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1

Sidhaye, D. S. "Studies on synthesis and assembly of metal nanoparticles." Thesis(Ph.D.), CSIR-National Chemical Laboratory, Pune, 2009. http://dspace.ncl.res.in:8080/xmlui/handle/20.500.12252/2779.

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2

So, Man-ho, and 蘇文浩. "Nanochemistry, synthesis, characterization and application studies of metal nanoparticles and metalloporphyrin nanowires." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2010. http://hub.hku.hk/bib/B43703677.

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3

So, Man-ho. "Nanochemistry, synthesis, characterization and application studies of metal nanoparticles and metalloporphyrin nanowires." Click to view the E-thesis via HKUTO, 2010. http://sunzi.lib.hku.hk/hkuto/record/B43703677.

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4

Raffa, Patrizio. "Metal vapour synthesis of stabilized transition metal nanoparticles: characterization, studies on factors affecting particle size and catalytic applications." Doctoral thesis, Scuola Normale Superiore, 2009. http://hdl.handle.net/11384/85791.

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This PhD thesis is focused on the synthesis, characterization and evaluation of catalytic activity of stabilized platinum and gold nanoparticles, generated by use of the metal vaporization technique. Metal vapour synthesis allows to obtain platinum and gold particles with diameters in the range of few nanometers. The introduction of suitable organic molecules at various stage of the synthesis has proven to be useful in order to control the final size of the produced particles. The metal nanoparticles obtained by this new approach are very stable and can be easily handled and characteriz
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5

Meduri, Kavita. "Carbon-Supported Transition Metal Nanoparticles for Catalytic and Electromagnetic Applications." Thesis, Portland State University, 2018. http://pqdtopen.proquest.com/#viewpdf?dispub=10933285.

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<p> Recently, there has been growing interest in using transition metals (TM) for catalytic and electromagnetic applications, due to the ability of TMs to form stable compounds in multiple oxidation states. In this research, the focus has been on the synthesis and characterization of carbon-supported TM nanoparticles (NPs), specifically palladium (Pd) and gold (Au) NPs, for catalytic applications, and transition metal oxides (TMO) NPs, specifically Fe<sub>3</sub>O<sub>4</sub> NPs for electromagnetic applications. Carbon supports have several advantages, such as enabling even distribution of pa
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6

Ray, Priyanka. "Calixarenes and Nanoparticles : Synthesis, Properties and Applications." Thesis, Paris 11, 2013. http://www.theses.fr/2013PA112131.

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Le travail présenté dans ce manuscrit inclut la synthèse organique des différents types de calixarènes, l'étude de leurs propriétés optiques, des simulations théoriques pour déterminer leurs conformations favorables et leurs utilisations pour stabiliser des nanoparticules. Des nanoparticules d’argent, d’or, de platine et des nanoparticules bimétalliques (Ag-Au) ont été synthétisées en utilisant par réduction radiolytique ainsi que la synthèse la photochimique. Ces nanoparticules sont stabilisées en utilisant des calixarènes et divers polymères. Les nanomatériaux ont été caractérisés par spectr
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7

Zimmermann, M., and G. Garnweitner. "Formation Studies on the Nonaqueous Synthesis of Metal Oxide Nanoparticles in a 1.5 L Reactor System." Thesis, Sumy State University, 2012. http://essuir.sumdu.edu.ua/handle/123456789/34891.

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In the last years, the nonaqueous synthesis has been demonstrated as a highly versatile method for the simple synthesis of highly crystalline metal oxide nanoparticles and nanomaterials. Thereby, we have presented the synthesis of a multitude of different metal oxides (e.g., TiO2, ZrO2, BaTiO3, Fe3O4). The mechanisms of particle formation as well as the influence of process parameters on the particle properties however remain largely unknown so far, as the molecular mechanisms are rather complex. In this paper, we show that the synthesis of metal oxide nanoparticles is feasible also on a m
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8

TRASATTI, Andrea. "New heteroscorpionate and macrocyclic ligands, related metal complexes and novel Gold nanoparticles: synthesis, structure analysis and biological studies." Doctoral thesis, Università degli Studi di Camerino, 2013. http://hdl.handle.net/11581/401702.

