Artykuły w czasopismach na temat „Liquid aerosols”
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Kaim, Sergii D. "The Molecular Theory of Liquid Nanodroplets Energetics in Aerosols". Entropy 23, nr 1 (24.12.2020): 13. http://dx.doi.org/10.3390/e23010013.
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Studies of the coronavirus SARS-CoV-2 spread mechanisms indicate that the main mechanism is associated with the spread in the atmosphere of micro- and nanodroplets of liquid with an active agent. However, the molecular theory of aerosols of microdroplets in gases remains poorly developed. In this work, the energy properties of aerosol nanodroplets of simple liquids suspended in a gas were studied within the framework of molecular theory. The three components of the effective aerosol Hamiltonian were investigated: (1) the interaction energy of an individual atom with a liquid nanodroplet; (2) the surface energy of liquid nanodroplet; and (3) the interaction energy of two liquid nanodroplets. The size dependence of all contributions was investigated. The pairwise interparticle interactions and pairwise interparticle correlations were accounted for to study the nanodroplet properties using the Fowler approximation. In this paper, the problem of the adhesion energy calculation of a molecular complex and a liquid nanodroplet is discussed. The derived effective Hamiltonian is generic and can be used for the cases of multicomponent nano-aerosols and to account for particle size distributions.
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Kudryashova, Olga, Evgeny Muravlev, Boris Vorozhtsov i Igor Akhmadeev. "The role of cavitation in submicron aerosol dispersion". MATEC Web of Conferences 243 (2018): 00003. http://dx.doi.org/10.1051/matecconf/201824300003.
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Here we discuss the problem of atomizing submicron aerosols by special design atomizers enabling the cavitation regime. The formation of submicron aerosol was studied using an impulse atomizer model powered by a high-energy material and an atomizer model with a special spray nozzle generating countercurrent flows. For these atomizers, the role played by cavitation in producing submicron liquid aerosols is demonstrated herein. A mathematical model is also suggested to describe the aerosol cloud genesis. The cavitation development critical pressure, outflow velocity, and the resulting droplet sizes were evaluated. The aerosol particle size and concentration were experimentally measured by optical methods. The measured disperse parameters of aerosols during the origination and propagation of the aerosol cloud resulted from the cavitation-assisted atomization of liquids are reported: the intrinsic particle diameter of water aerosol is 10…30 μm depending on the features of the atomizer designs and their operating regimes.
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Kim, Yong-Hyun, Mi-Kyung Song i Kyuhong Lee. "A Study on the Behavior Patterns of Liquid Aerosols Using Disinfectant Chloromethylisothiazolinone/Methylisothiazolinone Solution". Molecules 26, nr 19 (22.09.2021): 5725. http://dx.doi.org/10.3390/molecules26195725.
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This study evaluates the behavioral characteristics of components (methylisothiazolinone (MIT) and chloromethylisothiazolinone (CMIT)) contained in disinfectant solutions when they convert to liquid aerosols. The analytical method for MIT and CMIT quantitation was established and optimized using sorbent tube/thermal desorber-gas chromatography-mass spectrometry system; their behavioral characteristics are discussed using the quantitative results of these aerosols under different liquid aerosol generation conditions. MIT and CMIT showed different behavioral characteristics depending on the aerosol mass concentration and sampling time (sampling volume). When the disinfectant solution was initially aerosolized, MIT and CMIT were primarily collected on glass filter (MIT = 91.8 ± 10.6% and CMIT = 90.6 ± 5.18%), although when the generation and filter sampling volumes of the aerosols increased to 30 L, the relative proportions collected on the filter decreased (MIT = 79.0 ± 12.0% and CMIT = 39.7 ± 8.35%). Although MIT and CMIT had relatively high vapor pressure, in liquid aerosolized state, they primarily accumulated on the filter and exhibited particulate behavior. Their relative proportions in the aerosol were different from those in disinfectant solution. In the aerosol with mass concentration of ≤5 mg m−3, the relative proportion deviations of MIT and CMIT were large; when the mass concentration of the aerosol increased, their relative proportions constantly converged at a lower level than those in the disinfectant solution. Hence, it can be concluded that the behavioral characteristics and relative proportions need to be considered to perform the quantitative analysis of the liquid aerosols and evaluate various toxic effects using the quantitative data.
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Li, Meng, Hang Su, Guo Li, Nan Ma, Ulrich Pöschl i Yafang Cheng. "Relative importance of gas uptake on aerosol and ground surfaces characterized by equivalent uptake coefficients". Atmospheric Chemistry and Physics 19, nr 16 (29.08.2019): 10981–1011. http://dx.doi.org/10.5194/acp-19-10981-2019.
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Abstract. Quantifying the relative importance of gas uptake on the ground and aerosol surfaces helps to determine which processes should be included in atmospheric chemistry models. Gas uptake by aerosols is often characterized by an effective uptake coefficient (γeff), whereas gas uptake on the ground is usually described by a deposition velocity (Vd). For efficient comparison, we introduce an equivalent uptake coefficient (γeqv) at which the uptake flux of aerosols would equal that on the ground surface. If γeff is similar to or larger than γeqv, aerosol uptake is important and should be included in atmospheric models. In this study, we compare uptake fluxes in the planetary boundary layer (PBL) for different reactive trace gases (O3, NO2, SO2, N2O5, HNO3 and H2O2), aerosol types (mineral dust, soot, organic aerosol and sea salt aerosol), environments (urban areas, agricultural land, the Amazon forest and water bodies), seasons and mixing heights. For all investigated gases, γeqv ranges from magnitudes of 10−6–10−4 in polluted urban environments to 10−4–10−1 under pristine forest conditions. In urban areas, aerosol uptake is relevant for all species (γeff≥γeqv) and should be considered in models. On the contrary, contributions of aerosol uptakes in the Amazon forest are minor compared with the dry deposition. The phase state of aerosols could be one of the crucial factors influencing the uptake rates. Current models tend to underestimate the O3 uptake on liquid organic aerosols which can be important, especially over regions with γeff≥γeqv. H2O2 uptakes on a variety of aerosols are yet to be measured under laboratory conditions and evaluated. Given the fact that most models have considered the uptakes of these species on the ground surface, we suggest also considering the following processes in atmospheric models: N2O5 uptake by all types of aerosols, HNO3 and SO2 uptake by mineral dust and sea salt aerosols, H2O2 uptake by mineral dust, NO2 uptakes by sea salt aerosols and O3 uptake by liquid organic aerosols.
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Liu, Lixia, Yafang Cheng, Siwen Wang, Chao Wei, Mira L. Pöhlker, Christopher Pöhlker, Paulo Artaxo i in. "Impact of biomass burning aerosols on radiation, clouds, and precipitation over the Amazon: relative importance of aerosol–cloud and aerosol–radiation interactions". Atmospheric Chemistry and Physics 20, nr 21 (10.11.2020): 13283–301. http://dx.doi.org/10.5194/acp-20-13283-2020.
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Abstract. Biomass burning (BB) aerosols can influence regional and global climate through interactions with radiation, clouds, and precipitation. Here, we investigate the impact of BB aerosols on the energy balance and hydrological cycle over the Amazon Basin during the dry season. We performed simulations with a fully coupled meteorology–chemistry model, the Weather Research and Forecasting model coupled with Chemistry (WRF-Chem), for a range of different BB emission scenarios to explore and characterize nonlinear effects and individual contributions from aerosol–radiation interactions (ARIs) and aerosol–cloud interactions (ACIs). The ARIs of BB aerosols tend to suppress low-level liquid clouds by local warming and increased evaporation and to facilitate the formation of high-level ice clouds by enhancing updrafts and condensation at high altitudes. In contrast, the ACIs of BB aerosol particles tend to enhance the formation and lifetime of low-level liquid clouds by providing more cloud condensation nuclei (CCN) and to suppress the formation of high-level ice clouds by reducing updrafts and condensable water vapor at high altitudes (>8 km). For scenarios representing the lower and upper limits of BB emission estimates for recent years (2002–2016), we obtained total regional BB aerosol radiative forcings of −0.2 and 1.5 W m−2, respectively, showing that the influence of BB aerosols on the regional energy balance can range from modest cooling to strong warming. We find that ACIs dominate at low BB emission rates and low aerosol optical depth (AOD), leading to an increased cloud liquid water path (LWP) and negative radiative forcing, whereas ARIs dominate at high BB emission rates and high AOD, leading to a reduction of LWP and positive radiative forcing. In all scenarios, BB aerosols led to a decrease in the frequency of occurrence and rate of precipitation, caused primarily by ACI effects at low aerosol loading and by ARI effects at high aerosol loading. The dependence of precipitation reduction on BB aerosol loading is greater in a strong convective regime than under weakly convective conditions. Overall, our results show that ACIs tend to saturate at high aerosol loading, whereas the strength of ARIs continues to increase and plays a more important role in highly polluted episodes and regions. This should hold not only for BB aerosols over the Amazon, but also for other light-absorbing aerosols such as fossil fuel combustion aerosols in industrialized and densely populated areas. The importance of ARIs at high aerosol loading highlights the need for accurately characterizing aerosol optical properties in the investigation of aerosol effects on clouds, precipitation, and climate.
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Weisenstein, D. K., D. W. Keith i J. A. Dykema. "Solar geoengineering using solid aerosol in the stratosphere". Atmospheric Chemistry and Physics 15, nr 20 (26.10.2015): 11835–59. http://dx.doi.org/10.5194/acp-15-11835-2015.
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Abstract. Solid aerosol particles have long been proposed as an alternative to sulfate aerosols for solar geoengineering. Any solid aerosol introduced into the stratosphere would be subject to coagulation with itself, producing fractal aggregates, and with the natural sulfate aerosol, producing liquid-coated solids. Solid aerosols that are coated with sulfate and/or have formed aggregates may have very different scattering properties and chemical behavior than uncoated non-aggregated monomers do. We use a two-dimensional (2-D) chemistry–transport–aerosol model to capture the dynamics of interacting solid and liquid aerosols in the stratosphere. As an example, we apply the model to the possible use of alumina and diamond particles for solar geoengineering. For 240 nm radius alumina particles, for example, an injection rate of 4 Tg yr−1 produces a global-average shortwave radiative forcing of −1.2 W m−2 and minimal self-coagulation of alumina although almost all alumina outside the tropics is coated with sulfate. For the same radiative forcing, these solid aerosols can produce less ozone loss, less stratospheric heating, and less forward scattering than sulfate aerosols do. Our results suggest that appropriately sized alumina, diamond or similar high-index particles may have less severe technology-specific risks than sulfate aerosols do. These results, particularly the ozone response, are subject to large uncertainties due to the limited data on the rate constants of reactions on the dry surfaces.
