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Ruru, Tania Suzanne, i n/a. "The Resource Management Act 1991 and Nga Iwi Maori". University of Otago. Faculty of Law, 1997. http://adt.otago.ac.nz./public/adt-NZDU20070530.141814.
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This thesis describes the sections in the Resource Management Act 1991 of particular relevance for nga Iwi Maori and assesses how well these facilitate involvement for Maori in the management of New Zealand�s resources. The method of assessment used is one of comparison between the schemes and philosophies of 1991 Act, and the active involvement of Maori in decision-making for their resources which is requires by Article ii of the Treaty of Waitangi (Te Tiriti o Waitangi).
Part i describes the Maori world view of the environment and outlines the Treaty of Waitangi and its relevance to resource management law.
Part ii describes the purpose and principles contained in sections 5, 6(e), 7(a), and 8 of the 1991 Act. Chapter Three provides an overview of the relationship between the purpose and principles. Chapter Four discusses the purpose in section 5 and proclaims that the inclusion of sustainability as a purpose in resource management legislation is advantageous in terms of the indirect furtherance of Maori conservation aspirations for the enviroment. It also describes how the cultural wellbeing of Maori has been interpreted to be an express part of the purpose of the Act. Chapter Five provides an analysis of section 6(e) which makes the relationship of Maori and their culture and traditions with their taonga a matter of national importance under the Act. Chapter Six describes section 7(a) and kaitiakitanga which must be given particular regard under the Act. Chapter Seven discusses section 8 and the content and meaning of the principles of the Treaty of Waitangi. Part ii concludes that while the facilitation of Maori involvement in the management and protection of natural and physical resources is improved under this Act, these sections are an insufficient safeguard for Maori interests.
Part iii assesses the other sections in the Act which have a bearing on Maori involvement in resource management processes. Chapter Eight explores the planning system. Chapter Nine describes the resource consent processes in the 1991 Act. Chapter Ten comments on various procedural provisions which introduce tikanga Maori into the Act, and Chapter Eleven is devoted to exploring the sections in the Act which in the writer�s opinion provide the most potential for recognition of rangatiratanga in a limited form. This Part proclaims that the emphasis in the Act is very much on consultation with nga Iwi Maori as an effective means for their involement in resource management. It is submitted that this is not the active participation in decision-making that Maori seek and which is guaranteed under Article ii of the Treaty of Waitangi.
Chapter Twelve acknowledges that involvement of nga Iwi Maori in processes under the 1991 Act will rely to some extent on the content of policy statements and plans produced by the local authorities. An analysis of the Proposed Otago Regional Policy Statement is undertaken to explore how the concerns of Kai Tahu have been incorporated into the statement.
Chapter Thirteen ends by concluding that while the 1991 Act does provide for increased Maori involvement in resource management processes in New Zealand it does not facilitate the decision-making role guaranteed by Article ii of the Treaty of Waitangi.
2
Williams, Joseph Victor. "Te Mana Motuhake Me Te Iwi Maori : indigineous self determination". Thesis, University of British Columbia, 1988. http://hdl.handle.net/2429/27767.
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Maria Maori Motuhake or Maori self determination is developing into one of the most pressing political and legal issues in modern New Zealand. The Maori struggle for recognition of that right is a long one. It began with contact with British colonisers, and has continued in different forms throughout New Zealand's history. The following thesis suggests that that struggle is one which the Maori share with Indigenous peoples throughout the world. The recognition in law of Mana Maori Motuhake in New Zealand will come from an understanding, by both Maori and Pakeha, of the international nature of that struggle.
Accordingly the essential purpose of this thesis is to put the issue of Maori rights into an international and colonial perspective. In Part I, the question of Indigenous self determination is discussed in the context of historical and contemporary developments in international law. It is concluded firstly that there is room for the proposition that a right of Indigenous self determination can be drawn from the current state of international law. Secondly, it is argued that recent developments in the United Nations suggest positive recognition of that right will occur in the near future.
In Part II, the development of colonial law in the United States, Canada and New Zealand add a further dimension to this international perspective. In this part parallel developments in the three countries are highlighted to prove the 'indivisibility' of colonialism, and the inexorable development in modern law toward recognition of the 'colonial paradigm'- Native title and Native sovereignty.Law, Peter A. Allard School of
Graduate
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Anich, Vanessa F., i n/a. "Iwi management plans and consultation under the Resource Management Act 1991". University of Otago. Department of Geography, 1995. http://adt.otago.ac.nz./public/adt-NZDU20070531.125119.
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The Resource Management Act (hereafter �the RM Act�) has significantly changed the statutory framework for natural resource management in New Zealand. It is the result of a three year process of law reform, the largest law reform exercise ever undertaken in this country (M. F. E., 1992). It consolidates into one statute most of the laws that regulate the use of New Zealand�s natural and physical resources.
The purpose of the RM Act is the promotion of �the sustainable management of natural and physical resources�. The focus of this Project is the introduction into the RM Act of a number of positive obligations dealing with Maori interests, the principles of the Treaty of Waitangi, consultation, and iwi management plans.
The RM Act contains provisions designed to, amongst other things, safeguard Maori heritage interests, make consultation between consent agencies and tangata whenua mandatory in the preparation of local authority plans and policy statements, provide for the delegation of authority to iwi, and to instruct decision makers to take the principles of the Treaty into account when exercising functions and duties under the act. These provisions provide new opportunities for a distinctive Maori dimension to be incorporated into resource management decision making practice.
The ability is present within the RM Act to remove some of the barriers that have prevented Maori from participating in decisions on the management of resources. The interest of tangata whenua in natural resource management are now a part of the statutory framework. This has the effect of increasing the interaction, consultation and accountability of iwi and local government when natural resources are managed.
The realization of the potential of these iwi provisions in the RM Act will require decision makers and local iwi to develop a working relationship by exploring models of consultation and co-management. For the relationship to be effective, it will need to be based on mutual tolerance and cooperation. The rights and duties in the relationship are complementary and rest with both parties. Long-term sucess will require a commitment from both local authorities and tangata whenua to work together in good faith and with clarity of purpose to develop kaupapa (plan, strategy) for the present and future management of natural resources.
4
Doherty, William. "Mātauranga Tūhoe: the centrality of Mātauranga-a-iwi to Māori education". Thesis, University of Auckland, 2010. http://hdl.handle.net/2292/5639.
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The general aim of this thesis is to improve understanding about the place of mātauranga-a-iwi in the education system. In the modern education system, the linked terms mātauranga-a-iwi, mātauranga Māori, and kaupapa Māori theory are used to define Māori identity and Māori knowledge. But this thesis argues that these concepts must be grounded in a 'real', environmentally-located knowledge within tribal lands. It follows that mātauranga Māori, and kaupapa Māori theory, with their roots in mātauranga-a-iwi, must ultimately be understood as a relationship between the tribal environment and its people. The tribal environment, or rohe, of Tūhoe is the illustrative site of mātauranga-a-iwi for this thesis. The rohe for Tūhoe is Te Urewera. The relationship that exists between Tūhoe and this landscape is outlined mapping this intimate relationship (chapter 2). The thesis does the work of explaining what mātauranga-a-Tūhoe is, and how it has developed through a series of historical engagements. These things were learned by me at the feet of my grandmother (chapter 1). The engagements include: iwi interactions (chapter 6), Pakeha and Crown engagements (chapter 7), with more recent economic realities (chapter 4), and education (chapter 5). The key concepts of mātauranga Māori, kaupapa Māori theory, and mātauranga-a-iwi, as well as being grounded in a 'real', environmentally-located base, must be viewed as inseparable strands working collectively to enhance the understanding of the other. The indivisible strands are presented in a diagrammatic form (chapter 3). By mapping the complexities of what is mātauranga Tūhoe (chapter 8) this thesis illustrates the level of detailed understanding that needs to be included in the education system in order for mātauranga-a-iwi and kaupapa Māori theory to be properly understood and engaged for Māori educational success.
