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Artykuły w czasopismach na temat "Gas solid interaction"

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Dolmatov, A. I., i S. A. Polyviany. "Interaction of Solid Particles from a Gas Stream with the Surface of a Flat Nozzle". METALLOFIZIKA I NOVEISHIE TEKHNOLOGII 43, nr 3 (1.06.2021): 319–28. http://dx.doi.org/10.15407/mfint.43.03.0319.

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Sychov, Maxim М., Sergey V. Mjakin, Alexander I. Ponyaev i Victor V. Belyaev. "Acid-Base (Donor-Acceptor) Properties of Solids and Relations with Functional Properties". Advanced Materials Research 1117 (lipiec 2015): 147–51. http://dx.doi.org/10.4028/www.scientific.net/amr.1117.147.

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Distribution of active surface centers (DAC) spectroscopy is applied to study acid-base properties of solids. Surface characteristics of solid influences interface interaction in which this solid participates. Efficient approach to consider such interactions is to view them as acid-base ones, since acid-base interactions determine adsorption and bonding of organic molecules to solid surface. Paper describes application of method to study surface properties of components of luminescent materials, catalysts, gas sensors, proton membranes and polymer composites, and it was shown that their functional properties strongly depend on distribution of acid-base active surface centers.
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Li, Zhengquan, Kaiwei Chu, Renhu Pan, Aibing Yu i Jiaqi Yang. "Computational Study of Gas-Solid Flow in a Horizontal Stepped Pipeline". Mathematical Problems in Engineering 2019 (15.09.2019): 1–15. http://dx.doi.org/10.1155/2019/2545347.

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In this paper, the mechanism governing the particle-fluid flow characters in the stepped pipeline is studied by the combined discrete element method (DEM) and computational fluid dynamics (CFD) model (CFD-DEM) and the two fluid model (TFM). The mechanisms governing the gas-solid flow in the horizontal stepped pipeline are investigated in terms of solid and gas velocity distributions, pressure drop, process performance, the gas-solid interaction forces, solid-solid interaction forces, and the solid-wall interaction forces. The two models successfully capture the key flow features in the stepped pipeline, such as the decrease of gas velocity, solid velocity, and pressure drop, during and after the passage of gas-solid flow through the stepped section. What is more important, the reason of the appearance of large size solid dune and pressure surge phenomena suffered in the stepped pipeline is investigated macroscopically and microscopically. The section in which the blockage problem most likely occurs in the stepped pipeline is confirmed. The pipe wall wearing problem, which is one of the most common and critical problems in pneumatic conveying system, is analysed and investigated in terms of interaction forces. It is shown that the most serious pipe wall wearing problem happened in the section which is just behind the stepped part.
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Sharma, Renu, Karl Weiss, Michael McKelvy i William Glaunsinger. "Gas reaction chamber for gas-solid interaction studies by high-resolution TEM". Proceedings, annual meeting, Electron Microscopy Society of America 52 (1994): 494–95. http://dx.doi.org/10.1017/s0424820100170207.

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An environmental cell (E-cell) is a gas reaction chamber mounted inside an electron microscope column where thin solid samples can be observed under various gases (O2, H2, N2, NH3 etc.) at selected temperatures. Even though the idea of having an E-cell incorporated in the microscope column is as old as transmission electron microscopy itself, recent developments in the instrumentation and designs of both the microscopes and E-cells have made it possible to obtain high resolution images (0.3-0.6 nm). We have used the differentially pumped model proposed by Swan to modify a PHILLIPS 400T transmission electron microscope for gas-solid studies.Figure la shows a side view cross section schematic of the E-cell fitted in the 9 mm gap between twin lens objective pole pieces. It consists of a small chamber with 200 and 400 μm apertures on sides a and a’ respectively. The walls are machined at the same angle as the pole pieces for an optimum fit to the conical exterior of the pole pieces and the cell is held firmly in place with o-rings (b).
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Liu, Xiao Li, Wen Jing Si i Chun Ying Zhu. "Research on the Gas Migration Regularity of Municipal Solid Waste Landfill in the Solid-Liquid-Gas-Heat Interaction". Advanced Materials Research 243-249 (maj 2011): 2216–19. http://dx.doi.org/10.4028/www.scientific.net/amr.243-249.2216.

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With the establishment of large municipal solid waste landfills, the interaction of geological environment in landfill (seepage field, stress field and temperature field, etc.) has not to be ignored. The multi-field coupling problem of the municipal solid waste landfill is getting attention. But at present the study mainly concentrated on the solid-liquid-gas-heat coupling problem, the study of the waste gas of the municipal solid waste landfill is less. Gas diffusions, gas emissions, and gas collection are related to the secondary pollution problems of the municipal solid waste landfill. This paper established mathematical model which based on the solid-liquid-gas-heat interaction and researched the gas migration rule of the municipal solid waste landfills. The mainly work are as follows: (1) the definite conditions of dynamic model, (2) the solution of dynamic model, (3) results and analysis. The main conclusions are as follows: (1) Pore pressure along the gas flow direction is nonlinear distribution and shows decline trend. As time increases, the pore pressure of each horizontal section decreases. (2)The volumetric strain of the municipal solid waste landfill is nonlinear distribution along the gas flow direction and shows an increasing tendency. As time increases, volumetric strain of each horizontal section increases.(3)As the change of time, the pore pressure first increases, then decreases.(4) In the initial stage, as the change of time, gas output increases rapidly. When it achieves the maximum size, the production quantity of gas reduces and gradually tends to be a quantitative value.
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Giampaolo, Ciriaco, i Socio A. Mottana. "A new experimental technique for gas-solid interaction studies." Rendiconti Lincei 1, nr 2 (czerwiec 1990): 165–69. http://dx.doi.org/10.1007/bf03001891.

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Hrach, Rudolf, Jiří Šimek i Věra Hrachová. "Study of plasma—solid interaction in electronegative gas mixtures". Czechoslovak Journal of Physics 56, nr 12 (grudzień 2006): 1437–44. http://dx.doi.org/10.1007/s10582-006-0456-0.

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Doss, E. D., i M. G. Srinivasan. "Modeling of Wall Friction for Multispecies Solid-Gas Flows". Journal of Fluids Engineering 108, nr 4 (1.12.1986): 486–88. http://dx.doi.org/10.1115/1.3242608.

