Tesi sul tema "Diel cycle"
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Currie, Rebecca J. (Rebecca Jean). "Upper and Lower Temperature Tolerances of Three Freshwater Game-Fish Species Exposed to Cycling Temperatures". Thesis, University of North Texas, 1995. https://digital.library.unt.edu/ark:/67531/metadc279105/.
Testo completoPapadopoulou, Sofia. "The influence of diel cycles on the bacterial community composition of two boreal lakes : A case study in Jämtland". Thesis, Uppsala universitet, Limnologi, 2021. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-447209.
Testo completoBarkdull, Natalie Shepherd. "Impacts of Glacial Meltwater on Geochemistry and Discharge of Alpine Proglacial Streams in the Wind River Range, Wyoming, USA". BYU ScholarsArchive, 2019. https://scholarsarchive.byu.edu/etd/8590.
Testo completoGrácio, Ana Rita Pereira. "Diel variation in movement patterns and habitat use by the near-threatened cabrera vole in mediterranean farmland". Master's thesis, Universidade de Évora, 2016. http://hdl.handle.net/10174/18612.
Testo completoNeves, Leonardo Mitrano. "Estrutura e diversidade das assembleias de peixes recifais na Ba?a da Ilha Grande: import?ncia de vari?veis f?sicas, da estrutura do habitat e varia??es temporais de curto prazo". Universidade Federal Rural do Rio de Janeiro, 2013. https://tede.ufrrj.br/jspui/handle/jspui/2485.
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Conselho Nacional de Desenvolvimento Cient?fico e Tecnol?gico - CNPQ
Rocky reef fish assemblages change along extreme environmental conditions gradients; both spatial (across gradients of distance from the river mouths) and short term temporal (diel cycle of light intensity). Moreover, changes in connection to habitat heterogeneity can occur, even for tropical rocky reefs with a more homogenous habitat structure. Knowledge of the way that fish assemblages respond to these changes is fundamental to identify the variables that determine spatial patterns and to predict how impacts in great or low intensity can affect diversity. The main aims of this study were: (1) to determine influence of physical (distance from river mouth and wave exposure), biological (benthic cover) and structural (substratum height and number of shelters) variables in structuring fish assemblages, species richness, abundance, biomass and trophic groups diversity; (2) to assess diel changes in composition and structure of fish assemblages; (3) to relate changes in species composition (beta diversity) with habitat heterogeneity for a small scale (among transects in a given area), and the relationship between beta and alfa diversity (species richness, richness estimation and Shannon diversity). Subaquatic visual census were carried out in Ilha Grande coastal reefs, encompassing (1) islands distributed along a spatial gradient of distance from river mouth; (2) six different time periods, i.e., sunrise (06:00h), morning (08:30h), afternoon (14:00h), sunset (17:30h), early night (19:30h) and night (21:00h) in two shallow coastal reef; and (3) in transect in four areas to assess beta biodiversity. Habitat structure (benthic cover and topographic complexity) assessment was performed (objectives 1 and 3). The distance from river mouth explained from 12.4% to 38.2% of the estimated components of variation (ECV) of PERMANOVA for all analyzed response variables, playing a major role in determining spatial patterns of fish assemblages. Differences between reefs close and far from river mouth reached a maximum of 4.5x for richness, 11x for biomass and 10x for abundance. The substrate height was positively related to fish abundance, species richness and trophic groups diversity (ECV between 7.3 % and 17.4%), whereas the number of shelters was positively associated to small-sized species abundance such as Stegastes fuscus, Emblemariopsis signifer and Scartella cristata. Benthic cover had significant influence to determine spatial pattern in fish assemblage structure and diversity of trophic groups (ECV = 8% and 10%, respectively), but not in species richness, biomass and fish abundance. Wave exposure had significant influence on fish assemblage structure only (ECV = 10%). The fish assemblage changes drastically along diel cycle. Species richness and fish abundance were at the highest during the period of the day with intermediary values at twilight periods, and at the lowest during the night. The highest difference in assemblage structure was found between the periods of the day and the night. The families Sciaenidae, mainly represented by Pareques acuminatus, and Pempheridae represented by Pempheris schomburgkii were more abundant during the night, whereas Haemulidae Haemulon steindachneri, Pomacentridae Abudefduf saxatilis, Chaetodondidae Chaetodon striatus, and Labrisomidae Malacoctenus delalandii were more abundant during the day. The twilight periods were similar in assemblage structure, and had as characteristics species of the day (H. steindachneri, M. acutirostris) and the night (P. acuminatus), reflecting a transitional period. Significant positive relationship was detected between habitat heterogeneity and beta diversity. The area with more ix homogeneous habitat and low variation in fish assemblage was dominated by little threedimensionally complex organisms (zoanthids), while areas that had fleshy algae, turf and zoanthids with a more even percentage cover had higher heterogeneity and beta diversity. For all measures of examined alfa diversity, the area with more heterogeneous habitat and with the highest beta diversity had the highest alfa diversity compared with areas with more homogenous habitat e lowest beta diversity. However, positive relationship between alfa and beta diversity was significant for species richness, but not for estimate of richness and Shannon index. This study demonstrated that changes in assemblages in spatial and short term (from transects to 10 km, and diel cycle) scales may be attributed to changes in local habitat structure, both composition of dominant benthic organisms and habitat heterogeneity and can be associated to behavioral characteristics mainly related to strategies of food acquirement and protection against predation
