Artykuły w czasopismach na temat „LPG incineration”

The Sustainable Development Goals (SDGs) play an essential role, emphasizing responsible resource use, production, and consumption, including waste management. In addition, SDG 3, 7, 11, 12, and 13 are directly/indirectly related to waste management. This study aims to determine a suitable waste-to-energy (WtE) technology in Chittagong City, Bangladesh, focusing on cleaner technology. Anaerobic digestion, gasification, incineration, and landfill gas (LFG) recovery were considered as possible alternatives. Technical, economic, environmental, and social issues have been considered as necessary criteria for evaluation. An analytical hierarchy process was applied to rank these technologies based on stakeholders’ perceptions. The study found that anaerobic digestion (AD) ranked first, receiving 38% of overall weight. The second preferred technology is LFG (27%). Gasification and incineration stood at third and fourth, respectively (21% and 14%). According to a sensitivity study, the decision is only sensitive to the economy. LFG will become the most favoured solution for WtE conversion if the economy prioritizes more than 38%. Subsequently, this study’s findings will help achieve Bangladesh’s SDG agenda.

Abstract Nowadays in many countries legislation places stringent limits on the dumping of untreated sludge as land fill. One option for handling sludge is incineration. However, log-soaking bottom sludge contains a remarkable amount of sand, which hinders its use as fuel. This gives rise to the need for an appropriate means for separating sand from sludge. A pilot apparatus for the separation of sand from log-soaking bottom sludge was designed. The pilot apparatus consisted of a drum washer and gravity settling. The water consumption of the process was very low. The separation of sand was remarkable and the resulting sludge could be used in grate firing boilers after drying.

Background Anaerobic digestion (AD) is a suitable process for treating high moisture MSW with biogas and biofertilizer production. However, the low stability of AD performance and low methane production results from high moisture MSW due to the fast acidify of carbohydrate fermentation. The effects of organic loading and incineration fly ash addition as a pH adjustment on methane production from high moisture MSW in the single-stage AD and two-stage AD processes were investigated. Results Suitable initial organic loading of the single-stage AD process was 17 gVS L−1 at incineration fly ash (IFA) addition of 0.5% with methane yield of 287 mL CH4 g−1 VS. Suitable initial organic loading of the two-stage AD process was 43 gVS L−1 at IFA addition of 1% with hydrogen and methane yield of 47.4 ml H2 g−1 VS and 363 mL CH4 g−1 VS, respectively. The highest hydrogen and methane production of 8.7 m3 H2 ton−1 of high moisture MSW and 66.6 m3 CH4 ton−1 of high moisture MSW was achieved at organic loading of 43 gVS L−1 at IFA addition of 1% by two-stage AD process. Biogas production by the two-stage AD process enabled 18.5% higher energy recovery than single-stage AD. The 1% addition of IFA into high moisture MSW was useful for controlling pH of the two-stage AD process with enhanced biogas production between 87–92% when compared to without IFA addition. Electricity production and energy recovery from MSW using the coupled incineration with biogas production by two-stage AD process were 9,874 MJ ton−1 MSW and 89%, respectively. Conclusions The two-stage AD process with IFA addition for pH adjustment could improve biogas production from high moisture MSW, as well as reduce lag phase and enhance biodegradability efficiency. The coupled incineration process with biogas production using the two-stage AD process was suitable for the management of MSW with low area requirement, low greenhouse gas emissions, and high energy recovery.

Increased generation of methane (CH4) from municipal solid wastes (MSW) alarms the world to take proper initiative for the sustainable management of MSW, because it is 34 times stronger than carbon dioxide (CO2). Mounting land scarcity issue around the world brands the waste to energy (WtE) strategy for MSW management in urban areas as a promising option, because WtE not only reduces the land pressure problem, but also generates electricity, heat, and green jobs. The goal of this study is to evaluate the renewable electricity generation potential and associated carbon reduction of MSW management in Bangladesh using WtE strategies. The study is conducted in two major cities of Bangladesh: Dhaka and Chittagong. Six different WtE scenarios are evaluated consisting of mixed MSW incineration and landfill gas (LFG) recovery system. Energy potential of different WtE strategy is assessed using standard energy conversion model and subsequent GHGs emissions models. Scenario A1results in highest economic and energy potential and net negative GHGs emission. Sensitivity analysis by varying MSW moisture content reveals higher energy potential and less GHGs emissions from MSW possessing low moisture content. The study proposes mixed MSW incineration that could be a potential WtE strategy for renewable electricity generation in Bangladesh.

As Malaysia is a fast-developing country, its prospects of sustainable energy generation are at the center of debate. Malaysian municipal solid waste (MSW) is projected to have a 3.3% increase in annual generation rate at the same time an increase of 3.3% for electricity demand. In Malaysia, most of the landfills are open dumpsite and 89% of the collected MSW end up in landfills. Furthermore, huge attention is being focused on converting MSW into energy due to the enormous amount of daily MSW being generated. Sanitary landfill to capture methane from waste landfill gas (LFG) and incineration in a combined heat and power plant (CHP) are common MSW-to-energy technologies in Malaysia. MSW in Malaysia contains 45% organic fraction thus landfill contributes as a potential LFG source. Waste-to-energy (WTE) technologies in treating MSW potentially provide an attractive economic investment since its feedstock (MSW) is collected almost for free. At present, there are considerable issues in WTE technologies although the technology employing MSW as feedstock are well established, for instance the fluctuation of MSW composition and the complexity in treatment facilities with its pollutant emissions. Thus, this study discusses various WTE technologies in Malaysia by considering the energy potentials from all existing incineration plants and landfill sites as an effective MSW management in Malaysia. Furthermore, to promote local innovation and technology development and to ensure successful long-term sustainable economic viability, social inclusiveness, and environmental sustainability in Malaysia, the four faculties of sustainable development namely technical, economic, environmental, and social issues affiliated with MSW-to-Energy technologies were compared and evaluated.

