Rozprawy doktorskie na temat „Cyclophanes”
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Turner, Peter D. "Organic materials for nonlinear optics /". Title page, contents and abstract only, 1999. http://web4.library.adelaide.edu.au/theses/09PH/09pht951.pdf.
Pełny tekst źródłaRobbins, Steven Joseph, i University of Lethbridge Faculty of Arts and Science. "Cyclophanes from kinetically stabilized bis(isobenzofuran)s". Thesis, Lethbridge, Alta. : University of Lethbridge, Deptartment of Chemistry and Biochemistry, 2009, 2009. http://hdl.handle.net/10133/781.
Pełny tekst źródłaxxii, 122 leaves : ill. ; 29 cm.
Arifhodzic, Lejla. "Novel bis-quinolinium cyclophanes as SKca channel blockers". Thesis, University College London (University of London), 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.248484.
Pełny tekst źródłaRichard, Jimmy. "Cyclophanes de viologènes adressables pour stockage de charges". Thesis, Strasbourg, 2019. http://www.theses.fr/2019STRAF021.
Pełny tekst źródłaStoring data on a molecule is a fundamental challenge in developing a system that can store a large amount of data in a minimum of space. The project of this thesis is part of this theme, namely the design of molecular switches oscillating by redox stimuli and being readable without altering the different states to allow the creation of molecular memory. The bis-viologen cyclophanes are therefore potential candidates for the creation of information storage devices that could be reversibly written and read in many ways thanks to the magnetic, optical and conductive properties of the π-dimer. The first chapter of this thesis is devoted to an introduction to the chemistry of cyclophanes and the use of surfaces in the chemistry of cyclophanes and molecular switches. The second chapter deals with the synthesis of viologenes and bis-viologen cyclophanes. The third chapter is devoted to the synthesis of diazapyrenium-viologenes cyclophanes, possible alternatives for bis-viologen cyclophanes
Auffray, Morgan. "Cyclophanes, a bridge between photophysics and supramolecular chemistry". Thesis, Paris 6, 2017. http://www.theses.fr/2017PA066285/document.
Pełny tekst źródłaIn this work and due to their unique electronic properties, 3D-dithia[3.3]paracyclophane-based molecules have been studied for surface nanostructuration applications and as new fluorophore. First, the supramolecular self-assembly of molecules is used to create well-organised 2D-networks on conducting surfaces. However, the use of such substrates tends to quench any electronic properties of the adsorbed molecules. In this context, 3D-dithia[3.3]paracyclophane-based molecules were employed to lift up the active moiety from the surface. In this work, new pyridyl end-capped molecules were designed to self-assemble on any substrate. Preliminary characterisations were performed to study the supramolecular self-assembly of such molecules alone or with co-adsorbers, and the first images of organised 2D-networks on graphite and gold have been obtained by scanning probe microscopy. Second, the design of new and efficient emitter is a hot topic for the fabrication of OLED devices. A new type of compounds is currently investigated for their high electroluminescence efficiency due to thermally activated delayed fluorescence (TADF). This phenomenon is expected from molecules showing low electronic gap between singlet and triplet excited states, which is related to a low overlap of the HOMO and LUMO, localised on the electron-door and acceptor moieties of the molecule, respectively. In this sense, we propose a new design of donor-acceptor molecules where the HOMO (donor) and LUMO (acceptor) are separated by a cyclophane core. We synthesised a couple of emitters and their photophysics properties were studied in solution and in solid state
Auffray, Morgan. "Cyclophanes, a bridge between photophysics and supramolecular chemistry". Electronic Thesis or Diss., Paris 6, 2017. http://www.theses.fr/2017PA066285.