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Doherty, William. "Mātauranga Tūhoe : the centrality of mātauranga-a-iwi to Māori education /". e-Thesis University of Auckland, 2009. http://hdl.handle.net/2292/5639.
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Thesis (PhD--Education)--University of Auckland, 2009."A thesis submitted in fulfilment of the requirements for the degree of Doctor of Philosophy in Education, University of Auckland, New Zealand, August 2009." Includes bibliographical references.
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Rewai-Couch, Melanie R. "Puna kōrero: iwi and schools working together to support Māori student success". Thesis, University of Canterbury. Education, 2015. http://hdl.handle.net/10092/10250.
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This thesis explores the notion that iwi and schools working together can contribute to
culturally responsive curriculum and schooling. It investigates how some schools have
formed genuine education partnerships with iwi, and provides answers to the following
question: in what ways are iwi and schools working together to support Māori students?
An understanding of communities of practice, and what Māori student success looks like,
are essential. Imperatives for education partnerships and the educational policy, and
drivers for partnership are foundational in understanding and connecting collaboration
between iwi and schools with the wider educational picture in Aotearoa New Zealand.
In New Zealand, Māori are not as successful as their non-Māori peers. Approaches to
achieving education equity, including collaboration with iwi and Māori, is important for
informing education approaches and strategy. How those approaches are informed,
developed and implemented is equally important in achieving models likely to positively
affect Māori achievement in education. This is also important in ensuring that
participation expectations of iwi are co-constructed, reasonable and appropriately
resourced.
The theoretical base of this study draws upon the literature review on collaboration
between Māori/iwi and the New Zealand education system, as well as international
literature on supporting Indigenous students, using a community of practice approach.
The metaphor of ‘puna kōrero’ is used in this research, as an approach allowing for
consideration of different sites of investigation using an organic, kaupapa (issue, topic)
Māori perspective. The three puna kōrero explored are Te Kauhua: A Ministry of
Education funded professional development programme for schools and iwi; iwi voices:
six iwi education representatives speak about their experiences working with schools and
advancing their iwi education aspirations; Wai Study Help: an English-literacy
programme operating in a kura kaupapa Māori (Māori immersion schooling) setting that
has partnerships with its local university and iwi. From these puna kōrero, implications
for iwi, schools and the Ministry of Education are considered.
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Exploration of the three puna kōrero identified passionate leadership and purposeful
membership, funding and resourcing, monitoring and defining success,
whakawhanaungatanga (nurturing relationships with others) and involvement of whānau
(family) as key themes. Motivations for schools and iwi to work together are explored,
along with rationale for the Ministry of Education’s support of iwi-school communities of
practice. A framework for iwi-school communities of practice is proposed, including
recommendations for iwi, schools and the Ministry of Education.
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Raerino, Kimiora. "He tirohanga a Ngāti Awa uri taone mo ngā ahuatanga Māori an urban Ngāti Awa perspective on identity and culture : a thesis submitted to the Auckland University of Technology in partial fulfilment of the requirements for the degree Master of Arts, 2007". Click here to access this resource online, 2007. http://hdl.handle.net/10292/423.
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Thesis (MA--Maori Development) -- AUT University, 2007.Includes bibliographical references. Also held in print (v, 105 leaves : col. ill. ; 30 cm.) in the Archive at the City Campus (T 305.899442 RAE)
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Highman, Alexandra Emma-Jane. "Te iwi o Ngai Tahu : an examination of Ngai Tahu's approach to, and internal expression of, tino rangatiratanga". Thesis, University of Canterbury. Department of Sociology, 1997. http://hdl.handle.net/10092/4669.
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This thesis establishes a comprehensive understanding of the
contemporary exercise of tino rangatiratanga by Ngai Tahu. This
is achieved by examining Ngai Tahu's approach to, and internal
expression of, tino rangatiratanga.
In 1996 the Te Runanga 0 Ngai Tahu Act was passed. This, for
the first time since the Treaty of Waitangi and Pakeha
colonisation, legally recognised an organisational structure that
was tribally derived and, in turn, allowed for a new degree of
self-determination. This qualitative research provides an insight
into the directions Ngai Tahu is embarking upon under its new
administration in the attainment of tino rangatiratanga.
Ngai Tahu's new organisational structure, since its formal
inception, has not operated without its problems. These arise
from a transitional phase which indicates a shift in paradigm
from grievance mode to development mode. Internally, this has
created a time of tension. Some runanga struggle to reaffirm
their rangatiratanga in the wake of its tribal collectivisation
represented in Te Runanga o Ngai Tahu. During this phase,
communication throughout the organisational structure is
paramount. This will ensure the recognition of rangatiratanga at
all its levels and, thus, maintain tribal cohesion.
Within Ngai Tahu, tino rangatiratanga is approached differently
by its beneficiaries depending upon what element of the tribal
make-up is being emphasised. For some, tino rangatiratanga is
that expressed by the administrative structure, where it is
translated into the notion of achieving economic sovereignty for
the iwi. For others, it is derived from an individual's whakapapa
(genealogy), with its collective expression revolving around the
hapu and runanga only. With knowledge of these two divergent
approaches to tino rangatiratanga, Ngai Tahu can negotiate a
course of future development that embraces both the tribal,
runanga and individual elements inherent in them both.
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Reese, Alistair William. "Are You Listening? The Voice of Waitaha, A Forgotten People". The University of Waikato, 2006. http://hdl.handle.net/10289/2408.
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This thesis is a study of Waitaha, a Bay of Plenty iwi that has been marginalized through the loss of most of its land, much of its language, tikanga, and mana. The purpose of the work is to communicate, through the 'voice' and the history of the people, a chronicle, of their alienation to a Pākehā audience that remains in large part ignorant and distant from their plight. The thesis is motivated by an academic responsibility to the Treaty of Waitangi and the lack of understanding to the present needs of Māori as evidenced for example, by the support for the January 2004 Orewa speech, by the leader of the National Party, Don Brash. It is predicated upon the understanding that this response, which minimalises the impact of colonization upon Māori, is constructed by many, through a convenience of distance. It is motivated also on the understanding that most Pākehā who now inhabit the rohe of Waitaha, are completely ignorant of the identity of tangata whenua. It is hoped that the presentation of the Waitaha story, will provoke a greater empathy from Pākehā, and thereby facilitate an environment, whereby grievances can be addressed in an environment of greater understanding. The thesis is a qualitative based research exercise, carried out in consultation with kaumātua and other Waitaha members, and attempts to acknowledge and integrate current kaupapa Māori epistemologies with traditional Western academic methodology. The study uses interviews, Waitangi Tribunal evidence, and other historical references to construct a narrative that conveys something of the 'voice' of Waitaha. Specifically, it outlines a chronology of Waitaha settlement, followed by a description of their encounter with Pākehā, the consequent alienation of the majority of their lands by the Crown, and concludes, with a glimpse into the current circumstance of Manoeka, the papakainga of Waitaha.
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Matthews, Nathan W., i n/a. ""He kura Maori, he kura hahi, he kura katorika, he kura motuhake mo te iwi." Hato Paora College : a model of Maori Catholic education". University of Otago. Te Tumu - School of Maori, Pacific and Indigenous Studies, 2007. http://adt.otago.ac.nz./public/adt-NZDU20070921.134919.
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Church initiated and operated Maori secondary boarding schools have existed in Aotearoa in various forms since the arrival of the missionaries in the early 19th century. Since their inception, they have contributed significantly to the development of Maori society, particularly in the production of dynamic Maori leaders who have had a compelling influence on their communities, wider Maori society and in some instances on the nation state. This thesis will examine the Society of Mary�s establishment of Hato Paora College, Feilding, as an example of a Maori Catholic secondary boarding school.
