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Letteratura scientifica selezionata sul tema "Molybdenum"

Autore: Grafiati

Pubblicato: 4 giugno 2021

Ultima modifica: 29 luglio 2024

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Articoli di riviste sul tema "Molybdenum"

1

Halmi, M. I. E., e Siti Aqlima Ahmad. "Chemistry, biochemistry, toxicity and pollution of molybdenum: A mini review". Journal of Biochemistry, Microbiology and Biotechnology 2, n. 1 (31 luglio 2014): 1–6. http://dx.doi.org/10.54987/jobimb.v2i1.122.

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Molybdenum is used in various industries. Its pollution has been recorded globally and is an emerging pollutant. Molybdenum is poorly represented in the literature as compared to heavy metals such as mercury, chromium, arsenic, lead and cadmium for instance, due to the metalâ€™s low toxicity to humans. It has now been reported that molybdenum is very toxic to embryo and spermatogenesis of fish and mice and this worrying trend would place molybdenum at the forefront of toxicology and bioremediation studies in the future. This mini review attempts to summarize what we know on its chemistry, biochemistry, toxicity and pollution with the hope that this knowledge would be useful for future studies on molybdenumâ€™s removal from the environment.Â

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2

Choi, Byeong-Min, Seok-Hwan Son, Chul-Wee Lee, Sun-Yeong Park e Min-Chul Chung. "Characterization and Synthesis of Molybdenum Metal Precursors for Hydrocracking Reaction of Vacuum Residues". Journal of Nanoscience and Nanotechnology 20, n. 9 (1 settembre 2020): 5787–90. http://dx.doi.org/10.1166/jnn.2020.17650.

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In this study, Molybdenum precursors were synthesized with Triphenylphosphine, 1,2-Bis(diphenylphosphino)ethane, Pyridine, 2,2-Bipyridine as a ligands. The molybdenum precursors was used for Hydrocraking reaction of Vacuum Residue (VR). Hydrocracking reactions were carried out under the 430 °C and H2 pressure of 80 bar in an 100 ml high pressure reactor. New Molybdenum precursors were tested and their activities were compared with Mo-octoate. The Molybdeum-Phosphine precursor showed the best performances, high yield and low coke contents (below 0,5 wt%), in of hydrocracking for VR. To characterize the physicochemical properties of Moprecursor catalyst, various characterization techniques (NMR, XPS) were carried out. We confirmed that cokes in the reactor were contained the P atoms derived from ligand of Mo-precursor after hydrocracking of VR.

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3

Klienkov, Alexey V., e Alexander A. Petukhov. "Obtaining molybdenyl glycolate using ethanol as a salting out solvent". Butlerov Communications 59, n. 9 (30 settembre 2019): 66–70. http://dx.doi.org/10.37952/roi-jbc-01/19-59-9-66.

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The global production of propylene oxide is more than 8 million tons/year and is increasing by more than 5% annually. Almost all domestic propylene oxide (72 thousand tons/year) is produced at PJSC Nizhnekamskneftekhim (Russia) according to one of the variants of the Halcon process – epoxidation of propylene with ethylbenzene hydroperoxide (HPEB) in the presence of a molybdenum catalyst. One of the most important tasks arising in improving the process for the joint production of styrene and propylene oxide at PJSC Nizhnekamskneftekhim (Russia) is the search and development of new catalysts and catalytic systems, one of the stages of this process – the epoxidation of propylene with HPEB. The complex molybdenum catalyst used in the production of propylene oxide, having high activity and selectivity, has several disadvantages, namely: low dissolved molybdenum content, high consumption of ethylbenzene hydroperoxide for its production, and instability during storage. Thus, the problem of obtaining a catalyst with a higher content of dissolved molybdenum and increasing the stability of the catalytic complex, i.e. development of new catalytic systems with the best technological and technical and economic indicators. An analysis of the scientific and technical literature and patent publications showed that in the synthesis of a complex molybdenum catalyst, various molybdenum compounds of both organic and inorganic nature can be used. During the study, molybdenum-containing solutions based on ammonium paramolybdate and monoethylene glycol were tested, distillation distillation products prepared by distilling off excess monoethylene glycol by strengthening under vacuum. Molybdenyl glycolate was isolated by salting out with ethanol from a distillation bottoms product.

