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Artykuły w czasopismach na temat „Multiferroic Transition Metal Oxides”

Autor: Grafiati

Data publikacji: 7 września 2023

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1

Zhao, Li, Maria Teresa Fernández-Díaz, Liu Hao Tjeng i Alexander C. Komarek. "Oxyhalides: A new class of high-TC multiferroic materials". Science Advances 2, nr 5 (maj 2016): e1600353. http://dx.doi.org/10.1126/sciadv.1600353.

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Magnetoelectric multiferroics have attracted enormous attention in the past years because of their high potential for applications in electronic devices, which arises from the intrinsic coupling between magnetic and ferroelectric ordering parameters. The initial finding in TbMnO3 has triggered the search for other multiferroics with higher ordering temperatures and strong magnetoelectric coupling for applications. To date, spin-driven multiferroicity is found mainly in oxides, as well as in a few halogenides. We report multiferroic properties for synthetic melanothallite Cu2OCl2, which is the first discovery of multiferroicity in a transition metal oxyhalide. Measurements of pyrocurrent and the dielectric constant in Cu2OCl2 reveal ferroelectricity below the Néel temperature of ~70 K. Thus, melanothallite belongs to a new class of multiferroic materials with an exceptionally high critical temperature. Powder neutron diffraction measurements reveal an incommensurate magnetic structure below TN, and all magnetic reflections can be indexed with a propagation vector [0.827(7), 0, 0], thus discarding the claimed pyrochlore-like “all-in–all-out” spin structure for Cu2OCl2, and indicating that this transition metal oxyhalide is, indeed, a spin-induced multiferroic material.

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2

Rodgers, Jennifer A., Anthony J. Williams i J. Paul Attfield. "High-pressure / High-temperature Synthesis of Transition Metal Oxide Perovskites". Zeitschrift für Naturforschung B 61, nr 12 (1.12.2006): 1515–26. http://dx.doi.org/10.1515/znb-2006-1208.

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Perovskite and related Ruddlesden-Popper type transition metal oxides synthesised at high pressures and temperatures during the last decade are reviewed. More than 60 such new materials have been reported since 1995. Important developments have included perovskites with complex cation orderings on A and B sites, multiferroic bismuth-based perovskites, and new manganites showing colossal magnetoresistance (CMR) and charge ordering properties.

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3

Hu, Shunbo, Lei Chen, Yabei Wu, Liming Yu, Xinluo Zhao, Shixun Cao, Jincang Zhang i Wei Ren. "Selected multiferroic perovskite oxides containing rare earth and transition metal elements". Chinese Science Bulletin 59, nr 36 (11.10.2014): 5170–79. http://dx.doi.org/10.1007/s11434-014-0643-5.

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4

Long, Youwen. "High-pressure synthesis and physical properties of A-site ordered perovskites". Acta Crystallographica Section A Foundations and Advances 70, a1 (5.08.2014): C755. http://dx.doi.org/10.1107/s2053273314092444.

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ABO3-type perovskite oxides exhibit a wide variety of interesting physical properties such as superconductivity, colossal magnetoresistance, multiferroic behavior etc. For a simple ABO3 perovskite, if three quarters of the A site is replaced by a transition metal A', then the so-called A-site ordered double perovskite with the chemical formula of AA'3B4O12 can form. Since both A' and B sites accommodate transition metal ions, in addition to conventional B-B interaction, the new A'-A' and/or A'-B interaction is possible to show up, giving rise to the presence of many novel physical properties. Here we will show our recent research work on the high-pressure synthesis of several A-site ordered perovskites as well as a series of interesting physical properties like temperature- and pressure-induced intermetallic charge transfer, negative thermal expansion, magnetoelectric coupling multiferroic and so on. [1-3]

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5

Liu, Lei, Hua Y. Geng, Xiaolong Pan, Hong X. Song, Sergey Ivanov, Roland Mathieu, Matthias Weil, Yanchun Li, Xiaodong Li i Peter Lazor. "Irreversible phase transitions of the multiferroic oxide Mn₃TeO₆ at high pressures". Applied Physics Letters 121, nr 4 (25.07.2022): 044102. http://dx.doi.org/10.1063/5.0100302.

