Artykuły w czasopismach na temat „Corrosion inhibitor”
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Jasim, Haider Hadi, Read Abd Al-Hussain i Ahmed Shawqi Sadeq. "Evaluation the Efficiency of Various Types of Corrosion Inhibitors Used for Basrah Water Storage Tanks". Al-Nahrain Journal for Engineering Sciences 23, nr 3 (21.11.2020): 267–76. http://dx.doi.org/10.29194/njes.23030267.
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In this paper, the efficiency of six different types of corrosion inhibitors used in Basrah drinking water tanks was assessed using a potentiostatic test method. The mechanism of adsorption of silicate and phosphate inhibitors in AISI 316 stainless steel surfaces and the effects of different water components in inhibitors are discussed in detail. The values of corrosion rate obtained from the Potentiostatic test showed that the protection against corrosion in the presence of inhibitors is better compared to the case of absence of inhibitors. The results of the six types of corrosion inhibitors tested showed that the inhibitory efficacy is higher below the temperatures 45oC, but when raise the temperature above 45oC the inhibitory efficiency becomes to decrease. Also, the test results indicated that the corrosion inhibitor involves silicate products provided more inhibited efficiency compared to the phosphate inhibitor alone or used the combined silicate/phosphate corrosion inhibitor. The inspection of the surface of the tested samples using optical methods shows that the pitting corrosion is demonstrated on the specimen surfaces after testing with or without inhibitors.
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Flores-Garcia, N. S., C. D. Arrieta-Gonzalez, J. J. Ramos-Hernandez, G. K. Pedraza-Basulto, J. G. Gonzalez-Rodriguez, J. Porcayo-Calderon i L. Martinez-Gomez. "Rare Earth-Based Compounds as Inhibitors of Hot-Corrosion Induced by Vanadium Salts". Materials 12, nr 22 (19.11.2019): 3796. http://dx.doi.org/10.3390/ma12223796.
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In this study, the performance evaluation of lanthanum compounds as corrosion inhibitors of vanadium salts was performed. The inhibitors tested were lanthanum acetate and La2O3. The performance of the inhibitors was tested using sodium metavanadate (NaVO3) as a corrosive medium at 700, 800, and 900 °C. The corrosion inhibitory effect was evaluated on the corrosion process of 304H stainless steel. The corrosion rate of the steel was determined by the mass loss technique after 100 h of immersion in the corrosive salt with and without the addition of the corrosion inhibitor. The results show that lanthanum compounds act as corrosion inhibitors of vanadium salts. The inhibitory effect increases by increasing the concentration and tends to decrease when increasing the test temperature. Lanthanum compounds act as excellent corrosion inhibitors due to their ability to stabilize vanadium cations. Vanadium is stabilized by forming a new compound, lanthanum vanadate (LaVO4), with a melting point much higher than the compounds formed when Mg or Ni compounds are used as corrosion inhibitors.
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Zhu, Yanhua, Liqiang Zhao, Pingli Liu i Ming Yang. "Subsection corrosion inhibition of acidic-oxidized polymer degradant in offshore oil field". Anti-Corrosion Methods and Materials 65, nr 5 (3.09.2018): 451–57. http://dx.doi.org/10.1108/acmm-01-2018-1888.
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Purpose This paper aims to introduce a method to reduce corrosion caused by acidic-oxidized polymer degradant through subsection injection with different inhibitor. Design/methodology/approach This paper introduced a method to reduce corrosion caused by acidic-oxidized polymer degradant through subsection injection with different inhibitor. Findings The experimental results indicated that the influence of pre-corrosion status on corrosion rate and effectiveness of corrosion inhibitor are significant. The corrosion inhibitors in both injection stage inhibited the corrosion process by preventing the contact of corrosive medium and steel surface through formation of a protective film on the surface of N80 steel. The corrosion rate of polymer degradant can be reduced to 0.63 g/m 2 h through subsection injection with different inhibitor. Originality/value This result will increase the production of polymer injection plugging wells through expanding the application of acidic-oxidized polymer degradant.
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Shaker, Fatima Mahmood, i Dhifaf Jaafar Sadeqb. "Protecting Oil Flowlines from Corrosion Using 5-ACETYL-2-ANILINO-4-DIMETHYLAMINOTHIAZOLE". Pakistan Journal of Medical and Health Sciences 16, nr 6 (30.06.2022): 571–74. http://dx.doi.org/10.53350/pjmhs22166571.
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Oil flow lines are used to transport oil and its derivatives from a well over long distances, and because oil wells produce other potentially corrosive products, such as carbon dioxide and Hydrogen sulfide, it is necessary to take methods to protect the pipeline from corrosion. One of these methods is the use of corrosion inhibitors in this study. Prepare 5-acetyl-2-anilino-4-dimethylaminothiazole and test it as a corrosion inhibitor on a sample of the Rumaila flow line at a constant temperature 25°C in (3.5%) NaCl and (3.5%) KCl solution in the absence and presence of different concentrations of inhibitor (0 mM, 0.01 mM, 0.03 M, 0.05 mM). by using liner polarization (Tafel slope). The inhibiter exhibited the best performance at high concentration giving 94% in NaCl solution and 88% in KCl solution and solution, the inhibitor gave It was used FT-IR to find out the effective aggregates in the inhibitor, Tafel plot reveals that Ecorr for flowline in the presence the inhibitors shift to a higher (noble) position compared with blank solution, implying that the protection acts as an anodic protection. Keywords: corrosion inhibiter, oil flowline, leaks.
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Алмагамбетова, Сауле, i Saule Almagambetova. "Analysis of the ways of anticorrosive influence on food industry equipment protection". Food Processing: Techniques and Technology 48, nr 2 (10.01.2019): 129–35. http://dx.doi.org/10.21603/2074-9414-2018-2-129-135.
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Nowadays there is a significant engineering and technical issue which is corrosion of structural materials, metal equipment and installations. Inhibitors are one of the effective, universal and economical means of protection against corrosion. The author justifies the relevance of the problem connected with selection of corrosion inhibitors for food industry companies. The aim of the work is to study the effect of inhibitors based on plant raw materials on increasing the corrosion resistance of food industry equipment in technological corrosive media. A literature review showed that the use of synergistic inhibitory compositions is more effective than using inhibiting additives separately. A specified inhibitor is a modified plant raw material. It has biocidal and bactericidal properties that provide for high efficiency of corrosion protection of structural steels in neutral and acid media and is used to improve protective and physico-mechanical properties of coatings. The author studied the effect of concentrate inhibitor in the working environment on the basis of technological regulations to justify recommendations on the use of this concentrate in protecting equipment against corrosion. As a result of the study, the author determined that the greatest effect took place when a modified concentrate inhibitor was used. The plant-based concentrate inhibitor does not have lower corrosion protection effectiveness than the industrial inhibitor PB-5. On the contrary, it has a number of definite advantages such as environmental safety, multiple action directions as well as a positive effect on the sanitary and hygienic conditions in the process of inhibitor preparation and use. The author gives recommendations on the possibility of using this inhibitor to protect the mechanisms used in food industry against corrosion.
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Pletnev, Mikhail. "Carbon nanocomposites in the corrosion inhibition". E3S Web of Conferences 225 (2021): 05002. http://dx.doi.org/10.1051/e3sconf/202122505002.
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Metal-carbon nanocomposites have been investigated as additives to enhance the protective effect of corrosion inhibitors. Two inhibitors were used as corrosion inhibitors. Inhibitor VNH-L-113 (1-morpholinomethylcyclohexylamine) belongs to Schiff bases, which are known as corrosion inhibitors in neutral and acidic media. Inhibitor SNPKh-1004 is often used in the practice of corrosion protection in the oil and gas industry. For research, an electrochemical method was applied using corrosion rate meters of the Monicor type. Neutral aqueous solution and water simulating the corrosive environment of oil fields were chosen as corrosive media. The result shows, that the copper-carbon nanocomposite enhances the protective effect of corrosion inhibitors of various chemical nature in various corrosive environments. The studies carried out make it possible to consider the use of metal-carbon nanocomposites as a promising direction for increasing the effectiveness of inhibitors in the oil and gas industry.
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Septiyani Arifin, Devi Eka, Destri Muliastri, Rudi Rudiana i Fitri Nur Indah Sari. "Green Corrosion Inhibitors to Head Off the Corrosion Rate of ST 37 Steels". Current Journal: International Journal Applied Technology Research 2, nr 1 (21.05.2021): 21–28. http://dx.doi.org/10.35313/ijatr.v2i1.40.
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The corrosions process is a natural process and cannot be hindered, but it can be protected by adding a green inhibitor. Green corrosion inhibitors are a new alternative solution for corrosion protection because they are low-cost, biodegradable, and eco-friendly inhibitors. This research was used papaya leaves dan guava leaves extract as organic inhibitor solution by Maceration Method. The concentration of these green inhibitors is 0 mL, 1 mL, 2.5 mL, 3 mL, and 3.5 mL. The type of testing method used in this research is FTIR, PDP, and weight loss. The results show that there is Tanin function groups in papaya leaves and guava leaves extract. The potentiodynamic polarization shows the value of corrosion rate without inhibitor is 0,418 mm/year. In contrast, the corrosion rate was decreased with improving the green inhibitor as many 3.5 mL. The corrosion rate was decreased until 0,00055 mm/year, and the value of efficiency is 99,868%.
