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Artykuły w czasopismach na temat "Methane"

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Tselishchev, Oleksii, Ayodeji Ijagbuji, Maryna Loriia i Vanadii Nosach. "Synthesis of Methanol from Methane in Cavitation Field". Chemistry & Chemical Technology 12, nr 1 (21.03.2018): 69–73. http://dx.doi.org/10.23939/chcht12.01.069.

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Benstead, J., G. M. King i H. G. Williams. "Methanol Promotes Atmospheric Methane Oxidation by Methanotrophic Cultures and Soils". Applied and Environmental Microbiology 64, nr 3 (1.03.1998): 1091–98. http://dx.doi.org/10.1128/aem.64.3.1091-1098.1998.

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ABSTRACT Two methanotrophic bacteria, Methylobacter albus BG8 and Methylosinus trichosporium OB3b, oxidized atmospheric methane during batch growth on methanol. Methane consumption was rapidly and substantially diminished (95% over 9 days) when washed cell suspensions were incubated without methanol in the presence of atmospheric methane (1.7 ppm). Methanotrophic activity was stimulated after methanol (10 mM) but not methane (1,000 ppm) addition. M. albus BG8 grown in continuous culture for 80 days with methanol retained the ability to oxidize atmospheric methane and oxidized methane in a chemostat air supply. Methane oxidation during growth on methanol was not affected by methane deprivation. Differences in the kinetics of methane uptake (apparent Km andV max) were observed between batch- and chemostat-grown cultures. The V max and apparent Km values (means ± standard errors) for methanol-limited chemostat cultures were 133 ± 46 nmol of methane 108 cells−1 h−1and 916 ± 235 ppm of methane (1.2 μM), respectively. These values were significantly lower than those determined with batch-grown cultures (V max of 648 ± 195 nmol of methane 108 cells−1 h−1 and apparent Km of 5,025 ± 1,234 ppm of methane [6.3 μM]). Methane consumption by soils was stimulated by the addition of methanol. These results suggest that methanol or other nonmethane substrates may promote atmospheric methane oxidation in situ.
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Jensen, Sigmund, Anders Priemé i Lars Bakken. "Methanol Improves Methane Uptake in Starved Methanotrophic Microorganisms". Applied and Environmental Microbiology 64, nr 3 (1.03.1998): 1143–46. http://dx.doi.org/10.1128/aem.64.3.1143-1146.1998.

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ABSTRACT Methanotrophs in enrichment cultures grew and sustained atmospheric methane oxidation when supplied with methanol. If they were not supplied with methanol or formate, their atmospheric methane oxidation came to a halt, but it was restored within hours in response to methanol or formate. Indigenous forest soil methanotrophs were also dependent on a supply of methanol upon reduced methane access but only when exposed to a methane-free atmosphere. Their immediate response to each methanol addition, however, was to shut down the oxidation of atmospheric methane and to reactivate atmospheric methane oxidation as the methanol was depleted.
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Blankenship, Andrea N., Manoj Ravi i Jeroen A. van Bokhoven. "Esterification Product Protection Strategies for Direct and Selective Methane Conversion". CHIMIA International Journal for Chemistry 75, nr 4 (28.04.2021): 305–10. http://dx.doi.org/10.2533/chimia.2021.305.

