-N)(triphenylphosphine)nickel(ii). Bis(N-(pyrrol-2-ylmethyl)-N-furfuryldithiocarbamato-S,S′)nickel(ii) is used for the preparation of spherical nickel sulfide and nickel oxide nanoparticles.

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Liang, Shuqin, Meizan Jing, Erum Pervaiz, Haichuan Guo, Tiju Thomas, Weiyu Song, Jian Xu i in. "Nickel–Iron Nitride–Nickel Sulfide Composites for Oxygen Evolution Electrocatalysis". ACS Applied Materials & Interfaces 12, nr 37 (17.08.2020): 41464–70. http://dx.doi.org/10.1021/acsami.0c11324.

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Phimsen, Songphon, Worapon Kiatkittipong, Hiroshi Yamada, Tomohiko Tagawa, Kunlanan Kiatkittipong, Navadol Laosiripojana i Suttichai Assabumrungrat. "Nickel sulfide, nickel phosphide and nickel carbide catalysts for bio-hydrotreated fuel production". Energy Conversion and Management 151 (listopad 2017): 324–33. http://dx.doi.org/10.1016/j.enconman.2017.08.089.

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Sun, Jian Zhi, Bo Wei Chen, Jian Kang Wen i Biao Wu. "Nickel Bioleaching at Elevated pH: Research and Application". Solid State Phenomena 262 (sierpień 2017): 197–201. http://dx.doi.org/10.4028/www.scientific.net/ssp.262.197.

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Biohydrometallurgy has broad application prospect in the treatment of low-grade nickel sulfide ore. However, quite a number of nickel sulfide deposits are associated with basic gangue minerals such as contain olivine, serpentine. The high basic gangue minerals will lead to a higher acid consumption and make it difficult to bioleach at pH below 2.5. It is crucial to improve processes and adapt bacteria with this kind of ore. This paper reviews the experimental researches and industrial applications for bioleaching of the high acid consumption nickel sulfide ores. It is suggested that bioleaching at elevated pH will have similar leaching rate compared with pH below 2.5, meanwhile the cost will be decreased remarkably due to a lower acid consumption and less dissolved impurity ions.

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Tang, Min, Bao Liang Ge i Shu Ming Wen. "Exploiting the Influence of Oxidization on Ultra-Fine Copper and Nickel Sulfide Containing Pt-Pd in Yunnan Mine". Advanced Materials Research 712-715 (czerwiec 2013): 760–63. http://dx.doi.org/10.4028/www.scientific.net/amr.712-715.760.

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It is known that oxidation is one of the most common ways for penlandite to be introducted into tailing during traditional coarse-particle sulfide flotation. However, it could become much more complicated and challenging problems for the low-grade, fine-disseminated Cu-Ni sulfides containing Pt and Pd in Yunnan Mine, accompanied with more than 75% of the content of MgO in the ore sample is. Direct flotation tests had been conducted to extract the metallic values as much as possible by adding traditional depressants and collectors, such as carboxylmethyl cellulose, starch, sodium silicate, butyl xanthate, (BX), butyl ammonium dithophosphate (BA) and etc., the relatively satisfied recoveries of Cu, Ni, Pt and Pd in the concentrate from bench flotation tests were obtained, however, more than 30% of metallic values still lost in the slime. In this study, bench flotation tests for the ore sample fromYunnan Mine, micro-flotation tests of serpentines and pentlandite from Jinchuan Mine and their settling rate tests were conducted to figure out how the oxidation influence the recovery of the ultra-fine nickel sulfide. All the tests results pointed to the presence of over-oxidation on the ultra-fine nickel sulfide surface and lead to the loss of Ni containing Pt and Pd in the slime tailing. Some methods which tried to slow the speed of oxidation on mineral surface during grinding and flotation were introduced in order to recover the values before over-oxidation of sulfides; however, the slime coating of serpentines also may play an important role in disturbing the floatability of ultra-fine sulfide.

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Manikandan, Ramu, C. Justin Raj, Kook Hyun Yu i Byung Chul Kim. "Self-coupled nickel sulfide @ nickel vanadium sulfide nanostructure as a novel high capacity electrode material for supercapattery". Applied Surface Science 497 (grudzień 2019): 143778. http://dx.doi.org/10.1016/j.apsusc.2019.143778.

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Yuan, Binxia, i Weiling Luan. "Phase-controlled synthesis of nickel sulfide series via solvothermal method". Functional Materials Letters 07, nr 01 (luty 2014): 1450003. http://dx.doi.org/10.1142/s1793604714500039.

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Nickel sulfide series nanoparticles were synthesized by a simple solvothermal reduction method of nickel chloride and element sulfur in the oleylamine solvent. This method could offer potential advantages of mildness, safety, low cost, and simplified fabrication procedures. Through the adjustment of Ni / S raw material ratio, different phases of nickel sulfide, including cubic NiS 2, hexagonal NiS , orthorhombic Ni 7 S 6, and trigonal Ni 3 S 2 were obtained. In addition, the sulfur sources played important roles in the synthesis of nickel sulfide series compounds. The possible growth mechanisms had been discussed based on the influence of reaction temperatures and solvents on the phase structure and detailed composition of the final products. Finally, the obtained optical properties demonstrated that each sample had the unique absorption peak except cubic NiS 2.

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