Articoli di riviste: "Organoplatinum compounds"

1

Massa, W., G. Baum, B. S. Seo e J. Lorberth. "Organoplatinum compounds". Journal of Organometallic Chemistry 352, n. 3 (settembre 1988): 415–20. http://dx.doi.org/10.1016/0022-328x(88)83130-9.

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Donath, H., E. V. Avtomonov, I. Sarraje, K. H. von Dahlen, M. El-Essawi, J. Lorberth e B. S. Seo. "Organoplatinum compounds VII". Journal of Organometallic Chemistry 559, n. 1-2 (maggio 1998): 191–96. http://dx.doi.org/10.1016/s0022-328x(98)00481-1.

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Benn, Reinhard, Rolf-Dieter Reinhardt e Anna Rufińska. "195Pt NMR of organoplatinum compounds". Journal of Organometallic Chemistry 282, n. 2 (marzo 1985): 291–95. http://dx.doi.org/10.1016/0022-328x(85)87180-1.

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4

Deolka, Shubham, Orestes Rivada-Wheelaghan, Sandra L. Aristizábal, Robert R. Fayzullin, Shrinwantu Pal, Kyoko Nozaki, Eugene Khaskin e Julia R. Khusnutdinova. "Metal–metal cooperative bond activation by heterobimetallic alkyl, aryl, and acetylide PtII/CuI complexes". Chemical Science 11, n. 21 (2020): 5494–502. http://dx.doi.org/10.1039/d0sc00646g.

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The selective formation of heterobimetallic Pt^II/Cu^I complexes demonstrates how facile bond activation processes can be achieved by altering the reactivity of common organoplatinum compounds through their interaction with another metal center.

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Mahato, Dibyendu, Rahla Naghma, Mohammad Jane Alam, Shabbir Ahmad e Bobby Antony. "Electron impact ionisation cross section for organoplatinum compounds". Molecular Physics 114, n. 21 (24 agosto 2016): 3104–11. http://dx.doi.org/10.1080/00268976.2016.1219408.

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Nagashima, Hideo, Yoshiyuki Kato, Hirofumi Yamaguchi, Eiji Kimura, Teruhiko Kawanishi, Masanao Kato, Yahachi Saito, Masaaki Haga e Kenji Itoh. "Synthesis and Reactions of Organoplatinum Compounds of C60, C60Ptn". Chemistry Letters 23, n. 7 (luglio 1994): 1207–10. http://dx.doi.org/10.1246/cl.1994.1207.

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7

Melnik, Milan, Ondrej Sprusansky, Clive Eduard Holloway e Peter Mikus. "Platinum organometallic compounds: classification and analysis of crystallographic and structural data. Monomeric Pt compounds with PtC2AB, PtA2BC and PtABCD compositions". Reviews in Inorganic Chemistry 32, n. 2-4 (1 dicembre 2012): 111–80. http://dx.doi.org/10.1515/revic-2012-0008.

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AbstractThis review covers almost 350 four-coordinated monomeric organoplatinum complexes with PtC2AB, PtA2BC and PtABCD compositions, and there is wide variability of chromophores. The most common ligands in addition to the C donor are PPh3 and chlorine. Platinum(II) is found only in a square-planar environment involving cis- as well as trans-configurations with a different degree of distortion, especially when bi- or terdentate ligands are present. The trans-effect decreases in the order of the atoms in which the effect dominates, H>C>P>Si>S. There are at least two types of isomerism, cis-trans and distortion. The data strongly suggest that distortion isomerism is, for platinum chemistry, more common than cis- and trans-isomerism.

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Melník, Milan, Peter Mikuš e Clive Eduard Holloway. "Platinum organometallic compounds: classification and analysis of crystallographic and structural data of monomeric five and higher coordinated". Reviews in Inorganic Chemistry 33, n. 1 (1 maggio 2013): 13–103. http://dx.doi.org/10.1515/revic-2013-0001.

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AbstractFour hundred and twenty monomeric organoplatinum compounds, in which platinum atoms are five- and higher coordinated, are analyzed. The platinum atoms are found in the oxidation states +2, +3 and +4. The Pt(II) compounds by far prevail. There are wide varieties of the inner coordination spheres about the platinum centers. The Pt(II) compounds are five-coordinated (trigonal bipyramidal and square pyramidal), six-coordinated (different degrees of distortion), seven-coordinated (pentagonal bipyramidal, piano stool) and sandwiched (PtC10). The Pt(III) compound is square-planar. The Pt(IV) compounds are six- and eight-coordinated. There are several relationships between the Pt-L bond distances, covalent radii of the coordinated atom/ligand, and metallocycles, which are discussed. The trans-effect plays an important role in the inner coordination spheres about the Pt centers, especially on the Pt-L bond distances.

