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Gotowe bibliografie tematyczne / Nanoglasses

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Gotowa bibliografia na temat „Nanoglasses”

Autor: Grafiati

Data publikacji: 6 września 2023

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Artykuły w czasopismach na temat "Nanoglasses"

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Chen, Na, Di Wang, Tao Feng, Robert Kruk, Ke-Fu Yao, Dmitri V. Louzguine-Luzgin, Horst Hahn i Herbert Gleiter. "A nanoglass alloying immiscible Fe and Cu at the nanoscale". Nanoscale 7, nr 15 (2015): 6607–11. http://dx.doi.org/10.1039/c5nr01406a.

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Synthesized from ultrafine particles with a bottom-up approach, nanoglasses are of particular importance in pursuing unique properties. From different kinds of nanoglasses with immiscible metals, nanoglass alloys are created, which may open an avenue to an entirely new world of solid solutions. These new solid solutions are likely to have properties that are yet unknown in today's alloys.

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Gleiter, Herbert. "Nanoglasses: a new kind of noncrystalline materials". Beilstein Journal of Nanotechnology 4 (13.09.2013): 517–33. http://dx.doi.org/10.3762/bjnano.4.61.

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Nanoglasses are a new class of noncrystalline solids. They differ from today’s glasses due to their microstructure that resembles the microstructure of polycrystals. They consist of regions with a melt-quenched glassy structure connected by interfacial regions, the structure of which is characterized (in comparison to the corresponding melt-quenched glass) by (1) a reduced (up to about 10%) density, (2) a reduced (up to about 20%) number of nearest-neighbor atoms and (3) a different electronic structure. Due to their new kind of atomic and electronic structure, the properties of nanoglasses may be modified by (1) controlling the size of the glassy regions (i.e., the volume fraction of the interfacial regions) and/or (2) by varying their chemical composition. Nanoglasses exhibit new properties, e.g., a Fe90Sc10 nanoglass is (at 300 K) a strong ferromagnet whereas the corresponding melt-quenched glass is paramagnetic. Moreover, nanoglasses were noted to be more ductile, more biocompatible, and catalytically more active than the corresponding melt-quenched glasses. Hence, this new class of noncrystalline materials may open the way to technologies utilizing the new properties.

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Gleiter, Herbert. "Nanoglasses: A Way to Solid Materials with Tunable Atomic Structures and Properties". Materials Science Forum 584-586 (czerwiec 2008): 41–48. http://dx.doi.org/10.4028/www.scientific.net/msf.584-586.41.

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Recently, a new class of materials - called nanoglasses - with a glassy structure was synthesized. The novel feature of these materials is that the atomic structure in the entire volume of the material as well as the density of the material can be tuned. Nanoglasses are generated by introducing interfaces into metallic glasses on a nanometer scale. Interfaces in these nanoglasses delocalize upon annealing, so that the free volume associated with these interfaces spreads throughout the volume of the glass. This delocalization changes the atomic structure and the density of the glass throughout the volume. In fact, by controlling the spacing between the interfaces introduced into the glass as well as the degree of the delocalization (by modifying the annealing time and/or annealing temperature), the atomic structures as well as the density (and hence all structure/density dependent properties) of nanoglasses may be controlled. A comparable tuning of the atomic structure/density of crystalline materials is not conceivable, because defects in crystals do not delocalize upon annealing.

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Nandam, Sree Harsha, Ruth Schwaiger, Aaron Kobler, Christian Kübel, Chaomin Wang, Yulia Ivanisenko i Horst Hahn. "Controlling shear band instability by nanoscale heterogeneities in metallic nanoglasses". Journal of Materials Research 36, nr 14 (8.07.2021): 2903–14. http://dx.doi.org/10.1557/s43578-021-00285-4.

