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Cho, Kie Yong, A. Ra Cho, Yun Jae Lee, Chong Min Koo, Soon Man Hong, Seung Sangh Wang, Ho Gyu Yoon i Kyung Youl Baek. "Enhanced Electrical Properties of PVDF-TrFE Nanocomposite for Actuator Application". Key Engineering Materials 605 (kwiecień 2014): 335–39. http://dx.doi.org/10.4028/www.scientific.net/kem.605.335.
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Carbon nanotubes (CNTs) coated by compatibilizer (P3HT-PMMA) imparted sta-ble dispersion in organic solvents and polymer matrix (P(VDF-TrFE)). The compatibility be-tween CNTs with P3HT-PMMA was con rmed by measuring Raman spectroscopy. CoatedCNTs were then blended with P(VDF-TrFE) (70:30 mol%) to obtain polymer nanocompositesby solution- casting process. Polymer nanocomposites showed enhanced electrical characteris-tics, as nanocomposites near the threshold of the transition between P(VDF-TrFE) insulatorand CNT conductor revealed great improvement of electrical conductivity up to 10-6 S/cmat 1 KHz. Electromechanical properties of the polymer nanocomposite were examined as afunction of electric eld.
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Abou El Fadl, Faten Ismail, Maysa A. Mohamed, Magida Mamdouh Mahmoud i Sayeda M. Ibrahim. "Studying the electrical conductivity and mechanical properties of irradiated natural rubber latex/magnetite nanocomposite". Radiochimica Acta 110, nr 2 (22.11.2021): 133–44. http://dx.doi.org/10.1515/ract-2021-1080.
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Abstract Nanocomposites have received voluminous interest due to the combination of unique properties of organic and inorganic component in one material. In this class, magnetic polymer nanocomposites are of particular interest because of the combination of excellent magnetic properties, stability, and good biocompatibility. This paper reports the preparation and characterization of nanocomposites films based on natural rubber in latex state (NRL) loaded with different concentrations of semiconducting magnetite nanoparticles (Fe3O4) (MNPs) (5, 10, 15, 20, and 30%). NRL (100%) and NRL/Fe3O4 nanocomposites were prepared by solution casting technique then, exposed to various irradiation doses (50, 70, 100 kGy).The nanocomposite’s morphological, and physical properties were investigated through various spectroscopic techniques such as Fourier-transformed infrared, X-ray diffraction, scanning electron, and transmission electron microscopies. The mechanical properties, including the tensile strength and elongation at break percentage (E b %) of the nanocomposites were also studied and compared with the 100% NRL films. Based on the results obtained from the mechanical study, it is found that the NRL/20% Fe3O4 nanocomposite film exhibited the highest tensile strength at 100 kGy. On the other hand, based on the conductivity study, it is found that, NRL/Fe3O4 nanocomposite with 10% magnetite exhibit the highest conductivity as the content of magnetite plays an important and effective role based on the high and homogeneous dispersity.
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Polsterova, Helena. "Dielectric Properties of Nanocomposites Based on Epoxy Resin". ECS Transactions 105, nr 1 (30.11.2021): 461–66. http://dx.doi.org/10.1149/10501.0461ecst.
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Nanocomposites are subject of research in many fields of science. Electrical technology focused on the study of electrical properties of nanocomposites including breakdown strength, relative permittivity, resistivity and other. This paper describes the results of measurement of electrical parameters of a nanocomposite at various temperatures. The nanocomposite matrix was casting epoxy resin and nanoparticles were made of TiO2 powder at different concentrations.
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Sabo, Y. T., D. E. A. Boryo, I. Y. Chindo i A. M. Auwal. "Nanocomposites transformed from polystyrene waste/antimony, barium and nickel oxides nanoparticles with improved thermal and electrical properties". Nigerian Journal of Chemical Research 26, nr 2 (5.02.2022): 117–27. http://dx.doi.org/10.4314/njcr.v26i2.7.
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In this experiment, the oxide nanoparticles were synthesized via chemical precipitation and the nanocomposites were produced using in situ polymerization method with varying nanoparticles contents ranged from 0.1 g to 1.0 g for electrical conductivity and from 0.05 g to 0.25 g for thermal conductivity. The electrical and thermal conductivities of nanocomposites were investigated and compared with the values obtained for untreated polystyrene. It was observed that the electrical and thermal properties were higher for the nanocomposites and increase with increasing nanoparticle concentrations in the samples. It can be observed that nanocomposite containing NiO nanoparticles gave a better electrical and thermal conductivity followed by nanocomposite containing BaO nanoparticles and nanocomposite containing Sb2O3 nanoparticles respectively. It can also be observed that nanocomposite containing NiO nanoparticle showed increase in rate of heat transfer from 1.60 W to 2.60 W, while nanocomposite containing BaO nanoparticles recorded increase in rate of heat transfer from 1.40 W to 2.45 W and nanoomposite containing Sb2O3 nanoparticle showed increase in rate of heat transfer from 1.07 W to 2.21 W, as concentration of nanoparticles increased from 0.05 g to 0.25 g respectively. Conclusively, with these results, the nanocomposite containing NiO nanoparticles gave a better thermal and electrical conductivity by having a better conducting filler network inside the matrix than nanocomposite containing BaO nanoparticles and nanocomposite containing Sb2O3 nanoparticles. It is recommended that during the production of polymer nanocomposite, PS/NiO, PS/BaO and PS/Sb2O3 nanocomposites could be used in electrically conductive devices as well as suitable materials for heat transfer applications.
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V. C. Morais, Manuel, Marco Marcellan, Nadine Sohn, Christof Hübner i Frank Henning. "Process Chain Optimization for SWCNT/Epoxy Nanocomposite Parts with Improved Electrical Properties". Journal of Composites Science 4, nr 3 (14.08.2020): 114. http://dx.doi.org/10.3390/jcs4030114.
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Electrically conductive nanocomposites present opportunities to replace metals in several applications. Usually, the electrical properties emerging from conductive particles and the resulting bulk values depend on the micro/nano scale morphology of the particle network formed during processing. The final electrical properties are therefore highly process dependent. In this study, the electrical resistivity of composites made from single-walled carbon nanotubes in epoxy was investigated. Three approaches along the processing chain were investigated to reduce the electrical resistivity of nanocomposites-the dispersion strategy in a three-roll mill, the curing temperature, and the application of electric fields during curing. It was found that a progressive increase in the shear forces during dispersion leads to a more than 50% reduction in the electrical resistivities. Higher curing temperatures of the nanocomposite resin also lead to a decrease of around 50% in resistivity. Furthermore, a scalable resin transfer molding set-up with gold-coated electrodes was developed and tested with different mold release agents. It has been shown that curing the material under electric fields leads to an electrical resistivity approximately an order of magnitude lower, and that the properties of the mold release agent also influence the final resistivity of different samples in the same batch.
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Ouis, Nora, Assia Belarbi, Salima Mesli i Nassira Benharrats. "Improvement of Electrical Conductivity and Thermal Stability of Polyaniline-Maghnite Nanocomposites". Chemistry & Chemical Technology 17, nr 1 (27.03.2023): 118–25. http://dx.doi.org/10.23939/chcht17.01.118.
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A new nanocomposite based on conducting polyaniline (PANI) and Algerian montmorillonite clay dubbed Maghnite is proposed to combine conducting and thermal properties (Mag). The PANI-Mag nanocompo-sites samples were made by in situ polymerization with CTABr (cetyl trimethyl ammonium bromide) as the clay galleries' organomodifier. In terms of the PANI-Mag ratio, the electrical and thermal properties of the obtained nanocomposites are investigated. As the amount of Maghnite in the nanocomposite increases, thermal stability improves noticeably, as measured by thermal gravimetric analysis. The electric conductivity of nanocomposites is lower than that of free PANI. As the device is loaded with 5 % clay, the conductivity begins to percolate and decreases by many orders of magnitude. The findings show that the conductivity of nanocomposites is largely independent of clay loading and dispersion.
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Abdulla, Estabraq T. "Synthesis and electrical properties of conductive polyaniline/ SWCNT nanocomposites". Iraqi Journal of Physics (IJP) 15, nr 34 (8.01.2019): 106–13. http://dx.doi.org/10.30723/ijp.v15i34.126.