As assembleias de peixes recifais variam atrav?s de gradientes de mudan?as extremas nas condi??es ambientais, tanto espaciais (ao longo de gradientes de dist?ncia da foz de rios) quanto em escalas temporais curtas (ao longo do ciclo di?rio de intensidade luminosa). Al?m disto, varia??es em resposta ao n?vel de heterogeneidade do habitat tamb?m podem ocorrer, mesmo entre recifes rochosos situados fora de intensos gradientes ambientais. Entender como as assembleias de peixes respondem a tais mudan?as ? fundamental para identificar vari?veis determinantes dos padr?es espaciais e predizer como impactos de grande e pequena intensidade podem afetar os padr?es de diversidade. Os principais objetivos deste estudo foram: (1) determinar a influ?ncia de vari?veis f?sicas (dist?ncia da foz do rio e exposi??o a ondas), biol?gicas (cobertura b?ntica) e estruturais (altura do substrato e n?mero de ref?gios) na estrutura??o das assembleias de peixes, riqueza de esp?cies, abund?ncia, biomassa e diversidade dos grupos tr?ficos; (2) avaliar as mudan?as ao longo do ciclo di?rio na composi??o e estrutura da assembleia de peixes recifais; (3) relacionar a varia??o na composi??o de esp?cies (beta diversidade) com a heterogeneidade do habitat, para uma pequena escala (entre transectos de uma mesma ?rea), e as rela??es entre a beta diversidade e medidas de diversidade alfa (riqueza de esp?cies, estimativa da riqueza e diversidade de Shannon). Para tal, censos visuais subaqu?ticos foram realizados (1) em cost?es rochosos da ba?a da Ilha Grande, em ilhas localizadas atrav?s de um gradiente de dist?ncia da foz de rios; (2) em seis diferentes hor?rios, compreendendo o amanhecer (06:00h), manh? (08:30h), tarde (14:00h), anoitecer (17:30h) e in?cio da noite (19:30h) e noite (21:00h) em dois recifes rochosos rasos; e (3) em transectos de quatro ?reas para avaliar diversidade beta. Avalia??es da estrutura do habitat (cobertura b?ntica e complexidade topogr?fica) foram realizadas (para objetivos 1 e 3). A dist?ncia da foz do rio explicou entre 12,4% a 38,2% da estimativa dos componentes de varia??o (ECV) da PERMANOVA de todas as vari?veis respostas analisadas, desempenhando um papel principal nos padr?es espaciais da assembleia de peixes. Diferen?as entre recifes pr?ximos e distantes da foz atingiram um m?ximo de at? 4,5x para a riqueza, 11x para a biomassa e 10x para a abund?ncia. A altura do substrato foi positivamente relacionada com a abund?ncia de peixes, riqueza de esp?cies e diversidade dos grupos tr?ficos (ECV entre 7,3% a 17,4%), enquanto o n?mero de ref?gios foi associado positivamente com a abund?ncia de esp?cies de pequeno porte, como Stegastes fuscus, Emblemariopsis signifer e Scartella cristata. O efeito da cobertura b?ntica foi significativo em determinar os padr?es espaciais da estrutura da assembleia de peixes e da diversidade dos grupos tr?ficos (ECV = 8% e 10%, respectivamente), por?m n?o foram observadas influ?ncias significativas da cobertura b?ntica na riqueza de esp?cies, biomassa e abund?ncia. A exposi??o ?s ondas teve um efeito significativo apenas para a estrutura da assembleia de peixes (ECV = 10%). As assembleias de peixes variaram drasticamente ao longo do ciclo di?rio. A riqueza de esp?cies e a abund?ncia de peixes foram maiores durante os hor?rios do dia, com valores intermedi?rios nos hor?rios crepusculares e atingiram os menores valores durante a noite. Maiores diferen?as na estrutura da assembleia foram observadas entre o per?odo diurno e noturno. Durante a noite, as fam?lias Sciaenidae, representado por Pareques acuminatus, e Pempheridae vii representado por Pempheris schomburgkii foram mais abundantes, enquanto Haemulidae Haemulon steindachneri, Pomacentridae Abudefduf saxatilis, Chaetodondidae Chaetodon striatus, e Labrisomidae Malacoctenus delalandii foram abundantes durante o dia. Os hor?rios crepusculares foram semelhantes entre si, sendo caracterizados por esp?cies tanto dos hor?rios do dia (H. steindachneri, M. acutirostris) quanto da noite (P. acuminatus), refletindo esse per?odo de transi??o. Rela??es positivas significativas foram detectadas entre a heterogeneidade do habitat e a beta diversidade. A ?rea com habitat mais homog?neo e de menor varia??o na composi??o da assembleia foi dominada por organismos tridimensionalmente pouco complexos (zoant?deos), enquanto a ?reas que apresentaram algas frondosas, matriz de algas epil?ticas (MAE) e zoant?deos com uma percentagem de cobertura mais equitativa, tiveram a maior heterogeneidade do habitat e beta diversidade. Para todas as medidas de diversidade alfa utilizadas, a ?rea com habitat mais heterog?neo e com maior beta diversidade, apresentou uma diversidade alfa maior do que a ?rea com habitat mais homog?neo e de menor beta diversidade. Entretanto, as rela??es positivas entre a beta diversidade e a diversidade alfa foram significativas apenas para a riqueza de esp?cies, e n?o para a estimativa da riqueza e a diversidade de Shannon. Este estudo demonstrou que varia??es nas assembleias em escalas espaciais e temporais curtas (desde entre transectos at? 10 km, e ao longo do ciclo di?rio) podem ser atribu?das a mudan?as na estrutura dos habitats locais, tanto na composi??o dos organismos bent?nicos dominantes quanto na heterogeneidade do habitat e podem ser associadas a caracter?sticas comportamentais principalmente associadas a estrat?gias de obten??o de alimento e prote??o contra preda??o
Giron, Aline Karen Santana. "Variaçãos sazonal e migração vertical da comunidade zooplanctônica (exceto Rotifera) do reservatório de Itupararanga, Votorantim, SP". Universidade Federal de São Carlos, 2013. https://repositorio.ufscar.br/handle/ufscar/1528.
