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1

Abednatanzi, Sara, Parviz Gohari Derakhshandeh, Hannes Depauw, François-Xavier Coudert, Henk Vrielinck, Pascal Van Der Voort i Karen Leus. "Mixed-metal metal–organic frameworks". Chemical Society Reviews 48, nr 9 (2019): 2535–65. http://dx.doi.org/10.1039/c8cs00337h.

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Maity, Rahul, Debanjan Chakraborty, Shyamapada Nandi, Kushwaha Rinku i Ramanathan Vaidhyanathan. "Microporous mixed-metal mixed-ligand metal organic framework for selective CO2 capture". CrystEngComm 20, nr 39 (2018): 6088–93. http://dx.doi.org/10.1039/c8ce00752g.

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Oliver, Clive. "Porous metal-organic frameworks incorporating mixed ligands". Acta Crystallographica Section A Foundations and Advances 70, a1 (5.08.2014): C1476. http://dx.doi.org/10.1107/s2053273314085234.

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Metal-organic frameworks (MOFs), infinite systems built up of metal ions and organic ligands have been extensively studied in materials and supramolecular chemistry due their structural diversity and application as porous materials, in catalysis, ion exchange, gas storage and purification. [1] A novel, 2-fold interpenetrated, pillared, cadmium metal-organic framework was synthesized using trimesic acid and 1,2-bis(4-pyridyl)ethane.[2] Single crystal X-ray analysis revealed a 2-fold interpenetrated, 3-dimensional framework which exhibits a 3,5-connected network with the Schläfli symbol of [(6^3)(6^9.8)] and hms topology. This compound exhibits a temperature-induced single-to-crystal-single-crystal (SC–SC) transformation upon the release of N,N'-dimethylformamide (stable up to 3000C). SC–SC transformation was also observed when the desolvated form absorbed selected polar and non-polar organic solvents. In addition, gas (N_2, CO_2 and N_2O) sorption experiments were performed showing 2.5% N_2, 4.5% CO_2 and 3.4% N_2O absorption by mass at room temperature and moderate gas pressures (~10 bar). A similar MOF was produced when 1,3,5-benzenetricarboxylic acid was replaced with 5-nitro-1,3-benzenedicarboxylic acid. This MOF displays 4-fold interpenetration and also maintains the host framework structure upon heating.
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Dechnik, Janina, Friedrich Mühlbach, Dennis Dietrich, Tobias Wehner, Marcus Gutmann, Tessa Lühmann, Lorenz Meinel, Christoph Janiak i Klaus Müller-Buschbaum. "Luminescent Metal-Organic Framework Mixed-Matrix Membranes from Lanthanide Metal-Organic Frameworks in Polysulfone and Matrimid". European Journal of Inorganic Chemistry 2016, nr 27 (30.05.2016): 4408–15. http://dx.doi.org/10.1002/ejic.201600235.

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Cui, Yuanjing, Hui Xu, Yanfeng Yue, Zhiyong Guo, Jiancan Yu, Zhenxia Chen, Junkuo Gao, Yu Yang, Guodong Qian i Banglin Chen. "A Luminescent Mixed-Lanthanide Metal–Organic Framework Thermometer". Journal of the American Chemical Society 134, nr 9 (24.02.2012): 3979–82. http://dx.doi.org/10.1021/ja2108036.

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Tajuddin, Muhammad Hariz Aizat, Juhana Jaafar, Nik Abdul Hadi Md Nordin, Ahmad Fauzi Ismail, Mohd Hafiz Dzarfan Othman i Mukhlis A. Rahman. "Metal organic framework mixed-matrix membrane for arsenic removal". Malaysian Journal of Fundamental and Applied Sciences 16, nr 3 (15.06.2020): 359–62. http://dx.doi.org/10.11113/mjfas.v16n3.1488.

