Letteratura scientifica selezionata sul tema "Donor-Acceptor cyclopropane"
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Articoli di riviste sul tema "Donor-Acceptor cyclopropane":
Craig, Alexander J., e Bill C. Hawkins. "The Bonding and Reactivity of α-Carbonyl Cyclopropanes". Synthesis 52, n. 01 (1 ottobre 2019): 27–39. http://dx.doi.org/10.1055/s-0039-1690695.
Boichenko, Maksim A., Andrey Yu Plodukhin, Vitaly V. Shorokhov, Danyla S. Lebedev, Anastasya V. Filippova, Sergey S. Zhokhov, Elena A. Tarasenko, Victor B. Rybakov, Igor V. Trushkov e Olga A. Ivanova. "Synthesis of 1,5-Substituted Pyrrolidin-2-ones from Donor–Acceptor Cyclopropanes and Anilines/Benzylamines". Molecules 27, n. 23 (2 dicembre 2022): 8468. http://dx.doi.org/10.3390/molecules27238468.
Mead, Keith, e Yahaira Reyes. "Acetoxy-Substituted Cyclopropane Dicarbonyls as Stable Donor–Acceptor–Acceptor Cyclopropanes". Synthesis 47, n. 19 (25 giugno 2015): 3020–26. http://dx.doi.org/10.1055/s-0034-1379934.
Fadeev, Alexander A., Alexey O. Chagarovskiy, Anton S. Makarov, Irina I. Levina, Olga A. Ivanova, Maxim G. Uchuskin e Igor V. Trushkov. "Synthesis of (Het)aryl 2-(2-hydroxyaryl)cyclopropyl Ketones". Molecules 25, n. 23 (5 dicembre 2020): 5748. http://dx.doi.org/10.3390/molecules25235748.
Grover, Huck K., Michael R. Emmett e Michael A. Kerr. "Carbocycles from donor–acceptor cyclopropanes". Organic & Biomolecular Chemistry 13, n. 3 (2015): 655–71. http://dx.doi.org/10.1039/c4ob02117g.
Reyes, Yahaira, e Keith T. Mead. "ChemInform Abstract: Acetoxy-Substituted Cyclopropane Dicarbonyls as Stable Donor-Acceptor-Acceptor Cyclopropanes." ChemInform 47, n. 7 (gennaio 2016): no. http://dx.doi.org/10.1002/chin.201607087.
Budynina, Ekaterina, Konstantin Ivanov, Ivan Sorokin e Mikhail Melnikov. "Ring Opening of Donor–Acceptor Cyclopropanes with N-Nucleophiles". Synthesis 49, n. 14 (18 maggio 2017): 3035–68. http://dx.doi.org/10.1055/s-0036-1589021.
Ivanova, Olga, Vladimir Andronov, Irina Levina, Alexey Chagarovskiy, Leonid Voskressensky e Igor Trushkov. "Convenient Synthesis of Functionalized Cyclopropa[c]coumarin-1a-carboxylates". Molecules 24, n. 1 (24 dicembre 2018): 57. http://dx.doi.org/10.3390/molecules24010057.
Liu, Haidong, Lifang Tian, Hui Wang, Zhi-Qiang Li, Chi Zhang, Fei Xue e Chao Feng. "A novel type of donor–acceptor cyclopropane with fluorine as the donor: (3 + 2)-cycloadditions with carbonyls". Chemical Science 13, n. 9 (2022): 2686–91. http://dx.doi.org/10.1039/d2sc00302c.
Cavitt, Marchello A., Lien H. Phun e Stefan France. "Intramolecular donor–acceptor cyclopropane ring-opening cyclizations". Chem. Soc. Rev. 43, n. 3 (2014): 804–18. http://dx.doi.org/10.1039/c3cs60238a.
Tesi sul tema "Donor-Acceptor cyclopropane":
Cavitt, Marchello Alfonzo. "Stress relief: Exercising Lewis acid catalysis for donor-acceptor cyclopropane ring-opening annulations, a basis for new reaction methodologies". Diss., Georgia Institute of Technology, 2015. http://hdl.handle.net/1853/54448.
Colonna, Pierre. "Un cyclopropane donneur-accepteur original pour la synthèse de benzocylobutènes substitués via une cascade réactionnelle". Electronic Thesis or Diss., Aix-Marseille, 2022. http://www.theses.fr/2022AIXM0336.
