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Articoli di riviste sul tema "Ionic imaging by mass spectrometry"

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Autore: Grafiati

Pubblicato: 8 giugno 2024

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1

Meriaux, Céline, Julien Franck, Maxence Wisztorski, Michel Salzet e Isabelle Fournier. "Liquid ionic matrixes for MALDI mass spectrometry imaging of lipids". Journal of Proteomics 73, n. 6 (aprile 2010): 1204–18. http://dx.doi.org/10.1016/j.jprot.2010.02.010.

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2

Chan, Kenneth, Patricia Lanthier, Xin Liu, Jagdeep K. Sandhu, Danica Stanimirovic e Jianjun Li. "MALDI mass spectrometry imaging of gangliosides in mouse brain using ionic liquid matrix". Analytica Chimica Acta 639, n. 1-2 (aprile 2009): 57–61. http://dx.doi.org/10.1016/j.aca.2009.02.051.

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3

Metarapi, Dino, Johannes T. van Elteren, Martin Šala, Katarina Vogel-Mikuš, Iztok Arčon, Vid S. Šelih, Mitja Kolar e Samo B. Hočevar. "Laser ablation-single-particle-inductively coupled plasma mass spectrometry as a multimodality bioimaging tool in nano-based omics". Environmental Science: Nano 8, n. 3 (2021): 647–56. http://dx.doi.org/10.1039/d0en01134g.

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4

Matsushita, Yasuyuki, In-Cheol Jang, Takanori Imai, Ruka Takama, Kaori Saito, Takashi Masumi, Seung-Cheol Lee e Kazuhiko Fukushima. "Distribution of extracts including 4,8-dihydroxy-5-methoxy-2-naphthaldehyde in Diospyros kaki analyzed by gas chromatography-mass spectrometry and time-of-flight secondary ion mass spectrometry". Holzforschung 66, n. 6 (1 agosto 2012): 705–9. http://dx.doi.org/10.1515/hf-2011-0214.

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Abstract The distribution of ethyl acetate extracts and 4,8-dihydroxy-5-methoxy-2-naphthaldehyde (compound I), which is a major constituent of the extracts obtained from the blackened heartwood of Diospyros kaki, was analyzed via gas chromatography-mass spectrometry (GC-MS) and time-of-flight secondary ion mass spectrometry (ToF-SIMS). According to GC-MS, the extracts and compound I are high in concentration at the pith and at the edges of the blackened heartwood. ToF-SIMS analysis revealed a peak at a mass-to-charge ratio of (m/z) 218, which is characteristic of the ionic form of compound I. The ToF-SIMS imaging of compound I in the blackened heartwood based on m/z 218 shows that compound I is located in parenchyma cells and their neighboring axial elements.

5

Xi, Ying, e David C. Muddiman. "Enhancing Metabolomic Coverage in Positive Ionization Mode Using Dicationic Reagents by Infrared Matrix-Assisted Laser Desorption Electrospray Ionization". Metabolites 11, n. 12 (29 novembre 2021): 810. http://dx.doi.org/10.3390/metabo11120810.

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Mass spectrometry imaging is a powerful tool to analyze a large number of metabolites with their spatial coordinates collected throughout the sample. However, the significant differences in ionization efficiency pose a big challenge to metabolomic mass spectrometry imaging. To solve the challenge and obtain a complete data profile, researchers typically perform experiments in both positive and negative ionization modes, which is time-consuming. In this work, we evaluated the use of the dicationic reagent, 1,5-pentanediyl-bis(1-butylpyrrolidinium) difluoride (abbreviated to [C5(bpyr)2]F2) to detect a broad range of metabolites in the positive ionization mode by infrared matrix-assisted laser desorption electrospray ionization mass spectrometry imaging (IR-MALDESI MSI). [C5(bpyr)2]F2 at 10 µM was doped in 50% MeOH/H2O (v/v) electrospray solvent to form +1 charged adducted ions with anionic species (−1 charged) through post-electrospray ionization. This method was demonstrated with sectioned rat liver and hen ovary. A total of 73 deprotonated metabolites from rat liver tissue sections were successfully adducted with [C5(bpyr)2]2+ and putatively identified in the adducted positive ionization polarity, along with 164 positively charged metabolite ions commonly seen in positive ionization mode, which resulted in 44% increased molecular coverage. In addition, we were able to generate images of hen ovary sections showing their morphological features. Following-up tandem mass spectrometry (MS/MS) indicated that this dicationic reagent [C5(bpyr)2]2+ could form ionic bonds with the headgroup of glycerophospholipid ions. The addition of the dicationic reagent [C5(bpyr)2]2+ in the electrospray solvent provides a rapid and effective way to enhance the detection of metabolites in positive ionization mode.