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Weisenstein, D. K., i D. W. Keith. "Solar geoengineering using solid aerosol in the stratosphere". Atmospheric Chemistry and Physics Discussions 15, nr 8 (21.04.2015): 11799–851. http://dx.doi.org/10.5194/acpd-15-11799-2015.
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Abstract. Solid aerosol particles have long been proposed as an alternative to sulfate aerosols for solar geoengineering. Any solid aerosol introduced into the stratosphere would be subject to coagulation with itself, producing fractal aggregates, and with the natural sulfate aerosol, producing liquid-coated solids. Solid aerosols that are coated with sulfate and/or have formed aggregates may have very different scattering properties and chemical behavior than do uncoated non-aggregated monomers. We use a two-dimensional chemical transport model to capture the dynamics of interacting solid and liquid aerosols in the stratosphere. As an example, we apply the model to the possible use of alumina and diamond particles for solar geoengineering. For 240 nm radius alumina particles, for example, an injection rate of 4 Mt yr−1 produces a global-average radiative forcing of 1.3 W m−2 and minimal self-coagulation of alumina yet almost all alumina outside the tropics is coated with sulfate. For the same radiative forcing, these solid aerosols can produce less ozone loss, less stratospheric heating, and less forward scattering than do sulfate aerosols. Our results suggest that appropriately sized alumina, diamond or similar high-index particles may have less severe technology-specific risks than do sulfate aerosols. These results, particularly the ozone response, are subject to large uncertainties due the limited data on the rate constants of reactions on the dry surfaces.
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Frey, Lena, Frida A. M. Bender i Gunilla Svensson. "Cloud albedo changes in response to anthropogenic sulfate and non-sulfate aerosol forcings in CMIP5 models". Atmospheric Chemistry and Physics 17, nr 14 (31.07.2017): 9145–62. http://dx.doi.org/10.5194/acp-17-9145-2017.
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Abstract. The effects of different aerosol types on cloud albedo are analysed using the linear relation between total albedo and cloud fraction found on a monthly mean scale in regions of subtropical marine stratocumulus clouds and the influence of simulated aerosol variations on this relation. Model experiments from the Coupled Model Intercomparison Project phase 5 (CMIP5) are used to separately study the responses to increases in sulfate, non-sulfate and all anthropogenic aerosols. A cloud brightening on the month-to-month scale due to variability in the background aerosol is found to dominate even in the cases where anthropogenic aerosols are added. The aerosol composition is of importance for this cloud brightening, that is thereby region dependent. There is indication that absorbing aerosols to some extent counteract the cloud brightening but scene darkening with increasing aerosol burden is generally not supported, even in regions where absorbing aerosols dominate. Month-to-month cloud albedo variability also confirms the importance of liquid water content for cloud albedo. Regional, monthly mean cloud albedo is found to increase with the addition of anthropogenic aerosols and more so with sulfate than non-sulfate. Changes in cloud albedo between experiments are related to changes in cloud water content as well as droplet size distribution changes, so that models with large increases in liquid water path and/or cloud droplet number show large cloud albedo increases with increasing aerosol. However, no clear relation between model sensitivities to aerosol variations on the month-to-month scale and changes in cloud albedo due to changed aerosol burden is found.
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Yu, Xiang, Haifeng Gu, Weikai Yin i Qingyang Sun. "Bubble Bursting and Drainage Characteristics at the Free Surface of a Liquid Pool with an Aerosol". Science and Technology of Nuclear Installations 2020 (16.10.2020): 1–13. http://dx.doi.org/10.1155/2020/8829074.
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When nuclear reactor accidents such as steam generator pipe ruptures or core melting occur, radioactive aerosols will remain in the liquid pools. Bubbles may be generated by boiling or gas injection. Film droplets produced by bubble bursts may entrain radioactive aerosols from the liquid to the air. This long-lasting behavior can produce a considerable amount of aerosols. To evaluate radioactive source terms, many physical quantities related to bubble bursting need to be determined, such as bubble burst position, bubble lifetime, cap film roll-up velocity, and cap film thickness, which are very important parameters that influence the releasing of radioactive aerosols. In this research, the phenomenon of bubble bursting was investigated by visualization. The above parameters were measured. We obtained the lifetime distribution of bubbles under different conditions, and we found that the addition of an aerosol increased the lifetime of the bubbles. By comparing the bubble lifetime to the roll-up velocity and cap thickness, we showed that the increase of the liquid temperature thickened the cap at rupture and the increase of the air temperature thinned the cap. The addition of an aerosol increased the film roll-up velocity.
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Behar, Rachel Z., Yuhuan Wang i Prue Talbot. "Comparing the cytotoxicity of electronic cigarette fluids, aerosols and solvents". Tobacco Control 27, nr 3 (8.06.2017): 325–33. http://dx.doi.org/10.1136/tobaccocontrol-2016-053472.
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BackgroundAs thousands of electronic cigarette (e-cigarette) refill fluids continue to be formulated and distributed, there is a growing need to understand the cytotoxicity of the flavouring chemicals and solvents used in these products to ensure they are safe. The purpose of this study was to compare the cytotoxicity of e-cigarette refill fluids/solvents and their corresponding aerosols using in vitro cultured cells.MethodsE-cigarette refill fluids and do-it-yourself products were screened in liquid and aerosol form for cytotoxicity using the MTT (3-(4,5-dimethylthiazol-2-yl)−2,5-diphenyltetrazolium bromide) assay. The sensitivity of human pulmonary fibroblasts, lung epithelial cells (A549) and human embryonic stem cells to liquids and aerosols was compared. Aerosols were produced using Johnson Creek’s Vea cartomizer style e-cigarette.ResultsA hierarchy of potency was established for the aerosolised products. Our data show that (1) e-cigarette aerosols can produce cytotoxic effects in cultured cells, (2) four patterns of cytotoxicity were found when comparing refill fluids and their corresponding aerosols, (3) fluids accurately predicted aerosol cytotoxicity 74% of the time, (4) stem cells were often more sensitive to aerosols than differentiated cells and (5) 91% of the aerosols made from refill fluids containing only glycerin were cytotoxic, even when produced at a low voltage.ConclusionsOur data show that various flavours/brands of e-cigarette refill fluids and their aerosols are cytotoxic and demonstrate the need for further evaluation of e-cigarette products to better understand their potential health effects.
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Huang, J., P. Minnis, H. Yan, Y. Yi, B. Chen, L. Zhang i J. K. Ayers. "Dust aerosol effect on semi-arid climate over Northwest China detected from A-Train satellite measurements". Atmospheric Chemistry and Physics Discussions 10, nr 5 (12.05.2010): 12465–95. http://dx.doi.org/10.5194/acpd-10-12465-2010.
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Abstract. The impact of dust aerosols on the semi-arid climate of Northwest China is analyzed by comparing aerosol and cloud properties derived over the China semi-arid region (hereafter, CSR) and the United States semi-arid region (hereafter, USR) using several years of surface and A-Train satellite observations during active dust event seasons. These regions have similar climatic conditions, but aerosol concentrations are greater over the CSR. Because the CSR is close to two major dust source regions (Taklamakan and Gobi deserts), the aerosols over the CSR not only contain local anthropogenic aerosols (agricultural dust, black carbon and other anthropogenic aerosols), but also include natural dust transported from the source regions. The aerosol optical depth, averaged over a 3-month period, derived from MODIS for the CSR is 0.27, which is 47% higher than that over the USR (0.19). Although transported natural dust only accounts for 53% of this difference, it is a major contributor to the average absorbing aerosol index, which is 27% higher in the CSR (1.07) than in the USR (0.84). During dust event periods, liquid water cloud particle size, optical depth and liquid water path are smaller by 9%, 30% and 33% compared to dust-free conditions, respectively.
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Huang, J., P. Minnis, H. Yan, Y. Yi, B. Chen, L. Zhang i J. K. Ayers. "Dust aerosol effect on semi-arid climate over Northwest China detected from A-Train satellite measurements". Atmospheric Chemistry and Physics 10, nr 14 (23.07.2010): 6863–72. http://dx.doi.org/10.5194/acp-10-6863-2010.
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Abstract. The impact of dust aerosols on the semi-arid climate of Northwest China is analyzed by comparing aerosol and cloud properties derived over the China semi-arid region (hereafter, CSR) and the United States semi-arid region (hereafter, USR) using several years of surface and A-Train satellite observations during active dust event seasons. These regions have similar climatic conditions, but aerosol concentrations are greater over the CSR. Because the CSR is close to two major dust source regions (Taklamakan and Gobi deserts), the aerosols over the CSR not only contain local anthropogenic aerosols (agricultural dust, black carbon and other anthropogenic aerosols), but also include natural dust transported from the source regions. The aerosol optical depth, averaged over a 3-month period, derived from MODIS for the CSR is 0.27, which is 47% higher than that over the USR (0.19). Although transported natural dust only accounts for 53% of this difference, it is a major contributor to the average absorbing aerosol index, which is 27% higher in the CSR (1.07) than in the USR (0.84). During dust event periods, liquid water cloud particle size, optical depth and liquid water path are smaller by 9%, 30% and 33% compared to dust-free conditions, respectively.
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Noël, Alexandra, i Arpita Ghosh. "Carbonyl Profiles of Electronic Nicotine Delivery System (ENDS) Aerosols Reflect Both the Chemical Composition and the Numbers of E-Liquid Ingredients–Focus on the In Vitro Toxicity of Strawberry and Vanilla Flavors". International Journal of Environmental Research and Public Health 19, nr 24 (14.12.2022): 16774. http://dx.doi.org/10.3390/ijerph192416774.
