Gotowe bibliografie tematyczne / Blend Electrolytes Structure

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Gotowa bibliografia na temat „Blend Electrolytes Structure”

Autor: Grafiati

Data publikacji: 7 września 2023

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Artykuły w czasopismach na temat "Blend Electrolytes Structure"

Yang, Yan, Jie Tao i Li Ma. "Study on Properties of Quasi Solid Polymer Electrolyte Based on PVdF-PMMA Blend for Dye-Sensitized Solar Cells". Materials Science Forum 610-613 (styczeń 2009): 347–52. http://dx.doi.org/10.4028/www.scientific.net/msf.610-613.347.

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Poly(vinylidene fluoride)(PVDF) is photochemically stable even in the presence of TiO2 and Pt nanoparticles, and poly(methacrylate)(PMMA) has good solvent retention. The quasi-solid electrolytes based on PVDF-PMMA blend polymer were prepared in this work by soaking a porous membrane in an organic electrolyte solution containing the I−/I3− redox couple. The as-prepared electrolytes were characterized by means of Fourier Transform Infrared Spectroscopy, Scanning Electron Microscope respectively. Moreover, the conductivity and the voltage-current curves of the electrolytes were measured by electrochemical workstation. The results indicated that the optimum blend proportion of PVDF and PMMA was 6:4. The porous structure prepared with the addition of propanetriol was beneficial to ion diffusion and thus enhanced the conductivity of the electrolytes. The gel polymer electrolyte had a conductivity of 0.14 mS•cm-1 under the ambient atmosphere. Furthermore, electrolytes were assembled to fabricate DSSCs and the performance of the cells was tested. The good properties with the open-circuit voltage of 0.60V and the short-circuit current of 1.1mAcm-2 were achieved upon illumination with visible light.

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Ganesan, SV, M. Selvamurugan, M. Thamima, S. Karuppuchamy i KK Mothilal. "Effect of Different Lithium Salts on the Structure and Morphology of Polystyrene-co-acrylonitrile Based Composite Solid Polymer Electrolytes". Shanlax International Journal of Arts, Science and Humanities 8, S1-May (15.05.2021): 21–26. http://dx.doi.org/10.34293/sijash.v8is1-may.4498.

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In the present study, a series of poly(styrene-co-acrylonitrile) (SAN) polymer electrolytes and SAN- poly(vinyl alcohol) (PVA) polymer blend electrolytes were prepared with different lithium salts using a solvent casting technique. The morphology of prepared polymer blend electrolytes was studied by XRD studies. FT-IR spectroscopy studies reveal the interaction between polymer host and the lithium salt.

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Khan, Mohammad Saleem, Rahmat Gul i Mian Sayed Wahid. "Studies on thin films of PVC-PMMA blend polymer electrolytes". Journal of Polymer Engineering 33, nr 7 (1.10.2013): 633–38. http://dx.doi.org/10.1515/polyeng-2013-0028.

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Abstract Thin films of poly (vinyl chloride) (PVC)/poly (methyl methacrylate) (PMMA) blend polymers complexed with different concentrations of LiClO4 salt, containing ethylene carbonate (EC) as the plasticizer, were fabricated by the solution cast procedure. Ionic conductivity, thermal stability and X-ray diffraction (XRD) studies were undertaken. AC impedance measurements were done in the temperature range of 20–70°C. The highest ionic conductivity at room temperature was found to be 2.23×10-5 S cm-1 for the sample containing 15 wt% of LiClO4 salt. The XRD technique was used to investigate the structure and complex formation of solid polymer electrolytes. There was a decrease in degree of crystallinity. The amorphous nature of complexed solid polymer blend electrolyte films increased, due to the addition of LiClO4 salt. Thermogravimetric analysis (TGA) and differential thermal analysis (DTA) revealed the effect of salt on the thermal stability of the polymer electrolytes. It was found that these polymer electrolyte systems show stability up to about 280°C. It was also found that, with increased LiClO4 salt content in complexed polymer electrolyte systems, the degradation temperature decreased.

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Sukri, Nursyazwani, N. S. Mohamed i R. H. Y. Subban. "Conductivity and Structural Studies of PEMA/ENR-50 Blend with LiCF₃SO₃ Salt". Applied Mechanics and Materials 754-755 (kwiecień 2015): 157–60. http://dx.doi.org/10.4028/www.scientific.net/amm.754-755.157.