The first part contains four general chapters that provide relevant background information to the establishment of Hato Paora. The first identifies key aspects of a Maori Catholic world view and Maori Catholicism. Chapter two traces the arrival, and subsequent development, of the Catholic Church in New Zealand as a mission to Maori. The next chapter looks more specifically at the history of the Society of Mary in New Zealand and the development of the Diocese of Wellington, particularly their Maori missions, under their authority. Finally, Chapter four chronicles the situation of Maori within the New Zealand education system since its inception.
Part two of this thesis contains eight chapters that present a detailed case study of Hato Paora. The exploration of the type of educational environment provided by Hato Paora College begins in Chapter six with the examination of its foundation. Chapters seven and eight look at the philosophies and administration of each of the six rectors. The two succeeding chapters describe the defining characteristics of the school, its Maori character and its Catholic character. Chapter eleven evaluates how this school has influenced the boys who attended, using interviews with a representative sampling of old boys. Chapter twelve concerns the relationships that the College early established with the Maori communities that it belongs to.
In the final chapter, a model will be presented as a plan for the future of the school. This philosophical model attempts to provide a guide for Hato Paora, using Kaupapa Maori theory as the basic framework, while still retaining the ideals and philosophies of the College�s Marist founders.
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Carroll, Rowan Amber. "The acquisition of the Partington Collection by Whanganui Regional Museum : valuing relationships in museum policy & practice : a thesis presented in partial fulfilment of requirements for the degree of Master of Arts in Museum Studies at Massey University, Palmerston North, Aotearoa". Massey University, 2008. http://hdl.handle.net/10179/881.
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The purpose of this thesis is to underline the importance of developing useful and mutually beneficial relationships between local iwi and museums, and to consider the subsequent implications for museum practice. The thesis assembles a variety of contemporary sources in order to document and construct a chronological narrative of events: minutes and communications; interviews with staff and key participants in the process of acquiring the Partington Collection by the Whanganui Regional Museum; media reports; and a survey of recent literature. The Partington Collection of Whanganui Maori photographs is integral to this examination because of its importance to both Whanganui iwi and the Whanganui Regional Museum. The situation of colonial photography in museums has changed over the century from being viewed as a factual reflection of the cultural imperatives of indigenous peoples, to being viewed as a colonial construct consigning indigenous peoples to their past. Because this Collection is the most comprehensive photographic documentary of Whanganui Maori from the turn of last century it adds immense value to the Museum’s existing collections. However to Whanganui iwi the photographs of their ancestors are taonga tuku iho: far more than just photographic images they are demonstrably and undeniably imbued with the mana of their tupuna. The public auction in 2001 of the Partington Collection created a catalyst for action and an opportunity for Whanganui iwi and the Museum to work together to ensure the return of the photographs to Whanganui, an outcome that was finally achieved in 2002. The thesis concludes that the successful return of the Partington Collection to Whanganui could not have been possible without the long term evolving relationship between iwi and the Museum and in particular the more recent emergence of a bi-cameral governance structure. Furthermore the maintenance of relationships and communication is crucial to the evolution of museum practice. This would suggest a reversal of the traditional perspective that museum practice and procedure is pre-eminent. Instead, this case study demonstrates that relationships are at the heart of museum practice.
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Peters, Murray Hamaka. "The confiscation of Pare Hauraki: The impact of Te Ao Pākehā on the Iwi of Pare Hauraki Māori; on the whenua of Pare Hauraki 1835-1997 and The Foreshore and Seabed Act 2004". The University of Waikato, 2007. http://hdl.handle.net/10289/2366.
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Kia mau ki te rangatiratanga o te Iwi o Hauraki Just as the whakataukī explains Hold fast to the power and authority of the Hauraki tribes the focus of this study is to examine and evaluate the impact of Te Ao Pākehā on Pare Hauraki lands and Tīkapa Moana under the mana of Pare Hauraki Māori and Pare Hauraki tikanga. The iwi of Pare Hauraki have land claims through the, (Wai 100) and the Hauraki Māori Trust Board, before the Waitangi Tribunal highlighting whenua issues and their impact on Pare Hauraki iwi. Also relevant is the foreshore and seabed issue which is documented leading on to the infamous Foreshore and Seabed Act 2004, (for Māori anyway), sparking widespread opposition by Māori throughout the country, and other supportive non-Māori groups because of the issue concerning Māori kaitiiakitanga and guardianship roles. This investigation will commence by outlining the histories of discovery and settlement of Pare Hauraki, the concept of mana-whenua/mana-moana as it applies to Pare Hauraki Māori and our tikanga, and then to subsequent issues leading to land alienation of the early 19th to late 20th cenutries and then to the foreshore issue of the early 21st Century. This research will include information showing that before 1840 to Te Tiriti o Waitangi and thereafter that Pākehā and various Crown agents, through legislation claimed the rights to the lands, waterways and oceanic areas under the kaitiakitanga of my tupuna of Pare Hauraki. Tupuna and other iwi members have expressed their disgust seeing the mana of their traditional lands, waterways, oceanic areas and kaitiaki roles slipping away from them through these activities. Therefore, this thesis is a response to those issues and the impact on (a), Māori as a people, and our tikanga Māori and (b), Pare Hauraki Māori as the kaitiaki/guardians of the Pare Hauraki rohe/territory in accordance with tikanga Māori, and the significance of the responsibilities which arise out of the Māori concepts of kaitiakitanga, manaakitanga and rangatiratanga.
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Seager, Cecchini Ashley. "“Maybe I’ll see you on the stage”: Spontaneous Audience Action in the Performance of the Plays of Victoria Nalani Kneubuhl". Miami University / OhioLINK, 2010. http://rave.ohiolink.edu/etdc/view?acc_num=miami1281283461.
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Eckhart, Eric Ashton. "A search for charmless baryonic B meson decays at CLEO". Columbus, OH : Ohio State University, 2003. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=osu1054568796.
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Thesis (Ph. D.)--Ohio State University, 2003.Title from first page of PDF file. Document formatted into pages; contains xv, 133 p.: ill. Includes abstract and vita. Advisor: Richard D. Kass, Dept. of Physics. Includes bibliographical references (p. 132-133).
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Weigand, Stefan. "Metallierung von Pyridylmetallocenen durch Platin(II), Gold(III), Quecksilber(II) und Iridium(III)". Diss., Ludwig-Maximilians-Universität München, 2013. http://nbn-resolving.de/urn:nbn:de:bvb:19-166074.
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Carlson, William E. "Evaluating Hydrologic Controls on Fish and Macroinvertebrate Communities in Ohio’s Western Allegheny Plateau". Ohio University / OhioLINK, 2006. http://rave.ohiolink.edu/etdc/view?acc_num=ohiou1149193823.
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January, Mary Catherine. "HYDROPONIC PHYTOREMEDIATION OF Cd (III), Cr(III), Ni (II), As (V), AND Fe(II) BY HELIANTHUS ANNUUS". University of Akron / OhioLINK, 2006. http://rave.ohiolink.edu/etdc/view?acc_num=akron1145391303.
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Weigand, Stefan [Verfasser], i Karlheinz [Akademischer Betreuer] Sünkel. "Metallierung von Pyridylmetallocenen durch Platin(II), Gold(III), Quecksilber(II) und Iridium(III) / Stefan Weigand. Betreuer: Karlheinz Sünkel". München : Universitätsbibliothek der Ludwig-Maximilians-Universität, 2013. http://d-nb.info/1048014452/34.
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Vojtek, Tomáš. "Propagation of Fatigue Cracks under Shear Loading Modes II, III and II+III in the Near-Threshold Region". Doctoral thesis, Vysoké učení technické v Brně. Fakulta strojního inženýrství, 2014. http://www.nusl.cz/ntk/nusl-234220.