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Propylene glycol (PG) and glycerin (G) are the most widely used humectants in electronic nicotine delivery system (ENDS) devices. Carbonyls are present in aerosols produced when ENDS devices heat PG and G. Whether aerosolized PG and G are innocuous to the lungs has not been established. Here, we determined the chemical profiles of ENDS aerosols containing three humectant ratios (30/70, 50/50 and 70/30, PG/VG), for three flavors (strawberry, vanilla and Catalan cream) containing either 12 or 18 mg/mL of nicotine. Additionally, we examined the in vitro toxicity of the strawberry- and vanilla-flavored ENDS aerosol in human lung epithelial cells (BEAS-2B) exposed at the air-liquid interface for 1 h. For strawberry- and vanilla-flavored aerosols produced by a 3rd-generation ENDS device with the same PG/G ratio, the e-liquid nicotine content of 12 and 18 mg/mL did not transfer to the aerosol with substantial differences in concentrations. Our data also indicate the presence of carbonyls in all three flavored e-cig aerosols analyzed, with levels exceeding 1 µg/puff for acetone, butyraldehyde, and acetaldehyde, in strawberry-, vanilla, and Catalan cream-flavored e-cig aerosols, respectively. Furthermore, closed-system ENDS of the fourth generation emitted trace levels of carbonyls in the aerosols (<0.3 µg/puff), while open-system tank-style ENDS of the third generation produced elevated levels of harmful chemicals, including acrolein (>1 µg/puff), formaldehyde (>5 µg/puff), and m- & p-tolualdehyde (>4 µg/puff). Moreover, under non-cytotoxic conditions, BEAS-2B cells exposed to strawberry-flavored aerosols exhibited significantly increased reactive oxygen and nitric oxide species (ROS/NOS) levels in cell media compared to air controls, while vanilla-flavored ENDS aerosols up-regulated the expression of pro-inflammatory and oxidative stress markers. Our data suggest (a) that ENDS aerosol chemical composition will vary based upon the presence and concentration of the initial e-liquid ingredients, with a pronounced impact of the flavoring components; and (b) short-term exposures to flavored ENDS aerosols may impair lung cells’ redox signaling in a flavor-specific manner.
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Peters, K., J. Quaas i N. Bellouin. "Effects of absorbing aerosols in cloudy skies: a satellite study over the Atlantic Ocean". Atmospheric Chemistry and Physics Discussions 9, nr 5 (2.10.2009): 20853–80. http://dx.doi.org/10.5194/acpd-9-20853-2009.
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Abstract. Aerosol effects, direct as well as indirect, constitute one of the biggest sources of uncertainty when it comes to quantifying human forcing of climate change. Understanding these will thus increase the credibility of climate predictions. This study focuses on aerosol effects when absorbing aerosols reside in cloudy skies. In cloudfree conditions, aerosols usually exert a negative radiative forcing (RF) at the top of the atmosphere (TOA) due to their scattering properties. When located above clouds, absorbing aerosols can reduce the shortwave local planetary albedo α, resulting in an often significant local positive direct radiative forcing (DRF). A method for deriving the aerosol radiative effects of absorbing aerosols in cloudy situations from satellite retrievals is presented. Data of 2005 and 2006 from various sensors aboard satellites of the "A-Train" constellation, restricted to the tropical and subtropical Atlantic ocean, is used. A multiple linear regression is performed to identify the dependence of α in cloudy scenes on cloud liquid water path (LWP) and aerosol optical depth (AOD), using the OMI UV-Aerosolindex (UV-AI) as an indicator for absorbing aerosols. The results show an increase of α with increasing aerosol load, and a relative decrease of α with increasing amount of absorbing aerosols in cloudy scenes. This allows to derive the direct aerosol effect of absorbing aerosols above clouds, with the effect of aerosol absorption over clouds in the Atlantic contributing +0.08±1.2×10-3Wm-2 to the global TOA RF.
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Zhao, Pengguo, Zhanqing Li, Hui Xiao, Fang Wu, Youtong Zheng, Maureen C. Cribb, Xiaoai Jin i Yunjun Zhou. "Distinct aerosol effects on cloud-to-ground lightning in the plateau and basin regions of Sichuan, Southwest China". Atmospheric Chemistry and Physics 20, nr 21 (11.11.2020): 13379–97. http://dx.doi.org/10.5194/acp-20-13379-2020.
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Abstract. The joint effects of aerosol, thermodynamic, and cloud-related factors on cloud-to-ground lightning in Sichuan were investigated by a comprehensive analysis of ground-based measurements made from 2005 to 2017 in combination with reanalysis data. Data include aerosol optical depth, cloud-to-ground (CG) lightning density, convective available potential energy (CAPE), mid-level relative humidity, lower- to mid-tropospheric vertical wind shear, cloud-base height, total column liquid water (TCLW), and total column ice water (TCIW). Results show that CG lightning density and aerosols are positively correlated in the plateau region and negatively correlated in the basin region. Sulfate aerosols are found to be more strongly associated with lightning than total aerosols, so this study focuses on the role of sulfate aerosols in lightning activity. In the plateau region, the lower aerosol concentration stimulates lightning activity through microphysical effects. Increasing the aerosol loading decreases the cloud droplet size, reducing the cloud droplet collision–coalescence efficiency and inhibiting the warm-rain process. More small cloud droplets are transported above the freezing level to participate in the freezing process, forming more ice particles and releasing more latent heat during the freezing process. Thus, an increase in the aerosol loading increases CAPE, TCLW, and TCIW, stimulating CG lightning in the plateau region. In the basin region, by contrast, the higher concentration of aerosols inhibits lightning activity through the radiative effect. An increase in the aerosol loading reduces the amount of solar radiation reaching the ground, thereby lowering the CAPE. The intensity of convection decreases, resulting in less supercooled water being transported to the freezing level and fewer ice particles forming, thereby increasing the total liquid water content. Thus, an increase in the aerosol loading suppresses the intensity of convective activity and CG lightning in the basin region.
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Ko, Tae-Jun, i Shin Ae Kim. "Effect of Heating on Physicochemical Property of Aerosols during Vaping". International Journal of Environmental Research and Public Health 19, nr 3 (8.02.2022): 1892. http://dx.doi.org/10.3390/ijerph19031892.
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Many electronic cigarette manufacturers have offered different types of “high-end mods” that allow for controlled heating of the e-liquid. However, the controlled heating condition can drastically alter the inhaled aerosols’ physical properties and chemical substances, causing potential health risks. To investigate the contribution of heating on aerosol properties, we used four common power settings in the mods to conduct a physicochemical analysis. Our data showed that the aerosol mass and nicotine content in the aerosols increased at high power. Additionally, high power led to aerosolization of a viscous component in the e-liquid, increasing the viscosity of aerosol. However, the pH of the aerosol was constant regardless of the applied power. In addition, high-power operation made nicotine prone to oxidation, resulting in the color of the aerosol turning yellow. Lastly, we demonstrated that e-cigarette aerosol could contain various metals, including aluminum, arsenic, cadmium, chromium, copper, iron, magnesium, nickel, lead, and zinc. Even though these metal contents proportionally increased with the power setting, they remained far below the recommended exposure limits. Our finding demonstrates that the heating conditions of the e-cigarette change the physicochemical properties of the aerosols and their metal contents, thereby possibly affecting users’ oral and respiratory systems.
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Cerully, K. M., A. Bougiatioti, J. R. Hite, H. Guo, L. Xu, N. L. Ng, R. Weber i A. Nenes. "On the link between hygroscopicity, volatility, and oxidation state of ambient and water-soluble aerosols in the southeastern United States". Atmospheric Chemistry and Physics 15, nr 15 (7.08.2015): 8679–94. http://dx.doi.org/10.5194/acp-15-8679-2015.
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Abstract. The formation of secondary organic aerosols (SOAs) combined with the partitioning of semivolatile organic components can impact numerous aerosol properties including cloud condensation nuclei (CCN) activity, hygroscopicity, and volatility. During the summer 2013 Southern Oxidant and Aerosol Study (SOAS) field campaign in a rural site in the southeastern United States, a suite of instruments including a CCN counter, a thermodenuder (TD), and a high-resolution time-of-flight aerosol mass spectrometer (AMS) were used to measure CCN activity, aerosol volatility, composition, and oxidation state. Particles were either sampled directly from ambient or through a particle-into-liquid sampler (PILS), allowing the investigation of the water-soluble aerosol component. Ambient aerosols exhibited size-dependent composition with larger particles being more hygroscopic. The hygroscopicity of thermally denuded aerosols was similar between ambient and PILS-generated aerosols and showed limited dependence on volatilization. Results of AMS three-factor positive matrix factorization (PMF) analysis for the PILS-generated aerosols showed that the most hygroscopic components are most likely the most and the least volatile features of the aerosols. No clear relationship was found between organic hygroscopicity and the oxygen-to-carbon ratio; in fact, isoprene-derived organic aerosols (isoprene-OAs) were found to be the most hygroscopic factor, while at the same time being the least oxidized and likely most volatile of all PMF factors. Considering the diurnal variation of each PMF factor and its associated hygroscopicity, isoprene-OA and more-oxidized oxygenated organic aerosols are the prime contributors to hygroscopicity and co-vary with less-oxidized oxygenated organic aerosols in a way that induces the observed diurnal invariance in total organic hygroscopicity. Biomass burning organic aerosols contributed little to aerosol hygroscopicity, which is expected since there was little biomass burning activity during the sampling period examined.
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Niu, F., i Z. Li. "Cloud invigoration and suppression by aerosols over the tropical region based on satellite observations". Atmospheric Chemistry and Physics Discussions 11, nr 2 (10.02.2011): 5003–17. http://dx.doi.org/10.5194/acpd-11-5003-2011.
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Abstract. Aerosols may modify cloud properties and precipitation via a variety of mechanisms with varying and contradicting consequences. Using a large ensemble of satellite data acquired by the Moderate Resolution Imaging Spectroradiometer onboard the Earth Observing System's Aqua platform, the CloudSat cloud profiling radar and the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) satellite over the tropical oceans, we identified two distinct responses of clouds and precipitation to increases in aerosol loading. Cloud-top temperatures decrease significantly with increasing aerosol index (AI) over oceans and aerosol optical depth (AOT) over land for mixed-phase clouds with warm cloud bases; no significant changes were found for liquid clouds. The distinct responses are explained by two mechanisms, namely, the aerosol invigoration effect and the microphysical effect. Aerosols can significantly invigorate convection mainly through ice processes, while precipitation from liquid clouds is suppressed through aerosol microphysical processes. Precipitation rates are found to increase with AI for mixed-phase clouds, but decrease for liquid clouds, suggesting that the dominant effect differs for the two types of clouds. These effects change the overall distribution of precipitation rates, leading to more or heavier rains in dirty environments than in cleaner ones.
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Niemiec, Katarzyna, Anna Fitrzyk i Cezary Grabowik. "Methods of manufacture and innovations in steel aerosol cans’ production". International Journal of Modern Manufacturing Technologies 13, nr 3 (25.12.2021): 96–104. http://dx.doi.org/10.54684/ijmmt.2021.13.3.96.