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Abstract Strain localization during plastic deformation drastically reduces the shear band stability in metallic glasses, ultimately leading to catastrophic failure. Therefore, improving the plasticity of metallic glasses has been a long-standing goal for several decades. In this regard, nanoglass, a novel type of metallic glass, has been proposed to exhibit differences in short and medium range order at the interfacial regions, which could promote the formation of shear transformation zones. In the present work, by introducing heterogeneities at the nanoscale, both crystalline and amorphous, significant improvements in plasticity are realized in micro-compression tests. Both amorphous and crystalline dispersions resulted in smaller strain bursts during plastic deformation. The yield strength is found to increase significantly in Cu–Zr nanoglasses compared to the corresponding conventional metallic glasses. The reasons for the mechanical behavior and the importance of nanoscale dispersions to tailor the properties is discussed in detail. Graphic Abstract

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Ivanisenko, Yulia, Christian Kübel, Sree Harsha Nandam, Chaomin Wang, Xiaoke Mu, Omar Adjaoud, Karsten Albe i Horst Hahn. "Structure and Properties of Nanoglasses". Advanced Engineering Materials 20, nr 12 (26.10.2018): 1800404. http://dx.doi.org/10.1002/adem.201800404.

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Feng, Tao. "Electrodeposited Nanoglasses: Preparation, Structure, and Properties". Video Proceedings of Advanced Materials 2, nr 2 (1.02.2021): 2021–0182. http://dx.doi.org/10.5185/vpoam.2021.0182.

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Şopu, D., K. Albe, Y. Ritter i H. Gleiter. "From nanoglasses to bulk massive glasses". Applied Physics Letters 94, nr 19 (11.05.2009): 191911. http://dx.doi.org/10.1063/1.3130209.

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Kalcher, Constanze, Omar Adjaoud, Jochen Rohrer, Alexander Stukowski i Karsten Albe. "Reinforcement of nanoglasses by interface strengthening". Scripta Materialia 141 (grudzień 2017): 115–19. http://dx.doi.org/10.1016/j.scriptamat.2017.08.004.

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Çetin, Ayşegül Ö., i Murat Durandurdu. "Hard boron rich boron nitride nanoglasses". Journal of the American Ceramic Society 101, nr 5 (21.12.2017): 1929–39. http://dx.doi.org/10.1111/jace.15383.

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Franke, Oliver, Daniel Leisen, Herbert Gleiter i Horst Hahn. "Thermal and plastic behavior of nanoglasses". Journal of Materials Research 29, nr 10 (28.05.2014): 1210–16. http://dx.doi.org/10.1557/jmr.2014.101.

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Rozprawy doktorskie na temat "Nanoglasses"

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Sopu, Daniel [Verfasser], Albe [Akademischer Betreuer] Karsten i Horst [Akademischer Betreuer] Hahn. "Molecular Dynamics Simulations of Metallic Nanoglasses / Daniel Sopu. Betreuer: Albe Karsten ; Horst Hahn". Darmstadt : Universitäts- und Landesbibliothek Darmstadt, 2011. http://d-nb.info/1106113330/34.

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Nandam, Sree Harsha [Verfasser], Horst [Akademischer Betreuer] Hahn i Karsten [Akademischer Betreuer] Durst. "Structure and mechanical properties of metallic nanoglasses / Sree Harsha Nandam ; Horst Hahn, Karsten Durst". Darmstadt : Universitäts- und Landesbibliothek Darmstadt, 2019. http://d-nb.info/1186890398/34.

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Wang, Chaomin [Verfasser], Horst [Akademischer Betreuer] Hahn i Karsten [Akademischer Betreuer] Albe. "Atomic structure and structural stability of Fe90Sc10 nanoglasses / Chaomin Wang ; Horst Hahn, Karsten Albe". Darmstadt : Universitäts- und Landesbibliothek Darmstadt, 2017. http://d-nb.info/1147968446/34.

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Sopu, Daniel. "Molecular Dynamics Simulations of Metallic Nanoglasses". Phd thesis, 2011. https://tuprints.ulb.tu-darmstadt.de/2845/1/PhD_thesis_part1.pdf.