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Mohyaldinn, Mysara Eissa, Wai Lin, Ola Gawi, Mokhtar Che Ismail, Quosay A. Ahmed, Mohammed A. Ayoub i Anas Hasan. "Experimental Investigation of a New Derived Oleochemical Corrosion Inhibitor". Key Engineering Materials 796 (marzec 2019): 112–20. http://dx.doi.org/10.4028/www.scientific.net/kem.796.112.
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Most of the corrosion inhibitors that are used in industry contain chemicals that are harmful to health and environment. Corrosion inhibitors derived from green sources are, therefore, believed to be a good option for replacing the chemical corrosion inhibitors. In this work, a green oleochemical corrosion inhibitor derived from Jatropha Curcas is introduced. The paper discusses the methodology of deriving the corrosion inhibitor as well as the experimental test conducted for evaluating its corrosion inhibition efficiency. The new oleochemical corrosion inhibitor was derived via two reactions. Jatropha oil was firstly saponified with sodium hydroxide to yield gras acid and glycerol, which was then esterified with boron fluoride in presence of excess methanol to produce the oil methyl esters, which is used as oleo-chemical corrosion inhibitor. To evaluate the oleo-chemical corrosion inhibitor, the corrosion rate of mild steel in NaCl corrosive medium with CO2 is tested at static condition and two dynamic conditions, namely 500 and 1500 rpm. This is to simulate the transitional and turbulent flow in a pipeline. At each dynamic condition, the proposed corrosion inhibitor was tested at concentration dosages of 0, 50, 100, and 150 ppm. The experiments results revealed a good performance of the new oleochemical corrosion inhibitor. The inhibition efficiency was found to be highly affected by the concentration of corrosion inhibitor. Total corrosion inhibition of the mild steel was noticed by using 150 ppm at dynamic condition of 500 rpm.
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Bahtiti, Nawal H., i Ibrahim Abdel-Rahaman. "Anti-Corrosive Effect of Jordanian-Bay- Leaves Aqueous Extract on Mild Steel in 1.0 M Hydrochloric Acid Solution". WSEAS TRANSACTIONS ON ENVIRONMENT AND DEVELOPMENT 17 (11.06.2021): 614–18. http://dx.doi.org/10.37394/232015.2021.17.59.
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Natural inhibitors are the most crucial manner to lessen the corrosion price of various business metals. There are several strategies being used with corrosion inhibitors. One technique being used is the Electrochemical strategies. The gain with this technique is their brief size time and mechanistic information. It is beneficial in the corrosion's layout safety techniques besides the layout of the brand new inhibitors, there are 3 styles of corrosion inhibitors as anodic inhibitors, cathodic inhibitors, over one inhibitor. The corrosion inhibition of slight metallic in 1.0 M HCl solution with the aid of using Jordanian -Bay- leaves extract has been studied with the use of potentiodynamic polarization technique. Results received a display that Bay- leaves aqueous extract behaves as an anodic inhibitor for slight metallic in 1.0 M HCl solution. The inhibitor capabilities thru adsorption following Temkin adsorption isotherm. The impact of parameters like temperature and inhibitor awareness at the corrosion of slight metallic has additionally been studied.
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Bavarian, Behzad, Jia Zhang i Lisa Reiner. "Corrosion Inhibition of Stress Corrosion Cracking and Localized Corrosion of Turbo-Expander and Steam/Gas Turbines Materials". Key Engineering Materials 488-489 (wrzesień 2011): 61–64. http://dx.doi.org/10.4028/www.scientific.net/kem.488-489.61.
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Stress corrosion cracking of 7050 aluminum alloys and ASTM A470 steel in the turbo expander and steam/gas turbine industry can cause expensive catastrophic failures, especially for turbo machinery systems performing in hostile, corrosive environments. Commercially available inhibitors were investigated for their effectiveness in reducing and controlling the corrosion susceptibility. Inhibitor effectiveness was confirmed with electrochemical corrosion techniques in different solutions. Polarization resistance increased with concentration of corrosion inhibitor due to film formation and displacement of water molecules. Cyclic polarization behavior for samples in the 1.0% and 5.0% inhibitors showed a shift in the passive film breakdown potential. The substantial increase in the passive range has positive consequences for neutralizing pitting and crevice corrosion cell chemistry. The strain to failure and tensile strength obtained from the slow strain rate studies for both alloys showed pronounced improvement due to corrosion inhibitor ability to mitigate SCC; the fractographic analysis showed a changed morphology with ductile overload as the primary failure mode instead of transgranular or intergranular cracking.
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Reyes-Dorantes, E., J. Zuñiga-Díaz, A. Quinto-Hernandez, J. Porcayo-Calderon, J. G. Gonzalez-Rodriguez i L. Martinez-Gomez. "Fatty Amides from Crude Rice Bran Oil as Green Corrosion Inhibitors". Journal of Chemistry 2017 (2017): 1–14. http://dx.doi.org/10.1155/2017/2871034.
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Due to its high oil content, this research proposes the use of an agroindustrial byproduct (rice bran) as a sustainable option for the synthesis of corrosion inhibitors. From the crude rice bran oil, the synthesis of fatty amide-type corrosion inhibitors was carried out. The corrosion inhibitory capacity of the fatty amides was evaluated on an API X-70 steel using electrochemical techniques such as real-time corrosion monitoring and potentiodynamic polarization curves. As a corrosive medium, a CO2-saturated solution (3.5% NaCl) was used at three temperatures (30, 50, and 70°C) and different concentrations of inhibitor (0, 5, 10, 25, 50, and 100 ppm). The results demonstrate that the sustainable use of agroindustrial byproducts is a good alternative to the synthesis of environmentally friendly inhibitors with high corrosion inhibition efficiencies.
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Ryu, Hwa Sung, i Han Seung Lee. "Study on the Anti- Corrosion Properties of Organic and Inorganic Inhibitor by Electrochemical Treatment in Aqueous Solution". Advanced Materials Research 415-417 (grudzień 2011): 2070–73. http://dx.doi.org/10.4028/www.scientific.net/amr.415-417.2070.
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The various methods for improving chloride penetration resistance in the reinforced concrete have been developed. Among the related general ways, using of corrosion inhibitor became very common. Therefore, in this study, in order to comprehend performance of corrosion inhibitor, the experiment study was conducted about corrosion characteristic of 3 steps(0.0, norm 1/2, norm) compared to organic corrosion inhibitor standard use of liquid and molar 3 steps(0.0, 0.3, 0.6%) of Chloride by added amount of inorganic corrosion inhibitor by the corrosion inhibitor types about 2.4kg/m3, 4.8kg/m3based on Chloride ion content 1.2kg/m3for service life prediction of concrete structure by using Poteniostat. As results, in the case of inorganic nitrous acid corrosion inhibitor, it was confirmed that anti-corrosive performance of Chloride ion content 1.2kg/m3by corrosion Ecorr -0.30V in more than molar ratio 0.3%, and it also was confirmed that anti-corrosive performance of 2.4kg/m3, 4.8kg/m3in more than molar ratio 0.6%. In addition, the excellent anti-corrosive performance of organic corrosion inhibitor was shown in 1/2(0.42kg/m3) of norm regardless of Chloride ion content, and it can be seen that absorption types organic corrosion inhibitor has excellent anti-corrosive performance compared to the inorganic nitrous acid corrosion inhibitor by the added amount of corrosion inhibitor.
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Asmara, Yuli Panca, Tedi Kurniawan, Agus Geter Edy Sutjipto i Jamiluddin Jafar. "Application of Plants Extracts as Green Corrosion Inhibitors for Steel in Concrete - A review". Indonesian Journal of Science and Technology 3, nr 2 (30.08.2018): 158. http://dx.doi.org/10.17509/ijost.v3i2.12760.
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High requirements in protection of steel reinforcing bar (steel rebar) from corrosion are necessary since there are multi interaction of corrosive chemicals which cause early damage of concrete buildings. Corrosion of steel in concrete can destroy the concretes and reduce concrete strength. To protect rebar from corrosion, application of corrosion inhibitor is believed to have higher performance compared to other protection systems. To date, organic inhibitors have promising methods in steel rebar protection as they are environment-friendly, compatible with concrete, cost effective and applicable in any various concrete conditions. Thus, demands in using these inhibitors tend to increase significantly. This paper reviews the applications of green corrosion inhibitor specifically highlighted in protecting mechanisms, typical plants extracted, performance in corrosion protection, and classification of green corrosion inhibitors. The corrosion resistances of carbon steels in concrete protected by green inhibitors are in focus. As summary, it can be confidently notified that green corrosion inhibitors for steel in concrete will have a prospect to be used as corrosion prevention in the future with further improvements.
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Zultiniar, Muhammad Kurnia Sandy, Ervan Wibowo, Desi Heltina i Komalasari. "Coconut Fiber Extraction using Soda Pulping Method as Green Corrosion Inhibitor for ASTM A36 Steel". Journal of Physics: Conference Series 2049, nr 1 (1.10.2021): 012094. http://dx.doi.org/10.1088/1742-6596/2049/1/012094.
