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Data publikacji: 25 maja 2024

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1

Yao, Yongchao, Deqiu Xu, Yuhong Zhu, Xin Dai, Yunlong Yu, Jianbin Luo i Shiyong Zhang. "Dandelion flower-like micelles". Chemical Science 11, nr 3 (2020): 757–62. http://dx.doi.org/10.1039/c9sc05741b.

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2

Moretton, Marcela A., Diego A. Chiappetta i Alejandro Sosnik. "Cryoprotection–lyophilization and physical stabilization of rifampicin-loaded flower-like polymeric micelles". Journal of The Royal Society Interface 9, nr 68 (24.08.2011): 487–502. http://dx.doi.org/10.1098/rsif.2011.0414.

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Rifampicin-loaded poly( ε -caprolactone)– b -poly(ethylene glycol)–poly( ε -caprolactone) flower-like polymeric micelles display low aqueous physical stability over time and undergo substantial secondary aggregation. To improve their physical stability, the lyoprotection–lyophilization process was thoroughly characterized. The preliminary cryoprotectant performance of mono- and disaccharides (e.g. maltose, glucose), hydroxypropyl-β-cyclodextrin (HPβCD) and poly(ethylene glycol) (PEG) of different molecular weights was assessed in freeze–thawing assays at −20°C, −80°C and −196°C. The size and size distribution of the micelles at the different stages were measured by dynamic light scattering (DLS). A cryoprotectant factor ( f c ) was determined by taking the ratio between the size immediately after the addition of the cryoprotectant and the size after the preliminary freeze–thawing assay. The benefit of a synergistic cryoprotection by means of saccharide/PEG mixtures was also assessed. Glucose (1 : 20), maltose (1 : 20), HPβCD (1 : 5) and glucose or maltose mixtures with PEG3350 (1 : 20) (copolymer:cryoprotectant weight ratio) were the most effective systems to protect 1 per cent micellar systems. Conversely, only HPβCD (1 : 5) cryoprotected more concentrated drug-loaded micelles (4% and 6%). Then, those micelle/cryoprotectant systems that displayed f c values smaller than 2 were freeze-dried. The morphology of freeze-dried powders was characterized by scanning electron microscopy and atomic force microscopy and the residual water content analysed by the Karl Fisher method. The HPβCD-added lyophilisates were brittle porous cakes (residual water was between 0.8% and 3%), easily redispersable in water to form transparent systems with a minimal increase in the micellar size, as determined by DLS.
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3

Wu, Lin, Ronan McHale, Guoqiang Feng i Xiaosong Wang. "RAFT Synthesis and Self-Assembly of Free-Base Porphyrin Cored Star Polymers". International Journal of Polymer Science 2011 (2011): 1–11. http://dx.doi.org/10.1155/2011/109693.

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Reversible addition fragmentation chain transfer (RAFT) synthesis and self-assembly of free-base porphyrin cored star polymers are reported. The polymerization, in the presence of a free-base porphyrin cored chain transfer agent (CTA-FBP), produced porphyrin star polymers with controlled molecular weights and narrow polydispersities for a number of monomers includingN,N-dimethylacrylamide (DMA) and styrene (St). Well-defined amphiphilic star block copolymers, P-(PS-PDMA)4and P-(PDMA-PS)4(P: porphyrin), were also prepared and used for self-assembly studies. In methanol, a selective solvent for PDMA, spherical micelles were observed for both block copolymers as characterized by TEM. UV-vis studies suggested star-like micelles were formed from P-(PS-PDMA)4, while P-(PDMA-PS)4aggregated into flower-like micelles. Spectrophotometric titrations indicated that the optical response of these two micelles to external ions was a function of micellar structures. These structure-related properties will be used for micelle studies and functional material development in the future.
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4

Liu, Bing, Hongying Chen, Xiao Li, Chaonan Zhao, Yakun Liu, Lijuan Zhu, Hongping Deng i in. "pH-responsive flower-like micelles constructed via oxime linkage for anticancer drug delivery". RSC Adv. 4, nr 90 (2014): 48943–51. http://dx.doi.org/10.1039/c4ra08719d.