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Práce je zaměřena na šíření únavových trhlin v módech II, III a II + III v prahové oblasti v kovových materiálech. Byly provedeny experimenty pro ARMCO železo, titan, nikl a austenitickou ocel na třech druzích vzorků pro zatěžování trhliny ve smykových módech. Byl použit zvláštní způsob vytváření iniciační trhliny, který eliminoval efekt zavírání trhliny na začátku smykového zatěžování. Ve všech zkoumaných materiálech byly efektivní prahové hodnoty v módu II přibližně 1,7 krát nižší než v módu III. Měřením úhlů lokálních odklonů a natočení lomových faset s použitím stereofotogrammetrie v SEM bylo usuzováno na tendenci trhliny k vyhýbání do lokálního módu I. Nejmenší úhly byly zjištěny u ARMCO železa pro trhliny v módech II i III, středně velké úhly u titanu a niklu a největší úhly (vyhnutí do čistého módu I) byly pozorovány u austenitické oceli. Tyto rozdíly lze vysvětlit různým počtem dostupných skluzových systémů v krystalových mřížkách daných materiálů. Poměry mezi naměřenými prahovými hodnotami v módu I, II a III byly srovnány s předpověďmi teoretických modelů. Byl navržen analytický vztah pro efektivní prahové hodnoty v módu II, který byl v dobré shodě s experimentálními výsledky. Pomocí efektivních prahových hodnot bylo vyčísleno kritérium pro vyhýbání do módu I, které vedlo ke kritickému úhlu odklonu 40° souvisejícímu s přechodem z lokálního smykového módu do otevíracího módu.
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Нгуен, Тхи Ньюнг. "Окислительно-восстановительный катализ соединениями железа (II-III)". Rozprawa doktorska doktora nauk chemicznych, МВ и ССО Молд.ССР. Кишиневский гос. ун-т им. В.И.Ленина, 1987.
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Muwandi, Tinei. "Comparison of King III and King II, and the implications of King III". Thesis, Stellenbosch : University of Stellenbosch, 2010. http://hdl.handle.net/10019.1/8511.
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Thesis (MBA)--University of Stellenbosch, 2010.The introduction of King III has resulted in many changes to corporate governance practices. The changes inevitably have implications and challenges for organisations. If the changes introduced by King III as well as the implications and challenges are not well understood, implementing King III could be a very challenging exercise. This research report outlines the key differences between King III and King II. The research report also highlights the major implications and challenges of implementing the King III principles. In addition, those aspects of King III that are covered in the new Companies Act have also been outlined. In analysing the changes between King II and King III, and the implications and challenges of King III‟s principles and recommendations, the author followed the layout of the chapters in King III, namely ethical leadership and corporate citizenship, boards and directors, audit committees, the governance of risk, the governance of information technology, compliance with laws, codes, rules and standards, internal audit, governing stakeholder relationships and integrated reporting. The differences between King III and King II were analysed through a study and comparison of the King III and King II Reports. The implications and challenges were analysed through reading literature on King III and corporate governance in general. Aspects of King III covered in the Companies Act were analysed through a study of King III and the Companies Act. The author analysed the differences, implications and challenges of both the principles and the recommended practice in the King Reports. No distinction was made between principles and recommended practices. The main changes introduced by King III relate to the composition and role of the board, the board committees and the new topic on IT governance and the need to publish an integrated report. Though discussed in different chapters, King III has emphasised the link and interplay between ethics, corporate social responsibility, governing stakeholder relationships and integrated reporting. In addition to the above, the most contentious change is probably the applicability of King III to all entities regardless of form of incorporation. King III has also attempted to bring about a physiological change in the way companies perceive King III by changing the “comply or explain” concept to the “apply or explain concept”. The direct implications and challenges brought about by King III relate to the time, efforts and costs needed to implement the various King III principles and recommendations. King III could also result in an increase in the size or diversity of the board, and companies are likely to find it challenging to get qualified people to fill directorship posts. Integrated reporting is going to change the way companies view corporate social responsibility and the way they report non-financial information to stakeholders. Despite the challenges, there is no doubt that King III goes a long way to ensure that South Africa‟s corporate governance system is at par with the rest of the world.
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Shen, Zhigao. "C–H Activation by Iron(III), Manganese(II) and Rhoda(III)electro Catalysis". Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2020. http://hdl.handle.net/21.11130/00-1735-0000-0005-1525-A.
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Choate, Evan Wallace. ""Unborn and unbegot" : Richard III, Edward II, Richard II, and queer history". Thesis, University of British Columbia, 2013. http://hdl.handle.net/2429/44878.
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In my thesis, I treat Shakespeare’s Richard III, Marlowe’s Edward II, and Shakespeare’s Richard II as a queer sequence of history plays, or a kind of co-authored triptych, by reading their influences on each other and focusing on the iterative elements of their writing of history. I describe in my thesis how the queer affects, desires, and pleasures in these plays are integral to a History – the shared knowledge and impressions of a British national past – from which they are and have been systematically excluded.
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Peralta, Rosely Aparecida. "Novos complexos binucleares de cobre(II) e de ferro(III) zinco(II)". Florianópolis, SC, 2005. http://repositorio.ufsc.br/handle/123456789/101680.
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Tese (doutorado) - Universidade Federal de Santa Catarina, Centro de Ciências Físicas e Matemáticas. Programa de Pós-graduação em QuímicaMade available in DSpace on 2013-07-15T22:57:09Z (GMT). No. of bitstreams: 0
Neste trabalho foram sintetizados e caracterizados 6 novos complexos de Cu(II) empregando-se os ligantes: H2Ldtb, H2BPBPMP-CH3, H2BPBPMP-NO2 e H2BPBPMP. Os complexos de Cu(II) foram testados na reação de oxidação do substrato 3,5-DTBC e podem ser considerados modelos funcionais para as catecol oxidases. Também foram sintetizados e caracterizados 4 novos complexos de Fe(III)Zn(II) empregando-se os mesmos ligantes. Os compostos de Fe(III)Zn(II) foram testados frente à hidrólise do substrato 2,4-BDNPP e apresentaram fatores de aceleração de 2200 e 5200 vezes, respectivamente, em relação à reação não catalisada. Considerando os complexos de Fe(III)Zn(II) destaca-se que as propriedades espectroscópicas, eletroquímicas e de reatividade seguem uma relação linear com as constantes de Hammett. Desta forma, esses complexos podem ser considerados isoestruturais em solução, evidenciando-se que os complexos heterobinucleares de Fe(III)Zn(II) são os segundos a mimetizar a unidade (OH2)Fe(III)(m-OH)Zn(II) da kbPAP na literatura. Estudos preliminares de clivagem de DNA empregando-se os complexos de Cu(II) demonstraram que os complexos modelos são capazes de promover a clivagem da forma superenovelada para a forma circular e linear de DNA plasmidial levando a considerá-los como nucleases químicas.
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Cairns, John William. "The interfaces of II-VI/III-V semiconductors". Thesis, Cardiff University, 1991. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.296381.
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Bach, Quoc Thang. "Přesné přiblížení na přistání GNSS CAT II/III". Master's thesis, Vysoké učení technické v Brně. Fakulta strojního inženýrství, 2013. http://www.nusl.cz/ntk/nusl-230767.
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The content of this work is an overview of precision approach used by GNSS and avionics for operation in low visibility conditions. This thesis describes existing requirements and proposals for new standards that are important to define GBAS performance. The objective of this work is to compare the alternative systems to guide aircraft during precision approach CAT II/III. GBAS operational implementation is additionally devised in this thesis.
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Nam, Kwan-Hyun Tavlarides Lawrence L. "Sol-gel synthesized adsorbents for mercury(II), chromium(III) and cobalt(II) separations". Related electronic resource: Current Research at SU : database of SU dissertations, recent titles available full text, 2004. http://wwwlib.umi.com/cr/syr/main.
