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Artykuły w czasopismach na temat „2-dimensional polymers”

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Data publikacji: 6 września 2023

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1

Marchenko, Roman D., Taisiya S. Sukhikh, Alexey A. Ryadun, and Andrei S. Potapov. "Synthesis, Crystal Structure, and Luminescence of Cadmium(II) and Silver(I) Coordination Polymers Based on 1,3-Bis(1,2,4-triazol-1-yl)adamantane." Molecules 26, no. 17 (2021): 5400. http://dx.doi.org/10.3390/molecules26175400.

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Coordination polymers with a new rigid ligand 1,3-bis(1,2,4-triazol-1-yl)adamantane (L) were prepared by its reaction with cadmium(II) or silver(I) nitrates. Crystal structure of the coordination polymers was determined using single-crystal X-ray diffraction analysis. Silver formed two-dimensional coordination polymer [Ag(L)NO3]n, in which metal ions are linked by 1,3-bis(1,2,4-triazol-1-yl)adamantane ligands, coordinated by nitrogen atoms at positions 2 and 4 of 1,2,4-triazole rings. Layers of the coordination polymer consist of rare 18- and 30-membered {Ag2L2} and {Ag4L4} metallocycles. Cadm

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2

Dang, Ming-An, Zi-Feng Li, Ying Liu, and Gang Li. "Three Coordination Polymers Built by Methoxyphenyl Imidazole Dicarboxylate: Solvothermal Syntheses, Crystal Structures, and Properties." Australian Journal of Chemistry 68, no. 6 (2015): 956. http://dx.doi.org/10.1071/ch14159.

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Three coordination polymers [Sr(p-H2MOPhIDC)2]n (1) (p-H3MOPhIDC = 2-p-methoxyphenyl-1H-imidazole-4,5-dicarboxylic acid), {[Cd2(p-HMOPhIDC)2(4,4′-bipy)]⋅H2O}n (4,4′-bipy = 4,4′-bipyridine) (2), and [Zn(p-HMOPhIDC)(4,4′-bipy)]n (3) have been solvothermally synthesized, and structurally characterized by single-crystal X-ray diffraction. Polymer 1 indicates a three-dimensional framework, which can be simplified as a 6-connected lattice. Polymer 2 is also a three-dimensional framework, and contains mixed bridging ligands HMOPhIDC2– and 4,4′-bipy. Polymer 3 exhibits a sheet structure bearing infini

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3

Kadir, M. A., and Christopher J. Sumby. "Synthesis, Characterization and Crystal Structure of Coordination Polymers Developed as Anion Receptor." Solid State Phenomena 273 (April 2018): 134–39. http://dx.doi.org/10.4028/www.scientific.net/ssp.273.134.

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Reaction of diamide ligand, namelyN,N’-2,6-bis (4-pyridylmethyl) pyridine dicarboxamide (L) with cadmium nitrate and cadmium perchlorate has given rise to the formation of two types coordination polymers. Compound (CP1-Cd) with formula molecule {[Cd (L)2(H2O)2](NO3)2·6H2O}nis a one-dimensional coordination polymer while compound (CP2-Cd), with formula molecule {[Cd (L)2(H2O)2](ClO4)2·31⁄2H2O.CH3OH}n, is a two dimensional coordination polymer. These coordination polymers were preparedviaslow evaporation methods and completely characterized by combination of solid state techniques such as Fourie

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4

Hsu, H. P., and P. Grassberger. "2-Dimensional polymers confined in a strip." European Physical Journal B - Condensed Matter 36, no. 2 (2003): 209–14. http://dx.doi.org/10.1140/epjb/e2003-00337-6.

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5

Ullah, Ihsan, Jong Won Shin, Ryuya Tokunaga, Shinya Hayami, Hye Jin Shin, and Kil Sik Min. "Anion-Dependent Cu(II) Coordination Polymers: Geometric, Magnetic and Luminescent Properties." Crystals 12, no. 8 (2022): 1096. http://dx.doi.org/10.3390/cryst12081096.

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A one-dimensional (1D) coordination polymer [Cu2(bpba)(CH3COO)4] (1) and a two-dimensional (2D) coordination polymer [Cu(bpba)2(H2O)(NO3)](NO3)∙2H2O∙MeOH (2) were synthesized by the reaction between Cu(CH3COO)2∙H2O/Cu(NO3)2∙3H2O and bis(4-pyridyl)benzylamine (bpba). The Cu(II) ions of 1 and 2 have distorted-square pyramidal coordination with a paddle-wheel structure and an octahedral geometry, respectively. By coordinating the Cu(II) ions and bpba ligands, 1 and 2 formed zigzag 1D and puckered 2D coordination polymers, respectively. Polymer 1 exhibits strong emissions at 355 and 466 nm, wherea

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6

Baek, Geunryeol, and Su-Chul Yang. "Effect of the Two-Dimensional Magnetostrictive Fillers of CoFe2O4-Intercalated Graphene Oxide Sheets in 3-2 Type Poly(vinylidene fluoride)-Based Magnetoelectric Films." Polymers 13, no. 11 (2021): 1782. http://dx.doi.org/10.3390/polym13111782.

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In the last decade, magnetoelectric (ME) polymer films have been developed by including zero-dimensional or one-dimensional magnetostrictive fillers in a piezoelectric polymer matrix. Existing reports on ME polymer films reveal that the shape of the magnetostrictive fillers is a critical determinant of the polymeric phase conformation, strain transfer between the piezoelectric and magnetostrictive phases, and dipole alignment in the films. In this study, to investigate the effect of two-dimensional (2D) magnetostrictive fillers on piezoelectric, magnetic, and magnetoelectric responses, 3-2 typ

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7

Xu, Chao, Sheng-Bo Liu, Taike Duan, Qun Chen, and Qian-Feng Zhang. "Syntheses, Structures and Photoluminescent Properties of the Two Novel Coordination Polymers [Cd(pydc)2(tu)]n and [Cd2(SO4)(nic)2(tu)1.5(H2O)2]n (pydc = Pyridine-2,3-dicarboxylate, nic = Nicotinate, tu = Thiourea)." Zeitschrift für Naturforschung B 66, no. 5 (2011): 459–64. http://dx.doi.org/10.1515/znb-2011-0504.

