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Tesi sul tema "Macrocycles"

Autore: Grafiati
Pubblicato: 4 giugno 2021
Ultima modifica: 25 luglio 2025

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1

Azarias, Cloé. "Modeling azacalixphyrin macrocycles." Thesis, Nantes, 2018. http://www.theses.fr/2018NANT4021/document.

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Abstract (sommario):
Cette thèse porte sur la modélisation des propriétés structurales, aromatiques et spectroscopiques d'une nouvelle classe de macrocycles alternatifs aux porphyrines, les azacalixphyrines (ACPs). Ces macrocycles conjugués, synthétisés et caractérisés pour la première fois en 2010 par le groupe d’Olivier Siri à Marseille, ont montré des propriétés exceptionnelles (structure, absorption, tautomérie, et complexation). Cette thèse vise à proposer de nouveaux dérivés aux propriétés améliorées, notamment en ce qui concerne leur absorption, en utilisant les outils offerts par la chimie théorique. Parmi
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2

Danso-Danquah, Richmond Edward. "Syntheses of polypyrrolic macrocycles." Thesis, University of British Columbia, 1986. http://hdl.handle.net/2429/26240.

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Abstract (sommario):
Pentaphyrins are pentapyrrolic macrocycles containing five bridging methine groups between the five pyrrolic subunits. The syntheses of decamethylpentaphyrin 71, 2-ethoxycarbonyl-3,7,8,12,13,17,18,22,23-nonamethylpentaphyrin 74, 2-ethoxycarbonyl-3,7,8,22,23-pentamethyl-12,13,17,18-tetraethylpentaphyrin 75, 3,12-dimethoxycarbonylethyl-2,7,8,-13,17,18,22,23-octamethylpentaphyrins 29 and the zinc complexes of 71 and 74 are described. The physical properties of the pentaphyrins show them to be aromatic like sapphyrins, porphyrins and corroles. This aromaticity is reflected in the large shielding
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3

Norman, Timothy John. "Radioimmunotherapy with yttrium macrocycles." Thesis, Durham University, 1994. http://etheses.dur.ac.uk/5529/.

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Abstract (sommario):
Monoclonal antibody fragments (Fab') which recognise tumour-associated antigens provide an ingenious means of selectively targeting a therapeutic radionuclide to a tumour for radioimmunotherapy. The radionuclide yttrium-90, a long range β(^-) emitter, was chosen to deliver a sterilising dose of radiation to the tumour. A selection of novel functionalised macrocyclic ligands based on a 1,4,7,10-tetraazacyclododecane skeleton have been synthesised, and the stabilities of their yttrium (III) and gadolinium (III) complexes studied in vitro through association and dissociation measurements, and in
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4

Matthes, Karen Elizabeth. "Chemistry of functionalised macrocycles." Thesis, Durham University, 1987. http://etheses.dur.ac.uk/6704/.

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Abstract (sommario):
The work reported in this thesis is divided into two distinct areas. The first involves the synthesis of monoaza- and diaza-[12]-ring macrocycles, with differing side-arm N-substituents. The twelve-membered macrocycles possess a convenient ring-size for exploring the stability and selectivity of complexation of small cations, in particular those from groups IA and IIA. Amide substituents on nitrogen were expected to function as effective σ-donors to cations with high charge density (e.g. Li (^+), Ca (^2)(^+)), because of their high ground state dipole moments. The effect of the length of the s
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5

Sloman, Zachary Scott. "Novel thiophene based macrocycles." Thesis, Nottingham Trent University, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.297724.

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6

Marrs, Deborah Jane. "Macrocycles, macrobicycles : a study." Thesis, Open University, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.257447.

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7

Colombo-Khater, Dominique. "Macrocycles polyhétéroatomiques : synthèse, complexation." Toulouse 3, 1993. http://www.theses.fr/1993TOU30001.