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Solid polymer electrolytes (SPEs) comprising of a blend of Poly (ethyl methacrylate) (PEMA) and Epoxidized natural rubber-50 (ENR50) as polymer host and lithium triflate (LiCF3SO3) as dopant were prepared by solution cast technique. The blend based polymer electrolytes have a fixed PEMA/ENR50 ratio of 70:30 by wt. % as at this ratio ENR-50 imparted stable mechanical properties to the otherwise fragile PEMA. The incorporation of LiCF3SO3into the blend is found to increase the conductivity of PEMA/ENR50. The highest conductivity achieved was 3.64 x 10-5Scm-1at 40wt. % LiCF3SO3. The structure of the samples was investigated by X-ray diffraction and the results show that the highest conducting sample is the most amorphous.

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Mosa, Jadra, Jonh Fredy Vélez i Mario Aparicio. "Blend Hybrid Solid Electrolytes Based on LiTFSI Doped Silica-Polyethylene Oxide for Lithium-Ion Batteries". Membranes 9, nr 9 (27.08.2019): 109. http://dx.doi.org/10.3390/membranes9090109.

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Organic/inorganic hybrid membranes that are based on GTT (GPTMS-TMES-TPTE) system while using 3-Glycidoxypropyl-trimethoxysilane (GPTMS), Trimethyletoxisilane (TMES), and Trimethylolpropane triglycidyl ether (TPTE) as precursors have been obtained while using a combination of organic polymerization and sol-gel synthesis to be used as electrolytes in Li-ion batteries. Self-supported materials and thin-films solid hybrid electrolytes that were doped with Lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) were prepared. The hybrid network is based on highly cross-linked structures with high ionic conductivity. The dependency of the crosslinked hybrid structure and polymerization grade on ionic conductivity is studied. Ionic conductivity depends on triepoxy precursor (TPTE) and the accessibility of Li ions in the organic network, reaching a maximum ionic conductivity of 1.3 × 10−4 and 1.4 × 10−3 S cm−1 at room temperature and 60 °C, respectively. A wide electrochemical stability window in the range of 1.5–5 V facilitates its use as solid electrolytes in next-generation of Li-ion batteries.

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Matsumoto, Morihiko. "Polymer electrolytes with dual-phase structure composed of NBR/SBR blend polymer". Polymer 36, nr 16 (styczeń 1995): 3243–44. http://dx.doi.org/10.1016/0032-3861(95)97890-r.

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Mathew, Chithra M., K. Kesavan i S. Rajendran. "Structural and Electrochemical Analysis of PMMA Based Gel Electrolyte Membranes". International Journal of Electrochemistry 2015 (2015): 1–7. http://dx.doi.org/10.1155/2015/494308.

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New gel polymer electrolytes containing poly(vinylidene chloride-co-acrylonitrile) and poly(methyl methacrylate) are prepared by solution casting method. With the addition of 60 wt.% of EC to PVdC-AN/PMMA blend, ionic conductivity value0.398×10-6 S cm−1has been achieved. XRD and FT-IR studies have been conducted to investigate the structure and complexation in the polymer gel electrolytes. The FT-IR spectra show that the functional groups C=O and C≡N play major role in ion conduction. Thermal stability of the prepared membranes is found to be about 180°C.

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Nofal, Muaffaq M., Shujahadeen B. Aziz, Jihad M. Hadi, Rebar T. Abdulwahid, Elham M. A. Dannoun, Ayub Shahab Marif, Shakhawan Al-Zangana, Qayyum Zafar, M. A. Brza i M. F. Z. Kadir. "Synthesis of Porous Proton Ion Conducting Solid Polymer Blend Electrolytes Based on PVA: CS Polymers: Structural, Morphological and Electrochemical Properties". Materials 13, nr 21 (30.10.2020): 4890. http://dx.doi.org/10.3390/ma13214890.

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In this study, porous cationic hydrogen (H+) conducting polymer blend electrolytes with an amorphous structure were prepared using a casting technique. Poly(vinyl alcohol) (PVA), chitosan (CS), and NH4SCN were used as raw materials. The peak broadening and drop in intensity of the X-ray diffraction (XRD) pattern of the electrolyte systems established the growth of the amorphous phase. The porous structure is associated with the amorphous nature, which was visualized through the field-emission scanning electron microscope (FESEM) images. The enhancement of DC ionic conductivity with increasing salt content was observed up to 40 wt.% of the added salt. The dielectric and electric modulus results were helpful in understanding the ionic conductivity behavior. The transfer number measurement (TNM) technique was used to determine the ion (tion) and electron (telec) transference numbers. The high electrochemical stability up to 2.25 V was recorded using the linear sweep voltammetry (LSV) technique.

