Letteratura scientifica selezionata sul tema "Fluorocyclopropane"

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Articoli di riviste sul tema "Fluorocyclopropane"

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Dall'O, L., e H. Heydtmann. "Kinetic Study of Chemically Activated Fluorocyclopropane". Berichte der Bunsengesellschaft für physikalische Chemie 91, n. 1 (gennaio 1987): 24–30. http://dx.doi.org/10.1002/bbpc.19870910107.

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Toyota, Akemi, Yoshinori Ono, Chikara Kaneko e Isao Hayakawa. "A novel stereoselective synthesis of cis-2-fluorocyclopropane-1-carboxylic acid". Tetrahedron Letters 37, n. 47 (novembre 1996): 8507–10. http://dx.doi.org/10.1016/0040-4039(96)01952-1.

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TOYOTA, A., Y. ONO, C. KANEKO e I. HAYAKAWA. "ChemInform Abstract: A Novel Stereoselective Synthesis of cis-2-Fluorocyclopropane-1- carboxylic Acid." ChemInform 28, n. 12 (4 agosto 2010): no. http://dx.doi.org/10.1002/chin.199712078.

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Pons, Amandine, Jonathan Decaens, Riham Najjar, Nansalmaa Otog, Mathieu Arribat, Sandrine Jolly, Samuel Couve-Bonnaire et al. "Fluorocyclopropane-Containing Proline Analogue: Synthesis and Conformation of an Item in the Peptide Chemistʼs Toolbox". ACS Omega 7, n. 6 (4 febbraio 2022): 4868–78. http://dx.doi.org/10.1021/acsomega.1c05337.

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Kaupert, Cornelia, Horst Heydtmann e Walter Thiel. "The vibrational spectra of the monohalogenated cyclopropanes: Ab initio calculations and an experimental study of fluorocyclopropane". Chemical Physics 156, n. 1 (settembre 1991): 85–93. http://dx.doi.org/10.1016/0301-0104(91)87040-3.

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Zhang, Fei, Zhiguo J. Song, Dave Tschaen e R. P. Volante. "Enantioselective Preparation of Ring-Fused 1-Fluorocyclopropane-1-carboxylate Derivatives: En Route to mGluR 2 Receptor Agonist MGS0028". Organic Letters 6, n. 21 (ottobre 2004): 3775–77. http://dx.doi.org/10.1021/ol0484512.

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Saito, Akio, Hisanaka Ito e Takeo Taguchi. "A stereoselective preparation of 1-fluorocyclopropane-1-carboxylate derivatives through radical addition of fluoroiodoacetate to alkenes followed by intramolecular substitution reaction". Tetrahedron 57, n. 35 (agosto 2001): 7487–93. http://dx.doi.org/10.1016/s0040-4020(01)00726-8.

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Delion, Laëtitia, Thomas Poisson, Philippe Jubault, Xavier Pannecoucke e André B. Charette. "Synthesis of fluorocyclopropanes via the enantioselective cyclopropanation of fluoro-substituted allylic alcohols using zinc carbenoids". Canadian Journal of Chemistry 98, n. 9 (settembre 2020): 516–23. http://dx.doi.org/10.1139/cjc-2020-0036.

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Abstract (sommario):
Cyclopropanation reactions using zinc carbenoids are a powerful means to access cyclopropanes. Described herein is an enantioselective version of the reaction using zinc reagents and a chiral dioxaborolane ligand in the generation of fluorocyclopropanes. Readily available 2- and 3-fluoroallylic alcohols were efficiently cyclopropanated in high yields and excellent enantioselectivities. This method provides access to a variety of structurally diverse chiral fluorocyclopropanes that can be used as useful chiral building blocks.
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Saito, Akio, Hisanaka Ito e Takeo Taguchi. "ChemInform Abstract: A Stereoselective Preparation of 1-Fluorocyclopropane-1-carboxylate Derivatives Through Radical Addition of Fluoroiodoacetate to Alkenes Followed by Intramolecular Substitution Reaction." ChemInform 32, n. 51 (23 maggio 2010): no. http://dx.doi.org/10.1002/chin.200151053.

