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1

Wroblewska, Aleksandra, Arkadiusz Zych, Shanmugam Thiyagarajan, Dmytro Dudenko, Daan van Es, Michael Ryan Hansen, Cor Koning, Rob Duchateau i Lidia Jasinska-Walc. "Towards sugar-derived polyamides as environmentally friendly materials". Polymer Chemistry 6, nr 22 (2015): 4133–43. http://dx.doi.org/10.1039/c5py00521c.

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As part of our ongoing study investigating isohexide-based polyamides, we have synthesized isosorbide(bis(propan-1-amine)) (DAPIS) and studied its reactivity in the polymerization towards fully biobased polyamides.
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Marubayashi, Hironori, Takaaki Ushio i Shuichi Nojima. "Crystallization of polyesters composed of isohexides and aliphatic dicarboxylic acids: Effects of isohexide stereoisomerism and dicarboxylic acid chain length". Polymer Degradation and Stability 146 (grudzień 2017): 174–83. http://dx.doi.org/10.1016/j.polymdegradstab.2017.10.005.

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Ji, Xiaodong, Zikun Wang, Jingling Yan i Zhen Wang. "Partially bio-based polyimides from isohexide-derived diamines". Polymer 74 (wrzesień 2015): 38–45. http://dx.doi.org/10.1016/j.polymer.2015.07.051.

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4

Wu, Jing, Pieter Eduard, Shanmugam Thiyagarajan, Jacco van Haveren, Daan S. van Es, Cor E. Koning, Martin Lutz i Célia Fonseca Guerra. "Isohexide Derivatives from Renewable Resources as Chiral Building Blocks". ChemSusChem 4, nr 5 (4.05.2011): 599–603. http://dx.doi.org/10.1002/cssc.201100076.

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Wu, Jing, Shanmugam Thiyagarajan, Célia Fonseca Guerra, Pieter Eduard, Martin Lutz, Bart A. J. Noordover, Cor E. Koning i Daan S. van Es. "Isohexide Dinitriles: A Versatile Family of Renewable Platform Chemicals". ChemSusChem 10, nr 16 (12.07.2017): 3202–11. http://dx.doi.org/10.1002/cssc.201700617.

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Rajput, Bhausaheb S., Kalpakasseril Girija Lekshmy, Shamal K. Menon i Samir H. Chikkali. "Synthesis of isohexide-di(ether-ene)s and ADMET polymerization". Green Materials 5, nr 2 (czerwiec 2017): 63–73. http://dx.doi.org/10.1680/jgrma.16.00017.

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Wu, Jing, Jiefei Qi, Yiming Lin, Yong Chen, Xu Zhang, Rongliang Wu i Huaping Wang. "Lipase-Catalyzed Fully Aliphatic Copolyesters Based on Renewable Isohexide Isomers". ACS Sustainable Chemistry & Engineering 9, nr 4 (19.01.2021): 1599–612. http://dx.doi.org/10.1021/acssuschemeng.0c06733.

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8

Wu, Jing, Pieter Eduard, Lidia Jasinska-Walc, Artur Rozanski, Bart A. J. Noordover, Daan S. van Es i Cor E. Koning. "Fully Isohexide-Based Polyesters: Synthesis, Characterization, and Structure–Properties Relations". Macromolecules 46, nr 2 (31.12.2012): 384–94. http://dx.doi.org/10.1021/ma302209f.

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Gormong, Ethan A., Theresa M. Reineke i Thomas R. Hoye. "Synthesis of Isohexide Diyne Polymers and Hydrogenation to Their Saturated Polyethers". ACS Macro Letters 10, nr 8 (3.08.2021): 1068–72. http://dx.doi.org/10.1021/acsmacrolett.1c00422.

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10

Ji, Xiaodong, Zikun Wang, Zhen Wang i Jingling Yan. "Bio-Based Poly(Ether Imide)s from Isohexide-Derived Isomeric Dianhydrides". Polymers 9, nr 11 (3.11.2017): 569. http://dx.doi.org/10.3390/polym9110569.

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Gustini, Liliana, Cristina Lavilla, Antxon Martínez de Ilarduya, Sebastián Muñoz-Guerra i Cor E. Koning. "Isohexide and Sorbitol-Derived, Enzymatically Synthesized Renewable Polyesters with Enhanced Tg". Biomacromolecules 17, nr 10 (28.09.2016): 3404–16. http://dx.doi.org/10.1021/acs.biomac.6b01224.