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Da̧browska, A., i W. Wieczorek. "Conductivity and phase structure of blend based proton polymeric electrolytes II: Ammonium salts complexes". Materials Science and Engineering: B 22, nr 2-3 (styczeń 1994): 117–27. http://dx.doi.org/10.1016/0921-5107(94)90233-x.

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Gregorio, Víctor, Nuria García i Pilar Tiemblo. "Addressing Manufacturability and Processability in Polymer Gel Electrolytes for Li/Na Batteries". Polymers 13, nr 13 (24.06.2021): 2093. http://dx.doi.org/10.3390/polym13132093.

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Gel electrolytes are prepared with Ultra High Molecular Weight (UHMW) polyethylene oxide (PEO) in a concentration ranging from 5 to 30 wt.% and Li- and Na-doped 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide (PYR14-TFSI) by a simple procedure consisting of dissolving PEO by melting it directly in the liquid electrolyte while stirring the blend. This procedure is fast, reproducible and needs no auxiliary solvents, which makes it sustainable and potentially easy to scale up for mass production. The viability of the up-scaling by extrusion has been studied. Extrusion has been chosen because it is a processing method commonly employed in the plastics industry. The structure and morphology of the gel electrolytes prepared by both methods have been studied by DSC and FTIR, showing small differences among the two methods. Composite gels incorporation high concentrations of surface modified sepiolite fibers have been successfully prepared by extrusion. The rheological behavior and ionic conductivity of the gels have been characterized, and very similar performance of the extruded and manually mixed gels is detected. Ionic conductivity of all the gels, including the composites, are at or over 0.4 mS cm−1 at 25 °C, being at the same time thermoreversible and self-healing gels, tough, sticky, transparent and stretchable. This combination of properties, together with the viability of their industrial up-scaling, makes these gel electrolyte families very attractive for their application in energy storage devices.

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Rozprawy doktorskie na temat "Blend Electrolytes Structure"

Peng, Dong-Ren, i 彭東仁. "Studies on Structure and Electric Property Relationship ofPEO Blends and their MMT/MWCNT Composites asSolid Electrolytes". Thesis, 2017. http://ndltd.ncl.edu.tw/handle/rn292d.

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碩士
國立臺灣大學
材料科學與工程學研究所
106
In this study, a variety of polymers and their composites with exfoliate montmorillonite (MMT) blending with polyethylene oxide (PEO) and LiClO4 were used for solid electrolytes. First, poly(methyl acrylate) (PMA), poly(vinyl acetate) (PVAc), and poly(oligo(ethylene glycol) methyl ether methacrylate) (POEGMEMA) were prepared by soap-free emulsion polymerization. And then, PMA-MMT, PVAc-MMT, and POEGMEMA-MMT were fabricated through the above-mentioned method in the presence of MMT. By following the method published in the literature, we successfully prepared the solid polymer electrolyte of PEO by using solvent casting method. At r=0.0625 condition (r= [Li]/ [EO]), the ionic conductivity of PEO/Li electrolyte could reach 5.34*10-7 S/cm and the property of solid state still remained well. Based on r=0.0625 condition, PEO blending with PMA, PVAc, and POEGMEMA were employed to fabricate the solid-state polymer electrolyte respectively. The PEO/PVAc system achieved an ionic conductivity of 1.21*10-5 S/cm at 2.5 % PVAc. The ionic conductivity of PEO/PVAc system was better than PEO/PMA system because there is only one melting point in PEO/PVAc system. However, there are two melting points in PEO/PMA system. According to the above result, we speculate that there were two crystalline phases which blocked the movement of Li ion. Similarly, based on r=0.0625 condition, PEO blending with PMA-MMT, PVAc- MMT, and POEGMEMA-MMT were employed to fabricate the solid-state composite electrolyte respectively. In PEO/PVAc-MMT system, the ionic conductivity of 9.71*10- 6 S/cm was obtained at 5 % PVAc-MMT. From FTIR anaylsis, we found that there existes certain interaction between MMT and Li ion. Li ions are believed to perform the redox reaction on the surface of MMT that makes ionic conductivity increase because of the potential cation exchange on MMT. In addition, we also found that there were two melting points in PEO/PMA-MMT and PEO/POEGMEMA-MMT systems similar to the polymer blending system. In DSC anaylsis, we calculated the slope of descent in degree of PEO crystallization with the content of blending polymer and polymer-MMT respectively. The blending factor which represents the chelating capability of PEO on Li ions compared to the blending polymer or polymer-MMT. In polymer blending system, PVAc had the lowest blending factor (0.49055). In composites blending system, PVAc-MMT afforded the highest blending factor (0.58845). In FTIR anaylsis, within 10 % blending polymer in the PEO/polymer blending system, the ratio of ClO4 peak intensity with C=O peak intensity had the similar trend as the ionic conductivity. As to the PEO/polymer-MMT blending systems, the ratio of C=O peak intensity with ClO4 peak intensity had the similar trend as the ionic conductivity. Either from DSC analysis or FTIR analysis, the two kinds of system had the opposite trend. We speculate that it might be du to that the redox reaction of Li ions was maily through the surface of MMT for the PEO/polymer-MMT blending system. Next, because PEO/PVAc-MMT system has the highest ionic conductivity among the PEO/polymer-MMT system, we futher incorporated different amount of oxided MWCNT to fabricate PEO/PVAc-MMT/CNT/LiClO4 solid-state electrolyte. At 25 % PVAc-MMT, the electrolyte could accommodate more Li ions up to r=0.125 and still remained the solid status. The ionic conductivity reached 3.22*10-4 S/cm and the crystalline phase of PEO was destructed completely. Finally, by further adding 0.001 % OCNT, the ionic conductivity increased to 3.84*10-4 S/cm. Therefore, this research has demonstrated a simple and effective method to fabricate solid-state electrolyte and still can overcome the issue of low ionic conductivity in solid state.