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The empirical expressions for the equivalent friction factor to simulate the effect of particle-wall interaction with a single solid species have been extended to model the wall shear stress for multispecies solid-gas flows. Expressions representing the equivalent shear stress for solid-gas flows obtained from these wall friction models are included in the one-dimensional two-phase flow model and it can be used to study the effect of particle-wall interaction on the flow characteristics.
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Mironov, D. V., V. M. Mironov, V. F. Mazanko, D. S. Gertsriken i P. V. Peretyatku. "Interaction of metals and alloys with gas media under spark discharges". Resource-Efficient Technologies, nr 3 (28.08.2018): 19–36. http://dx.doi.org/10.18799/24056537/2018/3/199.

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The paper studies the penetration of nitrogen, oxygen, hydrogen, carbon, argon and krypton into copper, nickel, molybdenum, titanium, aluminum, iron and different steels under the action of spark discharges in various media based on radioactive indicators using step-by-step radiometric analysis, macro-, micro-, electron-microscopy and activation autoradiography, Mössbauer and Auger spectroscopy, secondary ion-ionic emission, X-ray diffraction and X-ray microanalysis. The study describes distribution features of penetrating atoms and their concentration profiles. Phase composition of near-surface layers is also determined. It is shown that supersaturated solid solutions of iron in copper and copper in iron are formed during simultaneous iron and oxygen penetration in copper and spinel (Fe6Cu3O4)4. Diffusion of iron and carbon results in supersaturated solid solutions of iron and carbon in copper, copper and carbon in iron, graphite and cementite. Inert gases and nitrogen form solid solutions with copper. Phase composition of near-surface layers in Fe is determined. Iron dioxide FeO, a carbon solid solution in iron with fcc lattice γ-Fe, tetragonal martensite and cementite, two iron (III) hydroxide FeOOH modifications, a supersaturated solid solution of nitrogen and nitride Fe4N, solid solutions of inert gases in iron are formed in the diffusion zone. Simultaneous interaction of molybdenum with iron (the anode material) and various gases results in the formation of substitutional solid solutions of iron in molybdenum and molybdenum in iron, a small amount of interstitial solid solutions of nitrogen and carbon in molybdenum and nitrogen in iron, interstitial phases: molybdenum nitrides and carbides and traces of nitrides of iron (Fe4N, Fe2N) and Fe1,9Mo (λ) phases in the form of needles. Treatment of nickel with a nickel anode in the nitrogen medium promotes formation of a solid solution of nitrogen and nitride Ni3N in the matrix with preserved hexagonal symmetry and lattice parameters that are characteristic of this phase under equilibrium conditions. Atoms of oxygen, nitrogen, carbon and argon are present in the interstitial solid solutions in treatment of nickel in ambient air; however, oxides are not found even on the surface (in the layer ~200 nm). Interaction of titanium with atmospheric gases leads to formation of a solid solution of nitrogen, oxygen, carbon, hydrogen and argon in titanium and titanium nitride Ti2N (ε). Simultaneous saturation of the titanium surface with nickel and nitrogen in the interaction zone causes formation of phases in the following order: nickel nitride; a solid solution of nitrogen and titanium in nickel and a solid solution of both alloying elements in titanium.
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Mironov, D. V., V. M. Mironov, V. F. Mazanko, D. S. Gertsriken i P. V. Peretyatku. "Interaction of metals and alloys with gas media under spark discharges". Resource-Efficient Technologies, nr 3 (28.08.2018): 19–36. http://dx.doi.org/10.18799/24056529/2018/3/199.

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The paper studies the penetration of nitrogen, oxygen, hydrogen, carbon, argon and krypton into copper, nickel, molybdenum, titanium, aluminum, iron and different steels under the action of spark discharges in various media based on radioactive indicators using step-by-step radiometric analysis, macro-, micro-, electron-microscopy and activation autoradiography, Mössbauer and Auger spectroscopy, secondary ion-ionic emission, X-ray diffraction and X-ray microanalysis. The study describes distribution features of penetrating atoms and their concentration profiles. Phase composition of near-surface layers is also determined. It is shown that supersaturated solid solutions of iron in copper and copper in iron are formed during simultaneous iron and oxygen penetration in copper and spinel (Fe6Cu3O4)4. Diffusion of iron and carbon results in supersaturated solid solutions of iron and carbon in copper, copper and carbon in iron, graphite and cementite. Inert gases and nitrogen form solid solutions with copper. Phase composition of near-surface layers in Fe is determined. Iron dioxide FeO, a carbon solid solution in iron with fcc lattice γ-Fe, tetragonal martensite and cementite, two iron (III) hydroxide FeOOH modifications, a supersaturated solid solution of nitrogen and nitride Fe4N, solid solutions of inert gases in iron are formed in the diffusion zone. Simultaneous interaction of molybdenum with iron (the anode material) and various gases results in the formation of substitutional solid solutions of iron in molybdenum and molybdenum in iron, a small amount of interstitial solid solutions of nitrogen and carbon in molybdenum and nitrogen in iron, interstitial phases: molybdenum nitrides and carbides and traces of nitrides of iron (Fe4N, Fe2N) and Fe1,9Mo (λ) phases in the form of needles. Treatment of nickel with a nickel anode in the nitrogen medium promotes formation of a solid solution of nitrogen and nitride Ni3N in the matrix with preserved hexagonal symmetry and lattice parameters that are characteristic of this phase under equilibrium conditions. Atoms of oxygen, nitrogen, carbon and argon are present in the interstitial solid solutions in treatment of nickel in ambient air; however, oxides are not found even on the surface (in the layer ~200 nm). Interaction of titanium with atmospheric gases leads to formation of a solid solution of nitrogen, oxygen, carbon, hydrogen and argon in titanium and titanium nitride Ti2N (ε). Simultaneous saturation of the titanium surface with nickel and nitrogen in the interaction zone causes formation of phases in the following order: nickel nitride; a solid solution of nitrogen and titanium in nickel and a solid solution of both alloying elements in titanium.
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Rozprawy doktorskie na temat "Gas solid interaction"

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Tian, Jian Atwood J. L. "Molecular organic solids for gas adsorption and solid-gas interaction". Diss., Columbia, Mo. : University of Missouri--Columbia, 2009. http://hdl.handle.net/10355/6882.