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Two novel cadmium coordination polymers, [Cd(pydc)2(tu)]n (1) and [Cd2(SO4)(nic)2(tu)1.5 - (H2O)2]n (2) (pydc = pyridine-2,3-dicarboxylate, nic = nicotinate, tu = thiourea), have been synthesized under hydrothermal conditions and structurally characterized by X-ray diffraction analysis. 1 is a one-dimensional ladder coordination polymer in a two-dimensional network formed by hydrogen bonds. 2 consists of two kinds of Cd(II) centers in different coordination environments connected via nicotinate and sulfate to form a two-dimensional grid network integrated in a three-dimensional framework gener

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8

Leonor, Isabel B., Hyun Min Kim, Francisco Balas, et al. "Formation of Bone-Like Apatite on Polymeric Surfaces Modified with -SO₃H Groups." Materials Science Forum 514-516 (May 2006): 966–69. http://dx.doi.org/10.4028/www.scientific.net/msf.514-516.966.

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Sulfonic groups (-SO3H) were covalently attached on different polymeric surfaces enabling them to induce apatite nucleation, for developing bioactive apatite-polymer composites with a bonelike 3-dimensional structure. High molecular weight polyethylene (HMWPE) and ethylene-co-vinyl alcohol co-polymer (EVOH) were used. The polymers were soaked in two types of sulphate-containing solutions with different concentrations, sulphuric acid (H2SO4) and chlorosulfonic acid (ClSO3H). To incorporate calcium ions into to the sulfonated polymers, the samples were soaked in a saturated Ca(OH)2 solution for

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9

Brown, Matthew L., and Daniel B. Leznoff. "Expanding uranyl dicyanoaurate coordination polymers into the second and third dimensions." Canadian Journal of Chemistry 98, no. 7 (2020): 365–72. http://dx.doi.org/10.1139/cjc-2020-0031.

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The solvothermal synthesis and characterization of a three-dimensional, interpenetrated uranyl dicyanoaurate coordination polymer, K2(UO2)2(UO2)2(Au(CN)2)2(O)2(NO3)4, from UO2(NO3)2·6H2O and KAu(CN)2 is described. The structure contains a three-dimensional (3D) lattice of planar tetranuclear uranyl–oxo–nitrate clusters connected by dicyanoaurate linkers, with the rotation of the clusters providing the increased dimensionality. The material undergoes a reversible single-crystal to single-crystal transformation on exposure to water vapour, which is taken up in the channels of the 3D system. A se

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10

Choi, Junhwan, and Hocheon Yoo. "Combination of Polymer Gate Dielectric and Two-Dimensional Semiconductor for Emerging Field-Effect Transistors." Polymers 15, no. 6 (2023): 1395. http://dx.doi.org/10.3390/polym15061395.

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Two-dimensional (2D) materials are considered attractive semiconducting layers for emerging field-effect transistors owing to their unique electronic and optoelectronic properties. Polymers have been utilized in combination with 2D semiconductors as gate dielectric layers in field-effect transistors (FETs). Despite their distinctive advantages, the applicability of polymer gate dielectric materials for 2D semiconductor FETs has rarely been discussed in a comprehensive manner. Therefore, this paper reviews recent progress relating to 2D semiconductor FETs based on a wide range of polymeric gate

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11

Ewert, Ernest, Izabela Pospieszna-Markiewicz, Martyna Szymańska, et al. "New N4-Donor Ligands as Supramolecular Guests for DNA and RNA: Synthesis, Structural Characterization, In Silico, Spectrophotometric and Antimicrobial Studies." Molecules 28, no. 1 (2023): 400. http://dx.doi.org/10.3390/molecules28010400.

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The present work reports the synthesis of new N4-donor compounds carrying p-xylyl spacers in their structure. Different Schiff base aliphatic N-donors were obtained synthetically and subsequently evaluated for their ability to interact with two models of nucleic acids: calf-thymus DNA (CT-DNA) and the RNA from yeast Saccharomyces cerevisiae (herein simply indicated as RNA). In more detail, by condensing p-xylylenediamine and a series of aldehydes, we obtained the following Schiff base ligands: 2-thiazolecarboxaldehyde (L1), pyridine-2-carboxaldehyde (L2), 5-methylisoxazole-3-carboxaldehyde (L3

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12

ZEGHAIDER, MUSTAPHA, and MABROUK BENHAMOU. "ANALYTICAL PROPERTIES OF SCATTERED INTENSITY FROM GAUSSIAN D-MANIFOLDS AND TWO-DIMENSIONAL MEMBRANES." Fractals 07, no. 04 (1999): 377–85. http://dx.doi.org/10.1142/s0218348x99000384.

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The purpose of the present work is a systematic and analytical study of the scattering properties of Gaussian D-manifolds (1≤D<2) and two-dimensional membranes (D=2). Here, D is the spectral (or internal) dimension of the polymeric complex. We first determine exactly their gyration radius and the higher order moments. Then, we construct a simple integral representation of the structure factor, in the case of D-manifolds (1≤D<2). By analytical continuation in dimension D, this representation enables us to get much information about those polymeric systems of non-integer internal dimension

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13

Shao, Zhi-Chao, Xiang-Ru Meng, and Hong-Wei Hou. "Effect of pH on the construction of CdII coordination polymers involving the 1,1′-[1,4-phenylenebis(methylene)]bis(3,5-dicarboxylatopyridinium) ligand." Acta Crystallographica Section C Structural Chemistry 75, no. 8 (2019): 1142–49. http://dx.doi.org/10.1107/s2053229619010192.

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Changing the pH value of a reaction system can result in polymers with very different compositions and architectures. Two new coordination polymers based on 1,1′-[1,4-phenylenebis(methylene)]bis(3,5-dicarboxylatopyridinium) (L 2−), namely catena-poly[[[tetraaquacadmium(II)]-μ2-1,1′-[1,4-phenylenebis(methylene)]bis(3,5-dicarboxylatopyridinium)] 1.66-hydrate], {[Cd(C22H14N2O8)(H2O)4]·1.66H2O} n , (I), and poly[{μ6-1,1′-[1,4-phenylenebis(methylene)]bis(3,5-dicarboxylatopyridinium)}cadmium(II)], [Cd(C22H14N2O8)] n , (II), have been prepared in the presence of NaOH or HNO3 and structurally characte

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14

Wang, Li-Fei, Xing-Gui Liu, Mei-Mei Meng, et al. "Three coordination polymers built by quaternary-ammonium-modified isophthalic acid." Acta Crystallographica Section C Structural Chemistry 77, no. 5 (2021): 221–26. http://dx.doi.org/10.1107/s2053229621003296.