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Części książek na temat "Blend Electrolytes Structure"

Mallikarjun, A., M. Sangeetha, Maheshwar Reddy Mettu, M. Vikranth Reddy, M. Jaipal Reddy, J. Siva Kumar i T. Sreekanth. "Morphological, Spectroscopic, Structural and Electrical Properties of $${\text{Mg}}^{ + 2}$$ Ion Conducting PMMA: PVDF-HFP Blend Polymer Electrolytes". W Advances in Sustainability Science and Technology, 401–16. Singapore: Springer Singapore, 2021. http://dx.doi.org/10.1007/978-981-16-4321-7_34.

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Adarakatti, Prashanth S., i Sumedha H. N. "MXenes based 2D nanostructures for supercapacitors". W Electrochemistry, 261–303. The Royal Society of Chemistry, 2023. http://dx.doi.org/10.1039/bk9781839169366-00261.

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A supercapacitor is made up of three parts: separator, electrolyte, and electrodes. A supercapacitor's performance depends on electrodes with high porosity, chemical stability, and low electrical resistivity. MXenes are getting a lot of attention because of their high electrical conductivity, good mechanical properties, and Faraday pseudocapacitive charge storage mechanism. They are being used in supercapacitor applications. MXenes electrochemical characteristics are very advantageous for energy storage applications. There are three different mechanisms for supercapacitors, which will be discussed completely in this chapter. Furthermore, MXene performance can be increased by modifying the surface groups, interlayer structures, electrode morphology, or by manufacturing a composite with an additional functional material. Manufacture of the MXene electrode for testing and analysis is a vital step in getting a supercapacitor with good performance. Choosing a good blend of materials to accompany MXene is also a vital step. It's hard to find anything else like MXenes when it comes to appealing and unique properties like high electronic conductivity, tunable layer structure, and chemistry.

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Streszczenia konferencji na temat "Blend Electrolytes Structure"

Reddeppa, N., T. J. R. Reddy, V. B. S. Achari, V. V. R. N. Rao, A. K. Sharma, P. Predeep, S. Prasanth i A. S. Prasad. "Structural and optical characterization of (PEO+PVAc) polymer blend electrolyte films". W THERMOPHYSICAL PROPERTIES OF MATERIALS AND DEVICES: IVth National Conference on Thermophysical Properties - NCTP'07. AIP, 2008. http://dx.doi.org/10.1063/1.2927544.

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Naji, Ahmed, Petra Pötschke i Amir Ameli. "Electrical Conductivity of Multifunctional Blend Composites of Polycarbonate and Polyethylene With Hybrid Fillers". W ASME 2022 Conference on Smart Materials, Adaptive Structures and Intelligent Systems. American Society of Mechanical Engineers, 2022. http://dx.doi.org/10.1115/smasis2022-97843.