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Murray, Karen J. "Acceleration of Cr(III) and Co(II) oxidation by Mn(II)-oxidizing bacteria /". Diss., Connect to a 24 p. preview or request complete full text in PDF format. Access restricted to UC campuses, 2005. http://wwwlib.umi.com/cr/ucsd/fullcit?p3191987.
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Shen, Zhigao [Verfasser]. "C–H Activation by Iron(III), Manganese(II) and Rhoda(III)electro Catalysis / Zhigao Shen". Göttingen : Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2020. http://d-nb.info/122370629X/34.
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Gustafsson, Victor, i Jens Gelin. "Bankregleringar : En jämförelsestudie mellan Basel II och Basel III". Thesis, Uppsala universitet, Företagsekonomiska institutionen, 2012. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-176710.
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Vintilescu, Ion Virgil. "Mixed-mode I-II-III fracture of adhesive joints". Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1997. http://www.collectionscanada.ca/obj/s4/f2/dsk2/ftp01/MQ28870.pdf.
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Žentelis, Šarūnas. "Būsimųjų sporto pedagogų (II ir III kurso) socialumo ypatumai". Master's thesis, Lithuanian Academic Libraries Network (LABT), 2005. http://vddb.library.lt/obj/LT-eLABa-0001:E.02~2005~D_20050523_202320-33535.
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Methods: 1.The analysis of literary sources. 2. Survey. 3. Mathematical statistics. Purpose. Display the social skills of prospective educators (course II –III). The tasks of the investigation: 1. Determine the competence level of prospective educators (course II –III). 2. Study the level of social skills of prospective educators (course II –III). 3. Display the level of social psychological adaptation of prospective educators (course II –III). 4. The analysis of literary sources. The characterization of sociability. The sociability, social skills, the conceptions of social adaptation and their importance are being discussed. Social competence – the summation of social skills. The conception of social competence is being discussed and social competence is being presented as the summation of social skills. The factors of social competence. The factors that determine communication are being presented. The conception of self-reliance. The characterization of self-estimation. The aspects of self-estimation are being presented. The connection between self-estimation and self-reliance. The specificity of restlessness. The notion of restlessness, its appearance and reactions are being presented.
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Paliulienė, Sima. "Ūkinės veiklos apribojimų II – III grupių miškuose ekonominė analizė". Master's thesis, Lithuanian Academic Libraries Network (LABT), 2010. http://vddb.laba.lt/obj/LT-eLABa-0001:E.02~2010~D_20100621_113213-87812.
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Magistro darbe tiriama ūkinės veiklos apribojimų II – III grupių miškuose įtaka ekonominiams ūkinės veiklos rezultatams.
Darbo objektas – II ir III grupių miškai bei juose taikomi ūkinės veiklos apribojimai. II miškų grupei priskiriami specialios paskirties miškai (ekosistemų apsaugos miškai ir rekreaciniai miškai), o III miškų grupei priklauso apsauginiai miškai.
Darbo tikslas – atlikti ūkinės veiklos apribojimų II – III grupių miškuose įtakos ekonominiams ūkinės veiklos rezultatams analizę.
Darbo metodai – taikant alternatyviųjų kaštų metodą, apskaičiuojamos miško valdytojų ir savininkų potencialios grynosios pajamos iš II ir III grupių miškų. Apskaičiuotos grynosios pajamos palygintos su pajamomis, kurios būtų gaunamos, kirtimus atliekant pagal IV miškų grupės apribojimus.
Rezultatai – nustatyta, kad medienos vertės priklausomybę nuo vidutinio skersmens geriausiai nusako antro laipsnio polinomo lygtis: y = a₀+a₁*x+a₂*x² (y – medienos vertė, Lt/m³; x – vidutinis medyno skersmuo, cm).
Naudojant skirtingus ūkinius režimus, apskaičiuota medynų renta II ir III grupės miškams. Gauti rezultatai palyginti su tų pačių medynų miško renta, jei jiems būtų taikomi IV miškų grupės ūkiniai apribojimai. Nustatyta, kad didžiausi yra II miškų grupės pušynų alternatyvieji kaštai. Negaunamos grynosios metinės pajamos (miško renta) iš II grupės pušynų sudaro 15,4 mln. Lt arba 137 Lt/ha, lyginant su IV miškų grupės ūkiniu režimu. Kituose medynuose negaunamos grynosios pajamos gerokai... [toliau žr. visą tekstą]Influence of forestry restrictions on economic results in forests of II and III forest groups is being investigated in this study. The subject of study – Lithuanian forests of II and III groups as well as forestry restrictions applied to those forests. Forests of II group are are assinged for ecosystems protection and recreation, and forests of III group are protective forests. The objective of master thesis – to carry out analysis of economic impact made by forestry restrictions applied to forests of II and III groups. Methods of sudy – potential net annual income (forest rent) from forests of II and III groups was calculated. Alternatively, the same indicators were calculated, assuming that the forest were managed as commercial forests of IV group. Results of study – ir was concluded, that the value of standing timber can be described as a function of mean diametre of the stand using polynomial function of 2nd order: y=a₀+a₁*x+a₂*x² (y – value of timber, Lt/m³; x – mean diametre, cm). Forest rent for forests of groups II and III was calculated, using different forestry regimes. The results were compared to forest rent if the forests were managed as commercial forest. It was found, that the biggest alternative costs are related to pine forests of II group - 15,4 mill. Lt, or 137 Lt/ha, comparing with forestry regime of IV forest group. Alternative costs in other stands are considerably lower.
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Мар'єнко, Н. І. "Індивідуальна анатомічна мінливість II-III часточок півкуль мозочка людини". Thesis, Сумський державний університет, 2016. http://essuir.sumdu.edu.ua/handle/123456789/44915.
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Серед всіх структур центральної нервової системи мозочок характеризується найбільш вираженою анатомічною мінливістю, яка обумовлена складною просторовою конфігурацією білої речовини мозочка.
Мета роботи – дослідити будову та вивчити закономірності індивідуальної анатомічної мінливості ІІ-ІІІ часточок півкуль мозочка людини.
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Halepoto, Dost Muhammad. "Syntheses and structures of some novel chromium(II), vanadium(II) and vanadium(III) complexes". Thesis, University of Surrey, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.375971.
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Altahan, Mohammed Abdulredha. "Cobalt(III), copper(II), and nickel(II) coordination compounds as cations in polyborate chemistry". Thesis, Bangor University, 2017. https://research.bangor.ac.uk/portal/en/theses/cobaltiii-copperii-and-nickelii-coordination-comppounds-as-cations-in-polyborate-chemistry(ba5f189b-2229-481f-9d8d-0bdce17903a8).html.