The Government of Canada has ratified the Kyoto Protocol, committing to a 6% reduction in greenhouse gas (GHG) emissions from 1990 levels during the commitment period of 2008–2012. To attain this target, emission reductions throughout many sectors must be achieved. The waste sector can assist Canada in reducing GHG emissions to meet its commitments under the Kyoto Protocol. In 2001, the waste sector generated 24.8 megatonnes (Mt) of carbon dioxide equivalent (CO2e) from landfill gas (LFG) generation, wastewater treatment, and incineration. Emissions from the transportation of solid waste were not considered, and are seen to be small. Several strategies for reducing GHG emissions from solid waste are analyzed. Source reduction decreases the amount of material being generated, thus reducing from the source any emissions that might be related to the life cycle of the material. Recycling can reduce GHG emissions by reducing the amount of virgin material being processed, avoiding life cycle emissions. Landfill gas collection for energy recovery can reduce methane (CH4) emissions from organic wastes in landfills, and the Government of Canada's Climate Change Plan has considered this strategy. Anaerobic digestion converts some of the organic matter in the municipal solid waste (MSW) to both CH4 and carbon dioxide (CO2), where the CH4 can be used to generate power, while composting converts some of the organic fraction to CO2. Both of these processes produce a soil conditioner as their residue. Waste incineration reduces MSW volume and can generate power, displacing generation from fossil fuels. An integrated approach, considering these techniques where appropriate, can succeed in reducing emissions from the solid waste sector. Policy choices such as extended producer responsibility, minimum recycled content laws, and LFG capture criteria would increase the impact of solid waste management on GHG emissions. Key words: climate change, Kyoto Protocol, municipal solid waste, source reduction, recycling, landfill gas capture, anaerobic digestion.

Chlorinated polycyclic aromatic hydrocarbons (ClPAHs) are a group of halogenated contaminants found in the urban environment with a toxic potential similar to dioxins. Little is well-known on the distribution and characteristics of ClPAHs on urban surfaces. In this study, concentrations of 20 ClPAH congeners were measured in road dust and soil from crossroads along arterial traffic, park and lake areas, a chemical industrial complex, waste incineration power plants nearby, and a steel factory in Shanghai. ClPAHs are ubiquitous and log-normally distribute in urban surface with a range from 0.27 to 206 ng/g dw for dust, and with a range from 0.05 to 94.3 ng/g dw for soils. The highest mean concentration of total 20 ClPAHs is found in floor dust from a steel factory. ClPyr and ClPhe are predominant in road dust, which infers that ClPAHs detected in the urban surface dust samples originate from vehicle exhaust.

Agricultural application of municipal sewage sludge has been emotionally discussed in the last decades, because the latter contains endocrine disrupting chemicals (EDCs) and other organic micro-pollutants with unknown fate and risk potential. Bisphenol A (BPA) was chosen as a model substance to investigate the influence of sludge conditioning on the end-concentration of EDCs in sludge. Adsorption studies with radioactive-labelled BPA showed that more than 75% BPA in anaerobically digested sludge is bound to solids (log Kd = 2.09-2.30; log Koc = 2.72-3.11). Sludge conditioning with polymer or iron (III) chloride alone had no influence on the adsorption of BPA. After conditioning with iron (III) chloride and calcium hydroxide desorption of BPA took place. Apparently, it occurred due to the deprotonation of BPA (pKa = 10.3) as the pH-value reached 12.4 during the process. The same behaviour is expected for other phenolic EDCs with similar pKa (nonylphenol, 17β-estradiol, estron, estriol, 17α-ethinylestradiol). This study shows high affinity of BPA to the anaerobically digested sludge and importance of conditioning in the elimination of EDCs during the sludge treatment. Addition of polymer is favourable in the case of sludge incineration. Conditioning with iron (III) chloride and calcium hydroxide shows advantages for the use of sludge as fertiliser.

Antarctic buildings are enclosed structures, which provide shelter and logistic support to researchers and personnel who remain indoors for long periods and can be affected by air pollution caused by construction materials and activities inside buildings. This study aims to investigate the indoor air quality at the Brazilian Comandante Ferraz Antarctic Station based on measurements of aldehydes, particulate matter and fungi conducted during the Antarctic summer in 2012. The sampling site was divided in conditioned (personnel living quarters) and unconditioned (service and utilities areas) compartments and outdoor sites. A field log book was used to record the activities in the station. Furniture and plywood coverings may have contributed to high average concentrations of formaldehyde. Cooking resulted in high average levels of acrolein and fine particles in most of the monitored environments. Other activities such as cleaning, use of personal and cosmetic products, waste incineration, building maintenance and movement of people and vehicles have also contributed to particles concentration increase. Dominance of the species Aspergillus versicolor and Penicillium sp. showed potential means of fungal proliferation. Considering that the functionality and operation are similar in many Antarctic buildings, some general recommendations were outlined.