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12

Jasinska-Walc, Lidia, Dmytro Dudenko, Artur Rozanski, Shanmugam Thiyagarajan, Paweł Sowinski, Daan van Es, Jie Shu, Michael Ryan Hansen i Cor E. Koning. "Structure and Molecular Dynamics in Renewable Polyamides from Dideoxy–Diamino Isohexide". Macromolecules 45, nr 14 (12.07.2012): 5653–66. http://dx.doi.org/10.1021/ma301091a.

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13

Thiyagarajan, Shanmugam, Linda Gootjes, Willem Vogelzang, Jacco van Haveren, Martin Lutz i Daan S. van Es. "Renewable Rigid Diamines: Efficient, Stereospecific Synthesis of High Purity Isohexide Diamines". ChemSusChem 4, nr 12 (25.11.2011): 1823–29. http://dx.doi.org/10.1002/cssc.201100398.

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14

Shin, Seunghan, Jae Won Seo, Jin Ku Cho, Sangyong Kim, Jaeryung Cha i Myoung Seon Gong. "Bio-based chiral dopants having an isohexide skeleton for cholesteric liquid crystal materials". Green Chemistry 14, nr 4 (2012): 1163. http://dx.doi.org/10.1039/c2gc16261j.

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15

Vijjamarri, Srikanth, Marianne Hull, Edward Kolodka i Guodong Du. "Renewable Isohexide-Based, Hydrolytically Degradable Poly(silyl ether)s with High Thermal Stability". ChemSusChem 11, nr 17 (26.07.2018): 2881–88. http://dx.doi.org/10.1002/cssc.201801123.

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16

Wu, Jing, Shanmugam Thiyagarajan, Célia Fonseca Guerra, Pieter Eduard, Martin Lutz, Bart A. J. Noordover, Cor E. Koning i Daan S. van Es. "Back Cover: Isohexide Dinitriles: A Versatile Family of Renewable Platform Chemicals (ChemSusChem 16/2017)". ChemSusChem 10, nr 16 (15.08.2017): 3278. http://dx.doi.org/10.1002/cssc.201701482.

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17

Thiyagarajan, Shanmugam, Jing Wu, Rutger J. I. Knoop, Jacco van Haveren, Martin Lutz i Daan S. van Es. "Isohexide hydroxy esters: synthesis and application of a new class of biobased AB-type building blocks". RSC Adv. 4, nr 89 (2014): 47937–50. http://dx.doi.org/10.1039/c4ra07896a.

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Here we present the synthesis of a new family of sugar derived 1,4:3,6-dianhydrohexitol based AB-type monomers, containing one methyl ester group and a secondary hydroxyl group in all four possible stereo isomers (RR, RS, SR, SS).
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18

Engel, Rebecca V., Johannes Niemeier, Anja Fink i Marcus Rose. "Unravelling the Mechanism of the Ru/C-Catalysed Isohexide and Ether Isomerization by Hydrogen Isotope Exchange". Advanced Synthesis & Catalysis 360, nr 12 (2.05.2018): 2358–63. http://dx.doi.org/10.1002/adsc.201800058.

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19

Craythorne, Steven J., Ciara L. Pollock, Alexander J. Blake, Mark Nieuwenhuyzen, Andrew C. Marr i Patricia C. Marr. "A low molecular weight hydro and organogelator derived from an isohexide and sol–gel transcription of the alcogel". New Journal of Chemistry 33, nr 3 (2009): 479. http://dx.doi.org/10.1039/b814274b.

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20

Vijjamarri, Srikanth, Marianne Hull, Edward Kolodka i Guodong Du. "Cover Feature: Renewable Isohexide-Based, Hydrolytically Degradable Poly(silyl ether)s with High Thermal Stability (ChemSusChem 17/2018)". ChemSusChem 11, nr 17 (31.08.2018): 2839. http://dx.doi.org/10.1002/cssc.201801922.

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21

Ji, Xiaodong, Jingling Yan, Xiuju Liu, Zikun Wang i Zhen Wang. "Synthesis and properties of polyimides derived from bis(4-aminophenyl)isohexides". High Performance Polymers 29, nr 2 (28.07.2016): 197–204. http://dx.doi.org/10.1177/0954008316634443.

