Tesi sul tema "Soils South Australia Phosphorus content"

[Truncated abstract] Eleven sites, each with the trio of land uses: Eucalyptus globulus plantation, pasture and natural vegetation, representing from the Mediterranean climate, high rainfall region (<550 mm annually) of south-western Australia were investigated to assess medium-term changes in the P-supplying capacity of soils in eucalypt plantations growing on agricultural land. The natural vegetation soils were a benchmark for comparing soil P change since land clearing and development for agriculture. The experimental framework provided an ideal basis for studying changes in P forms since land clearing and fertilization for agriculture and the ensuing conversion to plantations (on an average 9 years ago). Conventional soil P indices measure plant available P that is more relevant to short duration annual crops and pastures. To predict medium-term P availability, P forms were determined using Hedley et al.’s (1982) fractionation scheme and fractions were grouped using the Guo and Youst (1998) criteria into readily, moderately and sparingly available P. The P species were also determined by 31P NMR spectroscopy of 0.5M NaOH-0.1M EDTA extracts. Hedley et al.’s (1982) inorganic P extracted by anion exchange resin and by NaHCO3 are widely considered to be approximations to the actual plant available P. The availability to plants of other P fractions is less certain and this is examined in an experiment to compare the plant availability of various P fractions in soils from fertilized and unfertilized land uses following exhaustive cropping in the glasshouse. The soil texture for the sites studied included coarse sand, loamy sand, clayey sand, and sandy loam. Surface soils (0-10 cm) have pH(CaCl2) in the acidic range (mean 4.4) and there is no significant difference due to differences in land use (P<0.05). The soils are of low EC (1:5 H2O) - 6 mS m-1. There is an almost 5-fold variation in organic C among sites (from 1.4% to 8%) but organic C values did not show any significant effect (P<0.05) of changes in land use. To evaluate the degree of similarity of soils within each triplet set at a site principal component analysis was carried out on those soil chemical⁄mineralogical characteristics that were least likely to be affected by changes in land use practices. This analysis showed good matching of the triplet of sub-sites on the whole, especially for the duo of pasture and plantation land uses. This degree of matching of the trio of land uses was considered while interpreting the effects of land use on the forms and behaviour of soil P, and variations due to various extents of mismatch were mostly addressed using statistical techniques including regression analysis to interpret sub-site difference

