Gotowe bibliografie tematyczne / Interfaces liquide/solide

Gotowa bibliografia na temat „Interfaces liquide/solide”

Autor: Grafiati
Data publikacji: 25 maja 2024

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Artykuły w czasopismach na temat "Interfaces liquide/solide"

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Crumlin, Ethan J. "(Invited) Using Ambient Pressure XPS to Probe the Solid/Gas and Solid/Liquid Interface Under in Situ and Operando Conditions". ECS Meeting Abstracts MA2022-02, nr 46 (9.10.2022): 1715. http://dx.doi.org/10.1149/ma2022-02461715mtgabs.

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Interfaces play an essential role in nearly all aspects of life and are critical for electrochemistry. Prof. Robert Savinell has played a pivotal interface to me in the role of mentorship in both life and electrochemistry, and I look to honor his contributions to both through this talk. Electrochemical systems ranging from high-temperature solid oxide fuel cells (SOFC) to batteries to capacitors have a wide range of important interfaces between solids, liquids, and gases, which play a pivotal role in how energy is stored, transferred, and converted. I will share the use of ambient pressure XPS (APXPS) to directly probe the solid/gas and solid/liquid electrochemical interface. APXPS is a photon-in/electron-out process that can provide both atomic concentration and chemical-specific information at pressures greater than 20 Torr. Using synchrotron X-rays at Lawrence Berkeley Nation Laboratory, the Advanced Light Source has several beamlines dedicated to APXPS endstations that are outfitted with various in situ/operando features such as heating to temperatures > 500 °C, pressures greater than 20 Torr to support solid/liquid experiments and electrical leads to support applying electrical potentials support the ability to collect XPS data of actual electrochemical devices while it's operating in near ambient pressures. This talk will introduce APXPS and provide several interface electrochemistry examples using in situ and operando APXPS, including the probing of Sr segregation on a SOFC electrode to a Pt metal electrode undergoing a water-splitting reaction to generate oxygen, the ability to measure the electrochemical double layer (EDL) to our most recent efforts to directly probe an ion exchange membranes Donnan potential. Gaining new insight to guide the design and control of future electrochemical interfaces and how Bob, electrochemistry, and I have interfaced over the years.
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Josell, Daniel, i Frans Spaepen. "Surfaces, Interfaces, and Changing Shapes in Multilayered Films". MRS Bulletin 24, nr 2 (luty 1999): 39–43. http://dx.doi.org/10.1557/s0883769400051538.

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It is generally recognized that the capillary forces associated with internal and external interfaces affect both the shapes of liquid-vapor surfaces and wetting of a solid by a liquid. It is less commonly understood that the same phenomenology often applies equally well to solid-solid or solid-vapor interfaces.The fundamental quantity governing capillary phenomena is the excess free energy associated with a unit area of interface. The microscopic origin of this excess free energy is often intuitively simple to understand: the atoms at a free surface have “missing bonds”; a grain boundary contains “holes” and hence does not have the optimal electronic density; an incoherent interface contains dislocations that cost strain energy; and the ordering of a liquid near a solid-liquid interface causes a lowering of the entropy and hence an increase in the free energy. In what follows we shall show how this fundamental quantity determines the shape of increasingly complex bodies: spheres, wires, thin films, and multilayers composed of liquids or solids. Crystal anisotropy is not considered here; all interfaces and surfaces are assumed isotropic.Consideration of the equilibrium of a spherical drop of radius R with surface free energy γ shows that pressure inside the droplet is higher than outside. The difference is given by the well-known Laplace equation:This result can be obtained by equating work done against internal and external pressure during an infinitesimal change of radius with the work of creating a new surface.
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Saleman, Abdul Rafeq, Mohamad Shukri Zakaria, Ridhwan Jumaidin, Nur Hazwani Mokhtar i Nor Aslily Sarkam. "Molecular Dynamics Study: Correlation of Heat Conduction Across S-L Interfaces Between Constant Heat Flux and Shear Applied to Liquid Systems". Journal of Mechanical Engineering 19, nr 3 (15.09.2022): 33–53. http://dx.doi.org/10.24191/jmeche.v19i3.19795.

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Heat conduction (HC) at solid-liquid (S-L) interfaces play a significant role in the performance of engineering systems. Thus, this study investigates HC at S-L interfaces and its correlation between constant heat flux (CHF) and shear applied to liquid (SAL) systems using non-equilibrium molecular dynamics simulation. The S-L interface consists of solids with the face-centred cubic (FCC) lattice of (110), (111) and (100) planes facing the liquid. The solid is modelled by Morse potential whereas the liquid is modelled by Lennard Jones potential. The interaction between solid-liquid was modelled by Lorentz-Bertholet combining rules. The temperature and heat flux of the system is evaluated to correlate the HC at the S-L interface which reflect by the interfacial thermal resistance (ITR). The results suggest that the surfaces of FCC influence ITR at the S-L interface. The (110) surface for both cases of CHF and SAL has the lowest ITR as compared to other surfaces. In general, ITR for the case of SAL is higher than the CHF. SAL disturbs the adsorption behaviour of liquid at the S-L interfaces, thus reducing the HC. In conclusion, the surface of FCC and liquid experiencing shear do influence the characteristics of HC at the S-L interface.
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Streubel, Robert, Xubo Liu, Xuefei Wu i Thomas P. Russell. "Perspective: Ferromagnetic Liquids". Materials 13, nr 12 (15.06.2020): 2712. http://dx.doi.org/10.3390/ma13122712.