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The synthesis of conducting polyaniline (PANI) nanocomposites containing various concentrations of functionalized single-walled carbon nanotubes (f-SWCNT) were synthesized by in situ polymerization of aniline monomer. The morphological and electrical properties of pure PANI and PANI/SWCNT nanocomposites were examined by using Fourier transform- infrared spectroscopy (FTIR), and Atomic Force Microscopy (AFM) respectively. The FTIR shows the aniline monomers were polymerized on the surface of SWCNTs, depending on the -* electron interaction between aniline monomers and SWCNTs. AFM analysis showed increasing in the roughness with increasing SWCNT content. The AC, DC electrical conductivities of pure PANI and PANI/SWCNT nanocomposite have been measured in frequency range (50Hz - 600KHz) and in the temperature range from (30 to 160K). The results show the electrical conductivity of the nanocomposite is higher than pure PANI.
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Alam, Rabeya Binta, Md Hasive Ahmad, S. M. Nazmus Sakib Pias, Eashika Mahmud i Muhammad Rakibul Islam. "Improved optical, electrical, and thermal properties of bio-inspired gelatin/SWCNT composite". AIP Advances 12, nr 4 (1.04.2022): 045317. http://dx.doi.org/10.1063/5.0089118.
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In this study, we report a facile route to synthesize gelatin-based Single-Walled Carbon Nanotube (gelatin/SWCNT) nanocomposites using a simple solution casting process and investigate the impact of SWCNT filler on the structural, surface morphological, optical, electrical, and thermal features. According to the Fourier transform infrared spectroscopy study, the addition of SWCNTs improves the interaction between gelatin and SWCNTs. The field emission scanning electron microscope images showed the presence of the fillers increased with the increment of SWCNT. The roughness of the samples increased caused by high interfacial interactions between Gel and SWCNTs. The nanocomposite’s optical bandgap was observed to be reduced from 2.1 to 1.9 eV as the SWCNT was varied from 0% to 0.5 vol. %. The addition of SWCNTs significantly boosted the DC electrical conductivity of the prepared samples by four orders of magnitude. The incorporation of SWCNT into the gelatin matrix was also observed to improve the nanocomposite's melting enthalpy and degree of crystallinity up to 94.5%. The gelatin/SWCNT nanocomposites were found to be decomposed completely in 4 days in the soil in an open environment.
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Kasım, Hasan, i Murat Yazıcı. "Electrical Properties of Graphene / Natural Rubber Nanocomposites Coated Nylon 6.6 Fabric under Cyclic Loading". Periodica Polytechnica Chemical Engineering 63, nr 1 (18.06.2018): 160–69. http://dx.doi.org/10.3311/ppch.12122.
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In the present study, an elastomeric nanocomposite was prepared by two roller mixing mill with the Natural Rubber (NR) and Nano Graphene Platelets (NGP). The Nylon 6.6 cord fabrics were laminated with the prepared NR/NGP nanocomposite layers. The NR/NGP composites and Nylon 6.6 cord fabric laminated nanocomposite plates were cured at 165 °C for 10 min under pressure. Nylon 6.6 fabric reinforced NR/NGP nanocomposites were electrically characterized under free and cyclic loading conditions. NGP addition to NR improved the electrical conductivity. Under cyclic loading produced nanocomposite and cord fabric layered plates showed periodical sensing behavior with same amplitude in each period.
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Wang, Shaojing, Peng Xu, Xiangyi Xu, Da Kang, Jie Chen, Zhe Li i Xingyi Huang. "Tailoring the Electrical Energy Storage Capability of Dielectric Polymer Nanocomposites via Engineering of the Host–Guest Interface by Phosphonic Acids". Molecules 27, nr 21 (25.10.2022): 7225. http://dx.doi.org/10.3390/molecules27217225.
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Polymer nanocomposites have attracted broad attention in the area of dielectric and energy storage. However, the electrical and chemical performance mismatch between inorganic nanoparticles and polymer leads to interfacial incompatibility. In this study, phosphonic acid molecules with different functional ligands were introduced to the surface of BaTiO3 (BT) nanoparticles to tune their surface properties and tailor the host–guest interaction between BT and poly(vinylideneflyoride-co-hexafluroro propylene) (P(VDF-HFP)). The dielectric properties and electrical energy storage capability of the nanocomposites were recorded by broadband dielectric spectroscopy and electric displacement measurements, respectively. The influence of the ligand length and polarity on the dielectric properties and electrical energy storage of the nanocomposites was documented. The nanocomposite with 5 vol% 2,3,4,5,6-pentafluorobenzyl phosphonic acid (PFBPA)-modified BT had the highest energy density of 12.8 J cm−3 at 400 MV m−1, i.e., a 187% enhancement in the electrical energy storage capability over the pure P(VDF-HFP). This enhancement can be attributed to the strong electron-withdrawing effect of the pentafluorobenzyl group of PFBPA, which changed the electronic nature of the polymer–particle interface. On the other hand, PFBPA improves the compatibility of the host–guest interface in the nanocomposites and decreases the electrical mismatch of the interface. These results provide new insights into the design and preparation of high-performance dielectric nanocomposites.
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ZAVYALOV, S. A., E. I. GRIGORIEV, A. S. ZAVYALOV, I. A. MISURKIN, S. V. TITOV, T. S. ZHURAVLEVA, I. V. KLIMENKO, A. N. PIVKINA, E. M. KELDER i J. SCHOONMAN. "STRUCTURE AND PROPERTIES OF TITANIUM–POLYMER THIN FILM NANOCOMPOSITES". International Journal of Nanoscience 04, nr 01 (luty 2005): 149–61. http://dx.doi.org/10.1142/s0219581x05003000.
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Thin film titanium/poly-para-xylylene nanocomposites with controlled Ti content are prepared by vacuum coevaporation and cocondensation of Ti and paracyclophane. The structure and chemical composition of as-deposited samples and the changes of electrical resistivity, which they undergo upon heating, are studied by atomic force microscopy, optical absorption spectroscopy, and the temperature coefficient of the electrical resistivity. It is shown that vacuum coevaporation results in the production of nanocomposite thin films with average Ti particle size of 10–50 nm. The inorganic phase is shown to be amorphous Ti for the samples with high metal content, whereas for the low-filled nanocomposites it consists of amorphous titanium oxide. Two types of kinetics of the nanocomposite oxidation process have been found and modeled by (i) inverse logarithmic and (ii) logarithmic functions depending on the metal content within the thin film. After a long preconditioning period in air the electrical conductivity of the thin film nanocomposites was carefully investigated by two-probe DC measurements. A strong correlation between the concentration of Ti in the thin films and the electrical conductivity dependency on temperature is found and modeled by a heterogeneous model of conductivity.
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Alenazi, Mashal. "Electrical Properties of Nanocomposites". IARJSET 3, nr 4 (20.04.2016): 80–82. http://dx.doi.org/10.17148/iarjset.2016.3418.
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Banerjee, S., i D. Chakravorty. "Electrical Properties of Nanocomposites". Transactions of the Indian Ceramic Society 59, nr 1 (styczeń 2000): 1–11. http://dx.doi.org/10.1080/0371750x.2000.10799891.
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Backes, Eduardo H., Fabio R. Passador, Christian Leopold, Bodo Fiedler i Luiz A. Pessan. "Electrical, thermal and thermo-mechanical properties of epoxy/multi-wall carbon nanotubes/mineral fillers nanocomposites". Journal of Composite Materials 52, nr 23 (12.03.2018): 3209–17. http://dx.doi.org/10.1177/0021998318763497.
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Epoxy/multi-wall carbon nanotubes and epoxy/multi-wall carbon nanotubes/mineral fillers nanocomposites were produced via in situ polymerization assisted by three-roll-milling. Epoxy/multi-wall carbon nanotubes nanocomposites presented very low electrical percolation threshold, near to 0.05 wt %. In this study, we used different mineral fillers, with different aspect ratios: calcium carbonate, montmorillonite, and sepiolite. We evaluated the effect of the addition of these fillers on electrical, thermal, and thermo-mechanical properties of epoxy/multi-wall carbon nanotubes nanocomposites. The addition of calcium carbonate in epoxy/multi-wall carbon nanotubes nanocomposites increased the electrical conductivity of this nanocomposite, due to volume exclusion effect. The addition of sepiolite decreased the loss factor and improved electrical constant, however, reduced the electrical conductivity in these nanocomposites, when compared to epoxy/multi-wall carbon nanotubes. Regarding thermal properties, no significant change in glass transition was observed. Thermo-mechanical analysis for nanocomposites showed slight changes in tan (δ) and storage modulus, which is related to the interaction between epoxy, multi-wall carbon nanotubes and mineral fillers.
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Abd Razak, Jeefferie, Nor Aisah Khalid, Hazman Hasib, Mazlin Aida Mahamood, Mohd Muzafar Ismail, Noraiham Mohamad, Poppy Puspitasari i Moayad Husein Flaifel. "Electrical Conductivity and Antenna Properties of Polyaniline filled GNPs Nanocomposites". Malaysian Journal on Composites Science and Manufacturing 4, nr 1 (5.03.2021): 11–27. http://dx.doi.org/10.37934/mjcsm.4.1.1127.