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4

Bougié, D., J. Voirin, F. Bureau, J. F. Duhamel, G. Mutter e M. Drosdowsky. "Molybdenum." Acta Paediatrica 78, n. 2 (marzo 1989): 319–20. http://dx.doi.org/10.1111/j.1651-2227.1989.tb11079.x.

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5

MITCHELL, PHILIP C. H. "MOLYBDENUM". Chemical & Engineering News 81, n. 36 (8 settembre 2003): 108. http://dx.doi.org/10.1021/cen-v081n036.p108.

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6

Novotny, Janet A., e Catherine A. Peterson. "Molybdenum". Advances in Nutrition 9, n. 3 (1 maggio 2018): 272–73. http://dx.doi.org/10.1093/advances/nmx001.

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7

Barceloux, Donald G., e Donald Barceloux. "Molybdenum". Journal of Toxicology: Clinical Toxicology 37, n. 2 (gennaio 1999): 231–37. http://dx.doi.org/10.1081/clt-100102422.

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8

Minelli, Martin M. "Molybdenum". Coordination Chemistry Reviews 81 (novembre 1987): 1–49. http://dx.doi.org/10.1016/0010-8545(87)85012-9.

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9

Schwarz, Günter, e Ralf R. Mendel. "MOLYBDENUM COFACTOR BIOSYNTHESIS AND MOLYBDENUM ENZYMES". Annual Review of Plant Biology 57, n. 1 (giugno 2006): 623–47. http://dx.doi.org/10.1146/annurev.arplant.57.032905.105437.

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10

Turnlund, Judith R., e William R. Keyes. "Plasma molybdenum reflects dietary molybdenum intake". Journal of Nutritional Biochemistry 15, n. 2 (febbraio 2004): 90–95. http://dx.doi.org/10.1016/j.jnutbio.2003.10.003.

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Tesi sul tema "Molybdenum"

1

Ellis, S. R. "Characterisation of molybdenum compounds relevant to the molybdenum cofactor of the oxo-molybdenum enzymes". Thesis, University of Manchester, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.376593.

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2

Rickman, Sarah. "Growth and characterization of molybdenum disulfide, molybdenum diselenide, and molybdenum(sulfide, selenide) formed between molybdenum and copper indium(sulfide, selenide) during growth". Access to citation, abstract and download form provided by ProQuest Information and Learning Company; downloadable PDF file 0.94 Mb., 85 p, 2006. http://gateway.proquest.com/openurl?url_ver=Z39.88-2004&res_dat=xri:pqdiss&rft_val_fmt=info:ofi/fmt:kev:mtx:dissertation&rft_dat=xri:pqdiss:1435848.

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3

Womiloju, Olusola Olumuyiwa. "(Pentamethylcyclopentadienyl)molybdenum oxides". Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1999. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape7/PQDD_0017/NQ54601.pdf.

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4

Bancroft, Matthew N. "Molybdenum-sulfur chemistry". Thesis, University of Sheffield, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.301264.

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5

Paudel, Yadab Kumar. "Tribological properties of adaptive [molybdenum nitride/molybdenum sulfide/silver] nanocomposite coatings /". Available to subscribers only, 2008. http://proquest.umi.com/pqdweb?did=1597633321&sid=7&Fmt=2&clientId=1509&RQT=309&VName=PQD.

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6

Murugappan, Karthick. "Molybdenum trioxide and molybdenum carbide as promising hydrodeoxygenation catalysts for biomass conversion". Thesis, Massachusetts Institute of Technology, 2017. http://hdl.handle.net/1721.1/111404.

