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Artykuły w czasopismach na temat "Aromatic chemistry"

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Yan, Yingying, David Cabrera-Perez, Jintai Lin, Andrea Pozzer, Lu Hu, Dylan B. Millet, William C. Porter i Jos Lelieveld. "Global tropospheric effects of aromatic chemistry with the SAPRC-11 mechanism implemented in GEOS-Chem version 9-02". Geoscientific Model Development 12, nr 1 (4.01.2019): 111–30. http://dx.doi.org/10.5194/gmd-12-111-2019.

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Abstract. The Goddard Earth Observing System with chemistry (GEOS-Chem) model has been updated with the State-wide Air Pollution Research Center version 11 (SAPRC-11) aromatics chemical mechanism, with the purpose of evaluating global and regional effects of the most abundant aromatics (benzene, toluene, xylenes) on the chemical species important for tropospheric oxidation capacity. The model evaluation based on surface and aircraft observations indicates good agreement for aromatics and ozone. A comparison between scenarios in GEOS-Chem with simplified aromatic chemistry (as in the standard setup, with no ozone formation from related peroxy radicals or recycling of NOx) and with the SAPRC-11 scheme reveals relatively slight changes in ozone, the hydroxyl radical, and nitrogen oxides on a global mean basis (1 %–4 %), although remarkable regional differences (5 %–20 %) exist near the source regions. NOx decreases over the source regions and increases in the remote troposphere, due mainly to more efficient transport of peroxyacetyl nitrate (PAN), which is increased with the SAPRC aromatic chemistry. Model ozone mixing ratios with the updated aromatic chemistry increase by up to 5 ppb (more than 10 %), especially in industrially polluted regions. The ozone change is partly due to the direct influence of aromatic oxidation products on ozone production rates, and in part to the altered spatial distribution of NOx that enhances the tropospheric ozone production efficiency. Improved representation of aromatics is important to simulate the tropospheric oxidation.
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Lu, Zhengyu, Qin Zhu, Yuanting Cai, Zhixin Chen, Kaiyue Zhuo, Jun Zhu, Hong Zhang i Haiping Xia. "Access to tetracyclic aromatics with bridgehead metals via metalla-click reactions". Science Advances 6, nr 3 (styczeń 2020): eaay2535. http://dx.doi.org/10.1126/sciadv.aay2535.

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The never-ending pursuits for exploring aromatic molecular architectures result in the large libraries of aromatics with fascinating structures, which have greatly broadened the scope of aromaticity. Despite extensive efforts that have been paid to develop aromatic frameworks, the construction of polycyclic aromatics that share a bridgehead atom with more than three rings has never been accomplished. Here, an unprecedented family of aromatics, in which a metal center shared by 4 five-membered aromatic rings, has been achieved by using the metalla-click reactions with excellent yields and remarkable regioselectivity. The distinctive tetracyclic aromatics exhibit a broad absorption in the ultraviolet-visible near-infrared region and excellent thermal stability in air, enabling their potential applications in photoelectric materials and biomedicine. This study now makes it possible to incorporate four aromatic rings with one common sharing metal center by a straightforward strategy that would promote further development of previously unknown polycyclic complex motifs in aromatic chemistry.
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Plater, M. John. "4 Aromatic chemistry". Annual Reports Section "B" (Organic Chemistry) 96 (2000): 131–55. http://dx.doi.org/10.1039/b002149k.

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Toyota, Shinji, Masahiko Iyoda i Fumio Toda. "7 Aromatic chemistry". Annu. Rep. Prog. Chem., Sect. B: Org. Chem. 98 (2002): 359–407. http://dx.doi.org/10.1039/b111467k.

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Yeston, J. "CHEMISTRY: Aromatic Surprise". Science 319, nr 5860 (11.01.2008): 137d. http://dx.doi.org/10.1126/science.319.5860.137d.

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Jones, R. C. F. "Aromatic heterocyclic chemistry". Trends in Pharmacological Sciences 13 (styczeń 1992): 417–18. http://dx.doi.org/10.1016/0165-6147(92)90127-r.

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Newman, John W., i I. C. Lewis. "Industrial Aromatic Chemistry". Carbon 27, nr 3 (1989): 503–4. http://dx.doi.org/10.1016/0008-6223(89)90089-4.