Low availability of soil phosphorus (P) caused by strong sorption of P is a major constraint to agricultural production in most South African soils, particularly those from the high rainfall areas. The aim of this study was therefore to investigate whether combined addition of goat manure with inorganic P fertilizers could enhance P availability in some P fixing soils of the Transkei region, South Africa. The study addressed the following specific objectives (i) to assess P sorption capacities and requirements of selected soils and their relationship with selected soil properties and single point sorption test, (ii) to assess the effects of goat manure and lime addition on P sorption properties of selected P fixing soils (iii) to assess the temporal changes in concentration of inorganic and microbial biomass P fractions following application of inorganic fertilizer P with goat manure in a laboratory incubation experiment, and, (iv) to assess the effects of goat manure application with inorganic phosphate on inorganic and microbial biomass P fractions, P uptake and dry matter yield of maize. Sorption maxima (Smax) of seven soils examined ranged from 192.3 to 909.1 (mg P kg-1) and were highly and positively correlated with sorption affinity constant (r = 0.93, p = 0.01) and organic C (r = 0.71, p = 0.01). The amount of P required for maintaining a soil solution concentration of 0.2 mg P l-1 ranged from 2.1 to 123.5 mg P kg-1 soil. Soils collected from Qweqwe (a Cambisol), Qunu (an Acrisol), Ncihane (a Luvisol) and Bethania (a Ferralsol) had lower external P requirement values and were classified as lower sorbers, whereas soils from Ntlonyana (a Planosol), Chevy Chase (a Ferralsol) and Flagstaff (a Ferralsol) were classified as moderate sorbers. The results suggested that P availability could be compromised in 43 percent iii of the soils studied and that measures to mitigate the adverse effects of P sorption were needed to ensure that P is not a limiting factor to crop production, where such soils are found. Goat manure addition at varying rates (5, 10 and 20 tha-1 dry weight basis) to two of the moderately P fixing soils from Chevy Chase and Flagstaff, reduced P sorption maxima (Smax) compared to the control treatment. Phosphate sorption decreased with increasing amounts of goat manure in both soils but the extent of reduction was greater on Chevy Chase soil than on Flagstaff soil. The relative liming effects of the different rates of goat manure followed the order 20 t GM ha-1 > 10 t GM ha-1 > 5 t GM ha-1. In a separate experiment, addition of inorganic P at varying rates (0, 90, 180, and 360 kg P ha-1) to Flagstaff soil increased labile P fractions (resin P, biomass P and NaHCO3-Pi) and the increases were greater when goat manure was co-applied. The control treatments contained only 17.2 and 27.5 mg P kg-1 of resin extractable P in the un-amended and manure amended treatments, respectively which increased to 118.2 and 122.7 mg P kg-1 on day 28 of incubation. Biomass P concentration was increased from 16.8 to 43.9 mg P kg-1 in P alone treatments but the fraction was greatly enhanced with manure addition, increasing it from 32.6 to 97.7 mg P kg-1. NaOH-Pi was the largest extractable Pi fraction and ranged from 144.3 to 250.6 mg P kg-1 and 107.5 to 213.2 mg P kg-1 in the unamended and manure amended treatments, respectively. Dry matter yield and P uptake by maize grown in the glasshouse were highly and significantly (p = 0.05) correlated with the different P fractions in the soil. The correlations followed the order resin P (r = 0.85) > NaOH-Pi (r = 0.85) > NaHCO3-Pi (r = 0.84) >> biomass P (r = 0.56) for dry matter yield at 6 weeks after planting. At 12 weeks after planting, goat manure had iv highly significant effects on resin P and biomass P but had no effect on NaHCO3-Pi and NaOH–Pi. The combination of biomass P, resin P and NaHCO3-Pi explained 75.8 percent of the variation in dry matter yield of which 63.0 percent of the variation was explained by biomass P alone. The greatest increase in biomass P occurred when added P was co-applied with 5 or 10 tha-1 goat manure. The predictive equation for maize dry matter yield (DM) was: DM (g) = 1.897 biomass P + 0.645 resin P (r = 0.73). Resin P was the fraction that was most depleted due to plant uptake and decreased by 56 to 68 percent between the 6th week and the 12th week of sampling indicating that it played a greater role in supplying plant available P. The results therefore suggested that the use of goat manure may allow resource poor farmers to use lower levels of commercial phosphate fertilizers because of its effect to reduce soil P sorption. In addition, higher increases in biomass P due to manure addition observed at lower rates of added P indicated that goat manure has potential for enhancing bioavailability and fertilizer use efficiency of small inorganic P applications.

[Truncated abstract] Soils of Western Australian cropping regions are very low in phosphorous. White lupin, chickpea, and faba bean are being increasingly used in rotations with wheat on these soils. Yield of wheat after a legume crop is frequently higher than its yield after wheat. It has been reported that in addition to nitrogen, legumes can also contribute to improve the availability of phosphorous for the subsequent crops. This PhD research project aimed at optimising the economic returns of wheat-legume rotations through more efficient use of P fertiliser in the legume phase as well as enhanced availability of soil P in the subsequent wheat phase

[Truncated abstract] Relationships between the persistence of organic matter added to soil, the dynamics of soil organic carbon (C) and phosphorus (P) were examined in four experiments on lateritic soils of Western Australia. The main objective was to quantify the release of P following organic matter application in soils which have high P adsorbing capacity. Another objective was to confirm that due to its recalcitrant materials, the effect of peat lasted longer in soil than other sources of organic matter in terms of increasing plant-available P fractions. Three experiments were conducted under glasshouse conditions for various lengths of time, with nine- to twelve-month incubations to investigate these hypotheses. As expected, organic matter with lower C:N ratios than peat (lucerne hay) decomposed more rapidly compared with peat, and the most active mineralisation took place within the first three months of incubation. Soil organic-C (extracted by 0.5 M K2SO4) had a significant positive correlation with P extracted with 0.5 M NaHCO pH 8.53. For a higher application rate (120 ton ha-1), peat was better than wheat straw and lucerne hay in increasing extractable bicarbonate-P concentrations in soil, especially at incubation times up to 12 months. Throughout the experiment, peat was associated with a steady increase in all parameters measured. In contrast to peat, nutrient release from lucerne hay and wheat straw was rapid and diminished over time. There was a tendency for organic-C (either in the form of total extractable organic-C or microbial biomass-C) to steadily increase in soil with added peat throughout the experiment. Unlike wheat straw and lucerne hay, extractable organic-C from peat remained in soil and there was less C loss in the form of respiration. Therefore, peat persisted and sequestered C to the soil system for a longer time than the other source of organic matter. Freshly added organic matter was expected to have a greater influence on P transformation from adsorbed forms in lateritic soils than existing soil organic matter. By removing the existing soil organic matter, the effect of freshly applied organic matter can be determine separately from that of the existing soil organic matter for a similar organic-C content. In order to do this, some soil samples were combusted up to 450° C to eliminate inherent soil organic matter. The release of P was greater when organic-C from fresh organic matter was applied to combusted soils than in uncombusted soils that contained the existing soil organic matter. The exception only applied for parameters related to soil micro-organisms such as biomass-C and phosphatase. For such parameters, new soil organic matter did not create conditions favourable for organisms to increase in activity despite the abundance of organic matter available. More non-extractable-P was formed in combusted soils compared to bicarbonate-P and it contributed to more than 50% of total-P. As for the first experiment, peat also showed a constant effect in increasing bicarbonate extractable-P in the soil