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Thesis: Ph. D., Massachusetts Institute of Technology, Department of Chemical Engineering, 2017.
Cataloged from PDF version of thesis.
Includes bibliographical references (pages 171-176).
Growing concerns due to rising CO2 emissions have made biomass an indispensable source of renewable fuels and chemicals. However, biomass inherently has high oxygen content, which translates to low energy density, thereby necessitating a deoxygenation step before being utilized as fuels. Recently, MoO3 and Mo2C have emerged as promising earth-abundant cheap catalysts that perform hydrodeoxygenation (HDO) at relatively low temperatures ( 673 K) and ambient H2 pressures wherein oxygen is selectively removed as water. However, there exists a significant knowledge gap in understanding the stability and the active phases responsible for HDO of these catalysts. Furthermore, their applicability for real biomass conversions has not been largely demonstrated. In this thesis, first, HDO of m-cresol, a biomass-derived model compound, is investigated over bulk and supported MoO 3 catalysts. Detailed reactivity and characterization studies reveal that Mo5+ species plays a critical role during HDO. Specifically, TiO2 and ZrO2 are identified as ideal supports as they feature superior HDO reactivity and stability over bulk MoO3 by stabilizing intermediate Mo oxidation states (i.e. Mo5+) while bulk MoO 3 over-reduces to inactive metallic Mo. Translating from model compound studies, supported MoO3 catalysts are demonstrated to be effective in converting biomass (pine) pyrolysis vapors to hydrocarbons (ca. 30 % yield). In comparison with MoO 3, Mo2C is significantly more stable and selective for HDO of 4-methylanisole to toluene under identical reaction conditions. Mo2C predominantly breaks the stronger phenolic C-0 bond while MoO 3 also breaks the weaker aliphatic C-0 bond, likely due to the presence of Bronsted acid sites. To gain insights into the surface active sites, operando near-ambient XPS is employed during HDO and this technique revealed that HDO seems to operate via distinct active sites over both these materials. Finally, Mo2C is shown to be effective in upgrading real lignin streams to a single product propylbenzene, a precursor for renewable polymer. Overall, this thesis demonstrates the applicability of MoO3 and Mo2C in real biomass conversions and provides insights on the working nature of these catalysts, which will enable the design of more effective HDO catalysts.
by Karthick Murugappan.
Ph. D.

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7

Zhang, Liping. "Hydrodenitrogenation of organonitrogen compounds over nickel-molybdenum sulfide and Molybdenum nitride catalysts /". The Ohio State University, 1996. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487942739805674.

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Khanfar, Mohammad F. "Molybdenum-modified platinum electrodes /". Internet access available to MUN users only, 2003. http://collections.mun.ca/u?/theses,160874.

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Campbell, Selina. "New organo-molybdenum complexes". Thesis, University of Cambridge, 1993. https://www.repository.cam.ac.uk/handle/1810/272559.

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TRUJILLO, REBOLLO ANDRES. "SOLVENT EXTRACTION OF MOLYBDENUM". Diss., The University of Arizona, 1987. http://hdl.handle.net/10150/184009.

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The equilibrium and the kinetics of the reaction of Mo (VI) with 8-hydroxyquinoline; 8-hydroxyquinaldine; KELEX 100; LIX63; and LIX65N were studied by solvent extraction. From the equilibrium studies it was concluded that in weakly acidic solution (pH 5 to 6) the overall extraction reaction is (UNFORMATTED TABLE FOLLOWS) MoO₄²⁻ + 2H⁺ + 2HL(o) ↔ (K(ex)) MoO₂L ₂(o) + 2H₂O (TABLE ENDS) where HL is the monoprotic bidentate ligand, "(o)" refers to the organic phase, and K(,ex) is the extraction constant. It was concluded that the complexation reaction requires four protons to convert molybdate into molybdenyl. The extractions constants for LIX63 and 8-hydroxyquinaldine, corrected for the side reaction of the ligand and metal, are 10¹⁶·⁴³ and 10¹⁴·⁴⁰, respectively. In the case of LIX65N, the plot of log(D) vs pH has a maximum at pH 1.0, which was explained qualitatively in terms of protonation of the ligand and molybdic acid at low pH. The extraction constant for the reaction of molybdic acid and the neutral ligand was estimated to be 100,000. The kinetics of extraction Mo (VI) with LIX63, 8-hydroxyquinoline, 8-hydroxyquinaldine, and Kelex 100 were studied in this work. In all cases, except 8-hydroxyquinoline, the rate-determining step of the reaction involves the formation of a 1:1 complex between the neutral ligand and several Mo(VI) species differing in the degree of protonation. The rate-determining step for the reaction of Mo(VI) with 8-hydroxyquinoline involves the formation of a 1:2 complex. The rate constant for the reaction of HMoO₄ with 8-hydroxyquinaldine is four orders of magnitude smaller than the corresponding value reported in the literature for 8-hydroxyquinoline. The slower reaction with 8-hydroxyquinaldine was attributed to the presence of the methyl group next to the nitrogen atom of the ligand which hinders its binding with molybdenum in the rate determining step of the reaction.