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Three coordination polymers based on quaternary-ammonium-modified isophthalic acid, namely, catena-poly[[[aqua-μ2-bromido-di-μ3-hydroxido-methanoldinitratotetracopper(II)]-bis{μ4-5-[2-(tripropylazaniumyl)ethoxy]benzene-1,3-dicarboxylato}] nitrate], {[Cu4Br(C19H28NO5)2(NO3)2(OH)2(CH4O)(H2O)]NO3} n , 1, poly[μ3-bromido-μ2-bromido-bromido-μ3-hydroxido-{μ4-5-[2-(tripropylazaniumyl)ethoxy]benzene-1,3-dicarboxylato}tricopper(II)], [Cu3Br3(C19H28NO5)(OH)] n , 2, and poly[bromido{μ3-5-[2-(tripropylazaniumyl)ethoxy]benzene-1,3-dicarboxylato}zinc(II)], [ZnBr(C19H28NO5)] n , 3, were obtained by solvother

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15

Nonoguchi, Yoshiyuki, Dai Sato, and Tsuyoshi Kawai. "Crystallinity-Dependent Thermoelectric Properties of a Two-Dimensional Coordination Polymer: Ni3(2,3,6,7,10,11-hexaiminotriphenylene)2." Polymers 10, no. 9 (2018): 962. http://dx.doi.org/10.3390/polym10090962.

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The evaluation of thermoelectric properties has recently become a standard method for revealing the electronic properties of conducting polymers. Herein we report on the thermoelectric properties of a two-dimensional coordination polymer pellets. The pellets of Ni3(2,3,6,7,10,11-hexaiminotriphenylene)2, which has recently been developed, show n-type thermoelectric transport, dependent on crystallinity. The present results provide systematic feedback to the guideline for high-performance molecular thermoelectric materials.

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16

Wang, Yong-Tao, Gui-Mei Tang, and Da-Wei Qin. "Metal-Controlled Assembly Tuning Coordination Polymers with Flexible 2-(1H-imidazole-1-yl)acetic Acid (Hima)." Australian Journal of Chemistry 59, no. 9 (2006): 647. http://dx.doi.org/10.1071/ch06183.

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Three new inorganic–organic coordination polymers based on a versatile linking unit 2-(1H-imidazole-1-yl)acetate (Hima) and divalent Mn(ii), Ni(ii), and Cu(ii) ions, exhibiting two kinds of two dimensionalities with different topological structures, have been prepared in water medium and structurally characterized by single-crystal X-ray diffraction analysis. Reaction of MnCl2·4H2O and Ni(NO3)2·6H2O with Hima yielded neutral two-dimensional (2D) coordination polymers [M(ima)2]n, M = Mn(ii) 1, and Ni(ii) 2 with isostructural 2D coordination polymers possessing (3,6) topology structures, which f

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17

Xu, Yun, Qing-Hua Deng, Fang Ding, Ran An, Dong Liu, and Ti-Fang Miao. "Three New Supramolecular Coordination Polymers Based on 1H-pyrazolo[3,4-b]pyridin-3-amine and 1,3-benzenedicarboxylate Derivatives." Polymers 11, no. 5 (2019): 819. http://dx.doi.org/10.3390/polym11050819.

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Three new supramolecular coordination polymers, namely [Zn(1,3-BDC)(HL)]n (Polymer 1), [Zn3(1,3,5-BTC)2(HL)2(H2O)2]n (Polymer 2), and [Zn9(5-SO3-1,3-BDC)2(L)8(OH)4]n (Polymer 3), were synthesized under solvothermal conditions, based on 1H-pyrazolo[3,4-b]pyridin-3-amine (HL) along with 1,3-benzenedicarboxylate (1,3-BDC) and its derivatives, such as 1,3,5-benzenetricarboxylate (1,3,5-BTC) and 5-sulfo-1,3-benzenedicarboxylate (5-SO3-1,3-BDC). Polymers 1–3 were characterized by elemental analysis, IR spectroscopy, powder X-ray diffraction (PXRD), and single crystal X-ray diffraction analysis. Poly

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Krinchampa, Pattiya, Kittipong Chainok, Siriporn Phengthaisong, Sujittra Youngme, Filip Kielar та Nanthawat Wannarit. "A novel one-dimensional double-chain-like ZnIIcoordination polymer: poly[bis(1-benzyl-1H-imidazole-κN3)tris(μ-cyanido-κ2C:N)(cyanido-κC)disilver(I)zinc(II)]". Acta Crystallographica Section C Structural Chemistry 72, № 12 (2016): 960–65. http://dx.doi.org/10.1107/s2053229616017502.

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One of most interesting systems of coordination polymers constructed from the first-row transition metals is the porous ZnIIcoordination polymer system, but the numbers of such polymers containingN-donor linkers are still limited. The title double-chain-like ZnIIcoordination polymer, [Ag2Zn(CN)4(C10H10N2)2]n, presents a one-dimensional linear coordination polymer structure in which ZnIIions are linked by bridging anionic dicyanidoargentate(I) units along the crystallographicbaxis and each ZnIIion is additionally coordinated by a terminal dicyanidoargentate(I) unit and two terminal 1-benzyl-1H-

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Matijaković Mlinarić, Nives, Nikolina Penić, Boris-Marko Kukovec, and Marijana Đaković. "Chalcogen S∙∙∙S Bonding in Supramolecular Assemblies of Cadmium(II) Coordination Polymers with Pyridine-Based Ligands." Crystals 11, no. 6 (2021): 697. http://dx.doi.org/10.3390/cryst11060697.