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Garbacz, Piotr, Janusz Cukras e Michał Jaszuński. "A theoretical study of potentially observable chirality-sensitive NMR effects in molecules". Physical Chemistry Chemical Physics 17, n. 35 (2015): 22642–51. http://dx.doi.org/10.1039/c5cp02870a.

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Tesi sul tema "Fluorocyclopropane"

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Audet, Florian. "Development of new access routes to fluorinated building blocks for agrochemical applications". Electronic Thesis or Diss., Strasbourg, 2024. http://www.theses.fr/2024STRAF002.

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Abstract (sommario):
Le fluor est naturellement présent sur Terre sous forme de sels, notamment de fluorure de calcium. Il est également utilisé pour de nombreuses applications industrielles dont les domaines pharmaceutiques et agrochimiques. En effet, de nombreux principes actifs utilisés dans ces domaines contiennent au moins un atome de fluor ce qui leur confère des propriétés particulières en modulant ses paramètres physico-chimiques et biologiques. L’objectif de cette thèse, en partenariat avec Bayer CropScience, était de développer de nouvelles voies d’accès à des synthons fluorés pour des applications en agrochimie. Nous nous sommes d’abord intéressés à une réaction de couplage croisé d’électrophiles en conditions électrochimiques permettant l’accès au motif difluorométhylène. Des réactions de N-polyfluoroalkylations ont ensuite été développées en utilisant le fluorure de sulfuryle comme réactif clé. Enfin, une réaction de couplage croisé d’un nouveau réactif de type (1-fluorocyclopropyl)metalloïde a été mise au point, permettant l’introduction direct de ce motif fluoré émergent
Fluorine is naturally occurring on Earth in the form of salts, the most notable being calcium fluoride. Over the last decades, has been used in numerous industrial applications, including pharmaceuticals and agrochemicals. Indeed, many active ingredients used in these fields contain at least one fluorine atom, giving them unique properties by modulating their physico-chemical and biological parameters.The objective of this thesis, in partnership with Bayer CropScience, was to develop new ways of accessing fluorinated synthons for agrochemical applications. We started by investigating a cross-electrophile coupling reaction under electrochemical conditions to access the difluoromethylene moiety. N-Polyfluoroalkylation reactions were then developed using sulfuryl fluoride as the key reagent. Finally, a cross-coupling reaction with a new (1-fluorocyclopropyl)metaloid reagent was developed, enabling the direct introduction of this emerging fluorinated group
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Shelton, G. Robert. "Computational investigation of 1-fluorocyclopropenes". [Gainesville, Fla.] : University of Florida, 2004. http://purl.fcla.edu/fcla/etd/UFE0007541.

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Capitoli di libri sul tema "Fluorocyclopropane"

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"Product Class 2: Fluorocyclopropanes". In Category 5, Compounds with One Carbon Heteroatom Bond, a cura di Percy. Stuttgart: Georg Thieme Verlag, 2006. http://dx.doi.org/10.1055/sos-sd-034-00152.

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"34.2.2 Fluorocyclopropanes (Update 2017)". In Knowledge Updates: 2017/2, a cura di Christmann, Paquin, Weinreb, Carreira e Schaumann. Stuttgart: Georg Thieme Verlag, 2017. http://dx.doi.org/10.1055/sos-sd-134-00144.

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Kawase, T. "From 1-Bromo-1-fluorocyclopropanes". In Cumulenes and Allenes, 1. Georg Thieme Verlag KG, 2008. http://dx.doi.org/10.1055/sos-sd-044-00316.

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Challenger, S. "Synthesis of 1-Chloro-1-fluorocyclopropanes". In Acetals: Hal/X and O/O, S, Se, Te, 1. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-029-00037.

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Challenger, S. "Synthesis of 1-Bromo-1-fluorocyclopropanes". In Acetals: Hal/X and O/O, S, Se, Te, 1. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-029-00048.

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