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This thesis describes the synthesis and characterization of a number of polyborate compounds containing transition metal complex cations; most of these compounds contain 6-membered B3O3 boroxole rings within their structures. A total of twenty-six transition metal complex polyborate salts are reported: one contains the triborate monoanion, [B3O3(OH)4]-, three contain the tetraborate dianion [B4O5(OH)4]2-, twelve contain the pentaborate anion, [B5O6(OH)4]-, three contain the hexaborate dianion, [B6O7(OH)6]2- and five contain heptaborate anions (three of which are [B7O9(OH)5]2-, and two are [B7O9(OH)6]3-). Additionally, two compounds contain two isolated polyborate anion species (octaborate dianion [B8O10(OH)6]2- with pentaborate anion [B5O6(OH)4]-, and triborate anion [B3O3(OH)4]- with [B5O6(OH)4]-). The crystal structures of fifteen salts containing these polyborate anions are reported: [Co(en)3][B5O6(OH)4][B8O10(OH)6]∙5H2O (6), [Co(NH3)6]2[B4O5(OH)4]3∙11H2O (9), s-fac-[Co(dien)2][B7O9(OH)6]∙9H2O (11), [Co(diNOsar)]2[B3O3(OH)4]Cl5∙4.75H2O (12), [Cu(en)2][B5O6(OH)4]2∙2H2O (20), [Cu(pn)2{B5O6(OH)4}][B5O6(OH)4]∙4H2O (22), [Cu(TMEDA){B6O7(OH)6}]∙6H2O (23), [Cu(dac)2(H2O)2][Cu(dac)2][B7O9(OH)5]2∙4H2O (24), [Cu(N,N-dmen)2(H2O)][B5O6(OH)4]2·3H2O (27), [Cu(N,N-dmen){B6O7(OH)6}]·4H2O (28), [Ni(en){B6O7(OH)6}(H2O)2]∙H2O (37), [Ni(AEN)][B5O6(OH)4]∙H2O (38), [Ni(dac)2(H2O-)2][Ni(dac)2][B7O9(OH)5]2∙4H2O (39), [Ni(hn)2][B5O6(OH)4]2 (40), and s-fac-[Ni(dien)2][B5O6(OH)4]2 (41). All the synthesized compounds reported were characterized using spectroscopic (IR, multi-element NMR) and analytical (melting point, elemental analysis, magnetic susceptibility, thermal analysis, powder X-ray diffraction) techniques. The solid-state structures of transition metal complex polyborate salts all display multiple cation-anion H-bond interactions and these undoubtedly play a major role in the energetics of engineering these structures. For example, in compound [Co(NH3)6]2[B4O5(OH)4]3∙11H2O (9), fourteen of the 18 amino hydrogen atoms of the [Co(NH3)6]3+ cation are involved in secondary coordination to anions via H-bonds. Two unique polyborate anions, [B8O10(OH)6)]2- and [B7O9(OH)6]3- have been prepared and characterized in [Co(en)3][B5O6(OH)4][B8O10(OH)6]∙5H2O (6) and s-fac-[Co(dien)2][B7O9(OH)6]∙9H2O (11), respectively. vii The reaction of transition metal complex cations with boric acid in different ratios produced polyborate compounds with different polyborate anions e.g. reaction of [Cu(en)2]2+ with boric acid in 1:10 and 1:5 ratios produce polyborate compounds with pentaborate(1-) and tetraborate(2-) anions, respectively. New polyborate anion structural architectures are identified in this thesis: (i) the pentaborate(1-) anion in [Cu(pn)2{B5O6(OH)4}][B5O6(OH)4]∙4H2O (22) acts as a monodentate ligand coordinated to the Cu(II) cation, (ii) the hexaborate(2-) anion in [Cu(TMEDA){B6O7(OH)6}]∙6H2O (23) and [Cu(N,N-dmen){B6O7(OH)6}]·4H2O (28) coordinates as a tridentate ligand with the Cu(II) cations, and (iii) the hexaborate(2-) anion in [Ni(en){B6O7(OH)6}(H2O)2]∙H2O (37) coordinates as a bidentate ligand with the Ni(II) cation. This is the first time that such coordination mode (i) and (iii) have been observed.
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Marko, Rodić. "Kompleksi Co(III), Ni(II) i Cu(II) sa hidrazonima nekih 2-piridil-ketona". Phd thesis, Univerzitet u Novom Sadu, Prirodno-matematički fakultet u Novom Sadu, 2015. https://www.cris.uns.ac.rs/record.jsf?recordId=95722&source=NDLTD&language=en.
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U disertaciji su opisane sinteze i fizičko-hemijske karakterizacije 32 kompleksa kobalta(III), nikla(II) i bakra(II) sa ligandima S-metilizotiosemikarbazonom 2-acetilpiridina (HL¹), bis(S-metilizotiosemikarbazonom) 2,6-diacetilpiridina (H₂L²), tiosemikarbazonom-S-metilizotiosemikarbazonom 2,6-diacetilpiridina (HL³), 1-adamantoilhidrazonom 2-acetilpiridina (HL⁴) i 1-adamantoilhidrazonom di(2-piridil)-ketona (HL⁵).Kako ligandi HL³, HL⁴ i HL⁵ do sada nisu bili sintetisani, dobijeni rezultati ujedno predstavljaju i prve iz njihove koordinacione hemije. Iako je sa S-metilizotiosemikarbazonom 2-acetilpiridina poznato nekoliko kompleksa, do sada nijedan od njih nije strukturno okarakterisan, tako da su rezultati prikazani u ovoj disertaciji dali jasnu sliku o načinima koordinacije HL¹. Takođe, kako je sa H₂L² poznat vrlo malo broj kompleksa, dobijeni rezultati su dali značajan doprinos razumevanju koordinacione hemije ovog liganda.Gotovo svi sintetisani kompleksi (njih 27 od 32) su strukturno okarakterisani metodom rendgenske kristalografije. Odabrana jedinjenja su ispitana metodama termičke analize, a utvrđena je njihova antimikrobna i citotoksična aktivnost. This thesis describes syntheses and physico-chemical characterizations of 32 complexes of cobalt(III), nickel(II) and copper(II), with ligands 2-acetylpyridine S-methylisothiosemicarbazone (HL¹), 2,6-dicetylpyridine bis(S-methylisothiosemicarbazone) (H₂L²), thiosemicarbazone-S-methylisothiosemicarbazone 2,6-dicetylpyridine (HL³), 2-acetylpyridine 1-adamantoylhydrazone (HL⁴), and di(2-pyridil)-ketone 1-adamantoylhydrazone (HL⁵).Since the ligands HL³, HL⁴, and HL⁵ were not synthetized hitherto, the obtained results are the first regarding their coordination chemistry as well. Even though there are several complexes reported with 2-acetylpyridine S-methylisothiosemicarbazone as a ligand, none of them was structurally characterized. Therefore, here presented results gave clear insight into coordination modes of the HL¹. Moreover, since there is limited number of complexes with H₂L² reported hitherto, the obtained results gave significant contribution to understanding of its coordination chemistry.Almost each synthetized complex (27 out of 32) was structurally characterized by means of single crystal X-ray crystallography. The selected compounds were characterized by thermal analysis, and their antimicrobial and cytotoxic activity were determined.
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CHEHHAL, HANANE. "Complexes de catecholamines avec les cations mg(ii), co(ii), ni(ii), cu(ii), cd(ii), pb(ii) et fe(iii). Stabilite en solution aqueuse". Reims, 1996. http://www.theses.fr/1996REIMS018.
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Les interactions de quatre ligands avec sept cations metalliques (mg#2#+, co#2#+, ni#2#+, cu#2#+, cd#2#+, pb#2#+ et fe#3#+) ont ete etudiees a 25c, en milieu perchlorate de sodium de force ionique egale a 1. Les ligands sont des catecholamines de la classe des neurotransmetteurs: la dopamine, la l-dopa, l'adrenaline et la noradrenaline. La dopamine est connue notamment pour son utilisation dans le traitement de la maladie de parkinson. Avec la dopamine, l'adrenaline et la noradrenaline, les complexes formes sont de type catechol (un seul site de coordination est disponible). Par contre, la l-dopa presente deux sites de coordination possibles: un site catechol et un site amino-acide. En plus des complexes formes a partir d'un seul site de coordination, une complexation mixte catechol/amino-acide est egalement mise en evidence. Avec les quatre ligands, les cycles chelates obtenus a cinq chainons. L'utilisation de la methode protometrique et du programme d'affinement protaf, nous a permis de determiner les constantes d'equilibre avec les differents cations bivalents, ainsi que, dans le cas du fer(iii), les constantes de deprotonation du complexe superieur de rapport 1/3. La spectrophotometrie d'absorption visible a ete mise en uvre lors de la determination des autres constantes d'equilibre avec le fer(iii). Avec les cations mg#2#+, cd#2#+ et pb#2#+ les resultats obtenus sont pour l'essentiel inedits ; ils sont totalement originaux dans le cas du fer(iii)
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Mirjana, Radanović. "Kompleksi nekih prelaznih metala sa Šifovim bazama aminogvanidina". Phd thesis, Univerzitet u Novom Sadu, Prirodno-matematički fakultet u Novom Sadu, 2015. https://www.cris.uns.ac.rs/record.jsf?recordId=95548&source=NDLTD&language=en.