Abstract Landfilling is a dominant method of waste management in most developing countries. Moreover, a significant quantity of waste has been disposed on open dumps and unmanaged disposal sites. Landfill gas (LFG) can be considerable source of GHG emissions, as it consists of 50 % methane and 50 % carbon dioxide. Republic of Serbia is a developing country. Its waste management legislation is based on EU legislation. In the first decade of 2000s a set of laws was passed in this area. Unfortunately, the majority of goals were not fulfilled. An updated version of Waste management program is active since 2022. In Serbia, 2.95 million tons of waste is generated every year. It is estimated that 15-20 % is disposed on dumps, while 80 % is collected and disposed on the landfills. Waste treatment does not exist. Recycling rate is a very low, around 15%. Different waste management scenarios of impact on GHG emissions have been analysed. The analysis was performed using the software “Tool for Calculating Greenhouse Gases (GHG) in Solid Waste Management (SWM-GHG calculator)” developed by the German IFEU (ger. Institut für Energie- und Umweltforschung Heidelberg). The base scenario describes the current situation. Scenarios 1 and 2 describe goals set for 2025 and 2030 by Waste management program in the Republic of Serbia for the period 2022 - 2031. Scenario 3 describes best case scenario, with fully functional modern waste management system. The analysis includes several parameters, such as landfill type, recycling rate, LFG collection efficiency and use of waste incineration technology.

Polychlorinated dibenzo-p-dioxin and polychlorinated dibenzofuran (PCDD/F) emission characteristics and vapour/particulate phase partitions under three continued operation conditions, i.e. shut-down, start-up and after start-up, were investigated by sampling stack gas. The results indicated that the PCDD/F emission levels were 0.40–18.03 ng I-TEQ Nm −3 , much higher than the annual monitoring level (0.016 ng I-TEQ Nm −3 ). Additionally, the PCDD/F emission levels in start-up were higher than the other two conditions. Furthermore, the PCDD/F congener profiles differed markedly between shut-down and start-up, and the chlorination degree of PCDD/F increased in shut-down and decreased evidently in start-up. Moreover, PCDD/F vapour/particulate phase distributions varied significantly under three transient conditions. The PCDD/F vapour phase proportion decreased as the shut-down process continued, then increased as the start-up process proceeded, finally more than 98% of the PCDD/F congeners were distributed in the vapour phase after start-up. The correlations between log( C v / C s ) versus log p L 0 of each PCDD/F congener in stack gas were disorganized in shut-down, and trend to a linear distribution after start-up. Besides, polychlorinated biphenyl emissions show behaviour similar to that of PCDD/F, and the lower chlorinated congeners have a stronger relationship with 2,3,7,8-PCDD/Fs, such as M1CB and D2CB.

Deoxynivalenol (DON) is one of the most abundant and important trichothecene mycotoxins produced by Fusarium species. In chickens, DON intake causes feed refusal, impairs performance, gut barrier function, and immunity, and raises oxidative stress. To determine the effect of DON on bone mineralization and serum calcium and phosphorus, 80 newly-hatched chickens were fed 4 diets with 0, 2.5, 5, and 10 mg DON/kg feed in this pilot study. In week 5, chickens were euthanized, femur and tibiotarsus bones were separated from the meat, and after incineration ash composition, as well as serum calcium and phosphorus, were determined using clinical biochemistry. Dietary DON reduced chicken dry matter, calcium, and phosphorus intake, and subsequently body and leg weight. DON affected bone density and composition of the tibiotarsus more drastically than of the femur. However, lower mineral intake did not solely explain our observations of the quadratically lower tibiotarsus density and ash content, as well as linearly decreased Ca content in the femur and tibiotarsus with increasing DON levels. Linearly decreasing serum phosphorus concentrations with increasing DON levels further supported impaired mineral homeostasis due to DON. In conclusion, already low dietary DON contamination of 2.5 mg/kg feed can compromise bone mineralization in chickens.

Telah dilakukan penelitian mengenai analisis perpindahan panas pada water jacket di ruang bakar primer incinerator sampah kota. Analisis perpindahan panas dilakukan ketika water jacket berada dari fase cair hingga mencapai titik didihnya, yaitu 100 oC, Suhu api pembakaran diasumsikan seragam berdasarkan hasil pengukuran api ruang bakar diperoleh nilai stabil yakni 1097 oC. Variasi debit aliran water jacket adalah 300, 400, 500, dan 600 liter/jam. Tujuan penelitian ini adalah untuk mengetahui bagaimana kenaikan suhu dan karakteristik perpindahan panas pada water jacket dan pengaruh variasi debit terhadap kenaikan suhu water jacket di sepanjang ketinggian dinding ruang bakar. Penelitian dilakukan dengan melakukan perhitungan parameter termohidrolika yang merupakan fungsi suhu yang meliputi densitas, viskositas, konduktivitas, dan bilangan Prandtl. Kemudian, dilanjutkan dengan melakukan perhitungan bilangan Reynolds, Nusselt, koefisien perpindahan panas konveksi, Log Mean Temperature Difference (LMTD), resistensi termal total, dan laju perpindahan panas di sepanjang tinggi cerobong (L) sampai suhu air mencapai 100 oC. Perhitungan tersebut dilakukan dengan metode Euler. Dari hasil perhitungan perpindahan panas diketahui bahwa suhu water jacket di sepanjang ketinggian dinding ruang bakar mengalami kenaikan hingga mencapai titik didihnya. Akan tetapi, ketika aliran water jacket semakin mencapai ke atas, gradien kenaikan suhunya mengalami penurunan nilai. Dengan demikian, laju perpindahan panasnya juga ikut mengalami penurunan. Dari variasi debit diperoleh hasil bahwa semakin besar debit aliran water jacket, kenaikan suhu yang dialami water jacket di sepanjang ketinggian ruang bakar juga semakin kecil. Dengan demikian semakin besar debit aliran water jacket, lintasan yang dibutuhkan untuk mencapai titik didihnya juga semakin panjang. Semakin besar debit aliran water jacket, maka laju perpindahan panas di posisi aliran yang sama juga semakin besar.

