Książki na temat „First order reaction”

This book deals with a central topic at the interface of chemistry and physics—the understanding of how the transformation of matter takes place at the atomic level. Building on the laws of physics, the book focuses on the theoretical framework for predicting the outcome of chemical reactions. The style is highly systematic with attention to basic concepts and clarity of presentation. Molecular reaction dynamics is about the detailed atomic-level description of chemical reactions. Based on quantum mechanics and statistical mechanics or, as an approximation, classical mechanics, the dynamics of uni- and bimolecular elementary reactions are described. The first part of the book is on gas-phase dynamics and it features a detailed presentation of reaction cross-sections and their relation to a quasi-classical as well as a quantum mechanical description of the reaction dynamics on a potential energy surface. Direct approaches to the calculation of the rate constant that bypasses the detailed state-to-state reaction cross-sections are presented, including transition-state theory, which plays an important role in practice. The second part gives a comprehensive discussion of basic theories of reaction dynamics in condensed phases, including Kramers and Grote–Hynes theory for dynamical solvent effects. Examples and end-of-chapter problems are included in order to illustrate the theory and its connection to chemical problems. The book has ten appendices with useful details, for example, on adiabatic and non-adiabatic electron-nuclear dynamics, statistical mechanics including the Boltzmann distribution, quantum mechanics, stochastic dynamics and various coordinate transformations including normal-mode and Jacobi coordinates.

The First Sino-Japanese War (1894–95) has been perceived as a sign of a new East Asian power order, but the legitimacy of the war has yet to be clarified. The Japanese foreign minister Mutsu’s Kenkenroku shows that the reasons claimed by Japan were only pretexts for its ambition to put Korea under its control. The 1885 Convention of Tianjin, which was used to justify the Japanese behaviour, needs to be reinterpreted. The Chinese reaction can be understood by exploration into Confucianism, which opposed wars between equal peers. Meanwhile, the Western powers which invented and developed international law were self-interested and did little to prevent the war. The incident shows that international law, empowered by the strong states, failed to maintain peace efficiently in the late nineteenth century.

Searching for reaction in organic synthesis has been made much easier in the current age of computer databases. However, the dilemma now is which procedure one selects among the ocean of choices. Especially for novices in the laboratory, it becomes a daunting task to decide what reaction conditions to experiment with first in order to have the best chance of success. This collection intends to serve as an "older and wiser lab-mate" one could have by compiling many of the most commonly used experimental procedures in organic synthesis. With chapters that cover such topics as functional group manipulations, oxidation, reduction, and carbon-carbon bond formation, Modern Organic Synthesis in the Laboratory will be useful for both graduate students and professors in organic chemistry and medicinal chemists in the pharmaceutical and agrochemical industries.

This chapter examines the social functions of anti-Judaism in French Algeria during the period 1889–1902 by focusing on the roles played by ethnic groups involved in what came to be known as the “anti-Jewish crisis.” The anti-Jewish crisis erupted in the late 1890s, when the three enfranchised ethnic groups living in French Algeria—Frenchmen with roots in France, European immigrants, and local Jews—challenged the established social order in the colony. The chapter first provides a background on the anti-Jewish crisis before discussing the segregated landscape of Algiers and the rise of the French anti-Jewish movement in the early 1890s. It then considers how xenophobia developed among many Frenchmen with regard to European immigrants in French Algeria and the participation of such immigrants in anti-Jewish riots. It also looks at Jewish reaction to the anti-Jewish crisis.

This chapter examines the dynamics of race and race relations in Giuseppe Verdi's Aida in the context of nationalism in nineteenth-century Egypt. The world premiere of Aida took place at the Cairo Opera House on December 24, 1871. However, there seems to be little information available on the opera's Cairo production, particularly with regards to Egyptian reaction to this first performance. Focusing on its Cairo premiere, this chapter analyzes Aida's libretto and music in order to elucidate the workings of racial difference as it lies on the surface of the opera. It suggests that, for Egyptians, Aida may have spoken to a sense of emergent Egyptian identity. It also reveals Aida's racial dynamics by linking it to discourses of light-skinned Egyptian superiority and dark-skinned African inferiority. Furthermore, the relationships between characters in the opera highlight the specificities of Egypt's relations with its racial-national Others, implying a larger project of Egyptian identity formation through “racial fabrication.”