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U ovoj doktorskoj disertaciji opisane su sinteze novih kompleksa prelaznih metala sa piridoksiliden- (PLAG), odnosno saliciliden-aminogvanidinom (SALAG). Dobijenikompleksi su okarakterisani elementalnom analizom, IR spektrima, konduktometrijskim i magnetnim merenjima, a većina i rendgenskomstrukturnom analizom. Osim toga, dobijene su i nove forme ovih Šifovih baza, i to u vidu monokristala, čime su omogućena ispitivanja njihovih molekulskih i kristalnih struktura, kao i uporedna analiza sa koordinovanim ligandima. Sa PLAG je sintetisano 7 novi kompleksa Cu(II), a pored toga po prvi put suizolovani mono i bis(ligand) kompleksi Fe(III) i Co(III), mono(ligand) kompleksi V(V), kao i jedan kompleks Zn(II) u kojem ovaj potencijalno tridentatni ONN ligand, umonoprotonovanoj formi, ima ulogu kontra-jona. Sa stanovišta geometrije zajedničko za izolovane komplekse Cu(II) i V(V) je da imaju kvadratno-piramidalnu strukturu, sa izuzetkom jednog kvadratno-planarnog kompleksa Cu(II), dok je u kompleksima Fe(III) i Co(III) nađeno očekivano oktaedarsko okruženje centralnogjona. Pored ovih, sintetisano je i pet novih kompleksa sa SALAG, od kojih su dvakompleksa Cu(II) i kompleks V(V) okarakterisani rendgenskom strukturnomanalizom, dok je mikrokristalnim bis(ligand) kompleksima Co(III) i Ni(III) na osnovufizičko-hemijskih karakteristika predložena odgovarajuća struktura. Zajedničko za obe opisane Šifove baze je da se koordinuju na ONN tridentatni način, i to preko atoma kiseonika deprotonovane fenolne grupe i atoma azota azometinske i imino grupe AG fragmeta. Posebno je naglašeno da su saPLAG izolovana dva dimerna kompleksa Cu(II) u kojima je po prvi put nađena tetradentatna koordinacija ovog liganda, u koju je dodatno uključen atom kiseonika hidroksimetil-grupe PL-ostatka. Za razliku od SALAG, koji je u izolovanim kompleksima koordinovan isključivo kao monoanjon, nastao deprotonacijom fenolneOH-grupe, za PLAG je osim ove, potvđena koordinacija u neutralnoj, zwitter-jonskoj, ali i dvostruko deprotonovanoj formi. Zwitter-jonska forma liganda nastaje migracijom atoma vodonika sa fenolnog hidroksila na piridinski atom azota PL-ostatka, dok deprotonacijom piridinskog ili hidrazinskog atoma azota, odnosno oba pomenuta atoma nastaju monoanjon i dianjon helatnog liganda, respektivno. Na kraju, urađena su i ispitivanja antimikrobne aktivnosti odabranih jedinjenjaprema predstavnicima grampozitivnih i gramnegativnih bakterija, kao i dve kulturekvasca. Tom prilikom nije utvrđena nikakva inhibitorna aktivnost prema primenjenimbakterijskim sojevima, dok su u slučaju kvasaca izvesno mikrobicidno dejstvo pokazali samo kompleksi Cu(II).This PhD thesis describes the syntheses of some new transition metal complexes with pyridoxilidene- (PLAG) and salicylideneaminoguanidine (SALAG). Obtained complexes are characterized by elemental analysis, IR spectroscopy, conductometric and magnetic measurements. Besides, the structural analysis of majority of the obtained complexes was performed. Some new forms of these Schiff bases are synthesized in form of single crystals, which made their X-ray analysis as well as comparison with coordinated forms possible.With PLAG, 7 new Cu(II) complexes were obtained and for the first time mono and bis(ligand) complexes of Fe(III) and Co(III) as well mono(ligand) complexes of V(V) were isolated. Furthermore, the structure of Zn(II) complex in which PLAG in its monocationic form has a role of counter ion is presented. With the exception of one Cu(II) complex, all reported Cu(II) and V(V) complexes have a square-pyramidal geometry, whilst Fe(III) and Co(III) are situated in octahedral surroundings. Also, five new complexes of Cu(II), Co(III), Ni(II) and V(V) with SALAG were synthesized. In both Cu(II) complexes and V(V) complex the expected coordination mode and geometry were confirmed by X-ray analysis, while octahedral structure of bis(ligand) complexes with Co(III) and Ni(II) was proposed based on results of physico-chemical characterization.Both PLAG and SALAG coordinate the metal ion in tridentate ONN manner, through the oxygen atom of deprotonated phenolic group and nitrogen atoms of azomethine and imino groups of AG moiety. It is also emphasized that in two dimeric Cu(II) complexes with PLAG tetradentate coordination mode was found, in which the oxygen atom of hydroxymethyl group of PL residue was additionally involved. Unlike SALAG, which is coordinated as monoanion in all of the examined complexes, PLAG can have one of three degrees of deprotonation. Zwitter-ion of PLAG is formed by migration of H-atom from phenolic oxygen to pyridine nitrogen, while the deprotonation of pyridine or/and hydrazine nitrogen, makes it mono-and dianion, respectively.Also, microbiological tests on the selected compounds were preformed. Namely, antimicrobial activity of these compounds against some gram-positive and gram-negative bacteria, as well as some yeast cultures was examined and none of the samples showed antimicrobial activity against bacteria, whilst only Cu(II) complexes showed certain inhibitory effect against yeasts.
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Oliveira, Denys Ribeiro de. "Nanopartículas de hexacianoferrato (ii) de cério (iii) em meio água/formamida e sua aplicação na eletro-oxidação catalítica da l-dopamina /". Ilha Solteira, 2019. http://hdl.handle.net/11449/190964.
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Orientador: Devaney Ribeiro do CarmoResumo: Neste trabalho esta descrito a preparação de nanopartículas de Hexacianoferrato (II) de Cério (III) (NpsCe), em quatro proporções diferentes de solventes a saber: Água/Formamida (100:0; 80:20; 40:60; 0:100), afim de se investigar a influência dos solventes no tamanho, morfologia, nas propriedades físico-químicas, voltamétrica e eletrocatalíticas da NpsCe. As Nps foram caracterizadas pelas técnicas de Espectroscopia na Região do Infravermelho (FTIR), Difração de Raios-X (DRX), Microscopia Eletrônica de Varredura (MEV), Potencial Zeta, Voltametria Cíclica (VC) e Voltametria de Pulso Diferencial (VPD). Dos quatro sistemas estudados apenas o CeHCF-1 (100/0) e o CeHCF - 3 (40/60) se apresentaram sensíveis a concentrações do neurotransmissor L-dopamina permitindo a confecção de uma curva de calibração. O sistema CeHCF-1 apresentou duas regiões linerares de sinal em função da concentração de L-dopamina, com limite de detecção (LD) de 0,125 mmol L-1 e 0,023 mmol L-1 obtido pelas técnicas de VC e VPD, respectivamente. Para o sistema CeHCF-3 observou-se por VC uma região linear de intensidade de corrente anódica e a concentração de L-dopamina com LD de 0,0317 mmol L-1, já por VPD apresentou duas regiões lineares de sinal em função da concentração de L-dopamina, com LD de 1,98 x 10-4 e 0,0104 mmol L-1. O sistema CeHCF – 3 apresentou promissor a detecção e quantificação de DA em amostras reais. Assim realizou-se o estudo para avaliar a seletividade deste frente a substâncias comumente en... (Resumo completo, clicar acesso eletrônico abaixo)
Abstract: This work is rearmed to nanoparticles of Cerium (III) Hexacyanoferrate (II) (NpsCe) analog of PB in four different proportions of Water / Formamide solvents (100: 0, 80:20, 40:60, 0: 100 ), to investigate the influence of solvents on the size, morphology, physicochemical, electrochemical and electrocatalytic properties of NpsCe. The Nps were characterized by the techniques of Infrared Spectroscopy (FTIR), X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Zeta Potential, Cyclic Voltammetry (CV) and Differential Pulse Voltammetry (DPV). Of the four systems studied, only CeHCF-1 (100/0) and CeHCF-3 (40/60) are formed in small concentrations of the neurotransmitter L-dopamine. The CeHCF-1 system showed two signal regions as a function of L-dopamine concentration, with detection limit (LD) of 0.125 mmol L-1 and 0.023 mmol L-1 given by the CV and DPV techniques, respectively. For the CeHCF-3 system it can be seen as a linear signal region as a function of the L-dopamine concentration by the CV technique with LD of 0.0317 mmol L-1, or by DPV through two linear signal regions in the function of the concentration of L-dopamine, with LD of 1.98 x 10-4 and 0.0104 mmol L-1. The launched CeHCF – 3 system promises to detect and quantify DA in real cases. Thus, a study was carried out to reduce the resistance of a substance found in the physiological industries that have the potential of oxidation and reduction of the DA. Substantial subtranslators studied here were Urea and Asco... (Complete abstract click electronic access below)
Mestre
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Cheng, Hung Hsiang. "Magneto-optical studies of II-VI and III-V heterostructures". Thesis, University of Oxford, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.318838.