Halogenated aromatic industrial compounds, typified by the polychlorinated dibenzo-p-dioxins (PCDDs), dibenzofurans (PCDFs) and biphenyls (PCBs) have been identified as residues in almost every component of the global ecosystem. Risk assessment of the complex mixtures of halogenated aromatics found in envi ronmental samples is complicated by analytical problems and the lack of toxicological information on individual compounds and mixtures. Research in our laboratory has focused on the develop ment and vadidation of the in vitro aryl hydrocarbon hydroxylase (AHH) induction assay in rat hepatoma H-4-II E cells in culture for quantitating individual toxic halogenated aryl hydrocarbons and their mixtures. For several PCB, PCDD, PCDF congeners, their mixed bromo/chloro analogs and reconstituted mixtures there was an excellent linear correlation between their -log ED50 values for AHH induction in rat hepatoma cells and their -log ED50 values for in vivo hepatic microsomal AHH induction, inhibi tion of body weight gain and thymic atrophy in the rat. It has also been shown for selected compounds that there was a good correla tion between their in vitro AHH induction potencies and their effects in guinea pigs (AHH induction, inhibition of body weight gain) and mice (immunotoxicity). This assay system has been uti lized to quantitate the "2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) equivalents "present in extracts from diverse sources including fly ash from a municipal incinerator and pyrolyzed brom inated flame retardants which contain a complex mixture of halo genated dibenzo-p-dioxins and dibenzofurans.

The Ulex europaeus (also known as Common Gorse) represents a threat to the native ecosystems of different Colombian regions. Recently, the Ministry of the Environment and Sustainable Development introduced protocols for its prevention and management. Even though the Ulex europaeus has a high calorific value, a wide-spread solution for its post-processing is not yet available in its affected areas. In Colombia, the most common method for the disposal of the harvested plant is incineration, given that this is the suggested method by Resolution 684 of 2018. Due to the importance of the problem, this investigation is focused on studying the viability of creating solid biofuel alternatives derived from the plant. Grinded material and briquettes were produced with different log/foliage ratios in order to investigate both the domestic and industrial applications of the plant; e.g. heating, cooking and cogeneration, respectively. A proximate and ultimate analysis was performed on the produced samples. The generated solid biofuel presents 75% of the carbon heat value, a high volatile material content (83.3%), and low ash and Sulphur residues (1.41% and 0.15% respectively). These results applied to both dry and humid samples, demonstrated that the produced solid biofuel is adequate for applications oriented towards heat generation. However, further analysis and process optimization is required in order to establish the generation of solid biofuel as an appropriate use of the Ulex europaeus remnants. By further analyzing the overall process; from plant removal, through residue disposal, and finally remnant conversion, the investigations value chain can be better established and possibly established for real world implementation.

Municipal solid waste (MSW) management has become a major concern for developing countries. The physical and chemical aspects of MSW management and infrastructure need to be analyzed critically to solve the existing socio-economic problem. Currently, MSW production is 2.01 billion tonnes/yr. In developing countries, improper management of MSW poses serious environmental and public health risks. Depending on the socio-economic framework of a country, several MSW management procedures have been established, including landfilling, thermal treatment, and chemical treatment. Most of the MSW produced in underdeveloped and developing countries such as Bangladesh, India, and Pakistan is dumped into open landfills, severely affecting the environment. Waste-to-Energy (WTE) projects based on thermal treatments, e.g., incineration, pyrolysis, and gasification, can be feasible alternatives to conventional technologies. This research has explored a comprehensive method to evaluate MSW characteristics and management strategies from a global and Bangladesh perspective. The benefits, challenges, economic analysis, and comparison of MSW-based WTE projects have been analyzed concisely. Implementing the WTE project in developing countries can reduce unsupervised landfill and greenhouse gas (GHG) emissions. Alternative solutions and innovations have been discussed to overcome the high capital costs and infrastructural deficiencies. By 2050, Bangladesh can establish a total revenue (electricity sales and carbon credit revenue) of USD 751 million per year in Dhaka and Chittagong only. The landfill gas (LFG) recovery, waste recycling. and pyrolysis for energy production, syngas generation, and metal recovery are possible future directions of MSW management. The MSW management scenario in developing countries can be upgraded by improving waste treatment policies and working with government, academicians, and environmentalists together.

In epidemiological studies, both spatial and temporal variations in nitrogen dioxide (NO2) are a robust predictor of health risks. Compared to particulate matter, the experimental evidence for harmful effects at typical ambient concentrations is less extensive and not as clear for NO2. In the wake of the “Diesel emission scandal—Dieselgate”, the scientific basis of current limit values for ambient NO2 concentrations was attacked by industry lobbyists. It was argued that associations between NO2 levels and medical endpoints were not causal, as NO2 in older studies served as a proxy for aggressive particulate matter from incineration processes. With the introduction of particle filters in diesel cars, NO2 would have lost its meaning as a health indicator. Austria has a high percentage of diesel-powered cars (56%). If, indeed, associations between NO2 concentrations and health risks in previous studies were only due to older engines without a particle filter, we should expect a reduction in effect estimates over time as an increasing number of diesel cars on the roads were outfitted with particle filters. In previous time series studies from Vienna over shorter time intervals, we have demonstrated distributed lag effects over days up to two weeks and previous day effects of NO2 on total mortality. In a simplified model, we now assess the effect estimates for moving 5-year periods from the beginning of NO2 monitoring in Vienna (1987) until the year 2018 of same and previous day NO2 on total daily mortality. Contrary to industry claims of a spurious, no longer valid indicator function of NO2, effect estimates remained fairly stable, indicating an increase in total mortality of previous day NO2 by 0.52% (95% CI: 0.35–0.7%) per 10 µg/m3 change in NO2 concentration.