Benzocyclobutenes (BCBs) derivatives are of significant interest due to the cooperative effects between the thermodynamic stability coming from the aromatic ring and the high reactivity of the strained cyclobutene moiety. In this regard, BCBs have been used as an original building block for the synthesis of natural products and also as precursors for the development of polymers. On the other hand, small rings represent a valuable three-atoms building element in the search to reach molecular complexity in an atom economical manner and often participate in fascinating chemical transformations. This release of ring tension usually allows for a scalable, rapid and controlled synthetic access to the expected target molecules. In this context, a new class of donor-acceptor cyclopropane (DAC) has recently been developed in our laboratory combining a silyl protected cyclopropanol with an α,β-unsaturated ester. Gratifyingly, the latter delivered the corresponding highly functionalized benzocyclobutenes in good yields. Experimental investigations demonstrated that depending on the substitutions of the silyl protected cyclopropanol (donor part), a one-step or two-steps approach had to be adopted. In this way, a library of BCB with alkyl- or aryl- substituent on the cyclobutene ring have been synthesised. Mechanistic studies demonstrated experimentally the total regioselectivity observed on the substituted BCB depending on the diastereochemistry of the DAC. Finally, the synthesis of taylor-made monomers has been also explored. Typically, the introduction of an alkoxy or amino group on the four-membered ring has been envisaged thanks to a post-functionalisation approach
Sanders, Shanina Devondia Brookhart Maurice S. "Lewis acid-catalyzed cycloaddition reactions of donor-acceptor cyclopropanes". Chapel Hill, N.C. : University of North Carolina at Chapel Hill, 2009. http://dc.lib.unc.edu/u?/etd,2534.
Title from electronic title page (viewed Oct. 5, 2009). "... in partial fulfillment of the requirements for the degree of Doctor of Philosophy in the Department of Chemistry." Discipline: Chemistry; Department/School: Chemistry.
Lund, Elizabeth Anne. "Studies of samarium(II) iodide-induced ring openings and donor-acceptor cyclopropanes". Thesis, University of Ottawa (Canada), 1994. http://hdl.handle.net/10393/6817.
Dousset, Maxime. "Réaction d'expansion de cycle : études dirigées vers l'accès aux cycles de taille moyenne via des espèces polarisées". Thesis, Aix-Marseille, 2017. http://www.theses.fr/2017AIXM0577.
In the quest for new therapeutic candidates, the description of novel synthetic approaches to access to increasingly complex carbon systems remains a daunting challenge. In order to increase the structural of such scaffolds, it is necessary to overcome the encountered difficulties by developing new straightforward an efficient tools. In this context, this work has mainly focused on the access of structurally defined carbon cycles by ring expansion reactions via the use of polarized compounds. The first part of this study has been devoted to the Tiffeneau-Demjanov ring expansion reaction using ethyl α-chlorodiazoacetate. This approach allowed us to access highly versatile cyclic keto esters displaying a tetrasubstitued carbon center bearing a chlorine atom. The next topic of this study has been focused on the development of a (5 + 3) cycloaddition reaction between two polarized cyclopropane entities. This methodology led to the description of a novel reactivity of donor-acceptor cyclopropanes compounds to form α,β,γ-trisubstituted lactones under a BrØnsted acid activation. In order to gain mechanistic insights, a theoretical study has also been conducted which led us to rationalize the mechanism and the selectivity of this transformation. The last part described the reactivity of a underexplored class of molecule, the vinylbiscyclopropanes. These compound, can lead to the benzocyclobutene family and to the 8 membered-ring compounds through rearrangement or formal [3.3] sigmatropic rearrangement reaction. This last class of compound is still under study and should allow rapid access to diverse cyclic structures
Gladow, Daniel [Verfasser]. "Darstellung von perfluoralkyl- und perfluoraryl-substituierten Heterocyclen ausgehend von Donor-Acceptor-Cyclopropanen / Daniel Gladow". Berlin : Freie Universität Berlin, 2014. http://d-nb.info/1052893945/34.
Dousset, Maxime. "Réaction d'expansion de cycle : études dirigées vers l'accès aux cycles de taille moyenne via des espèces polarisées". Electronic Thesis or Diss., Aix-Marseille, 2017. http://www.theses.fr/2017AIXM0577.