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Bosdet, Michael J. D., i Warren E. Piers. "B-N as a C-C substitute in aromatic systems". Canadian Journal of Chemistry 87, nr 1 (1.01.2009): 8–29. http://dx.doi.org/10.1139/v08-110.

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The substitution of isoelectronic B–N units for C–C units in aromatic hydrocarbons produces novel heterocycles with structural similarities to the all-carbon frameworks, but with fundamentally altered electronic properties and chemistry. Since the pioneering work of Dewar some 50 years ago, the relationship between B–N and C–C and the wealth of parent all-carbon aromatics has captured the imagination of organic, inorganic, materials, and computational chemists alike, particularly in recent years. New applications in biological chemistry, new materials, and novel ligands for transition-metal complexes have emerged from these studies. This review is aimed at surveying activity in the area in the past couple of decades. Its organization is based on ring size and type of the all-carbon or heterocyclic subunit that the B–N analog is derived from. Structural aspects pertaining to the retention of aromaticity are emphasized, along with delineation of significant differences in physical properties of the B–N compound as compared to the C–C parent.Key words: boron-nitrogen heterocycles, aromaticity, organic materials, main-group chemistry.
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Parikh, Harshal M., Harvey E. Jeffries, Ken G. Sexton, Deborah J. Luecken, Richard M. Kamens i William Vizuete. "Evaluation of aromatic oxidation reactions in seven chemical mechanisms with an outdoor chamber". Environmental Chemistry 10, nr 3 (2013): 245. http://dx.doi.org/10.1071/en13039.

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Environmental context Regulatory air quality models used to develop strategies to reduce ozone and other pollutants must be able to accurately predict ozone produced from aromatic hydrocarbons. In urban areas, major sources of aromatic hydrocarbons are gasoline and diesel-powered vehicles. Our findings show that the representation of aromatic hydrocarbon chemistry in air quality models is an area of high uncertainty Abstract Simulations using seven chemical mechanisms are intercompared against O3, NOx and hydrocarbon data from photooxidation experiments conducted at the University of North Carolina outdoor smog chamber. The mechanisms include CB4–2002, CB05, CB05-TU, a CB05 variant with semi-explicit aromatic chemistry (CB05RMK), SAPRC07, CS07 and MCMv3.1. The experiments include aromatics, unsaturated dicarbonyls and volatile organic compound (VOC) mixtures representing a wide range of urban environments with relevant hydrocarbon species. In chamber simulations the sunlight is characterised using new solar radiation modelling software. A new heterogeneous chamber wall mechanism is also presented with revised chamber wall chemical processes. Simulations from all mechanisms, except MCMv3.1, show median peak O3 concentration relative errors of less than 25% for both aromatic and VOC mixture experiments. Although MCMv3.1 largely overpredicts peak O3 levels, it performs relatively better in predicting the peak NO2 concentration. For aromatic experiments, all mechanisms except CB4–2002, largely underpredict the NO–NO2 crossover time and over-predict both the absolute NO degradation slope and the slope of NO2 concentration rise. This suggests a major problem of a faster and earlier NO to NO2 oxidation rate across all the newer mechanisms. Results from individual aromatic and unsaturated dicarbonyl experiments illustrate the unique photooxidation chemistry and O3 production of several aromatic ring-opening products. The representation of these products as a single mechanism species in CB4–2002, CB05 and CB05-TU is not adequate to capture the O3 temporal profile. In summary, future updates to chemical mechanisms should focus on the chemistry of aromatic ring-opening products.
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Krompiec, Stanisław, Aneta Kurpanik-Wójcik, Marek Matussek, Bogumiła Gołek, Angelika Mieszczanin i Aleksandra Fijołek. "Diels–Alder Cycloaddition with CO, CO2, SO2, or N2 Extrusion: A Powerful Tool for Material Chemistry". Materials 15, nr 1 (27.12.2021): 172. http://dx.doi.org/10.3390/ma15010172.