Copy of author's previously published work inserted. Bibliography: leaves 147-189. This project examines the uptake of mineral N from the subsoil after anthesis and its effect on grain protein concentration (GPC) of wheat. The overall objective is to examine the importance of subsoil mineral N and to investigate the ability of wheat to take up N from the subsoil late in the season under different conditions of N supply and soil water availability. Greenhouse experiments investigate the importance of subsoil mineral N availability on GPC of wheat and the factors that contribute to the effective utilisation of N. The recovery of N from subsoil, the effect of split N application on GPC and short term N uptake by the wheat at different rooting densities are also studied.

The effects of 40 years of integrated field management on soil organic phosphorus and its forms was evaluated on a highly organic B.C. soil supporting high value vegetable crops. This project was undertaken to study the effects of cultivation on the soil content of organic phosphorus, as a predictor of overall degradation effects of the soil organic matter. Organic carbon, total nitrogen, soil pH and total and inorganic phosphorus were also evaluated, due to the strong relationship of organic P and these other soil chemical properties. The forms of organic P that were evaluated were the phytic acid, inositol polyphosphates and the soil biomass phosphorus. The biomass P was used as a predictor of the effects of cultivation on nucleic acids since the soil methods for nucleic acid determination were very complicated and time consuming. In this study, attempts were made to find a shorter soil analytical method for phytic acid, the largest pool of soil organic phosphorus. Due to chemical structure of phytic acid and its higher negative charge, it was believed that this molecule is highly stable in the soil environment due to its adsorption and/or precipitation on mineral surfaces through cation bridging at low soil pH particularly by Iron and Aluminium salts and hydrous oxides which bear pH-dependent positive charge or through P chermsorption, and hence its turnover rate due to cultivation could be used to predict the behaviour of the rest of soil organic P and hence the organic matter in the same soil environment. It was however realized that P analysis in soils was very cumbersome and there was a need for a shorter and precise quantitative analytical technique for this element in the soil. ³¹P NMR spectroscopy was thought to be the solution and its possibilities were evaluated in this project. Therefore the objectives of the study were; a) To determine the effects of 40 yrs of integrated field managements on organic P and its forms. b) To develop a shorter method for soil phytic acid analysis. c) To attempt the use of ³¹P NMR for qualitative and quantitative determinations of soil phytic acid. It was found that soil pH was significantly increased from pH 4.46 to 5.28 due to liming and the increased degree of organic matter decomposition. Total nitrogen was significantly decreased by 24% with larger significant decrease of 42% in the shallow organic cultivated soil site, and only 8% significant decrease in the highly organic, deeper cultivated soil site. The decline in soil nitrogen was attributed to mineralization of organic nitrogen followed by crop uptake and leaching losses. Organic carbon was significantly decreased by 22%. There was a 40% decrease in this organic carbon in the cultivated shallow organic cultivated soil site, but there was no significant effect of cultivation on organic carbon (hence the organic matter) in the highly organic deeper cultivated soil site. There was no significant effect of cultivation on the C/N ratio. However, the highly organic deeper soil site had significantly wider C/N ratio than the shallow organic cultivated soil site. This observation was attributed to the degree of decomposition of soil organic matter in the two sites. There was a significant 20% decrease in P total in the highly organic deeper cultivated soil site. There was no significant effect of cultivation on P total in the shallow organic cultivated soil site, however there were indications of 33% accumulation in total P in this soil site as determined by ignition method. There was 179% accumulation of inorganic P in the shallow organic cultivated soil site, but there was no significant effect of cultivation on inorganic P in the deeper highly organic soil cultivated site. Organic phosphorus was significantly decreased by 4 0 yrs of integrated field management by 31% on a soil basis and 25% on an ash free basis. The percentage of organic P in total soil P was significantly decreased from 66% to 45%. The C/orgnic P was increased significantly from 394 to 439. This reflected greater effects of cultivation on turnover of organic P than organic carbon in the organic matter and that P has a geological cycle which organic carbon does not have. The results further showed that before the field was placed under cultivation, the shallow organic soil site had a significantly larger amount (73%) of organic P in the soil total P. However cultivation had a significant decrease in organic P by 23% in the deeper highly organic soil cultivated site and 40% in the shallow organic cultivated soil site. The study soil sites started with same the amounts of biomass P (the most labile form of organic P) , however it was found that 40 years of cultivation had no significant effects on this biomass in the highly organic soil site, but there was a significant decrease in biomass P by 86% in the shallow organic cultivated soil site. Soil phytic acid, the largest pool of organic P was significantly decreased by 28% due to 40 yrs of integrated field management. Its turnover rate was found to be equal to the turnover rate of the other forms of organic P. It was however noted that the study soil sites started with same amount of phytic acid before the field was placed under cultivation. Phytic acid was significantly decreased due to cultivation in the shallow organic cultivated soil site by 35%, but there was no significant effect of cultivation on phytic acid in the highly organic cultivated soil site. Inositol polyphosphates were not significantly affected by 40 years of integrated management. This form of organic P was found to have the same turnover rate as the rest of soil organic P. The slower turnover rate of inositol polyphosphates assayed by the barium acetate precipitation method of McKercher and Anderson was attributed to methodology. In the present study, there were no significant differences in results obtained by various methods for total P determination except in a few cases where the ignition method was thought to have over-estimated total P. A tentative new method for phytic acid analysis was developed in the on-going research. This method was proposed to be applicable in all soils. However, further research is required to confirm the purity of the phytic acid determined by this method. ³¹P NMR spectroscopy showed potential possibility for qualitative and quantitative analysis of soil phytic acid. However, it was emphasized that care should be exercised particularly during sample concentration step. It was concluded that organic P and its forms, organic carbon, total nitrogen, soil pH and phytic acid were significantly decreased by 40 years of integrated field management more in the shallow organic cultivated soil sites than in the deeper highly organic soil sites. This observation was found very interesting and was in contrast to existing soil literature and further research was proposed in this direction to investigate this phenomenon.
Land and Food Systems, Faculty of
Graduate