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Title from PDF of title page (University of Missouri--Columbia, viewed on Feb 24, 2010). The entire thesis text is included in the research.pdf file; the official abstract appears in the short.pdf file; a non-technical public abstract appears in the public.pdf file. Dissertation advisor: Dr. Jerry L. Atwood. Vita. Includes bibliographical references.
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KHAN, BILAL ALAM. "Measurement methods of Gas-Solid Interactions". Doctoral thesis, Politecnico di Torino, 2021. http://hdl.handle.net/11583/2942142.

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Akizuki, Makoto. "Gas Cluster Ion-Solid Surface Interaction and Thin Film Formation". Kyoto University, 1999. http://hdl.handle.net/2433/181783.

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Brancher, Ricardo. "Experimental and numerical analysis of interaction between gas and solid surface". Thesis, Aix-Marseille, 2019. http://www.theses.fr/2019AIXM0677.

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Cette thèse est consacrée à l’étude expérimentale et numérique de l’interaction entre gaz et surface solide. L’écoulement de gaz raréfié à travers un microcanal rectangulaire dans des conditions isothermes et nonisothermes ont été évalués expérimentalement. Le coefficient d’accommodation de la composante tangentielle de la quantité de mouvement pour le matériau PEEK (Poly Ether Ether Ketone) associé à cinq gaz (hélium, néon, azote, argon, krypton) a été extrait des écoulements induits par gradient de pression et gradient de température. De plus, des écoulements unidimensionnels stables d’un gaz polyatomique en présence d’une surface adsorbante-désorbante maintenue à température constante et uniforme sont simulés en résolvant numériquement l’équation cinétique de Boltzmann par la méthode Direct Simulation Monte Carlo (DSMC). Il est considéré ici l’écoulement de gaz entre deux parois planes et infinies, où une seule paroi est capable d’adsorber et de désorber les molécules, tandis que l’autre est imperméable. Enfin,des recherches expérimentales et numériques ont été effectuées pour analyser la séparation des espèces BTEX (benzène, toluène, éthylbenzène et xylènes) à l’intérieur d’une colonne chromatographique. De l’étalonnage des constantes d’adsorption et de désorption, le temps de rétention de chaque espèce peut être prévu pour différentes conditions de fonctionnement en utilisant le code numérique développé
This thesis is devoted to the experimental and numerical study of the interaction between gas and solid surface. Rarefied gas flows through a rectangular microchannel under both isothermal and non-isothermal conditions were experimentally evaluated. The tangential momentum accommodation coefficient for PEEK (Poly Ether Ether Ketone) material associated to five gases (helium, neon, nitrogen, argon, krypton) was extracted from both pressure and temperature gradient driven flows. Additionally, steady one-dimensional flows of a polyatomic gas in the presence of an adsorbing-desorbing surface kept at constant and uniform temperature are simulated by solving numerically the Boltzmann kinetic equation by the Direct Simulation Monte Carlo (DSMC) method. It is considered the flow of gas between two planar and infinite surfaces,where only one surface is able to adsorb and desorb molecules, while the other one is impermeable. Finally, experimental and numerical investigation were performed to analyze the BTEX (benzene, toluene,ethylbenzene and xylenes) species separation inside a chromatographic column. From calibrating the constants of adsorption and desorption, the retention time of each species can be predicted for different operating conditions using the numerical code developed
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Qin, Tong. "Numerical Simulations of Interactions of Solid Particles and Deformable Gas Bubbles in Viscous Liquids". Diss., Virginia Tech, 2013. http://hdl.handle.net/10919/19225.

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Studying the interactions of solid particles and deformable gas
bubbles in viscous liquids is very important in many applications,
especially in mining and chemical industries. These interactions
involve liquid-solid-air multiphase flows and an
arbitrary-Lagrangian-Eulerican (ALE) approach is used for the direct
numerical simulations. In the system of rigid particles and
deformable gas bubbles suspended in viscous liquids, the
Navier-Stokes equations coupled with the equations of motion of the
particles and deformable bubbles are solved in a finite-element
framework. A moving, unstructured, triangular mesh tracks the
deformation of the bubble and free surface with adaptive refinement.
In this dissertation, we study four problems. In the first three
problems the flow is assumed to be axisymmetric and two dimensional
(2D) in the fourth problem.

Firstly, we study the interaction between a rising deformable bubble
and a solid wall in highly viscous liquids. The mechanism of the
bubble deformation as it interacts with the wall is described in
terms of two nondimensional groups, namely the Morton number (Mo)
and Bond number (Bo). The film drainage process is also
considered. It is found that three modes of bubble-rigid wall
interaction exist as Bo changes at a moderate Mo.
The first mode prevails at small Bo where the bubble deformation
is small. For this mode, the bubble is
hard to break up and will bounce back and eventually attach
to the rigid wall. In the second mode, the bubble may break up after
it collides with the rigid wall, which is determined by the film
drainage. In the third mode, which prevails at high Bo, the bubble
breaks up due to the bottom surface catches up the top surface
during the interaction.

Secondly, we simulate the interaction between a rigid particle and a
free surface. In order to isolate the effects of viscous drag and
particle inertia, the gravitational force is neglected and the
particle gains its impact velocity by an external accelerating
force. The process of a rigid particle impacting a free surface and
then rebounding is simulated. Simplified theoretical models are
provided to illustrate the relationship between the particle
velocity and the time variation of film thickness between the
particle and free surface. Two film thicknesses are defined. The
first is the thickness achieved when the particle reaches its
highest position. The second is the thickness when the particle
falls to its lowest position. The smaller of these two thicknesses
is termed the minimum film thickness and its variation with the
impact velocity has been determined. We find that the interactions
between the free surface and rigid particle can be divided into
three regimes according to the trend of the first film thickness.
The three regimes are viscous regime, inertial regime and jetting
regime. In viscous regime, the first film thickness decreases as the
impact velocity increases. Then it rises slightly in the inertial
regime because the effect of liquid inertia becomes larger as the
impact velocity increases. Finally, the film thickness decreases
again due to Plateau-Rayleigh instability in the jetting regime.
We also find that the minimum film thickness corresponds to an
impact velocity on the demarcation point between the viscous and
inertial regimes. This fact is caused by the balance of viscous
drag, surface deformation and liquid inertia.

Thirdly, we consider the interaction between a rigid particle and a
deformable bubble. Two typical cases are simulated: (1) Collision of
a rigid particle with a gas bubble in water in the absence of
gravity, and (2) Collision of a buoyancy-driven rising bubble with a
falling particle in highly viscous liquids. We also compare our
simulation results with available experimental data. Good agreement
is obtained for the force on the particle and the shape of the
bubble.