6

Shen, Kan, Jay G. Tarolli e Nicholas Winograd. "Cluster secondary ion mass spectrometry imaging of interfacial reactions of TiO2 microspheres embedded in ionic liquids". Rapid Communications in Mass Spectrometry 30, n. 3 (28 dicembre 2015): 379–85. http://dx.doi.org/10.1002/rcm.7447.

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7

Liu, Qiang, e Lin He. "Ionic matrix for matrix-enhanced surface-assisted laser desorption ionization mass spectrometry imaging (ME-SALDI-MSI)". Journal of the American Society for Mass Spectrometry 20, n. 12 (dicembre 2009): 2229–37. http://dx.doi.org/10.1016/j.jasms.2009.08.011.

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8

Perez, Consuelo J., Alessandra Tata, Michel L. de Campos, Chun Peng e Demian R. Ifa. "Monitoring Toxic Ionic Liquids in Zebrafish (Danio rerio) with Desorption Electrospray Ionization Mass Spectrometry Imaging (DESI-MSI)". Journal of The American Society for Mass Spectrometry 28, n. 6 (24 ottobre 2016): 1136–48. http://dx.doi.org/10.1007/s13361-016-1515-9.

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9

Kriegel, Fabian L., Benjamin-Christoph Krause, Philipp Reichardt, Ajay Vikram Singh, Jutta Tentschert, Peter Laux, Harald Jungnickel e Andreas Luch. "The Vitamin A and D Exposure of Cells Affects the Intracellular Uptake of Aluminum Nanomaterials and Its Agglomeration Behavior: A Chemo-Analytic Investigation". International Journal of Molecular Sciences 21, n. 4 (14 febbraio 2020): 1278. http://dx.doi.org/10.3390/ijms21041278.

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Aluminum (Al) is extensively used for the production of different consumer products, agents, as well as pharmaceuticals. Studies that demonstrate neurotoxicity and a possible link to Alzheimer’s disease trigger concern about potential health risks due to high Al intake. Al in cosmetic products raises the question whether a possible interaction between Al and retinol (vitamin A) and cholecalciferol (vitamin D3) metabolism might exist. Understanding the uptake mechanisms of ionic or elemental Al and Al nanomaterials (Al NMs) in combination with bioactive substances are important for the assessment of possible health risk associated. Therefore, we studied the uptake and distribution of Al oxide (Al2O3) and metallic Al0 NMs in the human keratinocyte cell line HaCaT. Possible alterations of the metabolic pattern upon application of the two Al species together with vitamin A or D3 were investigated. Time-of-flight secondary ion mass spectrometry (ToF-SIMS) imaging and inductively coupled plasma mass spectrometry (ICP-MS) were applied to quantify the cellular uptake of Al NMs.

10

Gabler, Christoph, Ernst Pittenauer, Nicole Dörr e Günter Allmaier. "Imaging of a Tribolayer Formed from Ionic Liquids by Laser Desorption/Ionization-Reflectron Time-of-Flight Mass Spectrometry". Analytical Chemistry 84, n. 24 (6 dicembre 2012): 10708–14. http://dx.doi.org/10.1021/ac302503a.

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11

Ingram, Peter, Scott D. Davilla e Ann LeFurgey. "Event Streamed Spectrum Imaging using Programmed Beam Acquisition in Biological Microprobe Analysis". Microscopy Today 17, n. 1 (gennaio 2009): 44–47. http://dx.doi.org/10.1017/s1551929500055024.

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The general trend of microscopical investigation in biology from the 1950s to the early 1970s was towards obtaining structural information. This goal initially was met using heavy metal and/or aldehyde fixatives, room temperature dehydration with polar organic liquids, embedding with epoxy and acrylate resins, and thin sectioning at room temperature. By the mid 1970s, a perceptible change occurred in the direction of both light and analytical electron microscopy towards investigation of the chemical reactivity and composition of structures made visible with increasingly better spatial resolution for light and electron microscopes. During the past 25 years there have been considerable innovations in microanalytical techniques, including analytical electron and x-ray microscopy and microanalysis, secondary ion mass spectrometry, laser microprobe mass analysis, the scanning probe microscopies, and confocal/multi-photon microscopy. In addition, cryopreservation and the development of chromophores for visualization of molecular and ionic sites within individual living cells as well as membranes have redefined the goal of microscopical preservation: to stabilize cell structure and composition as they exist in the living state.