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The synthesis, the structural and the biological analysis of a series of new macrocyclic, heteroscorpionate ligands and related copper complexes are reported in the first two parts of this PhD thesis. In the third part the study of the internalization processes of new gold nanoparticles in the HeLa cells were showed. In the first part the coordination environment and the stability behavior of the new macrocyclic ligands 1,10-dithia-4,7-diazacyclododecane-3,8-dicarboxylic acid (NEC-SE), 1,10-dithia-4,7-diazacyclotridecane-3,8-dicarboxylic acid (NEC-SP), 1,10-dithia-4,7-diazacyclotetradecane-3,8
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9

Tran, Kristina L. "Synthesis, Characterization, and Self-Assembly of Gold Nanorods and Nanoprisms." Scholar Commons, 2010. http://scholarcommons.usf.edu/etd/3446.

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The unique properties of gold nanoparticles make them excellent candidates for applications in electronics, sensing, imaging, and photothermal therapy. Though abundant literature exists for isotropic gold nanoparticles, work on nanoparticles of different shapes has been gaining interest recently. Anisotropic gold nanoparticles, such as nanorods and nanoprisms, have tunable optical properties in the visible and near-infrared regions. Through synthesis and surface modification, the production of various shapes of these gold nanoparticles can be controlled to meet different applications. Two diff
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10

Weerathunga, Kaluarachchige Don H. "Metal nanoparticle and semiconductor heterogeneous catalysis for synthetic organic oxidation reactions." Thesis, Queensland University of Technology, 2022. https://eprints.qut.edu.au/228677/1/Kaluarachchige%20Don_Weerathunga_Thesis.pdf.

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This thesis investigated new metal nanoparticle and semiconductor catalyst and photocatalyst systems for achieving fine chemical synthesis from both fossil-fuel sourced reactants and biomass carbohydrate-derived reactants. Photocatalysts for industrially important organic oxidation reactions were developed that efficiently worked with the aid of solar light irradiation, at low temperature and pressure, that avoided the use of hazardous chemicals. The effects on the organic reaction mechanisms of different noble metal nanoparticle and metal oxide nanostructures were explored for these chemical
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11

Freeman, David J. "Synthetic and metal binding studies of cyclic peptides." Thesis, University of Nottingham, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.299566.

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12

Cartwright, P. S. "Synthetic and spectroscopic studies of transition metal complexes." Thesis, Bucks New University, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.380302.

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13

Wellington, Kevin Wayne. "Synthetic and analytical studies of biomimetic metal complexes." Thesis, Rhodes University, 2000. http://hdl.handle.net/10962/d1005042.

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Several series of novel diamido, diamino and diimino ligands containing different spacers and heterocyclic donors have been synthesised. The spacers include the flexible biphenyl, the rigid 1,1 O-phenanthroline and various acyclic moieties, while the heterocyclic donors comprise pyridine, imidazole or benzimidazole groups. These ligands have been designed to complex copper and act as biomimetic models of the active site of the enzyme, tyrosinase, and their complexes with copper, cobalt, nickel and platinum have been analysed using microanalytical, IR, UV-Visible and cyclic voltammetric techniq
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14

Namura, Kyoko. "Studies on Photothermal Conversion by Noble Metal Nanoparticles." 京都大学 (Kyoto University), 2015. http://hdl.handle.net/2433/199303.

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15

Jones, Robert Edward. "Synthetic and structural studies on early transition metal siloxides." Thesis, University of Cape Town, 1993. http://hdl.handle.net/11427/23079.