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Due to their large bandgaps, multiferroic oxides, the promising candidates for overcoming the disadvantages of metal-halide perovskites as light absorbers, have so far very limited use in solar cell applications. Previous investigations demonstrate that high pressure represents an efficient tool for tuning the bandgap of multiferroic Mn3TeO6 (MTO). However, the underlying mechanism of the giant bandgap reduction discovered in MTO remains unclear, which critically prevents the design of next-generation light absorbers. In this study, we performed in situ x-ray diffraction analyses on the structure evolution of MTO upon compression and decompression, discovering a sequence of irreversible phase transitions R[Formula: see text]→ C2/c→ P21/n. The experimental results, supported by electronic structure calculations, show the shortening of Mn–O–Mn bonding, and, to a lower extent, the decrease in connectivity of octahedra across the phase transition, explain the giant bandgap reduction of MTO. These findings will facilitate the design and synthesis of next-generation light absorbers in solar cells.

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6

Lorenz, Michael. "Pulsed laser deposition of functional oxides - towards a transparent electronics". Acta Crystallographica Section A Foundations and Advances 70, a1 (5.08.2014): C1412. http://dx.doi.org/10.1107/s2053273314085878.

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Metal oxides, in particular with transition metals, show strong electronic correlations which determine a huge variety of electronic properties, together with other functionalities. For example, ZnO and Ga2O3 as wide-bandgap semiconductors have a high application potential as transparent functional layers in future oxide electronics [1-2]. Other oxides of current interest are ferrimagnetic spinels of the type MFe2O4 (M=Zn,Co,Ni), see K. Brachwitz et al. Appl. Phys. Lett. 102, 172104 (2013), or highly correlated iridate films, see M. Jenderka et al. Phys. Rev. B 88, 045111 (2013). Furthermore, combinations of ferroelectric and magnetic oxides in multiferroic composites and multilayers show promising magnetoelectric coupling. For the exploratory growth of the above mentioned novel oxides into nm-thin films, pulsed laser deposition (PLD) appears as the method of choice because of its extremely high flexibility in terms of material and growth conditions, high growth rate and excellent structural properties [3]. This talk highlights recent developments of new functional oxides using unique large-area PLD processes running for more than two decades in the lab of the author [3].

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7

Watson, Carla, Tara Peña, Marah Abdin, Tasneem Khan i Stephen M. Wu. "Dynamic adhesion of 2D materials to mixed-phase BiFeO₃ structural phase transitions". Journal of Applied Physics 132, nr 4 (28.07.2022): 045301. http://dx.doi.org/10.1063/5.0096686.

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Two-dimensional materials, such as transition metal dichalcogenides, have generated much interest due to their strain-sensitive electronic, optical, magnetic, superconducting, or topological properties. Harnessing control over their strain state may enable new technologies that operate by controlling these materials’ properties in devices such as straintronic transistors. Piezoelectric oxides have been proposed as one method to control such strain states on the device scale. However, there are few studies of how conformal 2D materials remain on oxide materials with respect to dynamic applications of the strain. Non-conformality may lead to non-optimal strain transfer. In this work, we explore this aspect of oxide-2D adhesion in the nanoscale switching of the substrate structural phase in thin 1T′-MoTe2 attached to a mixed-phase thin-film BiFeO3 (BFO), a multiferroic oxide with an electric-field induced structural phase transition that can generate mechanical strains of up to 2%. We observe that flake thickness impacts the conformality of 1T′-MoTe2 to structural changes in BFO, but below four layers, 1T′-MoTe2 fully conforms to the nanoscale BFO structural changes. The conformality of few-layer 1T′-MoTe2 suggests that BFO is an excellent candidate for deterministic, nanoscale strain control for 2D materials.

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8

Jiang, Xingyu, Yiren Liu, Yipeng Zang, Yuwei Liu, Tianyi Gao, Ningchong Zheng, Zhengbin Gu, Yurong Yang, Di Wu i Yuefeng Nie. "Uniaxial strain induced anisotropic bandgap engineering in freestanding BiFeO₃ films". APL Materials 10, nr 9 (1.09.2022): 091110. http://dx.doi.org/10.1063/5.0095955.