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Hubbert, Christoph, Marcus Breunig, Kristen J. Carroll, Frank Rominger e A. Stephen K. Hashmi. "Simple Synthesis of New Mixed Isocyanide-NHC-Platinum(II) Complexes and Their Catalytic Activity". Australian Journal of Chemistry 67, n. 3 (2014): 469. http://dx.doi.org/10.1071/ch13546.

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Using the new modular and convergent approach to isocyanide-N-hetrocyclic carbene-platinum(ii) complexes, eight new compounds have been synthesised. For three of these, detailed structural data could be obtained by X-ray crystal structure analyses. This new family of organoplatinum complexes is catalytically active for hydrosilylation reactions; styrene and phenylacetylene could be used as substrates; triethylsilane and 1,1,1,3,5,5,5-heptamethyltrisiloxane could be used as reagents. With some of the new platinum pre-catalysts, excellent regioselectivities of up to 98 : 2 could be obtained, and turnover numbers up to 840 were achieved.

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Noguchi, Kishie, Takashi Tamura, Hidetaka Yuge e Takeshi Ken Miyamoto. "Linkage isomerism of organoplatinum(II) compounds coordinated by two 1,3-dimethylbarbiturate anions". Acta Crystallographica Section C Crystal Structure Communications 56, n. 2 (15 febbraio 2000): 171–73. http://dx.doi.org/10.1107/s0108270199014109.

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11

Kolonial Prodjosantoso, Anti. "Preparation and Characterization of Chloride-Free Alumina-Supported Platinum Catalysts". Oriental Journal of Chemistry 34, n. 4 (31 luglio 2018): 2068–73. http://dx.doi.org/10.13005/ojc/3404046.

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Supported precious metal catalysts are extensively used as efficient catalysts. This kind of catalysts, particularly chloride-free catalysts, sintesized using organoplatinum compounds as precursors has attracted immense research interest compared to their parent metals due to their unique physico-chemical properties. The main objective of this research is to prepare and characterize the chloride-free alumina-supported platinum catalysts. An organometallic compound of ammonium bisoxalatoplatinate(II) hydrate was used to prepare unsupported and alumina supported platinum catalysts. A series method including IR, XRD, SEM, TEM, EDA, and XPS was used to characterize samples. The research shows that ammonium bisoxalatoplatinate(II) hydrate could be synthesized and used to prepare unsupported and alumina supported platinum free of chloride impurities.

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12

Singh, Khushwant, Ankit Gangrade, Achintya Jana, Biman B. Mandal e Neeladri Das. "Design, Synthesis, Characterization, and Antiproliferative Activity of Organoplatinum Compounds Bearing a 1,2,3-Triazole Ring". ACS Omega 4, n. 1 (10 gennaio 2019): 835–41. http://dx.doi.org/10.1021/acsomega.8b02849.

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13

Klein, Axel, Steffen Hasenzahl e Wolfgang Kaim. "EPR study of electron transfer and group transfer in organoplatinum(II) and (IV) compounds †". Journal of the Chemical Society, Perkin Transactions 2, n. 12 (1997): 2573–78. http://dx.doi.org/10.1039/a702466e.

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14

Sharutin, V. V., e A. V. Rybakova. "Organoplatinum Compounds Containing at Least Two Platinum–Carbon Bonds: Synthesis, Structure, and Practical Applications". Reviews and Advances in Chemistry 13, n. 2 (giugno 2023): 67–110. http://dx.doi.org/10.1134/s2634827623700216.

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15

Moustafa, Mohamed E., Paul D. Boyle e Richard J. Puddephatt. "Photoswitchable organoplatinum complexes containing an azobenzene derivative of 3,6-di(2-pyridyl)pyridazine". Canadian Journal of Chemistry 92, n. 8 (agosto 2014): 706–15. http://dx.doi.org/10.1139/cjc-2013-0588.

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The new, unsymmetrical azobenzene-tagged ligand 4-(4-azobenzene)-3,6-di(2-pyridyl)pyridazine, adpp, forms complexes with platinum(II) and platinum(IV), which exist as a mixture of geometrical isomers. The complexes are characterized primarily by their NMR spectra, while the structures of the ligand and its complexes [PtMe2(adpp)], [PtBrMe2(CH2C6H4-4-t-Bu)(adpp)], and [PtBrMe2(CH2C6H3-3,5-t-Bu2)(adpp)] have been structurally characterized. In solution, the compounds undergo easy photochemical trans−cis switching of the azobenzene group, with subsequent slow thermal isomerization back to the more stable trans-azobenzene isomer.