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[Super- and subscripts in abstract] n-Bu3SiOH was prepared from both n-Bu3SiH and n-Bu3SiCI. Reactions of n-Bu3SiOH with NaH, LiBun, MC15 (M = Ta or Mo) and Cp2MCl2 (Cp = 115-C5H5, M = Ti or Zr) were investigated, in some cases using the base Et3N as a hydrogen chloride acceptor. Na+(QSiPh3r was prepared from the reaction of Ph3SiOH with NaH, but in poor yield. Ph3SiOH was reacted with TaCI5, but the product, if formed at all, was intractable. When Ph3SiOH was reacted with Cp2MC12 (M = Ti or Zr) products were isolated and characterised, viz. [Cp2 TiCl(OSiPh3)]n (n = 1 or 2) and Cp2Zr(OSiPh3)2.
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16

Alwaaly, Ahmed Ali Swadi. "Protonation of metal-sulfur complexes : synthetic and mechanistic studies." Thesis, University of Newcastle upon Tyne, 2015. http://hdl.handle.net/10443/2958.

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Nickel and iron are present in certain metalloenzymes (e.g. nitrogenases, hydrogenases and carbon monoxide dehydrogenase) and also in some industrial catalysts (e.g. isomerization and hydrocyanation catalysts) where the substrate transformations also involve reactions with acids. Understanding the protonation of simple nickel and iron complexes is important in establishing the mechanisms of these natural and industrial catalysts, this thesis will focus on kinetic studies of the protonation mechanisms of various nickel and iron complexes. The complexes [Ni(S2CR)(triphos)]BPh4 {R = Me, Et or Bun
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17

Davies, Ian Wain. "Stereochemical and synthetic studies on transition metal-catalysed cyclisations." Thesis, University of Bath, 1992. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.306358.

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18

MUZZI, BEATRICE. "Investigation of synthetic strategies for enhancing the energy product of spinel ferrite nanoparticles." Doctoral thesis, Università di Siena, 2021. http://hdl.handle.net/11365/1126979.

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This work was focused on the development of synthesis strategies for enhancing the energy product of spinel ferrite nanoparticles. The final goal was that of finding the best conditions to realize novel materials with improved magnetic properties, which could be used as building blocks for the realization of rare earth free - permanent magnet with higher energy products than commercial ferrites (i.e. strontium ferrite). To this aim, we focused on quasi-zero-dimensional magnetic materials and as possible strategies to enhance their performances we explored the coupling at the nanoscale with mag
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19

Fogg, Andrew Michael. "Structural, kinetic and synthetic studies of intercalation compounds." Thesis, University of Oxford, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.297906.

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20

Prangige, Erandi Sakunthala Peiris. "Product selectivity control in synthetic organic reactions by metal nanoparticle photocatalysis." Thesis, Queensland University of Technology, 2019. https://eprints.qut.edu.au/132075/1/Erandi_Prangige_Thesis.pdf.

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In this thesis, an in-depth study on alloying effect of non-plasmonic metals with gold nanoparticles to selectively control product formation under light and dark conditions was done. Overall, it was demonstrated that fine tuning the alloying effect could enhance product selectivity switch. This may open up a new research pathway for many important organic syntheses.
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21

McAslan, Ewan Blyth. "Synthetic, structural and spectroscopic studies on some platinum group metal complexes." Thesis, University of Edinburgh, 1986. http://hdl.handle.net/1842/28560.

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22

Westbrook, Georgina. "Synthetic and electrochemical studies of novel transition metal and lanthanide complexes." Thesis, University of Nottingham, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.436811.

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23

Crossley, John Gordon. "Synthetic and structural studies of stacked square planar transition metal complexes." Thesis, University of Bristol, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.317920.

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24

Page, Nicola Alison. "Synthetic and structural studies of transition metal organometallic complexes and polymers." Thesis, University of Cambridge, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.627581.

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25

Nogueira, Helena Isabel Seguro. "Synthetic, spectroscopic and catalytic studies on transition metal complexes with oxygen." Thesis, Imperial College London, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.244195.

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26

Johnston, Karl Anthony Andrew. "Experimental and theoretical studies of transition metal impurities in synthetic diamond." Thesis, University of London, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.392528.

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This thesis is concerned with the properties of transition metals in High Pressure High Temperature synthetic diamond. They have been studied using the following techniques: optical and electron paramagnetic resonance spectroscopies, and a local density approximation code to model various defect centres. Experimental studies of recently-discovered lines, attributed to Co-N complexes in diamond, are presented. Under uniaxial stress, it is found that a zero-phonon line at 2.367 eV has its optical transition from an E- to A_1-ground state at a defect with trigonal symmetry. Another line at 2.135
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27

Nakano, Koji. "Synthetic studies on metal-catalyzed carbonation and carbonylation reactions of epoxides." 京都大学 (Kyoto University), 2005. http://hdl.handle.net/2433/144859.