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Abstract Currently, the corrosion inhibitor is a method that is widely used to control the corrosion rate of inner pipe in the chemical industry. This study aims to utilize coconut fiber as a green inhibitor, determine the effect of adding inhibitor concentration, immersing time, and determine the inhibition efficiency of coconut husk extract. The extraction method used is the soda pulping method with a solid to liquid ratio of 1:8 (w/v). The method used for testing the corrosion rate is the weight-loss method, UV-Vis Spectrophotometry and FT-IR are also used to analyze the lignin produced. The lowest corrosion rate was obtained in 1 M HCl corrosive medium with the addition of 3 g/L inhibitors at 48 hours immersion, which was 49.691 mpy. The highest inhibition efficiency was in 1 M HCl corrosive media solution with the addition of 3 g/L inhibitors at 48 hours immersion, which was 78.11%.
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Rani, Oricha Mutia, Ediman Ginting Suka i Yanti Yulianti. "Pengaruh Inhibitor Ekstrak Daun Inai (Lawsonia inermis L) Terhadap Laju Korosi Baja St37 dalam Larutan HCl 3%". Journal of Energy, Material, and Instrumentation Technology 2, nr 3 (31.08.2021): 104–9. http://dx.doi.org/10.23960/jemit.v2i3.147.
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Henna leaves extract (Lawsonia inermis L) is used as a corrosion inhibitor in St37 steel soaked in 3% HCl corrosive medium. To find out the effect of inhibitor concentration on the corrosion rate of steel, the variation of inhibitor concentration is 0, 3, 5, 7 and 9%. Corrosion rate testing is done by mass loss method. Corrosion rate was tested on low carbon steel with and without inhibition of henna extract for 6 days. The results showed that the greater the concentration of inhibitor of henna extract used, the corrosion rate would decrease and the ability to inhibit corrosion would increase. The greatest corrosion efficiency occurred at a concentration of 9% with an efficiency of 88.84%. The results of X-Ray Diffraction (XRD) characterization showed that the phase formed was pure iron (Fe). Secondary Electron Microscopy (SEM) characterization showed uneven clusters and smaller sizes, holes and cracks were also less with the addition of inhibitory leaves extract than without the addition of inhibitory leaves extract. This result is reinforced by the percentage of corrosion products shown in the results of the characterization of Energy Dispersive Spectroscopy (EDS).
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Triana, Yunita, Sari Shaimah Rinda, Awali Jatmoko i Sulistijono Sulistijono. "Studi Penambahan Inhibitor Organik Ekstrak Daun Bawang Tiwai (Eleutherine americana Merr.) pada Baja API 5L dalam Lingkungan 3,5% NaCl". SPECTA Journal of Technology 2, nr 3 (13.12.2018): 1. http://dx.doi.org/10.35718/specta.v2i3.11.
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One that can be used as an organic inhibitor is bawang tiwai leaves extract. This study used 3.5% NaCl as corrosive media with inhibitor concentration of bawang tiwai leaves extract from 0 ppm to 500 ppm and immersion time from 10 days up to 30 days. The efficiency of inhibition was measured using a weight loss corrosion test, while the corrosion rate was obtained from polarization measurements. The FTIR test results show that the extract contains flavonoid compounds that act as antioxidants and inhibit corrosion. Inhibitory efficiency achieved up to 95.4545% for the addition of 300 ppm inhibitor and 20 days of immersion time. This inhibitory behavior is also supported by polarization measurements where the lowest corrosion rate of 0.00128 mm/year is obtained at the same concentration and immersion time.
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Mas’ud, Zainal Alim, Noviyan Darmawan, Januari Dawolo i Yusuf Bramastya Apriliyanto. "Fatty Amidine as Copper Corrosion Inhibitor". Journal of Chemistry 2020 (4.11.2020): 1–8. http://dx.doi.org/10.1155/2020/1092643.
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The development of green and sustainable corrosion inhibitors for copper in a corrosive marine environment is highly desired. Herein, we studied the fatty acid-based amidine as the new type of renewable corrosion inhibitor. Stearamidine salt was used as a model inhibitor, and it was synthesized through stearonitrile intermediate with an excellent isolated yield of 88%. We used electrochemical (potentiodynamic polarization) and morphological (scanning electron microscopy) measurements to assess the corrosion inhibition efficiency of stearamidine in 3.0 wt.% NaCl at 300 K. We show that, in such a condition, the optimum inhibition efficiency of 96% was achieved using only 0.2 mM stearamidine. The results suggested the fatty amidine is a promising corrosion inhibitor for copper that is suitable in the saltwater ecosystem. The thermodynamic parameters of the interaction between the stearamidine and the copper surface were determined, and the result suggests that the adsorption process occurred accordingly with the Langmuir adsorption isotherm and involved both physisorption and chemisorption.
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Atan, F., R. Rosliza i W. M. Wan Syahidah. "The efficiency of moringa leaf (Moringa Oleifera) as green material carbon steel corrosion inhibitor for different concentration of sea water." Journal of Physics: Conference Series 2266, nr 1 (1.05.2022): 012009. http://dx.doi.org/10.1088/1742-6596/2266/1/012009.
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Abstract Carbon steel as materials of pipe is used in the plural oil and gas industry in Malaysia, but the corrosive working environment conditions create this type of pipe prone to corrosion. In electrical industries, Aluminum-conductor steel-reinforced (ACSR) are the most commonly used in transmission line systems due to aluminum’s light weight and cost, and carbon steel’s strand is high mechanical strength. Corrosion is an absolute phenomenon that occurs in carbon steel, but the rate of corrosion can be controlled by certain techniques. One of which is the use of environmentally friendly corrosion inhibitors or so-called green corrosion inhibitors. Moringa Leaf (Moringa Oleifera) is known to have a high content of antioxidant compounds and the use of this benefit only limited to water purification and as a food ingredient. From this issue, research was carried out on the use of Moringa leaf extract as green corrosion inhibitor on carbons steel. This research uses variations Moringa leaf powder concentration in 200 ml static seawater conditions (0 rpm) give the concentration of 200, 400, and 600, 800 and 1000 ppm to get optimal work. The linear polarization method used to determine the performance of Moringa leaf powder to reduce the corrosion reaction. In the tafel test, it was found that moringa leaf powder that is added suitable to work as inhibitor. Addition of the concentration able to reduce the corrosion rate up to 0.124 mmpy with efficiency from polarization resistance of 49.69 %, while efficiency from corrosion rate and corrosion current of 70.5% in static seawater conditions. Consequently, in inhibited solutions, the corrosion rate is indicative of the number of the free corrosion sites remaining after some sites have been blocked by inhibitor adsorption. Tafel test results found that a protective passive layer is formed on the surface of the steel make contact between the metal and sea water is reduced with existing of moringa leaf powder so that corrosion can be inhibited.
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Pradityana, Atria, Eddy Widiyono, Hari Subiyanto, Nur Husodo i Muhammad Saiful Rizal. "Application of Psidium Guajava Leaf Extract as an Organic Inhibitor in Acid Solution and Temperature Variation". Key Engineering Materials 940 (30.01.2023): 101–6. http://dx.doi.org/10.4028/p-1b8mqs.
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Corrosion is a change in the properties of a material, mainly metal, due to a reaction with the surrounding environment. One of The ways to inhibit corrosion is by adding inhibitors. Organic inhibitors are inhibitors that are considered environmentally friendly. In this study, the guava leaf extract of Psidium guajava was used as an organic inhibitor. Materials used are API 5L Grade B steel in 1M HCl solution as corrosive media with the concentration of the extract used in this study 1188ppm with a temperature variation of 30, 35, 40, 45, and 50 Celcius degrees. The types of tests carried out in this study were Electrochemical Impedance Spectroscopy and Potentiodynamic Polarization. The results of the potentiodynamic polarization test of organic inhibitors obtained an efficiency of 96.7550% with a corrosion rate of 1,04460 mm/year at a temperature of 30 degrees Celsius. In the electrochemical impedance spectroscopy test, the efficiency was 96,8546%, at a temperature of 30 degrees Celsius. The results of this study showed that the inhibitor of organic Psidium Guajava extract was The higher the temperature given to the inhibitor, it does not significantly affect the efficiency of the inhibitor, which acts the corrosion rate.
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Cheng, Yuan Peng, Zi Li Li, Hai Sheng Bi i Yi Xuan Song. "Research on the CO2 Corrosion Inhibitor Technology in Oil and Gas Fields". Advanced Materials Research 734-737 (sierpień 2013): 1240–45. http://dx.doi.org/10.4028/www.scientific.net/amr.734-737.1240.
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CO2 corrosion is the main safety problem of production process in gathering, delivering and treating of oil and gas. Injecting inhibitors to suppress CO2 corrosion in oil and gas fields is an easy-to-use, low investment, quick solution method. The goal of this study is to summarize the already established research results of controlling CO2 corrosion, inhibition mechanism of CO2 corrosion inhibitors is reviewed, application status of inhibitor technology in CO2 corrosive environment is discussed. Research status of amides, imidazoline derivatives, quatemary ammonium salts and schiff bases overseas and domestic is highlighted. Finally, an outlook on the development trend of CO2 corrosion inhibitors is presented.