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Depuis quelques annees, de nombreux macrocycles phosphores contenant des heteroatomes ont ete prepares dans le but d'obtenir des especes capables de complexer selectivement des cations voire meme des especes neutres. La methode de synthese mise au point au laboratoire en 1988 consiste a faire reagir un dialdehyde sur un phosphodihydrazide. Il s'agit d'une methode simple et generale de synthese de macrocycles polyphosphores. La reaction mise en jeu est une reaction de cyclocondensation 2+2. L'etude bibliographique presentee dans le premier chapitre nous a permis de faire le point sur les differ
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8

Watson, Walter Philip. "Hybrid Macrocycles for Supramolecular Assemblies." Diss., Georgia Institute of Technology, 2005. http://hdl.handle.net/1853/6958.

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Abstract (sommario):
Hybrid macrocycles, which chimerically integrate multiple chemical compositions and architectures, provide an effective way to impart new properties to polymers that are not found in their linear or homocyclic analogues. This dissertation addresses the incorporation of hydrophilic blocks into hydrophobic polymer, as either a poly(dimethyl siloxane)-block-poly(oxyethylene) (PDMS-POE) tadpole with a hydrophobic head and a hydrophilic tail or as a diblock poly(styrene)-block-diethylene glycol (PS-DEG) hydrophobic-hydrophilic macrocycle. The supramolecular association properties of both kinds of
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9

Morphy, John Richard. "Functionalised macrocycles for tumour targeting." Thesis, Durham University, 1988. http://etheses.dur.ac.uk/6407/.

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Abstract (sommario):
Monoclonal antibodies which recognise tumour-associated antigens provide a means of targeting radionuclides selectively to tumour cells. (^99m)Tc and (^64)Cu are potentially useful isotopes for radioimmunoimaging;(^ 90)Y and (^67)Cu may be suitable for radioimmunotherapy. The synthesis of functionalised macrocycles for binding these four radioisotopes to antibodies is described. In each case, a macrocycle has been selected to provide a complex which is kinetically inert, thereby preventing dissociation of the radiolabel in vivo. A novel strategy for conjugating a C-alkylated cyclam derivative
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10

Wood, Ian. "Hydrogen bonded double helical macrocycles." Thesis, University of Nottingham, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.285635.

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11

Munoz, Noelia Calcerrada. "Novel macrocycles derived from nucleosides." Thesis, University of Liverpool, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.343592.

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12

Mainolfi, Nello. "Making cycles, bicycles and macrocycles." Thesis, King's College London (University of London), 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.415446.

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13

Wright, Paul Trevor. "Synthesis of triphenylene based macrocycles." Thesis, University of Southampton, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.242705.

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14

Kowenicki, Richard Anthony. "Phosph(III)azane-based macrocycles." Thesis, University of Cambridge, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.615103.

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15

Barreira-Fontecha, Julia. "Polynuclear complexes of pseudocalixarene macrocycles." Thesis, Loughborough University, 2006. https://dspace.lboro.ac.uk/2134/33927.

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Abstract (sommario):
As part of a program to synthesise and investigate macrocyclic polynuclear arrays, a new range of phenol based pseudocalixarene macrocycles have been synthesized, combining some of the properties of the Schiff-base and calixarene macrocycle systems. A series of dinuclear complexes of the pseudocalixarene macrocycle H6LI containing two 2,2'-methylenediphenol groups have been synthesised and structurally characterised.
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16

Oussaid, Boualem. "Thiophène, pyrrole : synthèse, conformation, macrocycles." Toulouse 3, 1992. http://www.theses.fr/1992TOU30198.

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Abstract (sommario):
De nouveaux composes, derives du thiophene ou du pyrrole ont ete synthetises en plusieurs etapes. La conformation de divers composes thiopheniques ou pyrroliques a ete etablie a partir de calculs theoriques, de mesures de moments dipolaires et a partir du couplage stereospecifique a travers cinq liaisons. Quelques macrocycles possedant deux, trois ou quatre restes thiophene ou pyrrole a 18, 20, 30, 34 ou 40 chainons ont ete obtenus par des cyclisations de type 2+2, 3+3 ou 4+4
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17

Badri, Meryam. "Macrocycles phosphorés : synthèse, structure, réactivité." Toulouse, INPT, 1990. http://www.theses.fr/1990INPT002G.