Pełny tekst źródłaIn this work and due to their unique electronic properties, 3D-dithia[3.3]paracyclophane-based molecules have been studied for surface nanostructuration applications and as new fluorophore. First, the supramolecular self-assembly of molecules is used to create well-organised 2D-networks on conducting surfaces. However, the use of such substrates tends to quench any electronic properties of the adsorbed molecules. In this context, 3D-dithia[3.3]paracyclophane-based molecules were employed to lift up the active moiety from the surface. In this work, new pyridyl end-capped molecules were designed to self-assemble on any substrate. Preliminary characterisations were performed to study the supramolecular self-assembly of such molecules alone or with co-adsorbers, and the first images of organised 2D-networks on graphite and gold have been obtained by scanning probe microscopy. Second, the design of new and efficient emitter is a hot topic for the fabrication of OLED devices. A new type of compounds is currently investigated for their high electroluminescence efficiency due to thermally activated delayed fluorescence (TADF). This phenomenon is expected from molecules showing low electronic gap between singlet and triplet excited states, which is related to a low overlap of the HOMO and LUMO, localised on the electron-door and acceptor moieties of the molecule, respectively. In this sense, we propose a new design of donor-acceptor molecules where the HOMO (donor) and LUMO (acceptor) are separated by a cyclophane core. We synthesised a couple of emitters and their photophysics properties were studied in solution and in solid state
Collins, Shawn K. "Design, synthesis, and applications of novel phenyl/acetylenic cyclophanes". Thesis, University of Ottawa (Canada), 2001. http://hdl.handle.net/10393/9015.
Pełny tekst źródłaHoughton, Tom J. "Synthesis and study of some novel and interesting cyclophanes". Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1999. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape7/PQDD_0023/NQ54838.pdf.
Pełny tekst źródłaMoody, T. S. "Switches based on crown ethers, cyclophanes and amino acids". Thesis, Queen's University Belfast, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.390876.
Pełny tekst źródłaBartlett, Stephen James. "Synthesis, conformational studies and biological activity of bisindolylmaleimide cyclophanes". Thesis, University of Leeds, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.424060.
Pełny tekst źródłaBogdan, Niculina Daniela. "Design, synthèse, analyse structurale et réactivité de nouveaux cyclophanes". Rouen, 2006. http://www.theses.fr/2006ROUES030.
Pełny tekst źródłaWe reported here the synthesis and the structural analysis of [7. 7]pyridinophanes, [4. 4]cyclophanes diethers and [4. 4]cyclophanes diesters which exhibit 1. 3-dioxanes rings and mono and di ketones. The structural analysis was carried out using X-ray diffractometry, NMR and mass spectrometry. These investigations revealed the conformational behaviour of the molecules. Due to their dynamics the [7. 7]cyclophanes and some of the [4. 4]cyclophanes were considered molecular rotors. The formation of supramolecular aggregates for some of the macrocycle compounds with molecules of solvent, the intra and intermolecular interactions (π-stacking, CH-π and C=O-π) and the formation of the channels which embed (or not) molecules of solvents was also revealed
Suman, Priya. "The inorganic and organometallic chemistry of paracyclophanes". Thesis, Imperial College London, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.299296.
Pełny tekst źródłaPainting, C. L. "Metallo-assembled supramolecular architectures". Thesis, University of Warwick, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.344047.
Pełny tekst źródłaDANSOU, AHOEFA BENEDICTE. "Recherches sur la synthese totale des 7. 0 metacyclophanes appartenant a la serie de la myricanone". Le Mans, 1999. http://www.theses.fr/1999LEMA1002.
Pełny tekst źródłaHeuft, Matthew A. "Design and synthesis of helical acetylenic carbo- and heterocyclic cyclophanes". Thesis, University of Ottawa (Canada), 2004. http://hdl.handle.net/10393/29113.
Pełny tekst źródłaFischer, Kristapher Edward, i University of Lethbridge Faculty of Arts and Science. "Synthesis and characterization of novel cyclophanes from 5,5'-bi(isobenzofuran)". Thesis, Lethbridge, Alta. : University of Lethbridge, Faculty of Arts and Science, 2005, 2005. http://hdl.handle.net/10133/255.
Pełny tekst źródłax, 119 leaves : ill. ; 29 cm.
Mackie, Philip Ross. "Cation chelating [2]catenanes and cyclophanes based on 2,2'-bipyridine". Thesis, University of Glasgow, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.266746.
Pełny tekst źródłaLe, Bras Nathalie. "Nouveaux cyclophanes et cryptands : synthese, etude des conformations, electro-reduction". Rennes 1, 1992. http://www.theses.fr/1992REN10137.
Pełny tekst źródłaSchicke, Olivier. "Complexes binucléaires de cuivre, modèles de métalloenzymes". Aix-Marseille 3, 2007. http://www.theses.fr/2007AIX30008.