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Mechanical jamming of nanoparticles at liquid–liquid interfaces has evolved into a versatile approach to structure liquids with solid-state properties. Ferromagnetic liquids obtain their physical and magnetic properties, including a remanent magnetization that distinguishes them from ferrofluids, from the jamming of magnetic nanoparticles assembled at the interface between two distinct liquids to minimize surface tension. This perspective provides an overview of recent progress and discusses future directions, challenges and potential applications of jamming magnetic nanoparticles with regard to 3D nano-magnetism. We address the formation and characterization of curved magnetic geometries, and spin frustration between dipole-coupled nanostructures, and advance our understanding of particle jamming at liquid–liquid interfaces.
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Veen, J. F. van der, i H. Reichert. "Structural Ordering at the Solid–Liquid Interface". MRS Bulletin 29, nr 12 (grudzień 2004): 958–62. http://dx.doi.org/10.1557/mrs2004.267.

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AbstractMany processes in nature and technology are based on the static and dynamic properties of solid–liquid interfaces. Prominent examples are crystal growth, melting, and recrystallization. These processes are strongly affected by the local structure at the solid–liquid interface. Therefore, it is mandatory to understand the change in the structure across the interface. The break of the translational symmetry at the interface induces ordering phenomena, and interactions between the liquid's molecules and the atomically corrugated solid surface may induce additional ordering effects. In the past decade, new techniques have been developed to investigate the structural properties of such (deeply) buried interfaces in their natural environment. These methods are based on deeply penetrating probes such as brilliant x-ray beams, providing full access to the structure parallel and perpendicular to the interface. Here, we review the results of a number of case studies including liquid metals in contact with Group IV elements (diamond and silicon), where charge transfer effects at the interface may come into play. Another particularly important liquid in our environment is water. The structural properties of water vary widely as it is brought in contact with other materials. We will then proceed from these seemingly simple cases to complex fluids such as colloids.
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Titova, E. A., i D. V. Alexandrov. "The boundary integral equation for curved solid/liquid interfaces propagating into a binary liquid with convection". Journal of Physics A: Mathematical and Theoretical 55, nr 5 (11.01.2022): 055701. http://dx.doi.org/10.1088/1751-8121/ac463e.

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Abstract The boundary integral method is developed for unsteady solid/liquid interfaces propagating into undercooled binary liquids with convection. A single integrodifferential equation for the interface function is derived using the Green function technique. In the limiting cases, the obtained unsteady convective boundary integral equation transforms into a previously developed theory. This integral is simplified for the steady-state growth in arbitrary curvilinear coordinates when the solid/liquid interface is isothermal (isoconcentration). Finally, we evaluate the boundary integral for a binary melt with a forced flow and analyze how the melt undercooling depends on Péclet and Reynolds numbers.
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Briant, C. L. "Grain Boundary Chemistry and Reactions in Metals". MRS Bulletin 15, nr 10 (październik 1990): 26–32. http://dx.doi.org/10.1557/s0883769400058632.

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An interface can be defined as a surface that serves as a common boundary between two phases. Examples include the boundaries between two solids, two immiscible liquids, a solid and a liquid, a solid and a gas, and a liquid and a gas. Interfaces have been studied for decades by scientists of many different disciplines. One reason for this interest is that the atomic structure and the chemical composition at the interface can differ from that of the bulk material on either side of it. Consequently, the properties of the interface can differ greatly from those of either bulk phase, and chemical reactions can occur more readily at the interface than in the bulk.All the interfaces listed in the previous paragraph are of interest to materials scientists. However, this article will only consider the grain boundary because it has received the most attention by researchers in materials science. Furthermore, we will only consider grain boundaries in metals; nonmetallic systems will be covered in other articles in this issue.A grain boundary is an interface that exists where two single crystals are joined in such a way that their crystallographic orientations are not completely matched. Thus, any polycrystalline material contains many grain boundaries. They occur wherever the individual grains meet one another and can usually be observed by etching a polished cross section of the surface as shown in Figure 1. Grain boundaries first form in a metal as a result of the multiple nucleation sites that occur during solidification.
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Giunta, Giuliana, i Paola Carbone. "Cross-over in the dynamics of polymer confined between two liquids of different viscosity". Interface Focus 9, nr 3 (19.04.2019): 20180074. http://dx.doi.org/10.1098/rsfs.2018.0074.

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Using molecular dynamics simulations, we analysed the polymer dynamics of chains of different molecular weights entrapped at the interface between two immiscible liquids. We showed that on increasing the viscosity of one of the two liquids the dynamic behaviour of the chain changes from a Zimm-like dynamics typical of dilute polymer solutions to a Rouse-like dynamics where hydrodynamic interactions are screened. We observed that when the polymer is in contact with a high viscosity liquid, the number of solvent molecules close to the polymer beads is reduced and ascribed the screening effect to this reduced number of polymer–solvent contacts. For the longest chain simulated, we calculated the distribution of loop length and compared the results with the theoretical distribution developed for solid/liquid interfaces. We showed that the polymer tends to form loops (although flat against the interface) and that the theory works reasonably well also for liquid/liquid interfaces.
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Howe, J. M. "Quantification of order in the liquid at a solid-liquid interface by high-resolution transmission electron microscopy (HRTEM)". Proceedings, annual meeting, Electron Microscopy Society of America 54 (11.08.1996): 114–15. http://dx.doi.org/10.1017/s0424820100163034.

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A number of different theoretical approaches have been used to model the atomic structure and properties of solid-liquid interfaces. Most calculations indicate that ordering occurs in the first several layers of the liquid, adjacent to the crystal surface. In contrast to the numerous theoretical investigations, there have been no direct experimental observations of the atomic structure of a solid-liquid interface for comparison. Saka et al. examined solid-liquid interfaces in In and In-Sb at lattice-fringe resolution in the TEM, but their data do not reveal information about the atomic structure of the liquid phase. The purpose of this study is to determine the atomic structure of a solid-liquid interface using a highly viscous supercooled liquid, i.e., a crystal-amorphous interface.
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Pascall, Andrew J., i Todd M. Squires. "Electrokinetics at liquid/liquid interfaces". Journal of Fluid Mechanics 684 (28.09.2011): 163–91. http://dx.doi.org/10.1017/jfm.2011.288.