PT. XYZ is engaged in manufacturing in making aluminum profile products during the last one year period. XYZ company did not reach its production target by an average of 6.24%. As for the reasons why the production target did not reach the target, one of them was due to the high downtime of the extrusion machine 2500 which exceeded the company standard, namely 7800 minutes per year, the downtime of the extrusion machine 2500 in the last year was 9807 minutes. The purpose of this study is to reduce the downtime value of the extrusion machine using the OEE method (overall equipment effectiveness), to increase the productivity of the extrusion machine 2500 from the results of the analysis of six big losses and identify the main causes of downtime of the extrusion 2500 machine. The results show that the OEE value of the extrusion machine. 2500 by 45. 61% where this value is still below the ideal OEE average standard, namely 85%. The main cause of downtime is due to seven factors that dominate the causes of downtime, namely log heater 2230 minutes with 11 events, puller 1740 minutes with 11 events, dummi block 1390 with 4 events, loader 710 minutes with 4 events, finish cut 540 minutes with 3 events, stem 450 minutes with 2 events, 360 minutes table with 1 event. Based on the results of the calculation of six big losses, the results of downtime values: equipment failure losses 3,81%, setup and adjustment losses 3,95%, speed losses: idle and minor stoppage 3,03%, reduced speed losses 46,51, quality losses: defect losses 0,13%, reduced yield 0 %. The recommendation for improvement is to conduct special training, give warnings to operators who are not disciplined. Reference: Ahuja, I. P. S., Khamba, J. S. (2008). Total Productive Maintenance Literature Review and Directions. International Journal of Quality and Reliability Management, 25 (7), 709-756. Atmaja, L. T., Supriyadi, E., & Utaminingsih, S. (2018). Analisis Efektivitas Mesin Pressing Ph-1400 Dengan Metode Overall Equipment Effectiveness ( Oee ) Di Pt . Surya Siam Keramik. 1. Anggraini, M., Widya, M. W., Edy, K. F. B. (2017). Implementasi Metode Overall Equipment Effectiveness Dalam Menentukan Produktivitas Mesin Rotary Car Dumper. Seminar dan Konferensi Nasional IDEC 2017, 1 (1), 78-87. Hadi, S. (2019). Perawatan Dan Perbaikan Mesin Industri. Yogyakarta: Andi. Hamdy, I. M., Azizi, A. (2017). Analisis Nilai Overall Equipment Effectiveness (OEE) Pada Mesin Ripple Mill. Jurnal Hasil Penelitian dan Karya Ilmiah Dalam Bidang Industri, 3 (1), 53-58. Hamid, A., & Purnomo, S. A. (2018). Analisa Efektivitas Kinerja Mesin Turning Star SB-16 Dengan Metode Total Productive Maintenance ( TPM ) di PT Mitsuba Indonesia Dosen Teknik Industri Universitas Pamulang. Jitmi, 1 (1), 50 - 63. Hazmi, M. F., Juniani, A. I., Budiyantoro, E. N. (2017). Analisis Perhitungan OEE Dan Six Big Losses Terhadap Produktivitas Mesin Bottomer Line 4 PT. IKSG Tuban. Jurnal Conference on Safety Engineering and Application, 1 (1), 161-166. Heru, W., Ferdiansyah, F. (2018). Analisis Efektifitas Mesin Roughing Mill dengan Metode Overall Equipment Effectiveness (OEE). Jurnal Industri Manufacturing, 3 (2), 67-78. Jannah, R. M., Supriyadi., Nalhadi, A. (2017). Analisis Efektivitas Pada Mesin Centrifugal Dengan Menggunakan Metode Overall Equipment Effectiveness (OEE). Seminar Nasional Riset Terapan, 1 (1), 170-175. Karismawan, F. (2015). Pengukuran Kinerja Mesin Perusahaan Menggunakan Overall Equipment Effectiveness dan Usulan Perbaikan Menggunakan Diagram Sebab Akibat (Fish Bone) Pada CV. Jati Makmur Pasuruan. Jurnal Manajemen Teori dan Terapan, 1 (2), 107-115. Kholil, M., Maulidina, A. D., Rimawan, E. (2016).Analisa Total Productive Maintenance Terhadap Produktivitas Kapal Armada Menggunakan Metode Overall Equipment Effectiveness pada PT. Global Trans Energy International. Jurnal of Industrial Engineering and Management Systems, 9 (1), 1-18. Kholisdiantoro, S. (2016). Usulan Perbaikan Untuk Peningkatan Efektivitas Kinerja Mesin Crusher di Incinerator 2 Dengan Metode Overall Equipment Effectiveness. Teknik Industri. Universitas Bhayangkara Jakarta Raya. Rahmadhani, D. F., Taroepratjeka, H., & Fitria, L. (2014). Usulan Peningkatan Efektivitas Mesin Cetak Manual Menggunakan Metode Overall Equipment Effectiveness (OEE) (Studi Kasus Di Perusahaan Kerupuk TTN). Jurnal Online Institut Teknologi Nasional, 2 (4), 156 –165. Soemohadiwidjojo, A. T. (2017). Six Sigma metode pengukuran kinerja perusahaan berbasis statistik. Jakarta: Raih asa sukses (RAS). Suwardiyanto, P., Siregar, D., Umar, D. (2020). Analisis Perhitungan OEE dan Menentukan Six Big Losses pada Mesin Spot Welding Tipe X. Journal of Industrial and Engineering Sistem, 1 (1), 11-20.