12

Shrivas, Kamlesh, Takahiro Hayasaka, Naoko Goto-Inoue, Yuki Sugiura, Nobuhiro Zaima e Mitsutoshi Setou. "Ionic Matrix for Enhanced MALDI Imaging Mass Spectrometry for Identification of Phospholipids in Mouse Liver and Cerebellum Tissue Sections". Analytical Chemistry 82, n. 21 (novembre 2010): 8800–8806. http://dx.doi.org/10.1021/ac102422b.

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13

Cheng, Leo L., Anya B. Zhong, Isabella H. Muti, Stephen J. Eyles, Richard W. Vachet, Sylwia A. Stopka, Kristen N. Sikora et al. "Abstract 2322: Multiplatform metabolomics studies of human cancers with NMR and mass spectrometry imaging". Cancer Research 82, n. 12_Supplement (15 giugno 2022): 2322. http://dx.doi.org/10.1158/1538-7445.am2022-2322.

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Abstract Unfortunately, at present, there is no single technique that possesses all the characteristics needed to be considered an ideal global metabolite profiling tool. Thus, the use of multiple analytical platforms, such as combining the strengths of Mass spectrometry (MS) and nuclear magnetic resonance spectroscopy (NMR), for metabolic profiling can maximize coverage and generate more global metabolomic profiles. In this study, we demonstrate the utilities of the combined NMR and MSI multiplatform in our metabolomics results on human prostate and lung cancers. Statistical data on the natural history of prostate cancer (PCa) show that >70% of patients diagnosed by PSA screening will likely experience indolent disease with little impact on well-being. For about 17% of newly PSA-diagnosed patients, however, aggressive PCa proliferation ensues, truncating life expectancy. At present, no reliable clinical test can differentiate between these two groups. Using HRMAS 1HNMR followed by quantitative histology, we showed statistically significant correlations between concentrations of Spm and the amount of histologically-benign epithelial (Hb Epi) prostatic cells and glands in human cancerous prostates. However, as above discussed that using HRMAS NMR alone we cannot prove that Spm was indeed generated or resided in the Hb Epi cells. Nevertheless, using MALDI MSI, we were able to locate Spm (m/z: 203.223 ± 0.001Da) onto Hb Epi, where spermine on the PCa lesions appeared below detection limits. From these maps, for the first time, we could visualize and confirm the differential localizations of Spm in prostates. This proof of Sym relationship to prostate pathologies and its proposed PCa inhibitory effects may support further studies that are critical in differentiating aggressive from indolent PCa for disease evaluations and patient personalized treatment strategies. To search for such screening metabolomics biomarkers in lung cancer, we used HRMAS NMR to analyze 93 pairs of human LuCa tissue and serum samples, and 29 healthy human sera. A number of potential metabolite candidates capable to differentiate LuCa characteristics were identified, including glutamate, lipids, alanine, glycerylphosphorylcholine, glutamine, phosphorylcholine, etc. This list can be further expanded by analyzing metabolite composition in the serum of cancer patients and control healthy subjects using LC-MS, which offers a dramatic increase in sensitivity compared to HRMAS NMR and, therefore, is better suited for the biomarker discovery. In addition to acquiring high-resolution mass data, the high data acquisition rate allows the fragment ion mass spectra (MS/MS) to be generated for the most abundant ionic species in each chromatographic peak. This feature allows specific classes of tumor-attenuated metabolites to be identified based on the presence of unique structurally diagnostic fragment ions in MS/MS spectra. Citation Format: Leo L. Cheng, Anya B. Zhong, Isabella H. Muti, Stephen J. Eyles, Richard W. Vachet, Sylwia A. Stopka, Kristen N. Sikora, Cedric E. Bobst, Jeffrey N. Agar, Mari A. Mino-Kenudson, Chin-Lee Wu, David C. Christiani, Igor A. Kaltashov, Nathalie Y. Agar. Multiplatform metabolomics studies of human cancers with NMR and mass spectrometry imaging [abstract]. In: Proceedings of the American Association for Cancer Research Annual Meeting 2022; 2022 Apr 8-13. Philadelphia (PA): AACR; Cancer Res 2022;82(12_Suppl):Abstract nr 2322.