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AbstractElectrokinetic effects at liquid/liquid interfaces have received considerably less attention than at solid/liquid interfaces. Because liquid/liquid interfaces are generally mobile, one might expect electrokinetic effects over a liquid/liquid interface to be faster than over an equivalent solid surface. The earliest predictions for the electrophoretic mobility of charged mercury drops – distinct approaches by Frumkin, along with Levich, and Booth – differed by $O(a/ {\lambda }_{D} )$, where $a$ is the radius of the drop and ${\lambda }_{D} $ is the Debye length. Seeking to reconcile this rather striking discrepancy, Levine & O’Brien showed double-layer polarization to be the key ingredient. Without a physical mechanism by which electrokinetic effects are enhanced, however, it is difficult to know how general the enhancement is – whether it holds only for liquid metal surfaces, or more generally, for all liquid/liquid surfaces. By considering a series of systems in which a planar metal strip is coated with either a liquid metal or liquid dielectric, we show that the central physical mechanism behind the enhancement predicted by Frumkin is the presence of an unmatched electrical stress upon the electrolyte/liquid interface, which establishes a Marangoni stress on the droplet surface and drives it into motion. The source of the unbalanced electrokinetic stress on a liquid metal surface is clear – metals represent equipotential surfaces, so no field exists to drive an equal and opposite force on the surface charge. This might suggest that liquid metals represent a unique system, since dielectric liquids can support finite electric fields, which might be expected to exert an electrical stress on the surface charge that balances the electric stress. We demonstrate, however, that electrical and osmotic stresses on relaxed double layers internal to dielectric liquids precisely cancel, so that internal electrokinetic stresses generally vanish in closed, ideally polarizable liquids. The enhancement predicted by Frumkin for liquid mercury drops can thus be expected quite generally over ideally polarizable liquid drops. We then reconsider the electrophoretic mobility of spherical drops, and reconcile the approaches of Frumkin and Booth: Booth’s neglect of double-layer polarization leads to a standard electro-osmotic flow, without the enhancement, and Frumkin’s neglect of the detailed double-layer dynamics leads to the enhanced electrocapillary motion, but does not capture the (sub-dominant) electrophoretic motion. Finally, we show that, while the electrokinetic flow over electrodes coated with thin liquid films is $O(d/ {\lambda }_{D} )$ faster than over solid/liquid interfaces, the Dukhin number, $\mathit{Du}$, which reflects the importance of surface conduction to bulk conduction, generally increases by a smaller amount [$O(d/ L)$], where $d$ is the thickness of film and $L$ is the length of the electrode. This suggests that liquid/liquid interfaces may be utilized to enhance electrokinetic velocities in microfluidic devices, while delaying the onset of high-$\mathit{Du}$ electrokinetic suppression.
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Rozprawy doktorskie na temat "Interfaces liquide/solide"

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Retieb, Safia. "Simulations eulériennes des contacteurs diphasiques liquide-liquide et solide-liquide". Toulouse, INPT, 1999. http://www.theses.fr/1999INPT007G.

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Ce travail est consacre a une analyse des potentialites de la simulation numerique eulerienne de l'hydrodynamique de contacteurs liquide-liquide de type colonne pulsee a garnissage disques et couronnes, et liquide-solide de type lit fluidise. Cette analyse est fondee sur l'exploitation d'un code de calcul industriel diphasique de mecanique des fluides (astrid - edf/simulog) dont les resultats sont compares a des mesures experimentales issues de la litterature. L'etude numerique porte sur la prediction des grandeurs de l'ecoulement diphasique turbulent instationnaire (champ moyen de vitesse de la phase continue et de la phase dispersee, energie cinetique turbulente de la phase continue, agitation des inclusions, fraction volumique des inclusions) pour differentes conditions operatoires et geometriques. Ce code est construit sur un modeles a deux fluides dans lequel intervient un modele collisionnel permettant de rendre compte des inevitables collisions entre les inclusions dans de tels contacteurs. La turbulence de la phase continue est prise en compte a l'aide d'un modele q 2 1 diphasique. L'agitation de la phase dispersee est modelisee soit par le modele d'entrainement local (theorie de tchen) dans le cas des colonnes pulsees liquide-liquide, soit par un modele a deux equations de transport dans le cas du lit fluidise solide-liquide. Dans les colonnes pulsees, la comparaison quantitative des simulations euleriennes avec des resultats issus de la litterature en terme de retention moyenne determinee sur une periode de pulsation et sur un compartiment de la colonne, et en terme de perte de charge moyennee sur une periode de pulsation, s'avere satisfaisante. Les comparaisons sont menees jusqu'a des retentions moyennes de 30%. L'evolution de la retention moyenne en fonction de la frequence de pulsation (de 0,5hz a 1,25hz) et du diametre des gouttes (de 0,5 mm et 2,5 mm) s'accorde egalement avec les resultats issus de la litterature. Dans le cas des lits fluidises, consideres comme des milieux tres denses, la comparaison en terme de retention moyenne des resultats numeriques avec ceux obtenus par la correlation de richardson et zaki semble etre tres interessante. Les comparaisons sont menees dans ce cas pour des vitesses du liquide variant entre un et cinq fois la vitesse minimale de fluidisation.
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Ascon-Cabrera, Miguel-Angel. "Dégradation microbienne de composés xénobiotiques en bioréacteurs multiphasiques, aux interfaces liquide-liquide et solide-liquide". Compiègne, 1993. http://www.theses.fr/1993COMPD636.