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A scale-flexible process for the direct and selective oxidation of methane to primary oxygenates is of great interest, however, a commercially feasible approach has yet to be realized due to a number of challenges. Low product yields imposed by a well-established selectivity-conversion limit are particularly burdensome for direct methane-to-methanol chemistry. One strategy that has emerged to break out of this limit is the in situ esterification of produced methanol to the more oxidation-resistant methyl ester. However, these methaneto-methyl-ester approaches still elude commercialization despite their unprecedented high yields. Herein, we outline some of the key barriers that hinder the commercial prospects of this otherwise promising route for highyield direct catalytic methane conversion, including extremely corrosive reagents, homogeneous catalysts, and inviable oxidants. We then highlight directions to address these challenges while maintaining the characteristic high performance of these systems. These discussions support the efficacy of product protection strategies for the direct, selective oxidation of methane and encourage future work in developing creative solutions to merge this promising chemistry with more practical industrial requirements.
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Chun, Jin Woo, i Rayford G. Anthony. "Partial oxidation of methane, methanol, and mixtures of methane and methanol, methane and ethane, and methane, carbon dioxide, and carbon monoxide". Industrial & Engineering Chemistry Research 32, nr 5 (maj 1993): 788–95. http://dx.doi.org/10.1021/ie00017a004.

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Xu, Zhen Chao, i Eun Duck Park. "Gas-Phase Selective Oxidation of Methane into Methane Oxygenates". Catalysts 12, nr 3 (9.03.2022): 314. http://dx.doi.org/10.3390/catal12030314.

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Methane is an abundant resource and its direct conversion into value-added chemicals has been an attractive subject for its efficient utilization. This method can be more efficient than the present energy-intensive indirect conversion of methane via syngas, a mixture of CO and H2. Among the various approaches for direct methane conversion, the selective oxidation of methane into methane oxygenates (e.g., methanol and formaldehyde) is particularly promising because it can proceed at low temperatures. Nevertheless, due to low product yields this method is challenging. Compared with the liquid-phase partial oxidation of methane, which frequently demands for strong oxidizing agents in protic solvents, gas-phase selective methane oxidation has some merits, such as the possibility of using oxygen as an oxidant and the ease of scale-up owing to the use of heterogeneous catalysts. Herein, we summarize recent advances in the gas-phase partial oxidation of methane into methane oxygenates, focusing mainly on its conversion into formaldehyde and methanol.
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Sedov, I. V., V. S. Arutyunov, M. V. Tsvetkov, D. N. Podlesniy, M. V. Salganskaya, A. Y. Zaichenko, Y. Y. Tsvetkova i in. "Evaluation of the Possibility to Use Coalbed Methane to Produce Methanol Both by Direct Partial Oxidation and From Synthesis Gas". Eurasian Chemico-Technological Journal 24, nr 2 (25.07.2022): 157. http://dx.doi.org/10.18321/ectj1328.

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The possibility of using coalbed methane to produce methanol is assessed. Methanol can be obtained from methane both by direct partial oxidation and from synthesis gas formed through the oxidative conversion of methane. Thermodynamic analysis of coalbed methane conversion was carried out to determine the conditions for obtaining synthesis gas with the ratio [H2]/[CO] = 2, which is optimal for methanol production. The system consisting of methane, nitrogen, and oxygen, with different contents of oxygen and water vapor, was considered. The fuel-air equivalence ratio varied in the range from 2 to 4. The optimal conditions for obtaining synthesis gas for the production of methanol is the use of a mixture with an equivalence ratio of at least 4. It has also been shown that the addition of water vapor leads to an increase in the [H2]/[CO] ratio. Direct gas-phase oxidation of methane to methanol opens up the possibility of complex use of coal mining waste, including not only coalbed methane but also a large amount of coal waste accumulated during coal mining and beneficiation.
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Li, Zhi, Yanjun Chen, Zean Xie, Weiyu Song, Baijun Liu i Zhen Zhao. "Rational Design of the Catalysts for the Direct Conversion of Methane to Methanol Based on a Descriptor Approach". Catalysts 13, nr 8 (21.08.2023): 1226. http://dx.doi.org/10.3390/catal13081226.