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This study was conducted to investigate the potential of utilizing conductive polymer nanocomposite for flexible type antenna application. The polyaniline (PANI) filled with graphene nanoplatelets (GNPs) nanocomposites were synthesized by an oxidative aniline polymerization in an acidic medium. The PANI/GNPs nanocomposites were then characterized by using various spectroscopy and imaging tools. It was found that the strong interaction between PANI macromolecules and GNPs flakes is caused by the strong ?-? conjugation between them, as validated by an increase of Id/Ig ratio of PANI/GNPs nanocomposites. As a result, it established a three-fold improvement for the electrical conductivity of PANI/GNPs nanocomposites, due to the larger amount of charge carrier transport at higher GNPs nanofiller loadings (1.00 wt.%). Later, the PANI/GNPs nanocomposites powder was applied to the cotton fabric by integrating it with a rubber paint slurry. Electrical conductivity, antenna gain, return loss, and radiation pattern of the antenna were reported. It was found that PANI/GNPs flexible textile antenna possessed a constant gain of 4.1809 dB, return loss at -13.154 dB, and radiation pattern which operated at 10.36 GHz for 100% improvement of electrical conductivity, in comparison with unfilled PANI. From these findings, it can be said that the development of wearable textile antenna utilizing PANI/GNPs nanocomposites on the cotton fabric as flexible radiation patch, has great potential for wireless communication purposes.
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Ramakrishnaiah, Thejas, Prasanna Gunderi Dhananjaya, Chaturmukha Vakwadi Sainagesh, Sathish Reddy, Swaroop Kumaraswamy i Naveen Chikkahanumajja Surendranatha. "A review: electrical and gas sensing properties of polyaniline/ferrite nanocomposites". Sensor Review 42, nr 1 (5.01.2022): 164–75. http://dx.doi.org/10.1108/sr-02-2021-0051.
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Purpose This paper aims to study the various developments taking place in the field of gas sensors made from polyaniline (PANI) nanocomposites, which leads to the development of high-performance electrical and gas sensing materials operating at room temperature. Design/methodology/approach PANI/ferrite nanocomposites exhibit good electrical properties with lower dielectric losses. There are numerous reports on PANI and ferrite nanomaterial-based gas sensors which have good sensing response, feasible to operate at room temperature, requires less power and cost-effective. Findings This paper provides an overview of electrical and gas sensing properties of PANI/ferrite nanocomposites having improved selectivity, long-term stability and other sensing performance of sensors at room temperature. Originality/value The main purpose of this review paper is to focus on PANI/ferrite nanocomposite-based gas sensors operating at room temperature.
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Hrenechen, Jeferson Matos, Celso de Araujo Duarte, Ney Pereira Mattoso Filho i Evaldo Ribeiro. "Electrical and Optical Properties of Silicone Oil/Carbon Nanotube Nanocomposites". Journal of Nanoscience and Nanotechnology 21, nr 4 (1.04.2021): 2185–95. http://dx.doi.org/10.1166/jnn.2021.19073.
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The present work describes the preparation and the investigation of the room temperature electrical and optical properties of a series of liquid nanocomposites (lnC) prepared with different concentrations of multiwalled carbon nanotubes (MWCNT) in a variety of liquid matrices: glycerin, Vaseline, glucose, propylene glycol and silicone oil (SIO). Special attention is deserved to the SIO matrix, owing to its convenient electrical properties for our purposes. We verified that a small percent fraction of MWCNT dispersed along the SIO matrix is capable of improving the electrical conductivity of the matrix by orders of magnitude, indicating that the MWCNT strongly participates in the electrical conduction mechanism. Also, the application of an external electric field to this lnC resulted in large changes in the optical transmittance, that were interpreted as a consequence of the fieldinduced MWCNT alignment into the liquid matrix. The characteristics of such a new category of nanocomposite in the liquid state suggest further studies.
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Stanciu, Nicoleta-Violeta, Felicia Stan, Ionut-Laurentiu Sandu, Catalin Fetecau i Adriana-Madalina Turcanu. "Thermal, Rheological, Mechanical, and Electrical Properties of Polypropylene/Multi-Walled Carbon Nanotube Nanocomposites". Polymers 13, nr 2 (7.01.2021): 187. http://dx.doi.org/10.3390/polym13020187.
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In this paper, nanocomposites based on polypropylene (PP) filled with up to 5 wt.% of multi-walled carbon nanotubes (MWCNTs) were investigated for determining the material property data used in numerical simulation of manufacturing processes such as the injection molding and extrusion. PP/MWCNT nanocomposite pellets were characterized for rheological behavior, crystallinity, specific volume and thermal conductivity, while injection-molded samples were characterized for mechanical and electrical properties. The addition of MWCNTs does not significantly change the melting and crystallization behavior of the PP/MWCNT nanocomposites. The effect of MWCNTs on melt shear viscosity is more pronounced at low shear rates and MWCNT loadings of 1–5 wt.%. However, with the addition of up to 5 wt.% of MWCNTs, the PP/MWCNT nanocomposite still behaves like a non-Newtonian fluid. The specific volume of the PP/MWCNT nanocomposites decreases with increasing MWCNT loading, especially in the MWCNT range of 1–5 wt.%, indicating better dimensional stability. The thermal conductivity, depending on the pressure, MWCNT wt.% and temperature, did not exceed 0.35 W/m·K. The PP/MWCNT nanocomposite is electrical non-conductive up to 3 wt.%, whereas after the percolating path is created, the nanocomposite with 5 wt.% becomes semi-conductive with an electrical conductivity of 10−1 S/m. The tensile modulus, tensile strength and stress at break increase with increasing MWCNT loading, whereas the elongation at break significantly decreases with increasing MWCNT loading. The Cross and modified 2-domain Tait models are suitable for predicting the melt shear viscosity and specific volume as a function of MWCNTs, respectively. These results enable users to integrate the PP/MWCNT nanocomposites into computer aided engineering analysis.
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Sultan, Adil, Sharique Ahmad i Faiz Mohammad. "Synthesis, Characterization and Electrical Properties of Polypyrrole/ Zirconia Nanocomposite and its Application as Ethene Gas Sensor". Polymers and Polymer Composites 25, nr 9 (listopad 2017): 695–704. http://dx.doi.org/10.1177/096739111702500908.
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In this communication, we report the synthesis of polypyrrole (PPy) and polypyrrole/zirconia (PPy/ZrO2) nanocomposites by an in-situ chemical polymerisation method and their application as sensor for detection of ethene gas for the first time. The as-prepared PPy and PPy/ZrO2 nanocomposites were characterised by Fourier-transform infrared spectroscopy, thermogravimetric analysis, x-ray diffraction and scanning electron microscopy. The nanocomposite containing 20 wt.% of ZrO2 was found to possess higher DC (direct current) electrical conductivity than PPy and the other PPy/ZrO2 nanocomposites. Sensing response was calculated on the basis of change in DC electrical conductivity. The most conductive nanocomposite was found to be highly sensitive and reversible to ethene gas. This study indicates an effective approach to possible future sensing technology for the detection of ethene gas.
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Mostaani, F., M. R. Moghbeli i H. Karimian. "Electrical conductivity, aging behavior, and electromagnetic interference (EMI) shielding properties of polyaniline/MWCNT nanocomposites". Journal of Thermoplastic Composite Materials 31, nr 10 (1.11.2017): 1393–415. http://dx.doi.org/10.1177/0892705717738294.
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Electrically conducting polyaniline/multiwalled carbon nanotubes (PANi/MWCNTs) nanocomposites were successfully synthesized via chemical oxidative polymerization. For this purpose, PANi was first prepared in an aqueous acidic medium, hydrochloric acid (HCl), at various temperatures to determine the proper polymerization temperature and to prepare the polymer with the highest electrical conductivity. For nanocomposite preparation, the polymerization of aniline (ANi) was carried out in the presence of various amounts of MWCNTs dispersed using a proper surfactant. The effect of HCl and MWCNT contents on the conductivity of the resultant composites was investigated. The results showed that the conductivity was monotonically increased with increasing the MWCNT and HCl levels. In addition, the effect of anionic and cationic surfactant type, sodium dodecyl sulfate (SDS) and cetyltrimethylammonium bromide (CTAB), on the conductivity and morphology of the resulting nanocomposites, was studied. Fourier transform infrared (FT-IR) spectroscopy, Raman spectroscopy, two- and four-point resistivity measuring methods, and field emission scanning electron microscopy (FESEM) were used to characterize the neat PANi and PANi/MWCNT nanocomposites. The conductivity variation of the conducting polymers versus elapsed time was investigated to determine the intensity and dominant aging mechanism. Electromagnetic shielding properties of the conducting nanocomposites were also studied. The results indicated that the nanocomposite with the highest MWCNTs level absorbed more than 83% of the incident electromagnetic waves.