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16

Moriuchi, Toshiyuki, Yuki Sakamoto, Shunichi Noguchi, Takashi Fujiwara, Shigehisa Akine, Tatsuya Nabeshima e Toshikazu Hirao. "Design and controlled emission properties of bioorganometallic compounds composed of uracils and organoplatinum(ii) moieties". Dalton Transactions 41, n. 28 (2012): 8524. http://dx.doi.org/10.1039/c2dt30533j.

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17

Howell, B. A., E. W. Walles e R. Rashidianfar. "Noncovalent complexes of water-soluble polymers and organoplatinum compounds as potential time-release antitumor agents". Makromolekulare Chemie. Macromolecular Symposia 19, n. 1 (giugno 1988): 329–39. http://dx.doi.org/10.1002/masy.19880190126.

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18

Raven, William, Thomas Joschko, Irmgard Kalf e Ulli Englert. "Hydrogenversusfluorine: effects on molecular structure and intermolecular interactions in a platinum isocyanate complex". Acta Crystallographica Section C Structural Chemistry 72, n. 3 (13 febbraio 2016): 184–88. http://dx.doi.org/10.1107/s2053229616002382.

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At the molecular level, the enantiomerically pure square-planar organoplatinum complex (SP-4-4)-(R)-[2-(1-aminoethyl)-5-fluorophenyl-κ2C1,N][(R)-1-(4-fluorophenyl)ethylamine-κN](isocyanato-κN)platinum(II), [Pt(C8H9FN)(NCO)(C8H10FN)], and its congener without fluorine substituents on the aryl rings adopt the same structure within error. The similarities between the compounds extend to the most relevant intermolecular interactions,i.e.N—H...O and N—H...N hydrogen bonds link neighbouring molecules into chains along the shortest lattice parameter in each structure. Differences between the crystal structures of the fluoro-substituted and parent complex become obvious with respect to secondary interactions perpendicular to the classical hydrogen bonds; the fluorinated compound features short C—H...F contacts with an F...H distance ofca2.6 Å. The fluorine substitution is also reflected in reduced backbonding from the metal cation to the isocyanate ligand.

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19

Anderson, Craig M., Margarita Crespo, Michael C. Jennings, Alan J. Lough, George Ferguson e Richard J. Puddephatt. "Competition between intramolecular oxidative addition and ortho metalation in organoplatinum(II) compounds: activation of aryl-halogen bonds". Organometallics 10, n. 8 (agosto 1991): 2672–79. http://dx.doi.org/10.1021/om00054a031.

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20

Saha, Manik Lal, Xuzhou Yan e Peter J. Stang. "Photophysical Properties of Organoplatinum(II) Compounds and Derived Self-Assembled Metallacycles and Metallacages: Fluorescence and its Applications". Accounts of Chemical Research 49, n. 11 (13 ottobre 2016): 2527–39. http://dx.doi.org/10.1021/acs.accounts.6b00416.

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21

Yamago, Shigeru, Eiichi Kayahara e Takahiro Iwamoto. "Organoplatinum-Mediated Synthesis of Cyclic π-Conjugated Molecules: Towards a New Era of Three-Dimensional Aromatic Compounds". Chemical Record 14, n. 1 (febbraio 2014): 84–100. http://dx.doi.org/10.1002/tcr.201300035.

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22

Yamago, Shigeru, Eiichi Kayahara e Takahiro Iwamoto. "ChemInform Abstract: Organoplatinum-Mediated Synthesis of Cyclic π-Conjugated Molecules: Towards a New Era of Three-Dimensional Aromatic Compounds". ChemInform 45, n. 20 (28 aprile 2014): no. http://dx.doi.org/10.1002/chin.201420267.

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23

Janzen, Michael C., Michael C. Jennings e Richard J. Puddephatt. "Self-assembly using stannylplatinum(IV) halide complexes as ligands for organotin halides". Canadian Journal of Chemistry 80, n. 11 (1 novembre 2002): 1451–57. http://dx.doi.org/10.1139/v02-093.