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The prospect of realizing new bulk metallic glasses with improved properties has driven a large amount of research since the early work of Duwez [1]. In analogy to nanocrystalline solids, a new type of metallic glasses may by synthesized by consolidating glassy powder. This so-called nanoglass consists of glassy grains separated by interfaces [2]. So far, the existence of nanoglasses was only indirectly proven by experiments [2, 3, 4, 5]. This dissertation presents molecular dynamics simulations of nanoglasses and provides detailed insights into the structure and properties of this class of material. In the first part, an investigation of the structure and stability of a planar glass-glass interface is conducted by analyzing the local topology, alloy composition and density in comparison to the bulk structure. An analogy between an internal interface and a shear band is established. The stability of the glass-glass interfaces under thermal treatment and hydrostatic pressure is also analyzed. The second part is dedicated to the deformation behavior of metallic nanoglasses. Here, mechanical properties of a Cu64Zr36-nanoglass are characterized under tensile load and compared to the deformation behavior of a homogeneous bulk glass. For this study, dense and porous nanoglasses are used and the influence of grain size and porosity on the plastic behavior of nanoglasses is investigated. In addition, it is studied how thermal treatment and prior-deformation change the plastic response of the metallic nanoglass. In the third part, the phonon density of states (PDOS) of nanoglasses is studied in comparison to other nanostructures (nanoparticles, nanocrystals and embedded nanoparticles). In this case, germanium is used as representative reference material. By comparing with the PDOS of single crystalline and amorphous structures, the physical origins of additional or vanishing vibrational modes or frequency shift are identified. A general view on the interplay of nanostructural features and lattice vibrations is provided. In the last part, an investigation of the crystalline to amorphous transition of thin iron films embedded in AlFe glass is conducted. For the first time theoretical evidence is provided for the existence of a single-component metallic glass. The calculated PDOS reinforce the aforementioned statements. In addition, the investigation of finite size effects in PDOS is extended for the case of Fe thin films.

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Nandam, Sree Harsha. "Structure and mechanical properties of metallic nanoglasses". Phd thesis, 2019. https://tuprints.ulb.tu-darmstadt.de/8702/1/Doctoral%20Thesis_Sree%20Harsha%20Nandam.pdf.

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Metallic nanoglasses are a new class of amorphous materials with interesting magnetic and mechanical properties. They are characterized by interfacial regions with enhanced free volume compared to the core of the nanoparticles. Till now, nanoglasses are primarily synthesized by using thermal evaporation in inert gas condensation (IGC). However, due to the different vapour pressure of constituent elements and reproducibility issues in thermal evaporation, it is difficult/impossible to synthesize different glassy compositions. In this work, by using magnetron sputtering in IGC, Cu50Zr50, Cu60Zr40 and Pd84Si16 nanoglasses are produced with completely amorphous nature and good reproducibility. By varying several parameters, the yield of the sputtering process in IGC is optimized to make sufficient amount of material to obtain a nanoglass pellet. The influence of several processing parameters like inert gas pressure, sputtering power, the type of material etc., on the yield of the process are studied in the current work. The primary aim of the current work is to study the properties of the nanoglasses and compare them with conventional metallic glasses produced by melt-spinning and thus comment on the relation between the structure and properties of nanoglasses. Structural characterization of the metallic nanoglasses showed that the samples are amorphous in nature. Elemental segregation in the samples was studied by atom probe tomography and significant segregation was found in Cu-Zr alloys while very little chemical inhomogeneity was observed in Pd-Si nanoglasses. Crystallization temperature was higher in Cu-Zr nanoglasses than that in melt-spun ribbons while Pd-Si nanoglasses showed lower glass transition and crystallization temperature compared to melt-spun ribbons. Mechanical properties of the nanoglasses and melt-spun ribbons were tested by indentation and micropillar compression tests. Hardness and elastic modulus were found to be higher in Cu-Zr and lower in Pd-Si nanoglasses compared to their corresponding melt-spun ribbons. Deformation mode was also found to be different in Cu-Zr and Pd-Si nanoglasses. While Cu-Zr nanoglasses deformed homogenously without the formation of shear bands during indentation, Pd-Si alloys showed shear bands around the indents. Similar results were also observed in micropillar tests of Pd-Si and Cu-Zr nanoglasses. Cu-Zr nanoglasses showed less catastrophic deformation compared to the melt-spun ribbons while shear banding was observed in both Pd-Si nanoglasses and melt-spun ribbons. With the help of molecular dynamic simulations, the effect of topological structure at the interfacial regions was studied in Pd-Si metallic nanoglasses. Simulation results conveyed that the fraction of major Si polyhedra i.e. Si[0,3,6,0] played an important role in determining the shear band formation and consequently the ductility of glassy Pd-Si alloys. With the increase in the fraction of Si[0,3,6,0] in the interfacial regions of Pd-Si nanoglasses, the mode of deformation changed from homogenous to heterogeneous one. The importance of chemical inhomogeneity on the thermal and mechanical properties of nanoglasses was described in detail based on a segregation model. Finally, Pd80Si20 thin film nanoglasses synthesized by conventional magnetron sputtering were also studied in the current work. No elemental segregation was observed in thin films. Annealing the nanoglassy thin films did not lead to any change in the globular nanostructure even after crystallization. The mode of deformation was practically the same as that in the rapidly quenched ribbon. The reasons for similar behaviour of the thin films and melt-spun ribbons are discussed.