This monograph is a continuation of the monograph by V.V. Sadovnikov. Lateral interaction. Moscow 2006. Publishing house "Anta-Eco", 2006. ISBN 5-9730-0017-6. In this work, the foundations of the theory of heterogeneous catalysis and the theory of chemisorption are more easily formulated. The book consists of two parts, closely related to each other. These are the theoretical foundations of heterogeneous catalysis and chemisorption. In the theory of heterogeneous catalysis, an experiment is described in detail, which must be carried out in order to isolate the stages of a catalytic reaction, to find the stoichiometry of each of the stages. This experiment is based on the need to obtain the exact value of the specific surface area of the catalyst, the number of centers at which the reaction proceeds, and the output curves of each of the reaction products. The procedures for obtaining this data are described in detail. Equations are proposed and solved that allow calculating the kinetic parameters of the nonequilibrium stage and the thermodynamic parameters of the equilibrium stage. The description of the quantitative theory of chemisorption is based on the description of the motion of an atom along a crystal face. The axioms on which this mathematics should be based are formulated, the mathematical apparatus of the theory is written and the most detailed instructions on how to use it are presented. The first axiom: an atom, moving along the surface, is present only in places with minima of potential energy. The second axiom: the face of an atom is divided into cells, and the position of the atom on the surface of the face is set by one parameter: the cell number. The third axiom: the atom interacts with the surrounding material bodies only at the points of minimum potential energy. The fourth axiom: the solution of the equations is a map of the arrangement of atoms on the surface. The fifth axiom: quantitative equations are based on the concept of a statistically independent particle. The formation energies of these particles and their concentration are calculated by the developed program. The program based on these axioms allows you to simulate and calculate the interaction energies of atoms on any crystal face. The monograph is intended for students, post-graduate students and researchers studying work and working in petrochemistry and oil refining.

As the United States rose to ascendancy in the first decades of the twentieth century, observers abroad associated American economic power most directly with its burgeoning automobile industry. In the 1930s, in a bid to emulate and challenge America, engineers from across the world flocked to Detroit. Chief among them were Nazi and Soviet specialists who sought to study, copy, and sometimes steal the techniques of American automotive mass production, or Fordism. This book traces how Germany and the Soviet Union embraced Fordism amid widespread economic crisis and ideological turmoil. The book recovers the crucial role of activist states in global industrial transformations and reconceives the global thirties as an era of intense competitive development, providing a new genealogy of the postwar industrial order. The book uncovers the forgotten origins of Fordism in Midwestern populism, and shows how Henry Ford's antiliberal vision of society appealed to both the Soviet and Nazi regimes. It explores how they positioned themselves as America's antagonists in reaction to growing American hegemony and seismic shifts in the global economy during the interwar years, and shows how Detroit visitors helped spread versions of Fordism abroad and mobilize them in total war. The book challenges the notion that global mass production was a product of post-World War II liberal internationalism, demonstrating how it first began in the global thirties, and how the spread of Fordism had a distinctly illiberal trajectory.

The Second World War catalyzed a profound reconfiguration of the political discourse in East Central Europe. A considerable part of the region experienced consecutive occupation regimes, which triggered strategies of playing out the occupiers against each other. A central tenet of any legitimization of collaboration was the idea that the liberal democratic world order had disintegrated and a new totalitarian Zeitgeist had emerged in its stead. In turn, the resistance movements were organized either by communists or by members of the prewar elites. The former had a hard time coping with the Nazi–Soviet friendship in 1939–41, and later had to show their relative independence from the Soviet Union in order to gain legitimacy in their societies. The resistance led by the members of the old elites, in turn, had to prove that they were able to modify their old ideas for a new situation. The chapter also reviews the first reactions to the genocidal policies during the war.

In October 1909 Saxony’s new plural suffrage was tested for the first and only time. This chapter begins with an examination of Social Democratic strength and the election campaign. The chapter ends by citing different answers to a question that had resonance beyond Saxony’s borders: Did the plural suffrage save the existing social and political order from Social Democracy, or was it a grave miscalculation? In between, sections are devoted to the actions and reactions of anti-socialist groups during the campaign; to the role of left-liberal and National Liberal parties between Left and Right; to statistical analysis of plural voting and its impact on the parliamentary representation of workers and the lower-middle classes; and to contemporaries’ realization that statistical predictions about the plural suffrage’s effect on voting outcomes were flawed.