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The possibility of forming extended structures by self-association using transition metal halides as donors to organotin acceptors has been investigated. The stannylplatinum(IV) complex [PtClMe2(SnMe2Cl)(bu2bpy)] forms a 1:1 adduct [PtClMe2(SnMe2Cl)(bu2bpy)]·Me2SnCl2 with Me2SnCl2 in which the organoplatinum complex acts as a donor to the organotin halide. Similarly, [PtClMe2(SnMeCl2)(bu2bpy)] forms adducts [PtClMe2(SnMeCl2)(bu2bpy)]·MeSnCl3 or [PtClMe2(SnMeCl2)(bu2bpy)]·Me2SnCl2, and [{PtClMe2(bu2bpy)}2(µ-SnCl2)] forms [{PtClMe2(bu2bpy)}2(µ-SnCl2)]·Me2SnCl2. Structure determinations on selected compounds show that the donor is the Pt-Cl group and the acceptor tin centre is 5-coordinate. In the similar bromo complex [PtBrMe2(SnMeBr2)(bu2bpy)]·Me2SnBr2 both the Pt-Br and PtSn-Br groups coordinate to the Me2SnBr2 acceptor with short (3.14 or 3.29 Å) and long (3.99 or 4.05 Å) contacts, respectively, so that the acceptor tin centre adopts distorted octahedral stereochemistry in the solid state and a folded polymeric structure is formed. Reaction of [{PtClMe2(bu2bpy)}2(µ-SnCl2)] with AgO3SCF3 yields the complex [{PtClMe2(bu2bpy)}(µ-SnCl2){PtMe2(bu2bpy)O3SCF3}], which is fluxional in solution.Key words: platinum, tin, self-assembly, coordination chemistry, organometallics.

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24

Ebert, K. H., W. Massa, H. Donath, J. Lorberth, B. S. Seo e E. Herdtweck. "Organoplatinum compounds: VI. Trimethylplatinum thiomethylate and trimethylplatinum iodide. The crystal structures of [(CH3)3PtS(CH3)]4 and [(CH3)3PtI]4·0.5CH3I". Journal of Organometallic Chemistry 559, n. 1-2 (maggio 1998): 203–7. http://dx.doi.org/10.1016/s0022-328x(98)00414-8.

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25

Klein, Axel, Steffen Hasenzahl, Wolfgang Kaim e Jan Fiedler. "On the Question of Mixed-Valent States in Ligand-Bridged Dinuclear Organoplatinum Compounds [RkPt(μ-L)PtRk]n,k= 2 or 4†". Organometallics 17, n. 16 (agosto 1998): 3532–38. http://dx.doi.org/10.1021/om980107j.

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26

Bryndza, Henry E., Peter J. Domaille, Wilson Tam, Lawrence K. Fong, Rocco A. Paciello e John E. Bercaw. "Comparison of metal-hydrogen, -oxygen, -nitrogen and -carbon bond strengths and evaluation of functional group additivity principles for organoruthenium and organoplatinum compounds". Polyhedron 7, n. 16-17 (gennaio 1988): 1441–52. http://dx.doi.org/10.1016/s0277-5387(00)81773-8.

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27

Huang, Mei-Han, Yan-Ming Huang e Sheng-Nan Wu. "The Inhibition by Oxaliplatin, a Platinum-Based Anti-Neoplastic Agent, of the Activity of Intermediate-Conductance Ca2+-Activated K+ Channels in Human Glioma Cells". Cellular Physiology and Biochemistry 37, n. 4 (2015): 1390–406. http://dx.doi.org/10.1159/000430404.

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Oxaliplatin (OXAL) is a third-generation organoplatinum which is effective against advanced cancer cells including glioma cells. How this agent and other related compounds interacts with ion channels in glioma cells is poorly understood. OXAL (100 µM) suppressed the amplitude of whole-cell K+ currents (IK); and, either DCEBIO or ionomycin significantly reversed OXAL-mediated inhibition of IK in human 13-06-MG glioma cells. In OXAL-treated cells, TRAM-34 did not suppress IK amplitude in these cells. The intermediate-conductance Ca2+-activated K+ (IKCa) channels subject to activation by DCEBIO and to inhibition by TRAM-34 or clotrimazole were functionally expressed in these cells. Unlike cisplatin, OXAL decreased the probability of IKCa-channel openings in a concentration-dependent manner with an IC50 value of 67 µM. No significant change in single-channel conductance of IKCa channels in the presence of OXAL was demonstrated. Neither large-conductance Ca2+-activated K+ channels nor inwardly rectifying K+ currents in these cells were affected in the presence of OXAL. OXAL also suppressed the proliferation and migration of 13-06-MG cells in a concentration- and time-dependent manner. OXAL reduced IKCa-channel activity in LoVo colorectal cancer cells. Taken together, the inhibition by OXAL of IKCa channels would conceivably be an important mechanism through which it acts on the functional activities of glioma cells occurring in vivo.