Finally, we investigated the collisions of groups of bubbles and
particles in two dimensions. A preliminary example of the oblique
collision between a single particle and a single bubble is conducted
by giving the particle a constant acceleration. Then, to investigate
the possibility of particles attaching to bubbles, the interactions
between a group of 22 particles and rising bubbles are studied. Due
to the fluid motion, the particles involved in central collisions
with bubbles have higher possibilities to attach to the bubble.
Ph. D.
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Hackett, Gregory A. "Interaction of nickel-based SOFC anodes with trace contaminants from coal-derived synthesis gas". Morgantown, W. Va. : [West Virginia University Libraries], 2009. http://hdl.handle.net/10450/10728.

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Thesis (Ph. D.)--West Virginia University, 2009.
Title from document title page. Document formatted into pages; contains xii, 122 p. : ill. (some col.). Includes abstract. Includes bibliographical references (p. 115-122).
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Mohammad, Hasan Abid Urf Turabe Ali. "Ammonia gas adsorption on metal oxide nanoparticles". Thesis, Kansas State University, 2011. http://hdl.handle.net/2097/13094.

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Master of Science
Department of Mechanical and Nuclear Engineering
Steven J. Eckels
NanoActiveTM metal oxide particles have the ability to destructively adsorb organophosphorus compounds and chlorocarbons. These nanomaterials with unique surface morphologies are subjected to separate, low concentrations of gaseous ammonia in air. NanoActiveTM materials based on magnesium oxide have large specific surface areas and defective sites that enhance surface reactivity and consequently improved adsorptivity. In gas contaminant removal by adsorption, presence of vast specific surface area is essential for effective gas-solid interaction to take place. This is also the case in many industrial and chemical applications such as purification of gases, separation and recovery of gases, catalysis etc,. Typically carbonaceous compounds are utilized and engineered in toxic gas control systems. The purpose of this study was to compare NanoActiveTM materials with carbon based compounds in the effectivity of toxic gas adsorption at low concentrations. A test facility was designed to investigate the adsorption properties of novel materials such as adorption capacity and adsorption rate. Adsorption capacity along with adsorption kinetics is a function of properties of the adsorbent and the adsorbate as well as experimental conditions. Nanomaterials were placed on a silica matrix and tested with increasing flow rates. Electrochemical sensing devices were placed at inlet and outlet of the facility to monitor real time continuous concentration profiles. Breakthrough curves were obtained from the packed bed column experiments and saturation limits of adsorbents were measured. Adsorption rates were obtained from the breakthrough curves using modified Wheeler-Jonas equation. The NanoActiveTM materials adsorbed ammonia though to a lesser extent than the Norit® compounds. This study also included measurement of pressure drop in packed beds. This information is useful in estimating energy losses in packed bed reactors. Brauner Emmet Teller tests were carried out for the calculation of surface area, pore volume and pore size of materials. These calculations suggest surface area alone had no notable influence on adsorption capacity and adsorption rates. This lead to the conclusion that adsorption was insignificant cause of absence of functional groups with affinity towards ammonia. In brief, adsorption of ammonia is possible on NanoActiveTM materials. However functional groups such as oxy-flouro compounds should be doped with novel materials to enhance the surface interactions.
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Niaki, Seyed Reza Amini. "Effects of inter particle friction on the meso-scale hydrodynamics of dense gas-solid fluidized flows". Universidade de São Paulo, 2018. http://www.teses.usp.br/teses/disponiveis/18/18147/tde-10122018-165927/.