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Kyoto University (京都大学)<br>0048<br>新制・論文博士<br>博士(工学)<br>乙第11664号<br>論工博第3856号<br>新制||工||1352(附属図書館)<br>23477<br>UT51-2005-D582<br>京都大学大学院工学研究科材料化学専攻<br>(主査)教授 檜山 爲次郎, 教授 大嶌 幸一郎, 教授 中條 善樹<br>学位規則第4条第2項該当
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28

Fluch, Ulrike [Verfasser]. "Noble Metal Nanoparticles and their Application in Electrochemical Studies / Ulrike Fluch." München : Verlag Dr. Hut, 2014. http://d-nb.info/1060587920/34.

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29

Lawlor, Fiona Jayne. "Synthetic and structural studies involving the elements boron, antimony and bismuth." Thesis, University of Newcastle Upon Tyne, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.320603.

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30

Fisher, George Ayrton. "Synthetic and catalytic studies of organo and organo transition metal bismouth compounds." Thesis, University of Newcastle Upon Tyne, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.357646.

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31

Badahdah, Khadija Omer. "Studies of quinone monooximes and of their metal complexes and synthetic applications." Thesis, London Metropolitan University, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.300686.

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32

Moss, I. "Synthetic and spectroscopic studies on transition metal complexes of sulphur-containing ligands." Thesis, University of Exeter, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.374940.

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33

Jones, A. G. "Synthetic, structural and catalytic studies of metal carbonyl clusters of Group VIII." Thesis, University of Southampton, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.374567.

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34

Cook, S. L. "Structural and synthetic studies on homo- and heterogeneous transition metal carbonyl cluster." Thesis, University of Southampton, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.303890.

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35

Angeloni, Alessandro. "Synthetic studies of hydrogen bonding in crystal structures of metal chloride complexes." Thesis, University of Bristol, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.399876.

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36

Williams, I. D. "Structural and synthetic studies of transition metal complexes with unsaturated organic ligands." Thesis, University of Bristol, 1985. http://hdl.handle.net/1983/7447913d-4afc-419a-ac89-d8de8e14c77e.

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37

Li, Zheng. "Structural Studies of Natural and Synthetic Macromolecules Stabilized by Metal Ion Binding." Case Western Reserve University School of Graduate Studies / OhioLINK, 2011. http://rave.ohiolink.edu/etdc/view?acc_num=case1295646060.

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38

Nelson, Janet E. Bercaw John E. Bercaw John E. "Synthetic, structural, and mechanistic studies in early transition metal and actinide chemistry /." Diss., Pasadena, Calif. : California Institute of Technology, 1991. http://resolver.caltech.edu/CaltechETD:etd-07192007-074200.

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39

Machell, Jonathan Charles. "Structural and synthetic studies of compounds containing tin and the noble metals." Thesis, University of Oxford, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.253417.

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40

Hegde, V. R. "Development of homogeneous and heterogeneous transition metal based catalytic organic synthetic methodologies and synthetic studies towards bioactive molecules." Thesis(Ph.D.), CSIR-National Chemical Laboratory, Pune, 1996. http://dspace.ncl.res.in:8080/xmlui/handle/20.500.12252/2910.

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41

Clarkson, Lucy Mary. "Synthetic and structural studies in organotransition metal complexes of gallium, indium and thallium." Thesis, University of Newcastle Upon Tyne, 1991. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.315678.

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42

Poole, Mark Charles. "Synthetic and spectroscopic studies of organic sulphides, sulphoxides, sulphones, and their metal complexes." Thesis, University of Exeter, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.332281.

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43

Che, Lah Nurul Akmal. "Conductivity studies of the size-induced metal-insulator transition (SIMIT) in silver nanoparticles." Thesis, University of Oxford, 2015. https://ora.ox.ac.uk/objects/uuid:a2337bd5-0502-4bc0-a565-971e0fa8f6fc.