Pełny tekst źródłaCopper monooxygenases involved in dioxygen metabolism, are important in numerous living systems. Dopamine β-monooxygenase (DBM) plays a major role in catecholamine biosynthesis, central and peripheral nervous system neurotransmitters. The mechanism of enzymatic action is not totally described, so many structural and functional models have been proposed. The aim of this thesis is to combine two chemistry's domains in order to prepare biomimetic models of DBM. These two domains are supramolecular chemistry, to mimic enzyme-substract complex, and inorganic chemistry, to synthesise analogous active sites. Two models combining a cyclophane-type hydrophobic pocket and a binuclear copper centre have been synthesised. Many intermediate and final products have been totally described (X-ray diffraction, IR, NMR. . . ), informing on conformation, space available, and intra- and intermolecular interactions in these compounds. Moreover an intermediate cyclophane was co-cristallised with a chloroform molecule inside the cavity. One of these binuclear models has been checked in phosphodiesters hydrolysis reaction. Despite an unexpected kinetic curve appearance (tensioactive effect of BNPP may increase active sites availability of complex 18) binuclear complex 18 showed a higher activity (5x) than a mononuclear copper complex (two equivalents). This higher activity can be explained either by hydrophobic interactions increasing the rate of reaction, or synergic effect of the two copper ions (binuclear structure) on hydrolysis
Haque, Rosenani S. M. Anwarul. "Silver, mercury and ruthenium complexes of N-heterocyclic carbene linked cyclophanes". University of Western Australia. Chemistry Discipline Group, 2008. http://theses.library.uwa.edu.au/adt-WU2008.0236.
Pełny tekst źródłaChoi, So-Young Amy. "Synthesis, properties, and asymmetric catalysis of chiral cyclophanes and their metal complexes". Connect to a 24 p. preview or request complete full text in PDF format. Access restricted to UC campuses, 2006. http://wwwlib.umi.com/cr/ucsd/fullcit?p3206584.
Pełny tekst źródłaTitle from first page of PDF file (viewed May 10, 2006). Available via ProQuest Digital Dissertations. Vita. Includes bibliographical references (p. 244-263).
Spenst, Peter [Verfasser], i Frank [Gutachter] Würthner. "Xylylene Bridged Perylene Bisimide Cyclophanes and Macrocycles / Peter Spenst ; Gutachter: Frank Würthner". Würzburg : Universität Würzburg, 2016. http://d-nb.info/1141054272/34.
Pełny tekst źródłaThibault, Michelle Elizabeth, i University of Lethbridge Faculty of Arts and Science. "Novel bis(isobenzofuran)s and their utility in the synthesis of cyclophanes". Thesis, Lethbridge, Alta. : University of Lethbridge, Faculty of Arts and Science, 2003, 2003. http://hdl.handle.net/10133/239.
Pełny tekst źródłax, 122 leaves : ill. ; 28 cm.
Rotzler, Jürgen [Verfasser]. "Tailoring Intra- and Intermolecular Properties: From Cyclophanes to Daisy Chains / Jürgen Rotzler". München : Verlag Dr. Hut, 2012. http://d-nb.info/1023435365/34.
Pełny tekst źródłaChristensen, Christian Ausig. "Redox active cyclophanes and donor-acceptor systems from new TTFAQ building blocks". Thesis, Durham University, 2002. http://etheses.dur.ac.uk/3880/.
Pełny tekst źródłaSchooler, Paul. "Linked arene clusters : the interaction of transition metal clusters with the cyclophanes". Thesis, University of Cambridge, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.624962.
Pełny tekst źródłaDVORNIKOVS, VADIMS. "Evolution of the artificial enzyme: from simple cyclophanes to sophisticated host-rotaxanes". University of Cincinnati / OhioLINK, 2002. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1037897753.
Pełny tekst źródłaFlorian, Maria Carmen. "Design, synthèse et analyse structurale de nouvelles molécules hôtes : Macrocycles et cyclophanes". Rouen, 2006. http://www.theses.fr/2006ROUES034.