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Gas-solid fluidized bed reactors are widely applied in chemical and energy industries, and their design and scale-up are virtually empirical, extremely expensive and time consuming. This scenario has motivated the development of alternative theoretical tools, and two-fluid modeling, where gas and particulate are both treated as interpenetrating continuum phases, has appeared as a most promising approach. Owing to the large domains to be resolved in real-scale fluidized bed reactors, only filtered modeling approaches are feasible, and closure models become necessary to recover sub-grid effects that are filtered by the very coarse numerical grids that are imposed owing to computational limitations. Those closure models, which in hydrodynamic formulations account for filtered interphase momentum exchanges and filtered and residual stresses in the phases, can be derived from results of highly resolved simulations (HRS) performed over small size domains under refined numerical grids. One widely practiced approach consists of applying two-fluid modeling under micro-scale defined closures, generally known as microscopic two-fluid modeling. This approach includes microscopic closures for solid phase stresses derived from the kinetic theory of granular flows (KTGF), which accounts for kinetic-collisional effects only, and is adequate to dilute flows. Otherwise, the conventional KTGF does not account for interparticle friction effects, and its application to dense flow conditions is quite questionable. In this work a literature available modified version of KTGF is applied which also accounts for interparticle friction, and highly resolved simulations are performed for dense flow conditions in order to evaluate the effects of friction over relevant filtered parameters (namely effective drag coefficient, filtered and residual stresses). Ranges of domain average solid volume fractions and gas Reynolds numbers are considered (macro-scale conditions) embracing dense gas-solid fluidized flows from suspensions up to pneumatic transport. The MFIX open source code is used in all the simulations, which are performed over 2D periodical domains for a unique monodisperse particulate. The HRS results (i.e. meso-scale flow fields) are filtered over regions compatible with grid sizes in large scale simulations, and the relevant filtered parameters of concern are derived and classified by ranges of other filtered parameters taken as independent variables (filtered solid volume fraction, filtered slip velocity, and filtered kinetic energy of solid velocity fluctuations, which are referred to as markers). Results show that the relevant filtered parameters of concern are well correlated to all of those filtered markers, and also to all of the imposed macro-scale conditions. Otherwise, interparticle friction showed no significant effects over any filtered parameter. It is recognized that this issue clearly requires further investigation notably regarding the suitability of the markers that were assumed for classifying the filtered results. The current work is intended as a contribution for future developments of more accurate closure models for large scale simulations of gas-solid fluidized flows.
Reatores de leito fluidizado de escoamento gás-sólido são largamente utilizados nas indústrias química e de energia, e o seu projeto e escalonamento são virtualmente empíricos, extremamente caros e demorados. Este cenário tem motivado o desenvolvimento de ferramentas teóricas alternativas, e a modelagem de dois fluidos, onde gás e particulado são ambos tratados com fases contínuas interpenetrantes, tem surgido como uma aproximação muito promissora. Devido aos grandes domínios a serem resolvidos em reatores de leito fluidizado de escala real, apenas aproximações de modelagem filtradas são viáveis, e modelos de fechamento tornam-se necessários para recuperar efeitos sub-malha que são filtrados pelas malhas numéricas grosseiras que são impostas devido as limitações computacionais. Estes modelos de fechamento, que em formulações hidrodinâmicas respondem principalmente por trocas de momentum filtradas entre fases e tensões filtradas e residuais nas fases, podem ser obtidos de resultados de simulações altamente resolvidas (SAR) realizadas em domínios de dimensões reduzidas sob malhas numéricas refinadas. Uma aproximação largamente praticada consiste na aplicação de modelagem de dois fluidos sob fechamentos definidos na micro-escala, genericamente conhecida como modelagem microscópica de dois fluidos. Esta aproximação inclui fechamentos microscópicos para tensões da fase sólida obtidos da teoria cinética dos escoamentos granulares (TCEG), que considera apenas efeitos cinéticos-colisionais, e é adequada para escoamentos diluídos. Por outro lado, a TCEG convencional não leva em conta efeitos de fricção interpartículas, e sua aplicação para condições densas de escoamento é bastante questionável. Neste trabalho aplica-se uma versão modificada da TCEG disponível na literatura que também leva em conta fricção interpartículas, e simulações altamente resolvidas são realizadas para condições de escoamentos densos visando avaliar os efeitos da fricção sobre os parâmetros filtrados relevantes (coeficiente de arrasto efetivo, tensões filtradas e residuais). Considera-se faixas de frações volumétricas de sólido e números de Reynolds do gás médios no domínio (condições de macro-escala) abrangendo escoamentos gás-sólido fluidizados densos desde suspensões até transporte pneumático. O código aberto MFIX é utilizado em todas as simulações, que foram executadas sobre domínios periódicos 2D para um único particulado monodisperso. Os resultados das SAR (i.e., campos de escoamento de meso-escala) foram filtrados sobre regiões compatíveis com tamanhos de malha praticados em simulações de grandes escalas, e os parâmetros filtrados relevantes de interesse são calculados e classificados por faixas de outros parâmetros filtrados tomados como variáveis independentes (fração volumétrica de sólido filtrada, velocidade de deslizamento filtrada, e energia cinética das flutuações de velocidade da fase sólida filtrada, que são referidos como marcadores). Os resultados mostram que os parâmetros filtrados relevantes de interesse são bem correlacionados com todos os marcadores, e também com todas as condições de macro-escala impostas. Por outro lado, a fricção interpartículas não mostrou efeitos significativos sobre qualquer parâmetro filtrado. Reconhece-se que este aspecto claramente requer investigações adicionais, notadamente com respeito à adequação dos marcadores que foram considerados para classificação dos resultados filtrados. O trabalho corrente é posto como uma contribuição para o desenvolvimento futuro de modelos de fechamento mais acurados para simulações de grandes escalas de escoamentos gás-sólido fluidizados.
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Lazarevic, David Andrew. "In-situ Removal of Hydrogen Sulphide from Landfill Gas : Arising from the Interaction between Municipal Solid Waste and Sulphide Mine Environments within Bioreactor Conditions". Thesis, KTH, Industriell ekologi, 2007. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-32770.

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This project was compiled in co-operation with the Royal Institute of Technology, Stockholm and Veolia Environmental Services (Australia) at the Woodlawn Bioreactor in NSW, Australia. Hydrogen sulphide is an unwanted component of landfill gas, raising occupational health and safety concerns, whilst leading to acid gas corrosion of power generation equipment and increased emissions of SOx, a primary constituent of acidification. Australian governmental requirements to place a periodic cover over the unused proportion of the tipping surface of landfills and bioreactors create an interesting opportunity for the removal of the hydrogen sulphide component of landfill gas. Using waste materials containing a high concentration of metals as waste cover can enhance the precipitation of sulphur in the form of metal sulphides. The reduction of sulphate via sulphate reducing bacteria is prevalent in sites that have a sizeable inflow of sulphate. The Woodlawn Bioreactor is located in an area where the influence of sulphate has a critical influence of bioreactor performance and production of hydrogen sulphide. Through a series of experimental bioreactors it was established that from the use of metalliferous periodic waste covers, the hydrogen sulphide component of landfill gas was maintained at an extremely low level when compared to the levels of hydrogen sulphide produced in waste under the influence of high sulphate loads with no waste cover.
www.ima.kth.se
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Tóth, Balázs. "Two-phase flow investigation in a cold-gas solid rocket motor model through the study of the slag accumulation process". Doctoral thesis, Universite Libre de Bruxelles, 2008. http://hdl.handle.net/2013/ULB-DIPOT:oai:dipot.ulb.ac.be:2013/210575.

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The present research project is carried out at the von Karman Institute for Fluid Dynamics (Rhode-Saint-Genèse, Belgium) with the financial support of the European Space Agency.

The first stage of spacecrafts (e.g. Ariane 5, Vega, Shuttle) generally consists of large solid propellant rocket motors (SRM), which often consist of segmented structure and incorporate a submerged nozzle. During the combustion, the regression of the solid propellant surrounding the nozzle integration part leads to the formation of a cavity around the nozzle lip. The propellant combustion generates liquefied alumina droplets coming from chemical reaction of the aluminum composing the propellant grain. The alumina droplets being carried away by the hot burnt gases are flowing towards the nozzle. Meanwhile the droplets may interact with the internal flow. As a consequence, some of the droplets are entrapped in the cavity forming an alumina puddle (slag) instead of being exhausted through the throat. This slag reduces the performances.

The aim of the present study is to characterize the slag accumulation process in a simplified model of the MPS P230 motor using primarily optical experimental techniques. Therefore, a 2D-like cold-gas model is designed, which represents the main geometrical features of the real motor (presence of an inhibitor, nozzle and cavity) and allows to approximate non-dimensional parameters of the internal two-phase flow (e.g. Stokes number, volume fraction). The model is attached to a wind-tunnel that provides quasi-axial flow (air) injection. A water spray device in the stagnation chamber realizes the models of the alumina droplets, which are accumulating in the aft-end cavity of the motor.

To be able to carry out experimental investigation, at first the the VKI Level Detection and Recording(LeDaR) and Particle Image Velocimetry (PIV) measurement techniques had to be adapted to the two-phase flow condition of the facility.