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La thèse a pour objectif de définir clairement la biodégradation des composes xénobiotiques aux interfaces liquide-liquide et solide-liquide des bioréacteurs multiphasiques, en considérant principalement les aspects physiologiques des microorganismes aux interfaces. D'une part, la thèse décrit la performance d'un système multiphasique contenant une interface liquide-liquide (utilisant l'huile de silicone comme une phase organique) pour la sélection rapide des microorganismes capables de dégrader les composes xénobiotiques, et la dégradation des composés xénobiotiques peu solubles dans l'eau a taux de dégradation élevés. De plus, les effets de l'aire interfaciale du système liquide-liquide et l'hydrophobicité cellulaire des microorganismes sur la haute performance de dégradation des composes xénobiotiques sont déterminés et expliqués. D'autre part, la thèse décrit la performance d'un système multiphasique contenant une interface solide-liquide (utilisant du verre poreux, de la gomme de silicone et des fragments de polystyrène comme supports solides) pour atteindre une forte dégradation des composes xénobiotiques par des microorganismes adhérés aux surfaces. De plus, la formation et les mécanismes physiologiques qui déterminent le fonctionnement des biofilms à l'état stationnaire dans des réacteurs à lit fixé et à recirculation pendant la dégradation des composés xénobiotiques sont déterminés et expliqués. Finalement, la performance des biofilms aérobiques et anaérobiques à l'état stationnaire couplés et recyclés pour la dégradation des composés xénobiotiques récalcitrantes chlorés sont exposés et expliqués.
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PRINZ, CHRISTELLE. "Brosses de polyelectrolytes faibles aux interfaces liquide-solide et liquide-gaz". Université Louis Pasteur (Strasbourg) (1971-2008), 1999. http://www.theses.fr/1999STR13186.

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Nous avons etudie les brosses de polyelectrolytes faibles aux interfaces liquide-solide et liquide-gaz. Les brosses sont construites a l'interface eau-air, dans une cuve de langmuir avec des copolymeres bisequences de polystyrene-polyvinylpyridine. La polystyrene sert de point d'ancrage a la sequence de polyvinylpyridine qui est une polybase faible. Les brosses sont caracterisees a l'interface eau-air grace a l'etude des isothermes de langmuir. D'autre part, des mesures de forces par afm a l'interface eau-solide permettent de determiner l'epaisseur des brosses. Nous avons etudie l'effet du ph, de la longueur des chaines et du sel sur les isothermes de langmuir. A ph3, les isothermes revelent l'existence d'une transition de phase du premier ordre. La couche passe d'un etat ou les chaines sont adsorbees a l'interface aux petites densites de greffage a un etat de brosse de polyelectrolytes forts aux grandes densites de greffage. A ph 2, les isothermes montrent que la brosse est dans le regime fortement sale. Par contre, les mesures d'epaisseur de la brosse par afm a ph 2 indiquent que la brosse est dans le regime fortement sale aux grandes aires par chaines et dans le regime osmotique, domine par les contreions, aux petites aires par chaines. Dans ce dernier regime, l'epaisseur de la brosse diminue quand la densite de greffage augmente.
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Favrie, Nicolas. "Un modèle d'interfaces diffuses pour l'intéraction solide-fluide dans le cas des grandes déformations". Aix-Marseille 1, 2008. http://www.theses.fr/2008AIX11043.

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Pinhas, Marie-France. "Etude thermodynamique des interactions accepteur-donneur d'électrons par mouillabilité : application aux interfaces liquide-liquide et solide-solide". Mulhouse, 1993. http://www.theses.fr/1993MULH0301.

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L'émergence du concept accepteur-donneur d'électrons en adhésion a constitué une avancée considérable dans la compréhension de la nature des interactions non-dispersives. L'importante contribution de F. M. Fowkes développée à partir des concepts de Drago et Gutmann nous permet de déterminer l'enthalpie exothermique de formation des liaisons acide-base à partir de la composante acide-base du travail d'adhésion. Fowkes et al. Ont supposé négligeable la contribution des effets entropiques impliqués dans la formation de l'interface. Cette hypothèse peut conduire à des erreurs importantes sur les résultats et les interprétations étant donné que ces effets entropiques qui dépendent des structures moléculaires et de la nature des interactions peuvent affecter de façon considérable l'énergie libre de Gibbs et sa composante enthalpique. Dans ce travail, le but est de développer une analyse cohérente des mesures de mouillabilité pour estimer de la façon la plus précise possible le caractère acide-base des interactions échangées à l'interface (liquide-liquide et solide-liquide). A travers une analyse thermodynamique simple des mesures effectuées en fonction de la température, la variation de la contribution entropique apparaît être d'un importance tant numérique que physique. Nos résultats coïncident avec la structure moléculaire des substrats et le caractère accepteur-donneur d'électrons des liquides sondes et supportent bien la comparaison avec les valeurs déterminées sur des solides similaires par des techniques usuelles telles que chromatographie gazeuse inverse, microcalorimétrie. . .
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Sarraf, Riad. "Adsorption compétitive du tétrahydrothiophène et du benzène aux interfaces liquide-solide et gaz-solide". Montpellier 2, 1994. http://www.theses.fr/1994MON20230.

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L'etude de l'impact du stockage souterrain du gaz naturel sur la qualite de l'aquifere et l'evolution de la concentration de polluants polaires, dans le gaz et dans l'eau a ete entreprise en selectionnant les molecules liquides (tetrahydrothiophene, benzene) et les mineraux representatifs de la roche reservoir (quartz, kaolin, sable de gue, illite,). Apres une premiere phase de caracterisation physico-chimique des solides et des adsorbats retenus, nous nous sommes interesses a l'etude des phenomenes interfaciaux. L'etude a l'interface solide solution aqueuse est exploree en realisant les isothermes d'adsorption et de desorption de differents adsorbats sur les differents adsorbants. Les resultats des isothermes d'adsorption montrent : _ qu'il existe une affinite du tetrahydrothiophene (tht) selon le classement suivant : charbon actif g212 > quartz > sable de gue > kaolin > alumine > calcite > illite _ l'adsorption du tht est plutot reversible, augmente avec la temperature et la salinite et elle est sensible a la nature et au nombre de groupements superficiels. _ l'adsorption du benzene est du type physique, reversible et augmente avec la temperature. _ la presence du benzene en solution aqueuse contenant du tht (et inversement) modifie d'une maniere consequente l'adsorption de tht sur le quartz a 25\c. Dans une seconde phase, nous avons concu et realise un appareil original d'adsorption multigaz, pour la determination des isothermes d'adsorption et de desorption a l'interface gaz - solide. Cet appareil nous a permis de tracer : _ les isothermes d'adsorption individuelle de l'eau, le benzene et du tht _ les isothermes d'adsorption composite des systemes (eau / tht et eau / benzene).
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Dreher, Thibaud. "Simulation moléculaire d'interfaces solide-liquide : calcul de la tension de surface". Thesis, Université Clermont Auvergne‎ (2017-2020), 2018. http://www.theses.fr/2018CLFAC089/document.