14

Ashhar, Zarif, Nor Azah Yusof, Fathinul Fikri Ahmad Saad, Siti Mariam Mohd Nor, Faruq Mohammad, Wan Hamirul Bahrin Wan Kamal, Muhammad Hishar Hassan, Hazlina Ahmad Hassali e Hamad A. Al-Lohedan. "Preparation, Characterization, and Radiolabeling of [68Ga]Ga-NODAGA-Pamidronic Acid: A Potential PET Bone Imaging Agent". Molecules 25, n. 11 (9 giugno 2020): 2668. http://dx.doi.org/10.3390/molecules25112668.

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Early diagnosis of bone metastases is crucial to prevent skeletal-related events, and for that, the non-invasive techniques to diagnose bone metastases that make use of image-guided radiopharmaceuticals are being employed as an alternative to traditional biopsies. Hence, in the present work, we tested the efficacy of a gallium-68 (68Ga)-based compound as a radiopharmaceutical agent towards the bone imaging in positron emitting tomography (PET). For that, we prepared, thoroughly characterized, and radiolabeled [68Ga]Ga-NODAGA-pamidronic acid radiopharmaceutical, a 68Ga precursor for PET bone cancer imaging applications. The preparation of NODAGA-pamidronic acid was performed via the N-Hydroxysuccinimide (NHS) ester strategy and was characterized using liquid chromatography-mass spectrometry (LC-MS) and tandem mass spectrometry (MSn). The unreacted NODAGA chelator was separated using the ion-suppression reverse phase-high performance liquid chromatography (RP-HPLC) method, and the freeze-dried NODAGA-pamidronic acid was radiolabeled with 68Ga. The radiolabeling condition was found to be most optimum at a pH ranging from 4 to 4.5 and a temperature of above 60 °C. From previous work, we found that the pamidronic acid itself has a good bone binding affinity. Moreover, from the analysis of the results, the ionic structure of radiolabeled [68Ga]Ga-NODAGA-pamidronic acid has the ability to improve the blood clearance and may exert good renal excretion, enhance the bone-to-background ratio, and consequently the final image quality. This was reflected by both the in vitro bone binding assay and in vivo animal biodistribution presented in this research.

15

PEI, Xing-Li, Yu-Yu HUANG, Can GONG e Xu XU. "Matrix-assisted Laser Desorption/Ionization-Mass Spectrometry Imaging of Oligosaccharides in Soybean and Bean Leaf with Ionic Liquid as Matrix". Chinese Journal of Analytical Chemistry 45, n. 8 (agosto 2017): 1155–63. http://dx.doi.org/10.1016/s1872-2040(17)61031-4.

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Chang, Hung-Ming, Wen-Chieh Liao, Ji-Nan Sheu, Chun-Chao Chang, Chyn-Tair Lan e Fu-Der Mai. "Sleep Deprivation Impairs Ca2+ Expression in the Hippocampus: Ionic Imaging Analysis for Cognitive Deficiency with TOF-SIMS". Microscopy and Microanalysis 18, n. 3 (12 aprile 2012): 425–35. http://dx.doi.org/10.1017/s1431927612000086.

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AbstractSleep deprivation causes cognitive dysfunction in which impaired neuronal plasticity in hippocampus may underlie the molecular mechanisms of this deficiency. Considering calcium-mediated NMDA receptor subunit 1 (NMDAR1) and neuronal nitric oxide synthase (nNOS) activation plays an important role in the regulation of neuronal plasticity, the present study is aimed to determine whether total sleep deprivation (TSD) would impair calcium expression, together with injury of the neuronal plasticity in hippocampus. Adult rats subjected to TSD were processed for time-of-flight secondary ion mass spectrometry, NMDAR1 immunohistochemistry, nNOS biochemical assay, cytochrome oxidase histochemistry, and the Morris water maze learning test to detect ionic, neurochemical, bioenergetic as well as behavioral changes of neuronal plasticity, respectively. Results indicated that in normal rats, strong calcium signaling along with intense NMDAR1/nNOS expression were observed in hippocampal regions. Enhanced calcium imaging and neurochemical expressions corresponded well with strong bioenergetic activity and good performance of behavioral testing. However, following TSD, both calcium intensity and NMDAR1/nNOS expressions were significantly decreased. Behavioral testing also showed poor responses after TSD. As proper calcium expression is essential for maintaining hippocampal neuronal plasticity, impaired calcium expression would depress downstream NMDAR1-mediated nNOS activation, which might contribute to the initiation or development of TSD-related cognitive deficiency.