Pentachlorophenol is used as an industrial wood preservative for utility poles, crossarms, fence posts, and other purposes (79%);for NaPCP (12%); and miscellaneous, including mill uses, consumer wood preserving formulations and herbicide intermediate (9%) (CMR, 1980). As a wood preservative, pentachlorophenol acts as both a fungicide and insecticide (Freiter, 1978). The miscellaneous mill uses primarily involve the application of pentachlorophenol as a slime reducer in paper and pulp milling and may constitute ∼6% of the total annual consumption of pentachlorophenol (Crosby et al., 1981). Sodium pentachlorophenate (NaPCP) is also used as an antifungal and antibacterial agent (Freiter, 1978). Pentachlorophenol also is used as a general herbicide (Martin and Worthing, 1977). Photolysis and microbial degradation are the important chemical removal mechanisms for pentachlorophenol in water. In surface waters, pentachlorophenol photolyzes rapidly (ECETOC, 1984; Wong and Crosby. 1981; Zepp et al., 1984); however, the photolytic rate decreases as the depth in water increases (Pignatello et al., 1983). Pentachlorophenol is readily biodegradable in the presence of accli-mated microorganisms; however, biodegradation in natural waters requires the presence of microbes that can become acclimated. A natural river water that had been receiving domestic and industrial effluents significantly biodegraded pentachlorophenol after a 15-day lag period, while an unpolluted natural river water was unable to biodegrade the compound (Banerjee et al., 1984). Even though pentachlorophenol is in ionized form in natural waters, sorption to organic particulate matter and sediments can occur (Schellenberg et al., 1984), with desorption contributing as a continuing source of pollution in a contaminated environment (Pierce and Victor, 1978). Experimentally determined BCFs have shown that pentachlorophenol can significantly accumulate in aquatic organisms (Gluth et al., 1985; Butte et al., 1985; Statham et al., 1976; Veith et al., 1979a,b; Ernst and Weber, 1978), which is consistent with its widespread detection in fish and other organisms. Direct photolysis may be an important environmental sink for pen tachlorophenol present in the atmosphere. The detection of pen tachlorophenol in snow and rain water (Paasivirta et al., 1985; Bevenue et al., 1972) suggests that removal from air by dissolution is possible. Soil degradation studies indicate that pentachlorophenol is biodegrad able; microbial decomposition is an important and potentially domin ant removal mechanism in soil (Baker et al., 1980; Baker and Mayfield, 1980; Edgehill and Finn, 1983; Kirsch and Etzel, 1973; Ahlborg and Thunberg, 1980). The degree to which pentachlorophenol leaches in soil is dependent on the type of soil. In soils of neutral pH, leaching may be significant, but in acidic soils, adsorption to soil generally increases (Callahan et al. , 1979; Sanborn et al. , 1977). The ionized form of pentachlorophenol may be susceptible to adsorption in some soils (Schellenberg et al., 1984). In laboratory soils, pen tachlorophenol decomposes faster in soils of high organic content as compared with low organic content, and faster when moisture content is high and the temperature is conducive to microbial activity. Half- lives are usually ∼2-4 weeks (Crosby et al., 1981). Monitoring studies have confirmed the widespread occurrence of pentachlorophenol in surface waters, groundwater, drinking water and industrial effluents (see Table 2). The U.S. EPA's National Urban Runoff Program and National Organic Monitoring Survey reported frequent detections in storm water runoff and public water supplies (Cole et al., 1984; Mello, 1978). Primary sources by which pen tachlorophenol may be emitted to environmental waters may be through its use in wood preservation and the associated effluents and its pesticidal applications. Pentachlorophenol can be emitted to the atmosphere by evaporation from treated wood or water surfaces, by releases from cooling towers using pentachlorophenol biocides or by incineration of treated wood (Skow et al., 1980; Crosby et al., 1981). Pentachlorophenol has been detected in ambient atmospheres (Caut reels et al., 1977), in snow and rain water (Paasivirta et al,. 1985; Bevenue et al., 1972) and in emissions from hazardous waste incinera tion (Oberg et al., 1985). The U.S. Food and Drug Administration's Total Diet Study (conducted between 1964 and 1977) found pen tachlorophenol residues in 91/4428 ready-to-eat food composites (See Tables 4 and 5). The average American dietary intake of pen tachlorophenol during 1965-1969 was estimated to range from <0.001-0.006 mg/day (Duggan and Corneliussen, 1972). The most likely source of pentachlorophenol contamination in many food prod ucts may be the exposure of the food to pentachlorophenol-treated wood materials such as storage containers (Dougherty, 1978). Acute toxicity data indicated that salmonids are more sensitive to the toxic effects of pentachlorophenol than other fish species, with LC50 values of 34-128 μ g/l for salmonids and 60-600 μ g/l for other species. More recent data showed that carp larvae, bluegills, channel catfish and knifefish also had LC50 values < 100 μ gl (see Table 10). The most sensitive marine fishes were pinfish larvae, the goby, Gobius minutus, and eggs and larvae of the flounder, Pleuronectes platessa, all with LC50 values <100 μ g/l (Adema and Vink, 1981). The most sensitive freshwater invertebrate species were the chironomid, Chironomus gr. thummi (Slooff, 1983) and the snail, Lymnaea luteola (Gupta et al., 1984). The most sensitive marine invertebrates were the Eastern oyster (Borthwick and Schimmel, 1978), larvae of the crusta ceans, Crangon crangon and Palaemon elegans (VanDijk et al. , 1977), and the copepod, Pseudodiaptomus coronatus (Hauch et al., 1980), all with LC50 values <200 μ g/l. In chronic toxicity tests, the lowest concentration reported to cause adverse effects was 1.8 μ g/l (NaPCP), which inhibited growth of sockeye salmon (Webb and Brett, 1973). The marine species tested displayed similar thresholds for chronic toxicity. Both acute and chronic toxicity increased at lower pH, probably because a lower pH favors the un-ionized form of pentachlorophenol, which is taken up more readily and is therefore more toxic than ionized pentachlorophenol (Kobayashi and Kishino, 1980; Spehar et al., 1985). Data concerning the effects of pentachlorophenol on aquatic plants were highly variable. Therefore, it was difficult to draw conclusions from these data. Pentachlorophenol did not appear to bioaccumulate in aquatic or ganisms to very high concentrations. BCFs for pentachlorophenol were <1000 for most species tested. The highest BCF was 3830 for the polychaete, Lanice conchilega (Ernst, 1979). Some species appear to have an inducible pentachlorophenol-detoxification mechanism, as evidenced in several experiments in which pentachlorophenol tissue levels peaked