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Dybek, Aneta. "Production and Characterisation of Fullerenes, Fullerene Derivatives and Fullerene-Based Electronic Devices". Thesis, Queen Mary, University of London, 2008. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.522327.
Pełny tekst źródłaRathna, A. "Theoretical Studies Of Fullerenes And Fullerene Derivatives". Thesis, Indian Institute of Science, 1994. https://etd.iisc.ac.in/handle/2005/111.
Pełny tekst źródłaRathna, A. "Theoretical Studies Of Fullerenes And Fullerene Derivatives". Thesis, Indian Institute of Science, 1994. http://hdl.handle.net/2005/111.
Pełny tekst źródłaWessendorf, Florian. "Supramolecular fullerene-porphyrin architectures = Supramolekulare Fulleren-Porphyrin-Architekturen". kostenfrei, 2010. http://d-nb.info/1000613593/34.
Pełny tekst źródłaMo^n, Dyfrig. "Fullerene crystallisation in Fullerene/Polymer bilayers". Thesis, Swansea University, 2014. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.678620.
Pełny tekst źródłaPeel, Jason Alexander. "The synthesis and characterisation of some new organometallic derivatives of [60]fullerene". Thesis, University of Reading, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.389639.
Pełny tekst źródłaRahmer, Jürgen. "Electronic spin states in fullerides and endohedral fullerenes". [S.l. : s.n.], 2003. http://www.bsz-bw.de/cgi-bin/xvms.cgi?SWB10934928.
Pełny tekst źródłaSamoylova, Nataliya. "Cluster-based redox activity in Endohedral Metallofullerenes:". Doctoral thesis, Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2017. http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-230132.
Pełny tekst źródłaDuggan, Andrew Charles. "Fullerene intercalation chemistry". Thesis, University of Oxford, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.298749.
Pełny tekst źródłaHenry, Paul Francis. "Fullerene intercalation chemistry". Thesis, University of Oxford, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.363757.
Pełny tekst źródłaKurz, Arnd. "Protein-fullerene complexes". Thesis, University of Oxford, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.299798.
Pełny tekst źródłaWood, Robert A. "C₆₀ fullerene polymers". Thesis, University of Warwick, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.397268.
Pełny tekst źródłaTerrones-Maldonado, Mauricio. "Production and characterisation of novel fullerene-related materials : nanotubes, nanofibres and giant fullerenes". Thesis, University of Sussex, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.361404.
Pełny tekst źródłaMancel, Dorothée. "Complexes of [60]fullerene". Thesis, University of Nottingham, 2011. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.546290.
Pełny tekst źródłaO'Donovan, Bryan Finbarr. "Organofunctional [60]fullerene chemistry". Thesis, University of Sussex, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.297559.
Pełny tekst źródłaRamanitra, Hasina Harimino. "Incorporation du fullerène dans des polymères pour applications dans le photovoltaïque". Thesis, Pau, 2015. http://www.theses.fr/2015PAUU3048/document.
Pełny tekst źródłaPhotovoltaic technology (PV) makes it possible to directly convert sunlight into electricity and it is seen as a very promising solution to the current energy crisis. Although the PV market is dominated by inorganic-based devices, those systems present high production costs and deployment issues that limit their application. Polymer-based organic solar cells (OPVs) are promising sources of renewable energy due to their facile, low cost production, and formable nature. Due to its electronic properties and high electron mobility, small molecule fullerene (C60 ) derivatives are widely used in large scale OPVs. However the morphological properties of C60 derivatives decrease device stability as C60 easily undergoes self-aggregation during OPV use. The processibility of C60 can be improved by incorporating it into a polymer. These systems are already described in literature but have in general a multistage synthesis that could affect the electronic properties of C60 as well as give insoluble products due to reticulative reactions. The objective of the work here presented was to prepare innovative polymers based on C60 for photovoltaic and electronic devices using reliable, well-known C60 chemistry. At the University of Pau (EPCP