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In his tenth decade, Professor Sir Nevill Mott, in a letter to Professor Peter P. Edwards, reminiscenced about the fundamental difference between metals and non-metals; thus he wrote of the situation at the absolute zero of temperature (T = 0 K) '... there a metal conducts, and a non-metal doesn't'. This simple but amazingly powerful commentary stands as a powerful abiding description of the challenge of the fascinating question as to what makes a metal conduct. Many years of experimental studies of metals and nonmetals, targeted at the experimental verification in divided-metal systems rangin
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44

Teng, Die. "Computational studies of transition metal nanoclusters on metal-supported graphene moiré." Diss., Georgia Institute of Technology, 2014. http://hdl.handle.net/1853/51830.

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The graphene moiré superstructure formed on Ru(0001) (g/Ru(0001)) has shown the potential as a template to self-assemble super-lattices of metal nanoparticles as model catalysts. To explore the possibility of rational catalyst design on g/Ru(0001), detailed density functional theory (DFT) calculations have been performed to investigate the adsorption and diffusion of Rh and Au adatoms on g/Ru(0001). The consequences of different hopping rates for cluster nucleation have been explored by performing Monte Carlo-based statistical analysis, which suggests that diffusing species other than adatoms
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45

Wood, Barry Alan. "Synthetic and analytical studies of phytochelations, the metal(loid)-binding peptides of terrestrial plants." Thesis, University of Aberdeen, 2011. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.540437.

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This thesis describes research based around phytochelatins (PCs), plant peptides synthesised during the influx of metal(loid)s such as arsenic.  Development of synthetic strategies for production of PCs and a bromine-based thiol tag were pursued.  The role of PCs in the arsenic translocation system in plants was monitored firstly by statistical analysis, then by monitoring arsenic translocation of <i>L-</i>BSO-poisoned and mutant plants. Whilst protected PC<sub>2</sub> was synthesised in good yield, subsequent isolation of deprotected PC<sub>2</sub> was not achieved via SEC or RP chromatograph
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46

Sumida, Yuto. "Studies on New Synthetic Reactions via sp3C-sp3C Bond Cleavage under Transition Metal Catalysis." 京都大学 (Kyoto University), 2010. http://hdl.handle.net/2433/120875.

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47

Waikar, Smruti. "Metal complexes of oxygen-, nitrogen-, and sulphur-containing macrocyclic ligands : synthetic and structural studies." Thesis, London Metropolitan University, 1992. http://repository.londonmet.ac.uk/3388/.

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It was at the turn of this century, within the area of co-ordination chemistry that the interdependence of structure and reactivity was first realised. The understanding of interactions between metal and ligand has become more complex progressing from simple unidentate to the more complicated multidentate systems and in some instances, ligand designs have imposed unusual co-ordination geometrics around metal atoms. Such offsets are particularly evident in macrocyclic ligands. Their intrinsic properties as ligands gives them the potential to behave as catalysts, semiconductors and sequestering
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48

Carew, Alexander Jon. "Fundamental studies into the catalytic properties of metal-oxide supported gold and copper nanoparticles." Thesis, University of Liverpool, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.367710.

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49

Navas, M. P. "Pulsed laser ablation of composite metal nanoparticles: studies on growth, plasmonic sensing and catalysis." Thesis, IIT Delhi, 2017. http://localhost:8080/iit/handle/2074/7229.

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50

Nouar, Farid. "Design, Synthesis and Post-Synthetic Modifications of Functional Metal-Organic Materials." Scholar Commons, 2010. https://scholarcommons.usf.edu/etd/1725.

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Porous solids are a class of materials of high scientific and technological significance. Indeed, they have the ability to interact with atoms, ions or molecules not only at their surface but also throughout the bulk of the solid. This ability places these materials as a major class involved in many applications such as gas storage and separation, catalysis, drug delivery and sensor technology. Metal-Organic Materials (MOMs) or coordination polymers (CPs) are crystalline compounds constructed from metal ions or clusters and organic components that are linked via coordination bonds to form zero
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