In the post-truth era, postmodern satiric media have emerged as prominent critical voices playing an unprecedented role at the heart of public debate, filling the gaps left not only by traditional media but also by weak social institutions and discredited political elites. Satiric TV in the Americas analyzes some of the most representative and influential satiric TV shows on the continent (focusing on cases in Argentina, Peru, Ecuador, Mexico, Chile, and the United States) in order to understand their critical role in challenging the status quo, traditional journalism, and the prevalent local media culture. It illuminates the phenomenon of satire as resistance and negotiation in public discourse, the role of entertainment media as a site where sociopolitical tensions are played out, and the changing notions of journalism in today’s democratic societies. Introducing the notion of “critical metatainment”—a postmodern, carnivalesque result of and a transgressive, self-referential reaction to the process of tabloidization and the cult of celebrity in the media spectacle era—Satiric TV in the Americas is the first book to map, contextualize, and analyze relevant cases to understand the relation between political information, social and cultural dissent, critical humor, and entertainment in the region. Evaluating contemporary satiric media as distinctively postmodern, multilayered, and complex discursive objects that emerge from the collapse of modernity and its arbitrary dichotomies, Satiric TV in the Americas also shows that, as satiric formats travel to a particular national context, they are appropriated in different ways and adapted to local circumstances, thus having distinctive implications.

This chapter focuses on the reactions of overseas Filipino communities to anti-martial law activists in exile. Much of the print coverage of the U.S.-based anti-Marcos groups tended to spotlight prominent exile figures. Having found the freedom to speak out, to write for publication, to demonstrate, to organize openly—activities that could get their colleagues back home in trouble with the authorities—they plunged into furious rounds of organizing the resident Filipino population. They had assumed that their compatriots in the United States would empathize with their experience and respond readily to appeals for money, membership, and participation. However, anti-martial law activists who reached out to Filipino communities were met with two reactions—apathy and fear. Apathy was most pronounced among the newer immigrants. They had come to the United States to improve their prospects for a livelihood they found unachievable back in the Philippines. The first order of business was to get settled—employment, housing, education for their children—all the basics of survival in their new home. There was no room to indulge in politics, local or Philippine. There was also the fear of getting involved. News of roundups, interrogations, and military detentions was constant. They would not want to jeopardize relatives back home once their U.S. activities were made known.

This chapter examines the years 1866–76 as a period of far-reaching liberal achievements in Germany’s Second Reich, and more modest, temporary liberal successes in Saxony. The first section provides a close examination of the Reichstag elections of February 1867, when Germans confronted the novelty of mass politics. It considers principal campaign themes and key races in order to convey the look and feel of this election contest, and discusses reactions to the election outcome in light of the political parties’ future prospects. A second section examines Saxony’s important but uncertain role in the North German Confederation, and the Reichstag election of August 1867. A third section is devoted to Saxony’s Landtag suffrage reform of 1868. Liberals, Conservatives, and the Saxon government put forward competing agendas for reform. The final reform reflected a mix of liberal and conservative ideals, and the general election of 1869 inaugurated a fragile liberal era.

The year 1714 was a revolutionary one for Dissenters across the British Empire. The Hanoverian Succession upended a political and religious order antagonistic to Protestant non-conformity and replaced it with a regime that was, ostensibly, sympathetic to the Whig interest. The death of Queen Anne and the dawn of Hanoverian Rule presented Dissenters with fresh opportunities and new challenges as they worked to negotiate and legitimize afresh their place in the polity. The essays in this collection examine how Dissenters and their allies in a range of geographic contexts confronted and adapted to the Hanoverian order. Collectively, they argue that though generally overlooked compared to the Glorious Revolution of 1688–9 or the 1707 Act of Union, 1714 was a pivotal moment with far reaching consequences for Dissenters at home and abroad. By decentralizing the narrative beyond England and exploring dissenting reactions in Scotland, Ireland and North America, the authors in this volume demonstrate the extent to which the Succession influenced the politics and touched the lives of ordinary people across the British Atlantic world. As well as offering a thorough breakdown of confessional tensions within Britain during the short and medium terms, this volume also marks the first attempt to look at the complex interaction between religious communities in consequence of the Hanoverian Succession.