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Abstract (sommario):
Ce travail a ete consacre a la mise au point d'une strategie de synthese simple et efficace permettant l'acces a une nouvelle classe de macrocycles organophosphores. La reaction mise en jeu est une cyclocondensation entre dialdehydes et phosphodihydrazides. Apres une mise au point bibliographique sur les methodes de synthese des macrocyles phosphores, la preparation et la caracterisation des precurseurs acycliques (phosphodihydrazides, phosphodi, trihydradrazones fonctionnalisees, dialdehydes en 1-2, 1-3, 1-4, 1-11, trialdehydes 1-11-11) sont decrites. Dans une seconde partie, la synthese de m
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18

Najimi, Ouafa. "Macrocycles tétrahétérocycliques synthèse et complexation /." Grenoble 2 : ANRT, 1988. http://catalogue.bnf.fr/ark:/12148/cb376169502.

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19

Boden, Britta Nicole. "Investigations of highly conjugated macrocycles and polymers for aggregation and chemical sensing." Thesis, University of British Columbia, 2007. http://hdl.handle.net/2429/269.

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Abstract (sommario):
With the goal of developing Schiff base macrocycles with conjugation extended over multiple aromatic rings, new phenanthrene and triphenylene-containing bis(salicylates) were synthesized. A convenient route to 3,6,9,10-tetraalkoxy-2,7-diiodophenanthrene was developed. This compound has been found to be a useful precursor for Pd-catalyzed cross-coupling reactions. Macrocycles were synthesized by Schiff base condensation of the phenanthrene and triphenylene precursors. Reaction of smaller phenanthrene and triphenylene bis(salicylates) with 1,2-dialkoxy-4,5-phenylenediamine afforded macrocycles
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20

Müri, Marcel [Verfasser]. "Shape Switchable Azo Macrocycles / Marcel Müri." München : Verlag Dr. Hut, 2011. http://d-nb.info/1015606938/34.

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21

Everitt, Simon Robert Lorrie. "Peptidic macrocycles for enantioselective electrophile transfer." Thesis, Heriot-Watt University, 1997. http://hdl.handle.net/10399/683.

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22

Tallis, Huw Aubrey. "Novel approaches towards phosphorous containing macrocycles." Thesis, Cardiff University, 2009. http://orca.cf.ac.uk/54905/.

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Abstract (sommario):
The first chapter in this thesis discusses the general trends in group 15 donor ligands, in particularly nitrogen and phosphorus. The major advancements in phosphorus donor macrocyclic chemistry over the past two decades are documented, and the various synthetic strategies are described. The properties of triphosphorus macrocycles and ensuing complexes are discussed, and the aims of this thesis are summarised. In chapter 2, the preparation of 1-trimemylsilylphosphirane, 2.3, from cUoroemylbis(trimemylsilyl)phospriine, 2.1, is discussed. 1-trimemylsilylphosphirane may be converted to the parent
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23

Cromie, Sarah Jane Frances. "Chemistry and synthesis of polynuclear macrocycles." Thesis, Loughborough University, 2003. https://dspace.lboro.ac.uk/2134/35559.

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Abstract (sommario):
A series of di-, tetra- and octanuclear transition metal complexes of tetranucleating macrocyclic ligands derived from a Schiff-base [2+2] template condensation of 2,6-diformyl-4-methylphenol (dfmp) or 2,6-diformyl-4-tbutylphenol (tdfp) with 1,5-diaminopentan-3-ol dihydrochloride (dahp), H4L1 and H4L2 respectively, has been investigated. The characterisation of these complexes was achieved using infrared spectrometry, elemental analysis, FAB mass spectrometry and where possible single-crystal X-ray diffraction data. A study of the interaction of tetranickel(II) complexes of H4L1 and H4L2 with
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24

Bley, Escrich Jordi. "Propriétés rédox de nouveaux macrocycles polypyrroliques." Université Louis Pasteur (Strasbourg) (1971-2008), 2001. http://www.theses.fr/2001STR13097.

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25

Lee, Sang-Hun. "Supramolecular architectures : macrocycles, catenanes and polyrotaxanes /." Diss., This resource online, 1996. http://scholar.lib.vt.edu/theses/available/etd-08232007-112703/.

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26

Zidane, Ismail. "Macrocycles tétrapyrazoliques synthèse et complexes métalliques /." Grenoble 2 : ANRT, 1986. http://catalogue.bnf.fr/ark:/12148/cb376019979.