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The direct oxidation of methane to methanol as a liquid fuel and chemical feedstock is arguably the most desirable methane conversion pathway. Currently, constructing and understanding linear scaling relationships between the fundamental physical or chemical properties of catalysts and their catalytic performance to explore suitable descriptors is crucial for theoretical research on the direct conversion of methane to methanol. In this review, we summarize the energy, electronic, and structural descriptors used to predict catalytic activity. Fundamentally, these descriptors describe the redox properties of active sites from different dimensions. We further explain the moderate principle of descriptors in methane-to-methanol catalyst design and provide related application work. Simultaneously, the underlying activity limitation of methane activation and active species generation is revealed. Based on the selectivity descriptor, the inverse scaling relationship limitation between methane conversion and methanol selectivity is quantitatively understood. Finally, multiscale strategies are proposed to break the limitation and achieve the simultaneous enhancement of activity and selectivity. This descriptor-based review provides theoretical insights and guidance to accelerate the understanding, optimization, and design of efficient catalysts for direct methane-to-methanol conversion.
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JACOBY, MITCH. "TURNING METHANE INTO METHANOL". Chemical & Engineering News 87, nr 35 (31.08.2009): 7. http://dx.doi.org/10.1021/cen-v087n035.p007.

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Shen, Haiqing, Huihong Liao, Qiyang Wang, Cangsu Xu, Kai Liu i Wenhua Zhou. "Effects of methane addition on the laminar burning velocity and Markstein length of methanol/air premixed flame". Thermal Science, nr 00 (2023): 193. http://dx.doi.org/10.2298/tsci230201193s.

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Adding methane to methanol can solve the problem of difficult cold starts of methanol engines. Therefore, it is important to understand the combustion of methane and methanol fuel blends. Because of this, this study explores the effect of methane addition on the laminar burning velocity and Markstein length of methanol/methane premixed flames under stoichiometric conditions at the initial temperatures of 353 K, 373 K, and 393 K, initial pressures of 1 bar, 2 bar, and 4 bar, using methane addition ratios of 0%, 25%, 50%, 75% and 100% in a constant volume combustion chamber. The results show that the laminar burning velocity decreases linearly with the increase of methane addition ratio due to the linear decrease of the Arrhenius factor. The sensitivity analysis revealed that the kinetic effect is the main reason for the inhibition of laminar burning velocity, which is insensitive to initial temperature but enhanced at a high initial pressure. The Markstein length decreases with the addition of methane and the increase of initial pressure, which is mainly caused by the high mass diffusivity of methane and the decrease of flame thickness due to the increase of initial pressure.
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Rozprawy doktorskie na temat "Methane"

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Squire, Gavin Daniel. "Partial oxidation of methane to methanol and formaldehyde". Thesis, University of Reading, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.278072.

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Chellappa, Anand S. "Methane conversion to methanol : homogeneous and catalytic studies /". free to MU campus, to others for purchase, 1997. http://wwwlib.umi.com/cr/mo/fullcit?p9842517.

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Matthews, Terry. "The Partial Oxidation of Methane to Methanol & Formaldehyde". TopSCHOLAR®, 1987. https://digitalcommons.wku.edu/theses/2602.

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The conversion of methane into methanol is viewed as one approach to utilizing the vast reserves of natural gas. One such prospect for the utilization of natural gas is the partial oxidation of methane to methanol. Methanol ranks high on the commodity market. As a liquid it is easily transportable and therefore skirts the issue of vast amounts of a gas having to be transported either by pipeline or by liquifying. The catalytic partial oxidation of methane to methanol is investigated. Two different reactor systems are employed. The first system is a fixed bed system. The second is a fluid bed system. Areas to be addressed are different catalyst systems, different loading rates, elemental promotion, different supports, surface area, catalyst particle mesh size, and effects of preparation.
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Afonso, Joana da Costa Franco. "Catalytic hydrogenation of carbon dioxide to form methanol and methane". Master's thesis, Faculdade de Ciências e Tecnologia, 2013. http://hdl.handle.net/10362/10854.

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Olsson, Susanna. "Dynamics of a spin-forbidden reaction transforming methane to methanol". Thesis, Uppsala universitet, Institutionen för kemi - BMC, 2019. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-385895.

