Gotowe bibliografie tematyczne / Atmospheric chemistry

Gotowa bibliografia na temat „Atmospheric chemistry”

Autor: Grafiati
Data publikacji: 4 czerwca 2021
Data aktualizacji: 29 lipca 2024

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Artykuły w czasopismach na temat "Atmospheric chemistry"

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Faxon, C. B., i D. T. Allen. "Chlorine chemistry in urban atmospheres: a review". Environmental Chemistry 10, nr 3 (2013): 221. http://dx.doi.org/10.1071/en13026.

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Environmental context Atmospheric chlorine radicals can affect the chemical composition of the atmosphere through numerous reactions with trace species. In urban atmospheres, the reactions of chlorine radicals can lead to effects such as increases in ozone production, thus degrading local and regional air quality. This review summarises the current understanding of atmospheric chlorine chemistry in urban environments and identifies key unresolved issues. Abstract Gas phase chlorine radicals (Cl•), when present in the atmosphere, react by mechanisms analogous to those of the hydroxyl radical (OH•). However, the rates of the Cl•-initiated reactions are often much faster than the corresponding OH• reactions. The effects of the atmospheric reactions of Cl• within urban environments include the oxidation of volatile organic compounds and increases in ozone production rates. Although concentrations of chlorine radicals are typically low compared to other atmospheric radicals, the relatively rapid rates of the reactions associated with this species lead to observable changes in air quality. This is particularly evident in the case of chlorine radical-induced localised increases in ozone concentrations. This review covers five aspects of atmospheric chlorine chemistry: (1) gas phase reactions; (2) heterogeneous and multi-phase reactions; (3) observational evidence of chlorine species in urban atmospheres; (4) regional modelling studies and (5) areas of uncertainty in the current state of knowledge.
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Grgić, Irena. "Atmospheric Aqueous-Phase Chemistry". Atmosphere 12, nr 1 (23.12.2020): 3. http://dx.doi.org/10.3390/atmos12010003.

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CICERONE, R. J. "Atmospheric Chemistry: The Photochemistry of Atmospheres." Science 233, nr 4766 (22.08.1986): 896–97. http://dx.doi.org/10.1126/science.233.4766.896-a.

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Watanabe, Yasuto, i Kazumi Ozaki. "Relative Abundances of CO2, CO, and CH4 in Atmospheres of Earth-like Lifeless Planets". Astrophysical Journal 961, nr 1 (1.01.2024): 1. http://dx.doi.org/10.3847/1538-4357/ad10a2.

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Abstract Carbon is an essential element for life on Earth, and the relative abundances of major carbon species (CO2, CO, and CH4) in the atmosphere exert fundamental controls on planetary climate and biogeochemistry. Here we employed a theoretical model of atmospheric chemistry to investigate diversity in the atmospheric abundances of CO2, CO, and CH4 on Earth-like lifeless planets orbiting Sun-like (F-, G-, and K-type) stars. We focused on the conditions for the formation of a CO-rich atmosphere, which would be favorable for the origin of life. Results demonstrated that elevated atmospheric CO2 levels trigger photochemical instability of the CO budget in the atmosphere (i.e., CO runaway) owing to enhanced CO2 photolysis relative to H2O photolysis. Higher volcanic outgassing fluxes of reduced C (CO and CH4) also tend to initiate CO runaway. Our systematic examinations revealed that anoxic atmospheres of Earth-like lifeless planets could be classified in the phase space of CH4/CO2 versus CO/CO2, where a distinct gap in atmospheric carbon chemistry is expected to be observed. Our findings indicate that the gap structure is a general feature of Earth-like lifeless planets with reducing atmospheres orbiting Sun-like (F-, G-, and K-type) stars.
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Finlayson-Pitts, B. J. "Atmospheric Chemistry". Proceedings of the National Academy of Sciences 107, nr 15 (13.04.2010): 6566–67. http://dx.doi.org/10.1073/pnas.1003038107.

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Heard, Dwayne E., i Alfonso Saiz-Lopez. "Atmospheric chemistry". Chemical Society Reviews 41, nr 19 (2012): 6229. http://dx.doi.org/10.1039/c2cs90076a.