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Wang, Chaomin. "Atomic structure and structural stability of Fe90Sc10 nanoglasses". Phd thesis, 2017. https://tuprints.ulb.tu-darmstadt.de/6981/1/CMW-Atomic%20Structure%20and%20Structural%20Stability%20of%20Fe90Sc10%20Nanoglasses.pdf.

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Nanoglasses are non-crystalline solids whose internal structure is characterized by fluctuations of the free volume. Due to the typical dimensions of the structural features in the nanometer-range and the disordered atomic structure of the interfacial regions, the atomic structure and the structural stability of nanoglasses is not yet completely understood. Nanoglasses are typically produced by consolidation of glassy nanoparticles. Consequently, the basis for the understanding of the atomic structure of nanoglasses lies in the atomic structure of the primary glassy nanoparticles. Using electron energy loss spectroscopy, the elemental distribution in the Fe90Sc10 primary glassy nanoparticles and in the corresponding nanoglasses produced by consolidation of these glassy nanoparticles have been studied. Due to surface segregation, Fe has been found to be enriched at the surface of the primary Fe90Sc10 glassy nanoparticles. This behavior was found to be consistent with theoretical results based on a monolayer model for surface segregation behavior of the binary liquid alloys. In addition, the heterogeneous structure of Fe90Sc10 nanoglasses with Fe enriched interfaces was also directly observed, and may be attributed to the segregation of the primary glassy nanoparticles on the surface. Furthermore, the electron density of the isolated and loosely compacted primary glassy nanoparticles was investigated using small- and wide- angle X-ray scattering. The results indicate that the surface shells of glassy nanoparticles have an electron density that is lower than the electron density in the cores of the glassy nanoparticles. The lower electron density seems to result mainly from a lower atomic packing density of the surface shells rather than from compositional variations due to the surface segregation. During the consolidation of the glassy nanoparticles, the inhomogeneous elemental distribution and the short-range order in the shells of Fe90Sc10 glassy nanoparticles can be transferred into the interfaces of the resulting bulk Fe90Sc10 nanoglasses. The free volume within the shells of the Fe90Sc10 glassy nanoparticles may delocalize into the interfaces between the Fe90Sc10 glassy nanoparticles resulting in interfacial regions of lower atomic packing density in the Fe90Sc10 nanoglasses. The structural stability of Fe90Sc10 nanoglasses has been studied by means of low temperature annealing in situ in a transmission electron microscope, and ex situ in an ultra-high-vacuum tube-furnace. The analysis of both experiments showed similar results. The structure of the Fe90Sc10 nanoglasses was stable for up to 2 hours when annealed at 150 °C. Annealing of nanoglasses at higher temperatures resulted in the formation of a metastable nanocrystalline bcc-Fe(Sc) with Sc-enriched interfaces. The crystallization process of Fe90Sc10 nanoglasses was clarified and a plausible mechanism for the structural stability was proposed.

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Singh, Indrasen. "Continuum Analysis of Cavitation Induced Failure and Tensile Deformation Response of Metallic Glasses & Nanoglasses". Thesis, 2016. https://etd.iisc.ac.in/handle/2005/4890.