Testo completoThe present study aimed to analyse the Itupararanga reservoir zooplankton community in relation to diel and seasonal variation and vertical migration of the organisms in the water column and verify if there are patterns of variation. For this two samples were performed in the reservoir in 2011: in February, rainy period and in july, dry period. The collections were performed in diel cycle (every four hours), in three different layers of the water column (surface, middle and bottom) and in two environments of the reservoir (dam and central body). Stratification in the water column was observed for both environments and both periods. 25 species of the mesozooplankton were identified. Chaoborus larvae were more abundant in February in relation to july and the opposite was observed for cladocerans and copepods. Among the copepods, dominance of juvenile stages (nauplii and copepodites) was observed in both environments and periods. Among the adults of copepods the specie more abundant was Notodiaptomus deitersi (1.298 org.m3) and among the cladocerans was Bosmina freyi (32.282 org.m3). The peak of the total density of the zooplankton community occurred during the dry period in the dam environment with 81.211 org.m3. Chaoborus exercised predation pressure on microcrustaceans during the rainy period. During the dry period, in the absence of Chaoborus in the water column, cladocerans and copepods were more ecologically successful. For all of the groups was observed the usual pattern of vertical migration; reverse migration was not observed. Despite predation pressure, the microcrustaceans not altered their vertical distribution for decrease special overlap with Chaoborus. For all of the groups the migration pattern adopted seems a result of escape from predators and search for good food resources.
O presente estudo teve como objetivo analisar a comunidade zooplanctônica do reservatório de Itupararanga com relação à variação nictemeral, sazonal e migração vertical dos organismos na coluna de água e verificar a existência de padrões de variação. Para isto foram realizadas duas coletas no reservatório no ano de 2011: em fevereiro, período chuvoso e em julho, período seco. As coletas foram realizadas no ciclo nictemeral (de 4 em 4 horas), em três diferentes estratos da coluna de água (superfície, meio e fundo) e em dois pontos do reservatório (barragem e corpo central). Foi observada estratificação na coluna de água para ambos os pontos e em ambos os meses. Foram identificadas 25 espécies do mesozooplâncton. Larvas de Chaoborus spp. foram mais abundantes em fevereiro com relação a julho sendo o contrário observado para Cladocera e Copepoda. Entre os Copepoda observou-se dominância dos estágios juvenis (náuplios e copepoditos) para ambos os pontos e em ambos os períodos. Entre os adultos a espécie de Copepoda mais abundante foi Notodiaptomus deitersi (1.298 org.m3) e entre os Cladocera a espécie mais abundante foi Bosmina freyi (32.282 org.m3). O pico de densidade total da comunidade zooplanctônica ocorreu durante o período seco no ponto da barragem com 81.211 org.m3. Chaoborus exerceu pressão de predação sobre os microcrustáceos durante o período chuvoso. Durante o seco, na ausência de Chaoborus na coluna de água, foi observado maior sucesso ecológico para Cladocera e Copepoda. Para todos os grupos foi observado o padrão comum de migração vertical; migração reversa não foi observada. Apesar da pressão de predação, os microcrustáceos não ajustaram sua distribuição vertical de forma a diminuir a sobreposição espacial com Chaoborus. Para todos os grupos considerados o padrão de migração adotado parece ter sido resultado da fuga de predadores e busca por boas condições alimentares.
Verspecht, Florence. "Temporal dynamics of the coastal water column". University of Western Australia. School of Environmental Systems Engineering, 2008. http://theses.library.uwa.edu.au/adt-WU2008.0097.
Testo completoGoebel, Patrick C. "Distribution, Abundance and Movement of Fish among Seagrass and Mangrove Habitats in Biscayne Bay". NSUWorks, 2016. http://nsuworks.nova.edu/occ_stuetd/403.
Testo completoVaughan, Chester Dewey. "Cycle-to-cycle control of reconfigurable die sheet metal forming". Thesis, Massachusetts Institute of Technology, 2004. http://hdl.handle.net/1721.1/17953.
Testo completoIncludes bibliographical references (leaves 85-86).
This research addresses cycle to cycle control as applied to a sheet metal stretch forming process. More specifically, it attempts to validate the use of cycle to cycle (CtC) control for a multiple input-multiple output process. The work presented in this thesis attempts to answer some basic manufacturing questions. The first is, "Can a multivariable discrete system control theory be used to model a sheet metal shape control process?" The second question is, "Does such a "cycle to cycle control system provide a significant improvement over the present industry standard control methods". To address these questions, CtC control methods are applied to a reconfigurable die stretch forming process. The theoretical foundation of the stretch forming process is presented. Several open and closed loop control methods are discussed. A methodology for evaluating the part quality is defined in terms of the process mean shift and variance. The system dynamics are presented in terms of unwanted process disturbances. In-depth experiments are then performed to quantify the process performance under CtC control. The CtC process yield is compared the process yield of an identical process under open loop control using the Expected Quality Loss Function. It is shown that implementation of the reconfigurable die under CtC control eliminates the process mean shift but increases the part variation. It is also shown that CtC control produces the highest yield of acceptable parts.
by Chester Dewey Vaughan, IV.