The politics of 1789 cannot be understood without considering the psychology and group dynamics of France’s national legislators. Facing an unexpectedly large power vacuum at Versailles as the Estates-General commenced, Third Estate-led legislators would increasingly assert their own sovereignty and expand an agenda initially centred on financial reform into a thorough revolution of French politics and culture. Operating in dialogue with broader sets of revolutionary actors, both stimulating and reacting to outside changes, legislators forged a new rights-based order which virtually all agreed to support by late 1789. This process inspired a ‘personal revolution’ for many deputies: men who were previously pillars of Old Regime society broke with prior societal and emotional constraints to create the most radical revolution yet seen. Understanding the first National Assembly requires comprehending the backgrounds and experiences of its 1200 members, and the stresses of the complex political and social processes which drove such events forward.

The monograph should be seen as an attempt to present changes affecting the category of family farm owners in Poland over the last 70 years, since the end of World War II. These changes brought significant social transformations, including the dismantling of the landowner class (who had large agricultural farms in their possession), moving the state border westward and changing the multiethnic Polish society into one close to ethnic homogeneity. The main goal of this reflection is to recount ways in which family farms coped with various unfavorable forces and factors in order to remain in operation. One could say that the entire study can be viewed as a manifestation of the well-known phrase that served as the title of the James C. Scott book (1990): Domination and the Arts of Resistance. The monograph presented here refers to these analyses stemming from another edition of sociological research, completed within the framework of the MAESTRO project financed by the National Science Center of Poland. The main goal of the project was to depict the functioning of agricultural family farms as the traditional sector of agriculture in Poland in the contemporary context of globalization processes. The farms were examined in terms of the principles of sustainable development as well as flexibility and resilience in reaction to various crises. The monograph is divided into four essential parts. The first part is devoted to the theoretical issues and methodological groundwork for the entire publication. The second part of the book aims to capture the changes that took place from 1994 to 2017, which was an adequate period to encompass the changes and metamorphoses that mostly happened as a result of two things: the regime transformation which began in 1990, and Poland’s accession to the European Union on May 1, 2004. The third part deals with the crucial issues of regional variations, mostly in regard to life strategies and strategies of operating agricultural farms. Finally, there is a fourth part which places the focus on select themes, such as rural lifestyles, food safety and security, farmers’ utilization of new computer and IT resources, and the potential for socio-political mobilization.

A World From Dust describes how a set of chemical rules combined with the principles of evolution in order to create an environment in which life as we know it could unfold. Beginning with simple mathematics, these predictable rules led to the advent of the planet itself, as well as cells, organs and organelles, ecosystems, and increasingly complex life forms. McFarland provides an accessible discussion of a geological history as well, describing how the inorganic matter on Earth underwent chemical reactions with air and water, allowing for life to emerge from the world's first rocks. He traces the history of life all the way to modern neuroscience, and shows how the bioelectric signals that make up the human brain were formed. Most popular science books on the topic present either the physics of how the universe formed, or the biology of how complex life came about; this book's approach would be novel in that it condenses in an engaging way the chemistry that links the two fields. This book is an accessible and multidisciplinary look at how life on our planet came to be, and how it continues to develop and change even today. This book includes 40 illustrations by Gala Bent, print artist and studio faculty member at Cornish College of the Arts, and Mary Anderson, medical illustrator.