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Abstract Multifunctional composites are in high demand where a material needs to simultaneously satisfy several functional requirements. Bipolar plates of polymer electrolyte membrane fuel cells are great examples of this kind, requiring very high electrical and thermal conductivities together with good mechanical properties and environmental durability. Conductive filler/polymer composites (CPCs) have shown some promise towards this application. However, achieving high levels of through-plane and in-plane electrical conductivities in CPCs while maintaining scalable processability and satisfactory level of mechanical performance is challenging. In this work, a polymeric blend system together with hybrid conductive fillers was designed, manufactured, and characterized in an attempt to obtain melt-processable, highly conductive composites. Polycarbonate (PC) and high-density polyethylene (HDPE) were employed as the blend matrix with polyethylene glycol (PEG) as the compatibilizer. Carbon nanotubes (CNT), carbon fibers (CF), and graphite (G) were utilized as the conductive fillers. The HDPE was used as the minor component of blend matrix at 30 wt.% of the major matrix PC, with PC having the better affinity to the fillers. This was done to localize the conductive fillers in the major PC component of the blend. CF and G were used in ranges of 10–30 wt. % and 30–50 wt. % of the composites, respectively. CNT and PEG were fixed at 3 wt. % and 1.5 wt. %, respectively. The composites were first compounded using a twin-screw extrusion system and the test specimens were then made using compression molding process. The results showed that due to the preferential localization of the fillers in PC component of the PC/HDPE blend, the electrical conductivities were increased by about three times, compared to that of CPCs made with PC-only matrix. Consequently, high through-plane and in-plane conductivities of 10.0 and 61.1 S/cm, respectively, were achieved, which are superior to most of the previously reported results. The findings suggest that integrating blending and hybrid filler strategies could be a promising approach towards scalable manufacturing of highly conductive CPCs for applications such as bipolar plates.

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Irfan, Mohammed, Razikha Banu S., A. Manjunath i S. S. Mahesh. "Electrical and structural characterization of NaF doped PVA-PEG solid polymer blend electrolyte films". W DAE SOLID STATE PHYSICS SYMPOSIUM 2018. AIP Publishing, 2019. http://dx.doi.org/10.1063/1.5113433.

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Irfan, Mohammed, Alabur Manjunath i Sankanahally Srinivas Mahesh. "Studies on structural characterization and electrical properties of NaF doped PVA-PVP blend electrolyte films". W PROCEEDINGS OF THE INTERNATIONAL CONFERENCE ON PHYSICS OF MATERIALS AND NANOTECHNOLOGY ICPN 2019. AIP Publishing, 2020. http://dx.doi.org/10.1063/5.0009426.

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Ramesh, C. H., M. Jaipal Reddy, J. Siva Kumar i K. Narasimha Reddy. "Structural and transport properties of PVC blend PEG doped with Mg(ClO4)2 solid polymer electrolyte". W SOLID STATE PHYSICS: Proceedings of the 58th DAE Solid State Physics Symposium 2013. AIP Publishing LLC, 2014. http://dx.doi.org/10.1063/1.4872969.

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Jiang, Xinge, Taikai Liu i Hanlin Liao. "The Effect of a Gradient Porous Structure on the Performance of Cold-Sprayed Electrodes used in Alkaline Water Electrolysis". W ITSC 2023. ASM International, 2023. http://dx.doi.org/10.31399/asm.cp.itsc2023p0148.

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Abstract Alkaline water electrolysis is currently the most promising approach to produce hydrogen. However, a main limitation for large-scale application originates from the significant energy loss caused by the coverage of bubbles on the electrode surface. Here, pore-graded Ni electrodes with a positive and negative gradient porous structure that boosts the desorption and release of gas bubble are reported, resulting in a greatly advanced mass transference. The electrodes are obtained from a blend of Ni and Al via high-pressure cold spray. The gradient porosity is realized by varying the addition of Al and chemical etching. As-sprayed electrodes are annealed to eliminate the residual stress and strengthen the adhesion of layers, hence improving their durability. As a result, the electrode with a positive pore-graded structure exhibits a better HER/OER performance when tested with a carbon rob counter electrode. Notably, when tested with an annulus counter electrode of Nickel foam, the electrode with a negative pore-graded structure achieves minimal HER/OER overpotential, outperforming other porous electrodes. This is benefited from improved bubble removal and mass transference capability. All prepared electrodes showed an excellent stability that after 500 cycles of HER/OER test without a large potential fluctuation.

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Gupta, Ravindra Kumar, i Hee-Woo Rhee. "Electrical, Structural, Optical And Thermal Properties of (1-X)Blend: X LI[(CF3 SO2 ) 2N] Solid Polymer Electrolyte System". W 14th Asian Conference on Solid State Ionics (ACSSI 2014). Singapore: Research Publishing Services, 2014. http://dx.doi.org/10.3850/978-981-09-1137-9_162.

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Padmaraj, O., M. Venkateswarlu i N. Satyanarayana. "Structural and ionic conductivity studies of electrospun polymer blend P(VdF-co-HFP)/PMMA electrolyte membrane for lithium battery application". W NANOFORUM 2014. AIP Publishing LLC, 2015. http://dx.doi.org/10.1063/1.4917847.

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