Bibliography: leaves 164-193. This study aims to quantify the belowground input of organic carbon by barrel medic using techniques that account for root death and decomposition as well as root secretion and exudation. It also investigates the effect of defoliation on carbon allocation within the plant so as to determine the potential for optimising carbon input to the soil through grazing management.

Bibliography: leaves 131-153. This thesis investigates the mechanisms of manganese (Mn) efficiency (genetic tolerance to Mn-deficient soils) in barley (Hordeum vulgare L.) at both physiological and molecular levels.

"September 2001"
Bibliography: leaves 144-159.
xix, 159 leaves : ill. ; 30 cm.
Title page, contents and abstract only. The complete thesis in print form is available from the University Library.
The two main aims of this study were: 1) to determine if the presence of Calcium carbonate in soil was the reason behind soils from Yorke Peninsula having relatively high OC (organic carbon) contents, given local farming practices, and 2) to determine the effect that the composition of the soils' OC has on the mineralisation rates.
Thesis (Ph.D.)--University of Adelaide, Dept. of Agronomy and Farming Systems, 2002

Copy of author's previously published work inserted.
Bibliography: leaves 147-189.
xxi, 189 leaves : ill. (some col.) ; 30 cm.
Title page, contents and abstract only. The complete thesis in print form is available from the University Library.
This project examines the uptake of mineral N from the subsoil after anthesis and its effect on grain protein concentration (GPC) of wheat. The overall objective is to examine the importance of subsoil mineral N and to investigate the ability of wheat to take up N from the subsoil late in the season under different conditions of N supply and soil water availability. Greenhouse experiments investigate the importance of subsoil mineral N availability on GPC of wheat and the factors that contribute to the effective utilisation of N. The recovery of N from subsoil, the effect of split N application on GPC and short term N uptake by the wheat at different rooting densities are also studied.
Thesis (Ph.D.)--University of Adelaide, Dept. of Soil Science, 1997