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Phenyl, naphthyl, polyarylphenyl, coronene, and other aromatic and polyaromatic moieties primarily influence the final materials’ properties. One of the synthetic tools used to implement (hetero)aromatic moieties into final structures is Diels–Alder cycloaddition (DAC), typically combined with Scholl dehydrocondensation. Substituted 2-pyranones, 1,1-dioxothiophenes, and, especially, 1,3-cyclopentadienones are valuable substrates for [4 + 2] cycloaddition, leading to multisubstituted derivatives of benzene, naphthalene, and other aromatics. Cycloadditions of dienes can be carried out with extrusion of carbon dioxide, carbon oxide, or sulphur dioxide. When pyranones, dioxothiophenes, or cyclopentadienones and DA cycloaddition are aided with acetylenes including masked ones, conjugated or isolated diynes, or polyynes and arynes, aromatic systems are obtained. This review covers the development and the current state of knowledge regarding thermal DA cycloaddition of dienes mentioned above and dienophiles leading to (hetero)aromatics via CO, CO2, or SO2 extrusion. Particular attention was paid to the role that introduced aromatic moieties play in designing molecular structures with expected properties. Undoubtedly, the DAC variants described in this review, combined with other modern synthetic tools, constitute a convenient and efficient way of obtaining functionalized nanomaterials, continually showing the potential to impact materials sciences and new technologies in the nearest future.
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Rozprawy doktorskie na temat "Aromatic chemistry"

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Robertson, Charles Ray. "Chemistry towards curved polycyclic aromatic hydrocarbons". abstract and full text PDF (free order & download UNR users only), 2006. http://0-gateway.proquest.com.innopac.library.unr.edu/openurl?url_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:dissertation&res_dat=xri:pqdiss&rft_dat=xri:pqdiss:1438911.

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Sestiaa, Lionel G. "New pathways in aromatic polymer chemistry". Thesis, University of Reading, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.402914.

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Dainty, Richard Frank. "Aromatic annulations". Thesis, University of Southampton, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.242247.

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Laws, Andrew Peter. "The quantitative electrophilic aromatic reactivity of some novel aromatic compounds". Thesis, University of Sussex, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.328304.

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Myers, Eddie Leonard. "Heterocyclic aromatic nucleic acids". Thesis, McGill University, 2002. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=79056.

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In order to investigate the role played by the aromatic moiety of Aromatic Peptide Nucleic Acids (APNAs) in their ability to hybridize with RNA and DNA, as well as improve the solubility of APNA oligomers in aqueous solutions, a new generation of heterocyclic monomers were designed. APNA monomers, where the nucleobase can be thymine, cytosine adenine or guanine, with backbones contain thiophene and pyridine moieties were synthesized. Suitably protected APNA-APNA and PNA-APNA dimers were also synthesized as building blocks for the solid phase synthesis of APNA-PNA chimeras and APNA homopolymers. Due to the instability of the pyridine-containing APNA oligomers to the harsh acidic conditions required to cleave oligomers from the MBHA resin, a new protocol was developed for the synthesis of these molecules on the trityl chloride resin. Oligomers of PNA and APNA-PNA chimeras were successfully synthesized on this solid support, and cleaved from the resin using mild acidic conditions.
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Clough, Robert Steven. "The synthesis of aromatic polyethers by aromatic nucleophilic substitution". Case Western Reserve University School of Graduate Studies / OhioLINK, 1993. http://rave.ohiolink.edu/etdc/view?acc_num=case1057072167.

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Löbermann, Florian Wolfgang. "Contributions to the chemistry of polyhydroxylated aromatic compounds". Diss., Ludwig-Maximilians-Universität München, 2013. http://nbn-resolving.de/urn:nbn:de:bvb:19-169770.

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Ferguson, Jayne Louise. "Colossal Aromatic Molecules". Thesis, University of Canterbury. Chemistry, 2013. http://hdl.handle.net/10092/8108.