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Pradityana, Atria, Sulistijono, Abdullah Shahab, Lukman Noerochim i Diah Susanti. "Inhibition of Corrosion of Carbon Steel in 3.5% NaCl Solution byMyrmecodia PendansExtract". International Journal of Corrosion 2016 (2016): 1–6. http://dx.doi.org/10.1155/2016/6058286.
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Inhibitor is a substance that is added to the corrosive media to inhibit corrosion rate. Organic inhibitors are preferred to inorganic ones since they are environmentally friendly. One of the organic compounds which is rarely reported as a corrosion inhibitor isMyrmecodia Pendans. The organic compounds can be adsorbed on the metal surface and block the active surface to reduce the rate of corrosion. In this study, the used pipe was carbon steel API 5L Grade B with 3.5% NaCl solution as the corrosion medium. The objective of this research was to analyze the inhibition mechanismMyrmecodia Pendanstowards carbon steel in a corrosion medium. Concentration variations of extractMyrmecodia Pendanswere 0–500 ppm. Fourier Transform Infrared (FTIR) was used for chemical characterization ofMyrmecodia Pendans. Polarization and Electrochemical Impedance Spectroscopy (EIS) were used to measure the corrosion rate and behaviour. From the electrochemical measurements, it was found that the addition of 400 mg/L inhibitor gave the highest inhibition efficiency.Myrmecodia Pendansacted as a corrosion inhibitor by forming a thin layer on the metal surface.
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Wulandari, Pramesti A. D., i M. Noer Ilman. "Corrosion rate of AA 7050 in 3.5% NaCl environment with sodium chromate (Na2CrO4) inhibitor variation". MATEC Web of Conferences 197 (2018): 12002. http://dx.doi.org/10.1051/matecconf/201819712002.
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Aluminium alloy 7050 is widely used for aerospace applications due to its excellent mechanical properties. However, when the airplane is operated and exposed by the corrosive environment, alumina layer of aluminium is not thick enough to provide protection. Therefore, corrosion protection method in the airplane needs to be improved. In the recent experiments, corrosion process in the airplane could be inhibited by corrosion inhibitors that are mixed with a protective coating. In this current study, the effect of sodium chromate inhibitor on the corrosion rate of aluminium alloy AA 7050 has been investigated. The 7050 aluminium alloys in this experiment were machined into specimens for the tensile test, hardness test, corrosion test and metallographic examination. The corrosion test was performed in 3.5% NaCl solution containing 0.1%, 0.3%, 0.5%, 0.7% sodium chromate inhibitor and the results have been compared with the corrosion rate in 3.5% NaCl solution as reference. The tensile test results showed that the ultimate and yield strength were 527.36 MPa and 481.42 MPa. Hardness test results were 175.36 VHN on the short transverse plane, 164.43 VHN on the long transverse plane, and 164.23 VHN on the longitudinal plane. This experimental study can be concluded that the corrosion rate of material decreases with increasing of Na2CrO4 concentration in the solution.
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Nurahman, Titan, Ediman Ginting Suka i Leni Rumiyanti. "PENGARUH KONSENTRASI INHIBITOR KOROSI EKSTRAK KULIT PISANG KEPOK (Musa paradisiaca L) TERHADAP LAJU KOROSI BAJA KARBON API 5L PADA SUHU PERENDAMAN 40OC DAN 80OC". Jurnal Teori dan Aplikasi Fisika 9, nr 2 (31.07.2021): 133–42. http://dx.doi.org/10.23960/jtaf.v9i2.2719.
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Research has been carried out on the effect of the concentration of Kepok banana peel extract as an inhibitor on API 5L carbon steel in 3% NaCl corrosive medium. API 5L carbon steel immersion was carried out for 7 hours with two variations of immersion temperature, namely 40 and 80 oC and five variations in the concentration of corrosion inhibitors, namely 0%, 2%, 4%, 6%, 8%. Corrosion rate testing was carried out using the weight loss method. The results showed that the largest corrosion rates at immersion temperatures of 40 and 80 oC were at 0% inhibitor concentrations, namely 60.91 mm / y and 86.91 mm / y. Meanwhile, the lowest corrosion rate was at the inhibitor concentration of 8% at immersion temperatures of 40 and 80 oC, namely 32.51 mm / y and 63.92 mm / y. The greatest effectiveness of corrosion inhibitors occurred at a concentration of 8% at immersion temperatures of 40 and 80 oC of 56.63%, and 26.44%. The results of the X-Ray Diffraction (XRD) characterization showed that the phase formed was pure Fe. Scanning Electron Microscopy (SEM) characterization showed uneven clusters and smaller size, holes and cracks were also less in 8% inhibitor at immersion temperature of 40 and 80 oC compared to inhibitor 0% at immersion temperature 40 and 80 oC.
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Widyawati, Fauzi, Syamsul Hidayat, Syamsul Bahtiar i Musbihin Musbihin. "Effect of the addition of inhibitors of kirinyuh leaf (Chromolaena Odorata) in methanol extract on corrosion rate of ASTM 36 steel". Jurnal Pijar Mipa 17, nr 6 (30.11.2022): 793–99. http://dx.doi.org/10.29303/jpm.v17i6.4276.
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Kirinyuh leaves (Chromolaena Odorata) contain alkaloids, saponins, flavonoids, phenols, and tannins with the potential as a natural inhibitor that can be used to inhibit the rate of corrosion. Kirinyuh leaf extract inhibitors were added at various concentrations of 100 ppm, 200 ppm, 300 ppm, 400 ppm, and 500 ppm, which were sprayed onto the sample surface before being soaked for seven days. Calculation of the corrosion rate using the method of weight loss (weight loss). The results showed that kirinyuh leaf extract effectively inhibited the corrosion rate. The smallest corrosion rate value was found in the sample with the addition of 400 ppm inhibitor concentration, which was 2.053 ppm. Meanwhile, an efficiency inhibitor was also found in the same concentration of inhibitor that is equal to 87%.
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Ade, Suraj B. "Corrosion Inhibition of Mild Steel in Different Acid Medium by Using Various Acidic Groups of Organic Compounds". International Journal for Research in Applied Science and Engineering Technology 10, nr 2 (28.02.2022): 367–73. http://dx.doi.org/10.22214/ijraset.2022.40288.
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Abstract: Benzoic acid, salicylic acid, Anthranilic acid, 2- Nitro benzoic acid, 2- Chlorobenzoic acid compounds containing acidic group as a corrosion inhibitor for carbon steel was investigated. The study revealed that the various group such as (- COOH, OH, Cl and –NO2) containing in organic compounds has an inhibitory action on the corrosion of carbon steel in the investigated medium. Corrosion rate of mild steel was studied using chemical weight loss method at room temperature. This research paper presents use of carboxylic group organic compounds as corrosion inhibitors for metals in 0.1N, 0.01N and 0.001N (HCl, HNO3 and H2SO4) acidic medium. A common mechanism for inhibiting corrosion involves formation of a coating, often a passivation layer, which prevents access of the corrosive substance to the metal. Organic corrosion inhibitors adsorb on the surface to form protective film, which displace water and protect it against deteriorating. Effective organic corrosion inhibitors contain nitrogen, oxygen, sulphur and phosphorus with lone electron pairs as well can contain structural moieties with π-electrons that interact with metal favouring the adsorption process. This review presents mechanisms and monitoring of corrosion, laboratory methods for corrosion study, relationship between structure and efficacy of corrosion inhibitions, theoretical approach to design new inhibitors and some aspects of corrosion. Keywords: Corrosion, Inhibition, carbon steel, Weight loss and acidic group (-COOH, OH, -Cl and –NO2) group containing organic compounds.
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Kolyada, L. G., E. V. Tarasyuk i A. P. Ponomarev. "Estimation of protective ability, physical and mechanical properties of polymer inhibited films". Ferrous Metallurgy. Bulletin of Scientific , Technical and Economic Information 75, nr 5 (20.06.2019): 601–6. http://dx.doi.org/10.32339/0135-5910-2019-5-601-606.
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Metal products are subjected to atmosphere corrosion during transporting and longtime storing. Utilization of packing materials eliminating the access of water vapor and aggressive gases to the metal products surface is an important ways of struggling against the corrosion. Among the methods of metal products protection against the corrosion, application of volatile inhibitors is one of most effective one. As a carrier of the volatile corrosion inhibitors, polyethylene films can be used. Study of strength and barrier properties of polyethylene films with a volatile corrosion inhibitor and without it accomplished. As an object of the study, the films, produced under laboratory conditions by extrusion with blowing of low-density polyethylene and mixture of low-density polyethylene and IFKhAN volatile inhibitor, developed by the Institute of Physical Chemistry (Academy of Sciences of RF). For accelerated corrosion tests, samples of 08пс cold rolled steel used. The prepared samples packed in the studied films, a part of the closed airtight, and another part – not compact. It was traced, that the samples packed in the polyethylene film without the volatile inhibitor, had a point corrosion. The airtight sealed polymer film casings protect the carbon steel much better, comparing with the not compact casings. The surface of samples corrosion worms, which were airtight packed, was 0.15%, not compact ones – 0.33%. When inhibited polymer film was used for not compact packing, the corrosion had a uniform character, no local corrosion worms (pitting) was observed. The corrosion products were spongy, weekly cohered with the basic metal, easily peeling off. During the test period, the samples airtight packed in polyethylene film, containing IFKhAN volatile inhibitors, had no areas of corrosion. It was found, that input of inhibitor into the polyethylene matrix results in decreasing the film strength properties due to formation structure defects at the sub-molecular level during the extrusion, and also as a result of inhibitor desorption.