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Metal organic framework (MOF) is a recent class of porous materials that are built from metal cluster and organic linker. Among the discovered MOFs, UiO-66 has demonstrated both attributes of water stability and hydrophilic, making it suitable for wastewater treatment. In this study, 0.5 wt% UiO-66 was integrated into polysulfone membrane as nanofiller to form mixed-matrix membrane (MMM) with a thin-film composite, dense polyamide layer formed on top of the substrate layer that intended to remove 100 ppm of arsenic V from wastewater through forward osmosis. The successful synthetization of UiO-66 nanoparticle was proven by XRD and FESEM. The pure water permeability was significantly higher with the presence of LiCl in dope solution as pore former. It was found that the arsenic rejection achieved was 87.5% with satisfactory water flux and salt reverse flux.
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Wang, Shunzhi, Yijun Liao, Omar K. Farha, Hang Xing i Chad A. Mirkin. "Electrostatic Purification of Mixed-Phase Metal–Organic Framework Nanoparticles". Chemistry of Materials 30, nr 15 (31.07.2018): 4877–81. http://dx.doi.org/10.1021/acs.chemmater.8b01164.

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8

Adams, Ryan, Cantwell Carson, Jason Ward, Rina Tannenbaum i William Koros. "Metal organic framework mixed matrix membranes for gas separations". Microporous and Mesoporous Materials 131, nr 1-3 (czerwiec 2010): 13–20. http://dx.doi.org/10.1016/j.micromeso.2009.11.035.

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Chen, Fei, Yong-Mei Wang, Weiwei Guo i Xue-Bo Yin. "Color-tunable lanthanide metal–organic framework gels". Chemical Science 10, nr 6 (2019): 1644–50. http://dx.doi.org/10.1039/c8sc04732d.

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MOF gels with intrinsic emission color are prepared with 5-boronoisophthalic acid and Eu3+, Tb3+, and/or Dy3+. Single-metal gels exhibit trichromatic fluorescence, so full color emissions are readily obtained by tuning the type and/or ratio of Ln3+ ions to prepare mixed-metal gels. Nano-ribbons form from the precursors and then entangle together to generate the gels.
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10

Denny, Michael S., Mark Kalaj, Kyle C. Bentz i Seth M. Cohen. "Multicomponent metal–organic framework membranes for advanced functional composites". Chemical Science 9, nr 47 (2018): 8842–49. http://dx.doi.org/10.1039/c8sc02356e.

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Several strategies are presented for combining different metal–organic frameworks (MOFs) into composite mixed-matrix membranes. Some membranes are shown to be component for multistep organic catalytic transformations.
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11

Dhakshinamoorthy, Amarajothi, Abdullah M. Asiri i Hermenegildo Garcia. "Mixed-metal or mixed-linker metal organic frameworks as heterogeneous catalysts". Catalysis Science & Technology 6, nr 14 (2016): 5238–61. http://dx.doi.org/10.1039/c6cy00695g.

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12

Collings, Ines E., Paul J. Saines, Mirko Mikolasek, Tiziana Boffa Ballaran i Michael Hanfland. "Static disorder in a perovskite mixed-valence metal–organic framework". CrystEngComm 22, nr 16 (2020): 2859–65. http://dx.doi.org/10.1039/d0ce00119h.

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Liu, Xue, Sebastiaan Akerboom, Mathijs de Jong, Ilpo Mutikainen, Stefania Tanase, Andries Meijerink i Elisabeth Bouwman. "Mixed-Lanthanoid Metal–Organic Framework for Ratiometric Cryogenic Temperature Sensing". Inorganic Chemistry 54, nr 23 (24.11.2015): 11323–29. http://dx.doi.org/10.1021/acs.inorgchem.5b01924.

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14

Figuerola, Andreu, Deyber A. V. Medina, Alvaro J. Santos-Neto, Carlos Palomino Cabello, Víctor Cerdà, Gemma Turnes Palomino i Fernando Maya. "Metal–organic framework mixed-matrix coatings on 3D printed devices". Applied Materials Today 16 (wrzesień 2019): 21–27. http://dx.doi.org/10.1016/j.apmt.2019.04.011.

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15

Dechnik, Janina, Christopher J. Sumby i Christoph Janiak. "Enhancing Mixed-Matrix Membrane Performance with Metal–Organic Framework Additives". Crystal Growth & Design 17, nr 8 (12.06.2017): 4467–88. http://dx.doi.org/10.1021/acs.cgd.7b00595.

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16

Erucar, Ilknur, Gamze Yilmaz i Seda Keskin. "Recent Advances in Metal-Organic Framework-Based Mixed Matrix Membranes". Chemistry - An Asian Journal 8, nr 8 (25.03.2013): 1692–704. http://dx.doi.org/10.1002/asia.201300084.