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Two cadmium(II) coordination polymers, with thiocyanate and pyridine-based ligands e.g., 3-acetamidopyridine (3-Acpy) and niazid (nicotinic acid hydrazide, nia), namely one-dimensional {[Cd(SCN)2(3-Acpy)]}n (1) and two-dimensional {[Cd(SCN)2(nia)]}n (2), are prepared in the mixture of water and ethanol. The adjacent cadmium(II) ions in 1 are bridged by two N,S-thiocyanate ions and an N,O-bridging 3-Acpy molecule, forming infinite one-dimensional polymeric chains, which are assembled by the intermolecular N–H∙∙∙S hydrogen bonds in one direction and by the intermolecular S∙∙∙S chalcogen bonds in

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Tran, Bay V., Tuan Anh Pham, Michael Grunst, Milan Kivala, and Meike Stöhr. "Surface-confined [2 + 2] cycloaddition towards one-dimensional polymers featuring cyclobutadiene units." Nanoscale 9, no. 46 (2017): 18305–10. http://dx.doi.org/10.1039/c7nr06187k.

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Gardner, Heather C., Alan R. Kennedy, Karen M. McCarney, Edward Staunton, Heather Stewart, and Simon J. Teat. "Structures of five salt forms of disulfonated monoazo dyes." Acta Crystallographica Section C Structural Chemistry 76, no. 10 (2020): 972–81. http://dx.doi.org/10.1107/s2053229620012735.

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The structures of five s-block metal salt forms of three disulfonated monoazo dyes are presented. These are poly[di-μ-aqua-diaqua[μ4-3,3′-(diazane-1,2-diyl)bis(benzenesulfonato)]disodium(I)], [Na2(C12H8N2O6S2)(H2O)4] n , (I), catena-poly[[tetraaquacalcium(II)]-μ-3,3′-(diazane-1,2-diyl)bis(benzenesulfonato)], [Ca(C12H8N2O6S2)(H2O)4] n , (II), catena-poly[[[diaquacalcium(II)]-μ-2-(4-amino-3-sulfonatophenyl)-1-(4-sulfonatophenyl)diazenium] dihydrate], {[Na(C12H10N3O6S2)(H2O)2]·2H2O} n , (III), hexaaquamagnesium bis[2-(4-amino-3-sulfonatophenyl)-1-(4-sulfonatophenyl)diazenium] octahydrate, [Mg(H2O

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Sciortino, Natasha F., and Suzanne M. Neville. "Two-Dimensional Coordination Polymers with Spin Crossover Functionality." Australian Journal of Chemistry 67, no. 11 (2014): 1553. http://dx.doi.org/10.1071/ch14381.

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In the solid state, the propagation of spin crossover (SCO) information is governed by a complex interplay between inner and outer coordination sphere effects. In this way, lattice cooperativity can be enhanced through solid state packing interactions (i.e. hydrogen-bonding and π-stacking) and via coordinatively linking spin switching sites (i.e. coordination polymers). SCO framework materials have successfully provided an avenue for enhanced cooperativity and additional function as host–guest sensors via their potential porosity. In this review, we explore two-dimensional SCO coordination pol

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Arlin, Jean-Baptiste, Alan R. Kennedy, and Kenneth Shankland. "Magnesium, calcium and strontium salts of phenylacetic acid." Acta Crystallographica Section C Crystal Structure Communications 68, no. 2 (2012): m29—m33. http://dx.doi.org/10.1107/s0108270111055284.

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Three alkaline earth metal salts of phenylacetic acid were examined and all were found to have similar structural types to analogous salts of benzoic and halobenzoic acids. Thus, a synchrotron study shows that the cations incatena-poly[[[tetraaquamagnesium(II)]-μ-phenylacetato-κ2O:O′] phenylacetate], {[Mg(C8H7O2)(H2O)4](C8H7O2)}n, form a one-dimensional coordination polymer that propagates through Mg—O—C—O—Mg interactions involving both crystallographically independent Mg centres (Z′ = 2) and through translation along theaaxis. The polymeric chains pack to give alternate inorganic layers and o

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Qin, Zengquan, Hilary A. Jenkins, Simon J. Coles, Kenneth W. Muir, and Richard J. Puddephatt. "Self-assembly of one-dimensional polymers by coordination and hydrogen bonding in palladium(II) complexes." Canadian Journal of Chemistry 77, no. 1 (1999): 155–57. http://dx.doi.org/10.1139/v99-027.

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The ligands L = pyridine- or quinoline-carboxylic acid easily give complexes trans-[PdCl2L2], which self-assemble through hydrogen bonding between carboxylic acid groups to give one-dimensional polymers, as proved by structure determinations when L = NC5H4COOH-4, NC5H4COOH-3, and 2-Ph-NC9H5COOH-4.Key words: polymer, hydrogen-bonding, palladium, coordination.

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Shao, Zhi-Chao, Xiang-Ru Meng, and Hong-Wei Hou. "Two new CdII and ZnII coordination polymers incorporating 1-aminobenzene-3,4,5-tricarboxylic acid: synthesis, crystal structure and characterization." Acta Crystallographica Section C Structural Chemistry 75, no. 8 (2019): 1065–72. http://dx.doi.org/10.1107/s2053229619009227.

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Aminobenzoic acid derivatives are widely used in the preparation of new coordination polymers since they contain O-atom donors, as well as N-atom donors, and have a rich variety of coordination modes which can lead to polymers with intriguing structures and interesting properties. Two new coordination polymers incorporating 1-aminobenzene-3,4,5-tricarboxylic acid (H3abtc), namely, poly[(μ3-1-amino-5-carboxybenzene-3,4-dicarboxylato)diaquacadmium(II)], [Cd(C9H5NO6)(H2O)2] n , (I), and poly[[bis(μ5-1-aminobenzene-3,4,5-tricarboxylato)triaquatrizinc(II)] dihydrate], {[Zn3(C9H4NO6)2(H2O)3]·2H2O} n

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Kim, Hyun-Chul, Ja-Min Gu, Seong Huh, Chul-Hyun Yo, and Youngmee Kim. "One-dimensional CuIIcoordination polymers containingC2h-symmetric 1,1′:4′,1′′-terphenyl-3,3′-dicarboxylate linkers." Acta Crystallographica Section C Structural Chemistry 71, no. 10 (2015): 929–35. http://dx.doi.org/10.1107/s2053229615017088.