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Borchardt, Lars, Winfried Nickel, Mirian Casco, Irena Senkovska, Volodymyr Bon, Dirk Wallacher, Nico Grimm, Simon Krause i Joaquín Silvestre-Albero. "Illuminating solid gas storage in confined spaces – methane hydrate formation in porous model carbons". Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2017. http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-221847.

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Methane hydrate nucleation and growth in porous model carbon materials illuminates the way towards the design of an optimized solid-based methane storage technology. High-pressure methane adsorption studies on pre-humidified carbons with well-defined and uniform porosity show that methane hydrate formation in confined nanospace can take place at relatively low pressures, even below 3 MPa CH4, depending on the pore size and the adsorption temperature. The methane hydrate nucleation and growth is highly promoted at temperatures below the water freezing point, due to the lower activation energy in ice vs. liquid water. The methane storage capacity via hydrate formation increases with an increase in the pore size up to an optimum value for the 25 nm pore size model-carbon, with a 173% improvement in the adsorption capacity as compared to the dry sample. Synchrotron X-ray powder diffraction measurements (SXRPD) confirm the formation of methane hydrates with a sI structure, in close agreement with natural hydrates. Furthermore, SXRPD data anticipate a certain contraction of the unit cell parameter for methane hydrates grown in small pores.
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Prince, Bruce M. "The Mechanisms of Methane C–H Activation and Oxy-insertion Via Small Transition Metal Complexes: a DFT Computational Investigation". Thesis, University of North Texas, 2014. https://digital.library.unt.edu/ark:/67531/metadc500116/.

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Our country continues to demand clean renewable energy to meet the growing energy needs of our time. Thus, natural gas, which is 87% by volume of methane, has become a hot topic of discussion because it is a clean burning fuel. However, the transportation of methane is not easy because it is a gas at standard temperature and pressure. The usage of transition metals for the conversion of small organic species like methane into a liquid has been a longstanding practice in stoichiometric chemistry. Nonetheless, the current two-step process takes place at a high temperature and pressure for the conversion of methane and steam to methanol via CO + H2 (syngas). The direct oxidation of methane (CH4) into methanol (CH3OH) via homogeneous catalysis is of interest if the system can operate at standard pressure and a temperature less than 250 C. Methane is an inert gas due to the high C-H bond dissociation energy (BDE) of 105 kcal/mol. This dissertation discusses a series of computational investigations of oxy-insertion pathways to understand the essential chemistry behind the functionalization of methane via the use of homogeneous transition metal catalysis. The methane to methanol (MTM) catalytic cycle is made up of two key steps: (1) C-H activation by a metal-methoxy complex, (2) the insertion of oxygen into the metal−methyl bond (oxy-insertion). While, the first step (C-H activation) has been well studied, the second step has been less studied. Thus, this dissertation focuses on oxy-insertion via a two-step mechanism, oxygen-atom transfer (OAT) and methyl migration, utilizing transition metal complexes known to activate small organic species (e.g., PtII and PdII complexes). This research seeks to guide experimental investigations, and probe the role that metal charge and coordination number play.
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York, Andrew P. E. "Methane conversion chemistry". Thesis, University of Oxford, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.334954.

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Hammond, Charles Rhodri. "Partial oxidation of methane to methanol using modified mixed metal oxides". Thesis, Cardiff University, 2004. http://orca.cf.ac.uk/54537/.