A parametric liquid accumulation assessment is performed experimentally using the LeDaR technique to identify the influence of various parameters on the liquid deposition rate. The obstacle tip to nozzle tip distance (OT2NT) is identified to be the most relevant, which indicates how much a droplet passing just at the inhibitor tip should deviate transversally to leave through the nozzle and not to be entrapped in the cavity.

As LeDaR gives no indication of the driving mechanisms, the flow field is analysed experimentally, which is supported by numerical simulations to understand the main driving forces of the accumulation process. A single-phase PIV measurement campaign provides detailed information about the statistical and instantaneous flow structures. The flow quantities are successfully compared to an equivalent 3D unsteady LES numerical model.

Two-phase flow CFD simulations suggest the importance of the droplet diameter on the accumulation rate. This observation is confirmed by two-phase flow PIV experiments as well. Accordingly, the droplet entrapment process is described by two mechanisms. The smaller droplets (representing a short characteristic time) appear to follow closely the air-phase. Thus, they may mix with the air-phase of the recirculation region downstream the inhibitor and can be carried into the cavity. On the other hand, the large droplets (representing a long characteristic time) are not able to follow the air-phase motion. Consequently, a large mean velocity difference is found between the droplets and the air-phase using the two-phase flow measurement data. Therefore, due to the inertia of the large droplets, they may fall into the cavity in function of the OT2NT and their velocity vector at the level of the inhibitor tip.

Finally, a third mechanism, dripping is identified as a contributor to the accumulation process. In the current quasi axial 2D-like set-up large drops are dripping from the inhibitor. In this configuration they are the main source of the accumulation process. Therefore, additional numerical simulations are performed to estimate the importance of dripping in more realistic configurations. The preliminary results suggest that dripping is not the main mechanism in the real slag accumulation process. However, it may still lead to a considerable contribution to the final amount of slag.


Doctorat en Sciences de l'ingénieur
info:eu-repo/semantics/nonPublished

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Książki na temat "Gas solid interaction"

1

Hedahl, Marc O. Comparisons of the Maxwell and CLL gas/surface interaction models using DSMC. Hampton, Va: National Aeronautics and Space Administration, Langley Research Center, 1995.

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G, Wilmoth Richard, i Langley Research Center, red. Comparisons of the Maxwell and CLL gas/surface interaction models using DSMC. Hampton, Va: National Aeronautics and Space Administration, Langley Research Center, 1995.

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J, Singh D., Old Dominion University. Dept. of Mechanical Engineering and Mechanics. i Langley Research Center, red. Interaction of transient radiation in nongray gaseous systems: Progress report for the period ending December 31, 1986 (a supplementary report). Norfolk, Va: Dept. of Mechanical Engineering and Mechanics, College of Engineering & Technology, Old Dominion University, 1987.

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Billing, Gert D. Dynamics of molecule surface interactions. New York: Wiley, 2000.

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NATO Advanced Study Institute on the Physics of the Two-Dimensional Electron Gas (1986 Oostduinkerke, Belgium). The physics of the two-dimensional electron gas. New York: Plenum Press, 1987.

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A, Hoffbauer Mark, i Lyndon B. Johnson Space Center., red. Measurement of momentum transfer coefficients for H₂, N₂, CO, and CO₂ incident upon spacecraft surfaces. Houston, Tex: National Aeronautics and Space Administration, Lyndon B. Johnson Space Center, 1997.

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Mahmoud, Mohamed, i Ibnelwaleed A. Hussein. Fluid-Solid Interactions in Upstream Oil and Gas Applications. Elsevier, 2023.

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Mahmoud, Mohamed, i Ibnelwaleed A. Hussein. Fluid-Solid Interactions in Upstream Oil and Gas Applications. Elsevier, 2023.

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Physical interactions and energy exchange at the gas-solid interface. London: Faraday Division, Royal Society of Chemistry, 1985.

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Devreese, J. T., i F. M. Peeters. The Physics of the Two-Dimensional Electron Gas: Proceedings of a Nato Advanced Study Institute on the Physics of the Two-Dimensional Electron Gas, H (Nato a S I Series Series B, Physics). Springer, 1987.

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Części książek na temat "Gas solid interaction"

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Kreuzer, Hans Jürgen, i Zbigniew Wojciech Gortel. "Gas-Solid Interaction". W Physisorption Kinetics, 23–88. Berlin, Heidelberg: Springer Berlin Heidelberg, 1986. http://dx.doi.org/10.1007/978-3-642-82695-5_2.

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Grimley, T. B. "Gas-Surface Interactions". W Interaction of Atoms and Molecules with Solid Surfaces, 25–52. Boston, MA: Springer US, 1990. http://dx.doi.org/10.1007/978-1-4684-8777-0_2.

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Anděra, L., i E. Smolková-Keulemansová. "The Effect of Water Vapour on the Cyclodextrin-Solute Interaction in Gas-Solid Chromatography". W Inclusion Phenomena in Inorganic, Organic, and Organometallic Hosts, 289–97. Dordrecht: Springer Netherlands, 1987. http://dx.doi.org/10.1007/978-94-009-3987-5_51.

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Bourloutski, E., i M. Sommerfeld. "Euler/Lagrange Calculations of Gas-Liquid-Solid-Flows in Bubble Columns with Phase Interaction". W Bubbly Flows, 243–59. Berlin, Heidelberg: Springer Berlin Heidelberg, 2004. http://dx.doi.org/10.1007/978-3-642-18540-3_19.

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Brewster, M. Q. "High-Temperature Solids-Gas Interactions". W Direct-Contact Heat Transfer, 167–95. Berlin, Heidelberg: Springer Berlin Heidelberg, 1988. http://dx.doi.org/10.1007/978-3-662-30182-1_9.

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Farıas, Daniel, i Rodolfo Miranda. "Thermal Energy Atomic and Molecular Beam Diffraction from Solid Surfaces". W Dynamics of Gas-Surface Interactions, 51–73. Berlin, Heidelberg: Springer Berlin Heidelberg, 2013. http://dx.doi.org/10.1007/978-3-642-32955-5_3.

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Grabke, H. J. "Solid-Gas and Solid-Solid Interactions of Ceramic Oxides at High Temperatures". W Surfaces and Interfaces of Ceramic Materials, 599–624. Dordrecht: Springer Netherlands, 1989. http://dx.doi.org/10.1007/978-94-009-1035-5_38.