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27

Pisciottani, Luca. "Synthèse de macrocycles et rotaxanes électroactifs." Thesis, Bordeaux, 2018. http://www.theses.fr/2018BORD0270/document.

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Le développement d'architectures moléculaires enchevêtrées (rotaxanes) est un sujet d'actualité en chimie supramoléculaire. Cette thèse examine la synthèse multi-étape de sous-unités de rotaxanes, notamment de composants macrocycliques électroactifs, et leur assemblage dans des structures moléculaires imbriquées. De nouveaux cycles à 31 et 35 chaînons à liaison hydrogène comprenant un motif récepteur bis (2,6-diamidopyridine) et une unité électroactive, à savoir du ferrocène ou de la triphénylamine, ont été synthétisés. Ces macrocycles ont été analysés par voltampérométrie cyclique, analyse pa
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28

Lucas, Jeremy. "Reaction dynamics of some pendant arm macrocycles /." Title page, contents and abstract only, 1994. http://web4.library.adelaide.edu.au/theses/09PH/09phl9333.pdf.

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29

Lopez, Periago Ana Maria. "Synthesis and supramolecular chemistry of trianglimine macrocycles." Thesis, University of Surrey, 2004. http://epubs.surrey.ac.uk/804876/.

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30

Willey, Alan David. "Substituted aza macrocycles as novel membrane precursors." Thesis, University of Liverpool, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.316629.

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31

Mammoliti, Oscar. "Bis-sulfonamide macrocycles as receptors for carboxylates." Thesis, University of Southampton, 2007. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.438730.

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32

Jantos, Katja. "Targeting G-quadruplex DNA with amide macrocycles." Thesis, University of Cambridge, 2007. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.613084.

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33

Tatchell, Thomas. "Coordination chemistry of pendant aniline aza-macrocycles." Thesis, Cardiff University, 2005. http://orca.cf.ac.uk/56099/.

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Abstract (sommario):
The selective functionalisation of triazamacrocycles is investigated herein, with the focus on 1, 4, 7-triazacyclononane (tacn) The ligands tris (5-fluoro, 2- aminophenyl) 1, 4, 7-triazacyclononane (L1), tris (4-fluoro, 2-aminophenyl) 1,4, 7- triazacyclononane (L") and tris (3-fluoro, 2-ammophenyl) 1, 4, 7-triazacyclononane (L ) were studied. X-Ray crystal data was obtained for (L,)M (C104)2.x:MeCN where M=Mn,,/FeII/Ni"/CuII/Znn/CdII/Hgn, (L2)M (C104)2 xMeCN where M=Mn1I/Fe,I/NiII/CuII/ZnII/Cdn and (L3)M (C104)2 xMeCN where M=Mn,1/NiI,/Cun/Zn,I/Cd,,/Pb11 complexes. The (L,)Cu (C104)2 complex e
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34

Manning, Joanna M. "Synthesis and complexes of new selenoether macrocycles." Thesis, University of Southampton, 2010. https://eprints.soton.ac.uk/173855/.

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The first known examples of alkyl Pt(II) complexes with macrocyclic selenoethers [PtMe2L] (L = [8]aneSe2 and [16]aneSe4) have been synthesised and characterised as part of a series of dimethyl Pt(II) complexes with selenoether ligands (L = MeSe(CH2)nSeMe, n = 2, 3; o-C6H4(CH2SeMe)2). A new series of [PtMe3I(κ2-L-L)] complexes has been synthesised and characterised, which includes the first examples of this type with macrocyclic selenoethers (L-L = o-C6H4(CH2EMe)2, E = Se, Te; MeC(CH2SeMe)3; [8]aneSe2 and [16]aneSe4). The first bridging ditelluroether trimethyliodo Pt(IV) complex, [(PtMe3I)2(Me
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35

Andrianatoandro, Harimbola. "Macrocycles aromatiques complexants. Radiocristallographie et spectrométrie électronique." Bordeaux 1, 1992. http://www.theses.fr/1992BOR10582.