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The current steam reforming process for the production of CH3OH is complicated and difficult, and therefore the direct partial oxidation of CH4 to CH3OH would be economically desirable. In previous work a design approach for a selective partial oxidation catalyst has been investigated, which comprises the combination of components with a desired reactivity, producing a successful selective partial oxidation catalyst. In this approach, it is considered a successful partial oxidation catalyst must activate methane, activate oxygen and not destroy the desired product, methanol. All these properties could not be found in a single catalyst, so it was proposed that two synergistic components could be combined, one responsible for methane activation and the other for oxygen activation/insertion. Previous work has studied the CH4/D2 exchange reaction as an indication of the ability of a metal oxide surface to activate CH4. Two metal oxides demonstrated appreciable activity for the activation of CH4, these being Ga2C3 and ZnO. These oxides were then doped with different metals in order to try and increase the activity of the catalyst. The doping of Ga2O3 with Zn or Mg did not improve the methane oxidation properties of Ga2C3, and the doping of ZnO with Ga significantly lowered the light off temperature, the temperature at which CH4 was first detected, and increased its oxidative capacity. The addition of precious metals significantly affected the catalysts ability to activate CH4. The addition of Au to the Ga and Zn catalysts dramatically reduced the light off temperature, and increased its rate of oxidation at lower temperatures, with the optimum loading 2% for both catalysts. For GaO(OH) and ZnO, the addition of 1%Au and l%Pt by coprecipitation produced a synergistic effect, producing lower light offs and higher CH4 conversion than the singly doped catalysts with Au and Pt separately. When the methane activation catalysts were combined with MoO3 in a physical mixture, a number of the mixtures produced higher methanol per pass percentage yields than its constituent parts. It is concluded that the increased methane activation properties beneficially interact with the oxygen activation and insertion properties of MoO3. However, none of the yields reported were significantly higher. A dual bed system, with the lower layer comprising the methane activation catalysts, and the upper layer consisting of MoO 3 was tested. The results for this system were promising, with the low temperature activation of CH4, combined with the oxygen insertion ability of MoO3, producing high selectivities of CH3OH at much lower temperatures. The best results were obtained when the ratio of the two layers was 50:50 with respect to 2%Au ZnO and MoO3. In previous work a design approach for a selective partial oxidation catalyst has been investigated, by combining components with a desired reactivity to produce a successful selective partial oxidation catalyst, which must activate methane and oxygen, and not destroy methanol. All these properties could not be found in a single catalyst, so it was proposed that two synergistic components could be combined, one responsible for methane activation and the other for oxygen activation/insertion. The doping of ZnO with Ga significantly lowered the light off temperature, and increased its oxidative capacity, an effect which was not seen with the doping of Ga2O3 with Zn or Mg. The addition of Au to the Ga and Zn catalysts dramatically reduced the light off temperature, and increased its rate of oxidation at lower temperatures, both with optimum loading of 2%. The addition of l%Au and l%Pt produced a synergistic effect, producing lower light offs and higher CH4 conversion than the singly doped catalysts with Au and Pt separately. When the methane activation catalysts were combined with MoO3 in a physical mixture, a number of the mixtures produced higher methanol per pass percentage yields than its constituent parts. It is concluded that the increased methane activation properties beneficially interact with the oxygen activation and insertion properties of MoO3. The dual bed system, with the lower layer comprising the methane activation catalysts, and the upper layer consisting of MoO 3 produced promising results, with the low temperature activation of CH4, combined with the oxygen insertion ability of MoO3, producing high selectivities of CH3OH at much lower temperatures. The best results were obtained when the ratio of the two layers was 50:50 with respect to 2%Au ZnO and MoO3. (Abstract shortened by UMI.).
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Borchardt, Lars, Winfried Nickel, Mirian Casco, Irena Senkovska, Volodymyr Bon, Dirk Wallacher, Nico Grimm, Simon Krause i Joaquín Silvestre-Albero. "Illuminating solid gas storage in confined spaces – methane hydrate formation in porous model carbons". Royal Society of Chemistry, 2016. https://tud.qucosa.de/id/qucosa%3A30232.