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Two new one-dimensional CuIIcoordination polymers (CPs) containing theC2h-symmetric terphenyl-based dicarboxylate linker 1,1′:4′,1′′-terphenyl-3,3′-dicarboxylate (3,3′-TPDC), namelycatena-poly[[bis(dimethylamine-κN)copper(II)]-μ-1,1′:4′,1′′-terphenyl-3,3′-dicarboxylato-κ4O,O′:O′′:O′′′] monohydrate], {[Cu(C20H12O4)(C2H7N)2]·H2O}n, (I), andcatena-poly[[aquabis(dimethylamine-κN)copper(II)]-μ-1,1′:4′,1′′-terphenyl-3,3′-dicarboxylato-κ2O3:O3′] monohydrate], {[Cu(C20H12O4)(C2H7N)2(H2O)]·H2O}n, (II), were both obtained from two different methods of preparation: one reaction was performed in the prese

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Iranmanesh, Hasti, Kasun S. A. Arachchige, William A. Donald та ін. "Rage Against Conformity: Ruthenium(ɪɪ) Bisterpyridine Complexes Respond to Crystal Engineering Instructions with Whelming Results". Australian Journal of Chemistry 70, № 5 (2017): 529. http://dx.doi.org/10.1071/ch16620.

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Four heteroleptic ruthenium(ii) complexes of 4′-functionalised 2,2′:6′,2′′-terpyridine are reported, along with their solid-state single-crystal X-ray structures. The complexes feature complementary hydrogen-bond donor (phenol) and acceptor (pyridyl) groups designed to assemble into one-dimensional polymers. In one example, the system obeys the programmed instructions to form a one-dimensional, self-complementary hydrogen-bonded polymer. In one other example, a water-bridged hydrogen-bonded polymer is formed. In the remaining two structures, aryl–aryl interactions dominate the intermolecular i

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28

Davarcı, Derya, Rüştü Gür, Serap Beşli, Elif Şenkuytu, and Yunus Zorlu. "Silver(I) coordination polymers assembled from flexible cyclotriphosphazene ligand: structures, topologies and investigation of the counteranion effects." Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials 72, no. 3 (2016): 344–56. http://dx.doi.org/10.1107/s2052520616002663.

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The reactions of a flexible ligand hexakis(3-pyridyloxy)cyclotriphosphazene (HPCP) with a variety of silver(I) salts (AgX;X= NO3−, PF6−, ClO4−, CH3PhSO3−, BF4−and CF3SO3−) afforded six silver(I) coordination polymers, namely {[Ag2(HPCP)]·(NO3)2·H2O}n(1), {[Ag2(HPCP)(CH3CN)]·(PF6)2}n(2), {[Ag2(HPCP)(CH3CN)]·(ClO4)2}n(3), [Ag3(HPCP)(CH3PhSO3)3]n(4), [Ag2(HPCP)(CH3CN)(BF4)2]n(5) and {[Ag(HPCP)]·(CF3SO3)}n(6). All of the isolated crystalline compounds were structurally determined by X-ray crystallography. Changing the counteranions in the reactions, which were conducted under similar conditions of

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29

Liu, Chun-Sen, Min Hu, Song-Tao Ma, et al. "Coordination Polymers with a Bulky Perylene-Based Tetracarboxylate Ligand: Syntheses, Crystal Structures, and Luminescent Properties." Australian Journal of Chemistry 63, no. 3 (2010): 463. http://dx.doi.org/10.1071/ch09411.

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To explore the coordination possibilities of perylene-based ligands with a larger conjugated π-system, four ZnII, MnII, and CoII coordination polymers with perylene-3,4,9,10-tetracarboxylate (ptc) and the chelating 1,10-phenanthroline (phen) ligands were synthesized and characterized: {[Zn2(ptc)(phen)2](H2O)10}∞ (1), {[Zn3(ptc)(OH)2(phen)2](H2O)3}∞ (2), {[Mn(ptc)0.5(phen)(H2O)2](H2O)1.5}∞ (3), and {[Co(ptc)0.5(phen)(H2O)2](H2O)2.5}∞ (4). Structural analysis reveals that complexes 1 and 2 both take one-dimensional polymeric chain structures with dinuclear and trinuclear units as nodes, respecti

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30

Li, Xiao-Fei, Di Cheng, Xiang-Ru Meng, and Huai-Xia Yang. "Effects of two benzenedicarboxylic acids on the construction of CdII coordination polymers incorporating a flexible N-donor ligand." Acta Crystallographica Section C Structural Chemistry 75, no. 6 (2019): 643–49. http://dx.doi.org/10.1107/s2053229619005758.

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Compared with the monomorphic type of ligand, combining mixed ligands in one coordination polymer offers greater tunability of the structural framework. Employment of N-heterocyclic ligands and aromatic polycarboxylates is an effective approach for the construction of metal–organic frameworks (MOFs). Two new coordination polymers incorporating both 2-[(1H-imidazol-1-yl)methyl]-1H-benzimidazole (imb) and benzenedicarboxylic acid isomers, namely, catena-poly[[[di-μ-chlorido-bis[(2-carboxybenzoato-κ2 O 1,O 1′)cadmium(II)]]-bis{μ-2-[(1H-imidazol-1-yl)methyl]-1H-benzimidazole-κ2 N:N′}] dihydrate],

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31

Karthikeyan, Ammasai, Packianathan Thomas Muthiah, and Franc Perdih. "Supramolecular architectures in CoIIand CuIIcomplexes with thiophene-2-carboxylate and 2-amino-4,6-dimethoxypyrimidine ligands." Acta Crystallographica Section C Structural Chemistry 72, no. 5 (2016): 442–50. http://dx.doi.org/10.1107/s2053229616006148.

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The coordination chemistry of mixed-ligand complexes continues to be an active area of research since these compounds have a wide range of applications. Many coordination polymers and metal–organic framworks are emerging as novel functional materials. Aminopyrimidine and its derivatives are flexible ligands with versatile binding and coordination modes which have been proven to be useful in the construction of organic–inorganic hybrid materials and coordination polymers. Thiophenecarboxylic acid, its derivatives and their complexes exhibit pharmacological properties. Cobalt(II) and copper(II)

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32

Jin, Guoxia, Jia Wang, Qidi Wu, Zheng Han, and Jianping Ma. "Novel one- and two-dimensional ZnIIcoordination polymers based on a versatile 3,6-bis(pyridin-4-yl)phenanthrene-9,10-dione ligand." Acta Crystallographica Section C Structural Chemistry 71, no. 12 (2015): 1089–95. http://dx.doi.org/10.1107/s2053229615022159.