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Abstract (sommario):
De nouveaux macrocycles aromatiques complexants ont ete etudies en presence et en l'absence de cations, par diffraction des rayons x et photophysique (absorption electronique et fluorescence). Les interactions intramoleculaires entre chromophores (benzene, naphtalene et anthracene) et heteroatomes (n, s) dans le monocristal sont decrites et reliees aux proprietes photophysiques a l'etat solide et en solution. En particulier, pour deux cryptates d'argent (trois conformeres differents) et un complexe de sodium, l'influence de la position des cations sur la spectroscopie des ligands est abordee e
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36

Zamyatin, Andrey V. "A Photophysical Investigation of Nickel Tetrapyrrole Macrocycles." Bowling Green State University / OhioLINK, 2006. http://rave.ohiolink.edu/etdc/view?acc_num=bgsu1134849222.

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37

Bornet, Céline. "Synthèse et réactivité de nouveaux macrocycles séléniés." Dijon, 1998. http://www.theses.fr/1998DIJOS043.

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Ce mémoire apporte une contribution à la synthèse et à l'étude des propriétés complexantes de nouveaux macrocycles séléniés. Ceux-ci ont été pour la plupart construits autour d'entités rigides de type orthodisélénophénylène obtenues au départ d'un complexe du zirconium préparé antérieurement au laboratoire. Une chaine oxygénée a été dans chaque cas utilisée pour réaliser la cyclisation ou pour jouer le rôle d'espaceur entre deux entités. A des fins de comparaisons, d'autres systèmes construits au départ de ligands orthothio-séléno ou orthothio-tellurophénylène ont également été synthétisés. Le
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38

PULPOKA, BUNCHA. "Synthese d'oxa-aza macrocycles derivant du calix4arene." Université Louis Pasteur (Strasbourg) (1971-2008), 1997. http://www.theses.fr/1997STR13030.

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Le travail presente dans cette these a consiste en la synthese de ligands macrocycliques polytopiques et en l'etude de leurs proprietes complexantes. Ces ligands derivent du calix4arene et comportent des chaines (n,o)-ether-couronnes et des motifs cryptands. Cet arrangement moleculaire se fait de part et d'autre d'un calix4arene en conformation 1,3-alternee. Dans un premier temps nous avons synthetise des calix4arene-di(aza-benzo)couronne-ether-couronnes-6 comportant une chaine polyethylene glycolique d'un cote du calixarene et une chaine (n,o)-ether-couronne de l'autre. Le double-pontage du c
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39

Kaiser, Achim. "Physicochemical Properties and Synthesis of Oligothiophene Macrocycles." [S.l. : s.n.], 2008. http://nbn-resolving.de/urn:nbn:de:bsz:289-vts-64614.

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40

Cai, Sheng. "Magnetic resonance investigations of iron tetrapyrrolic macrocycles." Diss., The University of Arizona, 2001. http://hdl.handle.net/10150/279817.

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Abstract (sommario):
¹H NMR and EPR techniques were used to investigate the electron spin distribution and electronic ground state in several iron tetrapyrrolic macrocycles. The first macrocycle studied is corrole, including [(Me₈C)FeCl] (Me₈C = 2,3,7,8,12,13,17,18-octamethylcorrole) and [(7,13-Me₂Et₆C)FeCl] (7,13-Me₂Et₆C = 7,13-dimethyl-2,3,8,12,17,18-hexaethylcorrole) and four meso-substituted corrolates--[(TPCorr)FeCl], [(4-NO2TPCorr)FeCl], [(4-MeOTPCorr)FeCl] and [(TPCorr)FeClO₄] (TPCorr = 5,10,15-triphenylcorrole). These chloroiron corrolates were all found to be S = 3/2 intermediate-spin iron(III) π cation r
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41

Heberlig, Graham William. "Harnessing Natural Product Biosynthesis to Access Macrocycles." Thesis, Université d'Ottawa / University of Ottawa, 2019. http://hdl.handle.net/10393/39260.

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Abstract (sommario):
Macrocyclic natural products are conformationally restricted molecules that often have improved ability to bind with high affinity and selectivity on a target. Within macrocycle chemistry, macrolactone formation is a particularly challenging transformation and has spurred the development of highly diverse synthetic strategies. A key strategy that is missing is a chemoenzymatic approach to this challenge, and the logical place to look for such a catalyst is the thioesterases (TEs) from the biosynthetic pathways that generate these molecules in Nature. These TEs are α/β-hydrolases containing an
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42

Le, Derf Franck. "Macrocycles complexants électrochimiquement commandables incorporant l'unité tétrathiafulvalène." Angers, 1998. http://www.theses.fr/1998ANGE0021.