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The production of aerosols has had a significant position in the industry for many years. We use aerosol products almost every day for very different purposes. The aerosol industry growth very dynamically, the shapes and the materials of the containers are changing, but the main principle remains the same – “aerosol dispenser shall mean any non-reusable container made of metal, glass or plastic and containing a gas compressed, liquefied or dissolved under pressure, with or without a liquid, paste or powder, and fitted with a release device allowing the contents to be ejected as solid or liquid particles in suspension in a gas, as a foam, paste or powder or in a liquid state”. The purpose of this article is to present the methods of aerosols’ steel can manufacture together with the changes that have been made over the last century. Since the beginning of aerosol industry metal is the main material from which aerosol containers are made of, and steel is one of the most popular raw materials, the main law requirements regarding aerosol containers made of steel will be analysed. As the consequence of these analyses, the future possible development directions will be shown.
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Stancampiano, Augusto, Tommaso Gallingani, Matteo Gherardi, Zdenko Machala, Paul Maguire, Vittorio Colombo, Jean-Michel Pouvesle i Eric Robert. "Plasma and Aerosols: Challenges, Opportunities and Perspectives". Applied Sciences 9, nr 18 (14.09.2019): 3861. http://dx.doi.org/10.3390/app9183861.
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The interaction of plasmas and liquid aerosols offers special advantages and opens new perspectives for plasma–liquid applications. The paper focuses on the key research challenges and potential of plasma-aerosol interaction at atmospheric pressure in several fields, outlining opportunities and benefits in terms of process tuning and throughputs. After a short overview of the recent achievements in plasma–liquid field, the possible application benefits from aerosol injection in combination with plasma discharge are listed and discussed. Since the nature of the chemicophysical plasma-droplet interactions is still unclear, a multidisciplinary approach is recommended to overcome the current lack of knowledge and to open the plasma communities to scientists from other fields, already active in biphasic systems diagnostic. In this perspective, a better understanding of the high chemical reactivity of gas–liquid reactions will bring new opportunities for plasma assisted in-situ and on-demand reactive species production and material processing.
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Qiu, Yuqing, i Valeria Molinero. "Morphology of Liquid–Liquid Phase Separated Aerosols". Journal of the American Chemical Society 137, nr 33 (13.08.2015): 10642–51. http://dx.doi.org/10.1021/jacs.5b05579.
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Gantt, B., J. Xu, N. Meskhidze, Y. Zhang, A. Nenes, S. J. Ghan, X. Liu, R. Easter i R. Zaveri. "Global distribution and climate forcing of marine organic aerosol – Part 2: Effects on cloud properties and radiative forcing". Atmospheric Chemistry and Physics Discussions 12, nr 3 (15.03.2012): 7453–74. http://dx.doi.org/10.5194/acpd-12-7453-2012.
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Abstract. In the first part of this paper series (Meskhidze et al., 2011), a treatment of marine organic aerosols (including primary organic aerosol, secondary organic aerosols, and methane sulfonate) was implemented into the Community Atmosphere Model version 5 (CAM5) with a 7-mode Modal Aerosol Module. A series of simulations was conducted to quantify the changes in aerosol and cloud condensation nuclei concentrations in the marine boundary layer. In this study, changes in the cloud microphysical properties and radiative forcing resulting from marine organic aerosols are assessed. Model simulations show that the anthropogenic aerosol indirect forcing (AIF) predicted by CAM5 is decreased in absolute magnitude by up to ~0.10 W m−2 (8%) when marine organic aerosols are included. Changes in the AIF from marine organic aerosols are associated with small global increases in low-level in-cloud droplet number concentration and liquid water path of ~1.3 cm−3 (~1.6%) and 0.2 g m−2 (0.5%), respectively. Areas especially sensitive to changes in cloud properties due to marine organic aerosol include the Southern Ocean, North Pacific Ocean, and North Atlantic Ocean, all of which are characterized by high marine organic emission rates. As climate models are particularly sensitive to the background aerosol concentration, this small but non-negligible change in the AIF due to marine organic aerosols provides a notable link for ocean-ecosystem marine low-level cloud interactions and may be a candidate for consideration in future earth system models.
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Wang, H., R. C. Easter, P. J. Rasch, M. Wang, X. Liu, S. J. Ghan, Y. Qian, J. H. Yoon, P. L. Ma i V. Vinoj. "Sensitivity of remote aerosol distributions to representation of cloud–aerosol interactions in a global climate model". Geoscientific Model Development 6, nr 3 (5.06.2013): 765–82. http://dx.doi.org/10.5194/gmd-6-765-2013.
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Abstract. Many global aerosol and climate models, including the widely used Community Atmosphere Model version 5 (CAM5), have large biases in predicting aerosols in remote regions such as the upper troposphere and high latitudes. In this study, we conduct CAM5 sensitivity simulations to understand the role of key processes associated with aerosol transformation and wet removal affecting the vertical and horizontal long-range transport of aerosols to the remote regions. Improvements are made to processes that are currently not well represented in CAM5, which are guided by surface and aircraft measurements together with results from a multi-scale aerosol–climate model that explicitly represents convection and aerosol–cloud interactions at cloud-resolving scales. We pay particular attention to black carbon (BC) due to its importance in the Earth system and the availability of measurements. We introduce into CAM5 a new unified scheme for convective transport and aerosol wet removal with explicit aerosol activation above convective cloud base. This new implementation reduces the excessive BC aloft to better simulate observed BC profiles that show decreasing mixing ratios in the mid- to upper-troposphere. After implementing this new unified convective scheme, we examine wet removal of submicron aerosols that occurs primarily through cloud processes. The wet removal depends strongly on the subgrid-scale liquid cloud fraction and the rate of conversion of liquid water to precipitation. These processes lead to very strong wet removal of BC and other aerosols over mid- to high latitudes during winter months. With our improvements, the Arctic BC burden has a 10-fold (5-fold) increase in the winter (summer) months, resulting in a much-better simulation of the BC seasonal cycle as well. Arctic sulphate and other aerosol species also increase but to a lesser extent. An explicit treatment of BC aging with slower aging assumptions produces an additional 30-fold (5-fold) increase in the Arctic winter (summer) BC burden. This BC aging treatment, however, has minimal effect on other underpredicted species. Interestingly, our modifications to CAM5 that aim at improving prediction of high-latitude and upper-tropospheric aerosols also produce much-better aerosol optical depth (AOD) over various other regions globally when compared to multi-year AERONET retrievals. The improved aerosol distributions have impacts on other aspects of CAM5, improving the simulation of global mean liquid water path and cloud forcing.
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Wang, H., R. C. Easter, P. J. Rasch, M. Wang, X. Liu, S. J. Ghan, Y. Qian, J. H. Yoon, P. L. Ma i V. Velu. "Sensitivity of remote aerosol distributions to representation of cloud-aerosol interactions in a global climate model". Geoscientific Model Development Discussions 6, nr 1 (21.01.2013): 331–78. http://dx.doi.org/10.5194/gmdd-6-331-2013.
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Abstract. Many global aerosol and climate models, including the widely used Community Atmosphere Model version 5 (CAM5), have large biases in predicting aerosols in remote regions such as upper troposphere and high latitudes. In this study, we conduct CAM5 sensitivity simulations to understand the role of key processes associated with aerosol transformation and wet removal affecting the vertical and horizontal long-range transport of aerosols to the remote regions. Improvements are made to processes that are currently not well represented in CAM5, which are guided by surface and aircraft measurements together with results from a multi-scale aerosol-climate model (PNNL-MMF) that explicitly represents convection and aerosol-cloud interactions at cloud-resolving scales. We pay particular attention to black carbon (BC) due to its importance in the Earth system and the availability of measurements. We introduce into CAM5 a new unified scheme for convective transport and aerosol wet removal with explicit aerosol activation above convective cloud base. This new implementation reduces the excessive BC aloft to better simulate observed BC profiles that show decreasing mixing ratios in the mid- to upper-troposphere. After implementing this new unified convective scheme, we examine wet removal of submicron aerosols that occurs primarily through cloud processes. The wet removal depends strongly on the sub-grid scale liquid cloud fraction and the rate of conversion of liquid water to precipitation. These processes lead to very strong wet removal of BC and other aerosols over mid- to high latitudes during winter months. With our improvements, the Arctic BC burden has a10-fold (5-fold) increase in the winter (summer) months, resulting in a much better simulation of the BC seasonal cycle as well. Arctic sulphate and other aerosol species also increase but to a lesser extent. An explicit treatment of BC aging with slower aging assumptions produces an additional 30-fold (5-fold) increase in the Arctic winter (summer) BC burden. This BC aging treatment, however, has minimal effect on other under-predicted species. Interestingly, our modifications to CAM5 that aim at improving prediction of high-latitude and upper tropospheric aerosols also produce much better aerosol optical depth over various other regions globally when compared to multi-year AERONET retrievals. The improved aerosol distributions have impacts on other aspects of CAM5, improving the simulation of global mean liquid water path and cloud forcing.
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Yang, Junwei, Lan Ma, Xiao He, Wing Chi Au, Yanhao Miao, Wen-Xiong Wang i Theodora Nah. "Measurement report: Abundance and fractional solubilities of aerosol metals in urban Hong Kong – insights into factors that control aerosol metal dissolution in an urban site in South China". Atmospheric Chemistry and Physics 23, nr 2 (25.01.2023): 1403–19. http://dx.doi.org/10.5194/acp-23-1403-2023.
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Abstract. Water-soluble metals are known to produce greater adverse human health outcomes than their water-insoluble forms. Although the concentrations of water-soluble aerosol metals are usually limited by atmospheric processes that convert water-insoluble metals to water-soluble forms, factors that control the solubilities of aerosol metals in different environments remain poorly understood. In this study, we investigated the abundance and fractional solubilities of different metals in size-fractionated aerosols collected at an urban site in Hong Kong and identified the factors that modulated metal solubilities in fine aerosols. The concentrations of total and water-soluble metals in fine and coarse aerosols were the highest during the winter and spring seasons due to the long-range transport of air masses by northerly prevailing winds from emission sources located in continental areas north of Hong Kong. The study-averaged metal fractional solubilities spanned a wide range for both fine (7.8 % to 71.2 %) and coarse (0.4 % to 47.9 %) aerosols, but higher fractional solubilities were typically observed for fine aerosols. Sulfate was found to be strongly associated with both the concentrations of water-soluble Cr, Fe, Co, Cu, Pb, and Mn and their fractional solubilities in fine aerosols, which implied that sulfate-driven acid processing likely played an important role in the dissolution of the water-insoluble forms for these six metals. Further analyses revealed that these strong associations were due to sulfate providing both the acidic environment and liquid water reaction medium needed for the acid dissolution process. Thus, the variability in the concentrations of water-soluble Cr, Fe, Co, Cu, Pb, and Mn and their fractional solubilities were driven by both the aerosol acidity levels and liquid water concentrations, which in turn were controlled by sulfate. These results highlight the roles that sulfate plays in the acid dissolution of metals in fine aerosols in Hong Kong. Our findings will likely also apply to other urban areas in South China, where sulfate is the dominant acidic and hygroscopic component in fine aerosols.