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Two new ZnIIcoordination polymers, namely,catena-poly[[dibromidozinc(II)]-μ-[3,6-bis(pyridin-4-yl)phenanthrene-9,10-dione-κ2N:N′]], [ZnBr2(C24H14N2O2)]n, (1), and poly[[bromido[μ3-10-hydroxy-3,6-bis(pyridin-4-yl)phenanthren-9-olato-κ3N:N′:O9]zinc(II)] hemihydrate], {[ZnBr(C24H15N2O2)]·0.5H2O}n, (2), have been synthesized through hydrothermal reaction of ZnBr2and a 60° angular phenanthrenedione-based linker,i.e.3,6-bis(pyridin-4-yl)phenanthrene-9,10-dione, in different solvent systems. Single-crystal analysis reveals that polymer (1) features one-dimensional zigzag chains connected by weak C—H.

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33

Wright, James S., Iñigo J. Vitórica-Yrezábal, Harry Adams, Stephen P. Thompson, Adrian H. Hill, and Lee Brammer. "Solvent-vapour-assisted pathways and the role of pre-organization in solid-state transformations of coordination polymers." IUCrJ 2, no. 2 (2015): 188–97. http://dx.doi.org/10.1107/s2052252515000147.

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A family of one-dimensional coordination polymers, [Ag4(O2C(CF2)2CF3)4(phenazine)2(arene)n]·m(arene),1(arene = toluene or xylene), have been synthesized and crystallographically characterized. Arene guest loss invokes structural transformations to yield a pair of polymorphic coordination polymers [Ag4(O2C(CF2)2CF3)4(phenazine)2],2aand/or2b, with one- and two-dimensional architectures, respectively. The role of pre-organization of the polymer chains of1in the selectivity for formation of either polymorph is explored, and the templating effect of toluene andp-xylene overo-xylene orm-xylene in th

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34

Liu, Guo-Cheng, Zhi-Chao Guo, Xiu-Li Wang, Yun Qu, Song Yang, and Hong-Yan Lin. "Tuning 1-D Pb(II) Coordination Polymers by Flexible and Semirigid Dicarboxylates: Synthesis, Structure and Properties." Zeitschrift für Naturforschung B 67, no. 3 (2012): 185–91. http://dx.doi.org/10.1515/znb-2012-0301.

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Two new one-dimensional (1-D) Pb(II) coordination polymers, namely, [Pb(3-pdip)(L1)]·H2O (1) and [Pb(3-pdip)(L2)] (2) [L1H2 = 1,6-hexanedioic acid, L2H2 = homophthalic acid, 3-pdip = 2-(3-pyridyl)imidazo[4,5-f]1,10-phenanthroline] have been obtained from hydrothermal reactions of Pb(II) nitrate with the phenanthroline derivative and the two dicarboxylic acids. Single-crystal X-ray diffraction analysis reveals that compound 1 is a staircase-like double-chain coordination polymer constructed from binuclear [Pb2N4O8] subunits and pairs of [L1]2− anions. Compound 2 is a linear coordination polymer

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35

Hsu, Wayne, Kedar Bahadur Thapa, Xiang-Kai Yang, Kuan-Ting Chen, Han-Yun Chang, and Jhy-Der Chen. "Dinitrogen-supported coordination polymers." CrystEngComm 18, no. 3 (2016): 390–93. http://dx.doi.org/10.1039/c5ce02127h.

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Two novel three-dimensional dinitrogen-supported coordination polymers adopting the (5<sup>3</sup>·7<sup>3</sup>)<sub>2</sub>(5<sup>4</sup>·8<sup>2</sup>) and (5<sup>3</sup>)<sub>4</sub>(5<sup>8</sup>·6<sup>4</sup>·7<sup>8</sup>·8<sup>4</sup>·9<sup>4</sup>)<sub>2</sub>-3,8T16 topologies are reported.

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36

Liu, Chun-Li, Qiu-Ying Huang, and Xiang-Ru Meng. "A one-dimensional zinc(II) coordination polymer with a three-dimensional supramolecular architecture incorporating 1-[(1H-benzimidazol-2-yl)methyl]-1H-tetrazole and adipate." Acta Crystallographica Section C Structural Chemistry 72, no. 12 (2016): 1002–6. http://dx.doi.org/10.1107/s205322961601874x.

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The synthesis of coordination polymers or metal–organic frameworks (MOFs) has attracted considerable interest owing to the interesting structures and potential applications of these compounds. It is still a challenge to predict the exact structures and compositions of the final products. A new one-dimensional coordination polymer,catena-poly[[[bis{1-[(1H-benzimidazol-2-yl)methyl]-1H-tetrazole-κN3}zinc(II)]-μ-hexane-1,6-dicarboxylato-κ4O1,O1′:O6,O6′] monohydrate], {[Zn(C6H8O4)(C9H8N6)2]·H2O}n, has been synthesized by the reaction of Zn(Ac)2(Ac is acetate) with 1-[(1H-benzimidazol-2-yl)methyl]-1

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37

Dequeant, Michael Q., Guangbin Wang, Guo-Lin Xu, et al. "One-dimensional coordination polymers based on [Ru2(DMBA)4]2+ units." Inorganica Chimica Acta 468 (November 2017): 105–8. http://dx.doi.org/10.1016/j.ica.2017.05.011.

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38

Rood, Jeffrey A., Steven Boyer, and Allen G. Oliver. "One- and two-dimensional CdIIcoordination polymers incorporating organophosphinate ligands." Acta Crystallographica Section C Structural Chemistry 70, no. 11 (2014): 1069–74. http://dx.doi.org/10.1107/s2053229614022256.