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Kerr, J. A. "Atmospheric Chemistry". Analytica Chimica Acta 193 (1987): 402–3. http://dx.doi.org/10.1016/s0003-2670(00)86189-9.

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Benarie, Michel. "Atmospheric chemistry". Science of The Total Environment 64, nr 3 (lipiec 1987): 341–42. http://dx.doi.org/10.1016/0048-9697(87)90261-0.

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Sanderson, H. Preston. "Atmospheric chemistry". Chemical Geology 51, nr 1-2 (październik 1985): 153–54. http://dx.doi.org/10.1016/0009-2541(85)90100-7.

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Lodge, James P. "Atmospheric chemistry". Atmospheric Environment (1967) 21, nr 1 (styczeń 1987): 268–69. http://dx.doi.org/10.1016/0004-6981(87)90306-4.

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Rozprawy doktorskie na temat "Atmospheric chemistry"

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Pinot, de Moira John C. "Laser studies of atmospheric chemistry". Thesis, University of Oxford, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.299100.

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Steiner, Allison L. "The influence of atmospheric chemistry and climate on atmosphere-biosphere interactions". Diss., Georgia Institute of Technology, 2003. http://hdl.handle.net/1853/25751.

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Drummond, Benjamin. "The chemistry of hot exoplanet atmospheres : developing and applying chemistry schemes in 1D and 3D models". Thesis, University of Exeter, 2017. http://hdl.handle.net/10871/27993.

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The focus of this work is the development and improvement of chemistry schemes in both 1D and 3D atmosphere models, applied to exoplanets. With an ever increasing number of known exoplanets, planets orbiting stars other than the Sun, the diversity in the physical and chemical nature of planets and their atmospheres is becoming more apparent. One of the prime targets, and the focus of many observational and theoretical studies, are the subclass of exoplanets termed hot Jupiters, Jovian sized planets on very short period orbits around their host star. Due to their close orbit, with orbital periods of just a few days, the atmospheres of such planets are heated to very high temperatures (~1000-2000 K) by the intense irradiation from the star. In addition, it is expected that these planets should have synchronised their rotation with their orbital period, a phenomenon called tidal-locking, that leads to a permanently illuminated dayside and a perpetually dark nightside. This combination of intense heating and tidal-locking leads to an exotic type of atmosphere that is without analogue in our own Solar system. Observational constraints suggest that some of these atmospheres may be clear whilst others may be cloudy or contain haze. Some hot Jupiters appear to be inflated with radii larger than is expected for their mass. For the warmest hot Jupiters optical absorbing species TiO and VO are expected to be present, due to the thermodynamical conditions, where they can strongly influence the thermal structure of the atmosphere, yet so far these species have remained elusive in observations. Theoretical simulations of these planets appear to provide poor matches to the observed emission flux from the nightside of the planet whilst providing a much better agreement with the observed dayside flux. These outstanding questions can be tackled in two complimentary ways. Firstly, the number of exoplanets subject to intense observational scrutiny must be increased to improve the statistical significance of observed trends. Secondly, and in tandem, the suite of available theoretical models applied to such atmospheres must be improved to allow for a more comprehensive understanding of the potential physical and chemical processes that occur in these atmospheres, as well as for better comparison of model predictions with observations. In this thesis we present the development and application of one-dimensional (1D) and three-dimensional (3D) models to the atmospheres of hot exoplanets, with a focus on improving the representation of chemistry. One of the concerns of this work is to couple the radiative transfer and chemistry calculations in a one-dimensional model to allow for a self-consistent model that includes feedback between the chemical composition and the thermal structure. We apply this model to the atmospheres of two typical hot Jupiters to quantify this effect. Implications for previous models that do not include this consistency are discussed. Another major focus is to improve the representation of chemistry in the Met Office Unified Model (UM) for exoplanet applications, a three-dimensional model with its heritage in modelling the Earth atmosphere that has recently been applied to exoplanets. We discuss the coupling of two new chemistry schemes that improve both the flexibility and capabilities of the UM applied to exoplanets. Ultimately these developments will allow for a consistent approach to calculate the 3D chemical composition of the atmosphere taking into account the effect of large scale advection, one of the processes currently hypothesised to cause the discrepancy between model predictions and observations of the nightside emission flux of many hot Jupiters.
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Srithawirat, Thunwadee. "Atmospheric chemistry of saccharides and furfural". Thesis, University of East Anglia, 2010. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.551251.