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This thesis describes the preparation of a series of compounds containing π-excessive, five-membered, heterocyclic rings with peripheral aryl substituents, designed to investigate their oxidative cyclodehydrogenation and/or photocyclisation to form curved, fused aromatic systems with a heterocyclic atom at the core of the compound. The ability of these compounds to undergo oxidative cyclodehydrogenation was investigated using a range of conditions, including the use of Lewis acidic transition metals, organic reagents and light as catalysts to carry out the desired carbon-carbon bond forming reactions. Two backbone linked 2,2’-biimidazole ligands were prepared to investigate their coordination chemistry with a range of different metal ions and counter ions. Two families of model compounds, including ten previously unreported compounds, were prepared and subjected to various conditions for oxidative cyclodehydrogenation and photocyclisation resulting in the isolation of compounds with one carbon-carbon bond formed between the peripheral aryl rings in the same position on the heterocyclic ring, nineteen previously unreported compounds were isolated. Additionally, in one case oxidative cyclodehydrogenation resulted in the formation of two carbon-carbon bonds, producing a highly strained aromatic compound containing a heterocyclic ring. Photocyclisation of one family of compounds resulted in the formation of a different heterocyclic core dependent upon the substituent on the nitrogen atom. Five pentaarylpyrrole compounds, three of which were previously unreported, were also prepared after the exploration of various synthetic routes towards the pentaarylpyrrole motif. Photocyclisation also resulted in the formation of one carbon-carbon bond. The compounds resulting from oxidative cyclodehydrogenation and photocyclisation were characterised by NMR spectroscopy, UV/vis spectroscopy and fluorometry, where possible X-ray crystallography was also used. The coordination chemistry of backbone linked 2,2’-biimidazole ligands to various metal ions could be controlled by the length of the backbone linker. The ethyl linked 2,2’-biimidazole ligand formed bridging and monodentate coordination compounds with various metal ions, the metallosupramolecular assemblies produced with silver ions could be controlled by the anion present. Discrete coordination complexes were usually formed, but in two cases metallopolymers were produced. The propyl linked 2,2’-biimidazole ligand formed exclusively discrete, chelating complexes with copper (II) metal ions. Eighteen coordination complexes were prepared during the course of this study characterized by X-ray crystallography, and NMR spectroscopy where appropriate.
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Brown, James S. "The chemistry of nickel on the edge of polycyclic aromatic hydrocarbons /". free to MU campus, to others for purchase, 2004. http://wwwlib.umi.com/cr/mo/fullcit?p1422914.

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Walsh, Kelly Ann. "The alkylation of aromatic amines". Thesis, University of Ottawa (Canada), 1992. http://hdl.handle.net/10393/7659.

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N-alkylated anilines can be obtained in moderate yields from aniline and methyl formate in the presence of Rh$\sb6$(CO)$\sb $ and KI after 72 hours at 180-200$\sp\circ$C. Ru$\sb3$(CO)$\sb $ gave similar results to the unpromoted rhodium carbonyl system. Formanilide and N-methylformanilide were also formed in the reaction. The (HCr(CO)$\sb5$) -anion in the form of its PPN$\sp+$ and Et$\sb4$N$\sp+$ salts also catalysed this reaction (under hydrogen) but was selective to the formanilide products. The presence of an electron donating group on the aromatic ring favoured the formation of alkylated products in the presence of bis(triphenylphosphine)iminium (PPN$\sp+$) hydridochromiumpenta-carbonyl. Several possible mechanisms were tested and the nature of the polynuclear catalysts investigated.
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Książki na temat "Aromatic chemistry"

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Aromatic chemistry. Oxford: Oxford University Press, 1992.

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Abel, E. W., red. Aromatic Chemistry. Cambridge: Royal Society of Chemistry, 2007. http://dx.doi.org/10.1039/9781847550163.

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Sainsbury, M. Aromatic chemistry. Oxford: Oxford University Press, 1992.

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Hepworth, John D. Aromatic chemistry. New York: Wiley-Interscience, 2002.

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Franck, Heinz-Gerhard, i Jürgen Walter Stadelhofer. Industrial Aromatic Chemistry. Berlin, Heidelberg: Springer Berlin Heidelberg, 1988. http://dx.doi.org/10.1007/978-3-642-73432-8.

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Aromatic heterocyclic chemistry. Oxford: Oxford University Press, 1991.

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Bird, C. W., i G. W. H. Cheeseman, red. Aromatic and Heteroaromatic Chemistry. Cambridge: Royal Society of Chemistry, 2007. http://dx.doi.org/10.1039/9781847555694.

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Suschitzky, H., i O. Meth-Cohn, red. Aromatic and Heteroaromatic Chemistry. Cambridge: Royal Society of Chemistry, 2007. http://dx.doi.org/10.1039/9781847555755.