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5

Kangarlou, Behrad, Rasika Dahanayake, Ian J. Martin, Dennis Ndaya, Chun-Ming Wu, Rajeswari M. Kasi, Elena E. Dormidontova i Mu-Ping Nieh. "Flower-like Micelles of Polyethylene Oxide End-Capped with Cholesterol". Macromolecules 54, nr 19 (30.09.2021): 8960–70. http://dx.doi.org/10.1021/acs.macromol.1c00896.

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6

Najafi, Marzieh, Neda Kordalivand, Mohammad-Amin Moradi, Joep van den Dikkenberg, Remco Fokkink, Heiner Friedrich, Nico A. J. M. Sommerdijk, Mathew Hembury i Tina Vermonden. "Native Chemical Ligation for Cross-Linking of Flower-Like Micelles". Biomacromolecules 19, nr 9 (13.08.2018): 3766–75. http://dx.doi.org/10.1021/acs.biomac.8b00908.

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7

Mouline, Zineb, Mona Semsarilar, Andre Deratani i Damien Quemener. "Stimuli responsive nanostructured porous network from triblock copolymer self-assemblies". Polymer Chemistry 6, nr 11 (2015): 2023–28. http://dx.doi.org/10.1039/c4py01692k.

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Well controlled ABA triblock copolymer with pendent boronic acid groups is prepared using RAFT chemistry. The resulting flower like micelles in mixture of H2O/NMP forms stimuli responsive porous network.
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8

Mandal, Madhuri, i Kalyan Mandal. "Synthesis of Snowball Flower-like Ni Nanoparticles by Negatively Charged Micelles". Chemistry Letters 38, nr 8 (5.08.2009): 768–69. http://dx.doi.org/10.1246/cl.2009.768.

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9

Cho, Eun-Bum, Eunji Choi, Shu Yang i Mietek Jaroniec. "Hollow mesoporous organosilica nanospheres templated with flower-like micelles of pentablock copolymers". Journal of Colloid and Interface Science 528 (październik 2018): 124–34. http://dx.doi.org/10.1016/j.jcis.2018.05.076.

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10

Liu, Hengchang, i Yujun Feng. "Flower-Like Multicompartment Micelles with Janus-Core Self-Assembled from Fluorocarbon-Terminated Pluronics". Macromolecular Chemistry and Physics 219, nr 8 (7.02.2018): 1700558. http://dx.doi.org/10.1002/macp.201700558.

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11

You, Chao, Qiang Zhang, Yun Zhao i Qing Ze Jiao. "Surfactants-Controlled Morphosynthesis of Strontium Carbonate". Advanced Materials Research 194-196 (luty 2011): 683–88. http://dx.doi.org/10.4028/www.scientific.net/amr.194-196.683.

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The controlled synthesis of SrCO3microstructures with different morphologies, such as flower-like, cauliflower-like and finger-like, were successfully achieved in the presence of mixed nonionic/anionic surfactants polyoxyethylene (20) sorbitan monolaurate (Tween20) and sodium dodecyl sulfate (SDS). Results indicated that SDS/Tween20 complex micelles played important roles in the morphological control of SrCO3microstructures. Also, the influence of CO32-concentration on the morphology of SrCO3crystals was investigated and discussed. X-ray powder diffraction (XRD), fourier transform infrared spectroscopy (FT-IR) and field-emission scanning electron microscope (FE-SEM) were used to characterize the as-synthesized crystals.
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12

Weiss, Jan, Hans Wienk, Rolf Boelens i André Laschewsky. "Block Copolymer Micelles with an Intermediate Star-/Flower-Like Structure Studied by1H NMR Relaxometry". Macromolecular Chemistry and Physics 215, nr 9 (28.03.2014): 915–19. http://dx.doi.org/10.1002/macp.201300753.

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13

Bai, Xiao Mei, Jiang Wei Wang, Yu Min Xia, Yan Ping Wang i Yi Min Wang. "Synthesis of Hydroxyapatite Mediated by Amphiphilic Block Copolymer PS112-b-PAA38". Applied Mechanics and Materials 713-715 (styczeń 2015): 2933–36. http://dx.doi.org/10.4028/www.scientific.net/amm.713-715.2933.