Protestant Dissent was assailed by Anglo-Catholics in England and by the Mercersburg Theologians in the United States for its fissiparous tendencies, sectarian nature, and privileging of emotional conversionism over apostolic order and objective, sacramental religion. Yet this chapter argues that personal conversion was essential to the faith of Dissent and the key to its spirituality, worship, and congregational life. Whether conversion was gradual or instantaneous, it remained the point of entry into the Christian life and the full privileges of church membership. Spurred by the preaching of the gospel and sometimes, but not always, accompanied by the application of the divine law, the earlier underpinning of conversionism in Calvinism gave way to an emphasis on human response. Popular in both the United States and Great Britain, the ‘new measures’ of the Presbyterian evangelist Charles Finney, in which burdened souls were called forward to ‘the anxious bench’ and prayerfully incited to undergo the new birth, brought thousands into the churches. However, in more liberal circles especially, conversion had by the end of the century become less of a crisis of guilt and redemption than a smooth progression towards spiritual fullness. Although preaching was often linked, especially in the first part of the century, with revivalist exuberance, it remained a mainstay of congregational life. Mainly expository and practical with a view of building up congregants in the faith, it was accompanied by hymn singing, scriptural readings, public prayers, and the two sacraments or ‘ordinances’ of baptism and the Lord’s Supper. Sermons tended to become shorter as the century progressed, from an hour or so to thirty or forty minutes, while the ‘long prayer’, invariably offered by the minister, tended to be didactic in tone. From mid-century onwards, there was a move towards more rounded worship, though congregations would sit (or sometimes stand) for prayer, but not kneel. The liturgical use of the church year with congregational recitation of the Lord’s Prayer became slowly more acceptable. Communion, either monthly or quarterly, was usually a Zwinglian memorial of Christ’s atoning sacrifice. The impact of the temperance movement during the latter part of the century dictated the use of non-alcoholic rather than fermented wine in the Lord’s Supper, while in a reaction to Anglican sacerdotalism, baptism too, whether believers’ baptism or paedo-baptism, progressively lost its sacramental character. Throughout the century, Dissenters sang. In the absence of an externally imposed prayer book or a standardized liturgy, hymns provided them with both devotional aids and a collective identity. Unaccompanied at first, hymn singing, inspired mostly by the muse of Isaac Watts, Charles Wesley, and, in Wales, William Williams, became more disciplined, eventually with organ accompaniment. Even while moving towards a more sophisticated, indeed bourgeois mode, Dissent maintained a vibrant congregational life which prized a simple, biblically based spirituality.

Reading, however fundamental the task may seem to everyday life, is a complex process that takes years to master. Yet, learning to read in the early stages is not an overwhelming problem for most children, especially when their classroom learning is coupled with a nurturing home environment in which reading is cherished, and pencil and paper are always available and fun to use. In fact, studies have shown that children score higher in reading if their parents support and encourage them at home. Unfortunately, though many parents want to involve themselves actively in their children's education, very few know just what to do. Now Dr. Harvey S. Wiener, author of the classic Any Child Can Write, provides an indispensable guide for parents who want to help their children enter the magic realm of words. In Any Child Can Read Better, Second Edition, Dr. Wiener offers practical advice on how to help children make their way through the maze of assignments and exercises related to classroom reading. In this essential book, parents learn how to be "reading helpers" without replacing or superseding the teacher--by supporting a child's reading habits and sharing the pleasures of fiction, poetry, and prose. Home learning parents also will find a wealth of information here. Through comfortable conversation and enjoyable exercises that tap children's native abilities, parents can help their child practice the critical thinking and reading skills that guarantee success in the classroom and beyond. For example, Dr. Wiener explains how exercises such as prereading warm-ups like creating word maps (a visual scheme that represents words and ideas as shapes and connects them) will allow youngsters to create a visual format and context before they begin reading. He shows how pictures from a birthday party can be used to create patterns of meaning by arranging them chronologically to allow the party's "story" to emerge, or how they might by arranged by order of importance--a picture of Beth standing at the door waiting for her friends to arrive could be displayed first, Beth blowing out the birthday cake placed toward the middle of the arrangement, and the pictures of Beth opening her gifts, especially the skates she's been begging for all year, would surely go toward the end of the sequence. Dr. Wiener shows how these activities, and many others, such as writing games, categorizing toys or clothes or favorite foods, and reading journals, will help children draw meaning out of written material. This second edition includes a new chapter describing the benefits of encouraging children to keep a journal of their personal reactions to books, the value of writing in the books they own (underlining, writing in the margins, and making a personal index) and a variety of reading activities to help children interact with writers and their books. Dr. Wiener has also expanded and updated his fascinating discussion of recommended books for children of all ages, complete with plot summaries. Written in simple, accessible prose, Any Child Can Read Better offers sensible advice for busy parents concerned with their children's education.