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Le présent manuscrit présente le développement méthodologique du calcul de la tension de surface d’interfaces solide-liquide via des simulations de dynamique moléculaire. Après une courte présentation des avancées dans le domaine du calcul de la tension de surface pour les interfaces fluide-fluide et solide-fluide, les principales méthodes de calcul de la tension de surface d’un point de vue théorique sont montrées et généralisées pour le cas des interfaces solide-liquide, puis mises en oeuvre dans le cas de simulations de dynamique moléculaire. Un système école, constitué d’une feuille de graphène pour la phase solide et d’un bain de méthane pour la phase liquide, est ensuite étudié pour observer l’influence des artefacts de simulation sur le calcul de la tension de surface, montrant en particulier des effets de taille bien plus importants que pour le cas des interfaces liquide-liquide. Un autre système constitué d’une tranche de cuivre pour la phase solide, et d’un bain de méthane pour la phase liquide, a permis d’étudier l’effet inédit aux systèmes solide-liquide appelé anisotropie, montrant en particulier l’importance du caractère tensoriel de la tension de surface pour ce type de système. L’influence des paramètres du potentiel croisé entre les atomes de cuivre et de méthane est ensuite étudié. Finalement, deux systèmes applicatifs sont abordés, d’une part le système graphène-eau permettant d’étudier les effets de l’interaction électrostatique, et d’autre part un système constitué d’un solide explosif, le 1,3,5-triamino-2,4,6-trinitrobenzène (TATB) en contact avec un bain polymère pour la phase liquide, représentatif d’un cas réel d’intérêt
This manuscript presents the methodological development of surface tension calculation of solid-liquidinterfaces via molecular dynamics simulations. After a short presentation of the advances in the field ofsurface tension calculation for fluid-fluid and solid-fluid interfaces, the main methods of surface tensioncalculation from a theoretical point of view are shown and generalized for solid-liquid interfaces, thenimplemented in the case of molecular dynamics simulations. A school system, consisting of a graphenesheet for the solid phase and a methane bath for the liquid phase, is then studied to observe the influenceof simulation artifacts on the surface tension calculation, showing in particular much larger size effectsthan in the case of liquid-liquid interfaces. Another system consisting of a copper slice for the solid phaseand a methane bath for the liquid phase made it possible to study the novel effect of solid-liquid systemscalled anisotropy, showing in particular the importance of the tensor character of the surface tension forthis type of system. The influence of the parameters of the cross potential between copper and methaneatoms is then studied. Finally, two application systems are discussed, on the one hand the graphene-watersystem for studying the effects of electrostatic interaction, and on the other hand a system consisting ofan explosive solid, 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) in contact with a polymer bath for theliquid phase, representing a real case of interest
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Steinberger, Audrey Charlaix Elisabeth. "Nanorhéologie écoulement limite et friction à l'interface liquide-solide /". [s.l.] : [s.n.], 2006. http://tel.archives-ouvertes.fr/docs/00/13/42/61/PDF/these_311006.pdf.

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Giordano, Palmino Fabienne. "Etude thermodynamique de la coadsorption de molécules tensioactives à l'interface silice-solution aqueuse". Aix-Marseille 2, 1993. http://www.theses.fr/1993AIX22030.

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Dans un premier temps, on etudie l'adsorption du tensioactif non ionique seul (un octylphenol polyoxyethylenique) sur des silices poreuses ou colloidales. A partir de la determination des isothermes d'adsorption et des enthalpies de deplacement, nous en deduisons la formation, sur la surface, d'agregats dont la structure est proche de celle des micelles. Ensuite, l'etude des melanges (constitues du tensioactif non ionique precedent avec soit un alkyl sulfonate soit un alkylpyridinium) est realisee en deux etapes. D'une part une etude des proprietes des solutions avec notamment la determination des enthalpies de micellisation en fonction de la composition nous permet de calculer un parametre d'interaction entre tensioactifs que l'on peut comparer aux modeles courants. Les resultats obtenus montrent une part enthalpique importante dans la stabilisation des micelles mixtes que nous interpretons par la rehydratation des maillons oxyethyleniques. D'autre part, une etude de l'adsorption montre que, grace a la formation d'agregats superficiels mixtes, l'adsorption du tensioactif anionique sur la silice (il ne s'adsorbe pas lorsqu'il est seul) est rendue possible mais au detriment de la quantite totale adsorbee. Par contre, dans le cas du cationique, on observe un net accroissement de la quantite totale adsorbee par rapport aux composes seuls. La comparaison des agregats superficiels et des micelles, tant au niveau de leur composition qu'a celui des enthalpies d'exces de formation de ces differents agregats, montre que les interactions laterales predominent dans le processus d'adsorption et sont similaires a celles conduisant a la formation des micelles
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Brunet, Léna Casamatta Gilbert Prat Laurent. "Conception d'un nouveau type de colonne pulsée appliquée au contact solide-liquide". Toulouse : INP Toulouse, 2005. http://ethesis.inp-toulouse.fr/archive/00000190.

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Książki na temat "Interfaces liquide/solide"

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1942-, Kallay Nikola, red. Interfacial dynamics. New York: M. Dekker, 2000.

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Ecole, d'été de physique théorique (Les Houches Haute-Savoie France) (48th 1988). Liquides aux interfaces =: Liquids at interfaces. Amsterdam: North-Holland, 1990.