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Strain engineering has been demonstrated to be an effective knob to tune the bandgap in perovskite oxides, which is highly desired for applications in optics, optoelectronics, and ferroelectric photovoltaics. Multiferroic BiFeO3 exhibits great potential in photovoltaic applications and its bandgap engineering is of great interest. However, the mechanism of strain induced bandgap engineering in BiFeO3 remains elusive to date. Here, we perform in situ ellipsometry measurements to investigate the bandgap evolution as a function of uniaxial strain on freestanding BiFeO3 films. Exotic anisotropic bandgap engineering has been observed, where the bandgap increases (decreases) by applying uniaxial tensile strain along the pseudocubic [100]p ([110]p) direction. First-principles calculations indicate that different O6 octahedral rotations under strain are responsible for this phenomenon. Our work demonstrates that the extreme freedom in tuning the strain and symmetry of freestanding films opens a new fertile playground for novel strain-driven phases in transition metal oxides.

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9

Raveau, Bernard, Vincent Caignaert, Vincent Hardy i Mohammad Motin Seikh. "Transition metal oxides with triangular metallic sublattices: From multiferroics to low-dimensional magnets". Comptes Rendus Chimie 21, nr 10 (październik 2018): 952–57. http://dx.doi.org/10.1016/j.crci.2018.07.012.

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10

El Housni, I., N. El Mekkaoui, R. Khalladi, S. Idrissi, S. Mtougui, H. Labrim, S. Ziti i L. Bahmad. "The magnetic properties of the multiferroic transition metal oxide perovskite-type Pb(Fe1/2Nb1/2)O3: Monte Carlo simulations". Ferroelectrics 568, nr 1 (3.11.2020): 191–213. http://dx.doi.org/10.1080/00150193.2020.1834776.

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11

Mun, Eundeok, Jason Wilcox, Jamie L. Manson, Brian Scott, Paul Tobash i Vivien S. Zapf. "The Origin and Coupling Mechanism of the Magnetoelectric Effect inTMCl2-4SC(NH2)2(TM= Ni and Co)". Advances in Condensed Matter Physics 2014 (2014): 1–4. http://dx.doi.org/10.1155/2014/512621.

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Most research on multiferroics and magnetoelectric effects to date has focused on inorganic oxides. Molecule-based materials are a relatively new field in which to search for magnetoelectric multiferroics and to explore new coupling mechanisms between electric and magnetic order. We present magnetoelectric behavior in NiCl2-4SC(NH2)2(DTN) and CoCl2-4SC(NH2)2(DTC). These compounds form tetragonal structures where the transition metal ion (Ni or Co) is surrounded by four electrically polar thiourea molecules [SC(NH2)2]. By tracking the magnetic and electric properties of these compounds as a function of magnetic field, we gain insights into the coupling mechanism by observing that, in DTN, the electric polarization tracks the magnetic ordering, whereas in DTC it does not. For DTN, all electrically polar thiourea molecules tilt in the same direction along thec-axis, breaking spatial-inversion symmetry, whereas, for DTC, two thiourea molecules tilt up and two tilt down with respect toc-axis, perfectly canceling the net electrical polarization. Thus, the magnetoelectric coupling mechanism in DTN is likely a magnetostrictive adjustment of the thiourea molecule orientation in response to magnetic order.

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12

Rao, C. N. R. "Transition Metal Oxides". Annual Review of Physical Chemistry 40, nr 1 (październik 1989): 291–326. http://dx.doi.org/10.1146/annurev.pc.40.100189.001451.

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13

Greenblatt, Martha. "Transition metal oxides". Materials Research Bulletin 31, nr 4 (kwiecień 1996): 426–27. http://dx.doi.org/10.1016/0025-5408(96)80020-1.

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14

Lany, Stephan. "Semiconducting transition metal oxides". Journal of Physics: Condensed Matter 27, nr 28 (30.06.2015): 283203. http://dx.doi.org/10.1088/0953-8984/27/28/283203.

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15

GUO, Xianji. "Pillared layered transition metal oxides". Chinese Science Bulletin 48, nr 2 (2003): 101. http://dx.doi.org/10.1360/03tb9021.

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16

Walia, Sumeet, Sivacarendran Balendhran, Hussein Nili, Serge Zhuiykov, Gary Rosengarten, Qing Hua Wang, Madhu Bhaskaran, Sharath Sriram, Michael S. Strano i Kourosh Kalantar-zadeh. "Transition metal oxides – Thermoelectric properties". Progress in Materials Science 58, nr 8 (październik 2013): 1443–89. http://dx.doi.org/10.1016/j.pmatsci.2013.06.003.