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Breeze, Matthew I., Guillaume Clet, Betiana C. Campo, Alexandre Vimont, Marco Daturi, Jean-Marc Grenèche, Andrew J. Dent, Franck Millange i Richard I. Walton. "Isomorphous Substitution in a Flexible Metal–Organic Framework: Mixed-Metal, Mixed-Valent MIL-53 Type Materials". Inorganic Chemistry 52, nr 14 (15.07.2013): 8171–82. http://dx.doi.org/10.1021/ic400923d.

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18

Khandelwal, Gaurav, Nirmal Prashanth Maria Joseph Raj i Sang-Jae Kim. "ZIF-62: a mixed linker metal–organic framework for triboelectric nanogenerators". Journal of Materials Chemistry A 8, nr 34 (2020): 17817–25. http://dx.doi.org/10.1039/d0ta05067a.

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19

Thorne, Michael F., María Laura Ríos Gómez, Alice M. Bumstead, Shichun Li i Thomas D. Bennett. "Mechanochemical synthesis of mixed metal, mixed linker, glass-forming metal–organic frameworks". Green Chemistry 22, nr 8 (2020): 2505–12. http://dx.doi.org/10.1039/d0gc00546k.

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Methods to produce glass forming metal–organic frameworks (MOFs) rely on solvothermal syntheses which have high energy requirements, low yields and large teratogenic solvent usage. We present mechanochemical methods to overcome these issues.
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20

Lin, Jian-Bin, i George K. H. Shimizu. "Pyridinium linkers and mixed anions in cationic metal–organic frameworks". Inorg. Chem. Front. 1, nr 4 (2014): 302–5. http://dx.doi.org/10.1039/c3qi00065f.

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21

Masoomi, Mohammad Yaser, Ali Morsali, Amarajothi Dhakshinamoorthy i Hermenegildo Garcia. "Mixed‐Metal MOFs: Unique Opportunities in Metal–Organic Framework (MOF) Functionality and Design". Angewandte Chemie International Edition 58, nr 43 (21.10.2019): 15188–205. http://dx.doi.org/10.1002/anie.201902229.

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Masoomi, Mohammad Yaser, Ali Morsali, Amarajothi Dhakshinamoorthy i Hermenegildo Garcia. "Mixed‐Metal MOFs: Unique Opportunities in Metal–Organic Framework (MOF) Functionality and Design". Angewandte Chemie 131, nr 43 (30.07.2019): 15330–47. http://dx.doi.org/10.1002/ange.201902229.

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23

Shi, Dongying, Chao-Jie Cui, Min Hu, A.-Hao Ren, Lu-Bin Song, Chun-Sen Liu i Miao Du. "A microporous mixed-metal (Na/Cu) mixed-ligand (flexible/rigid) metal–organic framework for photocatalytic H2 generation". Journal of Materials Chemistry C 7, nr 33 (2019): 10211–17. http://dx.doi.org/10.1039/c9tc03342d.

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24

Li, Wanbin, Guoliang Zhang, Congyang Zhang, Qin Meng, Zheng Fan i Congjie Gao. "Synthesis of trinity metal–organic framework membranes for CO2 capture". Chem. Commun. 50, nr 24 (2014): 3214–16. http://dx.doi.org/10.1039/c3cc49815h.

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25

Yue, Dan, Yike Huang, Ling Zhang, Ke Jiang, Xin Zhang, Yuanjing Cui, Yang Yu i Guodong Qian. "Ratiometric luminescence sensing based on a mixed Ce/Eu metal–organic framework". Journal of Materials Chemistry C 6, nr 8 (2018): 2054–59. http://dx.doi.org/10.1039/c7tc05309f.

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26

Das, Madhab C., Shengchang Xiang, Zhangjing Zhang i Banglin Chen. "Functional Mixed Metal-Organic Frameworks with Metalloligands". Angewandte Chemie International Edition 50, nr 45 (16.09.2011): 10510–20. http://dx.doi.org/10.1002/anie.201101534.

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Choi, Hwa-Jin, i Dong-Yeun Koh. "Homochiral Metal-Organic Framework Based Mixed Matrix Membrane for Chiral Resolution". Membranes 12, nr 4 (24.03.2022): 357. http://dx.doi.org/10.3390/membranes12040357.