S.M.
Meier, Fabian. "Solar thermochemical cycle for ammonia production based on aluminium-based redox reactions". Zürich : Eidgenössische Technische Hochschule, 2007. http://e-collection.ethbib.ethz.ch/show?type=dipl&nr=310.
Testo completoZimmerli, Urs. "Limit cycles in homogeneous azeotropic distillation". Zürich : ETH, Eidgenössische Technische Hochschule Zürich, 2001. http://e-collection.ethbib.ethz.ch/show?type=dipl&nr=15.
Testo completoRoberts, Michael John, e edu au jillj@deakin edu au mikewood@deakin edu au wildol@deakin edu au kimg@deakin. "A Modified Life Cycle Inventory of Aluminium Die Casting". Deakin University. School of Engineering and Technology, 2003. http://tux.lib.deakin.edu.au./adt-VDU/public/adt-VDU20040825.110759.
Testo completoIkeme, Patience Obianuju. "Human ecological stress and menstrual function". Thesis, University of Cambridge, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.360734.
Testo completoAdams, Barbara Ann Nieland. "The effect of the human menstrual cycle on kilocalorie and nutrient intake". Thesis, Virginia Tech, 1985. http://hdl.handle.net/10919/45580.
Testo completoKilocalorie, protein, fat and carbohydrate intakes of five women were examined during the period of at least one menstrual cycle. Kilocalorie intake was significantly lower in the periovulatory phase of the cycle compared to the midluteal phase (t=2.10, p <.05). Carbohydrate and fat intakes were higher, although not significantly, during the midluteal phase compared to the periovulatory phase. Mean intake was 85 kilocalories higher in the postovulatory phase compared to preovulatory, but the difference was not significant. Mean carbohydrate and fat intakes were also increased, but not significantly, in the postovulatory phase. Protein intakes remained relatively stable when phases of the cycle were compared. A spectral analysis of variance produced two cycles showing monophasic sine component variations. Protein intake had a significant monophasic variation in two cycles; fat and carbohydrate had significant monophasic variation in one cycle each. The period of two to four days contained the most often significant sine components (10) and the period of five to seven days was next with five significant values.
Master of Science
Hischier, Illias. "CO₂ splitting via a solar thermochemical cycle based on Zn/ZnO redox reactions: thermodynamic and kinetic analysis". Zürich : ETH, Swiss Federal Institute of Technology Zurich, Institute of Energy Technology, 2008. http://e-collection.ethbib.ethz.ch/show?type=dipl&nr=360.
Testo completoSieti, Natalia. "Life cycle environmental and economic sustainability in the baby food sector". Thesis, University of Manchester, 2018. https://www.research.manchester.ac.uk/portal/en/theses/life-cycle-environmental-and-economic-sustainability-in-the-baby-food-sector(f098fc2e-6148-443c-b374-16fb506730d3).html.
Testo completoMcGinnis, Amanda Anne. "Effects of menstrual cycle phases and dietary behavior on threshold and preference for sucrose". Thesis, Virginia Polytechnic Institute and State University, 1989. http://hdl.handle.net/10919/54379.
Testo completoMaster of Science
Tavakoli, Shahab. "Modélisation du cycle thermique des moules de fonderie sous pression". Thesis, Paris 10, 2014. http://www.theses.fr/2014PA100095.
Testo completoReducing the weight of vehicles, specially the powertrain Group, contributes to the reduction of the emissions. Today, in order to achieve this objective, the automobile parts conception (Housing gear box, Cylinder block) in lightweight materials such as aluminum and its alloys is increasing. For the mass production, aluminum alloys are formed by a foundry process called ‘’High Pressure Die Casting’’.This process uses the metal molds. Control the thermal behavior of the mold : Heating, intern cooling (by circuit) and extern cooling, is a key point to ensure castings quality and rate of production.In this thesis, the industrial process has been detailed since the mold closing and aluminum melting injection in the die, to the mold opening time and the part (Gearbox RENAULT) ejection. Then, the mold design details, different generation of the cooling systems and the parameters of each step of the manufacturing process taking into account the actual cooling system are presented. The actual cooling systems in the dies are positioned today in empirical way. The ultimate goal of this thesis is to provide the key elements for the cooling system conception from the thermal behavior point of view. For this one, a complete modeling of the phenomena has been realized and validated by 8 thermocouples and the cooling system position has been defined from the thermal equations. The thermal cycle of the die has been optimized and allowed us to reduce and homogenize the temperature fields on the die surface during the production. The rate of production, the castings quality and the lifetime of the die have been consequently increased
Haussener, Sophia. "Efficiency calculations and optimization analysis of a solar reactor for the high temperature step of the zinc/zinc-oxide thermochemical redox cycle". Zürich : ETH, Eidgenössische Technische Hochschule Zürich, Departement Maschinenbau und Verfahrenstechnik, 2007. http://e-collection.ethbib.ethz.ch/show?type=dipl&nr=331.
Testo completoMatasci, Cecilia. "Life cycle assessment of 21 buildings: analysis of the different life phases and highlighting of the main causes of their impact on the environment". Zürich : ETH, Eidgenössische Technische Hochschule Zürich, 2008. http://e-collection.ethbib.ethz.ch/show?type=dipl&nr=381.
Testo completoPowell, Thomas William Robert. "Closing loops to rebalance the global carbon cycle : biomass flows modelling of global agricultural carbon fluxes". Thesis, University of Exeter, 2015. http://hdl.handle.net/10871/18699.