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Più fonti

Libri sul tema "Molybdenum"

1

Lepora, Nathan. Molybdenum. New York: Marshall Cavendish Benchmark, 2006.

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2

Jehn, Hermann, Wolfgang Kurtz, Dietrich Schneider, Ursula Trobisch e Joachim Wagner. Mo Molybdenum. A cura di Hartmut Katscher, Wolfgang Kurtz e Friedrich Schröder. Berlin, Heidelberg: Springer Berlin Heidelberg, 1989. http://dx.doi.org/10.1007/978-3-662-06327-9.

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3

Tytko, Karl-Heinz, Wolf-Dietrich Fleischmann, Dieter Gras e Eberhard Warkentin. Mo Molybdenum. A cura di Hartmut Katscher e Friedrich Schröder. Berlin, Heidelberg: Springer Berlin Heidelberg, 1985. http://dx.doi.org/10.1007/978-3-662-07836-5.

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Tytko, Karl-Heinz. Mo Molybdenum. A cura di Hartmut Katscher e Friedrich Schröder. Berlin, Heidelberg: Springer Berlin Heidelberg, 1986. http://dx.doi.org/10.1007/978-3-662-08837-1.

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5

Czack, Gerhard, Wolf-Dietrich Fleischmann, Dieter Gras, Vera Haase e Gerhard Kirschstein. Mo Molybdenum. A cura di Gerhard Czack, Vera Haase e Gerhard Kirschstein. Berlin, Heidelberg: Springer Berlin Heidelberg, 1987. http://dx.doi.org/10.1007/978-3-662-09293-4.

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6

1935-, Spiro Thomas G., a cura di. Molybdenum enzymes. New York: Wiley, 1985.

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7

Stegen, Ralph J., Robert Cal Callaghan, Robert Cal Callaghan e Ralph J. Stegen, a cura di. Porphyry Molybdenum Deposits in Colorado I. Climax Porphyry Molybdenum Deposits II. Henderson Molybdenum Mine. Tulsa, Oklahoma, U.S.A.: SEPM Society for Sedimentary Geology, 2006. http://dx.doi.org/10.5382/gb.38.

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8

C, Gupta Umesh, a cura di. Molybdenum in agriculture. New York: Cambridge University Press, 1997.

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9

Suryanto. Electrodeposited nickel molybdenum. Birmingham: University of Birmingham, 1996.

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10

R, Braithwaite E., e Haber Jerzy, a cura di. Molybdenum: An outline of its chemistry and uses. Amsterdam: Elsevier, 1994.

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Capitoli di libri sul tema "Molybdenum"

1

Parker, Gordon A. "Molybdenum". In Anthropogenic Compounds, 217–40. Berlin, Heidelberg: Springer Berlin Heidelberg, 1986. http://dx.doi.org/10.1007/978-3-540-39468-6_6.

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2

Kurtz, Wolfgang, e Hans Vanecek. "Molybdenum". In W Tungsten, 122–33. Berlin, Heidelberg: Springer Berlin Heidelberg, 1987. http://dx.doi.org/10.1007/978-3-662-08690-2_20.

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3

Chappaz, Anthony, Jennifer B. Glass e Timothy W. Lyons. "Molybdenum". In Encyclopedia of Earth Sciences Series, 1–4. Cham: Springer International Publishing, 2016. http://dx.doi.org/10.1007/978-3-319-39193-9_256-1.