17

Steinkoenig, Jan, Martina M. Cecchini, Anja S. Goldmann, Samantha Reale, Francesco De Angelis e Christopher Barner-Kowollik. "Just Add Salt: A Mass Spectrometric Analysis Method for Imaging Anion-Exchanged Poly(Ionic Liquid)s". Macromolecular Rapid Communications 37, n. 20 (29 agosto 2016): 1662–66. http://dx.doi.org/10.1002/marc.201600376.

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Bonnel, David, Julien Franck, Céline Mériaux, Michel Salzet e Isabelle Fournier. "Ionic matrices pre-spotted matrix-assisted laser desorption/ionization plates for patient maker following in course of treatment, drug titration, and MALDI mass spectrometry imaging". Analytical Biochemistry 434, n. 1 (marzo 2013): 187–98. http://dx.doi.org/10.1016/j.ab.2012.10.035.

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Garate, Jone, Albert Maimó-Barceló, Joan Bestard-Escalas, Roberto Fernández, Karim Pérez-Romero, Marco A. Martínez, Mª Antònia Payeras, Daniel H. Lopez, José Andrés Fernández e Gwendolyn Barceló-Coblijn. "A Drastic Shift in Lipid Adducts in Colon Cancer Detected by MALDI-IMS Exposes Alterations in Specific K+ Channels". Cancers 13, n. 6 (17 marzo 2021): 1350. http://dx.doi.org/10.3390/cancers13061350.

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Even though colorectal cancer (CRC) is one of the most preventable cancers, it is one of the deadliest, and recent data show that the incidence in people <50 years has unexpectedly increased. While new techniques for CRC molecular classification are emerging, no molecular feature is as yet firmly associated with prognosis. Imaging mass spectrometry (IMS) lipidomic analyses have demonstrated the specificity of the lipid fingerprint in differentiating pathological from healthy tissues. During IMS lipidomic analysis, the formation of ionic adducts is common. Of particular interest is the [Na+]/[K+] adduct ratio, which already functions as a biomarker for homeostatic alterations. Herein, we show a drastic shift of the [Na+]/[K+] adduct ratio in adenomatous colon mucosa compared to healthy mucosa, suggesting a robust increase in K+ levels. Interrogating public databases, a strong association was found between poor diagnosis and voltage-gated potassium channel subunit beta-2 (KCNAB2) overexpression. We found this overexpression in three CRC molecular subtypes defined by the CRC Subtyping Consortium, making KCNAB2 an interesting pharmacological target. Consistently, its pharmacological inhibition resulted in a dramatic halt in commercial CRC cell proliferation. Identification of potential pharmacologic targets using lipid adduct information emphasizes the great potential of IMS lipidomic techniques in the clinical field.

20

Gabriel, Stefan J., Dietmar Pfeifer, Clemens Schwarzinger, Ulrich Panne e Steffen M. Weidner. "Matrix-assisted laser desorption/ionization time-of-flight mass spectrometric imaging of synthetic polymer sample spots prepared using ionic liquid matrices". Rapid Communications in Mass Spectrometry 28, n. 5 (27 gennaio 2014): 489–98. http://dx.doi.org/10.1002/rcm.6810.

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Khabir, Zahra, Amy M. Holmes, Yi-Jen Lai, Liuen Liang, Anand Deva, Michael A. Polikarpov, Michael S. Roberts e Andrei V. Zvyagin. "Human Epidermal Zinc Concentrations after Topical Application of ZnO Nanoparticles in Sunscreens". International Journal of Molecular Sciences 22, n. 22 (16 novembre 2021): 12372. http://dx.doi.org/10.3390/ijms222212372.