Pełny tekst źródłaIn the first part, we reported the synthesis of new dispiro-1. 3-dioxane compounds as syn and anti isomers. The synthesis of new macromolecules embedding semiflexible dispiro-1. 3-dioxane units was performed by high-dilution technique and using the template effect. The design of these macrocyclic compounds is based on the stereochemistry of the precursors which show a favourable pre-organization for the incorporation in macrocycle systems. In the second part, we reported the synthesis and the stereochemistry of new 1. 3. 5-triacetylbenzene derivatives and the attempts to obtain new “cage” molecules from these derivatives
Balog, Mirela. "Synthèse et analyse structurale de nouveaux coronands, cyclophanes et composés 1,3-dioxaniques". Rouen, 2004. http://www.theses.fr/2004ROUES004.
Pełny tekst źródłaThe stereochemistry investigations performed with 1,3-dioxane derivatives obtained from meso-2,4-pentanediol, 2,6-diacetylpyridine and 5-aryl-2-furaldehydes, shown in the first part of this work, revealed the axial or equatorial preference for several substituents at position 2 of the 1,3-dioxane ring. The atropisomery of some derivatives exhibiting aromatic substituents and the unexpected mass-spectrometry discrimination of cis and trans isomers of some 2,4,6-substituted-1,3-dioxanes were discussed. In the second part of this work we report the synthesis and the structural analysis of a series of coronands with spirane units and cyclophanes which embed in their structure 1,3-dioxane rings. The design of these macrocycle compounds is based on the stereochemistry of the precursors which show a favourable pre-organization for the incorporation in macrocycle systems. The structural analysis is based on high-field NMR investigations (ROESY, NOESY and dynamic experiments), X-ray diffractometry (six molecular structures) and mass spectrometry experiments (MALDI, ESI-MS). These investigations correlate the size of the cavities of different macrocycles with the selectivity of the coordination for different alkali cations and reveal the supramolecular aggregates formed by some of the macrocycle compounds with molecules of solvent and the intra and intermolecular interactions (p-stacking) among the aromatic rings. The tandem flipping of the two 1,3-dioxane rings of the para-para cyclophane, suggesting the dynamics of a rocking chair, was observed as the first example showing the concerted flipping of two six-membered rings incorporated in the same macrocycle
Rotzler, Jürgen Stefan [Verfasser]. "Tailoring Intra- and Intermolecular Properties: From Cyclophanes to Daisy Chains / Jürgen Rotzler". München : Verlag Dr. Hut, 2012. http://d-nb.info/1023435365/34.
Pełny tekst źródłaDvornikovs, Vadims. "Evolution of the artificial enzyme from simple cyclophanes to sophisticated host-rotaxanes /". Cincinnati, Ohio : University of Cincinnati, 2002. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=ucin1037897753.
Pełny tekst źródłaGodbert, Nicolas. "Anthracenediylidene derivatives : control of molecular and supramolecular architecture". Thesis, Durham University, 2002. http://etheses.dur.ac.uk/3818/.
Pełny tekst źródłaKrieger, Jean-Philippe. "Réarrangements de cycles et activation de liaisons C-H : synthèse de macrocycles". Thesis, Paris 6, 2015. http://www.theses.fr/2015PA066765.
Pełny tekst źródłaThere is currently a growing interest for macrocycles as scaffolds in medicinal chemistry. Therefore, the development of new and efficient strategies toward this class of compounds represents a major challenge. In the first part of our research work, we have been interested in the synthesis of functionalized paracyclophanes incorporating heteroatoms, capitalizing on a Diels-Alder/retro-Diels-Alder reaction sequence from tricyclic dienes and acetylenic dienophiles. The tricyclic dienes precursors could be quickly assembled from simple and readily available building blocks, using a reliable sequence involving a Sonogashira cross-coupling, the semi-hydrogenation of an alkyne and a six-pi electron electrocyclization. The resulting tricyclic dienes were engaged in an intermolecular Diels-Alder/retro-Diels-Alder reaction sequence to provide paracyclophanes possessing a trisubstituted aromatic ring. An intramolecular version of this sequence was devised which enabled access to unique paracyclophanes with a cage architecture incorporating a tri- or tetrasubstitued aromatic ring. The second part of our investigations was devoted to the development of transition metal-catalyzed C-H activation mediated macrocyclizations. In the presence of a ruthenium(II) complex as the catalyst, the cyclization of Omethylhydroxamic acids substituted by a carbon chain possessing a remote alkyne could be achieved and provided an efficient access to macrocyclic isoquinolones. A similar transformation was applied to alpha,betaunsaturated hydroxamic acids derivatives substituted by an acetylenic chain, using a catalytic system based on a rhodium(III) complex, to afford macrocyclic pyridones
Renault, Anne. "Cyclophanes-tétracyanoéthylène : des complexes moléculaires à transfert de charge : études chimiques et cristallographiques". Grenoble 1, 1986. http://www.theses.fr/1986GRE10144.