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Metallic glasses (MGs), which are metals solidified in an amorphous state, have shown attractive mechanical properties such as high strength (up to 5 GPa), yield strain (around 2%) and good corrosion resistance. They exhibit heterogeneous plastic flow by formation of shear bands (SBs) at temperatures well below the glass transition temperature. However, they can be very brittle with KIc ∼ 1 - 15 MPa √ m or very tough (KIc ∼ 80 MPa √ m). Experiments and MD simulations suggest that failure in the brittle MGs occurs by cavitation with little shear banding and can be traced to nanoscale fluctuations in atomic density. Also, notwithstanding their high KIc, MG samples lack tensile ductility and fail catastrophically by crack propagation in a dominant SB. However, nano-sized MG samples and a novel architecture called as nanoglass (NG) composed of nano-grains of MGs separated by fine free volume rich interfaces do exhibit tensile ductility. Relatively few continuum simulations have been undertaken to understand the deformation and fracture behavior of MGs and NGs from a mechanics standpoint. Therefore, continuum finite element analysis of cavitation and cavitation induced fracture in brittle MGs are performed in this work. In addition, tensile deformation behavior of nano-scale notched MG and NG samples are analyzed. Brittle MGs are modeled as heterogeneous elastic-plastic solid containing doubly periodic distribution of weak zones with lower yield strength. The presence of the weak zones mimics the density/strength fluctuation in brittle MGs as observed in experiments and atomistic simulations. Finite element simulations are performed by subjecting a square unit cell containing a circular weak zone to different (biaxiality) stress ratios under 2D plane strain conditions. A tiny void is introduced in the weak zone to trigger cavitation. The results show that the critical hydrostatic stress at cavitation is reduced due to the presence of the weak zones and is governed by yield properties of the weak zone and the prevailing stress state. Moreover, unlike in a homogeneous plastic solid, the cavitation stress of the heterogeneous aggregate does not reduce appreciably as the stress ratio decreases from unity when the yield strength of the weak zone is low. The volume fraction of the weak zones and stress ratio influence the nature of cavitation bifurcation. This includes the possibility of snap cavitation wherein a void of finite size suddenly forms in the intact material which does not happen in a homogeneous plastic solid. Further, continuum simulations of crack initiation under mode-I plane strain, small scale yielding conditions in a heterogeneous elastic-plastic solid having a distribution of weak zones are performed. The results show that a three-step process is involved in the catastrophic fracture observed in brittle MGs. First, cavities nucleate in weak zones ahead of the crack tip and start growing rapidly. Secondly, curved shear bands form linking the current crack tip with the nearby cavity. Thirdly, as plastic strain and free volume accumulate within these shear bands, failure takes place facilitating further extension of the crack. The proposed fracture mechanism explains the formation of nano-corrugations in brittle MGs. The results also predict a correlation between notched fracture toughness and Poisson’s ratio and brittle-ductile transition which is qualitatively similar to that observed in experiments. the deformation behavior of nano-sized notched MG samples subjected to plane strain tensile loading is modeled through finite element simulations using a non-local plasticity theory for MGs. The results show that a plastic zone first develops around the notch root and grows to a critical size before a dominant shear band emanates from this zone that would lead to failure. The SB width and the saturation notch root plastic zone size scales with an intrinsic material length lc associated with interaction stress between flow defecrs. Also, the ratio of the ligament length to saturation plastic zone size governs the transition from shear banding to necking. The deformation behaviour of NGs subjected to plane strain tensile loading is investigated through finite element simulations using the above non-local plasticity theory. It is found that the ratio of the material length lc to nano-grain size governs the deformation behavior of NGs. Also, SB width scales in same manner with lc both in MG and NG specimens and moderate changes in specimen size have little effect on mechanical response of NGs.

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Części książek na temat "Nanoglasses"

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Şopu, D., i O. Adjaoud. "Metallic Nanoglasses Investigated by Molecular Dynamics Simulations". W 21st Century Nanoscience – A Handbook, 21–1. Boca Raton, Florida : CRC Press, [2020]: CRC Press, 2019. http://dx.doi.org/10.1201/9780367333003-21.

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"Glass: Nanoglass". W CRC Concise Encyclopedia of Nanotechnology, 257–67. CRC Press, 2016. http://dx.doi.org/10.1201/b19457-27.

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Fecht, Hans-J., i Pierre Denis. "Nanoglass Thin Films". W Topics in Nanoscience, 173–232. World Scientific, 2022. http://dx.doi.org/10.1142/9789811242700_0005.