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NOH, HYUN-JI, SUNG-PILL NAM, SUNG-GAP LEE, BYEONG-LIB AHN, WOO-SIK WON, HYOUNG-GWAN WOO i SANG-MAN PARK. "ELECTRICAL AND MECHANICAL CHARACTERISTICS OF EPOXY-NANOCLAY COMPOSITE". Modern Physics Letters B 23, nr 31n32 (30.12.2009): 3925–30. http://dx.doi.org/10.1142/s0217984909022010.
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In this study, we investigated the effects of nanoclay additives on the electrical and mechanical properties of diglycidyl ether of bisphenol A (DGEBA) epoxy resin. Epoxy-clay nanocomposites were synthesized using organically modified two montmorillonite clays (MMT) with different interlamellar spacing (31.5 Å and 18.5 Å). The electrical and mechanical properties of epoxy-clay nanocopomosites were measured with variation of the amount and type of clay. The nanocomposites were found to be homogenous materials although the nanocomposites still have clay aggregates with increasing nanoclay contents. The dielectric constant showed between 3.2 ~ 3.5 and the dielectric loss showed between 3.2 ~ 5.7% in all nanocoposites. The dielectric strength and tensile strength of the 5 wt% Cloisite 15A added epoxy-oclay nanocomposite were 23.9 kV/mm and 86.7 MPa, respectively.
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Al-Saleh, Mohammed H., i Mohammad R. Irshidat. "Effect of viscosity reducing agent on the properties of CNT/epoxy nanocomposites". Journal of Polymer Engineering 36, nr 4 (1.05.2016): 407–12. http://dx.doi.org/10.1515/polyeng-2015-0245.
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Abstract Epoxy nanocomposites that are produced in a solvent-free environment suffer from the inadequate dispersion of nanofiller and poor interfacial interaction between the nanofiller and polymer matrix. In this work, the effect of replacing a portion of the epoxy resin with a viscosity reducing agent (VRA) on the structure, electrical and mechanical properties of carbon nanotube (CNT)/epoxy nanocomposite have been investigated. Optical microscopy (OM) and transmission electron microscopy (TEM) were used to characterize the structure of the nanocomposite at the microscale and nanoscale, respectively. For nanocomposites without VRA, it was found that the addition of CNT degrades the tensile strength and toughness; meanwhile, it enhances the flexural modulus, Young’s modulus and electrical conductivity of the nanocomposite. However, the addition of VRA retained the tensile strength of the epoxy system and maintained the improvements in flexural strength and electrical conductivity that have been achieved due to CNT addition.
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Chandra, R. B. Jagadeesh, B. Shivamurthy, M. Sathish Kumar, Niranjan N. Prabhu i Devansh Sharma. "Mechanical and Electrical Properties and Electromagnetic-Wave-Shielding Effectiveness of Graphene-Nanoplatelet-Reinforced Acrylonitrile Butadiene Styrene Nanocomposites". Journal of Composites Science 7, nr 3 (14.03.2023): 117. http://dx.doi.org/10.3390/jcs7030117.
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Polymer nanocomposites have attracted global attention as a metal replacement for electrical and electronic applications. Graphene nanoplatelets (GNPs) are widely used as a nanoreinforcement to enhance the functional and structural properties of thermoset and thermoplastic polymers. In the present study, ABS nanocomposites were prepared by reinforcing 3–15 wt.% GNPs in steps of 3 wt.%. The neat ABS and ABS+GNP nanocomposite specimens for the mechanical test were prepared using injection molding, followed by extrusion, as per American Society for Testing and Materials (ASTM) standards. It was found that the modulus of ABS improved due to the reinforcement of GNPs. Additionally, we noticed higher thermal stability of nanocomposites due to the faster heat-conducting path developed in the nanocomposites by the presence of GNPs. However, observed agglomeration of GNPs at higher concentrations and poor wetting with ABS led to the deterioration of the mechanical properties of the nanocomposites. Moreover, 350 µm thick nanocomposite films were manufactured by compression molding, followed by the extrusion method, and we investigated their electrical conductivity, magnetic permeability, permittivity, and electromagnetic-wave-shielding effectiveness. The developed nanocomposites showed improved conductivity and effective electromagnetic wave shielding by absorption. The 15 wt.% GNP-reinforced ABS composite film showed a maximum shielding effectiveness of 30 dB in the X-band.
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Song, Jae Phil, Sung Ho Choi, Dae-Won Chung i Seong Jae Lee. "Latex-Based Polystyrene Nanocomposites with Non-Covalently Modified Carbon Nanotubes". Polymers 13, nr 7 (5.04.2021): 1168. http://dx.doi.org/10.3390/polym13071168.
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We prepared electrically conductive polystyrene (PS) nanocomposites by incorporating non-covalently surface-modified carbon nanotubes (CNTs) with hydrophilic polymers such as polydopamine (PDA) and poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS). Further, ethylene glycol (EG) was introduced as a second dopant to improve the electrical properties of the nanocomposites prepared with PEDOT:PSS-wrapped CNTs. All conductive PS nanocomposites were prepared through latex-based process, and the morphology and properties of the nanocomposites were investigated. The electrical properties of the nanocomposites with PEDOT:PSS-wrapped CNTs were better than those of the nanocomposites with PDA-coated CNTs owing to the conducting nature of PEDOT:PSS, although the dispersions of both types of modified CNTs in the PS matrix were excellent, as evidenced by morphology and rheology. In the case of PEDOT:PSS modification, the electrical properties of the nanocomposites with EG-doped PEDOT:PSS-wrapped CNTs were superior to those of the nanocomposites without EG treatment.
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Sánchez, Alejandro Gomez, Evgen Prokhorov, Gabriel Luna-Barcenas, Yuriy Kovalenko, Eric M. Rivera-Muñoz, Maria G. Raucci i Giovanna Buonocore. "Effect of Chemical Oxidation Routes on the Properties of Chitosan- MWCNT Nanocomposites". Current Nanoscience 15, nr 6 (11.10.2019): 618–25. http://dx.doi.org/10.2174/1573413714666181114105422.
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Background: Chitosan-multiwall carbon nanotubes (CS-MWCNTs) nanocomposites are an attractive material due to their biocompatibility and possibility to produce nanocomposites with high conductivities and high mechanical properties. Both electrical and mechanical properties depend upon the method of MWCNT chemical oxidation; this oxidation affects the interaction of CS side groups with MWCNT’s surface groups. However, in the literature, there are no reports on how different methods of MWCNT oxidation will affect the electrical and mechanical properties of related nanocomposites. Objective: The objective of this work is to probe CS-MWCNT nanocomposite’s electrical and mechanical properties by taking advantage of the presence of interfacial layer and its dependence on the methods of MWCNTs chemical oxidation routes. Methods: Nanocomposites are prepared with non-functionalized MWCNT and functionalized MWCNTs obtained by chemical oxidation treatments in HNO3 in H2SO4/NHO3 mixtures and commercially carboxyl-terminated MWCNTs, respectively. Properties of MWCNTs and nanocomposites were evaluated using SEM, FTIR, Raman, TGA, XRD, impedance and mechanical measurements. Results: It was shown that different chemical oxidation routes produce MWCNTs with a different number of carboxylic groups and defects which influence the interaction between MWCNTs with CS matrix and thickness of the interfacial layer between MWCNTs and CS matrix. Additionally, it was shown that the formation of the interfacial layer dominates on the dispersion of MWCNTs and affects on the electrical and mechanical percolation effects. Conclusion: It was shown that contrary to many studies previously reported, good dispersion of MWCNT does not guarantee obtained nanocomposites with the best electrical and mechanical properties.
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Zheng, Wenyue, Lulu Ren, Xuetong Zhao, Can Wang, Lijun Yang i Ruijin Liao. "Roles of Al2O3@ZrO2 Particles in Modulating Crystalline Morphology and Electrical Properties of P(VDF-HFP) Nanocomposites". Molecules 27, nr 13 (4.07.2022): 4289. http://dx.doi.org/10.3390/molecules27134289.