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17

Szotek, Z., W. M. Temmerman, A. Svane, L. Petit, G. M. Stocks i H. Winter. "Half-metallic transition metal oxides". Journal of Magnetism and Magnetic Materials 272-276 (maj 2004): 1816–17. http://dx.doi.org/10.1016/j.jmmm.2003.12.818.

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18

Moreo, Adriana. "Complexity in transition metal oxides". Journal of Physics and Chemistry of Solids 67, nr 1-3 (styczeń 2006): 32–36. http://dx.doi.org/10.1016/j.jpcs.2005.10.138.

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19

Zhang, Huigang, Hailong Ning, John Busbee, Zihan Shen, Chadd Kiggins, Yuyan Hua, Janna Eaves i in. "Electroplating lithium transition metal oxides". Science Advances 3, nr 5 (maj 2017): e1602427. http://dx.doi.org/10.1126/sciadv.1602427.

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20

He, Tao, i Jian-Nian Yao. "Photochromism in transition-metal oxides". Research on Chemical Intermediates 30, nr 4 (1.06.2004): 459–88. http://dx.doi.org/10.1163/1568567041280890.

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21

Cho, Jae-Hyeon, i Wook Jo. "Progress in the Development of Single-Phase Magnetoelectric Multiferroic Oxides". Ceramist 24, nr 3 (30.09.2021): 228–47. http://dx.doi.org/10.31613/ceramist.2021.24.3.03.

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Magnetoelectric (ME) multiferroics manifesting the coexistence and the coupling of ferromagnetic and ferroelectric order are appealing widespread interest owing to their fascinating physical behaviors and possible novel applications. In this review, we highlight the progress in single-phase ME multiferroic oxides research in terms of the classification depending on the physical origins of ferroic properties and the corresponding examples for each case, i.e., material by material, along with their ME multiferroic properties including saturation magnetization, spontaneous polarization, (anti)ferromagnetic/ferroelectric transition temperature, and ME coefficient. The magnetoelectrically-active applications of high expectancy are presented by citing the representative examples such as magnetoelectric random-access-memory and multiferroic photovoltaics. Furthermore, we discuss how the development of ME multiferroic oxides should proceed by considering the current research status in terms of developed materials and designed applications. We believe that this short review will provide a basic introduction for the researchers new to this field.

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22

Wang, Shanmin, Jinlong Zhu, Yi Zhang, Xiaohui Yu, Jianzhong Zhang, Wendan Wang, Ligang Bai i in. "Unusual Mott transition in multiferroic PbCrO3". Proceedings of the National Academy of Sciences 112, nr 50 (24.11.2015): 15320–25. http://dx.doi.org/10.1073/pnas.1510415112.

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The Mott insulator in correlated electron systems arises from classical Coulomb repulsion between carriers to provide a powerful force for electron localization. Turning such an insulator into a metal, the so-called Mott transition, is commonly achieved by “bandwidth” control or “band filling.” However, both mechanisms deviate from the original concept of Mott, which attributes such a transition to the screening of Coulomb potential and associated lattice contraction. Here, we report a pressure-induced isostructural Mott transition in cubic perovskite PbCrO3. At the transition pressure of ∼3 GPa, PbCrO3 exhibits significant collapse in both lattice volume and Coulomb potential. Concurrent with the collapse, it transforms from a hybrid multiferroic insulator to a metal. For the first time to our knowledge, these findings validate the scenario conceived by Mott. Close to the Mott criticality at ∼300 K, fluctuations of the lattice and charge give rise to elastic anomalies and Laudau critical behaviors resembling the classic liquid–gas transition. The anomalously large lattice volume and Coulomb potential in the low-pressure insulating phase are largely associated with the ferroelectric distortion, which is substantially suppressed at high pressures, leading to the first-order phase transition without symmetry breaking.

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23

Tokura, Y. "Metal-insulator phenomena in 3d transition metal oxides". Physica C: Superconductivity 235-240 (grudzień 1994): 138–41. http://dx.doi.org/10.1016/0921-4534(94)91332-3.

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24

Zhou, Wu Zong. "Mesoporous Crystals of Transition Metal Oxides". Solid State Phenomena 140 (październik 2008): 37–46. http://dx.doi.org/10.4028/www.scientific.net/ssp.140.37.

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Using mesoporous silicas as hard templates and facilitating crystal growth of transition metal oxides inside the pores, some mesoporous crystals can be produced after removing the templates. This paper gives a brief review of the research of mesoporous crystals of transition metal oxides in the last five years, including the technical development and potential applications of the new form of oxides.