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4

Chappaz, Anthony, Jennifer B. Glass e Timothy W. Lyons. "Molybdenum". In Encyclopedia of Earth Sciences Series, 947–50. Cham: Springer International Publishing, 2018. http://dx.doi.org/10.1007/978-3-319-39312-4_256.

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5

Crowson, Phillip. "Molybdenum". In Minerals Handbook 1992–93, 166–71. London: Palgrave Macmillan UK, 1992. http://dx.doi.org/10.1007/978-1-349-12564-7_26.

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6

Dror, Yosef, e Felicia Stern. "Molybdenum". In Trace Elements and Minerals in Health and Longevity, 179–207. Cham: Springer International Publishing, 2018. http://dx.doi.org/10.1007/978-3-030-03742-0_7.

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7

Jonmaire, Paul. "Molybdenum". In Hamilton & Hardy's Industrial Toxicology, 167–72. Hoboken, New Jersey: John Wiley & Sons, Inc., 2015. http://dx.doi.org/10.1002/9781118834015.ch24.

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8

Crowson, Phillip. "Molybdenum". In Minerals Handbook 1994–95, 176–81. London: Palgrave Macmillan UK, 1994. http://dx.doi.org/10.1007/978-1-349-13431-1_28.

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Crowson, Phillip. "Molybdenum". In Minerals Handbook 1996–97, 246–52. London: Palgrave Macmillan UK, 1996. http://dx.doi.org/10.1007/978-1-349-13793-0_29.

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10

Brookins, Douglas G. "Molybdenum". In Eh-pH Diagrams for Geochemistry, 104–5. Berlin, Heidelberg: Springer Berlin Heidelberg, 1988. http://dx.doi.org/10.1007/978-3-642-73093-1_41.

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Atti di convegni sul tema "Molybdenum"

1

Lavayen, V. "Molybdenum Disulfide — Amine Nanostructures". In MOLECULAR NANOSTRUCTURES: XVII International Winterschool Euroconference on Electronic Properties of Novel Materials. AIP, 2003. http://dx.doi.org/10.1063/1.1628074.

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2

"Influence of molybdenum and tungsten on the enzymatic activity of molybdenum enzymes". In Plant Genetics, Genomics, Bioinformatics, and Biotechnology. Institute of Cytology and Genetics, Siberian Branch of the Russian Academy of Sciences, 2019. http://dx.doi.org/10.18699/plantgen2019-057.

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3

Peterson, Joshua R., Gail Lee Arnold, Benjamin Brunner e Philip C. Goodell. "MOLYBDENUM-SULFUR ISOTOPE RELATIONSHIPS IN A PORPHYRY COPPER MOLYBDENUM DEPOSIT (SIERRITA MINE, AZ)". In GSA Annual Meeting in Seattle, Washington, USA - 2017. Geological Society of America, 2017. http://dx.doi.org/10.1130/abs/2017am-300630.

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Kindvall, Anna, Jason Kephart e Walajabad Sampath. "Molybdenum Oxide and Molybdenum Nitride Back Contacts for Thin-Film CdTe Solar Cells". In 2017 IEEE 44th Photovoltaic Specialists Conference (PVSC). IEEE, 2017. http://dx.doi.org/10.1109/pvsc.2017.8366271.

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5

Li, Y. X., Q. B. Yang, X. F. Yu, A. Trinchi, A. Z. Sadek, W. Wlodarski e K. Kalantar-zadeh. "Nanostructured Molybdenum Oxide Gas Sensors". In 2006 5th IEEE Conference on Sensors. IEEE, 2006. http://dx.doi.org/10.1109/icsens.2007.355764.

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Andersson, J. D., K. Gagnon, J. S. Wilson, J. Romaniuk, D. N. Abrams e S. A. McQuarrie. "Separation of molybdenum and technetium". In 14TH INTERNATIONAL WORKSHOP ON TARGETRY AND TARGET CHEMISTRY. AIP, 2012. http://dx.doi.org/10.1063/1.4773975.