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Polymer materials with excellent physicochemical and electrical properties are desirable for energy storage applications in advanced electronics and power systems. Here, Al2O3@ZrO2 nanoparticles (A@Z) with a core-shell structure are synthesized and introduced to a P(VDF-HFP) matrix to fabricate P(VDF-HFP)/A@Z nanocomposite films. Experimental and simulation results confirm that A@Z nanoparticles increase the crystallinity and crystallization temperature owing to the effect of the refined crystal size. The incorporation of A@Z nanoparticles leads to conformational changes of molecular chains of P(VDF-HFP), which influences the dielectric relaxation and trap parameters of the nanocomposites. The calculated total trapped charges increase from 13.63 μC of the neat P(VDF-HFP) to 47.55 μC of P(VDF-HFP)/5 vol%-A@Z nanocomposite, indicating a substantial improvement in trap density. The modulated crystalline characteristic and interfaces between nanoparticles and polymer matrix are effective in inhibiting charge motion and impeding the electric conduction channels, which contributes to an improved electrical property and energy density of the nanocomposites. Specifically, a ~200% and ~31% enhancement in discharged energy density and breakdown strength are achieved in the P(VDF-HFP)/5 vol%-A@Z nanocomposite.
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Cuenca-Bracamonte, Quimberly, Mehrdad Yazdani-Pedram i Héctor Aguilar-Bolados. "Electrical Properties of Polyetherimide-Based Nanocomposites Filled with Reduced Graphene Oxide and Graphene Oxide-Barium Titanate-Based Hybrid Nanoparticles". Polymers 14, nr 20 (11.10.2022): 4266. http://dx.doi.org/10.3390/polym14204266.
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The electrical properties of nanocomposites based on polyetherimide (PEI) filled with reduced graphene oxide (rGO) and a graphene oxide hybrid material obtained from graphene oxide grafted with poly(monomethyl itaconate) (PMMI) modified with barium titanate nanoparticles (BTN) getting (GO-g-PMMI/BTN) were studied. The results indicated that the nanocomposite filled with GO-g-PMMI/BTN had almost the same electrical conductivity as PEI (1 × 10−11 S/cm). However, the nanocomposite containing 10 wt.% rGO and 10 wt.% GO-g-PMMI/BTN as fillers showed an electrical conductivity in the order of 1 × 10−7 S/cm. This electrical conductivity is higher than that obtained for nanocomposites filled with 10% rGO (1 × 10−8 S/cm). The combination of rGO and GO-g-PMMI/BTN as filler materials generates a synergistic effect within the polymeric matrix of the nanocomposite favoring the increase in the electrical conductivity of the system.
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Dul, Sithiprumnea, Alessandro Pegoretti i Luca Fambri. "Effects of the Nanofillers on Physical Properties of Acrylonitrile-Butadiene-Styrene Nanocomposites: Comparison of Graphene Nanoplatelets and Multiwall Carbon Nanotubes". Nanomaterials 8, nr 9 (29.08.2018): 674. http://dx.doi.org/10.3390/nano8090674.
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The effects of carbonaceous nanoparticles, such as graphene (GNP) and multiwall carbon nanotube (CNT) on the mechanical and electrical properties of acrylonitrile–butadiene–styrene (ABS) nanocomposites have been investigated. Samples with various filler loadings were produced by solvent free process. Composites ABS/GNP showed higher stiffness, better creep stability and processability, but slightly lower tensile strength and electrical properties (low conductivity) when compared with ABS/CNT nanocomposites. Tensile modulus, tensile strength and creep stability of the nanocomposite, with 6 wt % of GNP, were increased by 47%, 1% and 42%, respectively, while analogous ABS/CNT nanocomposite showed respective values of 23%, 12% and 20%. The electrical percolation threshold was achieved at 7.3 wt % for GNP and 0.9 wt % for CNT. The peculiar behaviour of conductive CNT nanocomposites was also evidenced by the observation of the Joule’s effect after application of voltages of 12 and 24 V. Moreover, comparative parameters encompassing stiffness, melt flow and resistivity were proposed for a comprehensive evaluation of the effects of the fillers.
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AlFannakh, Huda, S. S. Arafat i S. S. Ibrahim. "Synthesis, electrical properties, and kinetic thermal analysis of polyaniline/ polyvinyl alcohol - magnetite nanocomposites film". Science and Engineering of Composite Materials 26, nr 1 (28.01.2019): 347–59. http://dx.doi.org/10.1515/secm-2019-0020.
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AbstractPolyaniline-poly vinyl alcohol (PANI-PVA) conducting blends containing 15 wt% aniline were synthesized by in situ polymerization of aniline. Three-phase polymer blended nanocomposites with different contents of magnetite (5, 10 and 15 wt.%) were also synthesized. We measured the current-voltage (I-V) curves for the conducting blend and its magnetite nanocomposite. We also measured their thermal stability, and performed kinetic analysis through thermogravimetric analysis. We observed that the three phase nanocomposites showed enhanced electrical conductivity compared with that of the conductive blend, and no electrical hysteresis. The PVA/PANi blend was more stable above 350∘C and the addition of Fe3O4 enhanced the thermal stability of the conductive blend. The apparent activation energy of the three phase nanocomposites was greater than those of both the pure PVA and PVA/PANi samples. These results suggest that such three phase nanocomposites could be used in a range of applications.
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Doagou-Rad, Saeed, Aminul Islam i Jakob Søndergaard Jensen. "Correlation of mechanical and electrical properties with processing variables in MWCNT reinforced thermoplastic nanocomposites". Journal of Composite Materials 52, nr 26 (4.04.2018): 3681–97. http://dx.doi.org/10.1177/0021998318768390.
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The influence of the processing variables and nanotube content on the mechanical and electrical properties of polyamide 6,6-based nanocomposites reinforced with multi-walled carbon nanotubes is investigated. Results show that variation in the processing variables such as compounding method, injection melt temperature, injection speed, mold temperature, and holding pressure varies the properties significantly. In fact, composites containing similar contents of the nanofillers show variations in mechanical properties up to 30.0% and in the electrical properties up to three orders of magnitude. Different processing parameters required for achieving optimal mechanical and electrical performances are also found. Correlation between processing parameters and microstructure within the nanocomposites is studied. Results show that variation of the processing parameters defines the existence or absence of a nanotube network in the nanocomposite structure. Experimental and micromechanical modeling results show that less control over the nanocomposite morphology and nanotube alignment is achievable in higher nanofiller contents. The underlying mechanisms responsible for the modulation in the properties are also discussed using scanning and transmission electron microscopy, rheological and crystallization investigations. The research provides a recipe to manufacture the tailored nanocomposite with the specified properties for various industrial applications.
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Darabi, Marjan, i Masoud Rajabi. "Synthesis of Cu-CNTs nanocomposites via double pressing double sintering method". Metallurgical and Materials Engineering 23, nr 4 (9.01.2018): 319–34. http://dx.doi.org/10.30544/244319.
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In this research, copper (Cu)-carbon nanotubes (CNTs) nanocomposites were synthesized with different weight percentages of CNTs by double pressing double sintering (DPDS) method as well as conventional sintering method. A planetary ball mill was used to disperse CNTs in Cu matrix. The milled powders were first cold pressed to 450 MPa in a uniaxial stainless-steel die with cylindrical compacts (diameter: 12 mm and height: 5 mm). The effect of CNTs content and the DPDS method on the properties of the nanocomposites were investigated. The microstructure and phase analysis of Cu-CNTs nanocomposite samples were studied by FESEM and X-Ray Diffraction. The electrical conductivity of nanocomposites was measured and compared to both sintering methods. Mechanical properties of Cu-CNTs nanocomposites were characterized using bending strength and micro-hardness measurements. Enhancements of about 32% in bending strength, 31.6% in hardness and 19.5% in electrical conductivity of Cu-1 wt.% CNTs nanocomposite synthesized by DPDS method were observed as compared to Cu-1 wt.% CNTs nanocomposites fabricated under the similar condition by a conventional sintering process.
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Sun, Lan-Hui, Zoubeida Ounaies, Xin-Lin Gao, Casey A. Whalen i Zhen-Guo Yang. "Preparation, Characterization, and Modeling of Carbon Nanofiber/Epoxy Nanocomposites". Journal of Nanomaterials 2011 (2011): 1–8. http://dx.doi.org/10.1155/2011/307589.