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25

Rodenbücher, Christian, i Kristof Szot. "Electronic Phenomena of Transition Metal Oxides". Crystals 11, nr 3 (5.03.2021): 256. http://dx.doi.org/10.3390/cryst11030256.

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Transition metal oxides with ABO3 or BO2 structures have become one of the major research fields in solid state science, as they exhibit an impressive variety of unusual and exotic phenomena with potential for their exploitation in real-world applications [...]

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26

Wang, Yan, Jin Guo, Tingfeng Wang, Junfeng Shao, Dong Wang i Ying-Wei Yang. "Mesoporous Transition Metal Oxides for Supercapacitors". Nanomaterials 5, nr 4 (14.10.2015): 1667–89. http://dx.doi.org/10.3390/nano5041667.

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27

Rao, C. N. R., i A. K. Cheetham. "Giant Magnetoresistance in Transition Metal Oxides". Science 272, nr 5260 (19.04.1996): 369–70. http://dx.doi.org/10.1126/science.272.5260.369.

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28

Littrell, Donald M., Daniel H. Bowers i Bruce J. Tatarchuk. "Hydrazine reduction of transition-metal oxides". Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases 83, nr 11 (1987): 3271. http://dx.doi.org/10.1039/f19878303271.

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29

Nakamura, Keisuke, Yuya Oaki i Hiroaki Imai. "Monolayered Nanodots of Transition Metal Oxides". Journal of the American Chemical Society 135, nr 11 (7.03.2013): 4501–8. http://dx.doi.org/10.1021/ja400443a.

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30

Sawa, Akihito. "Resistive switching in transition metal oxides". Materials Today 11, nr 6 (czerwiec 2008): 28–36. http://dx.doi.org/10.1016/s1369-7021(08)70119-6.

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31

Zhao, Yongbiao, Jun Zhang, Shuwei Liu, Yuan Gao, Xuyong Yang, Kheng Swee Leck, Agus Putu Abiyasa i in. "Transition metal oxides on organic semiconductors". Organic Electronics 15, nr 4 (kwiecień 2014): 871–77. http://dx.doi.org/10.1016/j.orgel.2014.01.011.

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32

Attfield, J. Paul. "Charge ordering in transition metal oxides". Solid State Sciences 8, nr 8 (sierpień 2006): 861–67. http://dx.doi.org/10.1016/j.solidstatesciences.2005.02.011.

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33

Matsushita, Eiko, i Akifumi Tanase. "Conduction mechanism in transition-metal oxides". Physica B: Condensed Matter 237-238 (lipiec 1997): 21–23. http://dx.doi.org/10.1016/s0921-4526(97)00029-x.

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34

Fujimori, Atsushi, i Takashi Mizokawa. "Electronic structure of transition-metal oxides". Current Opinion in Solid State and Materials Science 2, nr 1 (luty 1997): 18–22. http://dx.doi.org/10.1016/s1359-0286(97)80100-3.

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35

Encheva, G., B. Samuneva, P. Djambaski, E. Kashchieva, D. Paneva i I. Mitov. "Silica gels containing transition metal oxides". Journal of Non-Crystalline Solids 345-346 (październik 2004): 615–19. http://dx.doi.org/10.1016/j.jnoncrysol.2004.08.108.

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36

Büttgen, N., H. A. Krug von Nidda, W. Kraetschmer, A. Günther, S. Widmann, S. Riegg, A. Krimmel i A. Loidl. "Quantum Criticality in Transition-Metal Oxides". Journal of Low Temperature Physics 161, nr 1-2 (11.08.2010): 148–66. http://dx.doi.org/10.1007/s10909-010-0200-9.

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37

Seike, Tetsuya, i Junichi Nagai. "Electrochromism of 3d transition metal oxides". Solar Energy Materials 22, nr 2-3 (lipiec 1991): 107–17. http://dx.doi.org/10.1016/0165-1633(91)90010-i.

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38

Goodenough, John B. "Perspective on Engineering Transition-Metal Oxides". Chemistry of Materials 26, nr 1 (9.09.2013): 820–29. http://dx.doi.org/10.1021/cm402063u.