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Pritchard, Ruth. "Studies of Iron (II) and Iron (III) spin crossover compounds". Thesis, University of Leeds, 2008. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.487772.
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Raerino, Kimiora. "He tirohanga a Ngāti Awa uri taone mo ngā ahuatanga Māori: An urban Ngāti Awa perspective on identity and culture". 2007. http://hdl.handle.net/10292/423.
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Tribal traditions and practices are integral to iwi identity. From the past to the present, the biggest impact on iwi identity was colonisation and subsequent urbanisation. Urbanisation changed the foundation of identity largely due to the demographic rural-urban shift, effectively creating a distance physically and spiritually for Māori between their place of residence and their traditional tribal turangawaewae. Today a larger proportion of tribal members reside in the main urban centres of New Zealand and Australia. This phenomenon provides an ideal opportunity to explore how iwi identity is maintained in an urban setting – away from the traditional sites of cultural practice. The study, which focuses on Ngāti Awa members residing in Auckland, provided evidence that the foundation of an iwi identity is still heavily reliant on strong iwi-based whānau. The corollary is that, strengthening the tribal knowledge base of whānau residing in urban centres may require new or increased active participation in the customs and practices of their iwi. Regrettably, only three of the ten research participants had an in-depth knowledge of their whakapapa, histories and traditions. However, all the participants indicated the need to become more pro-active in creating and expanding on their knowledge base of iwitanga (including te reo). There was also acknowledgement that urban-based iwi marae and whānau wānanga can provide individuals with the opportunities to learn more about their iwi traditions (and thereby reinforce their sense of tribal identity). Encouragingly, each participant confirmed that identifying as Ngāti Awa was important to them, largely due to the sense of belonging and identity. The study concluded that the sustainability of iwi is reliant on iwi members supporting their iwi regardless of the location of their upbringing.
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Healy, Susan. "The nature of the relationship of the Crown in New Zealand with iwi Maori". 2006. http://hdl.handle.net/2292/2930.
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This study investigates the nature of the relationship that the state in New Zealand, the Crown, has established with Māori as a tribally-based people. Despite the efforts of recent New Zealand Governments to address the history of Crown injustice to Māori, the relationship of the Crown with Iwi Māori continues to be fraught with contradictions and tension. It is the argument of the thesis that the tension exists because the Crown has imposed a social, political, and economic order that is inherently contradictory to the social, political, and economic order of the Māori tribal world. Overriding an order where relationships are negotiated and alliances built between autonomous groups, the Crown constituted itself as a government with single, undivided sovereignty, used its unilateral power to introduce policy and legislation that facilitated the dispossession of whānau and hapū of their resources and their authority in the land, and enshrined its own authority and capitalist social relations instead. The thesis is built round a critical reading of five Waitangi Tribunal reports, namely the Muriwhenua Fishing Report, Mangonui Sewerage Report, The Te Roroa Report, Muriwhenua Land Report, and Te Whanau o Waipareira Report.
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Colvin, Gina. "A soliloquy of whiteness : colonial discourse and New Zealand's settler press 1839-1873 : a thesis submitted in partial fulfilment of the requirements for the degree of Doctor of Philosophy in Journalism in the University of Canterbury /". 2009. http://hdl.handle.net/10092/3689.
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Reese, Alistair. "Are you listening? the 'voice' of Waitaha : a forgotten people = Whakarongo mai koutou? : ko te 'reo' o Waitaha : he iwi whakarerea /". 2006. http://adt.waikato.ac.nz./public/adt-uow20060911.112836.
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Katene, Selwyn. "The politics of iwi voice : a thesis presented in partial fulfilment of the requirements for the degree of Doctor of Philosophy in Maori Studies at Massey University, Wellington, New Zealand". 2006. http://hdl.handle.net/10179/911.
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This doctorate thesis The Politics of Iwi Voice focuses on the struggle of a modern, urban iwi authority to secure political recognition from other iwi and the Crown as it attempts to assert an independent iwi voice, and exercise mana and tino rangatiratanga. The responses of the local iwi/Maori community, the Crown, and others to the re-emergence of the new iwi entity are critically examined. The thesis demonstrates how a small iwi group resists attempts to assimilate into a broader coalition of iwi, hapu, whanau and marae interests, preferring instead to maintain and develop its own distinctive identity. It uses the iwi Ngati Tama to exemplify the diaspora of an iwi, and shows how iwi identity and fortunes are buffeted by both iwi and urban contestations as well as changing political directions. The study suggests that a Ngati Tama future away from its homeland will depend primarily on the development of pragmatic adaptive and innovative strategies, and a fervent resolve to retain a distinctive identity, while participating in a dynamic and often oppressive environment. This thesis concludes that to maintain a distinctive iwi presence its members should have the right to decide who best represents them. An iwi is considered an appropriate vehicle to represent its members and manage its interests. In order to survive in a constantly changing environment, an iwi must be dynamic, flexible, relevant, and meet the needs of its membership. Further, its leadership should be focused on negotiating relationships in good faith - including third party interventions - and seeking pathways that will advance its interests into the future.
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O'Reilly, Denis Christopher. "Mahi whanau (2) : reflecting on the use of consensus cardsort as an effective process for whanau Maori to construct a future narrative. A dissertation submitted in partial fulfilment of the requirements for the degree of Master of Social Practice, Unitec New Zealand /". Diss., 2008. http://www.coda.ac.nz/cgi/viewcontent.cgi?article=1000&context=unitec_tpkw_di.
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Thesis (M.SP)--Unitec New Zealand, 2008.Cardsort is a generic name for any process that uses statements written on cards and has participants sieve, cluster or rank ideas or statements. When the participants themselves create the statements in question this process is consensus cardsort. Includes bibliographical references (leaves 134-145).
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Peters, Murray Hamaka. "The confiscation of Pare Hauraki the impact of Te Ao Pākeha on the iwi of Pare Hauraki Māori, on the whenua of Pare Hauraki, 1835-1997, and the Foreshore and Seabed Act 2004 = Te raupatutanga o Pare Hauraki". 2007. http://adt.waikato.ac.nz./public/adt-uow20070321.101430.
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Huygens, Ingrid. "Processes of Pakeha change in response to the Treaty of Waitangi". 2007. http://adt.waikato.ac.nz/public/adt-uow20080815.151820/index.html.
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