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Ma, X., K. von Salzen i J. Cole. "Constraints on first aerosol indirect effect from a combination of MODIS-CERES satellite data and global climate simulations". Atmospheric Chemistry and Physics Discussions 10, nr 6 (7.06.2010): 13945–68. http://dx.doi.org/10.5194/acpd-10-13945-2010.
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Abstract. Retrievals of cloud top effective radius from MODIS (as derived by CERES) were combined with aerosol concentrations from the CCCma CanAM4 to examine relationships between aerosol and cloud that underlie the first aerosol indirect (cloud albedo) effect. Evidence of a strong negative relationship between sulphate, and organic aerosols, with cloud top effective radius was found for low clouds, indicating both aerosol types are contributing to the first indirect effect on a global scale. Furthermore, effects of aerosol on the cloud droplet effective radius are more pronounced for larger cloud liquid water paths. While CanAM4 broadly reproduces the observed relationship between sulphate aerosols and cloud droplets, it does not reproduce the dependency of cloud top droplet size on organic aerosol concentrations nor the dependency on cloud liquid water path. Simulations with a modified version of the model yield a more realistic dependency of cloud droplets on organic carbon. The robustness of the methods used in the study are investigated by repeating the analysis using aerosol simulated by the GOCART model and cloud top effective radii derived from the MODIS science team.
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Ma, X., K. von Salzen i J. Cole. "Constraints on interactions between aerosols and clouds on a global scale from a combination of MODIS-CERES satellite data and climate simulations". Atmospheric Chemistry and Physics 10, nr 20 (19.10.2010): 9851–61. http://dx.doi.org/10.5194/acp-10-9851-2010.
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Abstract. Satellite-based cloud top effective radius retrieved by the CERES Science Team were combined with simulated aerosol concentrations from CCCma CanAM4 to examine relationships between aerosol and cloud that underlie the first aerosol indirect (cloud albedo) effect. Evidence of a strong negative relationship between sulphate, and organic aerosols, with cloud top effective radius was found for low clouds, indicating both aerosol types are contributing to the first indirect effect on a global scale. Furthermore, effects of aerosol on the cloud droplet effective radius are more pronounced for larger cloud liquid water paths. While CanAM4 broadly reproduces the observed relationship between sulphate aerosols and cloud droplets, it does not reproduce the dependency of cloud top droplet size on organic aerosol concentrations nor the dependency on cloud liquid water path. Simulations with a modified version of the model yield a more realistic dependency of cloud droplets on organic carbon. The robustness of the methods used in the study are investigated by repeating the analysis using aerosol simulated by the GOCART model and cloud top effective radii derived from the MODIS Science Team.
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Lee, S. S., i J. E. Penner. "Comparison of a global-climate model to a cloud-system resolving model for the long-term response of thin stratocumulus clouds to preindustrial and present-day aerosol conditions". Atmospheric Chemistry and Physics Discussions 9, nr 5 (9.10.2009): 21317–69. http://dx.doi.org/10.5194/acpd-9-21317-2009.
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Abstract. The response of a case of thin, warm marine-boundary-layer (MBL) clouds to preindustrial (PI) and present-day (PD) conditions is simulated by a cloud-system resolving model (CSRM). Here, both the aerosol conditions and environmental conditions match those of a general circulation model (GCM). The environmental conditions are characterized by the initial condition and the large-scale forcings of humidity and temperature, as well as the surface fluxes. The response of the CSRM is compared to that simulated by GCM. The percentage increase of liquid-water path (LWP) due to a change from the PI to PD conditions is ~3 times larger in the CSRM than that in the GCM due to the formation of cumulus clouds. The formation of cumulus clouds is controlled by a larger increase in the surface latent-heat (LH) flux in the PD environment than in the PI environment rather than by the change in aerosols. However, the aerosol increase from the PI to PD level determines the LWP response in the stratocumulus clouds, while the impacts of changes in environmental conditions are negligible for stratocumulus clouds. The conversion of cloud liquid to rain through autoconversion and accretion plays a negligible role in the CSRM in the response to aerosols, whereas it plays a role that is as important as condensation in the GCM. Supplementary simulations show that increasing aerosols increase the sensitivity of the cloud responses to the PI and PD environmental conditions and that aerosol effects on clouds depend on the cloud type; the liquid water path (LWP) of warm cumulus clouds is more sensitive to aerosols than the LWP of stratocumulus clouds.
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Crosswhite, Mark R., Lena N. Jeong, Patrick C. Bailey, J. Brian Jameson, Anastasia Lioubomirov, David Cook, Clarissa Yang, Adam Ozvald, Matthew Lyndon i I. Gene Gillman. "Non-Targeted Chemical Characterization of JUUL-Menthol-Flavored Aerosols Using Liquid and Gas Chromatography". Separations 9, nr 11 (11.11.2022): 367. http://dx.doi.org/10.3390/separations9110367.
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The aerosol constituents generated from JUUL Menthol pods with 3.0% and 5.0% nicotine by weight (Me3 and Me5) are characterized by a non-targeted approach, which was developed to detect aerosol constituents that are not known to be present beforehand or that may be measured with targeted methods. Three replicates from three production batches (n = 9) were aerosolized using two puffing regimens (intense and non-intense). Each of the 18 samples were analyzed by gas chromatography electron ionization mass spectrometry and by liquid chromatography electrospray ionization high-resolving power mass spectrometry. All chemical constituents determined to differ from control were identified and semi-quantified. To have a complete understanding of the aerosol constituents and chemistry, each chemical constituent was categorized into one of five groups: (1) flavorants, (2) harmful and potentially harmful constituents, (3) leachables, (4) reaction products, and (5) chemical constituents that were unable to be identified or rationalized (e.g., chemical constituents that could not be categorized in groups (1–4). Under intense puffing, 74 chemical constituents were identified in Me3 aerosols and 68 under non-intense puffing, with 53 chemical constituents common between both regimens. Eighty-three chemical constituents were identified in Me5 aerosol using an intense puffing regimen and seventy-five with a non-intense puffing regimen, with sixty-two chemical constituents in common. Excluding primary constituents, reaction products accounted for the greatest number of chemical constituents (approximately 60% in all cases, ranging from about 0.05% to 0.1% by mass), and flavorants—excluding menthol—comprised the second largest number of chemical constituents (approximately 25%, ranging consistently around 0.01% by mass). The chemical constituents detected in JUUL aerosols were then compared to known constituents from cigarette smoke to determine the relative chemical complexities and commonalities/differences between the two. This revealed (1) a substantial decrease in the chemical complexity of JUUL aerosols vs. cigarette smoke and (2) that there are between 55 (Me3) and 61 (Me5) unique chemical constituents in JUUL aerosols not reported in cigarette smoke. Understanding the chemical complexity of JUUL aerosols is important because the health effects of combustible cigarette smoke are related to the combined effect of these chemical constituents through multiple mechanisms, not just the effects of any single smoke constituent.
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Waquet, F., C. Cornet, J. L. Deuzé, O. Dubovik, F. Ducos, P. Goloub, M. Herman i in. "Retrieval of aerosol microphysical and optical properties above liquid clouds from POLDER/PARASOL polarization measurements". Atmospheric Measurement Techniques Discussions 5, nr 4 (27.08.2012): 6083–145. http://dx.doi.org/10.5194/amtd-5-6083-2012.
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Abstract. Most of the current aerosol retrievals from passive sensors are restricted to cloud-free scenes, which strongly reduces our ability to monitor the aerosol properties at a global scale. The presence of Aerosols Above Clouds (AAC) affects the polarized light reflected by the cloud layer, as shown by the spaceborne measurements provided by the POlarization and Directionality of Earth Reflectances (POLDER) instrument. We present new developments that allow retrieving the properties of mineral dust particles when they are present above clouds. These particles do not much polarize light but strongly attenuate the polarized cloud bow generated by the beneath liquid cloud layer. The spectral attenuation can be used to qualitatively identify the nature of the particles (i.e. mineral dust particles or biomass burning aerosols) whereas the magnitude of the attenuation is related to the optical thickness of the aerosol layer. We provide accurate polarized radiance calculations for AAC scenes and evaluate the contribution of the POLDER polarization measurements for the simultaneous retrieval of the aerosol and clouds properties. We investigate various scenes with mineral dust particles and biomass burning aerosols above clouds. We found that the magnitude of the primary cloud bow cannot be accurately estimated with a plane parallel transfer radiative code. The errors for the modelling of the polarized cloud bow are between 5 and 8% for homogenous cloudy scenes, as shown by a 3-D radiative transfer code. For clouds, our results confirm that the droplets size distribution is narrow in high latitude ocean regions and that the droplets effective radii retrieved from polarization measurements and from total radiance measurements are generally close for AAC scenes (departures smaller than 2 μm). For the aerosols, the POLDER polarization measurements are primarily sensitive to the particles load, size distribution, shape and real refractive index. An algorithm was developed to retrieve the Aerosol Optical Thickness (AOT) and the Angström exponent above clouds in an operational way. This method was applied to various regions of the world and time period. Large mean AOTs above clouds at 0.865 μm (>0.3) are retrieved for oceanic regions near the coasts of South Africa and California (>0.1) that correspond to biomass burning aerosols whereas even larger mean AOTs above clouds for mineral dust particles (>0.6) are also retrieved near the coasts of Senegal (for June–August 2008). For these regions and time period, the direct AAC radiative forcing is likely to be significant. The final aim of this work is the global monitoring of the aerosol above clouds properties and the estimation of the direct aerosol radiative forcing in cloudy scenes.
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Jeong, Gill-Ran. "Weather Effects of Aerosols in the Global Forecast Model". Atmosphere 11, nr 8 (12.08.2020): 850. http://dx.doi.org/10.3390/atmos11080850.