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Damayanti, Rizky, Pulung Karo Karo i Agus Riyanto. "Pemanfaatan Biomassa Sebagai Inhibitor Organik Pada Baja Aisi 1020 Di Universitas Lampung". Jurnal Teori dan Aplikasi Fisika 7, nr 2 (31.07.2019): 197–206. http://dx.doi.org/10.23960/jtaf.v7i2.2055.
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Research has been conducted on. The utilization of biomassa as an organic inhibitor in AISI 1020 steel at Lampung University. Samples of carbon steel AISI 1020 were immersed in 3% corrosive medium HCl without being given and given inhibitors of leaf extract jengkol, salam, ketapang and mango 0.8% for 4 and 7 days. inhibitors of leaf extract jengkol, salam, ketapang and mango 0.8% for 4 and 7 days. Calculation of reduction in corrosion rate is carried out by the method of weight loss. The results showed that the addition of Biomasaa inhibitors was effective in reducing the corrosion rate of the samples with the greatest efficiency in the soaking of 7 days of ketapang leaves, which was equal to 74.22%. The results of XRD characterization showed that the phases formed were Fe and Fe2O3 in samples coated with inhibitors and in samples soaked without phase inhibitors Fe2O3 which were corrosion products. The results of SEM characterization showed that the microstructure of the surface of the sample after immersion in the inhibitor contained thin layers overlaying the steel in the sample not coated with the inhibitor, clearly visible cracks and holes indicating that the sample had undergone corrosion.
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Bessarab, O. V., i T. F. Platonova. "Usage of food additives for improvement the quality and safety of fruit canned food in metallic packaging". Proceedings of the Voronezh State University of Engineering Technologies 80, nr 3 (17.12.2018): 170–75. http://dx.doi.org/10.20914/2310-1202-2018-3-170-175.
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Because of the metal packaging corrosion, during storage of canned food the quality deteriorates.One of the ways to reduction of quality loss and increase the shelf life of canned products is the use of food additives - corrosion inhibitors. From the literary data it is known that pectin and gelatin are corrosion inhibitors whose action is based on adsorption to the metal surface.Besides the usual gelatin, in the work we used hydrolyzed gelatin, which does not increase in the viscosity of the liquid phase.The aim of the present work was to study the effect of pectin, gelatin and hydrolysed gelatin on the tinplate corrosion rate in the liquid phase of stone fruit compotes (cherries, merries, peaches and plums). The corrosion rate was measured by the method of linear polarization resistance, based on the creating a potential difference between two identical samples of metal and measuring the amperage.The measurements were carried out using the universal automatic corrosion-meter "Expert-004".For all corrosive media, the corrosion rate kinetics is as follows: at the beginning of the test, the maximum corrosion rate of tinplate is observed, which decreases to a stationary value within 24-36 hours. The presence of inhibitors has not effect the kinetics of the process, but the steady-state corrosion rate for the liquid phase of compote from cherries decreased 1.6 - 3 times, for the liquid phase of compote from peaches - by 1.9 times.For the liquid phase of compotes from merries and plums, the application of pectin and hydrolysed gelatin does not has an inhibitory effect.The greatest inhibitory effect for the liquid phase of compotes from cherries is observed when applying 0.5% hydrolyzed gelatin - without an inhibitor, the steady-state corrosion rate of tinplate was 8.3 ?m / year, with the inhibitor - 2.8 ?m / year. According to the results of the study, it was found that in order to reduce quality losses during the storage of stone fruit compotes in a metal package, it is advisable to apply hydrolyzed gelatin in an amount of 0.5% to the mass of the liquid phase.
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Kim, K. T., H. Y. Chang, B. T. Lim, H. B. Park i Y. S. Kim. "New Mechanism on Synergistic Effect of Nitrite and Triethanolamine Addition on the Corrosion of Ductile Cast Iron". Advances in Materials Science and Engineering 2016 (2016): 1–14. http://dx.doi.org/10.1155/2016/4935602.
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In general, we compared the different inhibition mechanisms of organic inhibitor with that of anodic inhibitor. When triethanolamine or nitrite was added separately to tap water for inhibiting the corrosion of ductile cast iron, large amounts of inhibitor were needed. This is because the corrosion inhibitors had to overcome the galvanic corrosion that occurs between graphite and matrix. In this work, we investigated the corrosion of ductile cast iron in tap water with/without inhibitors. The corrosion rate was measured using chemical immersion test and electrochemical methods, including anodic polarization test. The inhibited surface was analyzed using EPMA and XPS. Test solutions were analyzed by performing FT-IR measurement. When triethanolamine and nitrite coexisted in tap water, synergistic effect built up, and the inhibition effect wasca.30 times more effective than witnessed with single addition. This work focused on the synergistic effect brought about by nitrite and triethanolamine and its novel mechanism was also proposed.
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Malau, Viktor, i Wisnu Hakiki. "Chromate and Molybdate Inhibitors Effects on Corrosion Charateristic of API 5L Grade B in a Brine Water Solution Containing 8 % NaCl". Key Engineering Materials 892 (13.07.2021): 115–23. http://dx.doi.org/10.4028/www.scientific.net/kem.892.115.
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Piping systems at gathering stations in the oil and gas industries often fail due to corrosion attacks from the brine water solution containing 8% NaCl that flows through the system. This solution is highly corrosive on the API 5L grade B steel pipes, thereby shortening its lifespan, with an increase in the frequency of pipe replacements. However, the corrosion resistance of API 5L grade B pipes can be improved by using chromate and molybdate inhibitors. Therefore, the objective of this research is to improve the corrosion resistance of the steel pipes using sodium chromate (Na2CrO4) and sodium molybdate (Na2MoO4) inhibitors with concentrations of 0.2, 0.4, 0.6, 0.8 and 1,0%. This research also aim to determine the optimum concentration of inhibitors to produce minimum corrosion rate, by testing the brine water solution containing 8% NaCl through the potentiodynamic polarization method. The results show that generally, the addition of sodium chromate and sodium molybdate inhibitors to the brine solution causes the steel pipes to be more resistant to corrosion. Furthermore, the sodium chromate inhibitor concentration of 0.6% produces the greatest corrosion potential of – 400 mV with the lowest rate of 0.38 mpy, while sodium molybdate concentration of 0.4% produces the highest corrosion potential of – 385 mV with the lowest rate of 0.34 mpy. The results of SEM observations at 0.4% sodium molybdate concentration showed that the corrosion inhibition/passivation effect of the inhibitor made the steel surface smoother, while the sodium chromate inhibitor at similar percentage failed to reach the optimal concentration to inhibit the corrosion process.
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Lee, Han Seung, i Hwa Sung Ryu. "Anti-Corrosion Properties of the Reactive Anode and Cathode Inhibitor by Electrochemical Treatment in Aqueous". Applied Mechanics and Materials 284-287 (styczeń 2013): 31–34. http://dx.doi.org/10.4028/www.scientific.net/amm.284-287.31.
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The durability of a concrete structure is most significantly influenced by the corrosion of reinforcing bars, rather than by the deterioration of concrete itself. The corrosion of reinforcement bars due to chloride serves as a main deterioration factor at the interface between the bars and the concrete in the concrete structure. Accordingly, the corrosion inhibitors are widely used to improve the resistance to chloride penetration into reinforced concrete. Corrosion inhibitors are generally divided into the anode-type inorganic inhibitors and anode-cathode-type organic inhibitors, in terms of the reaction type. It is known that when the Cl-:OH- concentration ratio exceeds 0.6%, film on passive state metal on the bar-concrete interface is damaged and local corrosion starts regardless of the chloride ion content. In this study, the performance of the corrosion inhibitor was examined using a potentiostat, with chloride ion contents of 1.2kg/m3 (as reference), 2.4kg/m3, and 4.8kg/m3. The variables were the inhibitor type, Cl-:OH- molar ratio according to the addition of anode-type inorganic corrosion inhibitor (four ratios: 0.0%, 0.3%, 0.6% and 1.2%), and ratio compared to the standard anode-cathode-type organic corrosion inhibitor liquid (four ratios: 0.0, norm 1/2, norm, norm 2 times). As a result, with the anode-type inorganic nitrite corrosion inhibitor, the corrosion inhibition performance was verified with a corrosion potential of -0.30V at a molar ratio of 0.3% or higher when the chloride ion content was 1.2kg/m3, and at a molar ratio of 0.6% or higher when the chloride ion content was 2.4kg/m3 or 4.8kg/m3. With the anode-cathode-type organic corrosion inhibitor, the corrosion inhibition performance was very good at half the standard quantity (0.42kg/m3) regardless of the chloride ion content. From the added corrosion inhibitor quantities, the anode-cathode-type organic corrosion inhibitor had a better corrosion inhibition performance than the anode-type inorganic nitrite corrosion inhibitor.