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Efficient separation of enantiomers is critical in the chemical, pharmaceutical, and food industries. However, conventional separation methods, such as chromatography, crystallization, and enzymatic kinetic resolution, require high energy costs and specific reaction conditions for the efficient purification of one enantiomer. In contrast, membrane-based processes are continuous processes performed with less energy than conventional separation processes. Enantioselective polymer membranes have been developed for the chiral resolution of pharmaceuticals; however, it is difficult to generate sufficient enantiomeric excess (ee) with polymer membranes. In this work, a homochiral filler of L-His-ZIF-8 was synthesized by the ligand substitution method and mixed with polyamide(imide) (i.e., Torlon®) to fabricate an enantioselective mixed-matrix membrane (MMM). The enantio-selective separation of R-1-phenylethanol over S-1-phenylethanol was demonstrated with a 25 wt% loaded L-His-ZIF-8/Torlon® MMM in an organic solvent nanofiltration (OSN) mode.
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28

Erucar, Ilknur, i Seda Keskin. "Screening Metal–Organic Framework-Based Mixed-Matrix Membranes for CO2/CH4Separations". Industrial & Engineering Chemistry Research 50, nr 22 (16.11.2011): 12606–16. http://dx.doi.org/10.1021/ie201885s.

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29

Luz, Ignacio, Lora Toy, Feras Rabie, Marty Lail i Mustapha Soukri. "Synthesis of Soluble Metal Organic Framework Composites for Mixed Matrix Membranes". ACS Applied Materials & Interfaces 11, nr 17 (12.04.2019): 15638–45. http://dx.doi.org/10.1021/acsami.9b02622.

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Pan, Yue, Hai-Quan Su, En-Long Zhou, Hong-Zong Yin, Kui-Zhan Shao i Zhong-Min Su. "A stable mixed lanthanide metal–organic framework for highly sensitive thermometry". Dalton Transactions 48, nr 11 (2019): 3723–29. http://dx.doi.org/10.1039/c9dt00217k.

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A stable mixed Ln-MOF with a novel (4,8)-connected binodal network was constructed, which could be used as a ratiometric and colorimetric temperature sensor with high relative sensitivity (Sm = 9.42% per K at 310 K).
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Huxley, Michael, Campbell J. Coghlan, Alexandre Burgun, Andrew Tarzia, Kenji Sumida, Christopher J. Sumby i Christian J. Doonan. "Site-specific metal and ligand substitutions in a microporous Mn2+-based metal–organic framework". Dalton Transactions 45, nr 10 (2016): 4431–38. http://dx.doi.org/10.1039/c5dt05023e.

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Vuong, Gia-Thanh, Minh-Hao Pham i Trong-On Do. "Synthesis and engineering porosity of a mixed metal Fe2Ni MIL-88B metal–organic framework". Dalton Trans. 42, nr 2 (2013): 550–57. http://dx.doi.org/10.1039/c2dt32073h.

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Lee, Yeob, Sangjun Kim, Jeung Ku Kang i Seth M. Cohen. "Photocatalytic CO2 reduction by a mixed metal (Zr/Ti), mixed ligand metal–organic framework under visible light irradiation". Chemical Communications 51, nr 26 (2015): 5735–38. http://dx.doi.org/10.1039/c5cc00686d.

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Kharisov, Boris, Oxana Kharissova, Vladimir Zhinzhilo, Julia Bryantseva i Igor Uflyand. "Solid-Phase Extraction of Organic Dyes on Mixed-Ligand Zr(IV) Metal–Organic Framework". Applied Sciences 12, nr 23 (29.11.2022): 12219. http://dx.doi.org/10.3390/app122312219.

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Currently, among the various areas of targeted wastewater treatment, great attention is being given by researchers to the solid-phase extraction of organic dyes using metal–organic frameworks (MOFs). In this work, a mixed-ligand Zr-MOF containing terephthalic acid and 1,10-phenanthroline as linkers was used for this purpose. The limiting adsorption of the dyes Congo red and methylene blue, according to experimental data, is 40 mg/g. The influence of various parameters (time, temperature, adsorbent dosage, pH, and coexisting ions) on adsorption characteristics was studied. The sorbent was tested for the removal of dyes from drinks in water and in artificial seawater. The possibility of the separation of dyes by column chromatography using a sorbent as a filler was studied.
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35

Xiang, Long, Donghui Liu, Hua Jin, Long-Wei Xu, Chongqing Wang, Shutao Xu, Yichang Pan i Yanshuo Li. "Locking of phase transition in MOF ZIF-7: improved selectivity in mixed-matrix membranes for O2/N2 separation". Materials Horizons 7, nr 1 (2020): 223–28. http://dx.doi.org/10.1039/c9mh00409b.