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The weather effects of aerosol types were investigated using well-posed aerosol climatology through the aerosol sensitivity test of thermodynamic and hydrometeor fields, and the weather forecast performances in July of 2017. The largest aerosol direct radiative forcing (ADRF) in July was due to dust aerosols at the surface and atmosphere, and sulfate at the top of the atmosphere (TOA), respectively. The ADRF of total aerosols had unilateral tendencies in thermodynamic and hydrometeor fields. The contribution of individual aerosols was linearly additive to those of total aerosols in the heat fluxes, heating rates, humidity, and convective precipitation. However, no such linearity existed in temperature, geopotential height, cloud liquid or ice contents, and large-scale precipitation. Dust was the most influential forcing agent in July among five aerosol types due to the largest light-absorption capacity. Such unilateral tendencies of total aerosols and a part of the linearity of individual aerosols were exerted on the weather systems. The verification of medium-range forecasts showed that aerosols alleviated the overestimation of surface shortwave (SW) downward fluxes, the negative biases of temperature and geopotential heights at TOA and surface, and the underestimation in light and moderate precipitation. In contrast, they enhanced warm biases at the mid-atmosphere and underestimation in heavy precipitations, particularly negative biases in the intertropical convergence zone (ITCZ). Weather forecast scores including current aerosol information were improved in geopotential height (GPH) of the northern hemisphere (NH); however, they got worse in the temperature and the upper atmosphere GPH of the southern hemisphere (SH), which was mostly due to black carbon (BC) aerosols in the tropical regions. The missing mechanisms such as aerosol–cloud interactions, better aerosol spectral optical properties including mixing states and aging, and the near-real-time (NRT) based aerosol loading data are worthwhile to be tried in the near future for fixing the intrinsic underestimation of precipitation in ITCZ and surface radiative fluxes in the desert and biomass burning area.
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Murray-Watson, Rebecca J., i Edward Gryspeerdt. "Stability-dependent increases in liquid water with droplet number in the Arctic". Atmospheric Chemistry and Physics 22, nr 9 (3.05.2022): 5743–56. http://dx.doi.org/10.5194/acp-22-5743-2022.
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Abstract. The effects of aerosols on cloud microphysical properties are a large source of uncertainty when assessing anthropogenic climate change. The aerosol–cloud relationship is particularly unclear in high-latitude polar regions due to a limited number of observations. Cloud liquid water path (LWP) is an important control on cloud radiative properties, particularly in the Arctic, where clouds play a central role in the surface energy budget. Therefore, understanding how aerosols may alter cloud LWP is important, especially as aerosol sources such as industry and shipping move further north in a warming Arctic. Using satellite data, this work investigates the effects of aerosols on liquid Arctic clouds over open ocean by considering the relationship between cloud droplet number concentration (Nd) and LWP, an important component of the aerosol–LWP relationship. The LWP response to Nd varies significantly across the region, with increases in LWP with Nd observed at very high latitudes in multiple satellite datasets, with this positive signal observed most strongly during the summer months. This result is in contrast to the negative response typically seen in global satellite studies and previous work on Arctic clouds showing little LWP response to aerosols. The lower tropospheric stability (LTS) was found to be an important control on the spatial variations in LWP response, strongly influencing the sign and magnitude of the Nd–LWP relationship, with increases in LWP in high-stability environments. The influence of humidity varied depending on the stability, with little impact at low LTS but a strong influence at high LTS. The mean Nd state does not dominate the LWP response, despite the non-linearities in the relationship. As the Nd–LWP sensitivity changed from positive to negative when moving from high- to low-LTS environments, this work shows evidence of a temperature-dependent aerosol indirect effect. Additionally, the LWP–LTS relationship changes with Nd, generating an aerosol-dependent cloud feedback. As the LTS is projected to decrease and the boundary layer to become more polluted in a future Arctic, these results show that aerosol increases may produce lower cloud water paths. This shift to more unstable environments implies that LWP adjustments shift from enhancing the Twomey effect by 8 % to offsetting it by around 40 %, with this warming effect having potential consequences for sea ice extent.
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Cheng, Y. S., B. T. Chen i H. C. Yeh. "Size measurement of liquid aerosols". Journal of Aerosol Science 17, nr 5 (styczeń 1986): 803–9. http://dx.doi.org/10.1016/0021-8502(86)90034-0.
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Gryspeerdt, Edward, Tom Goren, Odran Sourdeval, Johannes Quaas, Johannes Mülmenstädt, Sudhakar Dipu, Claudia Unglaub, Andrew Gettelman i Matthew Christensen. "Constraining the aerosol influence on cloud liquid water path". Atmospheric Chemistry and Physics 19, nr 8 (18.04.2019): 5331–47. http://dx.doi.org/10.5194/acp-19-5331-2019.
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Abstract. The impact of aerosols on cloud properties is one of the largest uncertainties in the anthropogenic radiative forcing of the climate. Significant progress has been made in constraining this forcing using observations, but uncertainty remains, particularly in the magnitude of cloud rapid adjustments to aerosol perturbations. Cloud liquid water path (LWP) is the leading control on liquid-cloud albedo, making it important to observationally constrain the aerosol impact on LWP. Previous modelling and observational studies have shown that multiple processes play a role in determining the LWP response to aerosol perturbations, but that the aerosol effect can be difficult to isolate. Following previous studies using mediating variables, this work investigates use of the relationship between cloud droplet number concentration (Nd) and LWP for constraining the role of aerosols. Using joint-probability histograms to account for the non-linear relationship, this work finds a relationship that is broadly consistent with previous studies. There is significant geographical variation in the relationship, partly due to role of meteorological factors (particularly relative humidity). The Nd–LWP relationship is negative in the majority of regions, suggesting that aerosol-induced LWP reductions could offset a significant fraction of the instantaneous radiative forcing from aerosol–cloud interactions (RFaci). However, variations in the Nd–LWP relationship in response to volcanic and shipping aerosol perturbations indicate that the Nd–LWP relationship overestimates the causal Nd impact on LWP due to the role of confounding factors. The weaker LWP reduction implied by these “natural experiments” means that this work provides an upper bound to the radiative forcing from aerosol-induced changes in the LWP.
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Gantt, B., J. Xu, N. Meskhidze, Y. Zhang, A. Nenes, S. J. Ghan, X. Liu, R. Easter i R. Zaveri. "Global distribution and climate forcing of marine organic aerosol – Part 2: Effects on cloud properties and radiative forcing". Atmospheric Chemistry and Physics 12, nr 14 (25.07.2012): 6555–63. http://dx.doi.org/10.5194/acp-12-6555-2012.
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Abstract. A series of simulations with the Community Atmosphere Model version 5 (CAM5) with a 7-mode Modal Aerosol Model were conducted to assess the changes in cloud microphysical properties and radiative forcing resulting from marine organic aerosols. Model simulations show that the anthropogenic aerosol indirect forcing (AIF) predicted by CAM5 is decreased in absolute magnitude by up to 0.09 W m−2 (7%) when marine organic aerosols are included. Changes in the AIF from marine organic aerosols are associated with small global increases in low-level in-cloud droplet number concentration and liquid water path of 1.3 cm−3 (1.5%) and 0.22 g m−2 (0.5%), respectively. Areas especially sensitive to changes in cloud properties due to marine organic aerosol include the Southern Ocean, North Pacific Ocean, and North Atlantic Ocean, all of which are characterized by high marine organic emission rates. As climate models are particularly sensitive to the background aerosol concentration, this small but non-negligible change in the AIF due to marine organic aerosols provides a notable link for ocean-ecosystem marine low-level cloud interactions and may be a candidate for consideration in future earth system models.
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Lohmann, U. "Global anthropogenic aerosol effects on convective clouds in ECHAM5-HAM". Atmospheric Chemistry and Physics Discussions 7, nr 5 (15.10.2007): 14639–74. http://dx.doi.org/10.5194/acpd-7-14639-2007.
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Abstract. Aerosols affect the climate system by changing cloud characteristics in many ways. They act as cloud condensation and ice nuclei and may have an influence on the hydrological cycle. Here we investigate aerosol effects on convective clouds by extending the double moment cloud microphysics scheme developed for stratiform clouds to convective clouds in the ECHAM5 general circulation model. This increases the liquid water path in the tropics and reduces the sensitivity of the liquid water path with increasing aerosol optical depth in better agreement with observations and large-eddy simulation studies. In simulations in which greenhouse gases and aerosols emissions are increased since pre-industrial times, accounting for microphysics in convective clouds matches most closely the observed increase in precipitation. The total anthropogenic aerosol effect since pre-industrial time is slightly reduced from −1.6 to −1.9 W m−2 when microphysics are only included in stratiform clouds to −1.5 W m−2 when microphysics are included both in stratiform and convective clouds.
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Farmer, Delphine K., Erin K. Boedicker i Holly M. DeBolt. "Dry Deposition of Atmospheric Aerosols: Approaches, Observations, and Mechanisms". Annual Review of Physical Chemistry 72, nr 1 (20.04.2021): 375–97. http://dx.doi.org/10.1146/annurev-physchem-090519-034936.
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Aerosols are liquid or solid particles suspended in the atmosphere, typically with diameters on the order of nanometers to microns. These particles impact air quality and the radiative balance of the planet. Dry deposition is a key process for the removal of aerosols from the atmosphere and plays an important role in controlling the lifetime of atmospheric aerosols. Dry deposition is driven by turbulence and shows a strong dependence on particle size. This review summarizes the mechanisms behind aerosol dry deposition, including measurement approaches, field observations, and modeling studies. We identify several gaps in the literature, including deposition over the cryosphere (i.e., snow and ice surfaces) and the ocean; in addition, we highlight new techniques to measure black carbon fluxes. While recent advances in aerosol instrumentation have enhanced our understanding of aerosol sources and chemistry, dry deposition and other loss processes remain poorly investigated.
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Manigrasso, Maurizio, Carmela Protano, Matteo Vitali i Pasquale Avino. "Passive Vaping from Sub-Ohm Electronic Cigarette Devices". International Journal of Environmental Research and Public Health 18, nr 21 (4.11.2021): 11606. http://dx.doi.org/10.3390/ijerph182111606.
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To investigate passive vaping due to sub-ohm electronic cigarettes (e-cigs), aerosol number size distribution measurements (6 nm–10 µm) were performed during volunteer-vaping sessions. E-liquids, with vegetable glycerin (VG) and propylene glycol (PG), with a VG/PG ratio of 50/50 (with nicotine) and 80/20 (without nicotine), were vaped with a double-coil, single aerosol exit hole at 25–80 W electric power, corresponding to 130–365 kW m−2 heat fluxes and with an octa-coil, four aerosol exit holes atomizers, at 50–150 W electric power, corresponding to 133–398 kW m−2 heat fluxes. At the lowest heat flux, lower particle number concentrations (NTot) were observed for the nicotine-liquid than for the nicotine-free liquid, also due to its higher content of PG, more volatile than VG. For the octa-coil atomizer, at 265 and 398 kW m−2, NTot decreased below the first-generation e-cig, whereas volume concentrations greatly increased, due to the formation of super micron droplets. Higher volume concentrations were observed for the 80/20 VG/PG liquid, because of VG vaporization and of its decomposition products, greater than for PG. For the double coil atomizer, increasing the electric power from 40 W (208 kW m−2) to 80 W (365 kW m−2) possibly led to a critical heat flow condition, causing a reduction of the number concentrations for the VG/PG 50/50 liquid, an increase for the 80/20 VG/PG liquid and a decrease of the volume concentrations for both of them. Coherently, the main mode was at about 0.1 µm on both metrics for both liquids. For the other tests, two main modes (1 and 2 µm) were observed in the volume size distributions, the latter becoming wider at 100 and 150 W (265 and 398 kW m−2), suggesting the increased emission of light condensable decomposition products. The lower aerosol emissions observed at 150 W than at 100 W suggest the formation of gas-phase decomposition products. The observation of low-count high-volume aerosols addresses the relevance of the volume metric upon measuring the second-hand concentration of the aerosols released by sub-ohm e-cigarettes.