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There is a lack of systematic investigations on both mechanical and electrical properties of carbon nanofiber (CNF)-reinforced epoxy matrix nanocomposites. In this paper, an in-depth study of both static and dynamic mechanical behaviors and electrical properties of CNF/epoxy nanocomposites with various contents of CNFs is provided. A modified Halpin-Tsai equation is used to evaluate the Young's modulus and storage modulus of the nanocomposites. The values of Young's modulus predicted using this method account for the effect of the CNF agglomeration and fit well with those obtained experimentally. The results show that the highest tensile strength is found in the epoxy nanocomposite with a 1.0 wt% CNFs. The alternate-current (AC) electrical properties of the CNF/epoxy nanocomposites exhibit a typical insulator-conductor transition. The conductivity increases by four orders of magnitude with the addition of 0.1 wt% (0.058 vol%) CNFs and by ten orders of magnitude for nanocomposites with CNF volume fractions higher than 1.0 wt% (0.578 vol%). The percolation threshold (i.e., the critical CNF volume fraction) is found to be at 0.057 vol%.
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Akhtarian, Shiva, Hadi Veladi i Sajedeh Mohammadi Aref. "Fabrication and characterization of conductive poly(dimethylsiloxane)-carbon nanotube nanocomposites for potential microsensor applications". Sensor Review 39, nr 1 (21.01.2019): 1–9. http://dx.doi.org/10.1108/sr-04-2017-0055.
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PurposeThe purpose of the study is to explore the potential possibility of using the conductive and piezoresistive nanocomposites that consist of insulating poly(dimethylsiloxane), a very popular silicone polymer, and the amazing properties of carbon nanotubes (CNT) in sensing applications. This nanocomposite is prepared by an optimized process to achieve a high-quality nanocomposite with uniform properties.Design/methodology/approachThe optimized process achieved in this study to provide PDMS/CNT nanocomposite includes the appropriate use of ultrasonic bath, magnetic stirrer, molding and curing in certain circumstances that results in obtaining high-quality nanocomposite with uniform properties. Experiments to characterize the influence of some factors such as pressure, temperature and the impact of CNT’s concentration on the electrical properties of the prepared nanocomposite have been designed and carried out.FindingsThe obtained preparing method of this nanocomposite is found to have better homogeneity in comparison to other methods for CNT/PDMS nanocomposite. This nanocomposite has both desirable properties of the PDMS elastomer and the additional conductive CNT, and it can be used to create all-polymer systems. Furthermore, the conductivity values of these nanocomposites can be changed by varying some factors such as temperature and pressure, so that those can be used in temperature- and pressure-sensoring applications.Originality/valueIn the present research, a convenient, inexpensive and reproducible method for preparing CNT/PDMS nanocomposite was investigated. These nanocomposites with the unique properties of both PDMS elastomer and CNTs and also with high electrical conductivity, piezoresistive properties and temperature dependent resistivity can be used in different sensoring applications.
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Bouchard, Jonas, Aurélie Cayla, Vincent Lutz, Christine Campagne i Eric Devaux. "Electrical and mechanical properties of phenoxy/multiwalled carbon nanotubes multifilament yarn processed by melt spinning". Textile Research Journal 82, nr 20 (26.06.2012): 2106–15. http://dx.doi.org/10.1177/0040517512450760.
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Nanocomposites based on Poly ((hydroxy ether) of bisphenol A) (Phenoxy) filled with multiwalled carbon nanotubes has been prepared by extrusion. Rheological behaviour and thermal degradation of these nanocomposites have been studied by melt flow index and thermogravimetric analysis. The results show that the addition of carbon nanotubes up to 2wt% increases the viscosity but does not modify significantly the spinnability of the compounds. Moreover, incorporation of these nanofillers allows an improvement of the thermal decomposition. In a second step, these nanocomposites have been processed by melt spinning to produce multifilament yarn. Transmission electron microscopy observations have been done to study carbon nanotubes dispersion and orientation. Nanocomposite morphology correlated with electrical measurements reveal an electrical percolation around 1.5 wt.% without decreasing significantly mechanical properties.
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Kandulna, R., U. Das, Ms Rimpi, B. Kachhap i N. Prasad. "Hybrid Polymeric Nanocomposites Based High Performance Oleds: A Review". Shodh Sankalp Journal 1, nr 3 (1.09.2021): 16–34. http://dx.doi.org/10.54051/shodh.2021.1.3.1.
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This review reports the recent significant progress for achieving the synthesis of various types of polymer-based nanocomposites and understanding of the basic principle which determine their optical, electronic and magnetic properties. Some of the polymeric nanocomposite materials show remarkable electrical as well as optical properties regarding towards interest for applications in OLEDs. Nanoparticles which are basically inorganic, plays important role in the opto-electronic field. A nanoparticle with conjugate polymer matrix makes polymer nanocomposite and that nanocomposite used as an active emissive layer between the structures of optoelectronic device like OLEDs, OPVs etc. Application of such polymeric nanocomposite materials are discussed in this present communication with their success and failure, towards their optical as well as electrical properties in the fabrication of OLEDs.
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Izzati, Wan Akmal, Yanuar Z. Arief, Zuraimy Adzis i Mohd Shafanizam. "Partial Discharge Characteristics of Polymer Nanocomposite Materials in Electrical Insulation: A Review of Sample Preparation Techniques, Analysis Methods, Potential Applications, and Future Trends". Scientific World Journal 2014 (2014): 1–14. http://dx.doi.org/10.1155/2014/735070.
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Polymer nanocomposites have recently been attracting attention among researchers in electrical insulating applications from energy storage to power delivery. However, partial discharge has always been a predecessor to major faults and problems in this field. In addition, there is a lot more to explore, as neither the partial discharge characteristic in nanocomposites nor their electrical properties are clearly understood. By adding a small amount of weight percentage (wt%) of nanofillers, the physical, mechanical, and electrical properties of polymers can be greatly enhanced. For instance, nanofillers in nanocomposites such as silica (SiO2), alumina (Al2O3) and titania (TiO2) play a big role in providing a good approach to increasing the dielectric breakdown strength and partial discharge resistance of nanocomposites. Such polymer nanocomposites will be reviewed thoroughly in this paper, with the different experimental and analytical techniques used in previous studies. This paper also provides an academic review about partial discharge in polymer nanocomposites used as electrical insulating material from previous research, covering aspects of preparation, characteristics of the nanocomposite based on experimental works, application in power systems, methods and techniques of experiment and analysis, and future trends.
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Min, Daomin, Chenyu Yan, Rui Mi, Chao Ma, Yin Huang, Shengtao Li, Qingzhou Wu i Zhaoliang Xing. "Carrier Transport and Molecular Displacement Modulated dc Electrical Breakdown of Polypropylene Nanocomposites". Polymers 10, nr 11 (30.10.2018): 1207. http://dx.doi.org/10.3390/polym10111207.
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Dielectric energy storage capacitors have advantages such as ultra-high power density, extremely fast charge and discharge speed, long service lifespan and are significant for pulsed power system, smart power grid, and power electronics. Polypropylene (PP) is one of the most widely used dielectric materials for dielectric energy storage capacitors. It is of interest to investigate how to improve its electrical breakdown strength by nanodoping and the influencing mechanism of nanodoping on the electrical breakdown properties of polymer nanocomposites. PP/Al2O3 nanocomposite dielectric materials with various weight fraction of nanoparticles are fabricated by melt-blending and hot-pressing methods. Thermally stimulated current, surface potential decay, and dc electrical breakdown experiments show that deep trap properties and associated molecular chain motion are changed by incorporating nanofillers into polymer matrix, resulting in the variations in conductivity and dc electrical breakdown field of nanocomposite dielectrics. Then, a charge transport and molecular displacement modulated electrical breakdown model is utilized to simulate the dc electrical breakdown behavior. It is found that isolated interfacial regions formed in nanocomposite dielectrics at relatively low loadings reduce the effective carrier mobility and strengthen the interaction between molecular chains, hindering the transport of charges and the displacement of molecular chains with occupied deep traps. Accordingly, the electrical breakdown strength is enhanced at relatively low loadings. Interfacial regions may overlap in nanocomposite dielectrics at relatively high loadings so that the effective carrier mobility decreases and the interaction between molecular chains may be weakened. Consequently, the molecular motion is accelerated by electric force, leading to the decrease in electrical breakdown strength. The experiments and simulations reveals that the influence of nanodoping on dc electrical breakdown properties may origin from the changes in the charge transport and molecular displacement characteristics caused by interfacial regions in nanocomposite dielectrics.
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Okolo, Chinyere, Rafaila Rafique, Sadia Sagar Iqbal, Tayyab Subhani, Mohd Shahneel Saharudin, Badekai Ramachandra Bhat i Fawad Inam. "Customizable Ceramic Nanocomposites Using Carbon Nanotubes". Molecules 24, nr 17 (1.09.2019): 3176. http://dx.doi.org/10.3390/molecules24173176.