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Saccharides and furfural are derived from biomass burning and contribute to aerosol composition. This study examined the potential of saccharides and furfural to be tracers of biomass combustion. Furfural is likely to be oxidized quickly so comparison with saccharides may give a sense of the age of the aerosols in biomass smoke. However, few furfural emissions are available for biomass combustion. Saccharides and furfural were determined in coarse aerosols (diameter> 2.4/lm ) and fine aerosols (diameter < 2.4/lm ) collected in 24 hour periods during different seasons in the United Kingdom and PMIO collected from Thailand and Malaysia including biomass burning areas such as haze episodes and forest fires. Also total suspended particulate matter (TSP) was collected from Taiwan. Saccharides and furfural dominated in fine fractions, especially in the UK autumn. The Principle component analysis showed that the fine mode UK aerosols probably originate from long-range transport emissions from Europe. This was also an important contribution for the crustal group and the biomass burning emission. Sea salt and combustion emission may contribute to coarse mode aerosols. Fraction of saccharides and furfural in aerosols were higher during Southeast Asian haze episodes and forest fires. They were also correlated to potassium and total carbon. Collection of aerosol particles led to blackening on filter papers. The oxidation processes in the atmosphere may lead to more yellowness of aerosols. The yellowness of aerosols collected from forest fires correlated with saccharides and furfural. This may indicate that the organic carbons from forest fires are related to the oxidation process. Although the emission rates of saccharides and furfural from biomass burning were found to have similar levels, furfural was detected at low concentration suggesting loss from atmospheric aerosols. Laboratory experimental simulation suggested furfural is more rapid destroyed by UV, sunlight and ozone than saccharides.
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Wittig, Ann Elizabeth. "Atmospheric hydrocarbon chemistry in central Texas /". Digital version accessible at:, 1998. http://wwwlib.umi.com/cr/utexas/main.

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Helmer, Magdalena. "Meteoric metal chemistry". Thesis, University of East Anglia, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.318079.

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Surl, Luke. "Modelling the atmospheric chemistry of volcanic plumes". Thesis, University of East Anglia, 2016. https://ueaeprints.uea.ac.uk/59407/.

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Volcanoes are the principal way by which volatiles are transferred from the solid Earth to the atmosphere-hydrosphere system. Once released into the atmosphere, volcanic emissions rapidly undergo a complex series of chemical reactions. This thesis seeks to further the understanding of such processes by both observation and numerical modelling. I have adapted WRF-Chem to model passive degassing from Mount Etna, the chemistry of its plume, and its influence on the wider atmosphere. This investigation considers model plumes from the point of emission up to a day’s travel from the vent and is able to reproduce observed phenomena of BrO formation and O3 depletion within volcanic plumes. The model plume influences several atmospheric chemistry systems, including reactive nitrogen and organic chemistry. Plume chemistry is driven by sunlight, and I examine how the modelled phenomena identified in this investigation vary with the diurnal cycle. In the modelled plume all of the bromine is involved in O3-destructive cycling. When HBr is exhausted, volcanic HCl sustains the cycling. The rate-limiting factor of this cycling, and therefore the rate of O3 destruction, is sunlight. I find qualitative differences between the chemistry of low and high intensity plumes, with the bromine chemistry in the latter case being limited by O3 depletion. This modelling investigation is complemented by an observational study of O3 in a young Etnean plume from which I estimate the rate of in-plume O3 destruction within seconds to minutes after emission. These investigations demonstrate that volcanic plumes can be included in complex, 3D atmospheric chemistry models, and that the output from these can be used to observe and quantify influences of volcanic plumes on the wider atmosphere.
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Clegg, S. L. "The atmospheric chemistry of extremely concentrated solutions". Thesis, University of East Anglia, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.376080.

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Sanderson, Michael George. "Experimental and modelling studies of atmospheric chemistry". Thesis, University of York, 1994. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.259802.

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Horst, Sarah M. "Post-Cassini Investigations of Titan Atmospheric Chemistry". Diss., The University of Arizona, 2011. http://hdl.handle.net/10150/145467.