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Tang, Po-Hsiang, Pamela Berilyn So, Kueir-Rarn Lee, Yu-Lun Lai, Cheng-Shiuan Lee i Chia-Her Lin. "Metal Organic Framework-Polyethersulfone Composite Membrane for Iodine Capture". Polymers 12, nr 10 (9.10.2020): 2309. http://dx.doi.org/10.3390/polym12102309.

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A variety of metal organic frameworks (MOFs) were synthesized and evaluated for their iodine adsorption capacity. Out of the MOFs tested, ZIF-8 showed the most promising result with an iodine vapor uptake of 876.6 mg/g. ZIF-8 was then incorporated into a polymer, polyethersulfone (PES), at different proportions to prepare mixed matrix membranes (MMMs), which were then used to perform further iodine adsorption experiments. With a mixing ratio of 40 wt % of ZIF-8, the iodine adsorption capacity reached 1387.6 mg/g, wherein an astounding 60% improvement in adsorption was seen with the MMMs prepared compared to the original ZIF-8 powder.
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Datta, Shuvo Jit, Alvaro Mayoral, Narasimha Murthy Srivatsa Bettahalli, Prashant M. Bhatt, Madhavan Karunakaran, Ionela Daniela Carja, Dong Fan i in. "Rational design of mixed-matrix metal-organic framework membranes for molecular separations". Science 376, nr 6597 (3.06.2022): 1080–87. http://dx.doi.org/10.1126/science.abe0192.

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Conventional separation technologies to separate valuable commodities are energy intensive, consuming 15% of the worldwide energy. Mixed-matrix membranes, combining processable polymers and selective adsorbents, offer the potential to deploy adsorbent distinct separation properties into processable matrix. We report the rational design and construction of a highly efficient, mixed-matrix metal-organic framework membrane based on three interlocked criteria: (i) a fluorinated metal-organic framework, AlFFIVE-1-Ni, as a molecular sieve adsorbent that selectively enhances hydrogen sulfide and carbon dioxide diffusion while excluding methane; (ii) tailoring crystal morphology into nanosheets with maximally exposed (001) facets; and (iii) in-plane alignment of (001) nanosheets in polymer matrix and attainment of [001]-oriented membrane. The membrane demonstrated exceptionally high hydrogen sulfide and carbon dioxide separation from natural gas under practical working conditions. This approach offers great potential to translate other key adsorbents into processable matrix.
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38

Ji, Zhe, Tong Li i Omar M. Yaghi. "Sequencing of metals in multivariate metal-organic frameworks". Science 369, nr 6504 (6.08.2020): 674–80. http://dx.doi.org/10.1126/science.aaz4304.

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We mapped the metal sequences within crystals of metal-oxide rods in multivariate metal-organic framework–74 containing mixed combinations of cobalt (Co), cadmium (Cd), lead (Pb), and manganese (Mn). Atom probe tomography of these crystals revealed the presence of heterogeneous spatial sequences of metal ions that we describe, depending on the metal and synthesis temperature used, as random (Co, Cd, 120°C), short duplicates (Co, Cd, 85°C), long duplicates (Co, Pb, 85°C), and insertions (Co, Mn, 85°C). Three crystals were examined for each sequence type, and the molar fraction of Co among all 12 samples was observed to vary from 0.4 to 0.9, without changing the sequence type. Compared with metal oxides, metal-organic frameworks have high tolerance for coexistence of different metal sizes in their rods and therefore assume various metal sequences.
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Khazalpour, Sadegh, Vahid Safarifard, Ali Morsali i Davood Nematollahi. "Electrochemical synthesis of pillared layer mixed ligand metal–organic framework: DMOF-1–Zn". RSC Advances 5, nr 46 (2015): 36547–51. http://dx.doi.org/10.1039/c5ra04446d.