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D, Astruc, red. Modern arene chemistry. Weinheim: Wiley-VCH, 2002.

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Polycyclic aromatic hydrocarbons: Chemistry and carcinogenicity. Cambridge: Cambridge University Press, 1991.

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Części książek na temat "Aromatic chemistry"

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Moloney, Mark G. "Aromatic Chemistry". W How to Solve Organic Reaction Mechanisms, 128–59. Chichester, UK: John Wiley & Sons, Ltd, 2015. http://dx.doi.org/10.1002/9781118698532.ch5.

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Gupta, Radha Raman, Mahendra Kumar i Vandana Gupta. "Aromatic Heterocycles". W Heterocyclic Chemistry, 39–104. Berlin, Heidelberg: Springer Berlin Heidelberg, 1998. http://dx.doi.org/10.1007/978-3-642-72276-9_3.

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Carey, Francis A., i Richard J. Sundberg. "Aromatic Substitution". W Advanced Organic Chemistry, 539–94. Boston, MA: Springer US, 1990. http://dx.doi.org/10.1007/978-1-4613-9795-3_10.

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Agteren, Martin H., Sytze Keuning i Dick B. Janssen. "Aromatic compounds". W Environment & Chemistry, 189–286. Dordrecht: Springer Netherlands, 1998. http://dx.doi.org/10.1007/978-94-015-9062-4_4.

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Klumpp, Douglas A. "Electrophilic Aromatic Substitution". W Arene Chemistry, 1–31. Hoboken, NJ: John Wiley & Sons, Inc, 2015. http://dx.doi.org/10.1002/9781118754887.ch1.

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Hoffmann, Norbert, i Emmanuel Riguet. "Aromatic Photochemical Reactions". W Arene Chemistry, 835–68. Hoboken, NJ: John Wiley & Sons, Inc, 2015. http://dx.doi.org/10.1002/9781118754887.ch29.

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Crampton, Michael R. "Nucleophilic Aromatic Substitution". W Arene Chemistry, 131–73. Hoboken, NJ: John Wiley & Sons, Inc, 2015. http://dx.doi.org/10.1002/9781118754887.ch6.

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Rossi, Roberto A., María E. Budén i Javier F. Guastavino. "Homolytic Aromatic Substitution". W Arene Chemistry, 219–42. Hoboken, NJ: John Wiley & Sons, Inc, 2015. http://dx.doi.org/10.1002/9781118754887.ch9.

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Franck, Heinz-Gerhard, i Jürgen Walter Stadelhofer. "The future of aromatic chemistry". W Industrial Aromatic Chemistry, 447–48. Berlin, Heidelberg: Springer Berlin Heidelberg, 1988. http://dx.doi.org/10.1007/978-3-642-73432-8_16.

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Franck, Heinz-Gerhard, i Jürgen Walter Stadelhofer. "History". W Industrial Aromatic Chemistry, 1–7. Berlin, Heidelberg: Springer Berlin Heidelberg, 1988. http://dx.doi.org/10.1007/978-3-642-73432-8_1.

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Streszczenia konferencji na temat "Aromatic chemistry"

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Mongin, Florence, William Erb i Frédéric Lassagne. "Aromatic Iodides: Synthesis and Conversion to Heterocycles". W International Electronic Conference on Synthetic Organic Chemistry. Basel Switzerland: MDPI, 2022. http://dx.doi.org/10.3390/ecsoc-26-13641.

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Leontaritis, Kosta J. "PARA-Based (Paraffin-Aromatic-Resin-Asphaltene) Reservoir Oil Characterizations". W International Symposium on Oilfield Chemistry. Society of Petroleum Engineers, 1997. http://dx.doi.org/10.2118/37252-ms.

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Loru, Donatella, Melanie Schnell, Amanda Steber, Sébastien Gruet i Daniel Rap. "REVEALING THE CHEMISTRY OF POLYCYCLIC AROMATIC HYDROCARBONS BY PLASMA SOURCES". W 2021 International Symposium on Molecular Spectroscopy. Urbana, Illinois: University of Illinois at Urbana-Champaign, 2021. http://dx.doi.org/10.15278/isms.2021.fc02.