Lab), after the syntheses of small molecules to be used as co-monomers, two synthetic routes were used in order to obtain main- chain oligo- and polyfullerenes. The first route is based on the atom transfer radical addition polymerization (ATRAP), which has already been used for the preparation of main-chain polyfullerenes. With this method, soluble compounds with various molecular weights were prepared. The second route was discovered in this work and exploits a well-known fullerene chemistry to prepare soluble polyfullerenes with reasonably high molecular weights. Preliminary studies to understand the effect of the reaction parameters (reagents, reagents concentration, temperature, time and solvent) and the kinetics of the polymerisation were performed. Material characterisations were carried out via GPC chromatography, NMR spectroscopy, and UV-visible and IR spectroscopies. Thermal analyses (TGA and DSC) were also run to complete the characterisations. Both C60 and its derivative, [6,6]-phenyl-C61-butyric acid methyl ester (PCBM), have been exploited as monomers in the reactions. A nine-month (cotutelle) stay at Tübingen University, Germany, permitted a study of the synthesized materials by means of XPS and UPS spectroscopies. The aim of these studies was to obtain a better understanding of the energy levels pictures of the oligo- and polyfullerenes. Thin films of the compounds were deposited on different substrates via solution processes (doctor blade or spin coating) to obtain ex-situ samples for characterisation. Samples of polyfullerene-containing active layers were prepared during a short stay (1 week) at BELECTRIC OPV GmbH, Nuremberg (Germany), and analysed by optical microscopy and AFM microscopy during thermal-degradation studies at Tübingen University. These studies were completed thanks to collaborations with researchers at BELECTRIC OPV GmbH, who have incorporated the compounds into devices and performed complementary and comparable experiments. As general trends, the compounds are found to improve the stability of the devices upon thermal stresses
Wang, Yonggang. "Transport and retention of fullerene-based nanoparticles in water-saturated porous media". Diss., Atlanta, Ga. : Georgia Institute of Technology, 2009. http://hdl.handle.net/1853/29782.
Pełny tekst źródłaCommittee Chair: Pennell, Kurt; Committee Member: Hughes, Joseph; Committee Member: Kim, Jaehong; Committee Member: Snyder, Robert; Committee Member: Yiacoumi, Sotira. Part of the SMARTech Electronic Thesis and Dissertation Collection.
Morinaka, Yuta. "Studies on Properties of Endohedral Fullerenes and Development of Fullerene Derivatives for Organic Photovoltaic Devices". 京都大学 (Kyoto University), 2013. http://hdl.handle.net/2433/174889.
Pełny tekst źródłaYang, Yi-Fan [Verfasser], i Lorenz S. [Akademischer Betreuer] Cederbaum. "Electronic States of Fullerene Anions and Endohedral Fullerenes / Yi-Fan Yang ; Betreuer: Lorenz S. Cederbaum". Heidelberg : Universitätsbibliothek Heidelberg, 2020. http://d-nb.info/1212935608/34.
Pełny tekst źródłaGevorgyan, Suren. "Growth of fullerene (C70) thin films and photovoltaic characterization of fullerene-based solar cells /". [Sede Boker] : Ben-Gurion University of the Negev, 2006. http://aranne5.lib.ad.bgu.ac.il/others/GevorgyanSuren.pdf.
Pełny tekst źródłaScarel, Francesco [Verfasser], i Bernhard [Akademischer Betreuer] Breit. "Fullerene-stoppered rotaxane: a multifunctional supramolecular material = Fullerene Topfen Rotaxan: ein supramolekulares Multifunktions-Material". Freiburg : Universität, 2014. http://d-nb.info/1115813579/34.
Pełny tekst źródłaLuzan, S. M., Y. O. Tsybin i A. V. Talzyin. "In situ monitoring of C60 hydrogenation". Thesis, Sumy State University, 2011. http://essuir.sumdu.edu.ua/handle/123456789/20618.
Pełny tekst źródłaDavis, Jason John. "Fullerene biochemistry and surface investigations". Thesis, University of Oxford, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.244592.
Pełny tekst źródłaShi, Wenda. "Fullerene isomers for organic photovoltaics". Thesis, Queen Mary, University of London, 2017. http://qmro.qmul.ac.uk/xmlui/handle/123456789/25945.
Pełny tekst źródłaToth, Kalman. "(Endo)fullerene functionalization : from material science to biomedical applications". Thesis, Strasbourg, 2012. http://www.theses.fr/2012STRAE021/document.