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The hierarchical hydroxyapatite (HAP), such as needle-shaped, spherical and flower-like, was successfully synthesized by a homogenous precipitation method with poly (styrene)-block-poly (acrylic acid) (PS-b-PAA). The self-assembled “crew-cut” micelles of amphiphilic block copolymer were found to play an important role in directing the nucleation and growth of HAP crystals. The morphology, crystal phrase and chemical structure of HAP crystal were investigated by scanning electron microscope (SEM), X-ray diffractions (XRD) and Fourier transform infrared spectroscopy (FT-IR) respectively.
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14

Shi, Linqi, Wangqing Zhang, Fenfang Yin, Yingli An, Huan Wang, Lichao Gao i Binglin He. "Formation of flower-like aggregates from assembly of single polystyrene-b-poly(acrylic acid) micelles". New Journal of Chemistry 28, nr 8 (2004): 1038. http://dx.doi.org/10.1039/b400445k.

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15

Sivokhin, Alexey Р., Dmitry V. Orekhov, Oleg A. Kazantsev, Olga V. Gubanova, Denis M. Kamorin, Irina S. Zarubina, Evgeniya A. Bolshakova i Sergey D. Zaitsev. "Amphiphilic thermoresponsive copolymer bottlebrushes: synthesis, characterization, and study of their self-assembly into flower-like micelles". Polymer Journal 53, nr 5 (20.01.2021): 655–65. http://dx.doi.org/10.1038/s41428-020-00456-w.

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16

Moretton, Marcela A., Romina J. Glisoni, Diego A. Chiappetta i Alejandro Sosnik. "Molecular implications in the nanoencapsulation of the anti-tuberculosis drug rifampicin within flower-like polymeric micelles". Colloids and Surfaces B: Biointerfaces 79, nr 2 (wrzesień 2010): 467–79. http://dx.doi.org/10.1016/j.colsurfb.2010.05.016.

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17

Zhou, Ling, Michal Slaný, Bingbing Bai, Weichao Du, Chengtun Qu, Jie Zhang i Ying Tang. "Enhanced Removal of Sulfonated Lignite from Oil Wastewater with Multidimensional MgAl-LDH Nanoparticles". Nanomaterials 11, nr 4 (28.03.2021): 861. http://dx.doi.org/10.3390/nano11040861.

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In this study, hierarchical MgAl-LDH (layered double hydroxide) nanoparticles with a flower-like morphology were prepared under a hydrothermal condition by employing worm-like micelles formed by cetyltrimethylammonium bromide (CTAB) and salicylic acid (SA) as templates. The morphology and structure of the materials were characterized by Brunauer–Emmett–Teller (BET), SEM, and XRD analyses. The performance for the adsorption of sulfonated lignite (SL) was also investigated in detail. FTIR was used to detect the presence of active functional groups and determine whether they play important roles in adsorption. The results showed that the hierarchical MgAl-LDH nanoparticles with a specific surface area of 126.31 m2/g possessed a flower-like morphology and meso–macroporous structures. The adsorption capacity was high—its value was 1014.20 mg/g at a temperature of 298 K and an initial pH = 7, which was higher than traditional MgAl-LDH (86 mg/g). The adsorption process of sulfonated lignite followed the pseudo-second-order kinetics model and conformed to Freundlich isotherm model with a spontaneous exothermic nature. In addition, the hierarchical MgAl-LDH could be regenerated and used, and the adsorption was high after three adsorption cycles. The main adsorption mechanisms were electrostatic attraction and ion exchange between the hierarchical MgAl-LDH and sulfonated lignite.
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18

Moretton, Marcela A., Diego A. Chiappetta, Fernanda Andrade, José das Neves, Domingos Ferreira, Bruno Sarmento i Alejandro Sosnik. "Hydrolyzed Galactomannan-Modified Nanoparticles and Flower-Like Polymeric Micelles for the Active Targeting of Rifampicin to Macrophages". Journal of Biomedical Nanotechnology 9, nr 6 (1.06.2013): 1076–87. http://dx.doi.org/10.1166/jbn.2013.1600.