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Shalabiea, Osama M., Eric Herbst i Paola Caselli. "Modified Models of Gas/Grain Interactions". W Formation and Evolution of Solids in Space, 123–30. Dordrecht: Springer Netherlands, 1999. http://dx.doi.org/10.1007/978-94-011-4806-1_7.

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Sólyom, Jenő. "Excitations in the Interacting Electron Gas". W Fundamentals of the Physics of Solids, 175–209. Berlin, Heidelberg: Springer Berlin Heidelberg, 2010. http://dx.doi.org/10.1007/978-3-642-04518-9_4.

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Dmitriev, A. N., D. Z. Kudinov i L. I. Leontiev. "Metal Oxides Interaction with Reducing Gas in Bubble Ore Melt". W Diffusion in Solids and Liquids III, 176–80. Stafa: Trans Tech Publications Ltd., 2008. http://dx.doi.org/10.4028/3-908451-51-5.176.

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Streszczenia konferencji na temat "Gas solid interaction"

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Peratta, A. "Numerical modelling of gas-solid interface for homogeneous propellant combustion". W FLUID STRUCTURE INTERACTION/MOVING BOUNDARIES 2007. Southampton, UK: WIT Press, 2007. http://dx.doi.org/10.2495/fsi070271.

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Timokhin, Maksim, Henning Struchtrup, Alexey Kokhanchik i Yevgeniy Bondar. "R13 moment equations applied to supersonic flow with solid wall interaction". W 31ST INTERNATIONAL SYMPOSIUM ON RAREFIED GAS DYNAMICS: RGD31. AIP Publishing, 2019. http://dx.doi.org/10.1063/1.5119614.

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Nassir, Mohammad, Antonin Settari i Richard G. Wan. "Modeling Shear Dominated Hydraulic Fracturing as a coupled fluid-solid interaction". W International Oil and Gas Conference and Exhibition in China. Society of Petroleum Engineers, 2010. http://dx.doi.org/10.2118/131736-ms.

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Zhang, Xinyu, i Goodarz Ahmadi. "Roles of Neutrally Buoyant Particles in Gas-Liquid-Solid Flows". W ASME 2012 Fluids Engineering Division Summer Meeting collocated with the ASME 2012 Heat Transfer Summer Conference and the ASME 2012 10th International Conference on Nanochannels, Microchannels, and Minichannels. American Society of Mechanical Engineers, 2012. http://dx.doi.org/10.1115/fedsm2012-72038.

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A CFD study is carried out to investigate the roles of neutrally buoyant particles in gas-liquid-solid flows in bubble columns. An Eulerian-Lagrangian model is used and the liquid flow is modeled using a volume-averaged system of governing equations, while motions of bubbles and particles are evaluated using Lagrangian trajectory analysis. Bubbles are assumed to remain spherical. Bubble-liquid interaction and particle-liquid interaction are included in the study. The drag, lift, buoyancy, and virtual mass forces are included in the discrete phase equations. Particle-particle interactions and bubble-bubble interactions are accounted for by a hard sphere model. The bubble coalescence is also included in the analysis. Neutrally buoyant particles are used in the study. The predicted results were compared with the experimental data in a previous work, and good agreement was obtained. The transient flow characteristics of a gas-liquid-solid three-phase flow and a gas-liquid two-phase flow are studied and the roles of neutrally buoyant particles are discussed. The simulations show that the transient characteristics of the flows in a bubble column are dominated by time-dependent vortices. The presence of particles can affect the characteristics of the flows and flows with particles evolve faster.
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GALDIKAS, Algirdas, Audruzis MIRONAS, Daiva SENULIENE i Arunas SETKUS. "Gas-Surface Interaction Influence on Electrical Properties of New Gas Sensitive Metal Oxide-Metal Sandwich Structure". W 1995 International Conference on Solid State Devices and Materials. The Japan Society of Applied Physics, 1995. http://dx.doi.org/10.7567/ssdm.1995.pc-7-2.

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Mödi, A., F. Budde, T. Gritsch, T. J. Chuang i G. Ertl. "Laser probing of gas-surface interaction dynamics". W Microphysics of Surfaces, Beams, and Adsorbates. Washington, D.C.: Optica Publishing Group, 1987. http://dx.doi.org/10.1364/msba.1987.wa1.

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Collision of a molecule with a solid surface leads to energy redistribution within its translational as well as internal degrees of freedom. The populations of the various quantum states of the latter may be probed by laser induced fluorescence (LIF) or by multiphoton ionisation (MPI). Combination of these techniques with time-of-flight (TOF) measurements in a molecular beam apparatus allows, in addition, determination of state-selected translational energy distributions.
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Iwata, Ryuichi, Takeo Kajishima i Shintaro Takeuchi. "Interaction Between Multiple Solid Objects and Bubbles". W ASME 2010 International Mechanical Engineering Congress and Exposition. ASMEDC, 2010. http://dx.doi.org/10.1115/imece2010-40180.

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In the present study, bubble-particle interactions in suspensions are investigated by a coupled immersed-boundary and volume-of-fluid method (IB-VOF method), which is proposed by the present authors. The validity of the numerical method is examined through simulations of a rising bubble in a liquid and a falling particle in a liquid. Dilute particle-laden flows and a gas-liquid-solid flow involving solid particles and bubbles of comparable sizes to one another (Db/Dp = 1) are simulated. Drag coefficients of particles in particle-laden flows are estimated and flow fields involving multiple particles and a bubble are demonstrated.
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Sedrez, Thiana A., i Siamack A. Shirazi. "The Effect of Phase Interaction Forces and Particle Rotation on Solid Particle Erosion in Liquid-Solid and Liquid-Gas-Solid Flows". W ASME 2022 Fluids Engineering Division Summer Meeting. American Society of Mechanical Engineers, 2022. http://dx.doi.org/10.1115/fedsm2022-86755.