Pełny tekst źródłaWe have synthesized different π-conjugated system-fullerene dyads for photovoltaic applications, where the donor units were either oligophenylenevinylene (OPV) or oligophenyleneethynylene (OPE) derivatives and for the acceptor, C60 or Y3N@C80 was used. There was an additional requirement for our materials: liquid crystallinity. All the donor units contained a mesogenic promoter in order to induce mesomorphism in the D-A dyad and to control the morphology of the prepared film through supramolecular organization. Apart from that, we investigated the effect of the chemical nature of the donor moiety (ie. lyophilic or amphiphilic), the oligomeric length and multiaddition on the photophysical properties and on the self-assembly. We have synthesized an OPE-Y3N@C80 dyad which is the first trimetallic nitride template endohedral metallofullerene derivative with mesomorphic and photoactive properties
Keykhosravi, Sanaz. "[60]Fullerène et dérivés : critères de pureté et impact fonctionnel in vivo sur les mitochondries, in vitro et ex vivo sur les cellules de l’allergie". Thesis, Université Paris-Saclay (ComUE), 2019. http://www.theses.fr/2019SACLS047/document.
Pełny tekst źródłaIn 1985 Kroto discovered the third allotrope of carbon, fullerene, spherical molecule consists of 60 carbons with 1 nm in diameter with a specific physico-chemical characteristic. The chemical reactivity of C₆₀ is governed by addition reactions and its high affinity for scavenging free radicals thanks to its 30 double bonds. This property has been widely explored in the field of oxidative stress, in vitro and in vivo, where redox balance is involved, as physio-pathological situations involving inflammation and cellular degeneration. In particular, treatment with C₆₀ solubilized in olive oil extended life span in a rat experimental model. The product, marketed worldwide, has not yet been clinically tested. On the other hand, some preparations may contain impurities. It is therefore important to establish criteria for the purity and integrity of C₆₀ preparations. This thesis work consists of two parts. In the first physico-chemical part, a criterion of C₆₀ purity was established for evaluating the purity of several commercial preparations of C₆₀ with different origins using the following techniques: scanning electron microscopy, X-ray diffraction, Differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), liquid chromatography and gas chromatography coupled to mass spectrometry (GC-MS), as well as ultraviolet-visible and Fourier transform infrared (FTIR) spectroscopy. The results show that FTIR is the easiest way to control the quality of C₆₀ and GC-MS is necessary for identifying volatile impurities, while HPLC remains essential for detecting other fullerenes and C₆₀ derivatives. The second part of the thesis deals with functional aspect of fullerenes and for this purpose we used the pure preparation of C₆₀ evaluated according to the previously defined criteria. In a first chapter, to precise the sub-cellular compartment targeted, the C₆₀ dissolved in olive oil were in vivo injected in mice. After administration, C₆₀ molecules were visualized in the liver and in the spleen, inside the cells and sometimes in mitochondria and endoplasmic reticulum. The targeting of [60]fullerene to the mitochondria was confirmed by a specific modification of the activities of mitochondrial enzymes (malate dehydrogenase and complex I of respiratory chain). In a second chapter we studied the effect of fullerenes on cells involved in an immune dysregulation where inflammation plays a role: allergy. The cellular mechanism at the basis of allergic symptoms is the release in circulation and tissues of mediators of inflammation and immune response from IgE-dependent activation of basophiles and mast cells. The regulatory effects of [60]fullerene and 4 hydrosoluble derivatives, fullerol, β-cyclodextrin [60]fullerene, dendro [60]fullerene and [60]fullerene serinol-malonate, were tested. In vitro experiments showed an absence of toxicity at nanomolar concentrations and inhibitory abilities on the IgE-dependent and -independent activation of the rat mast cell line (RBL). In a cellular activation test monitoring the expression of the degranulation and activation markers CD63 and CD203c on basophiles, by flow cytometry, we show that the various fullerenes are able also to inhibit the ex vivo activation of basophiles from peanut allergic patients in a natural physiological environment: in whole blood. Inhibition rates depend on patients and derivatives with a maximum inhibition observed at 35% in presence of [60]fullerene serinol-malonate. These inhibitions were reproduced on purified human basophiles by studying further activation markers CD107a and CD69. Working perspectives will be on the specificity and the mechanisms of inhibition by studying intracellularly calcium influx or the expression of fusion proteins and transcription factors
Brumm, Holger. "Synthese, Kristallstruktur und Bindungseigenschaften von Fulleriden und Fullerensolvaten". [S.l. : s.n.], 2002. http://www.bsz-bw.de/cgi-bin/xvms.cgi?SWB10447206.