In the quest for new therapeutic candidates, the description of novel synthetic approaches to access to increasingly complex carbon systems remains a daunting challenge. In order to increase the structural of such scaffolds, it is necessary to overcome the encountered difficulties by developing new straightforward an efficient tools. In this context, this work has mainly focused on the access of structurally defined carbon cycles by ring expansion reactions via the use of polarized compounds. The first part of this study has been devoted to the Tiffeneau-Demjanov ring expansion reaction using ethyl α-chlorodiazoacetate. This approach allowed us to access highly versatile cyclic keto esters displaying a tetrasubstitued carbon center bearing a chlorine atom. The next topic of this study has been focused on the development of a (5 + 3) cycloaddition reaction between two polarized cyclopropane entities. This methodology led to the description of a novel reactivity of donor-acceptor cyclopropanes compounds to form α,β,γ-trisubstituted lactones under a BrØnsted acid activation. In order to gain mechanistic insights, a theoretical study has also been conducted which led us to rationalize the mechanism and the selectivity of this transformation. The last part described the reactivity of a underexplored class of molecule, the vinylbiscyclopropanes. These compound, can lead to the benzocyclobutene family and to the 8 membered-ring compounds through rearrangement or formal [3.3] sigmatropic rearrangement reaction. This last class of compound is still under study and should allow rapid access to diverse cyclic structures
Patil, Dadasaheb V. "Intramolecular cyclization strategies for synthesizing medium-ring polycycles and the total synthesis of natural products". Diss., Georgia Institute of Technology, 2012. http://hdl.handle.net/1853/50118.
Yu, Ming. "New chemistry of donor-acceptor cyclopropanes". Thesis, 2004. http://hdl.handle.net/2152/1441.
Yu, Ming Pagenkopf Brian L. "New chemistry of donor-acceptor cyclopropanes". 2004. http://repositories.lib.utexas.edu/bitstream/handle/2152/1441/yum73355.pdf.
Libri sul tema "Donor-Acceptor cyclopropane":
Banerjee, Prabal, e Akkattu T. Biju. Donor-Acceptor Cyclopropanes in Organic Synthesis. Wiley & Sons, Incorporated, John, 2022.
Banerjee, Prabal, e Akkattu T. Biju. Donor-Acceptor Cyclopropanes in Organic Synthesis. Wiley & Sons, Limited, John, 2022.
Banerjee, Prabal, e Akkattu T. Biju. Donor-Acceptor Cyclopropanes in Organic Synthesis. Wiley & Sons, Incorporated, John, 2022.
Banerjee, Prabal, e Akkattu T. Biju. Donor-Acceptor Cyclopropanes in Organic Synthesis. Wiley & Sons, Incorporated, John, 2022.
Novikov, Roman, Denis Borisov, Leonid Menchikov e Yuriy Tomilov. Donor-acceptor cyclopropanes. Cycloaddition and annulation reactions. LCC MAKS Press, 2022. http://dx.doi.org/10.29003/m2659.978-5-317-06797-7.
Capitoli di libri sul tema "Donor-Acceptor cyclopropane":
Reißig, H. U. "Donor-Acceptor-Substituted Cyclopropanes via Fischer Carbene Complexes". In Organometallics in Organic Synthesis 2, 311–22. Berlin, Heidelberg: Springer Berlin Heidelberg, 1989. http://dx.doi.org/10.1007/978-3-642-74269-9_17.
Wienand, A., M. Buchert, B. Hofmann e H. U. Reissig. "The Carbene Complex Route to Donor-Acceptor-Substituted Cyclopropanes". In Advances in Metal Carbene Chemistry, 271–73. Dordrecht: Springer Netherlands, 1989. http://dx.doi.org/10.1007/978-94-009-2317-1_30.
Reißig, Hans-Ulrich. "Donor-acceptor-substituted cyclopropanes: Versatile building blocks in organic synthesis". In Topics in Current Chemistry, 73–135. Berlin, Heidelberg: Springer Berlin Heidelberg, 1988. http://dx.doi.org/10.1007/bfb0111229.
Lambert, Tristan H. "Advances in Heterocyclic Aromatic Construction". In Organic Synthesis. Oxford University Press, 2015. http://dx.doi.org/10.1093/oso/9780190200794.003.0068.
Anderson, E. A., e B. Gockel. "Variation 2: Ring Expansion of Donor–Acceptor-Substituted Cyclopropanes". In Science of Synthesis Knowledge Updates KU 2010/4, 1. Georg Thieme Verlag KG, 2010. http://dx.doi.org/10.1055/sos-sd-129-00093.
Reißig, H. U. "Donor-Acceptor-Substituted Cyclopropanes: Versatile Building Blocks in Organic Synthesis". In Small Ring Compounds in Organic Synthesis III, 73–136. De Gruyter, 1987. http://dx.doi.org/10.1515/9783112597521-004.
Atti di convegni sul tema "Donor-Acceptor cyclopropane":
Chagarovskiy, Alex, Olga Ivanova e Igor Trushkov. "Donor-acceptor cyclopropanes with nucleophilic group at ortho-position of donor aromatic substituent". In PROCEEDINGS OF INTERNATIONAL CONFERENCE ON RECENT TRENDS IN MECHANICAL AND MATERIALS ENGINEERING: ICRTMME 2019. AIP Publishing, 2020. http://dx.doi.org/10.1063/5.0018466.