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The arrival of the Cassini-Huygens mission to the Saturn system ushered in a new era in the study of Titan. Armed with a variety of instruments capable of remote sensing and in situ investigations of Titan's atmosphere and surface, Cassini and Huygens have provided a wealth of new information about Titan and have finally allowed humankind to see its surface. This work focuses on two discoveries made by the Cassini Plasma Spectrometer (CAPS): the detection of oxygen ions (O+) precipitating into Titan's atmosphere (Hartle et al., 2006) and the discovery of very large positive (Waite et al., 2007; Crary et al., 2009) and negative ions (Coates et al., 2007, 2009) present in Titan's thermosphere.Through the use of a photochemical model, I demonstrate that the observed densities of CO, CO2 and H2O can be explained by a combination of O and OH or H2O input to the upper atmosphere. Given the detection of O+ precipitation into Titan's upper atmosphere, it is no longer necessary to invoke outgassing from Titan's interior as a source for atmospheric CO or to assume that the observed CO is the remnant of a larger primordial abundance in Titan's atmosphere. Instead, it is most likely that the oxygen bearing species in Titan's atmosphere are the result of external input, most likely from Enceladus.I have also used very high resolution mass spectrometry to investigate the com- position of Titan aerosol analogues, or "tholins". Although there are an enormous number of molecules present in tholin samples, they exhibit numerous patterns, in- cluding very regular spectral spacing. These patterns may help constrain the com- position of the very large ions observed in the CAPS spectra, since the resolution of the instrument makes identification of the molecules impossible. Additionally, tholins produced with CO possess molecules of prebiotic interest, including all 5 nucleotide bases and the 2 smallest amino acids (glycine and alanine). This indicates that chemistry occurring in Titan's upper atmosphere may be capable of forming incredibly complex organic molecules, which may have implications for the origin of life on Earth and elsewhere in the universe.
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Książki na temat "Atmospheric chemistry"

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Surkova, Galina. Atmospheric chemistry. ru: INFRA-M Academic Publishing LLC., 2021. http://dx.doi.org/10.12737/1079840.

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The textbook contains material corresponding to the course of lectures on atmospheric chemistry prepared for students studying meteorology and climatology. The basic concepts of atmospheric chemistry are given, its gaseous components, as well as aerosols and chemical processes related to their life cycles, which are important from the point of view of the formation of the radiation, temperature and dynamic regime of the atmosphere, as well as its pollution, are considered. The main regularities of the transport of impurities in the atmosphere and the role of processes of different spatial and temporal scales in this process are presented. The concept of approaches of varying degrees of complexity used to model the transport of matter in the atmosphere, taking into account its chemical transformations, is presented. The processes in the gaseous and liquid phases that affect the chemical composition and acidity of clouds and precipitation are described. Modern methods of using information about the concentration and state of chemical compounds, including their radioactive and stable isotopes, to obtain information about the meteorological regime of the atmosphere in the present and past are considered. Meets the requirements of the federal state educational standards of higher education of the latest generation. For students of higher educational institutions studying in the field of training "Hydrometeorology".
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Akimoto, Hajime. Atmospheric Reaction Chemistry. Tokyo: Springer Japan, 2016. http://dx.doi.org/10.1007/978-4-431-55870-5.

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Martin, Scot T., Yue Zhang, Pengfei Liu, Qi Chen, Yongjie Li, Mikinori Kuwata i Yuemei Han. Aerosols in Atmospheric Chemistry. Washington, DC, USA: American Chemical Society, 2022. http://dx.doi.org/10.1021/acsinfocus.7e5020.

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Prinn, Ronald G., red. Global Atmospheric-Biospheric Chemistry. Boston, MA: Springer US, 1994. http://dx.doi.org/10.1007/978-1-4615-2524-0.

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McNeill, V. Faye, i Parisa A. Ariya, red. Atmospheric and Aerosol Chemistry. Berlin, Heidelberg: Springer Berlin Heidelberg, 2014. http://dx.doi.org/10.1007/978-3-642-41215-8.

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G, Prinn Ronald, i International Global Atmospheric Chemistry (IGAC) Project. Scientific Conference, red. Global atmospheric-biospheric chemistry. New York: Plenum Press, 1994.

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Center, Goddard Space Flight, red. Atmospheric Chemistry & Dynamics Branch. Greenbelt, Md: NASA, Goddard Space Flight Center, 1997.