Testo completoHock, Florian. "Point-in-time vs. through-the-cycle : Berücksichtigung zyklischer Effekte in der Kreditrisikosteuerung". Hamburg Diplomica Verlag, 2008. http://www.wiso-net.de/r%5Febook/webcgi?START=A60&DOKV%5FDB=DIPL,ADIP&DOKV%5FNO=978383660749068&DOKV%5FHS=0&PP=1.
Testo completoJarvis, Toby. "The vertical export of carbon and nitrogen caused by zooplankton diel vertical migration". Thesis, Open University, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.272958.
Testo completoWang, Bin. "The prediction of low cycle fatigue for die casting with FEM". Thesis, National Library of Canada = Bibliothèque nationale du Canada, 2001. http://www.collectionscanada.ca/obj/s4/f2/dsk3/ftp04/MQ57753.pdf.
Testo completoMallek, Hichem. "Les réseaux biodégradables autocicatrisants utilisant des monomères biosourcés par réactions de Diels-Alder". Thesis, Saint-Etienne, 2013. http://www.theses.fr/2013STET4019.
Testo completoThe aim of this thesis is to elaboration of the thermoreversible elastomers networks. These polycaprolactone-based networks (PCL-based networks), most of which of the constituents from biomass, will have the particularity of being recyclable and biodegradable
Gostner, Walter. "Integrale Analyse eines murfähigen Wildbaches anhand einer Fallstudie Integral analysis of a debris flow in an alpine torrent based on a case study : Schlussbericht, Cycle d'études postgrade en aménagements hydrauliques 1999 - 2002 /". Zürich : ETH, Eidgenössische Technische Hochschule Zürich, Versuchsanstalt für Wasserbau, Hydrologie und Glaziologie (VAW), 2002. http://e-collection.ethbib.ethz.ch/show?type=dipl&nr=78.
Testo completoText dt., ital. und engl. Zus.fassung. Abschlussarbeit zum Nachdiplomstudium in hydraulischen Anlagen an der EPFL (École polytechnique fédérale de Lausanne). Die Betreuung der Arbeit ist an der Versuchsanstalt für Wasserbau, Hydrologie und Glaziologie (VAW) der ETH Zürich erfolgt.
Krause, Marcus. "Environmental Life Cycle Costing (ELCC) für Produkte der Solarenergie: Die Verbindung von Life Cycle Assessment (LCA) und Life Cycle Costing (LCC) - from Cradle to Grave - angewandt auf die Photovoltaik. Anforderungen bei der Durchführung und aktueller Stand in der Praxis". Technische Universität Dresden, 2011. https://tud.qucosa.de/id/qucosa%3A26141.
Testo completoThe special need of a sustainable energy supply in mind the technologies of the renewable source solar energy, especially photovoltaics (PV) is main subject of the present thesis. Using the inexhaustible, clean and “freely delievered” power from the sun solar devices may play a major role in a cleaner future, but, on the other hand, they are still energy consuming and expensive in their production which consequently demands a whole life cycle perspective when assessing this technology. For a closer look at PV the methodology of Environmental Life Cycle Costing (ELCC) is introduced by following three theoretical points of view. Namely these are sustainability, life cycle thinking and the three dimensional nature of this tool by regarding environmental, economic and technical aspects in their interaction. Based on theoretical elements of Life Cycle Assessment and Life Cycle Costing in combination with the technical background of photovoltaics main requirements and steps for performing an ELCC for PV are described. By executing software based content analysis the defined framework is checked (and modified) against a choice of 135 existing studies analyzing the life cycle of PV technologies from an environmental or economic perspective. As a result the main elements of an ELCC for PV, e.g. environmental impact categories and economic indicators, are identified (methodological feedback). Within the next step the existing studies are rated by their “quality” regarding the environmental, economic and more general parts of an ELCC for PV in order to create an inventory of life cycle studies for PV. This inventory is structured by technologies as well as quality of content respecting ELCC and might be used for further analyses. At this stage the results propose the possibility of a first estimate of the present status of ELCC for PV: until now there is a good pool of existing analyses of the life cycle of PV systems. But from an ELCC perspective the examination of common hot spots and trade offs between economic and environmental aspects should be expanded. The theoretical framework of ELCC for PV, the encoded studies and the inventory of life cycle analyses for PV are now the starting point for further analyses, especially of the individual outcome within studies, which will then pose a benchmark for new life cycle studies of PV technology.
Michel, Servane. "Fortune, Providence et liberté : une lecture augustinienne du cycle arthurien en prose". Thesis, Paris 4, 2014. http://www.theses.fr/2014PA040026.
Testo completoArthurian history is eschatological : the prose cycle drive it from evangelical times to the end of king Arthur's reign. With the Grail theme, narratives links their contemporary world straight to Sacred History and claims for a kind of prophetical authority. This scheme may be interpreted according to The City of God, where Augustine reads both Scripture and profane history. Through his exegesis he intends to show the action of providence and the process of salvation in human history. The prose romances themselves end in salvation : after King Arthur's fall and the destruction of chivalry, the last word is given to conversion – Lancelot's soul is taken to Paradise, after Gawain's one. For those excellent knights La Mort Artu should be read as an apocalypse, not only in the sense of punishment – La Queste had condemned the Arthurian world as « terrien » – but also as a "revelation" : profane heroism is identified to the highest Christian desire. The well-known presence of Fortune in La Mort Artu takes another sense : in personal or collective calamities, this character points out either the moral scandal or the irrational aspect of their causes. With Fortune, aventure and mescheance also relay Christian language to narrate the unexplainable. Prose romances betray Augustine's precepts : The City of God forbade the use of Fortune or similar terms that contradict the Christian faith. But in Arthurian romances providentialism is nonetheless present and proclaimed. In that "Age of Faith", the proper language of romance expresses the tragical aspects of human existence, and either lead to an eternal destiny, in the act of faith, or stay in the horizon of the terrestrial city
Janoco, Martin. "Evaluating the sustainability of vegetarian, vegan, and New Nordic diets in Sweden : Combining environmental and nutritional aspects". Thesis, KTH, Hållbar utveckling, miljövetenskap och teknik, 2019. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-260278.