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Several partially bio-based polyimides have been successfully synthesized by polycondensation between bis(4-aminophenyl)isohexides with various commercial dianhydrides. Flexible and free-standing films were readily obtained from their poly(amic acid) or polyimide solutions. A systematic investigation of the structure–property relationship of polyimides highlights the significant impact of the isohexides moieties on their physical and mechanical properties (glass transition temperature, inherent viscosity, thermal stability, solubility, and mechanical properties). The results revealed that these polyimides exhibited comparable thermal stability and mechanical properties to those of petrochemical-based ones.
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22

Rajput, B. S., S. R. Gaikwad, S. K. Menon i S. H. Chikkali. "Sustainable polyacetals from isohexides". Green Chemistry 16, nr 8 (12.06.2014): 3810. http://dx.doi.org/10.1039/c4gc00543k.

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23

Kieber, Robert J., Samantha A. Silver i Justin G. Kennemur. "Stereochemical effects on the mechanical and viscoelastic properties of renewable polyurethanes derived from isohexides and hydroxymethylfurfural". Polymer Chemistry 8, nr 33 (2017): 4822–29. http://dx.doi.org/10.1039/c7py00949f.

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Biomass-derived polyurethanes were synthesized using 2,5-bishydroxymethylfuran (BHMF) and diisocyanate functionalized isohexides, isosorbide bis(3-isocyanatopropanoate) (ISBIP) and isomannide bis(3-isocyanatopropanoate) (IMBIP), at varying feed ratios.
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24

Muñoz-Guerra, Sebastián, Cristina Lavilla, Cristina Japu i Antxon Martínez de Ilarduya. "Renewable terephthalate polyesters from carbohydrate-based bicyclic monomers". Green Chem. 16, nr 4 (2014): 1716–39. http://dx.doi.org/10.1039/c3gc42394h.

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Carbohydrate-based bicyclic compounds, isohexides and diacetalized alditols and aldarates, are suitable polycondensation monomers to prepare partially renewable aromatic copolyesters displaying a satisfactory pattern of basic properties and enhancedTgand hydrodegradability.
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25

Jennifer B. Galvin, Gary Bond. "2-METHYLPENTANE (ISOHEXANE)". Journal of Toxicology and Environmental Health, Part A 58, nr 1-2 (15.08.1999): 81–92. http://dx.doi.org/10.1080/009841099157449.

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Janvier, Marine, Sylvie Moebs-Sanchez i Florence Popowycz. "Nitrogen-functionalized Isohexides in Asymmetric Induction". CHIMIA International Journal for Chemistry 70, nr 1 (24.02.2016): 77–83. http://dx.doi.org/10.2533/chimia.2016.77.

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27

Kadraoui, Mohammed, Thibault Maunoury, Zoubir Derriche, Stéphane Guillarme i Christine Saluzzo. "Isohexides as Versatile Scaffolds for Asymmetric Catalysis". European Journal of Organic Chemistry 2015, nr 3 (17.11.2014): 441–57. http://dx.doi.org/10.1002/ejoc.201402851.

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28

Alghamdi, Mohammed, Ibrahim Al-Kharsan, Sana Shahab, Abdullah Albaker, Reza Alayi, Laveet Kumar i Mamdouh El Haj Assad. "Investigation of Energy and Exergy of Geothermal Organic Rankine Cycle". Energies 16, nr 5 (25.02.2023): 2222. http://dx.doi.org/10.3390/en16052222.

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In this study, modeling and thermodynamic analysis of the combined double flash geothermal cycle generation was conducted using zeotropic fluid as the working fluid in the Organic Rankine Cycle (ORC). The analysis was performed based on the first and second laws of thermodynamics. Hexane, cyclohexane, isohexane, R245fa, and R236ea exhibit good performance at higher temperatures. In this study, three fluids—hexane, cyclohexane, and isohexane—were used. First, the model results for the pure fluids were compared with those of previous studies. Then, the important parameters of the cycle, including the efficiency of the first law of thermodynamics, the efficiency of the second law of thermodynamics, net productive power, and the amount of exergy destruction caused by changing the mass fraction of the refrigerant for the zeotropic fluids (investigated for the whole cycle and ORC), were obtained and compared.
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29

Kadraoui, Mohammed, Thibault Maunoury, Zoubir Derriche, Stephane Guillarme i Christine Saluzzo. "ChemInform Abstract: Isohexides as Versatile Scaffolds for Asymmetric Catalysis". ChemInform 46, nr 13 (marzec 2015): no. http://dx.doi.org/10.1002/chin.201513310.