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Grigoreva, Anastasiya, Aleksandr Kotov i Аnton Shetnev. "THORPE REACTION STUDY INVOLVING NITRO-SUBSTITUTED AROMATIC NITRILES". W Chemistry of nitro compounds and related nitrogen-oxygen systems. LLC MAKS Press, 2019. http://dx.doi.org/10.29003/m762.aks-2019/237-240.

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Santos, M. Amelia. "Conformational studies of nucleoside adducts from aromatic amines". W The first European conference on computational chemistry (E.C.C.C.1). AIP, 1995. http://dx.doi.org/10.1063/1.47731.

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Sokhanvarian, Khatere, Cornell Stanciu, Jorge M. Fernandez, Ahmed Ibrahim i Hisham A. Nasr-El-Din. "Novel Non-Aromatic Non-Ionic Surfactants to Target Deep Carbonate Stimulation". W SPE International Conference on Oilfield Chemistry. Society of Petroleum Engineers, 2019. http://dx.doi.org/10.2118/193596-ms.

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Nyulászi, László, Tamás Kárpáti i Tamás Veszprémi. "Silylene the most stable form of silicone in aromatic compounds". W The first European conference on computational chemistry (E.C.C.C.1). AIP, 1995. http://dx.doi.org/10.1063/1.47669.

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Korkin, Anatoli A., i Paul von Ragué Schleyer. "Theoretical study of polysila analogs of conjugated and aromatic hydrocarbons." W The first European conference on computational chemistry (E.C.C.C.1). AIP, 1995. http://dx.doi.org/10.1063/1.47688.

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Bogdal, Dariusz, Jan Pielichowski i Adam Boron. "Synthesis of Aromatic Ethers under Microwave Irradiation in Dry Media". W The 1st International Electronic Conference on Synthetic Organic Chemistry. Basel, Switzerland: MDPI, 1997. http://dx.doi.org/10.3390/ecsoc-1-02046.

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Cabaleiro-Lago, Enrique M., Jorge A. Carrazana-García, Ivan Gonzalez-Veloso i Jesús Rodríguez-Otero. "Computational study of stacked complexes of aliphatic and aromatic species". W The 23rd International Electronic Conference on Synthetic Organic Chemistry. Basel, Switzerland: MDPI, 2019. http://dx.doi.org/10.3390/ecsoc-23-06603.

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Raporty organizacyjne na temat "Aromatic chemistry"

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Glassman, I., i K. Brezinsky. Aromatic-radical oxidation chemistry. Office of Scientific and Technical Information (OSTI), styczeń 1993. http://dx.doi.org/10.2172/6579384.

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Scott, L. T. High temperature chemistry of aromatic hydrocarbons. Office of Scientific and Technical Information (OSTI), grudzień 1991. http://dx.doi.org/10.2172/10110066.

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Glassman, I., i K. Brezinsky. Aromatic-radical oxidation chemistry. Progress report. Office of Scientific and Technical Information (OSTI), maj 1993. http://dx.doi.org/10.2172/10149531.

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Scott, L. T. High temperature chemistry of aromatic hydrocarbons. Office of Scientific and Technical Information (OSTI), styczeń 1991. http://dx.doi.org/10.2172/5900415.

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Brezinsky, Kenneth. Aromatic Radicals-Acetylene Particulate Matter Chemistry. Fort Belvoir, VA: Defense Technical Information Center, grudzień 2011. http://dx.doi.org/10.21236/ada555986.

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Scott, L. (High temperature chemistry of aromatic hydrocarbons). Office of Scientific and Technical Information (OSTI), listopad 1989. http://dx.doi.org/10.2172/5417776.

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Scott, Lawrence T. High Temperature Chemistry of Aromatic Hydrocarbons. Final Technical Report. Office of Scientific and Technical Information (OSTI), maj 2017. http://dx.doi.org/10.2172/1356819.

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Longwall, J. P., C. C. S. Chang, C. K. S. Lai, P. Chen, M. R. Hajaligol i W. A. Peters. Applications of organo-calcium chemistry to control contaminant aromatic hydrocarbons in advanced coal gasification processes: Final technical progress report. Office of Scientific and Technical Information (OSTI), wrzesień 1988. http://dx.doi.org/10.2172/6315937.

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