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Reaction of cadmium nitrate with diphenylphosphinic acid in dimethylformamide solvent yielded the one-dimensional coordination polymercatena-poly[[bis(dimethylformamide-κO)cadmium(II)]-bis(μ-diphenylphosphinato-κ2O:O′)], [Cd(C12H10O2P)2(C3H7NO)2]n, (I). Addition of 4,4′-bipyridine to the synthesis afforded a two-dimensional extended structure, poly[[(μ-4,4′-bipyridine-κ2N:N′)bis(μ-diphenylphosphinato-κ2O:O′)cadmium(II)] dimethylformamide monosolvate], {[Cd(C12H10O2P)2(C10H8N2)]·C3H7NO}n, (II). In (II), the 4,4′-bipyridine molecules link the CdIIcenters in the crystallographicadirection, while

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39

Fleischmann, Martin, Stefan Welsch, Laurence J. Gregoriades, Christian Gröger, and Manfred Scheer. "Supramolecular Assemblies of Polyphosphorus Ligands Based on Weak Tl–P and In–P Interactions." Zeitschrift für Naturforschung B 69, no. 11-12 (2014): 1348–56. http://dx.doi.org/10.5560/znb.2014-4177.

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Abstract A systematic investigation of the coordination behavior of Pn complexes towards the main group Lewis acids Tl+ and In+ is presented. While the reaction of the tetrahedral P2 complex [{CpMo(CO)2}2(μ,η2:η2-P2)] (A1) with Tl[TEF] ([TEF] = [Al{OC(CF3)3}4]-) leads to the formation of the dicationic complex [Tl2(A1)6]2+ (1) with a central six-membered Tl2P4 ring, the analogous reaction with In[TEF] leads instead to a tetranuclear [In4(A1)8]4+ complex (3) exhibiting a weak InI-InI interaction in the solid state. When the Cp*-analogous P2 complex [{Cp*Mo(CO)2}2(μ,η2:η2-P2)] (A2) is reacted wi

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40

Gu, Wenjun, Jinzhong Gu, and Alexander M. Kirillov. "A Flexible Aromatic Tetracarboxylate as a New Linker for Coordination Polymers." Crystals 10, no. 2 (2020): 84. http://dx.doi.org/10.3390/cryst10020084.

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Two new cadmium(II)-based materials, featuring two-dimensional (2D) [Cd2(μ6-deta)(bpy)(H2O)]n (1) and three-dimensional (3D) [Cd2(μ5-deta)(bpy)2(H2O)]n (2) structures, were constructed by the hydrothermal method from 2,3′,4′,5-diphenyl ether tetracarboxylic acid (H4deta) as an unexplored linker in research on coordination polymers (CPs) and 2,2′-bipyridine (bpy) as a mediator of crystallization. Microcrystalline samples of 1 and 2 were analyzed by IR/PXRD/EA/TGA and X-ray diffraction using single crystals. Structures and topologies of CPs 1 and 2 were established, revealing a 4,6L45 topologica

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41

Liu, Yan-Ju, Di Cheng, Ya-Xue Li, Xiang-Ru Meng, and Huai-Xia Yang. "A new two-dimensional managnese(II) coordination polymer constructed by 2,2′-(1,2-phenylene)bis(1H-imidazole-4,5-dicarboxylate)." Acta Crystallographica Section C Structural Chemistry 74, no. 5 (2018): 599–603. http://dx.doi.org/10.1107/s2053229618005508.

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In recent years, N-heterocyclic carboxylate ligands have attracted much interest in the preparation of new coordination polymers since they contain N-atom donors, as well as O-atom donors, and have a rich variety of coordination modes which can lead to polymers with intriguing structures and interesting properties. A new two-dimensional coordination polymer, namely poly[[μ3-2,2′-(1,2-phenylene)bis(4-carboxy-1H-imidazole-5-carboxylato)-κ6 O 4,N 3,N 3′,O 4′:O 5:O 5′]manganese(II)], [Mn(C16H8N4O8)] n or [Mn(H4Phbidc)] n , has been synthesized by the reaction of Mn(OAc)2·4H2O (OAc is acetate) with

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42

Wei, Yan, Lei Zhang, Meng-Jie Wang, Si-Chun Chen, Zi-Hao Wang, and Kou-Lin Zhang. "Synthesis, structure and characterization of two copper(II) supramolecular coordination polymers based on a multifunctional ligand 2-amino-4-sulfobenzoic acid." Acta Crystallographica Section C Structural Chemistry 71, no. 7 (2015): 570–77. http://dx.doi.org/10.1107/s2053229615011432.

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Copper(II) coordination polymers have attracted considerable interest due to their catalytic, adsorption, luminescence and magnetic properties. The reactions of copper(II) with 2-amino-4-sulfobenzoic acid (H2asba) in the presence/absence of the auxiliary chelating ligand 1,10-phenanthroline (phen) under ambient conditions yielded two supramolecular coordination polymers, namely (3-amino-4-carboxybenzene-1-sulfonato-κO1)bis(1,10-phenanthroline-κ2N,N′)copper(II) 3-amino-4-carboxybenzene-1-sulfonate monohydrate, [Cu(C7H6N2O5S)(C12H8N2)2](C7H6N2O5S)·H2O, (1), andcatena-poly[[diaquacopper(II)]-μ-3-

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43

Miao, Li, Xu, Deng, and Ji. "A Three-Dimensional Cadmium(II) Coordination Network Based on 1,3-Di-(1,2,4-triazole-4-yl)benzene: Synthesis, Structure, and Luminescence Properties." Crystals 9, no. 11 (2019): 592. http://dx.doi.org/10.3390/cryst9110592.

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1,2,4-Triazole and its derivatives have been investigated extensively in the construction of coordination polymers. Using a 1,2,4-triazole ligand 1,3-di-(1,2,4-triazole-4-yl)benzene (dtb), a new three-dimensional coordination polymer, {[Cd2(dtb)2(SO4)(H2O)]·(1,2-H2bdc)·SO4}n (1) (1,2-H2bdc = 1,2-benzenedicarboxylic acid), was synthesized under solvothermal conditions. Single-crystal X-ray diffraction analysis revealed that there are two crystallographically different Cd(II) ions in 1 with distorted pentagonal bipyramidal [CdN4O3] geometry and distorted octahedral [CdN4O2] geometry, respectivel

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44

Wang, Xia, Ning Ling, Hanbing Li, Xiaohe Xiao, and Yawen Zhang. "Synthesis, crystal structure and biological properties of Cd and Zn coordination polymers based on a flexible tripodal ligand." Acta Crystallographica Section C Structural Chemistry 75, no. 7 (2019): 1002–10. http://dx.doi.org/10.1107/s2053229619008714.