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Jacolot, Maïwenn, Sylvie Moebs-Sanchez i Florence Popowycz. "Diastereoselective Iridium-Catalyzed Amination of Biosourced Isohexides Through Borrowing Hydrogen Methodology". Journal of Organic Chemistry 83, nr 16 (11.06.2018): 9456–63. http://dx.doi.org/10.1021/acs.joc.8b01162.

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Bahé, Florian, Lucie Grand, Elise Cartier, Maïwenn Jacolot, Sylvie Moebs-Sanchez, Daniel Portinha, Etienne Fleury i Florence Popowycz. "Direct Amination of Isohexides via Borrowing Hydrogen Methodology: Regio- and Stereoselective Issues". European Journal of Organic Chemistry 2020, nr 5 (23.01.2020): 599–608. http://dx.doi.org/10.1002/ejoc.201901661.

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Pfützenreuter, Rebecca, i Marcus Rose. "Aqueous-Phase Amination of Biogenic Isohexides by using Ru/C as a Solid Catalyst". ChemCatChem 8, nr 1 (26.11.2015): 251–55. http://dx.doi.org/10.1002/cctc.201501077.

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Ershov, Mikhail A., Tamer M. M. Abdellatief, Dmitriy A. Potanin, Nikita A. Klimov, Elena A. Chernysheva i Vladimir M. Kapustin. "Characteristics of Isohexene as a Novel Promising High-Octane Gasoline Booster". Energy & Fuels 34, nr 7 (1.06.2020): 8139–49. http://dx.doi.org/10.1021/acs.energyfuels.0c00945.

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Kuk, M. S., i R. J. Hron. "Cottonseed extraction with a new solvent system: Isohexane and alcohol mixtures". Journal of the American Oil Chemists' Society 75, nr 8 (sierpień 1998): 927–30. http://dx.doi.org/10.1007/s11746-998-0268-4.

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Basevich, V. Ya, A. A. Belyaev, S. N. Medvedev, V. S. Posvyanskii i S. M. Frolov. "Detailed kinetic mechanism of the multistep oxidation and combustion of isopentane and isohexane". Russian Journal of Physical Chemistry B 9, nr 6 (listopad 2015): 933–39. http://dx.doi.org/10.1134/s1990793115060159.

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Vera, David, Francisco Jurado, Bárbara de Mena i Jesús C. Hernández. "A Distributed Generation Hybrid System for Electric Energy Boosting Fueled with Olive Industry Wastes". Energies 12, nr 3 (5.02.2019): 500. http://dx.doi.org/10.3390/en12030500.

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This paper presents the theoretical model and the simulation of a cutting edge hybrid power system composed of an externally-fired gas turbine (EFGT) coupled with an organic Rankine cycle (ORC) as a bottoming unit for the maximization of electrical power. The power plant is fed with different biomass sources from olive industry wastes (pruning, dry pomace, stones, leaves and twigs), providing more than 550 kW of electric power and a net electrical efficiency of 26.0%. These wastes were burnt directly at atmospheric pressure in an EFGT, producing 400 kW of electric power and exhaust gases at 300 °C. Ten suitable ORC working fluids have been studied to maximize the electric power generation: cyclohexane, isohexane, pentane, isopentane, neopentane, R113, R245fa, R365mfc, R1233zd and methanol. The best fluid was R1233zd, reaching 152.4 kW and 22.1% of ORC thermal efficiency; as drawback, however, R1233zd was not suitable for Combined Heat and Power CHP applications due its lower condensation temperature. Thus, despite R113 gave minor electricity production (137.5 kW) this allowed to generate additional thermal power (506.8 kW) in the way of hot water at 45 °C.
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Nagy, Istvan, Ryan A. Krenz, Robert A. Heidemann i Theo W. de Loos. "High-pressure phase equilibria in the system linear low density polyethylene+isohexane: Experimental results and modelling". Journal of Supercritical Fluids 40, nr 1 (luty 2007): 125–33. http://dx.doi.org/10.1016/j.supflu.2006.04.005.