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19

Zhao, Cong, Shirong Shuai, Siyao Zhou, Yu Liu, Weirong Huo, Hongyu Zhu, Zikun Rao i in. "Synthesis and characterization of photo-responsive flower-like copolymer micelles with o-nitrobenzyl as the junction point". Materials Letters 261 (luty 2020): 127151. http://dx.doi.org/10.1016/j.matlet.2019.127151.

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20

Huang, Chuan-qun, Chun-yan Hong i Cai-yuan Pan. "FORMATION OF FLOWER-LIKE AGGREGATES FROM SELF-ASSEMBLING OF MICELLES WITH PEO SHELLS AND CROSS-LINKED POLYACRYLAMIDE CORES". Chinese Journal of Polymer Science 26, nr 03 (2008): 341. http://dx.doi.org/10.1142/s0256767908002996.

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21

Mandal, Madhuri, Debabrata Pal i Kalyan Mandal. "Negatively charged micelles directed synthesis of snow-ball flower like superparamagnetic Ni nanoparticles and investigation of their properties". Colloids and Surfaces A: Physicochemical and Engineering Aspects 348, nr 1-3 (wrzesień 2009): 35–38. http://dx.doi.org/10.1016/j.colsurfa.2009.06.026.

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22

Moretton, Marcela A., Christian Hocht, Carlos Taira i Alejandro Sosnik. "Rifampicin-loaded ‘flower-like’ polymeric micelles for enhanced oral bioavailability in an extemporaneous liquid fixed-dose combination with isoniazid". Nanomedicine 9, nr 11 (sierpień 2014): 1635–50. http://dx.doi.org/10.2217/nnm.13.154.

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23

Lee, Eun Seong, Kyung Taek Oh, Dongin Kim, Yu Seok Youn i You Han Bae. "Tumor pH-responsive flower-like micelles of poly(l-lactic acid)-b-poly(ethylene glycol)-b-poly(l-histidine)". Journal of Controlled Release 123, nr 1 (październik 2007): 19–26. http://dx.doi.org/10.1016/j.jconrel.2007.08.006.

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24

Li, Boyu, Joey Kim i Julie Kornfield. "A Molecular Picture for the Thermo-Reversibility of Gels Formed by Isophthalic Acid-Ended Telechelic Polymers". MRS Proceedings 1794 (2015): 9–14. http://dx.doi.org/10.1557/opl.2015.638.

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ABSTRACTWe demonstrate that isophthalic acid-ended telechelic poly(1,5-cyclooctadiene)s (A-PCODs) form thermo-reversible gels in non-polar solvent with a unique molecular mechanism for their thermo-reversibility. Like other associative telechelic polymers, A-PCODs form “flower-like” micelles at low concentration and form gels through bridging at higher concentration which exhibit linear viscoelasticity. However, unlike the widely studied hydrophobically end-capped PEOs, A-PCODs show clear thermo-reversibility in viscosity and dynamic modulus around 30 °C due to the hydrogen-bonding end groups. In addition, they differ from other reported thermo-reversible gelators (eg. Pluronics, PNIPAm containing block copolymers, etc.): neither the end group nor the backbone in the present system has a critical solution temperature within the measured temperature range (0 °C to 60 °C), indicating that the present system has a unique mechanism for its thermo-reversibility. To obtain a molecular picture of the mechanism, rheology and small angle neutron scattering (SANS) studies were implemented. Topological changes above the transition temperature (30 °C) were observed in both oscillatory rheology and SANS. SANS reveals that the size of clusters, which are formed by interacting micelles, depends highly on temperature (T) but independent of polymer concentration. These results cannot be explained by current theories on associative telechelic polymers which assume constant and large aggregation number of end groups at all temperatures and concentrations. We hypothesize that the temperature-sensitive sol-gel transition is due to a decrease in aggregation number for T above the critical temperature in our system, and this temperature-dependence of aggregation number is further determined by the chemical structure and hydrogen-bonding property of isophthalic acid ends.
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25

Wada, Haruna, Yu Kitazawa, Shigeki Kuroki, Yasuyuki Tezuka i Takuya Yamamoto. "NMR Relaxometry for the Thermal Stability and Phase Transition Mechanism of Flower-like Micelles from Linear and Cyclic Amphiphilic Block Copolymers". Langmuir 31, nr 32 (4.08.2015): 8739–44. http://dx.doi.org/10.1021/acs.langmuir.5b01902.