Testo completoAtt ändra det västerländska kostmönstret mot en hälsosammare diet med minskat intag av animaliska livsmedel är en allmänt erkänd strategi i den pågående ansträngningen för global hållbarhet. Eftersom djurfoder tenderar att ha stor miljöpåverkan, är vegetariska dieter ofta föreslagna som ett ekologiskt alternativ till den typiska västerländska kosten. Den låga summan av miljöpåverkan innebär emellertid inte nödvändigtvis att det är en hållbar diet. Hållbarhet omfattar många andra aspekter, såsom näringskrav, överkomlighet och kulturell acceptans. När det gäller avskaffandet av animaliska livsmedel bör i synnerhet hälsorelaterade aspekter beaktas eftersom vissa näringsämnen levereras primärt via animaliska produkter vilket kan leda till näringsbrist och potentiellt negativa hälsoeffekter på lång sikt. Eftersom dietens huvudsakliga funktion är tillförseln av (tillräcklig) näring, borde miljöpåverkan av dieter jämföras med hänsyn till deras näringskvalitet. I detta projekt bedöms miljöpåverkan med avseende på klimatförändringar, markanvändning, blått blåvattenavtryck och biologisk mångfaldskador för fyra dieter tillsammans med deras näringsbehov och ekonomiska kostnader. De fyra bedömda kostvanorna är: en genomsnittlig svensk diet, ny nordisk kost, vegetarisk kost och vegansk kost. Miljöpåverkan normaliseras med ett näringsrikt diettvärde (NRD) för att jämföra effekterna av dieter i förhållande till deras näringskvalitet. Vegansk diet, följt av vegetarisk kost, resulterade i den lägsta övergripande effekten, med undantag för blå vattenavtryck, men normaliseringen med NRD-poäng minskade de relativa skillnaderna mellan den nya nordiska, vegetariska och veganska dieterna. Vidare visade näringsvärderingen ett potentiellt ohållbart intag av vitamin D för vegetarianer och vit. D och B12 för veganer, vilket inte korrekt återspeglas I det näringsmässiga kvalitetsresultatet. Ändå är användningen av näringsvärdet ganska enkelt och ger möjlighet att koppla den hälsorelaterade aspekten av dieter till deras miljöpåverkan. Genom att kombinera indikatorer för andra hållbarhetsaspekter, såsom den ekonomiska, kan denna metod erbjuda en mer holistisk bild av dieters hållbarhet.
Brisse, Julien. "Valorisation de la lignine par incorporation dans les polyesters aliphatiques". Electronic Thesis or Diss., Sorbonne université, 2018. https://accesdistant.sorbonne-universite.fr/login?url=https://theses-intra.sorbonne-universite.fr/2018SORUS504.pdf.
Testo completoThis work was devoted to the synthesis and the characterization of copolyesters derived from an organosolv wheat straw lignin extracted using the CIMV pulping process. A basic hydrolysis step followed by organic washes yielded a purified lignin that was then chemically modified by esterification or etherification of its reactive functions using triethylene glycol, chlorinated methoxyalkanes, haloalcohols or 1-bromotetradecane. The resulting samples exhibit homogeneous reactive functions, mainly composed with aliphatic alcohols. Their solubility within usual organic solvents is improved, especially using bromoalcane. Their aliphatic hydroxy functions were then used to initiate the ring opening polymerization of ε-caprolactone, in bulk or in solution, between 25 et 150°C, using stannous(II) ethylhexanoate or 1,5,7-triazabicyclo[4.4.0]dec-5-ene as a catalyst. This led to partially cross-linked systems due to side reactions of esterification, transesterification and etherification. To get around this problem, monofunctional poly(ε-caprolactone) (PCL) oligomers bearing an acyl chloride (COCl) end group was grafted onto triethylene glycol-modified lignin (Lp-TEG) with a COCl/OH ratio from 0.25 to 0.70. This led to thermoplastic copolyesters (Mn = 7000 to 12300 g/mol) incorporating up to 60% of lignin in their structure. Those ones are soluble within common solvents and show upgraded thermal stability compared to the starting materials. Adapted from this method, a difonctional PCL oligomer bearing COCl end groups and two Diels-Alder adducts per macromolecule was then grafted onto Lp-TEG. This led to a lignin based innovative 3D PCL network which is soluble in DMSO at 120°C after retro Diels-Alder reaction. All of the synthesized products were characterized by suitable analytical techniques (NMR, SEC, TGA, DSC, FTIR)
Miles, Lana. "Die toepassing van projekbestuursbeginsels in die proses van plaasarbeiderbemagtiging / L. Miles". Thesis, North-West University, 2004. http://hdl.handle.net/10394/482.
Testo completoThesis (M. Ontwikkeling en Bestuur)--North-West University, Potchefstroom Campus, 2005.
Dudic, Dalibor [Verfasser]. "Modell für die Fabrik-Life-Cycle-orientierte Produktplanung und -entwicklung / vorgelegt von Dalibor Dudic". Heimsheim : Jost-Jetter, 2010. http://d-nb.info/1010696564/34.