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40

Knope, K. E., i C. L. Cahill. "Synthesis and characterization of mixed-metal (UO22+/TM2+) inorganic/organic framework materials". Acta Crystallographica Section A Foundations of Crystallography 64, a1 (23.08.2008): C484. http://dx.doi.org/10.1107/s0108767308084456.

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41

Rao, Xingtang, Tao Song, Junkuo Gao, Yuanjing Cui, Yu Yang, Chuande Wu, Banglin Chen i Guodong Qian. "A Highly Sensitive Mixed Lanthanide Metal–Organic Framework Self-Calibrated Luminescent Thermometer". Journal of the American Chemical Society 135, nr 41 (8.10.2013): 15559–64. http://dx.doi.org/10.1021/ja407219k.

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42

Bae, Youn Jue, Eun Seon Cho, Fen Qiu, Daniel T. Sun, Teresa E. Williams, Jeffrey J. Urban i Wendy L. Queen. "Transparent Metal–Organic Framework/Polymer Mixed Matrix Membranes as Water Vapor Barriers". ACS Applied Materials & Interfaces 8, nr 16 (15.04.2016): 10098–103. http://dx.doi.org/10.1021/acsami.6b01299.

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43

Nik, Omid Ghaffari, Xiao Yuan Chen i Serge Kaliaguine. "Functionalized metal organic framework-polyimide mixed matrix membranes for CO2/CH4 separation". Journal of Membrane Science 413-414 (wrzesień 2012): 48–61. http://dx.doi.org/10.1016/j.memsci.2012.04.003.

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44

Liu, Jian, Louis R. Redfern, Yijun Liao, Timur Islamoglu, Ahmet Atilgan, Omar K. Farha i Joseph T. Hupp. "Metal–Organic-Framework-Supported and -Isolated Ceria Clusters with Mixed Oxidation States". ACS Applied Materials & Interfaces 11, nr 51 (2.12.2019): 47822–29. http://dx.doi.org/10.1021/acsami.9b12261.

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45

Nelson, Andrew P., Damon A. Parrish, Lee R. Cambrea, Lawrence C. Baldwin, Nirupam J. Trivedi, Karen L. Mulfort, Omar K. Farha i Joseph T. Hupp. "Crystal to Crystal Guest Exchange in a Mixed Ligand Metal−Organic Framework". Crystal Growth & Design 9, nr 11 (4.11.2009): 4588–91. http://dx.doi.org/10.1021/cg900735n.

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Xia, Tifeng, Jintong Wang, Ke Jiang, Yuanjing Cui, Yu Yang i Guodong Qian. "A Eu/Gd-mixed metal-organic framework for ultrasensitive physiological temperature sensing". Chinese Chemical Letters 29, nr 6 (czerwiec 2018): 861–64. http://dx.doi.org/10.1016/j.cclet.2017.10.038.

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47

Winarta, Joseph, Amogh Meshram, Feifei Zhu, Renjie Li, Hasan Jafar, Kunj Parmar, Jichang Liu i Bin Mu. "Metal–organic framework ‐based mixed‐matrix membranes for gas separation: An overview". Journal of Polymer Science 58, nr 18 (21.08.2020): 2518–46. http://dx.doi.org/10.1002/pol.20200122.

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48

Yue, Dan, Zhangjian Li, Dong Chen, Weidong Li, Bowen Qin, Bing Zhang, Yanping Li, Dian Zhao i Zhenling Wang. "Ratiometric luminescent thermometer based on a mixed Ce/Tb metal-organic framework". Journal of Solid State Chemistry 327 (listopad 2023): 124279. http://dx.doi.org/10.1016/j.jssc.2023.124279.

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Zhang, Wendi, Shuping Wang, Fei Yang, Zhijie Yang, Huiying Wei, Yanzhao Yang i Jingjing Wei. "Synthesis of catalytically active bimetallic nanoparticles within solution-processable metal–organic-framework scaffolds". CrystEngComm 21, nr 26 (2019): 3954–60. http://dx.doi.org/10.1039/c9ce00238c.

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Samantaray, Paresh Kumar, Sonika Baloda, Giridhar Madras i Suryasarathi Bose. "A designer membrane tool-box with a mixed metal organic framework and RAFT-synthesized antibacterial polymer perform in tandem towards desalination, antifouling and heavy metal exclusion". Journal of Materials Chemistry A 6, nr 34 (2018): 16664–79. http://dx.doi.org/10.1039/c8ta05052j.

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