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A novel tweakable nanocomposite was prepared by spark plasma sintering followed by systematic oxidation of carbon nanotube (CNT) molecules to produce alumina/carbon nanotube nanocomposites with surface porosities. The mechanical properties (flexural strength and fracture toughness), surface area, and electrical conductivities were characterized and compared. The nanocomposites were extensively analyzed by field emission scanning electron microscopy (FE-SEM) for 2D qualitative surface morphological analysis. Adding CNTs in ceramic matrices and then systematically oxidizing them, without substantial reduction in densification, induces significant capability to achieve desirable/application oriented balance between mechanical, electrical, and catalytic properties of these ceramic nanocomposites. This novel strategy, upon further development, opens new level of opportunities for real-world/industrial applications of these relatively novel engineering materials.
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Bugaev, N. M., Ekaterina L. Kuznetsova i Kyaw Ye Ko. "Thermophysical and Magnetic Properties of Magnetite – Polyethylene Composite". International Journal of Mechanics 15 (9.09.2021): 165–71. http://dx.doi.org/10.46300/9104.2021.15.19.
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In this work, it is shown that the advantage of using matrix-stabilized magnetic nanoparticles to obtain polymer nanocomposites based on them is that such nanoparticles retain their dispersion and stability of size and shape in the technological modes of obtaining polymer nanocomposite materials, and thus ensured stable ferro- and superparamagnetic properties of the obtained target products. For the production of films by the method of hot pressing from blanks obtained in an injection molding machine or a mechanochemical mixture, a manual electrically heated hydraulic press was used. The magnetic properties of nanocomposite samples (about 50 mg on average) were studied using a vibration magnetometer. The character of the dependence of the magnetization on the magnitude of the magnetic field confirms the ferromagnetic character of the behavior of the obtained nanocomposites. The resulting film nanocomposites exhibit ferromagnetic properties at room temperature.
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Vidakis, Nectarios, Markos Petousis, Lazaros Tzounis, Emmanuel Velidakis, Nikolaos Mountakis i Sotirios A. Grammatikos. "Polyamide 12/Multiwalled Carbon Nanotube and Carbon Black Nanocomposites Manufactured by 3D Printing Fused Filament Fabrication: A Comparison of the Electrical, Thermoelectric, and Mechanical Properties". C 7, nr 2 (23.04.2021): 38. http://dx.doi.org/10.3390/c7020038.
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In this study, nanocomposites with polyamide 12 (PA12) as the polymer matrix and multiwalled carbon nanotubes (MWCNTs) and carbon black (CB) at different loadings (2.5, 5.0, and 10.0 wt.%) as fillers, were produced in 3D printing filament form by melt mixing extrusion process. The filament was then used to build specimens with the fused filament fabrication (FFF) three-dimensional (3D) printing process. The aim was to produce by FFF 3D printing, electrically conductive and thermoelectric functional specimens with enhanced mechanical properties. All nanocomposites’ samples were electrically conductive at filler loadings above the electrical percolation threshold. The highest thermoelectric performance was obtained for the PA12/CNT nanocomposite at 10.0 wt.%. The static tensile and flexural mechanical properties, as well as the Charpy’s impact and Vickers microhardness, were determined. The highest improvement in mechanical properties was observed for the PA12/CNT nanocomposites at 5.0 wt.% filler loading. The fracture mechanisms were identified by fractographic analyses of scanning electron microscopy (SEM) images acquired from fractured surfaces of tensile tested specimens. The nanocomposites produced could find a variety of applications such as; 3D-printed organic thermoelectric materials for plausible large-scale thermal energy harvesting applications, resistors for flexible circuitry, and piezoresistive sensors for strain sensing.
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Wang, Yongkun, Tianran Ma, Wenchao Tian, Junjue Ye, Xing Wang i Xiangjun Jiang. "Electroactive shape memory properties of graphene/epoxy-cyanate ester nanocomposites". Pigment & Resin Technology 47, nr 1 (2.01.2018): 72–78. http://dx.doi.org/10.1108/prt-04-2017-0037.
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Purpose The purpose of this paper is to prepare novel electroactive shape memory nanocomposites based on graphene and study the thermomechanical property and shape memory behavior of nanocomposites. Design/methodology/approach Graphene was dispersed in N,N-dimethylformamide, and the mixture was spooned into epoxy-cyanate ester mixtures to form graphene/epoxy-cyanate ester nanocomposites. The nanocomposites were deformed under 150°C, and shape recovery test was conducted under an electric voltage of 20-100 V. Findings Graphene is used to improve the shape recovery behavior and performance of shape-memory polymers (SMPs) for enhanced electrical actuation effectiveness. With increment of graphene content, the shape recovery speed of nanocomposites increases significantly. Research limitations/implications A simple way for fabricating electro-activated SMP nanocomposites has been developed by using graphene. Originality/value The outcome of this study will help to fabricate the SMP nanocomposites with high electrical actuation effectiveness and improve the shape recovery speed of the nanocomposites.
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Loughney, Patricia A., Shakir B. Mujib, Timothy L. Pruyn, Gurpreet Singh, Kathy Lu i Vicky Doan-Nguyen. "Enhancing organosilicon polymer-derived ceramic properties". Journal of Applied Physics 132, nr 7 (21.08.2022): 070901. http://dx.doi.org/10.1063/5.0085844.
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Polymer-derived ceramic (PDC) nanocomposites enable access to a large library of functional properties starting from molecular design and incorporating nanofillers. Tailoring preceramic polymer (PCP) chemistry and nanofiller size and morphology can lead to usage of the nanocomposites in complex shapes and coatings with enhanced thermal and mechanical properties. A rational design of targeted nanocomposites requires an understanding of fundamental structure–property–performance relations. Thus, we tailor our discussions of PCP design and nanofiller integration into single source precursors as well as pyrolytic processing for functionalizing PDCs. We also discuss the promises and limitations of advanced characterization techniques such as 4D transmission electron microscopy and pair distribution functions to enable in situ mapping structural evolution. The feedback loop of in situ monitoring sets the foundation for enabling accelerated materials discovery with artificial intelligence. This perspective assesses the recent progress of PDC nanocomposite research nanocomposites and presents scientific and engineering challenges for synthesis, fabrication, processing, and advanced characterization of PDC nanocomposites for enhanced magnetic, electrical, and energy conversion and storage properties.
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Jin, Sung-Hun, i Dai-Soo Lee. "Electrical and Rheological Properties of Double Percolated Poly(methyl methacrylate)/Multiwalled Carbon Nanotube Nanocomposites". Journal of Nanoscience and Nanotechnology 7, nr 11 (1.11.2007): 3847–51. http://dx.doi.org/10.1166/jnn.2007.058.
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Electrical and rheological properties of nanocomposites based on poly(methyl methacrylate) (PMMA) and multiwalled carbon nanotube (MWCNT) were studied from view points of double percolation by adding crosslinked methyl methacrylate-butadiene-styrene (MBS) copolymer particles to lower percolation threshold concentration of MWCNTs. It was found that the critical concentrations of MWCNTs for the percolation in the nanocomposites decrease and then increase with increasing the MBS contents of the nanocomposites. It is postulated that the addition of MBS at low concentrations results in double percolation of MWCNT and the significant decrease of critical concentration for the percolations. However, adding MBS particles in large amounts results in limited space for the distribution of MWCNTs and less efficient dispersion of the MWCNTs and the increase of the critical concentrations of MWCNTs for the percolations. Rheological properties and change of Tgs reflect large interfacial areas in the well dispersed nanocomposite and were also interpreted to support the speculations for the effects of MBS contents and MWCNT concentrations of PMMA/MWCNT nanocomposites.
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Yoo, S. H., J. K. Yang, Sung Tag Oh, Kae Myung Kang, Sung Goon Kang, C. J. Lee i Yong Ho Choa. "The Synthesis and Characteristics of Homogenously Dispersed CNT-Al2O3 Nanocomposites by the Thermal CVD Method and Pulsed Electric Current Sintering Process". Solid State Phenomena 121-123 (marzec 2007): 295–98. http://dx.doi.org/10.4028/www.scientific.net/ssp.121-123.295.
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An optimum route to synthesize Al2O3-based composite powders with a homogeneous dispersion of carbon nanotubes (CNTs) was investigated. CNT/Metal/Al2O3 nanocomposite powders were fabricated by thermal chemical vapor deposition (CVD) over a metal catalyst homogeneously dispersed into an Al2O3 matrix by the means of chemical and selective reduction processes. The nanocomposite powders were densified by Pulse Electric Current Sintering (PECS). The experimental results show that the CNT/Metal/Al2O3 nanocomposites have unique electrical properties.