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Methane hydrate nucleation and growth in porous model carbon materials illuminates the way towards the design of an optimized solid-based methane storage technology. High-pressure methane adsorption studies on pre-humidified carbons with well-defined and uniform porosity show that methane hydrate formation in confined nanospace can take place at relatively low pressures, even below 3 MPa CH4, depending on the pore size and the adsorption temperature. The methane hydrate nucleation and growth is highly promoted at temperatures below the water freezing point, due to the lower activation energy in ice vs. liquid water. The methane storage capacity via hydrate formation increases with an increase in the pore size up to an optimum value for the 25 nm pore size model-carbon, with a 173% improvement in the adsorption capacity as compared to the dry sample. Synchrotron X-ray powder diffraction measurements (SXRPD) confirm the formation of methane hydrates with a sI structure, in close agreement with natural hydrates. Furthermore, SXRPD data anticipate a certain contraction of the unit cell parameter for methane hydrates grown in small pores.
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Książki na temat "Methane"

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Murrell, J. Colin, i Howard Dalton, red. Methane and Methanol Utilizers. Boston, MA: Springer US, 1992. http://dx.doi.org/10.1007/978-1-4899-2338-7.

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C, Murrell J., i Dalton Howard, red. Methane and methanol utilizers. New York: Plenum Press, 1992.

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Project, Thermodynamic Tables. Methane. Oxford: Blackwell Science, 1996.

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Lawrence, Clever H., Young Colin L, Battino Rubin, Hayduk Walter i Wiesenburg Denis A, red. Methane. Oxford: Pergamon, 1987.

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Lawrence, Clever H., Young Colin Leslie, Battino Rubin, Hayduk Walter i Wiesenburg Denis Alan 1948-, red. Methane. Oxford: Pergamon, 1987.

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Khalil, Mohammad Aslam Khan, red. Atmospheric Methane. Berlin, Heidelberg: Springer Berlin Heidelberg, 2000. http://dx.doi.org/10.1007/978-3-662-04145-1.

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De Falco, Marcello, i Angelo Basile, red. Enriched Methane. Cham: Springer International Publishing, 2016. http://dx.doi.org/10.1007/978-3-319-22192-2.

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Society of Petroleum Engineers (U.S.), red. Coalbed methane. Richardson, TX: Society of Petroleum Engineers, 1992.

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Demirbas, Ayhan. Methane gas hydrate. London: Springer, 2010.

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Demirbas, Ayhan. Methane Gas Hydrate. London: Springer London, 2010. http://dx.doi.org/10.1007/978-1-84882-872-8.

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Części książek na temat "Methane"

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Dalton, Howard. "Methane Oxidation by Methanotrophs". W Methane and Methanol Utilizers, 85–114. Boston, MA: Springer US, 1992. http://dx.doi.org/10.1007/978-1-4899-2338-7_3.

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Hanson, Richard S. "Introduction". W Methane and Methanol Utilizers, 1–21. Boston, MA: Springer US, 1992. http://dx.doi.org/10.1007/978-1-4899-2338-7_1.

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Green, Peter N. "Taxonomy of Methylotrophic Bacteria". W Methane and Methanol Utilizers, 23–84. Boston, MA: Springer US, 1992. http://dx.doi.org/10.1007/978-1-4899-2338-7_2.

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Murrell, J. Colin. "The Genetics and Molecular Biology of Obligate Methane-Oxidizing Bacteria". W Methane and Methanol Utilizers, 115–48. Boston, MA: Springer US, 1992. http://dx.doi.org/10.1007/978-1-4899-2338-7_4.

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Dijkhuizen, L., P. R. Levering i G. E. de Vries. "The Physiology and Biochemistry of Aerobic Methanol-Utilizing Gram-Negative and Gram-Positive Bacteria". W Methane and Methanol Utilizers, 149–81. Boston, MA: Springer US, 1992. http://dx.doi.org/10.1007/978-1-4899-2338-7_5.

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Lidstrom, Mary E. "The Genetics and Molecular Biology of Methanol-Utilizing Bacteria". W Methane and Methanol Utilizers, 183–206. Boston, MA: Springer US, 1992. http://dx.doi.org/10.1007/978-1-4899-2338-7_6.