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Zinc oxide nanoparticle (ZnO NP)-based sunscreens are generally considered safe because the ZnO NPs do not penetrate through the outermost layer of the skin, the stratum corneum (SC). However, cytotoxicity of zinc ions in the viable epidermis (VE) after dissolution from ZnO NP and penetration into the VE is ill-defined. We therefore quantified the relative concentrations of endogenous and exogenous Zn using a rare stable zinc-67 isotope (67Zn) ZnO NP sunscreen applied to excised human skin and the cytotoxicity of human keratinocytes (HaCaT) using multiphoton microscopy, zinc-selective fluorescent sensing, and a laser-ablation inductively coupled plasma–mass spectrometry (LA-ICP-MS) methodology. Multiphoton microscopy with second harmonic generation imaging showed that 67ZnO NPs were retained on the surface or within the superficial layers of the SC. Zn fluorescence sensing revealed higher levels of labile and intracellular zinc in both the SC and VE relative to untreated skin, confirming that dissolved zinc species permeated across the SC into the VE as ionic Zn and significantly not as ZnO NPs. Importantly, the LA-ICP-MS estimated exogenous 67Zn concentrations in the VE of 1.0 ± 0.3 μg/mL are much lower than that estimated for endogenous VE zinc of 4.3 ± 0.7 μg/mL. Furthermore, their combined total zinc concentrations in the VE are much lower than the exogenous zinc concentration of 21 to 31 μg/mL causing VE cytotoxicity, as defined by the half-maximal inhibitory concentration of exogenous 67Zn found in human keratinocytes (HaCaT). This speaks strongly for the safety of ZnO NP sunscreens applied to intact human skin and the associated recent US FDA guidance.

22

Bagarinao, Katherine Develos, Hiroki Muroyama, Toshiaki Matsui, Haruo Kishimoto e Teruhisa Horita. "Understanding Degradation Behavior of Direct-Ammonia Solid Oxide Fuel Cells Using Nanoscale Analyses". ECS Meeting Abstracts MA2023-02, n. 45 (22 dicembre 2023): 2203. http://dx.doi.org/10.1149/ma2023-02452203mtgabs.

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Direct-ammonia solid oxide fuel cells (SOFCs) offer a cost-effective and efficient avenue for accelerating the use of hydrogen as a major energy vector. The effect of directly feeding ammonia as a fuel into SOFCs and their associated degradation behavior, however, needs to be fully understood in order to design robust cells capable of operating with good performance and durability at the required high temperatures for extended periods of time. In this study, we performed detailed analyses using advanced techniques such as high-resolution secondary ion mass spectrometry (SIMS) imaging and microscopy methods to examine the microstructural evolution and factors affecting nickel nitriding behavior of model Ni metal surfaces as well as Ni/yttria-stabilized zirconia (YSZ) cermet anodes directly exposed to ammonia as a function of temperature. The results show preferential formation of nickel nitride and presence of OH- species on Ni metal surfaces directly exposed to ammonia, as well as grain boundaries in the bulk which were not directly exposed to ammonia, suggesting enhanced ionic diffusion along these regions. Nickel nitriding is also accompanied by volume expansion which is considered to result in additional mechanical stress. Ni/YSZ cermet anodes, on the other hand, exhibit a significantly higher amount of nickel nitride formed preferentially in pore regions at lower temperatures, suggesting the possibility of nickel nitride decomposition occurring at higher temperatures. The results further suggest a correlation between nickel nitride formation and microstructural features of Ni/YSZ cermet anodes which influence gas diffusion properties. Lastly, a model for the degradation behavior of Ni/YSZ cermet anodes on the basis these results will be proposed and discussed.

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Tepavcevic, Sanja, Michael Counihan, Jungkuk Lee, Pallab Barai, Justin G. Connell, Venkat Srinivasan e Yuepeng Zhang. "(Invited) Advancing Understanding of Composite Polymer Electrolytes with LLZO Nanofibers". ECS Meeting Abstracts MA2023-02, n. 4 (22 dicembre 2023): 618. http://dx.doi.org/10.1149/ma2023-024618mtgabs.