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Abstract Forces acting on both gas and particle phases and the interaction between them and the liquid phase in liquid-gas-solid flow are examined via Computational Fluid Dynamics (CFD) and the results are compared with experimental data. A simplified methodology to simulate multiphase flow is proposed using the Eulerian-Eulerian-Lagrangian approach. The proposed modeling approach for the liquid-gas interaction forces and particle rotation is compared with experimental erosion data for two elbows in series. For the experiments, a 50.8 mm inner diameter pipe vertical facility with water, air, and sand particles is used to collect wall thickness loss data in two elbows in series: one elbow vertical to horizontal and another horizontal to vertical downward. The particle rotation forces in these highly rotational flows with liquid-solid flows are considered in this investigation. In addition, interphase forces between liquid and gas for dispersed-bubble flow, such as drag, surface tension, turbulent dispersion, turbulence interaction, virtual mass, and wall lubrication, were investigated. Lastly, the simulated effect of the forces on fluid velocity, particle velocity, and erosion rates are presented and discussed. The results show that rotation of particles and Magnus lift force do not significantly impact particle trajectory for liquid-solid flows. However, the Magnus lift force exerts an increase in erosion in both elbows. Overall, for liquid-gas-solid flow, interphase forces separately do not significantly impact erosion (presenting on average 24% higher erosion than experimental data). The greater change is observed when drag, virtual mass, wall lubrication, and surface tension are applied together, increasing erosion considerably (83% higher than experimental data).
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Timokhin, M. Yu, I. E. Ivanov i I. A. Kryukov. "2D numerical simulation of gas flow interaction with a solid wall by regularized Grad's set of equations". W 28TH INTERNATIONAL SYMPOSIUM ON RAREFIED GAS DYNAMICS 2012. AIP, 2012. http://dx.doi.org/10.1063/1.4769630.

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Jain, Kunal, i J. J. McCarthy. "Discrete Characterization of Cohesion in Gas-Solid Flows". W ASME 2002 International Mechanical Engineering Congress and Exposition. ASMEDC, 2002. http://dx.doi.org/10.1115/imece2002-32491.

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Cohesive forces between grains can arise from a variety of sources – such as liquid bridge (capillary) forces, van der Waals forces, or electrostatic forces – and may play a significant role in the processing of fine and/or moist powders. While recent advances have been made in our understanding of liquid-induced cohesion at the macroscopic level, in general, it is still not possible to directly connect this macroscopic understanding of cohesion with a microscopic picture of the particle properties and interaction forces. In fact, conventional theories make no attempt to distinguish between these modes of cohesion, despite clear qualitative differences (lubrication forces in wet systems or electrostatic repulsion are two good examples). In this work, we discuss several discrete characterization tools for wet (cohesive) granular material with simple, physically relevant interpretations. We examine the utility of these tools, both computationally and experimentally, by exploring a range of cohesive strengths (from cohesionless to cohesive) in several prototypical applications of solid and gas-solid flows.
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Raporty organizacyjne na temat "Gas solid interaction"

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Celik, I., i G. Q. Zhang. Engineering models for the gas-solid motion and interaction in the return loop of circulating fluidized beds. Topical report, January 1992--June 1992. Office of Scientific and Technical Information (OSTI), sierpień 1992. http://dx.doi.org/10.2172/10184725.

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Vera, Jose, i Ken Evans. PR186-203600-Z01 Impact of Drag Reducing Agents on Corrosion Management. Chantilly, Virginia: Pipeline Research Council International, Inc. (PRCI), październik 2021. http://dx.doi.org/10.55274/r0012177.

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The purpose of this research was to understand the potential impact of drag reducing agents (DRA) on internal corrosion of liquid hydrocarbon pipelines. The first task of this project included a comprehensive review of literature and knowledge, both in public domain and from industry experience, on the effect of DRA on water and solid transport in liquid hydrocarbons, and possible interactions with other performance chemicals typically used in the oil and gas industry. This was the basis for defining the final bench test methodology and test matrix to be performed in the second task. A novel bench-top apparatus was designed based on a vertical Couette cell approach, and a test methodology was successfully implemented to evaluate the potential effect(s) of DRA on water accumulation and localized corrosion at the oil/water interface. A test matrix was conducted with two DRAs (a water based and an oil based) and two corrosion inhibitors (a water soluble and an oil soluble) at a given test condition (3.5% NaCl saturated with 97%CO2/3%O2, pH ~6 at 80 oF). There is a related webinar.
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Avnimelech, Yoram, Richard C. Stehouwer i Jon Chorover. Use of Composted Waste Materials for Enhanced Ca Migration and Exchange in Sodic Soils and Acidic Minespoils. United States Department of Agriculture, czerwiec 2001. http://dx.doi.org/10.32747/2001.7575291.bard.

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Restoration of degraded lands and the development of beneficial uses for waste products are important challenges facing our society. In addition there is a need to find useful and environmentally friendly applications for the organic fractions of municipal and other solid waste. Recent studies have shown that composted wastes combined with gypsum or gypsum-containing flue gas desulfurization by-products enhance restoration of sodic soils and acidic minespoils. The mechanism by which this synergistic effect occurs in systems at opposite pH extremes appears to involve enhanced Ca migration and exchange. Our original research objectives were to (1) identify and quantify the active compost components involved in Ca transport, (2) determine the relative affinity of the compost components for Ca and competing metals in the two soil/spoil systems, (3) determine the efficacy of the compost components in Ca transport to subjacent soil and subsequent exchange with native soil cations, and (4) assess the impacts of compost enhanced Ca transport on soil properties and plant growth. Acidic mine spoils: During the course of the project the focus for objective (1) and (2) shifted more towards developing and evaluating methods to appropriately quantify Ca2+ and Al3+ binding to compost derived dissolved organic matter (DOM). It could be shown that calcium complexation by sewage sludge compost derived DOM did not significantly change during the composting process. A method for studying Al3+ binding to DOM was successfully developed and should allow future insight into DOM-Al3+ interactions in general. Laboratory column experiments as well as greenhouse experiments showed that in very acidic mine spoil material mineral dissolution controls solution Al3+ concentration as opposed to exchange with Ca2+. Therefore compost appeared to have no effect on Al3+ and Ca2+ mobility and did not affect subsoil acidity. Sodic alkaline soils: Batch experiments with Na+ saturated cation exchange resins as a model for sodic soils showed that compost home cations exchanged readily with Na+. Unlike filtered compost extracts, unfiltered compost suspensions also significantly increased Ca2+ release from CaCO3. Soil lysimeter experiments demonstrated a clear impact of compost on structural improvement in sodic alkaline soils. Young compost had faster, clearer and longer lasting effects on soil physical and chemical properties than mature compost. Even after 2 growing seasons differences could still be observed. Compost increased Ca2+ concentration in soil solution and solubility of pedogenic CaCO3 that is highly insoluble under alkaline conditions. The solubilized Ca2+ efficiently exchanged Na+ in the compost treated soils and thus greatly improved the soil structure.
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