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McCoy, Daniel T., Susannah M. Burrows, Robert Wood, Daniel P. Grosvenor, Scott M. Elliott, Po-Lun Ma, Phillip J. Rasch i Dennis L. Hartmann. "Natural aerosols explain seasonal and spatial patterns of Southern Ocean cloud albedo". Science Advances 1, nr 6 (lipiec 2015): e1500157. http://dx.doi.org/10.1126/sciadv.1500157.
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Atmospheric aerosols, suspended solid and liquid particles, act as nucleation sites for cloud drop formation, affecting clouds and cloud properties—ultimately influencing the cloud dynamics, lifetime, water path, and areal extent that determine the reflectivity (albedo) of clouds. The concentration Nd of droplets in clouds that influences planetary albedo is sensitive to the availability of aerosol particles on which the droplets form. Natural aerosol concentrations affect not only cloud properties themselves but also modulate the sensitivity of clouds to changes in anthropogenic aerosols. It is shown that modeled natural aerosols, principally marine biogenic primary and secondary aerosol sources, explain more than half of the spatiotemporal variability in satellite-observed Nd. Enhanced Nd is spatially correlated with regions of high chlorophyll a, and the spatiotemporal variability in Nd is found to be driven primarily by high concentrations of sulfate aerosol at lower Southern Ocean latitudes (35o to 45oS) and by organic matter in sea spray aerosol at higher latitudes (45o to 55oS). Biogenic sources are estimated to increase the summertime mean reflected solar radiation in excess of 10 W m–2 over parts of the Southern Ocean, which is comparable to the annual mean increases expected from anthropogenic aerosols over heavily polluted regions of the Northern Hemisphere.
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Li, Zhanqing, Jianping Guo, Aijun Ding, Hong Liao, Jianjun Liu, Yele Sun, Tijian Wang, Huiwen Xue, Hongsheng Zhang i Bin Zhu. "Aerosol and boundary-layer interactions and impact on air quality". National Science Review 4, nr 6 (22.09.2017): 810–33. http://dx.doi.org/10.1093/nsr/nwx117.
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Abstract Air quality is concerned with pollutants in both the gas phase and solid or liquid phases. The latter are referred to as aerosols, which are multifaceted agents affecting air quality, weather and climate through many mechanisms. Unlike gas pollutants, aerosols interact strongly with meteorological variables with the strongest interactions taking place in the planetary boundary layer (PBL). The PBL hosting the bulk of aerosols in the lower atmosphere is affected by aerosol radiative effects. Both aerosol scattering and absorption reduce the amount of solar radiation reaching the ground and thus reduce the sensible heat fluxes that drive the diurnal evolution of the PBL. Moreover, aerosols can increase atmospheric stability by inducing a temperature inversion as a result of both scattering and absorption of solar radiation, which suppresses dispersion of pollutants and leads to further increases in aerosol concentration in the lower PBL. Such positive feedback is especially strong during severe pollution events. Knowledge of the PBL is thus crucial for understanding the interactions between air pollution and meteorology. A key question is how the diurnal evolution of the PBL interacts with aerosols, especially in vertical directions, and affects air quality. We review the major advances in aerosol measurements, PBL processes and their interactions with each other through complex feedback mechanisms, and highlight the priorities for future studies.
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Croft, B., J. R. Pierce, R. V. Martin, C. Hoose i U. Lohmann. "Strong sensitivity of aerosol concentrations to convective wet scavenging parameterizations in a global model". Atmospheric Chemistry and Physics Discussions 12, nr 1 (19.01.2012): 1687–732. http://dx.doi.org/10.5194/acpd-12-1687-2012.
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Abstract. This study examines the influences of assumptions in convective wet scavenging parameterizations on global climate model simulations of aerosol concentrations and wet deposition. To facilitate this study, an explicit representation of the uptake of aerosol mass and number into convective cloud droplets and ice crystals by the processes of activation, collisions, freezing and evaporation is introduced into the ECHAM5-HAM model. This development replaces the prescribed aerosol cloud-droplet-borne/ice-crystal-borne fractions of the standard model. Relative to the standard model, the more consistent treatment between convective aerosol-cloud microphysical processes yields a reduction of aerosol wet removal in mixed liquid and ice phase convective clouds by at least a factor of two, and the global, annual mean aerosol burdens are increased by at least 20%. Two limiting cases regarding the wet scavenging of entrained aerosols are considered. In the first case, aerosols entering convective clouds at their bases are the only aerosols that are scavenged into cloud droplets, and are susceptible to removal by convective precipitation formation. In the second case, aerosols that are entrained into the cloud above the cloud base layer can activate, can collide with existing cloud droplets and ice crystals, and can subsequently be removed by precipitation formation. The limiting case that allows aerosols entrained above cloud base to become cloud-droplet-borne and ice-crystal-borne reduces the annual and global mean aerosol burdens by 30% relative to the other limiting case, and yields the closest agreement with global aerosol optical depth retrievals, and black carbon vertical profiles from aircraft campaigns (changes of about one order of magntiude in the upper troposphere). Predicted convective cloud droplet number concentrations are doubled in the tropical middle troposphere when aerosols entrained above cloud base are allowed to activate. These results show that aerosol concentrations and wet deposition predicted in a global model are strongly sensitive to the assumptions made regarding the wet scavenging of aerosols in convective clouds.
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Morand, Gabriel, Pascale Chevallier, Cédric Guyon, Michael Tatoulian i Diego Mantovani. "In-Situ One-Step Direct Loading of Agents in Poly(acrylic acid) Coating Deposited by Aerosol-Assisted Open-Air Plasma". Polymers 13, nr 12 (10.06.2021): 1931. http://dx.doi.org/10.3390/polym13121931.
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In biomaterials and biotechnology, coatings loaded with bioactive agents are used to trigger biological responses by acting as drug release platforms and modulating surface properties. In this work, direct deposition of poly(acrylic acid) coatings containing various agents, such as dyes, fluorescent molecules, was achieved by aerosol-assisted open-air plasma. Using an original precursors injection strategy, an acrylic acid aerosol was loaded with an aqueous aerosol and deposited on silicon wafers. Results clearly showed that agents dissolved in the aqueous aerosol were successfully entrapped in the final coating. The effect of aerosols concentration, flow rate, and treatment time, on the coating morphology and the amount of entrapped agents, was also investigated. It was demonstrated that this process has the potential to entrap a tunable amount of any sensible water-soluble agent without altering its activity. To the best of our knowledge, this is the first time that the loading of an aqueous aerosol in coatings deposited by plasma from a liquid aerosol precursor is reported. This innovative approach complements plasma deposition of coatings loaded with bioactive agents from aqueous aerosols with the use of non-volatile liquid precursors.
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Graham, Emma, Lynda McCaig, Gloria Shui-Kei Lau, Akash Tejura, Anne Cao, Yi Y. Zuo i Ruud Veldhuizen. "E-cigarette aerosol exposure of pulmonary surfactant impairs its surface tension reducing function". PLOS ONE 17, nr 11 (9.11.2022): e0272475. http://dx.doi.org/10.1371/journal.pone.0272475.
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Introduction E-cigarette (EC) and vaping use continue to remain popular amongst teenage and young adult populations, despite several reports of vaping associated lung injury. One of the first compounds that EC aerosols comes into contact within the lungs during a deep inhalation is pulmonary surfactant. Impairment of surfactant’s critical surface tension reducing activity can contribute to lung dysfunction. Currently, information on how EC aerosols impacts pulmonary surfactant remains limited. We hypothesized that exposure to EC aerosol impairs the surface tension reducing ability of surfactant. Methods Bovine Lipid Extract Surfactant (BLES) was used as a model surfactant in a direct exposure syringe system. BLES (2ml) was placed in a syringe (30ml) attached to an EC. The generated aerosol was drawn into the syringe and then expelled, repeated 30 times. Biophysical analysis after exposure was completed using a constrained drop surfactometer (CDS). Results Minimum surface tensions increased significantly after exposure to the EC aerosol across 20 compression/expansion cycles. Mixing of non-aerosolized e-liquid did not result in significant changes. Variation in device used, addition of nicotine, or temperature of the aerosol had no additional effect. Two e-liquid flavours, menthol and red wedding, had further detrimental effects, resulting in significantly higher surface tension than the vehicle exposed BLES. Menthol exposed BLES has the highest minimum surface tensions across all 20 compression/expansion cycles. Alteration of surfactant properties through interaction with the produced aerosol was observed with a basic e-liquid vehicle, however additional compounds produced by added flavourings appeared to be able to increase inhibition. Conclusion EC aerosols alter surfactant function through increases in minimum surface tension. This impairment may contribute to lung dysfunction and susceptibility to further injury.
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Chang, Chiao-Wei, Wei-Ting Chen i Yi-Chun Chen. "Susceptibility of East Asian Marine Warm Clouds to Aerosols in Winter and Spring from Co-Located A-Train Satellite Observations". Remote Sensing 13, nr 24 (20.12.2021): 5179. http://dx.doi.org/10.3390/rs13245179.
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We constructed the A-Train co-located aerosol and marine warm cloud data from 2006 to 2010 winter and spring over East Asia and investigated the sensitivities of single-layer warm cloud properties to aerosols under different precipitation statuses and environmental regimes. The near-surface stability (NSS), modulated by cold air on top of a warm surface, and the estimated inversion strength (EIS) controlled by the subsidence are critical environmental parameters affecting the marine warm cloud structure over East Asia and, thus, the aerosols–cloud interactions. Based on our analysis, precipitating clouds revealed higher cloud susceptibility to aerosols as compared to non-precipitating clouds. The cloud liquid water path (LWP) increased with aerosols for precipitating clouds, yet decreased with aerosols for non-precipitating clouds, consistent with previous studies. For precipitating clouds, the cloud LWP and albedo increased more under higher NSS as unstable air promotes more moisture flux from the ocean. Under stronger EIS, the cloud albedo response to aerosols was lower than that under weaker EIS, indicating that stronger subsidence weakens the cloud susceptibility due to more entrainment drying. Our study suggests that the critical environmental factors governing the aerosol–cloud interactions may vary for different oceanic regions, depending on the thermodynamic conditions.