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28

Bryndza, Henry E., Lawrence K. Fong, Rocco A. Paciello, Wilson Tam e John E. Bercaw. "Relative metal-hydrogen, -oxygen, -nitrogen, and -carbon bond strengths for organoruthenium and organoplatinum compounds; equilibrium studies of Cp*(PMe3)2RuX and (DPPE)MePtX systems". Journal of the American Chemical Society 109, n. 5 (marzo 1987): 1444–56. http://dx.doi.org/10.1021/ja00239a026.

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29

Wouters, Jacqueline M. A., Rene A. Klein, Cornelis J. Elsevier, Martin C. Zoutberg e Casper H. Stam. "Insertion of isocyanide into (.sigma.-allenyl)platinum(II) and -palladium(II) compounds. Synthesis and mechanism of formation of new organoplatinum compounds containing a .sigma.-bonded vinylketenimine ligand. X-ray crystal structure of [PtBr{C(CMe2)(CH:C:NBu-tert)}(PPh3)2]". Organometallics 12, n. 10 (ottobre 1993): 3864–72. http://dx.doi.org/10.1021/om00034a019.

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30

Whitesides, George M., Marifaith Hackett, Robert L. Brainard, Jean Paul P. M. Lavalleye, Alan F. Sowinski, Alan N. Izumi, Stephen S. Moore, Duncan W. Brown e Erin M. Staudt. "Suppression of unwanted heterogeneous platinum(0)-catalyzed reactions by poisoning with mercury(0) in systems involving competing homogeneous reactions of soluble organoplatinum compounds: thermal decomposition of bis(triethylphosphine)-3,3,4,4-tetramethylplatinacyclopentane". Organometallics 4, n. 10 (ottobre 1985): 1819–30. http://dx.doi.org/10.1021/om00129a023.

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31

Van Beek, Johannus A. M., Gerard Van Koten, Wilberth J. J. Smeets e Anthony L. Spek. "Model for the initial stage in the oxidative addition of I2 to organoplatinum(II) compounds. X-ray structure of square-pyramidal [PtIII{C6H3(CH2NMe2)2-o,o'}(.eta.1-I2)] containing a linear Pt-I-I arrangement". Journal of the American Chemical Society 108, n. 16 (agosto 1986): 5010–11. http://dx.doi.org/10.1021/ja00276a053.

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32

Chen, Li‐Jun, Xin Wu, Alexander M. Gilchrist e Philip A. Gale. "Organoplatinum Compounds as Anion‐Tuneable Uphill Hydroxide Transporters". Angewandte Chemie, 11 marzo 2022. http://dx.doi.org/10.1002/ange.202116355.

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Chen, Li‐Jun, Xin Wu, Alexander M. Gilchrist e Philip A. Gale. "Organoplatinum Compounds as Anion‐Tuneable Uphill Hydroxide Transporters". Angewandte Chemie International Edition, 11 marzo 2022. http://dx.doi.org/10.1002/anie.202116355.

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34

Bhavsar, Rakesh, Yogesh Thakar, Minaxi Vinodkumar e Chetan Limbachiya. "Electron impact ionisation and other molecular processes for organoplatinum compounds". Molecular Physics, 29 aprile 2022. http://dx.doi.org/10.1080/00268976.2022.2070086.

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35

VAN BEEK, J. A. M., G. VAN KOTEN, W. J. J. SMEETS e A. L. SPEK. "ChemInform Abstract: Model for the Initial Stage in the Oxidative Addition of I2 to Organoplatinum (II) Compounds." Chemischer Informationsdienst 17, n. 50 (16 dicembre 1986). http://dx.doi.org/10.1002/chin.198650305.

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BRYNDZA, H. E., P. J. DOMAILLE, W. TAM, L. K. FONG, R. A. PACIELLO e J. E. BERCAW. "ChemInform Abstract: Comparison of Metal-Hydrogen, -Oxygen, -Nitrogen and -Carbon Bond Strengths and Evaluation of Functional Group Additivity Principles for Organoruthenium and Organoplatinum Compounds." ChemInform 20, n. 4 (24 gennaio 1989). http://dx.doi.org/10.1002/chin.198904098.

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37

BRYNDZA, H. E., L. K. FONG, R. A. PACIELLO, W. TAM e J. E. BERCAW. "ChemInform Abstract: Relative Metal-Hydrogen, -Oxygen, -Nitrogen, and -Carbon Bond Strengths for Organoruthenium and Organoplatinum Compounds; Equilibrium Studies of Cp*(PMe3)2RuX and (DPPE)MePtX Systems". ChemInform 18, n. 28 (14 luglio 1987). http://dx.doi.org/10.1002/chin.198728091.

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Articoli di riviste sul tema "Organoplatinum compounds"

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