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Center, Goddard Space Flight, red. Atmospheric Chemistry & Dynamics Branch. Greenbelt, Md: NASA, Goddard Space Flight Center, 1997.

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Center, Goddard Space Flight, red. Atmospheric Chemistry & Dynamics Branch. Greenbelt, Md: NASA, Goddard Space Flight Center, 1997.

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Center, Goddard Space Flight, red. Atmospheric Chemistry & Dynamics Branch. Greenbelt, Md: NASA, Goddard Space Flight Center, 1997.

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Części książek na temat "Atmospheric chemistry"

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Spiridonov, Vlado, i Mladjen Ćurić. "Atmospheric Chemistry". W Fundamentals of Meteorology, 327–47. Cham: Springer International Publishing, 2020. http://dx.doi.org/10.1007/978-3-030-52655-9_22.

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Nicolet, Marcel. "Atmospheric Chemistry". W Advances in Chemical Physics, 63–78. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470142790.ch5.

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Lazaridis, Mihalis. "Atmospheric Chemistry". W Environmental Pollution, 151–67. Dordrecht: Springer Netherlands, 2010. http://dx.doi.org/10.1007/978-94-007-0162-5_4.

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Zannetti, Paolo. "Atmospheric Chemistry". W Air Pollution Modeling, 223–47. Boston, MA: Springer US, 1990. http://dx.doi.org/10.1007/978-1-4757-4465-1_9.

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Morley, C., i I. W. M. Smith. "Atmospheric chemistry". W 100 Years of Physical Chemistry, 141–58. Cambridge: Royal Society of Chemistry, 2007. http://dx.doi.org/10.1039/9781847550002-00141.

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Mölders, Nicole, i Gerhard Kramm. "Atmospheric Chemistry". W Springer Atmospheric Sciences, 223–86. Cham: Springer International Publishing, 2014. http://dx.doi.org/10.1007/978-3-319-02144-7_5.

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Visconti, Guido. "Atmospheric Chemistry". W Fundamentals of Physics and Chemistry of the Atmosphere, 141–60. Cham: Springer International Publishing, 2016. http://dx.doi.org/10.1007/978-3-319-29449-0_5.

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Manahan, Stanley E. "The Atmosphere and Atmospheric Chemistry". W Environmental Chemistry, 205–36. Wyd. 11. Boca Raton: CRC Press, 2022. http://dx.doi.org/10.1201/9781003096238-8.

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Jaeschke, Wolfgang. "Multiphase Atmospheric Chemistry". W Chemistry of Multiphase Atmospheric Systems, 3–40. Berlin, Heidelberg: Springer Berlin Heidelberg, 1986. http://dx.doi.org/10.1007/978-3-642-70627-1_1.

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Wayne, Richard P. "Atmospheric Chemistry: Introduction". W Low-Temperature Chemistry of the Atmosphere, 1–20. Berlin, Heidelberg: Springer Berlin Heidelberg, 1994. http://dx.doi.org/10.1007/978-3-642-79063-8_1.

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Streszczenia konferencji na temat "Atmospheric chemistry"

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Adamov, Dmitri P., Alexey Y. Akhlyostin, Alexandre Z. Fazliev, Eugeni P. Gordov, Alexey S. Karyakin, Sergey A. Mikhailov i Olga B. Rodimova. "Information-computational system: atmospheric chemistry". W Sixth International Symposium on Atmospheric and Ocean Optics, redaktorzy Gennadii G. Matvienko i Vladimir P. Lukin. SPIE, 1999. http://dx.doi.org/10.1117/12.370548.

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Boone, Chris, i Peter Bernath. "The Atmospheric Chemistry Experiment (ACE)". W Fourier Transform Spectroscopy. Washington, D.C.: OSA, 2001. http://dx.doi.org/10.1364/fts.2001.fmc3.

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Crutzen, Paul J. "Problems in global atmospheric chemistry". W Environmental Sensing '92, redaktorzy Harold I. Schiff i Ulrich Platt. SPIE, 1993. http://dx.doi.org/10.1117/12.140182.