Pełny tekst źródłaGritsina, V. O., Наталія Ігорівна Муліна, Наталия Игоревна Мулина i Nataliia Ihorivna Mulina. "Fullerenes". Thesis, Сумський державний університет, 2013. http://essuir.sumdu.edu.ua/handle/123456789/31130.
Pełny tekst źródłaGödde, Burkart. "Synthese und Spektroskopie angereicherter stickstoffendohedraler Fullerene". [S.l.] : [s.n.], 2001. http://elib.tu-darmstadt.de/diss/000170/bgoedde.pdf.
Pełny tekst źródłaKravec, Nela S. "Herstellung und Charakterisierung endohedraler Li-Fullerene". [S.l. : s.n.], 1998. http://www.diss.fu-berlin.de/1998/21/index.html.
Pełny tekst źródłaShopova, Denitsa. "Crystal chemistry of fullerene co-crystals". [S.l. : s.n.], 2005. http://www.bsz-bw.de/cgi-bin/xvms.cgi?SWB12103660.
Pełny tekst źródłaAstefanei, Alina. "Analysis and characterisation of fullerene nanoparticles". Doctoral thesis, Universitat de Barcelona, 2015. http://hdl.handle.net/10803/346062.
Pełny tekst źródłaLos fulerenos son cada vez más utilizados en medicina (administración de fármacos), en procesos ambientales (remediación) y en la industria (células solares) debido a sus propiedades estructurales y electrónicas únicas. En este contexto, es importante aumentar el conocimiento actual con respecto a las características, el comportamiento, el destino y la toxicidad de los fulerenos, una nueva clase de contaminantes emergentes orgánicos. Por lo tanto, es cada vez es más importante ser capaz de caracterizar y cuantificar las nanopartículas de fulerenos en una amplia gama de tipos de matriz y para este fin, se necesita el desarrollo de métodos analíticos para su análisis cuantitativo y cualitativo. Además de la determinación de las concentraciones de fulerenos en matrices complejas, se requiere su caracterización en términos de grado de agregación, distribución del tamaño y morfología de la superficie en soluciones acuosas de diferentes características (fuerza iónica y pH) con el fin de proporcionar herramientas para establecer su riesgo. En esta tesis se han establecido metodologías para el análisis de ocho fulerenos en muestras ambientales (agua y sedimentos) por cromatografía líquida acoplada a espectrometría de masas y se ha detectado por la primera vez la presencia de tres derivados de fulerenos. Además, se ha desarollado metodología para el análisis de fulerenos hidrofobicos y solubles en agua mediante la electroforesis capilar en medio no-acuoso (NACE) y la cromatografía capilar electrocinética micelar (MECC) y los metodos se han aplicado para la determinación de C60 en productos cosmeticos. Por último, se ha estudiado el comportamiento de agregación de los fulerenos en soluciones acuosas de diferentes características (pHs, fuerzas iónicas) mediante diferentes técnicas (electroforesis capilar (CE), asymetrical flow-field flow fractionation (AF4), microscopia electrónica de transmisión (TEM)). En este contexto se han determinado los tamaños de los agregados formados en las condiciones evaluadas, y la morfología de las partículas.
Zhang, Jinying. "Fullerene Compounds for Quantum Computing Architectures". Thesis, University of Oxford, 2007. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.531661.
Pełny tekst źródłaMoujaes, Elie A. "Intermolecular vibronic interactions in fullerene anions". Thesis, University of Nottingham, 2007. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.438359.
Pełny tekst źródłaDiery, Wajood A. "Jahn-Teller effects in fullerene molecules". Thesis, University of Nottingham, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.422747.
Pełny tekst źródłaCotier, Bradley Neville. "Fullerene nanostructures, monolayers and thin films". Thesis, University of Nottingham, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.342471.
Pełny tekst źródłaArce, GarciÌa Isabel. "Mechanical properties of fullerene-like CN_x". Thesis, University of Newcastle Upon Tyne, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.421175.
Pełny tekst źródłaFleischer, Siegfried B. "Ultrafast dynamics of Fullerene thin films". Thesis, Massachusetts Institute of Technology, 1997. http://hdl.handle.net/1721.1/10750.
Pełny tekst źródłaIncludes bibliographical references (p. 134-143).
by Siegfried B. Fleischer.
Ph.D.