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Nasser, Rabab M., i Nora M. Masmali. "The effectiveness of Tamarindus Indica extracts as a metal corrosion inhibitor in various circumstances". Anti-Corrosion Methods and Materials 69, nr 3 (3.03.2022): 224–33. http://dx.doi.org/10.1108/acmm-06-2021-2490.
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Purpose Plant development and use as green corrosion inhibitors are already recognized as one of the most environmentally friendly and effective protocols. In recent years, efforts have been made to find green corrosion inhibitors as an alternative to synthetic inhibitors for metals in acid medium. This paper aims to report the investigation of use of aqueous extracts of Tamarindus Indica as green inhibitors for corrosion of metals within different circumstances. Design/methodology/approach The use of Tamarindus Indica extracts (leaves, stem, fruit pulp and fruit husk) as corrosion inhibitors for mild steel and aluminum in different mediums (HCl, H2SO4, formic acid and citric acid) at different temperatures was investigated. Findings The inhibitory efficiency of Tamarindus Indica extracts increases with increasing concentration and decreases with increasing temperature. Langmuir is the adsorption isotherm, and the extract (inhibitor) is a mixed-type inhibitor (physisorption and chemisorption). Practical implications Tamarindus extracts (leaves, stem, fruit pulp and fruit husk) are effective inhibitors and can be used to protect metals from corrosion at different circumstances. Originality/value To the best of the authors’ knowledge, this is the first review that discusses the use of Tamarindus Indica extracts as corrosion inhibitors for metals.
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Ivanova, A. G., L. N. Krasilnikova, O. S. Lezova, O. A. Zagrebelny, R. S. Khodzhaev, T. V. Khamova, V. I. Trusov i O. A. Shilova. "Electrochemical properties of anticorrosive coatings based on organosilicate composition in combination with corrosion inhibitors". Perspektivnye Materialy 7 (2022): 66–74. http://dx.doi.org/10.30791/1028-978x-2022-7-66-74.
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The article considers the effect of atmospheric corrosion inhibitors “NOTEH”, “N-M-1”, “FMT” and phosphating primer VL-02 on the electrochemical properties of anticorrosive coatings based on a new modification of the organosilicate composition — brand OS-51-03M. For corrosion tests using the method of potentiodynamic polarization, carbon steel plates of the St3sp5 brand were used, on which coatings were applied by the paint and varnish method. It was revealed that the aqueous phosphating composition “NOTEH” and the corrosion inhibitor “N-M-1” significantly increase the corrosion resistance of organosilicate coatings in an aggressive environment — 3 % NaCl solution. For these coatings, it is impossible to register the current and corrosion potential after 1 month of exposure of coatings in a corrosive environment. Under similar measurement conditions, the electrochemical parameters of steel plates with unmodified organosilicate coating were recorded — the corrosion current density and corrosion potential were equal to 8·10-9A/m2 and –144 mV, respectively. It was revealed that the phosphating primer VL-02 has a negligible effect on increasing the duration of anticorrosive protection of the organosilicate coating system. The type of inhibitory protection of atmospheric corrosion inhibitors has been determined.
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Desiasni, Rita, Mardiana Mardiana i Syamsul Hidayat. "Corrosion inhibition efficiency of moringa leaf extract (Moringa oleifera) against A36 steel". Jurnal Pijar Mipa 16, nr 5 (11.11.2021): 600–607. http://dx.doi.org/10.29303/jpm.v16i5.2969.
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The use of inhibitors is one of the most effective ways to control corrosion. The study aims to determine and examine more deeply the effect of variations in the concentration of organic inhibitors from Moringa leaf extract on the corrosion rate of A36 steel material in seawater media. Moringa leaf extract's effectiveness in inhibiting the corrosion rate of A36 steel material in seawater media is also determined. This research was conducted by immersing specimens with inhibitor concentrations of 0 ppm, 100 ppm, 200 ppm, 300 ppm, 400 ppm, and 500 ppm for seven days of immersion. The corrosion rate is calculated using the weight loss method. The results showed that the corrosion rate decreased with the inhibitor concentration in the corrosion media. The inhibitor concentration of 500 ppm Moringa leaf extract was able to inhibit the corrosion rate optimally. It is indicated by the smallest corrosion rate value of 1.07 mpy. On the other hand, the inhibitor efficiency increases with the inhibitor concentration in the corrosion media. The highest inhibitor efficiency was 78.71% at the addition of 500 ppm inhibitor to the solution.
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Agboola, Oluranti, Toluwani Adedoyin, Ojo Sunday Isaac Fayomi, Ayoola Ayodeji, Samuel E. Sanni, Augustine Omoniyin Ayeni, Patricia Popoola i in. "DNA Inhibition of Hydrogen Ion-Induced Corrosion of Mild Steel Used for Pipelines in Oil and Gas Industries". Asian Journal of Chemistry 33, nr 4 (20.03.2021): 767–74. http://dx.doi.org/10.14233/ajchem.2021.22686.
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Corrosion of mild steel via chemical reaction in a corrosive environment is a problematic occurrence that is very common in oil and gas industries. Corrosion constitutes a huge part of the total costs in the production of oil and gas. Corrosion inhibitors have found interest in the scientific domain because they are mainly understood by their chemical complexes and formulations. Their utilization in small amount on metal surface used in oil and gas industries can help shield the metal from corrosion devoid of any significant alteration in the concentration of the corrosive media in the environment. An effort was made to study the possibility of using calf thymus gland DNA (CTGDNA) inhibitor in chlorine induced mild steel for possible usage in piping in oil and gas industry. The SEM micrograph shows that the adsorption of the CTGDNA biomacromolecules coat on the mild steel surfaces functions as a protection against HCl corrosive solution. Electrochemical study and weight loss analysis showed that the inhibitor efficiency (70.48 and 72%, respectively) of the tested DNA (CTGDNA) in HCl acidic corrosion environment for the mild steel was high at 1.5 M of HCl. The inhibitor efficiency decreased with increasing HCl concentrations. The open circuit potential (OPC) revealed that the mild steels got corroded until the end of the immersion. The intensities of XRD peak substantiate the existence of corrosion products of FeCl2.
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Ismail, A., i Mohd Fuzaimie Ahmad Fuad. "Effect of Immersion and Green Inhibitor to Corrosion Rate of Carbon Steel". Advanced Materials Research 1087 (luty 2015): 276–81. http://dx.doi.org/10.4028/www.scientific.net/amr.1087.276.
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Corrosion is the reaction between the material and the environment that cause degradation of the material. Corrosion reduces the essential properties of materials such as strength, appearance, toughness and life expectancy. Carbon steels are composed of a mixture of metallic iron and carbon and being used extensively in every sector due to good mechanical properties and good cost. However, carbon steel are every susceptible to corrosion attack especially in corrosive environment. The use of inhibitors is one of the best options to protect against corrosion on metals and alloys especially in a closed system. Inhibitor is a chemical substance which can reduce corrosion attack when added into electrolyte. The organic inhibitor used in this study was from banana peel (scientific name Musa sapieutum) to extract tannin-a compound which can provide protective layer on metal [1-3]. The results elucidate that banana peel can be used as green inhibitor on canbon steel, however, the effect only can be seen when added with 10% and more. The immersion test was done to evaluate the effect of corrosion product to corrosion rate. The results explained that corrosion rate fluctuated during immersion period due to developed and dissolved of soluble product into electrolyte. The research provide a set of data elucidate that corrosion product developed on carbon steel cannot provide corrosion protection on carbon steel, however, using green inhibitor in high concentrations which is purely not harmful to environment could prevent corrosion attack on carbon steel.
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Sharma, Manish Kumar, Anil Kumar Sharma i S. P. Mathur. "Solanum surrattence as Potential Corrosion Inhibitor". ISRN Corrosion 2012 (28.08.2012): 1–5. http://dx.doi.org/10.5402/2012/907676.
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Developping chip and ecofriendlly corrosion inhibitors can replace toxic chemicals which are currently used in industries. Plant extract of Solanum surrattence in acetone, petroleum ether, and methanol has been tasted using mass loss and thermometric measurements for corrosion of aluminium in acid solutions. The plant extract of Solanum surrattence is a good corrosion inhibitor for aluminium. The inhibition efficiency depends upon the concentration of inhibitors, it inhibits the metal of 97.60% at its maximum value. This inhibitor shows efficiency at 25°C. At higher temperature the inhibition efficiency decreases. These types of inhibitors can be used to replace the toxic chemicals which are currently used in industries. We find out cheap and ecofriendlly corrosion inhibitors which can be used by acid, petrochemical, and chemical industries.
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Marlianto, Eddy. "Efficiency of Ketapang (Terminalia catappa L.) Leaves Tannin Extract as Organic Inhibitor Against Corrosion Rate of Iron Metal in Seawater". Journal of Technomaterials Physics 2, nr 1 (28.02.2020): 63–69. http://dx.doi.org/10.32734/jotp.v2i1.5268.