Pełny tekst źródłaRenault, Anne. "Cyclophanes-tétracyanoéthylène des complexes moléculaires à transfert de charges, études chimiques et cristallographiques /". Grenoble 2 : ANRT, 1986. http://catalogue.bnf.fr/ark:/12148/cb376007140.
Pełny tekst źródłaVonlanthen, David [Verfasser]. "Biphenyl-Cyclophanes: The Molecular Control over the Conductivity of Single-Molecule Junctions / David Vonlanthen". München : Verlag Dr. Hut, 2010. http://d-nb.info/1009972952/34.
Pełny tekst źródłaSuvannachut, Kessara. "Scope and mechanism of the rearrangement of alkoxybenzyl anions to alkylphenoxide ions; cyclophanes from 2,6-dimethylanisole". Diss., The University of Arizona, 1989. http://hdl.handle.net/10150/184679.
Pełny tekst źródłaEttahiri, El Ouahabi Abdelhak. "Synthèse, étude structurale et conformationnelle de paracumylcalixarenes". Lyon 1, 1994. http://www.theses.fr/1994LYO10026.
Pełny tekst źródłaDron, Paul Ionut. "Cyclopyridinophanes, capteurs moléculaires : synthèse, structure et propriétés électriques". Littoral, 2007. http://www.theses.fr/2007DUNK0178.
Pełny tekst źródłaThis thesis reports the synthesis of cyclo(bis-paraquat p-phenylene p-phenylene-carbonyle) tetrakis(hexapluorophosphate) (« CETEBOX »). This one exists in three tautomeric structures proved by NMR spectra, potentiometric titration and synthesis. Through its cycloimmonium ylide, in a [3+2] cycloaddition reaction, this compound furnishes a fluorescent cyclophane sensor. This sensor shows inclusion properties towards Volatile Organic Compounds. By a coupling reaction between the fluorescent indolizine sensor and 6-deoxy-6-amine-β-cyclodextrin a new dual cavity (β-cyclodextrine et cyclophane) fluorescent sensor is synthetized. All new structures reported in this thesis have been established by IR, RMN (1H-RMN, 13C-RMN, TOCSY, COSY, NOESY, HMQC). According to the molecular modeling methods (MM3, AM1, AM1-COSMO, B88LYPDFT), the found most stable conformers are in good agreement with the experiments. Using a bis(paraquat) salt a new Palladium multicavities complex has been synthetized. The electrical properties of the newly synthetized cyclopyridinophanes have been established by measurements of the electrical conductivity at different temperatures and frequencies. Two of them show very interesting properties concerning conversion of light energy into thermal energy
Guinand, Gérard. "Structures de structures de systèmes anthracéniques complexants". Bordeaux 1, 1986. http://www.theses.fr/1986BOR10526.
Pełny tekst źródłaElacqua, Elizabeth. "Supramolecular chemistry of molecular concepts: tautomers, chirality, protecting groups, trisubstituted olefins, cyclophanes, and their impact on the organic solid state". Diss., University of Iowa, 2012. https://ir.uiowa.edu/etd/3447.
Pełny tekst źródłaMannion, Michael R. "Synthesis and chemistry of highly distorted polycyclic aromatic hydrocarbons". Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1999. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape7/PQDD_0017/NQ52693.pdf.
Pełny tekst źródłaCollins, Mary. "Reactivity and Coordination Chemistry of Pnictogen-Containing Complexes". Thesis, University of Oregon, 2016. http://hdl.handle.net/1794/19657.
Pełny tekst źródła10000-01-01
Sapotta, Meike [Verfasser], i Frank [Gutachter] Würthner. "Perylene Bisimide Cyclophanes: Recognition of Alkaloids, Aggregation Behavior in Aqueous Environment and Guest-Mediated Chirality Transfer / Meike Sapotta ; Gutachter: Frank Würthner". Würzburg : Universität Würzburg, 2021. http://d-nb.info/1228272379/34.