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Wolfsberg, K., G. A. Cowan, E. A. Bryant, K. S. Daniels, S. W. Downey, W. C. Haxton, V. G. Niesen, N. S. Nogar, C. M. Miller e D. J. Rokop. "The molybdenum solar neutrino experiment". In AIP Conference Proceedings Vol.126. AIP, 1985. http://dx.doi.org/10.1063/1.35148.

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Nag, Aditi V., Priyank Kumar, D. S. Tripathi, N. K. Bhatt, P. R. Vyas e V. B. Gohel. "Dynamical elastic constants of molybdenum". In 3RD INTERNATIONAL CONFERENCE ON CONDENSED MATTER AND APPLIED PHYSICS (ICC-2019). AIP Publishing, 2020. http://dx.doi.org/10.1063/5.0001270.

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Blake, Richard L., Jeffrey C. Davis, Ping P. Gong, Dale E. Graessle e Warren Ruderman. "Measurement of molybdenum mirror reflectivities". In San Diego, '91, San Diego, CA, a cura di Richard B. Hoover. SPIE, 1992. http://dx.doi.org/10.1117/12.51260.

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Gemming, S. "Novel Elongated Molybdenum Sulfide Nanostructures". In ELECTRONIC PROPERTIES OF NOVEL NANOSTRUCTURES: XIX International Winterschool/Euroconference on Electronic Properties of Novel Materials. AIP, 2005. http://dx.doi.org/10.1063/1.2103886.

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Rapporti di organizzazioni sul tema "Molybdenum"

1

Kostelac, Cole, Nicholas Thompson, Rene Sanchez e Jesson Hutchinson. Molybdenum Benchmark Update. Office of Scientific and Technical Information (OSTI), luglio 2021. http://dx.doi.org/10.2172/1808823.

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2

Tysoe, W. T. An investigation of molybdenum and molybdenum oxide catalyzed hydrocarbon formation reactions. Office of Scientific and Technical Information (OSTI), settembre 1995. http://dx.doi.org/10.2172/93973.

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3

Kirkham, R. V., W. D. Sinclair, C. McCann, N. Prasad, A E Soregaroli, F. M. Vokes, G. Wine e J. J. Carrière. Canadian molybdenum occurrence database. Natural Resources Canada/ESS/Scientific and Technical Publishing Services, 2014. http://dx.doi.org/10.4095/295585.

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4

Beaux II, Miles Frank, e Igor Olegovich Usov. Molybdenum Tube Characterization report. Office of Scientific and Technical Information (OSTI), febbraio 2017. http://dx.doi.org/10.2172/1342881.

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5

Kjornrattanawanich, Benjawan. Reflectance, Optical Properties, and Stability of Molybdenum/Strontium and Molybdenum/Yttrium Multilayer Mirrors. Office of Scientific and Technical Information (OSTI), settembre 2002. http://dx.doi.org/10.2172/15002102.

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6

Ney, Adam, Sukhjinder Singh, Nathan Langlitz, Dominik Fritz, Jesson D. Hutchinson, Rian Mustafa Bahran e Nicholas William Thompson. MoSES: A Molybdenum-Sensitive Eigenreactor System for Validation of Molybdenum Neutron Cross Sections. Office of Scientific and Technical Information (OSTI), aprile 2018. http://dx.doi.org/10.2172/1435553.

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Pierce, R. A. Uranium-Molybdenum Dissolution Flowsheet Studies. Office of Scientific and Technical Information (OSTI), marzo 2007. http://dx.doi.org/10.2172/1183716.

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8

Pierce, R. A. Uranium-Molybdenum Dissolution Flowsheet Studies. Office of Scientific and Technical Information (OSTI), marzo 2007. http://dx.doi.org/10.2172/1183723.

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9

Smith, A. B. Neutron scattering and models : molybdenum. Office of Scientific and Technical Information (OSTI), maggio 1999. http://dx.doi.org/10.2172/12066.

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Lowden, Richard Andrew, Beth L. Armstrong e Kevin M. Cooley. Gel Fabrication of Molybdenum “Beads”. Office of Scientific and Technical Information (OSTI), novembre 2016. http://dx.doi.org/10.2172/1360052.

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