In the semi - arid Mediterranean - type environments of southern Australia, soil and water resources largely determine crop productivity and ultimately the sustainability of farming systems within the region. The development of sustainable farming systems is a constantly evolving process, of which cropping sequences ( rotations ) are an essential component. This thesis focused on two important soil resources, soil water and nitrogen, and studied the effects of different crop sequences on the dynamic of these resources within current farming systems practiced on the upper Eyre Peninsula of South Australia. The hypothesis tested was that : continuous cropping may alter N dynamics but will not necessarily alter water use efficiency in semi - arid Mediterranean - type environments. Continuous cropping altered N - dynamics ; increases in inorganic N were dependent on the inclusion of a legume in the cropping sequence. Associated with the increase in inorganic N supply was a decrease in WUE by the subsequent wheat crop. Overall, estimates of water use efficiency, a common index of the sustainability of farming systems, in this study concur with reported values for the semi - arid Murray - Mallee region of southern Australia and other semi - arid environments worldwide. Soil water balance and determination of WUE for a series of crop sequences in this thesis suggests that the adoption of continuous cropping may increase WUE and confer a yield benefit compared to crop sequences including a legume component in this environment. No differences in total water use ( ET ) at anthesis or maturity were measured for wheat regardless of the previous crop. Soil evaporation ( E [subscript s] ) was significantly affected by crop canopy development, measured as LAI from tillering until anthesis in 2002, however total seasonal E [subscript s] did not differ between crop sequences. Indeed in environments with infrequent rainfall, such as the upper Eyre Peninsula, soil evaporation may be water - limited rather than energy limited and the potential benefits from greater LAI and reduced E [subscript s] are less. Greater shoot dry matter production and LAI due to an enhanced inorganic N supply for wheat after legumes, and to a lesser degree wheat after canola, relative to continuous cereal crop sequences resulted in increases in WUE calculated at anthesis, as reported by others. Nonetheless the increase in WUE was not sustained due to limitations on available soil water capacity caused by soil physical and chemical constraints. Access to more soil water at depth ( > 0.8m ) through additional root growth was unavailable due to soil chemical limitations. More importantly, the amount of plant available water within the ' effective rooting depth ' ( 0 - 0.8m ) was significantly reduced when soil physical factors were accounted for using the integral water capacity ( IWC ) concept. The difference between the magnitude of the plant available water capacity and the integral water capacity was approximately 90mm within the ' effective rooting depth ' when measured at field capacity, suggesting that the ability of the soil to store water and buffer against periodic water deficit was severely limited. The IWC concept offers a method of evaluating the physical quality of soils and the limitations that these physical properties, viz. aeration, soil strength and hydraulic conductivity, impose on the water supply capacity of the soil. The inability of the soil to maintain a constant supply of water to satisfy maximal transpiration efficiency combined with large amounts of N resulted in ' haying off ', and reduced grain yields. A strong negative linear relationship was established between WUE of grain production by wheat and increasing soil NO [subscript 3] - N at sowing in 2000 and 2002, which conflicts with results from experiments in semi - arid Mediterranean climates in other regions of the world where applications of N increased water use efficiency of grain. Estimates of proportional dependence on N [subscript 2] fixation ( % N [subscript dfa] ) for annual medics and vetch from this study ( 43 - 80 % ) are comparable to others for environments in southern Australia ( < 450mm average annual rainfall ). Such estimates of fixation are considered low ( < 65 % ) to adequate ( 65 - 80 % ). Nevertheless, the amount of plant available N present at sowing for subsequent wheat crops, and the occurrence of ' haying off ', suggests that WUE is not N - limited per se, as implied by some reports, but constrained by the capacity of a soil to balance the co - limiting factors of water and nitrogen.
Thesis (Ph.D.)--School of Earth and Environmental Sciences, 2005.

Bibliography: leaves 290-324. This thesis investigates two avenues suggested by Graham and Ascher (1993) for approaching the problems of subsoil infertility, with particular reference to zinc. Field experiments with wheat and barley were established at Minnipa, on Eyre Peninsula in South Australia to investigate the effects of applying nutrients (principally zinc, nitrogen and phosphorus) to the subsoil to a depth of 0.4 m with a modified deep ripper. A deep pot experiment was designed to measure the zinc efficiencies (in terms of dry matter production) of a range of species grown in siliceous sand. The effects of added zinc on root growth were compared. A pot experiment was also designed to measure the effects of zinc placement in the soil on the zinc concentrations and uptake in Excalibur, particularly with respect to concentrations in grain.