Pełny tekst źródłaBleger, David. "Nanostructuration du graphite HOPG par des auto-assemblages moléculaires organiques : du contrôle de l’organisation bidimensionnelle à la construction d’édifices tridimensionnels". Paris 6, 2008. http://www.theses.fr/2008PA066404.
Pełny tekst źródłaMontagne-Marcellin, Corinne. "Recherche de molécules organiques complexantes pour la décorporation de l'ion uranyle". Montpellier 2, 1996. http://www.theses.fr/1996MON20069.
Pełny tekst źródłaDe, Smet Lieselot. "Création de systèmes polymères intelligents utilisant le cyclobis(paraquat-p-phénylène) et le cyclobis(paraquat-4,4'-biphénylène)". Thesis, Lille 1, 2020. http://www.theses.fr/2020LIL1R006.
Pełny tekst źródłaThe development of smart or intelligent polymeric materials has gained a lot of attention over the past decades. Smart materials are described as materials that are capable of altering their properties and functions in response to small external environmental changes such as fluctuations in temperature. Within this rapidly advancing field, supramolecular chemistry, including host-guest complexation, has emerged as a powerful tool for the creation of these responsive materials due to their dynamic, reversible and adaptive nature towards external stimuli. These host-guest inclusion complexes consist mostly of a macrocyclic host molecule which can interact in a highly controlled and selective manner with one or more smaller guest molecules, via both random non-covalent interactions and specific three-dimensional spatial arrangements. The integration of these dynamic supramolecular assemblies into conventional polymer chemistry through the incorporation of either the macrocyclic host or, mostly, the electron rich guest has allowed us to develop the next generation advanced materials in a less time-consuming way. In this PhD thesis macrocyclic host molecule cyclobis(paraquat-p-phenylene) and cyclobis(paraquat-4,4’-biphenylene) were incorporated in hydrophilic polymer systems (homopolymers, hydrogels) in a reversible manner. For thermoresponsive hydrogel systems, it was shown that they were able to remember how long they were exposed to a certain external temperature change. The complexation of these cyclophanes are accompagnied with a visible color change allowing the use of these materials for sensor applications
De, Smet Lieselot. "Création de systèmes polymères intelligents utilisant le cyclobis(paraquat-p-phénylène) et le cyclobis(paraquat-4,4'-biphénylène)". Electronic Thesis or Diss., Université de Lille (2018-2021), 2020. http://www.theses.fr/2020LILUR006.
Pełny tekst źródłaThe development of smart or intelligent polymeric materials has gained a lot of attention over the past decades. Smart materials are described as materials that are capable of altering their properties and functions in response to small external environmental changes such as fluctuations in temperature. Within this rapidly advancing field, supramolecular chemistry, including host-guest complexation, has emerged as a powerful tool for the creation of these responsive materials due to their dynamic, reversible and adaptive nature towards external stimuli. These host-guest inclusion complexes consist mostly of a macrocyclic host molecule which can interact in a highly controlled and selective manner with one or more smaller guest molecules, via both random non-covalent interactions and specific three-dimensional spatial arrangements. The integration of these dynamic supramolecular assemblies into conventional polymer chemistry through the incorporation of either the macrocyclic host or, mostly, the electron rich guest has allowed us to develop the next generation advanced materials in a less time-consuming way. In this PhD thesis macrocyclic host molecule cyclobis(paraquat-p-phenylene) and cyclobis(paraquat-4,4’-biphenylene) were incorporated in hydrophilic polymer systems (homopolymers, hydrogels) in a reversible manner. For thermoresponsive hydrogel systems, it was shown that they were able to remember how long they were exposed to a certain external temperature change. The complexation of these cyclophanes are accompagnied with a visible color change allowing the use of these materials for sensor applications
Duhart, Anne. "Synthèse et caractérisation de membranes hybrides organo-minérales contenant des calixarènes. Application au traitement des effluents radioactifs". Montpellier 2, 1998. http://www.theses.fr/1998MON20051.
Pełny tekst źródłaMattei, Sebastiano. "Dendrophane : dentrisch funktionalisierte Cyclophane /". Zürich, 1997. http://e-collection.ethbib.ethz.ch/show?type=diss&nr=12116.
Pełny tekst źródła