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Karmakar, B., N. Sasmal i M. Garai. "Nanoglass and Nanostructured Chalcogenide Glasses". W Glass Nanocomposites, 359–75. Elsevier, 2016. http://dx.doi.org/10.1016/b978-0-323-39309-6.00015-8.

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Streszczenia konferencji na temat "Nanoglasses"

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Lukowiak, Anna, Marzena Fandzloch, Katarzyna Halubek-Gluchowska, Yuriy Gerasymchuk, Leili Tahershamsi, Kamila Startek i Beata Borak. "Luminescent bioactive nanoglasses and graphene-based composites". W Optical Components and Materials XVIII, redaktorzy Michel J. Digonnet i Shibin Jiang. SPIE, 2021. http://dx.doi.org/10.1117/12.2578963.

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Lukowiak, Anna, Katarzyna Halubek-Gluchowska, Marzena Fandzloch, Weronika Bodylska, Damian Szymanski, Beata Borak i Yuriy Gerasymchuk. "Luminescent bioactive nanoglasses: different approaches to gain photoactivity". W Fiber Lasers and Glass Photonics: Materials through Applications III, redaktorzy Stefano Taccheo, Maurizio Ferrari i Angela B. Seddon. SPIE, 2022. http://dx.doi.org/10.1117/12.2620676.

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Bodylska, Weronika, Beata Borak, Marzena Fandzloch, Joanna Trzcińska-Wencel, Patrycja Golińska, Katarzyna Roszek i Anna Lukowiak. "SiO2‒CaO‒ZnO nanoglass as multifunctional material". W Fiber Lasers and Glass Photonics: Materials through Applications III, redaktorzy Stefano Taccheo, Maurizio Ferrari i Angela B. Seddon. SPIE, 2022. http://dx.doi.org/10.1117/12.2624464.

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Saha, Dhriti Ranjan, Partha Hajra, Mykanth Reddy Mada, Philip Boughton, Sri Bandyopadhyay i Dipankar Chakravorty. "Nanoindentation studies on composites of CuO nanoparticles-lithia silica nanoglass". W SOLID STATE PHYSICS: Proceedings of the 56th DAE Solid State Physics Symposium 2011. AIP, 2012. http://dx.doi.org/10.1063/1.4709992.

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Wang, Di. "The nature of nanoglass materials explored by STEM-RDF mapping technique". W European Microscopy Congress 2020. Royal Microscopical Society, 2021. http://dx.doi.org/10.22443/rms.emc2020.938.

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Zhang, F., O. Leonte, Z. J. Chen, L. Jin, J. A. Levert, A. Camarena, B. Daniels i in. "Nanoglass/sup TM/ E copper damascene processing for etch, clean, and CMP". W Proceedings of the IEEE 2001 International Interconnect Technology Conference. IEEE, 2001. http://dx.doi.org/10.1109/iitc.2001.930016.

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Saha, Dhriti Ranjan, i Dipankar Chakravorty. "Study of dielectric relaxation process in nanocomposite of Li2O−SiO2 nanoglass-CuO nanoparticles". W SOLID STATE PHYSICS: Proceedings of the 58th DAE Solid State Physics Symposium 2013. AIP Publishing LLC, 2014. http://dx.doi.org/10.1063/1.4872614.

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Cruz, Eugenia, Rolindes B. Balda, Joaquín Fernández, Alicia Duran Carrera i Yolanda Castro. "Transparent oxyfluoride nanoglass ceramic films obtained by sol-gel: the key of processing". W Fiber Lasers and Glass Photonics: Materials through Applications III, redaktorzy Stefano Taccheo, Maurizio Ferrari i Angela B. Seddon. SPIE, 2022. http://dx.doi.org/10.1117/12.2621656.

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Maity, Anupam, Subha Samanta, Debasish Biswas i Dipankar Chakravorty. "Room temperature magnetodielectric effect in composites of cobalt containing silica based nanoglass and mesoporous alumina". W DAE SOLID STATE PHYSICS SYMPOSIUM 2019. AIP Publishing, 2020. http://dx.doi.org/10.1063/5.0016735.

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