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1938-, Halley J. Woods, American Chemical Society. Division of Colloid and Surface Chemistry. i American Chemical Society Meeting, red. Solid-liquid interface theory. Washington, DC: American Chemical Society, 2001.

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Peker, Sümer M. Solid-liquid two phase flow. Amsterdam: Elsevier, 2008.

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Wandelt, Klaus, i Stephe Thurgate, red. Solid—Liquid Interfaces. Berlin, Heidelberg: Springer Berlin Heidelberg, 2002. http://dx.doi.org/10.1007/3-540-44817-9.

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Jerkiewicz, Gregory, Manuel P. Soriaga, Kohei Uosaki i Andrzej Wieckowski, red. Solid-Liquid Electrochemical Interfaces. Washington, DC: American Chemical Society, 1997. http://dx.doi.org/10.1021/bk-1997-0656.

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Gregory, Jerkiewicz, i International Chemical Congress of Pacific Basin Societies (1995 : Honolulu, Hawaii), red. Solid-liquid electrochemical interfaces. Washington, DC: American Chemical Society, 1997.

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Halley, J. Woods, red. Solid-Liquid Interface Theory. Washington, DC: American Chemical Society, 2001. http://dx.doi.org/10.1021/bk-2001-0789.

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Déjardin, Philippe, red. Proteins at Solid-Liquid Interfaces. Berlin, Heidelberg: Springer Berlin Heidelberg, 2006. http://dx.doi.org/10.1007/3-540-32658-8.

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P, Binks Bernard, i Horozov Tommy, red. Colloidal particles at liquid interfaces. Cambridge: Cambridge University Press, 2006.

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Części książek na temat "Interfaces liquide/solide"

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Masuda, Takuya, Toshihiro Kondo i Kohei Uosaki. "Solid–Liquid Interfaces". W XAFS Techniques for Catalysts, Nanomaterials, and Surfaces, 505–25. Cham: Springer International Publishing, 2016. http://dx.doi.org/10.1007/978-3-319-43866-5_31.

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Zhu, Yimei, Hiromi Inada, Achim Hartschuh, Li Shi, Ada Della Pia, Giovanni Costantini, Amadeo L. Vázquez de Parga i in. "Solid–Liquid Interfaces". W Encyclopedia of Nanotechnology, 2487. Dordrecht: Springer Netherlands, 2012. http://dx.doi.org/10.1007/978-90-481-9751-4_100787.

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Thomas, R. K., J. N. Israelachvili, D. J. Mitchell i B. W. Ninham. "Liquid-solid interfaces". W 100 Years of Physical Chemistry, 237–82. Cambridge: Royal Society of Chemistry, 2007. http://dx.doi.org/10.1039/9781847550002-00237.

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Tadros, Tharwat. "Interface, Solid-liquid". W Encyclopedia of Colloid and Interface Science, 636. Berlin, Heidelberg: Springer Berlin Heidelberg, 2013. http://dx.doi.org/10.1007/978-3-642-20665-8_110.

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Memming, Rüdiger. "Solid-Liquid Interface". W Semiconductor Electrochemistry, 89–125. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2015. http://dx.doi.org/10.1002/9783527688685.ch5.

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Li, Hua, Timo Carstens, Aaron Elbourne, Natalia Borisenko, René Gustus, Frank Endres i Rob Atkin. "Ionic Liquid-Solid Interfaces". W Electrodeposition from Ionic Liquids, 321–43. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2017. http://dx.doi.org/10.1002/9783527682706.ch9.

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Tosi, M. P. "Liquid Surfaces and Solid-Liquid Interfaces". W Amorphous Solids and the Liquid State, 125–56. Boston, MA: Springer US, 1985. http://dx.doi.org/10.1007/978-1-4757-9156-3_5.

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Morrison, S. Roy. "The Solid/Liquid Interface". W The Chemical Physics of Surfaces, 297–331. Boston, MA: Springer US, 1990. http://dx.doi.org/10.1007/978-1-4899-2498-8_8.

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Blinov, Lev M. "Liquid Crystal – Solid Interface". W Structure and Properties of Liquid Crystals, 257–82. Dordrecht: Springer Netherlands, 2010. http://dx.doi.org/10.1007/978-90-481-8829-1_10.

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O’Shea, S. J., M. A. Lantz i M. E. Welland. "AFM at Liquid-Solid Interfaces". W Micro/Nanotribology and Its Applications, 101–19. Dordrecht: Springer Netherlands, 1997. http://dx.doi.org/10.1007/978-94-011-5646-2_6.

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Streszczenia konferencji na temat "Interfaces liquide/solide"

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Bula, Antonio J., Muhammad M. Rahman i John E. Leland. "Transient Axial Free Jet Impinging Over a Flat Uniformly Heated Disk: Solid–Fluid Properties Effects". W ASME 2000 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 2000. http://dx.doi.org/10.1115/imece2000-1543.

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Abstract Transient conjugate heat transfer process during axial free jet impingement on a solid disk of finite thickness was considered. As the fluid reached steady state, power was turned on and a uniform heat flux was imposed on the disk at its opposite surface. The numerical model considered both solid and fluid regions. Equations for conservation of mass, momentum, and energy were solved in the liquid region taking into account the transport processes at the inlet and exit boundaries, as well as at the solid-liquid and liquid-gas interfaces. Inside the solid, only the heat conduction equation was solved. The shape and location of the free surface (liquid-gas interface) was determined iteratively as a part of the solution process by satisfying the kinematic condition as well as the balance of normal and shear forces at this interface. A non-uniform grid distribution, captured from a systematic grid-independence study, was used to adequately accommodate large variations near the solid-fluid interface. Computed results include the simulation of six different substrate materials namely, aluminum, constantan, copper, diamond, silicon, and silver, and three different impinging liquids, FC - 77, Mil - 7808, and water. The solids and fluids selected covered a wide range of possibilities of conjugate heat transfer phenomena. The analysis performed showed that the thermal storage capacity, defined as density times specific heat, is an important factor defining which material will attain steady state faster during conjugate heat transfer process, like the thermal diffusivity does it for pure conduction heat transfer.
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Bula, Antonio J., i Muhammad M. Rahman. "Transient Thermal Management of Microelectronics Using Free Liquid Jet Impingement". W ASME 2004 International Mechanical Engineering Congress and Exposition. ASMEDC, 2004. http://dx.doi.org/10.1115/imece2004-60840.