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Yang, Qinglai, Changyu He, Zhen Zhang, Lianjiang Tan, Bingya Liu, Zhenggang Zhu, Zhifeng Shao, Bing Gong i Yu-Mei Shen. "Redox-responsive flower-like micelles of poly(l-lactic acid)-b-poly(ethylene glycol)-b-poly(l-lactic acid) for intracellular drug delivery". Polymer 90 (maj 2016): 351–62. http://dx.doi.org/10.1016/j.polymer.2016.03.030.

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Oh, Kyung Taek, Young Taik Oh, Nam-Muk Oh, Kwangmyung Kim, Don Haeng Lee i Eun Seong Lee. "A smart flower-like polymeric micelle for pH-triggered anticancer drug release". International Journal of Pharmaceutics 375, nr 1-2 (czerwiec 2009): 163–69. http://dx.doi.org/10.1016/j.ijpharm.2009.04.005.

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Benu, Didi Prasetyo, Arie Hardian, Rino Rakhmata Mukti, Brian Yuliarto, Nobuyoshi Fukumitsu, Yusuke Ide, Yusuke Yamauchi, Yusuf Valentino Kaneti i Veinardi Suendo. "Reverse micelle-mediated synthesis of plate-assembled hierarchical three-dimensional flower-like gamma-alumina particles". Microporous and Mesoporous Materials 321 (lipiec 2021): 111055. http://dx.doi.org/10.1016/j.micromeso.2021.111055.

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Hameed, Nishar, Nisa V. Salim, Jyotishkumar Parameswaranpillai i Bronwyn L. Fox. "Flower like micellar assemblies in poly(styrene)-block-poly(4-vinyl pyridine)/poly(acrylic acid) complexes". Materials Letters 147 (maj 2015): 92–96. http://dx.doi.org/10.1016/j.matlet.2015.02.036.

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Yaghmur, Anan, Boi Vi Tran i Seyed Moein Moghimi. "Non-Lamellar Liquid Crystalline Nanocarriers for Thymoquinone Encapsulation". Molecules 25, nr 1 (19.12.2019): 16. http://dx.doi.org/10.3390/molecules25010016.

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Owing to their unique structural features, non-lamellar liquid crystalline nanoparticles comprising cubosomes and hexosomes are attracting increasing attention as versatile investigative drug carriers. Background: Depending on their physiochemical characteristics, drug molecules on entrapment can modulate and reorganize structural features of cubosomes and hexosomes. Therefore, it is important to assess the effect of guest molecules on broader biophysical characteristics of non-lamellar liquid crystalline nanoparticles, since drug-induced architectural, morphological, and size modifications can affect the biological performance of cubosomes and hexosomes. Methods: We report on alterations in morphological, structural, and size characteristics of nanodispersions composed from binary mixtures of glycerol monooleate and vitamin E on thymoquinone (a molecule with wide therapeutic potentials) loading. Results: Thymoquinone loading was associated with a slight increase in the mean hydrodynamic nanoparticle size and led to structural transitions from an internal biphasic feature of coexisting inverse cubic Fd3m and hexagonal (H2) phases to an internal inverse cubic Fd3m phase (micellar cubosomes) or an internal inverse micellar (L2) phase (emulsified microemulsions, EMEs). We further report on the presence of “flower-like” vesicular populations in both native and drug-loaded nanodispersions. Conclusions: These nanodispersions have the potential to accommodate thymoquinone and may be considered as promising platforms for the development of thymoquinone nanomedicines.
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Bae, Seokyoung, Dong Hyup Kim i So Youn Kim. "Constructing a Comprehensive Nanopattern Library through Morphological Transitions of Block Copolymer Surface Micelles via Direct Solvent Immersion". Small, 10.03.2024. http://dx.doi.org/10.1002/smll.202311939.