in 4-8 days and declined thereafter despite continued exposure (Pruitt et al., 1977; Trujillo et al., 1982). A study by Niimi and Cho (1983) indicated that uptake of waterborne pentachlorophenol from gills was much greater than uptake from food, indicating that bioconcentration of pentachlorophenol through the food chain is unlikely. Biomonitoring data of Lake Ontario fishes showed that similar pentachlorophenol levels were found in predators andforage species. Studies with experimental ecosystems have indicated that ecological effects may occur at pentachlorophenol levels as low as those causing chronic toxicity in sensitive species in single-species tests. The lowest concentration that caused adverse effects in these studies was 15.8 μ g/l, which caused a reduction in numbers of individuals and species in a marine benthic community (Tagatz et al., 1978). Pentachlorophenol is readily absorbed from the gastrointestinal tract of rats, mice, monkeys and humans (Braun et al. , 1977, 1978; Ahlborg et al., 1974; Braun and Sauerhoff, 1976). Peak plasma concentrations are reached within 12-24 hours after oral administration to monkeys (Braun and Sauerhoff, 1976), but 4-6 hours after oral administration to rats (Braun et al., 1977). After oral administration, the highest concentration of radioactivity was found in the liver and gastrointesti nal tract of monkeys (Braun et al., 1977). In rats and mice, tet rachlorohydroquinone was identified in the urine (Jakobson and Yllner, 1971; Braun et al., 1977; Ahlborg et al., 1974) as well as unmetabolized pentachlorophenol and glucuronide-conjugated pen tachlorophenol. Although Ahlborg et al. (1974) reported that oxidative dechlorination of pentachlorophenol occurs in humans, as evidenced by the presence of tetrachlorohydroquinone in the urine of workers occupationally exposed (probably by inhalation), analysis of human urine after ingestion of pentachlorophenol revealed the presence of conjugated pentachlorophenol and unmetabolized pentachlorophenol (Braun et al., 1978). The primary route of excretion after oral administrtation of all species studied is in the urine (Braun et al. , 1977, 1978; Ahlborg et al., 1974; Larsen et al., 1972; Braun and Sauerhoff, 1976). Although urinary excretion followed second-order kinetics in rats (Larsen et al., 1972; Braun et al., 1977) except in females receiving a single high dose (100 mg/kg) of pentachlorophenol, urinary excretion of pentachlorophenol in humans and monkeys followed first-order kinetics (Braun and Sauerhoff, 1976; Braun et al., 1978). Enterohepatic circulation played an importation role in the pharmacokinetics of pen tachlorophenol. The half-life of pentachlorophenol in the plasma is longer in female rats and monkeys than it is in male rats and monkeys (Braun et al. , 1978; Braun and Sauerhoff, 1976). Because many preparations of pentachlorophenol are contaminated with small but measurable amounts of highly toxic substances, such as dibenzodioxins, special attention must be paid to the composition of the pentachlorophenol solution tested. In studies where technical and purified pentachlorophenol have been evaluated (Schwetz et al., 1974; Goldstein et al., 1977; Kimbrough and Linder, 1978; Knudsen et al., 1974; Johnson et al., 1973; Kerkvliet et al., 1982), only the results of the experiments using purified pentachlorophenol were reported in detail. Oral exposure to pentachlorophenol was not carcinogenic in mice (BRL, 1968; Innes et al., 1969) or rats (Schwetz et al., 1977), regardless of the composition of the pentachlorophenol solution tested. Although there are a few studies that suggest pentachlorophenol may be mutagenic in B. subtilis (Waters et al., 1982; Shirasu, 1976), in yeast, Saccharomyces cerevisiae (Fahrig et al., 1977) and in mice, as evidenced by the coat-color spot test (Fahrig et al., 1977), no evidence of mutagenicity was reported in S. typhimurium (Anderson et al. , 1972; Simmon et al., 1977; Lemma and Ames, 1975; Moriya et al. , 1983; Waters et al., 1982; Buselmaier et al., 1973) or in E. coli (Simmon et al., 1977; Fahrig, 1974; Moriya et al., 1983; Waters et al., 1982) with or without metabolic activation. Three teratogenicitylreproductive toxicity studies (Schwetz et al., 1974, 1977; Courtney et al., 1976) indicate that pentachlorophenol is fetotoxic in rats at oral dose levels ≥5 mg/kg/day. At the highest dose tested (500 ppm) in a fourth teratogenicity/reproductive toxicity study (Exon and Koller, 1982), there was a statistically nonsignificant decrease in litter size. The lowest dose tested (5 mg/kg/day) by Schwetz et al. (1977) was the lowest dose at which any evidence offetotoxicity, as indicated by delayed ossification, was observed. No adverse fetal or reproductive effects were reported at ≤3 mg/kg/day (Schwetz et al., 1977; Exon and Koller, 1982). In subchronic and chronic toxicity studies, adverse effects occurred primarily in the liver (Kerkvliet et al., 1982; Johnson et al., 1973; Knudsen et al. , 1974; Goldstein et al. , 1977; Kimbrough and Linder, 1978; Schwetz et al., 1977), the kidney (Johnson et al., 1973; Kimbrough and Linder, 1978; Schwetz et al., 1977) and the immune system (Kerkvliet et al., 1982). Knudsen et al. (1974) reported increased liver weights in female rats and centrilobu lar vacuolization in male rats exposed to diets containing ≧50 ppm commercial pentachlorophenol, which contained 282 ppm dioxins. In the remaining studies, increased liver weight (Johnson et al., 1973) and increased pigmentation of hepatocytes (Schwetz et al., 1977) were observed at oral doses of≥10 mg/kg/day (∼90%), and SGPT levels significantly increased in rats ingesting 30 mg/kg/day pentachloro phenol (∼90%) for 2 years (Schwetz et al., 1977). Increased kidney weight unaccompanied by renal histopathology was reported in rats exposed to dietary concentration ≧20 ppm of pentachlorophenol (>99%) for 8 months (Kimbrough and Linder, 1978) and in rats ingesting 30 mg/kg/day (∼90%) for 90 days (Johnson et al., 1973). Increased pigmentation of the renal tubular epithelial cells was re ported in rats ingesting 10 or 30 mg/kg/day pentachlorophenol for 2 years (Schwetz et al., 1977). Although decreased immunocompetence was reported in mice exposed to dietary levels of 50 or 500 ppm of pentachlorophenol (>99%) for 34 weeks (Kerkvliet et al., 1982), the decrease was statistically significant only at the higher dose. An ADI of 0.03 mg/kg/day or 2.1 mg/day for a 70 kg human was derivedfrom the NOAEL of 3 mg/kg/day in rats in the chronic dietary study by Schwetz et al. (1977). An uncertainty factor of 100 was used. An RQ of 100 was derived based on the fetotoxic effects of pen tachlorophenol in rats in the study by Schwetz et al. (1974). Based on guidelines for carcinogen risk assessment (U.S. EPA, 1984b) and inadequate evidence for animal carcinogenicity or absence of human cancer data, pentachlorophenol is classified as Group D, meaning that it is not classified as a human carcinogen.