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Zheng, Jingjing, Tao Yu i Donald G. Truhlar. "Multi-structural thermodynamics of C–H bond dissociation in hexane and isohexane yielding seven isomeric hexyl radicals". Physical Chemistry Chemical Physics 13, nr 43 (2011): 19318. http://dx.doi.org/10.1039/c1cp21829h.

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Chicinaş, Horea Florin, Darius Ovidiu Jucan, Glad Contiu i Cătălin Popa. "Effect of Aqueous Milling on the Total Carbon Content of Hard Metal Powders". Advanced Engineering Forum 42 (7.09.2021): 3–8. http://dx.doi.org/10.4028/www.scientific.net/aef.42.3.

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Materials consisting of a hard phase, usually WC, and a tough binder, traditionally Co, form the most successful class of composite materials, also known as Hard Metals (HM) or Cemented Carbides. Powder metallurgy routes are employed generally for the production of such [1]. The typical processing route of such materials involves mixing the components, kneading and consolidation. Alcohols, alkanes and alkenes are commonly used to limit any excessive heating and oxidation of powders during mixing the components. In this study, we report the results of milling in a more environmentally friendly aqueous milling media. The obtained results are presented comparatively with milling under a traditional media, such as isohexane and acetone. The characterization of the milled samples has been done from the structural, compositional and morphological point of view. Considering our previous results, an important aspect of the milled powder is the carbon content, which dictates the sintering behavior of such parts. The carbon balance investigation performed on a carbon analyzer has revealed no significant differences upon changing the milling media. This work emphasizes the influence of the milling media on the HM powder. HM powders with similar properties have been obtained both by traditional and aqueous milling. The comparative study has revealed that the substitution of the traditional milling media does not influence the carbon content in the HM powder.
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Jin, Jun, Liyou Zheng, Warda Mwinyi Pembe, Jinfang Zhang, Dan Xie, Xiaosan Wang, Jianhua Huang, Qingzhe Jin i Xingguo Wang. "Production of sn -1,3-distearoyl-2-oleoyl-glycerol-rich fats from mango kernel fat by selective fractionation using 2-methylpentane based isohexane". Food Chemistry 234 (listopad 2017): 46–54. http://dx.doi.org/10.1016/j.foodchem.2017.04.165.

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Lin, Yiming, Mengting Ye, Xu Zhang, Yong Chen, Ye Chen, Jing Wu i Huaping Wang. "Biodegradable copolyesters based on a “soft” isohexide building block with tunable viscoelasticity and self-adhesiveness". Polymer Chemistry, 2022. http://dx.doi.org/10.1039/d2py00586g.

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With the aim of developing novel biodegradable functional polymers, a series of copolyesters (PBIA) with low Tg values and tunable self-adhesiveness were synthesized by utilizing a unique “soft” isohexide building...
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42

Zullo, Valerio, Anna Iuliano, Gennaro Pescitelli i Francesco Zinna. "Tunable Excimer Circularly Polarized Luminescence in Isohexide Derivatives from Renewable Resources". Chemistry – A European Journal 28, nr 15 (15.02.2022). http://dx.doi.org/10.1002/chem.202104226.

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Zullo, Valerio, Marcin Górecki, Lorenzo Guazzelli, Andrea Mezzetta, Gennaro Pescitelli i Anna Iuliano. "Exploiting isohexide scaffolds for the preparation of chiral ionic liquids tweezers". Journal of Molecular Liquids, październik 2020, 114528. http://dx.doi.org/10.1016/j.molliq.2020.114528.

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Wang, Yaning, Jing Wu, koning Cor E i Huaping Wang. "Short-process synthetic strategies of sustainable isohexide-based polyesters towards higher molecular weight and commercial applicability". Green Chemistry, 2022. http://dx.doi.org/10.1039/d2gc02608b.

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Isohexides (1,4:3,6-dianhydrohexitols) represent a family of bio-based heterocyclic diols attracting over 40 years’ attention from both industry and academia. Their unique properties, including high structural rigidity, high hydrophilicity and distinct...
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45

Sidduri, Achyutharao, Mark J. Dresel i Spencer Knapp. "Incorporation of an Isohexide Subunit Improves the Drug-like Properties of Bioactive Compounds". ACS Medicinal Chemistry Letters, 20.01.2023. http://dx.doi.org/10.1021/acsmedchemlett.2c00476.