Testo completoStinson-Bagby, Kelly Lucile. "Microstructural Evolution in Thermally Cycled Large-Area Lead and Lead-Free Solder Joints". Thesis, Virginia Tech, 2002. http://hdl.handle.net/10919/34573.
Testo completoMaster of Science
Schneider, Arne. "Die strategische Planung des Produktportfolios bei Automobilherstellern : Konzeption eines Instruments zur Bewertung des Cycle-Plans /". Baden-Baden : Nomos, 2006. http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&doc_number=015410314&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA.
Testo completoTrautheim, Andreas. "Digitale Transformation zurück in die Zukunft [Präsentationsfolien]". Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2016. http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-214129.
Testo completoLeite, Pedro Terra. "História natural de Mastigodryas bifossatus (Serpentes, Colubridae) em domínio subtropical no Brasil". Universidade Federal de Santa Maria, 2006. http://repositorio.ufsm.br/handle/1/5249.
Testo completoMastigodryas bifossatus is a large snake in the Colubrinae subfamily. It s widely distributed in open areas over the entire South America. The dissection of 224 especimens of this snake, proceeding from the southern states of Rio Grande do Sul, Santa Catarina and Paraná, stored in herpetological colections in Brazil, provides information on dietary habits, habitat use, daily and seazonal activities, sexual dimorphism and reproductive cycles of this snake in subtropical domains in Brazil. This snake eats mainly amphibians of the Leptodactylidae´s family (80%), mammals (10%) and lizards (2%). Eight percent of the items found could not be identified. There is no ontogenetic diet shift in M. bifossatus, but as the snake grows larger, the range of preys grow as well. Most specimens inhabit open areas during the day. The activity patterns are seazonal and unimodal. Adult specimens of M. bifossatus can reach average of 1115 mm in snout-vent-lenght, and female snakes are slightly bigger than male snakes. The reproductive cycle of females is seazonal, with vittelogenesis occuring from july on. Egg laying has been recorded from november to january. The average number of offsprings per clutch is 14 and there is positive correlation between clutch size and female lenght.
Mastigodryas bifossatus é uma serpente de grande porte pertencente à subfamília Colubrinae, família Colubridae. É distribuída ao longo de grande parte da América do Sul, onde vive em áreas abertas. A dissecação de 224 espécimes desta serpente provenientes dos estados do Rio Grande do Sul, Santa Cataria e Paraná, depositados em coleções herpetológicas no Brasil, proveram dados sobre hábitos alimentares, uso do substrato, atividade diária e sazonal, dimorfismo sexual, comprimento corporal e ciclo reprodutivo desta serpente em domínio subtropical no Brasil. Esta espécie alimenta-se preferencialmente de anfíbios da família Leptodactylidae (80%), seguido de mamíferos (10%) e lagartos (2%). Não há mudança ontogenética na dieta de M. bifossatus, mas há um aumento na gama de presas à medida que esta serpente atinge comprimentos corporais maiores. É uma serpente diurna que habita áreas abertas. A atividade é sazonal, com padrão unimodal. Os exemplares adultos de M. bifossatus atingem em média 1115 mm de comprimento rostro - cloacal, sendo as fêmeas um pouco maiores que os machos. O ciclo reprodutivo das fêmeas é sazonal, com vitelogênese ocorrendo a partir do mês de julho. Oviposições foram registradas de novembro a janeiro. O número médio de filhotes por ninhada é 14 e há correlação positiva entre o tamanho da ninhada e o comprimento das fêmeas.
Xu, Zhanjie. "Nouvelle synthèse de dérivés hétérocycliques thiazoliques, sélénazoliques, coumariniques, thiocoumariniques et quinolonéiques. Étude et évaluation de leur activité potentielle anticancéreuse". Thesis, Université de Lorraine, 2014. http://www.theses.fr/2014LORR0079/document.
Testo completoWe performed the synthesis of thiazoles, selenazoles, thieno[2,3-d]thiazoles and thieno[2,3-d][1,3] selenazoles which are easily prepared from cyanamide and carbon disulfide. By this way, we have synthesized 4-amino-1,3-thiazoles et 1,3-selenazoles substituted in position 2 and 5 in two steps. Used these heterocycles, 4-halogeno-1,3-thiazoles et 1,3-selenazoles were synthesized by Doyle’s method. Lability of halogens in previous derivatives allowed to prepare new thieno[2,3-d]thiazoles and [1,3]selenazoles. Determination of the antiproliferative activity of these compounds has brought out two compounds, showing IC50 values in micromolar range on investigated cancer cell lines: MCF-7, PC-3, Hs683, U373, SKMEL-28, and A549. One particular compound showed a high activity of anti-Na+/K+-ATPase and anti-ROS. In addition in the second subject, we were interested in the development of the synthesis of two isomers (alpha and beta) of 4-butoxylvinyl-coumarins, -thiocoumarin and -2-quinolones by Heck coupling. We showed that, depending on the substituent in the position 4 of the heterocycle, the coupling was regioselective. These butoxyvinylic derivatives, characterized by dienic character, were studied for their reactivity, stereoselectivity and regioselectivity with several dienophiles in Diels-Alder cycloaddition. Among all the polyheterocyclic compounds prepared, we have identified the tetracyclic compounds with quinonic ring which have potential anticancer activity by inhibition of CDC25 phosphatase and on several tumor cell lines
Matthee, Suzette. "The development of two-week menu cycles for households with children allergic to wheat, soy, cow's milk and egg respectively". Thesis, Stellenbosch : Stellenbosch University, 2002. http://hdl.handle.net/10019.1/53102.