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Abstract (sommario):
Une stratégie de synthèse de récepteurs macrocycliques associant a une sous unité électroactive tetrathiafulvalene (ttf), des chaines aza-, oxa- ou thia-polyethers de tailles variées a été développée. La capacite de ces systèmes à piéger divers cations métalliques a pu être déterminée a l'aide de différentes méthodes (spectrometrie de masse, résonance magnétique nucléaire, spectroscopie uv-vis), certains complexes ayant par ailleurs été caractérisés par diffraction aux rayons-x. La maitrise recherchée de processus de complexation / expulsion du métal en fonction du degré d'oxydation de l'unité
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43

Sakellariou, Efstathia G. "Seco- and solitaire porphyrazines : design, synthesis and photophysical evaluation." Thesis, Imperial College London, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.270124.

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44

Bakboord, Joan Vanessa. "Synthesis and spectroscopic studies of novel phthalocyanines-toward new electronic absorption properties." Thesis, University of East Anglia, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.323290.

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45

Tseki, Potlaki Foster. "Metal complexes of thiophene analogues of crown ethers and cryptands." Thesis, Nottingham Trent University, 1994. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.386053.

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46

Mousley, David P. "The application of bis(benzo)-crown ethers as multireceptors." Thesis, University of Newcastle Upon Tyne, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.295075.

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47

Korich, Andrew. "Phenylene Ethynylene and Phenylene Imine Macrocycles As Precursors for Organic Nanotubes." ScholarWorks @ UVM, 2009. http://scholarworks.uvm.edu/graddis/127.

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Abstract (sommario):
Single walled carbon nanotubes (SWCNTs) have unique physical, optical and electronic properties. Current production methods provide SWCNTs as a polydisperse mixture, with respect to helicity, diameter and length, and cannot be tuned to yield a discrete SWCNT isomer. A bottom up approach would yield a single SWCNT, which would allow for a better understanding of how chemical modification affects a carbon nanotube’s properties. Synthesis by this route has yet to be accomplished. Phenylene ethynylene macrocycles were synthesized by a stepwise linear fashion and cyclooligomerization. These
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48

Huez, Philippe. "Synthèses et analyses conformationnelles de macrocycles aza-β³-peptidiques contenant des atomes d'azote chirogéniques". Thesis, Rennes 1, 2014. http://www.theses.fr/2014REN1S072/document.

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Abstract (sommario):
Le travail présenté dans ce mémoire est consacré à la synthèse de cycles pseudopeptidiques construits à partir d'aza-β³-aminoacides, et à la détermination des conformations adoptées par ces cycles. Le travail réalisé a permis de montrer que les cycles obtenus à 8, 16 et 24 liaisons adoptent des conformations privilégiées dans lesquelles la configuration relative des atomes d'azote chiraux est fixée en dépit du phénomène d'inversion pyramidale associé à la structure électronique de cet élément chimique, en réponse à des contraintes structurelles qui varient selon la taille du macrocycle. Ces cy
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49

Klein, Jörg Martin. "Dynamic combinatorial chemistry of hydrazone and disulfide macrocycles." Thesis, University of Cambridge, 2011. https://www.repository.cam.ac.uk/handle/1810/252248.

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50

Edwards, David Ryan. "Towards liquid crystalline [3 + 3] Schiff-base macrocycles." Thesis, University of British Columbia, 2007. http://hdl.handle.net/2429/31612.

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Abstract (sommario):
Conjugated Schiff-base macrocycles are interesting compounds of interest as platforms for catalysis, the preparation of novel synthetic ion channels and potentially as porous or tubular discotic liquid crystals. The preparation of organic macrocycles is typically low yielding, with polymerization competing with cyclization; the use of imines derived from the condensation of an aldehyde and an amine provides a means by which to conduct cyclizations under thermodynamic control and thereby improve yields. The use of difunctional aldehydes and amines allows for the formation of macrocycles in high
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