Deb, Nabankur. "Morphological studies in polymer-fullerene blends". Diss., Georgia Institute of Technology, 2015. http://hdl.handle.net/1853/54381.
Pełny tekst źródłaPopov, M. Yu, A. P. Volkov, S. G. Buga, V. S. Bormashov, K. V. Kondrashov, R. L. Lomakin, N. V. Lyparev, V. V. Medvedev, S. A. Tarelkin i S. A. Perfilov. "Nanostructured metal-fullerene field emission cathode". Thesis, Sumy State University, 2011. http://essuir.sumdu.edu.ua/handle/123456789/20585.
Pełny tekst źródłaLi, Tinghui. "Fullerene Based Nanomaterials for Biomedical Applications". Diss., Virginia Tech, 2018. http://hdl.handle.net/10919/91439.
Pełny tekst źródłaPHD
Reich, Andreas. "Synthese und Strukturaufklärung neuer endohedraler Fullerene". [S.l. : s.n.], 2003. http://www.bsz-bw.de/cgi-bin/xvms.cgi?SWB11051835.
Pełny tekst źródłaDeutsch, Denny. "Nanostrukturierte Fullerenschichten für organische Bauelemente /". Berlin : Mbv, 2008. http://d-nb.info/990627632/04.
Pełny tekst źródłaWaiblinger, Markus. "Untersuchungen der endohedralen Fullerene mit eingeschlossenen Stickstoff- und Phosphor-Atomen". [S.l. : s.n.], 2001. http://deposit.ddb.de/cgi-bin/dokserv?idn=961229772.
Pełny tekst źródłaLandenberger, Peter. "Polyfunktionalisierte und hoch ungesättigte Dodecahedrane - das C20-Fulleren". [S.l. : s.n.], 2001. http://deposit.ddb.de/cgi-bin/dokserv?idn=961761911.
Pełny tekst źródłaMeyer, Carola. "Endohedral fullerenes for quantum computing". [S.l. : s.n.], 2003. http://www.diss.fu-berlin.de/2003/296/index.html.
Pełny tekst źródłaDecker, Silvio. "Fullerene im Strahlungsgleichgewicht - Untersuchungen in einem Quadrupolspeicher". Doctoral thesis, Universitätsbibliothek Chemnitz, 2009. http://nbn-resolving.de/urn:nbn:de:bsz:ch1-200901988.
Pełny tekst źródłaThe scientific goal of this work is the study of optical and chemical properties of carbon containing particles especially fullerenes at high temperatures. This work covered the construction and characterization of the measuring apparatus for the investigation of fullerene cations. It follows a characterization of the apparatus and its elements after a short introduction and a description of the structure of this work. This involved the further developed sublimation ion source, the quadrupole trap and the ion detections system. Extensive measurements of the ion trapping and the proof of the absolute number of trapped ions are presented. Further on the optical detections system is characterized in depth regarding the collection efficiency and sensitivity. After the introduction in the apparatus the distribution of the ions inside the trap is closer examined. The possibility of the optical detections of the number of trapped ions is shown. Additionally it is pointed out that the kinetic temperature of the ions can be extracted by geometrical measurement of the ion distribution. Further on it is enlarged on the thermal emission of hot C60. For this a classical dielectric model for the thermal emission is presented. Measuring principals of the temperature determination of laser heated ions are discussed and temperature measurements of the ion ensemble are presented. Measurements of the C2-loss as function of the temperature are presented. The results of the extracted activation energy of Ea = 2.3...5.4eV for the C2-loss reaction of C60+ shows a discrepancy to literature results. The results of this measurements are discussed with help of an numerical simulation of the internal energy distribution of the ion ensemble. This work closes with a summery and an outlook of further experimental potentialities of the measuring method
Lee-Dadswell, Geoffrey R. "Dynamics of helium trapped in fullerene cages". Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1999. http://www.collectionscanada.ca/obj/s4/f2/dsk2/ftp03/MQ40426.pdf.
Pełny tekst źródłaZettergren, Henning. "Electron transfer and fragmentation in fullerene collisions". Doctoral thesis, Stockholm : Department of Physics, Stockholm University, 2005. http://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-630.
Pełny tekst źródłaNeidhardt, Jörg. "Fullerene-like carbon nitride thin solid films /". Linköping : Univ, 2004. http://www.bibl.liu.se/liupubl/disp/disp2004/tek877s.pdf.
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