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46

"Iridium-Catalyzed Diastereoselective Amination of Isohexides". Synfacts 14, nr 11 (18.10.2018): 1152. http://dx.doi.org/10.1055/s-0037-1611250.

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Janvier, Marine, Sylvie Moebs-Sanchez i Florence Popowycz. "ChemInform Abstract: Nitrogen-Functionalized Isohexides in Asymmetric Induction". ChemInform 47, nr 50 (listopad 2016). http://dx.doi.org/10.1002/chin.201650204.

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Aziz, M. A. A., A. A. Jalil i N. S. Triwahyono. "Promotive effect of hydrogen in n-hexane isomerization over Ni/PtHY catalyst". Malaysian Journal of Fundamental and Applied Sciences 9, nr 4 (7.07.2014). http://dx.doi.org/10.11113/mjfas.v9n4.114.

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Bifunctional catalyst containing 0.1 wt% Ni and 0.1 wt% Pt supported on HY were prepared by incipient wetness impregnation method. The properties of the catalyst were determined by XRD analysis and pyridine adsorbed FTIR spectroscopy. The catalytic activities were tested on n-hexane isomerization by pulse method in a microcatalytic reactor under atmospheric pressure in the presence of hydrogen or nitrogen carrier gas. XRD result showed the decrease of the crystallinity of PtHY after introduction of 0.1 wt% of Ni. While, the ratio of Lewis to Brønsted acid sites increased after the introduction of Ni on PtHY as evidenced by pyridine adsorbed FTIR spectroscopy. In the presence of hydrogen gas, 0.1 wt% Ni increased the yield of isohexane by about 24 % and decreased the activation energy from 124.1 to 111.2 kJ/mol at the temperature range of 403-423 K. In addition, the activation energy decreased to 48.3 kJ/mol for Ni/PtHY at high temperature range of 478-498 K. The presence of hydrogen as a carrier gas gave a promotive effect on the reaction which led to increase the formation of isohexane and suppress the cracking process. While, the presence of nitrogen as a carrier gas promoted dimerization of nhexane which formed the cracking products.
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Triwahyono, Sugeng, Aishah Abdul Jalil, Hairul Amiza Azman i Che Rozid Mamat. "ISOMERIZATION OF C5-C7 LINEAR ALKANES OVER WO3-ZRO2 UNDER HELIUM ATMOSPHERE". Jurnal Teknologi 75, nr 6 (17.08.2015). http://dx.doi.org/10.11113/jt.v75.5197.

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The effect of WO3 on the properties and catalytic isomerization of C5-C7 linear alkanes over ZrO2 was studied under helium atmosphere. The WO3-ZrO2 was prepared by impregnation of Zr(OH)4 with an aqueous (NH4)6[H2W12O40], followed by calcination at 1093 K for 3 h in air. The amount WO3 was 10 wt%. XRD and BET studies showed that the introduction of WO3 stabilizes the tetragonal phase of ZrO2, leading to larger surface area and stronger acidity of ZrO2. Pyridine FTIR study verified the interaction of WO3 with ZrO2 formed strong Lewis and Bronsted acid sites. The presence of WO3 increased the catalytic isomerization of C5-C7 linear alkanes. The conversion of C5, C6 and C7 reached 1.3, 2.6 and 5.1 %, respectively. While the selectivity of isopentane, isohexane and isoheptane reached 15.6, 20.5 and 19.5 %, respectively. The high activity of WO3-ZrO2 was due to the ability of WO3 to adsorb and dissociate linear alkane to form hydrogen and alkane radical in which the atomic hydrogen underwent to the formation of protonic acid sites and hydride. The presence of protonic acid sites and hydride determined the activity of WO3-ZrO2.
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Rekhletskaya, Ekaterina S., Mikhail A. Ershov, Vsevolod D. Savelenko, Alisa E. Makhmudova, Vladimir M. Kapustin, Tamer M. M. Abdellatief, Dmitriy A. Potanin i in. "Unraveling the Superior Role of Characterizing Methyl Ester of Isohexene as an Innovative High-Octane Gasoline Mixing Component". Energy & Fuels, 26.09.2022. http://dx.doi.org/10.1021/acs.energyfuels.2c01973.

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