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The results of numerical simulation of a transient heat transfer process when a free jet of high Prandtl number fluid impinges perpendicularly on a solid substrate of finite thickness containing discrete electronics on the opposite surface are presented. The numerical model was developed considering both solid and fluid regions and solved as a conjugate problem. Equations for the conservation of mass, momentum, and energy were solved in the liquid region taking into account the transport processes at the inlet and exit boundaries as well as at the solid-liquid and liquid-gas interfaces. In the solid region, only heat conduction equation was solved. The shape and location of the free surface (liquid-gas interface) was determined iteratively as a part of the solution process by satisfying the kinematic condition as well as the balance of normal and shear forces at this interface. The number of elements in the fluid and solid regions were determined from a systematic grid-independence study. A non-uniform grid distribution was used to adequately capture large variations near the solid-fluid interface. Computed results included the local and average heat transfer coefficients at the solid-fluid interface. Computations were carried out to investigate the influence of different operating parameters such as jet velocity and plate material. It was found that the average heat transfer coefficient is maximum at early stages of the transient process and decreases gradually with time to the final steady state condition.
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Lewis, T. J. "The solid-liquid interface". W IEE Colloquium on An Engineering Review of Liquid Insulation. IEE, 1997. http://dx.doi.org/10.1049/ic:19970014.

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Rahman, Muhammad M., Antonio J. Bula i John E. Leland. "Numerical Modeling of Conjugate Heat Transfer During Free Liquid Jet Impingement". W ASME 1998 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 1998. http://dx.doi.org/10.1115/imece1998-0876.

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Abstract The paper presents the results of numerical simulation of a free jet of high Prandtl number fluid impinging perpendicularly on a solid substrate of finite thickness containing electronics on the opposite surface. The numerical model was developed considering both solid and fluid regions and solved as a conjugate problem. Equations for the conservation of mass, momentum, and energy were solved in the liquid region taking into account the transport processes at the inlet and exit boundaries as well as at the solid-liquid and liquid-gas interfaces. In the solid region, only heat conduction equation was solved. The shape and location of the free surface (liquid-gas interface) was determined iteratively as a part of the solution process by satisfying the kinematic condition as well as the balance of normal and shear forces at this interface. The number of elements in the fluid and solid regions were determined from a systematic grid-independence study. A non-uniform grid distribution was used to adequately capture large variations near the solid-fluid interface. Computed results included the velocity, temperature, and pressure distributions in the fluid, and the local and average heat transfer coefficients at the solid-fluid interface. Computations were carried out to investigate the influence of different operating parameters such as jet velocity, heat flux, plate thickness, and plate material. Numerical results were validated with available experimental data. It was found that the local heat transfer coefficient is maximum at the center of the disk and decreases gradually with radius as the flow moves downstream. The average heat transfer coefficient and the maximum temperature occurring in the solid decreased with increase of disk thickness and increase of thermal conductivity of the disk material.
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Beroual, Abderrahmane. "Creeping Discharges at Liquid/solid and Gas/Solid Interfaces: Analogies and Involving Mechanisms". W 2019 IEEE 20th International Conference on Dielectric Liquids (ICDL). IEEE, 2019. http://dx.doi.org/10.1109/icdl.2019.8796829.

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Olmsted, Brian L., i Michieal L. Jones. "Microcavities for Ultrasensitive Spectroscopy". W Modern Spectroscopy of Solids, Liquids, and Gases. Washington, D.C.: Optica Publishing Group, 1995. http://dx.doi.org/10.1364/msslg.1995.sthb11.

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Spectroscopy is often performed on emission or absorption centers that due to sample preparation are located within a thin film or located in proximity to a dielectric interface. However, locating emission or absorption centers near reflecting interfaces can strongly effect their interaction with the electromagnetic field. In recent years, there have been several reports of the observation of a change in the angular distribution of emission due to cavity confinement. In addition, changes in the radiative lifetime have also been reported. A review of spontaneous emission from planar microstructures has recently been presented by Deppe et. al.1 The perturbation of the radiative properties of centers can be predicted using quantum electrodynamics for the electromagnetic modes of the discontinuous media. In fact, it is possible to design a specific structure to enhance the mode amplitude, and therefore, the interaction at the position of a radiative center. This approach can be used for ultrasensitive spectroscopy. Furthermore, emission or excitation angle can be used to selectivity cause enhancement at a particular frequency or position within a planar structure.
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Wadley, Haydn N. G., Douglas T. Queheillalt i Yichi Lu. "Ultrasonic transmission at solid-liquid interfaces". W Nondestructive Evaluation Techniques for Aging Infrastructure and Manufacturing, redaktorzy Richard H. Bossi i Tom Moran. SPIE, 1996. http://dx.doi.org/10.1117/12.259189.

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Juric, Damir, i Grétar Tryggvason. "Numerical Simulations of Phase Change in Microgravity". W ASME 1996 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 1996. http://dx.doi.org/10.1115/imece1996-0026.