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Liang, H., Z. M. Chen, D. Huang, Y. Zhao i Z. Y. Li. "Impacts of aerosols on the chemistry of atmospheric trace gases: a case study of peroxides and HO<sub>2</sub> radicals". Atmospheric Chemistry and Physics Discussions 13, nr 6 (20.06.2013): 16549–95. http://dx.doi.org/10.5194/acpd-13-16549-2013.
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Abstract. Field measurements of atmospheric peroxides were obtained during the summer on two consecutive years over urban Beijing, and focused on the impacts of aerosols on the chemistry of peroxide compounds and hydroperoxyl radicals (HO2). The major peroxides were determined to be hydrogen peroxide (H2O2), methyl hydroperoxide (MHP), and peroxyacetic acid (PAA). A negative correlation was found between H2O2 and PAA in rainwater, providing evidence for a conversion between H2O2 and PAA in the aqueous phase. A standard gas phase chemistry model based on the NCAR Master Mechanism provided a good reproduction of the observed H2O2 profile on non-haze days but greatly overpredicted the H2O2 level on haze days. We attribute this overprediction to the reactive uptake of HO2 by the aerosols, since there was greatly enhanced aerosol loading and aerosol liquid water content on haze days. The discrepancy between the observed and modeled H2O2 can be diminished by adding to the model a newly proposed transition metal ion catalytic mechanism of HO2 in aqueous aerosols. This confirms the importance of the aerosol uptake of HO2 and the subsequent aqueous phase reactions in the reduction of H2O2. The closure of HO2 and H2O2 between the gas and aerosol phases suggests that the aerosols do not have a net reactive uptake of H2O2, because the conversion of HO2 to H2O2 on aerosols compensates for the H2O2 loss. Laboratory studies for the aerosol uptake of H2O2 in the presence of HO2 are urgently required to better understand the aerosol uptake of H2O2 in the real atmosphere.
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Liang, H., Z. M. Chen, D. Huang, Y. Zhao i Z. Y. Li. "Impacts of aerosols on the chemistry of atmospheric trace gases: a case study of peroxides and HO<sub>2</sub> radicals". Atmospheric Chemistry and Physics 13, nr 22 (20.11.2013): 11259–76. http://dx.doi.org/10.5194/acp-13-11259-2013.
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Abstract. Field measurements of atmospheric peroxides were obtained during the summer on two consecutive years over urban Beijing, which highlighted the impacts of aerosols on the chemistry of peroxide compounds and hydroperoxyl radicals (HO2). The major peroxides were determined to be hydrogen peroxide (H2O2), methyl hydroperoxide (MHP), and peroxyacetic acid (PAA). A negative correlation was found between H2O2 and PAA in rainwater, providing evidence for a conversion between H2O2 and PAA in the aqueous phase. A standard gas phase chemistry model based on the NCAR Master Mechanism provided a good reproduction of the observed H2O2 profile on non-haze days but greatly overpredicted the H2O2 level on haze days. We attribute this overprediction to the reactive uptake of HO2 by the aerosols, since there was greatly enhanced aerosol loading and aerosol liquid water content on haze days. The discrepancy between the observed and modeled H2O2 can be diminished by adding to the model a newly proposed transition metal ion catalytic mechanism of HO2 in aqueous aerosols. This confirms the importance of the aerosol uptake of HO2 and the subsequent aqueous phase reactions in the reduction of H2O2. The closure of HO2 and H2O2 between the gas and aerosol phases suggests that the aerosols do not have a net reactive uptake of H2O2, because the conversion of HO2 to H2O2 on aerosols compensates for the H2O2 loss. Laboratory studies for the aerosol uptake of H2O2 in the presence of HO2 are urgently required to better understand the aerosol uptake of H2O2 in the real atmosphere.
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Niu, Feng, i Zhanqing Li. "Systematic variations of cloud top temperature and precipitation rate with aerosols over the global tropics". Atmospheric Chemistry and Physics 12, nr 18 (21.09.2012): 8491–98. http://dx.doi.org/10.5194/acp-12-8491-2012.
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Abstract. Aerosols may modify cloud properties and precipitation via a variety of mechanisms with varying and contradicting consequences. Using a large ensemble of satellite data acquired by the Moderate Resolution Imaging Spectroradiometer onboard the Earth Observing System's Aqua platform, the CloudSat cloud profiling radar and the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) satellite over the tropical oceans, we identified two distinct correlations of clouds and precipitation with aerosol loading. Cloud-top temperatures are significantly negatively correlated with increasing aerosol index (AI) over oceans and aerosol optical depth (AOT) over land for deep mixed-phase clouds with liquid droplets near the warm bases and ice crystals near the cold tops; no significant changes were found for uniformly liquid clouds. Precipitation rates are positively correlated with the AI for mixed-phase clouds, but negatively correlated for liquid clouds. These distinct correlations might be a manifestation of two potential mechanisms: the invigoration effect (which enhances convection and precipitation) and the microphysical effect (which suppresses precipitation). We note that the highly limited information garnered from satellite products cannot unequivocally support the causal relationships between cloud-top temperature/precipitation rate and aerosol loading. But if aerosols are indeed the causes for the observed relationships, they may change the overall distribution of precipitation, leading to a more extreme and unfavorable rainfall pattern of suppressing light rains and fostering heavy rains.
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Andersen, Hendrik, Jan Cermak, Julia Fuchs, Reto Knutti i Ulrike Lohmann. "Understanding the drivers of marine liquid-water cloud occurrence and properties with global observations using neural networks". Atmospheric Chemistry and Physics 17, nr 15 (8.08.2017): 9535–46. http://dx.doi.org/10.5194/acp-17-9535-2017.
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Abstract. The role of aerosols, clouds and their interactions with radiation remain among the largest unknowns in the climate system. Even though the processes involved are complex, aerosol–cloud interactions are often analyzed by means of bivariate relationships. In this study, 15 years (2001–2015) of monthly satellite-retrieved near-global aerosol products are combined with reanalysis data of various meteorological parameters to predict satellite-derived marine liquid-water cloud occurrence and properties by means of region-specific artificial neural networks. The statistical models used are shown to be capable of predicting clouds, especially in regions of high cloud variability. On this monthly scale, lower-tropospheric stability is shown to be the main determinant of cloud fraction and droplet size, especially in stratocumulus regions, while boundary layer height controls the liquid-water amount and thus the optical thickness of clouds. While aerosols show the expected impact on clouds, at this scale they are less relevant than some meteorological factors. Global patterns of the derived sensitivities point to regional characteristics of aerosol and cloud processes.
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Wang, Yuan, Xiaojian Zheng, Xiquan Dong, Baike Xi, Peng Wu, Timothy Logan i Yuk L. Yung. "Impacts of long-range transport of aerosols on marine-boundary-layer clouds in the eastern North Atlantic". Atmospheric Chemistry and Physics 20, nr 23 (2.12.2020): 14741–55. http://dx.doi.org/10.5194/acp-20-14741-2020.
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Abstract. Vertical profiles of aerosols are inadequately observed and poorly represented in climate models, contributing to the current large uncertainty associated with aerosol–cloud interactions. The US Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Aerosol and Cloud Experiments in the Eastern North Atlantic (ACE-ENA) aircraft field campaign near the Azores islands provided ample observations of vertical distributions of aerosol and cloud properties. Here we utilize the in situ aircraft measurements from the ACE-ENA and ground-based remote-sensing data along with an aerosol-aware Weather Research and Forecast (WRF) model to characterize the aerosols due to long-range transport over a remote region and to assess their possible influence on marine-boundary-layer (MBL) clouds. The vertical profiles of aerosol and cloud properties measured via aircraft during the ACE-ENA campaign provide detailed information revealing the physical contact between transported aerosols and MBL clouds. The European Centre for Medium-Range Weather Forecasts Copernicus Atmosphere Monitoring Service (ECMWF-CAMS) aerosol reanalysis data can reproduce the key features of aerosol vertical profiles in the remote region. The cloud-resolving WRF sensitivity experiments with distinctive aerosol profiles suggest that the transported aerosols and MBL cloud interactions (ACIs) require not only aerosol plumes to get close to the marine-boundary-layer top but also large cloud top height variations. Based on those criteria, the observations show that the occurrence of ACIs involving the transport of aerosol over the eastern North Atlantic (ENA) is about 62 % in summer. For the case with noticeable long-range-transport aerosol effects on MBL clouds, the susceptibilities of droplet effective radius and liquid water content are −0.11 and +0.14, respectively. When varying by a similar magnitude, aerosols originating from the boundary layer exert larger microphysical influence on MBL clouds than those entrained from the free troposphere.
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Guo, H., J. E. Penner, M. Herzog i H. Pawlowska. "Examining aerosol indirect effect under contrasting environments during the ACE-2 experiment". Atmospheric Chemistry and Physics Discussions 6, nr 6 (20.11.2006): 11561–96. http://dx.doi.org/10.5194/acpd-6-11561-2006.
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Abstract. The Active Tracer High-resolution Atmospheric Model (ATHAM) has been adopted to examine the aerosol indirect effect in contrasting clean and polluted cloudy boundary layers during the Second Aerosol Characterization Experiment (ACE-2). Model results are in good agreement with available in-situ observations, which provides confidence in the results of ATHAM. Sensitivity tests have been conducted to examine the response of the cloud fraction (CF), cloud liquid water path (LWP), and cloud optical depth (COD) to changes in aerosols in the clean and polluted cases. It is shown for two cases that CF and LWP would decrease or remain nearly constant with an increase in aerosols, a result which shows that the second aerosol indirect effect is positive or negligibly small in these cases. Further investigation indicates that the background meteorological conditions play a critical role in the response of CF and LWP to aerosols. When large-scale subsidence is weak as in the clean case, the dry overlying air above the cloud is more efficiently entrained into the cloud, and in so doing, removes cloud water more efficiently, and results in lower CF and LWP when aerosol burden increases. However, when the large-scale subsidence is strong as in the polluted case, the growth of the cloud top is suppressed and the entrainment drying makes no significant difference when aerosol burden increases. Therefore, the CF and LWP remain nearly constant. In both the clean and polluted cases, the COD tends to increase with aerosols, and the total aerosol indirect effect (AIE) is negative even when the CF and LWP decrease with an increase in aerosols. Therefore, the first AIE dominates the response of the cloud to aerosols.