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de Koning, W., i W. Harder. "Methanol-Utilizing Yeasts". W Methane and Methanol Utilizers, 207–44. Boston, MA: Springer US, 1992. http://dx.doi.org/10.1007/978-1-4899-2338-7_7.

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Leak, David J. "Biotechnological and Applied Aspects of Methane and Methanol Utilizers". W Methane and Methanol Utilizers, 245–79. Boston, MA: Springer US, 1992. http://dx.doi.org/10.1007/978-1-4899-2338-7_8.

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McPherson, Malcolm J. "Methane". W Subsurface Ventilation and Environmental Engineering, 401–56. Dordrecht: Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-011-1550-6_12.

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Kobayashi, Kensei. "Methane". W Encyclopedia of Astrobiology, 1550–51. Berlin, Heidelberg: Springer Berlin Heidelberg, 2015. http://dx.doi.org/10.1007/978-3-662-44185-5_4007.

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Streszczenia konferencji na temat "Methane"

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Lamarre, Robert A. "Downhole Geochemical Analysis of Critical Desorption Pressure and Gas Content for Carbonaceous Reservoirs". W SPE Applied Technology Workshop on Coalbed Methane. Society of Petroleum Engineers, 2007. http://dx.doi.org/10.2118/111091-ms.

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Fukasawa, T., S. Hozumi, M. Morita, T. Oketani i M. Masson. "Dissolved Methane Sensor for Methane Leakage Monitoring in Methane Hydrate Production". W OCEANS 2006. IEEE, 2006. http://dx.doi.org/10.1109/oceans.2006.307110.

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Shemanin, Valery G., Eleonora N. Grishina i Elina I. Voronina. "Raman lidar spectrum reconstruction of methane and deuterium containing methanes mixture". W Lasers for Measurements and Information Transfer 2002, redaktor Vadim E. Privalov. SPIE, 2003. http://dx.doi.org/10.1117/12.501535.

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Hruby, V., J. Kolencik, K. Annen, R. Brown, V. Hruby, J. Kolencik, K. Annen i R. Brown. "Methane arcjet experiments". W 28th Plasmadynamics and Lasers Conference. Reston, Virigina: American Institute of Aeronautics and Astronautics, 1997. http://dx.doi.org/10.2514/6.1997-2427.

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Cocco, Daniele, i Vittorio Tola. "SOFC-MGT Hybrid Power Plants Fuelled by Methane and Methanol". W ASME 8th Biennial Conference on Engineering Systems Design and Analysis. ASMEDC, 2006. http://dx.doi.org/10.1115/esda2006-95482.

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Streszczenie:
In this paper the use of methane and methanol in SOFC-MGT hybrid power plants has been compared. As a matter of fact, SOFC-MGT hybrid plants are a very attractive near term option, as they can allow to achieve efficiencies of over 60–65%, even for small power outputs (200–400 kW). The SOFC systems currently developed are fuelled with natural gas, which is reformed inside the same stack at about 800–900 °C. However, the use of alternative fuels with low reforming temperature (for example, methanol reforms at about 250–300 °C) can lead to enhanced hybrid plant performance. In particular, this paper reports a comparative performance analysis of internally reformed SOFC-MGT power plants fuelled by methane and methanol. Moreover, in the case of methanol use, both internal and external reforming have been compared. The performance analysis has been carried out by considering different values for the most important operating parameters of the fuel cell. The comparative analysis has demonstrated that simply replacing methane with methanol in SOFC-MGT power plants slightly reduces the efficiency. However, the use of methanol in SOFC-MGT power plants with external reforming enhances efficiency significantly (by about 4–5 percentage points). The study shows that the use of methanol with external fuel reforming raises stack efficiency thanks to the improved heat management and to the higher hydrogen partial pressure.
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O'Brien, R. N., i B. D. Turnham. "Methane Solubility and Methane Storage in Suitable Liquid Hydrocarbon Mixtures". W International Congress & Exposition. 400 Commonwealth Drive, Warrendale, PA, United States: SAE International, 1990. http://dx.doi.org/10.4271/900586.