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The research is about effect of immersion time and mechanical properties on the rate of corrosion of ferrous metals by the addition of Ketapang (Terminalia catappa L.) leaf extract as an organic inhibitor in the seawater environment. In this study, ketapang leaf extract was used as a natural inhibitor to inhibit the rate of corrosion of ferrous metals. This inhibitor is used on iron metal plates which are immersed in corrosive media, namely sea water with variations in the composition of the inhibitors used at 0; 10% V; 20% V, and 40% V, with immersion time of 3 and 6 days. The characterizations tested included measurement of density, corrosion rate, inhibitor efficiency, and hardness testing using the Vickers method. From the measurement results, the density value decreases with the addition of the concentration of the inhibitor both on immersion 3 days and 6 days. The value of hardness increases with increasing composition of the inhibitor. The optimum hardness value is 165.03 N/m2 with immersion time of 6 days at an inhibitor concentration of 40% and a minimum hardness value of 145.603 N/m2 on immersion 6 days with no inhibitor. The smallest corrosion rate was obtained by samples with a composition of 40% inhibitor of 2.77 mpy with immersion time of 3 days and 1.33 mpy with immersion time of 6 days. And the efficiency value of Ketapang leaf extract inhibitors reached 47.01 % in the composition of 40% in the seawater environment with immersion time of 6 daysketapang leaves
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Pratikno, Herman, Harmin Sulistiyaning Titah i Yossy Kurnia Shandy. "Bio-Inhibitor on Corrosion Rate of ASTM A53 Steel in Marine Environment". MATEC Web of Conferences 177 (2018): 01019. http://dx.doi.org/10.1051/matecconf/201817701019.
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There are many methods to prevent the corrosion process. One of them is corrosion inhibitors usage. Inhibitor divided into two types, there are organic inhibitor and non-organic inhibitor. Organic inhibitor could be obtained by extracting some materials which exist in nature. In this research, bio-inhibitors were made from rambutan (Nephelium lappaceum) peel, banana (Musa acuminata Colla) peel, mango (Mangifera indica L.) leaves and papaya (Carica papaya)leaves. The determination of corrosion rate used weight loss method. The material of carbon steel ASTM A53 was used in the research. The salinity of artificial seawater was 35 ‰. The results showed that corrosion rate on carbon steel ASTM A53 was 0.2172 mpy at mango leaves and the efficiency of those inhibitor was 44.5%. The corrosion rate carbon steel ASTM A53 was 0.2436 mpy for corrosion rate and 37.8% of inhibitor efficiency when it used papaya leaves as bioinhibitor. Meanwhile, it reached 0.2739 mpy and 0.2812 mpy of corrosion rate for banana peel and rambutan peel, respectively. The efficiency of inhibitor were 30% and 28.2% for banana peel and rambutan peel, respectively. The corrosion rate on carbon steel ASTM A53 without inhibitor was 0.3914 mpy. Based on the microstructure results, all specimens in all variation of treatments showed pitting corrosion and uniform corrosion on specimen. In conclusion, mango leaves, papaya leaves, banana peel and rambutan peel have potentially to be used as bio-inhibitor to decrease the corrosion rate in marine environment.
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Raheem, Dina. "Evaluation of Mixed Corrosion Inhibitors in Cooling Water System". Journal of Petroleum Research and Studies 3, nr 1 (6.05.2021): 131–51. http://dx.doi.org/10.52716/jprs.v3i1.67.
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The effect of mixed corrosion inhibitors in cooling system was evaluated by using carbon steel specimens and weight loss analysis. The carbon steel specimens which immersed in mixture of sodium phosphate ( Na2HPO4 ) used as corrosion inhibitor and sodium glocunate ( C6 H11 NaO7 ) as scale dispersant at different concentrations (20,40, 60, 80 ppm) and at temperature 25°C for (1-5) days. The corrosion inhibitors efficiency was calculated by using uninhibited and inhibited water to give 98.1%. The result of these investigation indicate that the corrosion rate decrease with increase the corrosion inhibitors concentration at 80 ppm and for 5 days, (i.e. corrosion rate= 0.042 gmd).
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Sun, Shoumin, Yang Li, Kejing Gao, Li Cheng, Xue Yang i Ruiquan Liao. "Synthesis of a Hydroxyl-Containing Corrosion Inhibitor and Its Inhibitory Performance on N80 Steel in Hydrochloric Acid Solution". Coatings 12, nr 12 (16.12.2022): 1975. http://dx.doi.org/10.3390/coatings12121975.
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In the process of petroleum exploitation, in order to effectively inhibit the corrosion damage of acid to metal equipment. Mannich base corrosion inhibitors are generally added to inhibit the corrosion damage of acid. In order to enhance the solubility of Mannich base corrosion inhibitor. This paper intends to introduce hydrophilic groups to enhance the solubility of the Mannich base corrosion inhibitor. In this paper, two efficient corrosion inhibitors 3-(2-hydroxyethylamino)-1-phenylpropan-1-one (MY1) and 3-(2-aminoethylamino)-1-phenylpropan-1-one (MY2), were synthesized based on the Mannich reaction, using formaldehyde, acetophenone and ethanolamine/ethylenediamine as reaction raw materials. The corrosion inhibition performance of the inhibitor on N80 steel in 15% (mass fraction) hydrochloric acid solution was studied by means of the static weight loss method, electrochemical test and optical contact angle analysis. It could be seen from the static weight loss method that the corrosion rate in the hydrochloric acid solution before and after adding 0.7% (mass fraction) corrosion inhibitor concentration decreased from 129.39 g·m−2·h−1 to 1.45 g·m−2·h−1 and 2.79 g·m−2·h−1, respectively. The corrosion inhibition rate could reach 98%, indicating that both inhibitors had good corrosion inhibition performance, and the corrosion inhibition effect of MY1 was better than that of MY2. It was found from the electrochemical tests that the two inhibitors were mixed corrosion inhibitors mainly inhibiting the anodic reaction, and both inhibitors belonged to spontaneous adsorption, and their adsorption behaviors followed the Langmuir adsorption isotherm. In addition, the surface of N80 steel was characterized by SEM, EDS elemental mapping and contact angle measurement. The results show that a dense hydrophobic film is formed on the surface of the steel sheet after the addition of a corrosion inhibitor, which prevents corrosion.
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Musa, Mukhtaruddin, Mohd Hanafi Ani i Raihan Othman. "Natural Corrosion Inhibitor for Corrosion Protection of Metal Artefact: An Overview". Advanced Materials Research 701 (maj 2013): 323–28. http://dx.doi.org/10.4028/www.scientific.net/amr.701.323.
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The degradation of most of metals, with the exception of gold is a universal reaction. It is a constant and on-going problems, make it often difficult to eliminate completely causing either industrial or heritage conservation losing a lot of money. One way and most practical for corrosion protection are using green inhibitor. Therefore it is widely use either industry or heritage conservation. Unfortunately, the inhibitors used in conservation are frequently hazardous to conservator, either through inhaler or touch with skin. Responding to this, several researches has been conducted to look into environmental friendly inhibitors or green inhibitors. This paper will review current practice use of inhibitor in metal preservation before propose a new inhibitor which been used a long time ago in Malay traditional practice in Keris preservation.
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Wang, Bin, Min Du i Jing Zhang. "Study of the Inhibition Mechanism of Imidazoline Derivative Inhibitor on CO2 Corrosion for Q235 Steel". Advanced Materials Research 79-82 (sierpień 2009): 981–84. http://dx.doi.org/10.4028/www.scientific.net/amr.79-82.981.
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Imidazoline derivative inhibitors are successfully used in oil-gas field for CO2 and H2S corrosion. The inhibition performance and inhibition mechanism of imidazoline with thioureido to prevent corrosion of steel in saltwater saturated with CO2 were studied by polarization curves and electrochemical impedance spectroscopy (EIS), in the meantime, quantum chemical analysis was used to analysis the results. The results of electrochemical measurements indicated that the inhibitor belonged to mixed-type inhibitor which mainly inhibited anodic process and worked as “negative catalysis”. The inhibition efficiencies increased then decreased with the increase in inhibitor concentration. The electrochemical results have also been supplemented by quantum chemical analysis. It was found that the chemical adsorption of the imidazoline with thioureido molecule on Q235 steel depended on the imidazoline ring and thioureido, thus the inhibitor had good corrosion inhibition.
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Porcayo-Calderon, Jesus, Jorge Canto, L. M. Martinez-de-la-Escalera i Adrian Neri. "Sweet Corrosion Inhibition by CO2 Capture". Molecules 27, nr 16 (16.08.2022): 5209. http://dx.doi.org/10.3390/molecules27165209.
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The most practical and economical way to combat the problems derived from CO2 corrosion (sweet corrosion) is the use of corrosion inhibitors of organic origin. Its main protection mechanism is based on its ability to adsorb on the metal surface, forming a barrier between the metal surface and the aggressive medium. However, despite its excellent performance, its inhibition efficiency can be compromised with the increase in temperature as well as the shear stresses. In this study, the use of an inorganic inhibitor is proposed that has not been considered as an inhibitor of sweet corrosion. The reported studies are based on using LaCl3 as a corrosion inhibitor. Its behavior was evaluated on 1018 carbon steel using electrochemical measurements, such as potentiodynamic polarization curves, open-circuit potential measurements, linear polarization resistance measurements, and electrochemical impedance. The results showed an inhibition efficiency of the sweet corrosion process greater than 95%, and that the inhibition mechanism was different from the classic corrosion process in CO2-free electrolytes. In this case, it was observed that the inhibitory capacity of the La3+ cations is based on a CO2-capture process and the precipitation of a barrier layer of lanthanum carbonate (La2(CO3)3).