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Ceramic Li6.55Al0.2La3Zr2O12 (LLZO) is one of the most attractive electrolyte materials for solid-state batteries that combined with metallic Li anodes holds the promise for safer and more energetically dense battery, but its performance is limited by the increases in electrolyte-electrode interfacial resistances upon cycling. The combination of Li+-conducting ceramics and polymers offers a new pathway to create better electrolytes with both high ionic conductivity and good (electro)mechanical interfacial properties. We optimized two-step annealing processing conditions for the fabrication of low temperature cubic-LLZO nanofibers and Li2CO3 removal from the surface of the nanofibers. Using industrially relevant roll-to-roll electrospinning and slot-die coating, we fabricated thin composite membranes with reproducible thickness down to 50 microns. We investigated PEO based composite polymer electrolyte (CPE) with a high, 50 wt% loading of Al-doped LLZO nanofibers in comparison with nanofiber-free PEO electrolyte. XPS measurements show that LLZO is not present at the composite electrolyte surface, and solid electrolyte interphase (SEI) formation is dictated solely by PEO and LiTFSI when reacting with Li metal. Electrochemical SEI formation, studied by cyclic voltammetry, shows SEI formation is identical with and without up to 75 wt% LLZO in the electrolyte. Galvanostatic cycling with lithium symmetric cells shows that the critical current density (CCD) can be tripled by including 50 wt% LLZO, but half cell cycling reveals this comes at the cost of CE. Varying the LLZO loading shows that even a small amount of LLZO drastically lowers the CE, from 88% at 0 wt% LLZO to 77% at just 2 wt% LLZO. Mesoscale modelling reveals that the increase in CCD cannot be explained by an increase in the macroscopic or microscopic stiffness of the electrolyte; only the microstructure of the LLZO nanofibers in the PEO-LiTFSI matrix slows dendrite growth by presenting physical barriers that the dendrites must push or grow around. This tortuous lithium growth mechanism around the LLZO is corroborated with mass spectrometry imaging. Electrochemical impedance spectroscopy (EIS) analysis showed comparable bulk ionic and interfacial resistances with and without nanofibers, indicating that PEO dominates Li+ transport and interfacial chemistry. The total Li-ion conductivity of the composite is still governed by the polymer matrix due to high interfacial resistance between the garnet particles and the PEO/LiTFSI matrix. This work highlights important elements to consider in the design of CPEs for high-efficiency lithium metal batteries.

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Heeren, Ron M. A., e Jonathan V. Sweedler. "Imaging mass spectrometry imaging". International Journal of Mass Spectrometry 260, n. 2-3 (febbraio 2007): 89. http://dx.doi.org/10.1016/j.ijms.2006.11.016.

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NAITO, Yasuhide. "Imaging Mass Spectrometry". Journal of the Mass Spectrometry Society of Japan 55, n. 1 (2007): 39. http://dx.doi.org/10.5702/massspec.55.39.

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Nirasawa, Takashi, Toshiji Kudo e Takaya Satoh. "Imaging mass spectrometry". Japanese Journal of Pesticide Science 42, n. 1 (2017): 216–22. http://dx.doi.org/10.1584/jpestics.w17-51.

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Shimma, Shuichi. "Mass Spectrometry Imaging". Mass Spectrometry 11, n. 1 (25 febbraio 2022): A0102. http://dx.doi.org/10.5702/massspectrometry.a0102.

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Setou, Mitsutoshi. "Imaging Mass Spectrometry". YAKUGAKU ZASSHI 132, n. 4 (1 aprile 2012): 499–506. http://dx.doi.org/10.1248/yakushi.132.499.

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Smeal, Joseph, e Charles L. Wilkins. "Imaging Mass Spectrometry". Applied Spectroscopy Reviews 46, n. 6 (agosto 2011): 425–39. http://dx.doi.org/10.1080/05704928.2011.570834.

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McDonnell, Liam A., e Ron M. A. Heeren. "Imaging mass spectrometry". Mass Spectrometry Reviews 26, n. 4 (30 aprile 2007): 606–43. http://dx.doi.org/10.1002/mas.20124.

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ITO, Fumihiro, Shin ANDO, Masato IUCHI, Taki UKARI, Momoka TAKASAKI, Tomoko NAKAMURA, Satoko YORITA e Kentaro YAMAGUCHI. "Ionic Probe Attachment Ionization Mass Spectrometry". Journal of the Mass Spectrometry Society of Japan 60, n. 1 (2012): 5–12. http://dx.doi.org/10.5702/massspec.11-32.

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32

Ito, Fumihiro, Tomoko Nakamura, Satoko Yorita, Hiroshi Danjo e Kentaro Yamaguchi. "Ionic probe attachment ionization mass spectrometry". Tetrahedron Letters 50, n. 46 (novembre 2009): 6252–55. http://dx.doi.org/10.1016/j.tetlet.2009.09.021.

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33

Porta Siegel, Tiffany, e Shane R. Ellis. "Mass spectrometry imaging 2.0". Analytical and Bioanalytical Chemistry 413, n. 10 (23 marzo 2021): 2597–98. http://dx.doi.org/10.1007/s00216-021-03293-9.

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Blaschke, Calvin R. K., Colin T. McDowell, Alyson P. Black, Anand S. Mehta, Peggi M. Angel e Richard R. Drake. "Glycan Imaging Mass Spectrometry". Clinics in Laboratory Medicine 41, n. 2 (giugno 2021): 247–66. http://dx.doi.org/10.1016/j.cll.2021.03.005.