The idea of this project was to design and fabricate a combustion chamber of incinerator for Quran paper burning with a capacity of 10 kg/h, which is heated by Liquefied Petroleum Gas, LPG as fuel for the burner. This small capacity 10kg/h incinerator is portable type. The focus customers are Department of Islamic Development, Malaysia, JAKIM and other Islamic authority in Malaysia that can dispose the Quran used paper with their own facility without sending out to third parties. The customer can reduce space, cost and time because the storage and transport are not required. This incinerator is a retort type consist of primary and secondary chambers. The secondary chamber is further divided into mixing and combustion sections . The function of secondary chamber is to provide complete combustion to Quran paper burning process. The temperature for primary chamber is set of range from 200 to 218 degree Celsius. This design is fabricated based on standard stated by Environment Authority.

The current appraisal aims to educate and give valuable information about disposal methods adopted in hospitals and health sectors. Many healthcare departments like microbiology labs, pharma industries, medical agencies, healthcare sectors all produce waste which usually contains unsafe materials that should not be exposed untreated to the atmosphere. In these health sectors, many types of wastes are separated as lab debris, chemical, and biological waste. These waste are rich in contaminants and pathogenic microbes which will be more lethal if they are not properly disposed of. The authors describe the various wastes and the definite discarding process to minimize costs and impact on the surroundings. Presently many of these sector professionals have some difficulty in disposal, these issues can be overcome by the systematic and easy plan described by the authors. Specific treatment must be required for this waste before they disposed off. This waste must be washed before introducing them into a particular disposable discard. Medical waste can be disposed of thoroughly as they contain infectious or non-infectious microorganisms. Biological and pharmaceutical waste must be disposed of, to prevent environmental hazards. Among the various approaches adopted for the disposing of these waste includes incineration, autoclaving, chemical disinfection, ignitability, etc. are popularly adopted. Each particular waste can be disposed of in a specific manner. The authors succeed in bringing the systematic approach in the disposal of waste in health care units and concludes that proper disposal is important to reduce the contamination and pollution of the environment and maintain a healthy atmosphere.

The need for solid household waste (MSW) generated by economic and domestic activities is continuous and should be imposed to protect the health of the population and environmental factors. After sorting the generated waste, „the remaining residue” favours the occurrence of some pollutants, among which we mention suspended particulates, disagreeable odours, greenhouse gases, etc. This waste has to be managed in safe health and environment, no matter where it was generated. Managing them means either storing in statutory environmental protection facilities or incinerating in authorized installations with integrated environmental permitting. Waste storage may be subject to a mathematical equation called the time equation of a landfill. On the basis of such equation, it will be possible to calculate annually the amount of degraded waste gas generating gas (LFG) containing CH<sub>4</sub> and CO<sub>2</sub>. The amount of degraded waste means waste with high dissolved organic carbon (DOC).