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Li, Ke Hua, Bing Bing Yang, Zhi Wei Lan, Ren Fang Wang i Tie Jun Su. "The Research of Thiosemicarbazide Modified as Acidizing Corrosion Inhibitor". Applied Mechanics and Materials 723 (styczeń 2015): 605–9. http://dx.doi.org/10.4028/www.scientific.net/amm.723.605.
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Corrosion inhibition of N80 steel in 15% HCl was investigated in the absence and presence of different concentrations of some thiosemicarbazide derivatives (Mannich baseI, Mannich baseII) by weight loss, potentiodynamic polarization techniques. The adsorption of Mannich bases obeyed Langmuir adsorption isotherm. Both thermodynamic and activation parameters were calculated and discussed. The absorption process of Mannich base corrosion inhibitors on the surface of N80 steel is spontaneous, endothermic and entropy increase process. Polarization curves indicated that the inhibitor of Mannich bases are the mixed corrosion-controlling one which inhibited anodie corrosion. The results obtained from weight loss, Potentiodynamic polarization are in good agreement.
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Hassan, Refat, Ishaq Zaafarany, Adil Gobouri i Hideo Takagi. "A Revisit to the Corrosion Inhibition of Aluminum in Aqueous Alkaline Solutions by Water-Soluble Alginates and Pectates as Anionic Polyelectrolyte Inhibitors". International Journal of Corrosion 2013 (2013): 1–8. http://dx.doi.org/10.1155/2013/508596.
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The corrosion behavior of aluminum (Al) in alkaline media in presence of some natural polymer inhibitors has been reinvestigated. The inhibition action of the tested inhibitors was found to obey both Langmuir and Freundlich isotherms models. The inhibition efficiency was found to increase with increasing the inhibitors concentration and decrease with increasing the temperature, suggesting physical adsorption mechanism. Factors such as the concentration and geometrical structure of the inhibitor, concentration of the corrosive medium, and temperature affecting the corrosion rates were examined. The kinetic parameters were evaluated, and a suitable corrosion mechanism consistent with the kinetic results obtained is suggested and discussed.
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Mackenzie, C., C. Rowley-Williams, M. Achour, D. Blumer, M. Joosten i M. Rowe. "Potential for Measurement of Corrosion-Inhibitor-Micelle Presence as an Indicator of Optimum Dose". SPE Journal 17, nr 02 (24.01.2012): 393–401. http://dx.doi.org/10.2118/130285-pa.
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Summary This paper discusses the principle and proof of concept of a novel corrosion-management tool based on maintaining optimum corrosion-inhibitor dose in an inhibited environment. Film-forming corrosion inhibitors typically contain active ionic surfactant molecules, which adsorb on surfaces and form a protective barrier against corrosion. Upon saturation of surfaces by the inhibitor, the molecules are found in the aqueous phase as micelles or in the oil phase as reverse micelles. The proposed technique is based on the hypothesis that the presence of these micelles in the water phase could be used to indicate the total surface coverage and, therefore, the optimum dose. The technique has been applied in the laboratory simulating an actual inhibited multiphase production system. Fluorescent markers, which are extremely sensitive to micelle presence, have been developed and used during the laboratory testing. Results were compared with those from standard laboratory techniques, including interfacial tension (IFT) and particle-size analyses (diffraction), in order to determine the efficacy for micelle detection. Corrosion bubble tests were also used to determine any link to inhibitor efficiency. IFT results showed complex events occurring with increasing inhibitor concentration. The IFT vs. inhibitor concentration curve was nonclassical, probably because of the multicomponent nature of inhibitor formulations, but suggested micelle formation at approximately 150 ppm. Fluorescence analysis suggested that micelles formed starting at a 150-ppm dose. Particle-size analysis was consistent with micelle presence beyond this concentration. Separate experiments comparing fluorescence with corrosion rates demonstrated an apparent nonlinear variance with inhibitor concentration, supporting the hypothesis. The analytical comparisons supported the underlying principles of this micelle-detection technology. Development of a portable device is under way and will provide an important new tool for proactive corrosion management in the oil field as well as a useful laboratory qualification method.
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Algburi, Abbas Kh Ibrahim. "Effect of heat and mass transfer on corrosion of carbon steel in a crude oil medium using corrosion inhibitors sodium nitrate and castor oil under different circumstances". Journal of Petroleum Research and Studies 12, nr 3 (11.09.2022): 71–91. http://dx.doi.org/10.52716/jprs.v12i3.525.
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In the petroleum industry, corrosion is a fundamental problem that causes many operational and commercial problems, which require careful consideration and comprehensive studies in order to discover suitable solutions. Among these problems is the occurrence of corrosion in the crude oil production equipment as well as in the transportation pipelines of petroleum products, which leads to their failure; thus, increasing the cost as a result of maintenance or replacement. To protect them from corrosion, different types of inhibitors are commonly used, in which small amounts of inhibitor are continuously injected, slowly forming a thin layer of inhibitor between them and the corrosive materials to protect them from corrosion. In this study, the performance of the corrosion process was examined under varying temperatures, namely 20, 30, 40, 50 and 60 °C, at rotational speeds of 0, 500, 1250 and 2000 rpm. The concentrations of sodium nitrate (NaNO3) inhibitor were 0, 0.5, 1.0 and 1.5 g/l of crude oil, whereas the concentrations of castor oil inhibitor were 0, 0.5, 1.0 and 1.5 ml/l of crude oil. The results demonstrated that the corrosion rate of carbon steel in the crude oil decreases with the increase in the concentration of both types of inhibitors (NaNO3 and castor oil), while it increases with the rise in temperature and rotational speed. It was determined that the maximum efficiency of the green inhibitor (castor oil) in the crude oil was 93.7% at a concentration of 1.5 ml/l, temperature of 20 °C and a rotational speed of 0 rpm, while the maximum efficiency of the chemical inhibitor (NaNO3) in the crude oil was 98.6% at a concentration of 1.5 g/l, temperature of 20 ℃ and rotational speed of 0 rpm.
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Yang, Hyun-Min. "Role of Organic and Eco-Friendly Inhibitors on the Corrosion Mitigation of Steel in Acidic Environments—A State-of-Art Review". Molecules 26, nr 11 (7.06.2021): 3473. http://dx.doi.org/10.3390/molecules26113473.
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Steel has versatile application in chemical, structure and construction industries owing to its mechanical properties. However, it is susceptible to corrosion in acid environments. Thus, it requires to protect the steel from corrosion. Different types of corrosion resistance steel, coatings and inhibitors are developed to mitigate the corrosion, but, inhibitor is the best remedies to control the corrosion of steel in acid condition. Moreover, organic and green inhibitors used in acid condition for descaling, acid pickling, pipelines, boiler tubes and oil-wells. Organic inhibitors reduce the dissolution of steel in acid but, it is hazardous, expensive and needs expertise to synthesize the inhibitor. Therefore, there is utmost required to study and compile the latest research about the eco-friendly corrosion inhibitors, which showed more than 90% corrosion inhibition efficiency. In the present study, I have reviewed the state-of-arts, and compile the latest development in organic and eco-friendly corrosion inhibitor used in acid environment as well as suggested about the future scope and role of green inhibitor for sustainable society, which is economical, less hazardous and readily available from the natural sources.
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Sezer, Esma, i İpek Öztürk. "Mild steel protection with tannic and polyaspartic acid in cooling systems". Anti-Corrosion Methods and Materials 66, nr 5 (2.09.2019): 583–94. http://dx.doi.org/10.1108/acmm-04-2019-2105.
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Purpose Tannic acid (TA) is one of the green corrosion inhibitors for mild steel; its anti-corrosive performance in alkaline water on mild steel when it is used together with polyaspartic acid (PASA) still has not been investigated. The purpose of this study is to develop an effective, biodegradable and environment-friendly novel corrosion inhibitor based on TA and PASA as an alternative to the conventional inorganic inhibitors for mild steel in decarbonised water, which is common in cooling systems. Design/methodology/approach Corrosion inhibition mechanism is investigated by electrochemical techniques such as polarisation measurements and electrochemical impedance spectroscopy, and results were evaluated to determine the optimum inhibitor concentration for industrial applications. Additionally, practice-like conditions are carried out in pilot plant studies to simulate the conditions in cooling systems. Thus, the efficiencies of the inhibitors are evaluated through both weight loss and linear polarisation resistance measurements. Moreover, the corrosion product is characterised by scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDX) and Fourier-transform infrared spectroscopy (FTIR) analysis. Findings TA shows high inhibition efficiency especially towards pitting corrosion for mild steel in decarbonised water. PASA addition in the cooling systems improves the inhibition efficiency of TA, and at lower concentrations of TA + PASA, it is possible to obtained better inhibition efficiency than TA alone at higher inhibitor amounts, which is essential in economic and environmental aspect. Originality/value A blended inhibitor program including TA and PASA with suggested concentrations in this work can be used as an environmental friendly treatment concept for the mild steel corrosion inhibition at cooling systems.