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Franck, Julien, Karim Arafah, Mohamed Elayed, David Bonnel, Daniele Vergara, Amélie Jacquet, Denis Vinatier et al. "MALDI Imaging Mass Spectrometry". Molecular & Cellular Proteomics 8, n. 9 (18 maggio 2009): 2023–33. http://dx.doi.org/10.1074/mcp.r800016-mcp200.

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Pacholski, M. L., e N. Winograd. "Imaging with Mass Spectrometry". Chemical Reviews 99, n. 10 (ottobre 1999): 2977–3006. http://dx.doi.org/10.1021/cr980137w.

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Bamberger, Casimir, Uwe Renz e Andreas Bamberger. "Digital Imaging Mass Spectrometry". Journal of The American Society for Mass Spectrometry 22, n. 6 (12 aprile 2011): 1079–87. http://dx.doi.org/10.1007/s13361-011-0120-1.

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Kiss, András, Donald F. Smith, Julia H. Jungmann e Ron M. A. Heeren. "Cluster secondary ion mass spectrometry microscope mode mass spectrometry imaging". Rapid Communications in Mass Spectrometry 27, n. 24 (31 ottobre 2013): 2745–50. http://dx.doi.org/10.1002/rcm.6719.

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Setou, M., e N. Kurabe. "Mass microscopy: high-resolution imaging mass spectrometry". Journal of Electron Microscopy 60, n. 1 (24 novembre 2010): 47–56. http://dx.doi.org/10.1093/jmicro/dfq079.

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SHIMMA, Shuichi, e Mitsutoshi SETOU. "Review of Imaging Mass Spectrometry". Journal of the Mass Spectrometry Society of Japan 53, n. 4 (2005): 230–38. http://dx.doi.org/10.5702/massspec.53.230.

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YAO, Ikuko. "Imaging Mass Spectrometry for Acetylcholine". Journal of the Mass Spectrometry Society of Japan 64, n. 1 (2016): 31–34. http://dx.doi.org/10.5702/massspec.s16-07.

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SUGIURA, Yuki, e Shuichi SHIMMA. "Imaging Mass Spectrometry for Metabolomics". Journal of the Mass Spectrometry Society of Japan 65, n. 5 (2017): 215–19. http://dx.doi.org/10.5702/massspec.s17-51.

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Satoh, Takaya. "Imaging Mass Spectrometry Using SpiralTOFMS". Journal of the Mass Spectrometry Society of Japan 69, n. 5 (1 ottobre 2021): 147–48. http://dx.doi.org/10.5702/massspec.s21-29.

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Watrous, Jeramie D., e Pieter C. Dorrestein. "Imaging mass spectrometry in microbiology". Nature Reviews Microbiology 9, n. 9 (8 agosto 2011): 683–94. http://dx.doi.org/10.1038/nrmicro2634.

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Doerr, Allison. "Mass spectrometry imaging takes off". Nature Methods 15, n. 1 (gennaio 2018): 32. http://dx.doi.org/10.1038/nmeth.4546.

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Caprioli, Richard M. "Imaging Mass Spectrometry: A Perspective". Journal of Biomolecular Techniques : JBT 30, n. 1 (aprile 2019): 7–11. http://dx.doi.org/10.7171/jbt.19-3001-002.

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Odom, Robert W. "Secondary Ion Mass Spectrometry Imaging". Applied Spectroscopy Reviews 29, n. 1 (febbraio 1994): 67–116. http://dx.doi.org/10.1080/05704929408000898.

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Jones, Emrys A., Sören-Oliver Deininger, Pancras C. W. Hogendoorn, André M. Deelder e Liam A. McDonnell. "Imaging mass spectrometry statistical analysis". Journal of Proteomics 75, n. 16 (agosto 2012): 4962–89. http://dx.doi.org/10.1016/j.jprot.2012.06.014.

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Hanrieder, Jörg, Nhu T. N. Phan, Michael E. Kurczy e Andrew G. Ewing. "Imaging Mass Spectrometry in Neuroscience". ACS Chemical Neuroscience 4, n. 5 (30 aprile 2013): 666–79. http://dx.doi.org/10.1021/cn400053c.

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Goto-Inoue, Naoko, Takahiro Hayasaka, Nobuhiro Zaima e Mitsutoshi Setou. "Imaging mass spectrometry for lipidomics". Biochimica et Biophysica Acta (BBA) - Molecular and Cell Biology of Lipids 1811, n. 11 (novembre 2011): 961–69. http://dx.doi.org/10.1016/j.bbalip.2011.03.004.

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