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Park, JongGeol, i SooYoung Park. "Proposal of mep (methane emission presumptuion) method to investigate methane sources". W IGARSS 2016 - 2016 IEEE International Geoscience and Remote Sensing Symposium. IEEE, 2016. http://dx.doi.org/10.1109/igarss.2016.7730068.

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Josui, Kazuya, Tomoo Fujioka, Kazuyoku Tei i Daichi Sugimoto. "Development of extraction tools for methane from methane hydrate using COIL". W Prague -- 2004 DL over. SPIE, 2005. http://dx.doi.org/10.1117/12.611142.

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Brodawka, Brodawka, M. Bałys, J. Szczurowski, L. Czepirski, K. Zarębska i P. Da Costa. "Nanoporous Carbonaceous Adsorbents for Enrichmentof Ventilation Air Methane (VAM) with Methane". W Nanotech France 2019 Conference & Exhibition. SETCOR Conferences and events, 2019. http://dx.doi.org/10.26799/cp-nanotechfrance2019/4.

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Unger, Z., D. LeClair i I. Györfi. "Methane Hydrates as a Tertiary Methane Source in the Transylvanian Basin". W 2019 AAPG Europe Region Regional Conference: Paratethys Petroleum Systems Between Central Europe and the Caspian Region. Tulsa, OK, USA: American Association of Petroleum Geologists, 2019. http://dx.doi.org/10.1306/11307unger2020.

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Raporty organizacyjne na temat "Methane"

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Falconer, J. L., i R. D. Noble. Direct methane conversion to methanol. Office of Scientific and Technical Information (OSTI), grudzień 1992. http://dx.doi.org/10.2172/6744589.

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Noble, R. D., i J. L. Falconer. Direct methane conversion to methanol. Office of Scientific and Technical Information (OSTI), luty 1992. http://dx.doi.org/10.2172/6599498.

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Le Fevre, Chris. Methane Emissions. Oxford Institute for Energy Studies, lipiec 2017. http://dx.doi.org/10.26889/9781784670887.

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Watkins, B. E., R. T. Taylor i J. H. Satcher. Conversion of methane to higher hydrocarbons (Biomimetic catalysis of the conversion of methane to methanol). Final report. Office of Scientific and Technical Information (OSTI), wrzesień 1993. http://dx.doi.org/10.2172/10117847.

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Hornbostel, Marc, i Gopala Krishnan. Containerless Methane Storage. Office of Scientific and Technical Information (OSTI), lipiec 2014. http://dx.doi.org/10.2172/1145408.

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Williams, W., J. Henderson, J. Lawson i A. Droege. methane release LLNL. Office of Scientific and Technical Information (OSTI), październik 2012. http://dx.doi.org/10.2172/1055863.

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Noble, R. D., i J. L. Falconer. Direct methane conversion to methanol. Annual report, October 1993--September 1994. Office of Scientific and Technical Information (OSTI), styczeń 1995. http://dx.doi.org/10.2172/49116.

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Jiang, Yuan, Shuang Xu, Jotheeswari Kothandaraman, Lesley Snowden-Swan, Marye Hefty i Marcella Whitfield. Emerging Technologies Review: Carbon Capture and Conversion to Methane and Methanol. Office of Scientific and Technical Information (OSTI), styczeń 2024. http://dx.doi.org/10.2172/2325005.

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Dan Arthur, Bruce Langhus i Jon Seekins. Coal Bed Methane Primer. Office of Scientific and Technical Information (OSTI), maj 2005. http://dx.doi.org/10.2172/902748.

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George Marcelin. Direct Aromaization of Methane. Office of Scientific and Technical Information (OSTI), styczeń 1997. http://dx.doi.org/10.2172/1217.

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