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Pattanshetti, Virappa Virupaxappa, G. M. Shashidhara i Mysore Guruswamy Veena. "Dielectric and thermal properties of magnesium oxide/poly(aryl ether ketone) nanocomposites". Science and Engineering of Composite Materials 25, nr 5 (25.09.2018): 915–25. http://dx.doi.org/10.1515/secm-2016-0273.
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AbstractIn the present study, dielectric and thermal properties of poly(aryl ether ketone) (PAEK)-nanocomposites with varying weight percentage of magnesium oxide (MgO) have been reported. The thermal properties of PAEK/MgO nanocomposites were studied using differential scanning calorimetry, thermogravimetric analysis, thermo-mechanical analysis and thermal conductivity. Transmission electron microscopy of the developed nanocomposites shows agglomerate-free dispersion of MgO nanoparticles in PAEK matrix. From the dielectric properties, dielectric constant of 13 was achieved for 10 wt% PAEK/MgO nanocomposite at 230°C. Further, minimum tan δ and maximum volume resistivity were found for 10 wt% PAEK/MgO nanocomposite. Data from thermal studies indicate that the incorporation of MgO into PAEK significantly enhanced the glass transition temperature and slightly deteriorated the thermal stability, char yield, and flame-retardant properties. Also, highest thermal conductivity and lowest coefficient of thermal expansion were achieved at 10 wt% of the MgO content. An excellent combination of both dielectric and thermal properties of the PAEK/MgO nanocomposites developed in the present study finds its potential application in microelectronics and electrical insulation in power equipments.
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Praharaj, Ankita Pritam, Dibakar Behera, Tapan Kumar Bastia i Arun Kumar Rout. "BisGMA/EPDM/amine functionalised MWCNTs based nanocomposites". Pigment & Resin Technology 44, nr 5 (7.09.2015): 266–75. http://dx.doi.org/10.1108/prt-10-2014-0094.
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Purpose – This paper aims to focus on the development and study properties of bisphenol-A glycidyldimethacrylate (BisGMA) and ethylene–propylene–diene monomer (EPDM) blend-based nanocomposites containing amine-functionalised multi-walled carbon nanotubes (MWCNT-NH2) as a compatibiliser. Design/methodology/approach – First, BisGMA was synthesised from epoxy and methacrylic acid followed by the amine functionalisation of MWCNTs. A novel two-roll milling technique was then conducted to prepare nanocomposite specimens with MWCNT-NH2 as compatibiliser. Effect of MWCNT-NH2 content on the mechanical, thermal, electrical, corrosive and water absorption properties of the nanocomposites was investigated and results have been reported. Findings – The results of the present work reveal that MWCNT-NH2 acts as a potential compatibiliser and nanofiller in BisGMA/EPDM blend-based nanocomposites. The authors report here that the nanocomposites exhibit improved mechanical, thermal and electrical properties with increased addition of MWCNT-NH2. Moreover, desirable results are obtained at 5 phr of nanofiller loading beyond which the properties deteriorate due to particle agglomeration. The nanocomposites display negligible corrosion and water absorption characteristics. Thus, the above fabricated nanocomposites with optimum compatibiliser content can serve as low-cost structural, thermal and electrical materials which can also be utilised in corrosive and moist environments. Research limitations/implications – The present investigation has come up with the successful and cost-effective fabrication of BisGMA/EPDM blend-based nanocomposites with optimum nanofiller/compatibiliser (MWCNT-NH2) content that can be used for a wide range of structural, thermal and electrical projects, as it is corrosion and moisture resistant. It is also the most durable from the mechanical point of view. Originality/value – The above nanocomposites have never been designed before.
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Kasim, Hasan, Ahmad Naser Aldeen, Yücel Can i Murat Yazici. "Investigation of the Crack Propagation Behavior of the Multiwalled Carbon Nanotube/Graphite/Natural Rubber Hybrid Nanocomposites Using Digital Image Correlation Technique". Journal of Nanoelectronics and Optoelectronics 14, nr 12 (1.12.2019): 1766–70. http://dx.doi.org/10.1166/jno.2019.2675.
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In the presented study, a hybrid Natural Rubber (NR) based semiconductive nanocomposites was examined to obtain better electrical and mechanical properties. The hybrid nanocomposite produced by incorporation of the Multiwalled Carbon Nanotube (MWCNT) and graphite nanoparticles into the NR. The conventional curing additives also included in the compound. A functionalized MWCNT (1, 2 and 3 phr's) with 3 phr graphite quotas were studied to produce the NR nanocomposites. The MWCNT/Graphite and NR mixed homogeneously to advance the interfacial interaction with the matrix. The graphite nano-particulates added to obtain 3D electrical connectivity network in the hybrid nanocomposites by becoming bridging points between multiwalled carbon nanotubes. Nanocomposites were produced as 3 mm sheets in a steel mold by vulcanizing at 165 °C for 10 min under pressure. The single-edge notched tension specimens were subjected to estimate crack propagation and electrical resistance relation. Digital Image Correlation (DIC) technique was used to observe the crack resistivity function. The results evaluated to clarify the relationship between crack length, MWCNT filler ratio, and electrical conductivity properties. MWCNTs are generally preferred as the reinforcements for their very high aspect ratio and excellent specific surface area properties. However, the electrical conductivity of the nanocomposites is owing to the constitution of a continuous conductive 3D network of MWCNT and Graphite in the NR matrix.
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ABD RAZAK, SAIFUL IZWAN, SHARIF HUSSEIN SHARIF ZEIN i ABDUL LATIF AHMAD. "MnO2-FILLED MULTIWALLED CARBON NANOTUBE/POLYANILINE NANOCOMPOSITES: EFFECT OF LOADING ON THE CONDUCTION PROPERTIES AND ITS PERCOLATION THRESHOLD". Nano 06, nr 01 (luty 2011): 81–91. http://dx.doi.org/10.1142/s1793292011002378.
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This paper reports the synthesis and characterization of ternary nanocomposites consisting of polyaniline (PANI), multiwalled carbon nanotubes (MWCNTs) and manganese dioxide (MnO2) at different MWCNT– MnO2 loadings. The composite electrical percolation threshold is investigated as well. The in situ nanocomposites were characterized by UV-visible, Fourier transform and Raman spectroscopy, thermogravimetric analysis, field emission scanning electron microscopy, and electrical conductivity measurements. The conductivity of the nanocomposite reached up to 78.79 Scm-1 with 50 wt.% addition of MWCNT– MnO2 with good conduction stability and reversibility. The percolation threshold of this nanocomposite was achieved at 0.5 wt.%. Using the scaling law of the percolation theory, it was found that the theoretical conductivity of the nanocomposite exhibited an exponential factor, (t) of 1.38 instead of the universal t value of 2.
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Danikas, M., i S. Morsalin. "A Short Review on Polymer Nanocomposites for Enameled Wires: Possibilities and Perspectives". Engineering, Technology & Applied Science Research 9, nr 3 (8.06.2019): 4079–84. http://dx.doi.org/10.48084/etasr.2678.
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Polymer nanocomposites constitute a new generation of insulating materials, capable of offering better electrical, thermal and mechanical properties. Past research indicated that such materials may replace conventional polymers for a variety of industrial high voltage applications. In the present paper, polymer nanocomposites are investigated regarding the insulation of enameled wires. Possible nanocomposite candidates are discussed.
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Moheimani, Seyed Kiomars, Mehran Dadkhah, Mohammad Hossein Mosallanejad i Abdollah Saboori. "Fabrication and Characterization of the Modified EV31-Based Metal Matrix Nanocomposites". Metals 11, nr 1 (10.01.2021): 125. http://dx.doi.org/10.3390/met11010125.
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Metal matrix nanocomposites (MMNCs) with high specific strength have been of interest for numerous researchers. In the current study, Mg matrix nanocomposites reinforced with AlN nanoparticles were produced using the mechanical stirring-assisted casting method. Microstructure, hardness, physical, thermal and electrical properties of the produced composites were characterized in this work. According to the microstructural evaluations, the ceramic nanoparticles were uniformly dispersed within the matrix by applying a mechanical stirring. At higher AlN contents, however, some agglomerates were observed as a consequence of a particle-pushing mechanism during the solidification. Microhardness results showed a slight improvement in the mechanical strength of the nanocomposites following the addition of AlN nanoparticles. Interestingly, nanocomposite samples were featured with higher electrical and thermal conductivities, which can be attributed to the structural effect of nanoparticles within the matrix. Moreover, thermal expansion analysis of the nanocomposites indicated that the presence of nanoparticles lowered the Coefficient of Thermal Expansion (CTE) in the case of nanocomposites. All in all, this combination of properties, including high mechanical strength, thermal and electrical conductivity, together with low CTE, make these new nanocomposites very promising materials for electro packaging applications.