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Yamamoto, Takafumi, i Hiroshi Kageyama. "Hydride Reductions of Transition Metal Oxides". Chemistry Letters 42, nr 9 (5.09.2013): 946–53. http://dx.doi.org/10.1246/cl.130581.

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40

Mayer, B., St Uhlenbrock i M. Neumann. "XPS satellites in transition metal oxides". Journal of Electron Spectroscopy and Related Phenomena 81, nr 1 (czerwiec 1996): 63–67. http://dx.doi.org/10.1016/0368-2048(96)03030-7.

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41

Muraoka, Yuji, i Zenji Hiroi. "Photocarrier Injection to Transition Metal Oxides". Journal of the Physical Society of Japan 72, nr 4 (15.04.2003): 781–84. http://dx.doi.org/10.1143/jpsj.72.781.

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42

Tokura, Y. "Orbital Physics in Transition-Metal Oxides". Science 288, nr 5465 (21.04.2000): 462–68. http://dx.doi.org/10.1126/science.288.5465.462.

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43

Raveau, B. "Transition metal oxides: Promising functional materials". Journal of the European Ceramic Society 25, nr 12 (styczeń 2005): 1965–69. http://dx.doi.org/10.1016/j.jeurceramsoc.2005.03.220.

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44

Doumerc, J. P., M. Blangero, M. Pollet, D. Carlier, J. Darriet, R. Berthelot, C. Delmas i R. Decourt. "Transition-Metal Oxides for Thermoelectric Generation". Journal of Electronic Materials 38, nr 7 (10.01.2009): 1078–82. http://dx.doi.org/10.1007/s11664-008-0625-y.

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45

Krivanek, Ondrej L., i James H. Paterson. "Elnes of 3d transition-metal oxides". Ultramicroscopy 32, nr 4 (maj 1990): 313–18. http://dx.doi.org/10.1016/0304-3991(90)90077-y.

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Paterson, James H., i Ondrej L. Krivanek. "Elnes of 3d transition-metal oxides". Ultramicroscopy 32, nr 4 (maj 1990): 319–25. http://dx.doi.org/10.1016/0304-3991(90)90078-z.

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47

Kumar, Kadakuntla Santhosh, Gulloo Lal Prajapati, Rahul Dagar, Megha Vagadia, Dhanvir Singh Rana i Masayoshi Tonouchi. "Terahertz Electrodynamics in Transition Metal Oxides". Advanced Optical Materials 8, nr 3 (23.12.2019): 1900958. http://dx.doi.org/10.1002/adom.201900958.

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48

Neyestanaki, A. K., i L. E. Lindfors. "Catalytic Combustion Over Transition Metal Oxides and Platinum-Transition Metal Oxides Supported on Knitted Silica Fibre". Combustion Science and Technology 97, nr 1-3 (kwiecień 1994): 121–36. http://dx.doi.org/10.1080/00102209408935371.

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Wu, Menghao, J. D. Burton, Evgeny Y. Tsymbal, Xiao Cheng Zeng i Puru Jena. "Multiferroic Materials Based on Organic Transition-Metal Molecular Nanowires". Journal of the American Chemical Society 134, nr 35 (23.08.2012): 14423–29. http://dx.doi.org/10.1021/ja304199x.

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Peng, Bin, Ren-Ci Peng, Yong-Qiang Zhang, Guohua Dong, Ziyao Zhou, Yuqing Zhou, Tao Li i in. "Phase transition enhanced superior elasticity in freestanding single-crystalline multiferroic BiFeO3 membranes". Science Advances 6, nr 34 (sierpień 2020): eaba5847. http://dx.doi.org/10.1126/sciadv.aba5847.

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The integration of ferroic oxide thin films into advanced flexible electronics will bring multifunctionality beyond organic and metallic materials. However, it is challenging to achieve high flexibility in single-crystalline ferroic oxides that is considerable to organic or metallic materials. Here, we demonstrate the superior flexibility of freestanding single-crystalline BiFeO3 membranes, which are typical multiferroic materials with multifunctionality. They can endure cyclic 180° folding and have good recoverability, with the maximum bending strain up to 5.42% during in situ bending under scanning electron microscopy, far beyond their bulk counterparts. Such superior elasticity mainly originates from reversible rhombohedral-tetragonal phase transition, as revealed by phase-field simulations. This study suggests a general fundamental mechanism for a variety of ferroic oxides to achieve high flexibility and to work as smart materials in flexible electronics.

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