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AbstractThis study establishes a comprehensive library of nanopatterns achievable by a single block copolymer (BCP), ranging from spheres to complex structures like split micelles, flower‐like clusters, toroids, disordered micelle arrays, and unspecified unique shapes. The ordinary nanostructures of polystyrene‐b‐poly(2‐vinylpyridine) (PS‐b‐P2VP) surface micelles deposited on a SiOx surface undergo a unique morphology transformation when immersed directly in solvents. Investigating parameters such as immersion solvents, BCP molecular weight, substrate interactions, and temperature, this work reveals the influence of these parameters on the thermodynamics and kinetics governing the morphology transformation. Additionally, the practical application of BCP nanopattern templates for fabricating metal nanostructures through direct solvent immersion of surface micelles is demonstrated. This approach offers an efficient and effective method for producing diverse nanostructures, with the potential to be employed in nanolithography, catalysts, electronics, membranes, plasmonics, and photonics.
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32

Najafi, Marzieh, Mehdi Habibi, Remco Fokkink, Wim Hennink i Tina Vermonden. "LCST polymers with UCST behavior". Soft Matter, 2021. http://dx.doi.org/10.1039/d0sm01505a.

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In this study, temperature dependent behavior of dense dispersions of core crosslinked flower-like micelles is investigated. Micelles were prepared by mixing aqueous solutions of two ABA block copolymers with PEG...
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Anselmo, Sara, Giuseppe Sancataldo, Vito Foderà i Valeria Vetri. "α-casein micelles-membranes interaction: Flower-like lipid protein coaggregates formation". Biochimica et Biophysica Acta (BBA) - General Subjects, czerwiec 2022, 130196. http://dx.doi.org/10.1016/j.bbagen.2022.130196.

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Sugihara, Shinji, Yuto Tsutsui, Hideyuki Uematsu, Atsushi Matsumoto i Yasushi Maeda. "Synthesis of Flower-like Micelles That Recognize Thermal History via RAFT Aqueous Dispersion Polymerization". Macromolecules, 22.04.2024. http://dx.doi.org/10.1021/acs.macromol.4c00254.

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Hu, Xinping, Chuhang Zhou, Leqi Wang, Qi Liu, Yining Ma, Yingwei Tang, Xiaoxiao Wang, Kanghao Chen, Xinyu Wang i Yan Liu. "Procedurally Targeted Delivery of Antitumor Drugs Using FAPα-Responsive TPGS Dimer-Based Flower-like Polymeric Micelles". ACS Applied Bio Materials, 13.09.2023. http://dx.doi.org/10.1021/acsabm.3c00543.

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Prasser, Quirin, Thomas Fuhs, Bernhard Torger, Richard Neubert, Erica Brendler, Carla Vogt, Florian Mertens i Felix A. Plamper. "Nonequilibrium Colloids: Temperature-Induced Bouquet Formation of Flower-like Micelles as a Time-Domain-Shifting Macromolecular Heat Alert". ACS Applied Materials & Interfaces, 7.09.2023. http://dx.doi.org/10.1021/acsami.3c09590.

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Hassanzadeh, Salman, Sepideh Khoee, Mohamad Mahdavi i Alireza Foroumadi. "Crew cut, flower-like and mixed-shaggy micelles prepared from HLH and LHL triblocks as carriers: a comparative study of encapsulation, stability and release properties". Journal of Polymer Research 19, nr 11 (12.10.2012). http://dx.doi.org/10.1007/s10965-012-9978-2.

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"Stepwise Thermo-Responsive Amino Acid-Derived Triblock Vinyl Polymers: ATRP Synthesis of Polymers, Aggregation, and Gelation Properties via Flower-Like Micelle Formation". Materials 11, nr 3 (15.03.2018): 424. http://dx.doi.org/10.3390/ma11030424.

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