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Griffith, David W. "FTIR, bushfires, and atmospheric chemistry". W Luebeck - DL tentative, redaktorzy Herbert M. Heise, Ernst H. Korte i Heinz W. Siesler. SPIE, 1992. http://dx.doi.org/10.1117/12.56290.

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Pailharey, E., F. Châteauneuf i D. Aminou. "LIFT a future atmospheric chemistry sensor". W International Conference on Space Optics 2004, redaktorzy Josiane Costeraste i Errico Armandillo. SPIE, 2017. http://dx.doi.org/10.1117/12.2307979.

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Bernath, Peter F. "Atmospheric chemistry experiment (ACE): mission overview". W Optical Science and Technology, the SPIE 49th Annual Meeting, redaktorzy William L. Barnes i James J. Butler. SPIE, 2004. http://dx.doi.org/10.1117/12.556120.

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Henley, Michael V., Douglas S. Burns, Veeradej Chynwat, William Moore, Angela Plitz, Shawn Rottmann i John Hearn. "Modeling the atmospheric chemistry of TICs". W SPIE Defense, Security, and Sensing, redaktorzy Augustus W. Fountain III i Patrick J. Gardner. SPIE, 2009. http://dx.doi.org/10.1117/12.821924.

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Bernath, Peter F. "Atmospheric Chemistry Experiment (ACE): Mission overview". W Fourier Transform Spectroscopy. Washington, D.C.: OSA, 2005. http://dx.doi.org/10.1364/fts.2005.jma3.

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Bernath, Peter F. "Atmospheric Chemistry Experiment (ACE): Latest Results". W Fourier Transform Spectroscopy. Washington, D.C.: OSA, 2007. http://dx.doi.org/10.1364/fts.2007.jma2.

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Bernath, Peter F. "Atmospheric Chemistry Experiment (ACE): Latest Results". W Fourier Transform Spectroscopy. Washington, D.C.: OSA, 2011. http://dx.doi.org/10.1364/fts.2011.fmb2.

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Raporty organizacyjne na temat "Atmospheric chemistry"

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Caledonia, G. E., D. B. Oakes, B. L. Upschulte, R. H. Krech i H. C. Murphy. Chemistry of Atmospheric Excitation Processes. Fort Belvoir, VA: Defense Technical Information Center, styczeń 2002. http://dx.doi.org/10.21236/ada402983.

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Ramani, Suchitra. Microwave remote sensing for atmospheric chemistry. Office of Scientific and Technical Information (OSTI), wrzesień 2018. http://dx.doi.org/10.2172/1471300.

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Hopke, P. K. The atmospheric chemistry of Po-218. Office of Scientific and Technical Information (OSTI), wrzesień 1990. http://dx.doi.org/10.2172/6509075.

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Mroz, E. J., J. Olivares i G. Kok. Atmospheric Aerosol Chemistry Analyzer: Demonstration of feasibility. Office of Scientific and Technical Information (OSTI), kwiecień 1996. http://dx.doi.org/10.2172/219396.

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Yarkony, David R. Nonadiabatic Processes Relevant to HEDMs and Atmospheric Chemistry. Fort Belvoir, VA: Defense Technical Information Center, luty 2002. http://dx.doi.org/10.21236/ada399437.

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Reisdorf, Jill, i Christine Wiedinmyer. Report to the International Global Atmospheric Chemistry Project. Office of Scientific and Technical Information (OSTI), kwiecień 2017. http://dx.doi.org/10.2172/1362299.

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Park, Sung-Jin, i James Gary Eden. Collaborative Research. Atmospheric Pressure Microplasma Chemistry-Photon Synergies. Office of Scientific and Technical Information (OSTI), grudzień 2015. http://dx.doi.org/10.2172/1235075.

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Hopke, P. The atmospheric chemistry of Po-218: Final report. Office of Scientific and Technical Information (OSTI), czerwiec 1989. http://dx.doi.org/10.2172/5979057.

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Nizkorodov, Sergey. Chemistry of Atmospheric Aerosols at Pacifichem 2015 Congress. Office of Scientific and Technical Information (OSTI), grudzień 2016. http://dx.doi.org/10.2172/1339071.

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Moraes, Jr., Francis Perry. The global change research center atmospheric chemistry model. Office of Scientific and Technical Information (OSTI), styczeń 1995. http://dx.doi.org/10.2172/576052.

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