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Abstract Direct numerical simulations of liquid-solid and liquid-vapor phase change are conducted under microgravity conditions. The time-dependent governing equations are solved using a two-dimensional finite-difference/front-tracking method. Large interface deformations, topology change, latent heat, surface tension and unequal material properties between the phases are included in the simulations. Results are presented for two specific problems: directional solidification of a dilute binary alloy and the rapid evaporation of a superheated liquid (vapor explosion). For the directional solidification problem, solution of the fully coupled solute and energy equations reveals the evolution of morphologically complex structures such as tip splitting, coarsening and droplet detachment from deep intercellular grooves. A variety of important solute segregation patterns such as necking, coring and banding are also observed. The boiling problem couples the phase change with fluid flow. This requires the solution of the Navier-Stokes and energy equations with interphase mass transfer. The energetic growth of instabilities on planar and circular interfaces during the unstable explosive evaporation of a superheated liquid in microgravity is demonstrated.
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Scholz, Daniel, i Paul Simutis. "Understanding interfaces: Using contact angle measurements to determine surface tension, interfacial tension, and kinetic properties from contact angle hysteresis". W 2022 AOCS Annual Meeting & Expo. American Oil Chemists' Society (AOCS), 2022. http://dx.doi.org/10.21748/tjyy3220.

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When there is an interface between a liquid and a solid, the angle between the surface of the liquid and the baseline of the contact surface is described as the contact angle. The contact angle is a measure of the wettability of a solid by a liquid. Measurement of the contact angle helps in all situations where solids and liquids meet and there is benefit gained by control of wetting and adhesion properties. Applications where contact angle values are especially important include development of hydrophobic or hydrophilic surface coatings, paints and varnishes, cleaning agents, printing processes, and more. Contact angle goniometers are high-precision video camera-based devices which perform the optical analysis of the shape of liquid drops placed on a solid surface (sessile drop method) or the shape of drops that hang down from a dosing needle (pendant drop method). The drop shape helps in determination of different surface and interfacial parameters such as surface tension of a liquid, interfacial tension between two liquids, and surface energy of solid substrates. Contact angle hysteresis is an important physical phenomenon arising from chemical inhomogeneities, roughness, or impurities on a surface which can affect how a liquid droplet spreads across a surface. Contact angle hysteresis is the difference between advancing and receding contact angles and can be measured using the “needle-in method” or by tilting the actual contact angle goniometer or sample stage itself, allowing the droplet to roll across the surface of the substrate. This paper will describe recent advances in contact angle goniometry and will explain how surface tension, interfacial tension, and contact angle hysteresis measurements can be easily and accurately made using a modern contact angle goniometer and software.
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Torii, Daichi, Taku Ohara i Kenji Ishida. "Molecular Scale Mechanism of Thermal Resistance at Solid-Liquid Interfaces (Influence of Interaction Parameters Between Solid and Liquid Molecules)". W ASME/JSME 2007 Thermal Engineering Heat Transfer Summer Conference collocated with the ASME 2007 InterPACK Conference. ASMEDC, 2007. http://dx.doi.org/10.1115/ht2007-32391.

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Nonequilibrium molecular dynamics simulations have been performed for systems of a liquid film confined between atomistic solid walls. The two solid walls have different temperatures to generate a steady thermal energy flux in the system, which is the element of macroscopic heat conduction flux. Three kinds of liquid molecules and three kinds of solid walls are examined, and the thermal energy flux is measured at control surfaces in the liquid film and at the solid-liquid interfaces. By analyzing the thermal energy flux in detail by decomposing it into several molecular-scale contributions, influence of interaction parameters between solid and liquid molecules and the spacing of molecular alignment on the surface of the solid wall are clarified, and the molecular-scale mechanisms that govern the thermal resistance at a solid-liquid interface are elucidated.
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Raporty organizacyjne na temat "Interfaces liquide/solide"

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DR. PAUL WYNBLATT. ENERGETICS OF SOLID/SOLID AND LIQUID/SOLID INTERFACES. Office of Scientific and Technical Information (OSTI), październik 2004. http://dx.doi.org/10.2172/833421.

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Mark Asta. Computational Investigations of Solid-Liquid Interfaces. Office of Scientific and Technical Information (OSTI), sierpień 2011. http://dx.doi.org/10.2172/1023516.

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Cahil, David, G., i Paul, V. Braun. Final Report: Thermal Conductance of Solid-Liquid Interfaces. Office of Scientific and Technical Information (OSTI), maj 2006. http://dx.doi.org/10.2172/885425.

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Blum, L., i D. A. Huckaby. Exact Results for the Structured Liquid-Solid Interface. Fort Belvoir, VA: Defense Technical Information Center, styczeń 1991. http://dx.doi.org/10.21236/ada232992.

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Blum, L., i D. A. Huckaby. Exact Results for the Structured Liquid-Solid Interface. Fort Belvoir, VA: Defense Technical Information Center, kwiecień 1990. http://dx.doi.org/10.21236/ada222762.

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Kleiner, Kevin Gordon, Aparna Nair-Kanneganti, Ivana Gonzales, Christian Francisco Andres Negre i Anders Mauritz Niklasson. Modeling solid-liquid interfaces using next generation quantum molecular dynamics. Office of Scientific and Technical Information (OSTI), sierpień 2018. http://dx.doi.org/10.2172/1467197.

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Harvey W. Blanch. Enzyme Activity and Biomolecule Templating at Liquid and Solid Interfaces. Office of Scientific and Technical Information (OSTI), grudzień 2004. http://dx.doi.org/10.2172/1027457.

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Carlson, A. B. Liquid effluent services and solid waste disposal interface control document. Office of Scientific and Technical Information (OSTI), październik 1994. http://dx.doi.org/10.2172/10102583.

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P. Somasundaran. BEHAVIOR OF SURFACTANT MIXTURES AT SOLID/LIQUID AND OIL/LIQUID INTERFACES IN CHEMICAL FLOODING SYSTEMS. Office of Scientific and Technical Information (OSTI), listopad 2004. http://dx.doi.org/10.2172/837073.

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Rice, Stuart A. Experimental and Theoretical Studies of Liquid-Solid and Liquid-Vapor Interfaces of Metals and Alloys. Office of Scientific and Technical Information (OSTI), wrzesień 2012. http://dx.doi.org/10.2172/1052401.

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