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Two new coordination polymers, namely poly[[hexathiocyanatotetrakis{μ3-2,4,6-trimethyl-1,3,5-tris[(triazol-1-yl)methyl]benzene}tricadmium(II)] 3.5-hydrate], {[Cd3(SCN)6(C18H21N9)4]·3.5H2O} n (1), and poly[[hexathiocyanatotetrakis{μ3-2,4,6-trimethyl-1,3,5-tris[(triazol-1-yl)methyl]benzene}trizinc(II)] 3.5-hydrate], {[Zn3(SCN)6(C18H21N9)4]·3.5H2O} n (2), have been synthesized under hydrothermal conditions and characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction analysis. From the X-ray analysis, it is noteworthy that polymers 1 and 2 are isostructural, with t

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45

Škugor Rončević, Ivana, Nives Vladislavić, Nabanita Chatterjee, Vesna Sokol, Clive L. Oliver, and Boris-Marko Kukovec. "Structural and Electrochemical Studies of Cobalt(II) and Nickel(II) Coordination Polymers with 6-Oxonicotinate and 4,4′-Bipyridine." Chemosensors 9, no. 12 (2021): 352. http://dx.doi.org/10.3390/chemosensors9120352.

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The 6-oxonicotinate (6-Onic) salts of a one-dimensional cationic cobalt(II) or nickel(II) coordination polymers with 4,4′-bipyridine (4,4′-bpy), namely {[Co(4,4′-bpy)(H2O)4](6-Onic)2·2H2O}n (1) and {[Ni(4,4′-bpy)(H2O)4](6-Onic)2·2H2O}n (2), were prepared hydrothermally by reactions of cobalt(II) nitrate hexahydrate or nickel(II) nitrate hexahydrate, respectively, 6-hydroxynicotinic acid and 4,4′-bipyridine in a mixture of ethanol and water. In the hydrogen-bonded frameworks of 1 and 2, the one-dimensional polymeric chains of {[M(4,4′-bpy)(H2O)4]2+}n (M = Co, Ni), the 6-oxonicotinate anions and

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46

Bulicanu, Vladimir, Kasper S. Pedersen, Mathieu Rouzières, et al. "One-dimensional coordination polymers of [Co3(dpa)4]2+ and [MF6]2− (M = ReIV, ZrIV and SnIV)." Chemical Communications 51, no. 100 (2015): 17748–51. http://dx.doi.org/10.1039/c5cc06704a.

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1-D coordination polymers of alternating metal–metal bonded trinuclear [Co<sub>3</sub>(dpa)<sub>4</sub>]<sup>2+</sup> building blocks and [MF<sub>6</sub>]<sup>2−</sup> (M = Re, Zr, Sn) linkers have been structurally and magnetically characterized.

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47

Huang, Qiu-Ying, Yang Zhao, and Xiang-Ru Meng. "Syntheses, structures and characterization of isomorphous CoII and NiII coordination polymers based on 2-[(1H-imidazol-1-yl)methyl]-6-methyl-1H-benzimidazole and benzene-1,4-dicarboxylate." Acta Crystallographica Section C Structural Chemistry 73, no. 8 (2017): 645–51. http://dx.doi.org/10.1107/s2053229617010877.

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Careful choice of the organic ligands is one of the most important parameters in the rational design and synthesis of coordination polymers. Aromatic polycarboxylates have been widely used in the preparation of metal–organic polymers since they can utilize various coordination modes to form diverse structures and can act as hydrogen-bond acceptors and donors in the assembly of supramolecular structures. Nitrogen-heterocyclic organic compounds have also been used extensively as ligands for the construction of polymers with interesting structures. In the polymers catena-poly[[[diaquabis{2-[(1H-i

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Arlin, Jean-Baptiste, and Alan R. Kennedy. "Alkaline earth metal salts of 1-naphthoic acid." Acta Crystallographica Section C Crystal Structure Communications 68, no. 8 (2012): m213—m218. http://dx.doi.org/10.1107/s0108270112030399.

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The structures of the Mg, Ca, Sr and Ba salts of 1-naphthoic acid are examined and compared with analogous structures of salts of benzoate derivatives. It is shown thatcatena-poly[[[diaquabis(1-naphthoato-κO)magnesium(II)]-μ-aqua] dihydrate], {[Mg(C11H7O2)2(H2O)3]·2H2O}n, exists as a one-dimensional coordination polymer that propagates only through Mg—OH2—Mg interactions along the crystallographicbdirection. In contrast with related benzoate salts, the naphthalene systems are large enough to prevent inorganic chain-to-chain interactions, and thus species with inorganic channels rather than lay

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49

Hoshino, Norihisa, Sena Fujita, and Tomoyuki Akutagawa. "The trinuclear platinum(ii) complex in Vèzes’ red salt as a building block of coordination polymers." Dalton Transactions 48, no. 1 (2019): 176–81. http://dx.doi.org/10.1039/c8dt04121k.

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One-dimensional (1D) and three-dimensional (3D) coordination polymers comprising triangular [Pt<sub>3</sub>(NO<sub>2</sub>)<sub>6</sub>(μ<sub>3</sub>-O)]<sup>2−</sup> ([Pt3]<sup>2−</sup>) units were prepared from K<sub>2</sub>[Pt3]·3H<sub>2</sub>O (1), also known as Vèzes’ red salt.

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Wang, Hui-Ting. "Two different anionic manganese(II) coordination polymers constructed through dicyanamide coordination bridges." Acta Crystallographica Section C Structural Chemistry 71, no. 10 (2015): 850–55. http://dx.doi.org/10.1107/s2053229615015818.

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In order to explore new metal coordination polymers and to search for new types of ferroelectrics among hybrid coordination polymers, two manganese dicyanamide complexes, poly[tetramethylammonium [di-μ3-dicyanamido-κ6N1:N3:N5-tri-μ2-dicyanamido-κ6N1:N5-dimanganese(II)]], {[(CH3)4N][Mn2(NCNCN)5]}n, (I), andcatena-poly[bis(butyltriphenylphosphonium) [[(dicyanamido-κN1)manganese(II)]-di-μ2-dicyanamido-κ4N1:N5]], {[(C4H9)(C6H5)3P]2[Mn(NCNCN)4]}n, (II), were synthesized in aqueous solution. In (I), one MnIIcation is octahedrally coordinated by six nitrile N atoms from six anionic dicyanamide (dca)

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