Testo completoENGLISH ABSTRACT: Food allergies in children are a growing problem and have various effects on these children, their households, the community and the economy. No medication or cure is currently available to consumers suffering from food-allergies. Medical teams are aware of the patients' need for support, but information is lacking and understanding of their basic needs and problems neglected. Two qualitative research methods, namely the focus group technique and case studies were used to investigate the emotional and physical environment of children allergic to wheat, soy, cow's milk and egg respectively. Five focus group meetings were conducted with the caregivers of food-allergic children. Two during the pilot study and three in the main study. A total of twenty three participants attended the three meetings of the main study. A meeting schedule was developed and the meetings carefully moderated. After the data had been obtained from the focus group meetings, there was a need for more in-depth information and understanding. Seven of the participants of the focus groups were identified, through developed criteria, to be further investigated as case studies. Five units of investigation were identified for the case studies. It was the (i) caregiver, (ii) allergic child, (iii) other children, (iv) "non-caregiver parent" and (v) household. Some of the matters that were investigated in both the focus groups and case studies were health consciousness, menu planning, recipe needs and use, reading of food labels, hidden allergens and the social and emotional effects of having and being a food-allergic child. A great need for better support and educational programs to assist these households were identified. Very few of the households were health conscious, while they all experienced problems with menu planning, identifying hidden allergens and suffered from social and or emotional problems. Very few participants made use of recipes or identified a need for allergen-free recipes. After having gained insight in the daily lives of these households, four - virtually identical, two-week menu cycles were developed to suit the life style requirements and restrictions of these children. The same recipes were used, but allergens omitted, replacements made and the recipes adapted as necessary. Product scouting was done for hidden allergens in selected popular convenience foods, especially those from the lowest level of the USDA Food Guide Pyramid. Hidden allergens appeared to be a problem when food is prepared and bought for the food allergic child. It should be taken into account that despite the information stated on the food label undeclared allergens might still be present in food. The two-week menu cycle for the child allergic to cow's milk was then quantitatively evaluated for nutritional adequacy by FoodFinder ™ 2 - a software program, for children aged between seven and ten years. All the macronutrients and micronutrients identified by the National Survey in 1999 as insufficient «67% of the RDA) among South African children aged between one and nine years, were evaluated as well as those mentioned in the WHO Dietary and Health Goals. All the nutrients were sufficient, except for calcium and Vitamin D. Supplementation is advised. The sensory acceptability of the menu-items in the two-week menu cycles were not evaluated. A vast number of issues pertaining to the food-allergic child require further research. A great need exists for the development of educational programs to support the households with food-allergic children. The identification of hidden allergens and the development of reliable sensory testing models for food-allergic children are all areas that should urgently be researched further.
AFRIKAANSE OPSOMMING: Voedsel-allergieë by kinders is 'n groeiende probleem met 'n verskeidenheid effekte op dié kinders, hulle huishoudings, die gemeenskap en die ekonomie. Tans is geen medikasie of kuur teen voedsel-allergieë beskikbaar nie. Mediese spanne is bewus van die behoefte aan sorg en leiding wat deur dié spesifieke groep verbruikers benodig word, maar inligting oor hulle behoeftes en probleme is ontoereikend. Twee kwalitatiewe navorsingsmetodes, naamlik die fokusgroeptegniek en gevallestudies, is gebruik om die emosionele en fisiese omgewing van kinders allergies vir onderskeidelik grane, soja, melk en eiers te ondersoek. Tydens 'n voorloperstudie is twee fokusgroepvergaderings gehou. Vir die hoofstudie is drie fokusgroepvergaderings met versorgers van kinders met 'n voedsel-allergie gehou met 'n totaal van drie en twintig deelnemers. 'n Vergaderingskedule is ontwikkel en die vergaderings is sorgvuldig gemodereer. Nadat die data van die fokusgroepe ingesamel is, was daar behoefte aan meer in diepte inligting en begrip. Aan die hand van ontwikkelde kriteria is sewe van die deelnemers aan die fokus groepe as gevallestudies geselekteer. Vyf eenhede van ondersoek is geïdentifiseer vir die gevallestudies. Dit is: (i) die allergiese kind, (ii) versorger, (iii) ander kinders, (iv) die "nie-versorgende" ouer en (v) die huishouding. Sommige van die aspekte wat in beide die fokusgroepe en gevallestudies ondersoek is, was gesondheidsbewustheid, spyskaartbeplanning, die gebruik en behoefte aan resepte, lees van voedseletikette, verskuilde allergene en die sosiale en emosionele effek van 'n voedsel-allergie op die kind sowel as die ouers. 'n Groot behoefte aan beter ondersteuning en opvoedkundige programme, om hierdie huishoudings te help, is geïdentifiseer. Baie min van die huishoudings was werkilk gesondheidsbewus, terwyl hulle almal probleme met spyskaartbeplanning, identifisering van verborge allergene en sosioemosionele probleme ondervind het. Weinig van die deelnemers het gebruik gemaak van resepte of het 'n behoefte aan allergeen-vrye resepte ondervind. Nadat insig in die daaglikse lewenstyl van hierdie huishouding verkry is, is vier amper-identiese twee-weekse siklusspyskaarte ontwikkel wat die lewenstyl en behoeftes van hierdie huishoudings aanspreek. Dieselfde resepte was gebruik vir al vier twee-weeksiklusspyskaarte, met die verskil dat verskillende allergene vervang is, na gelang van die allergie verskillende behoefte. Marknavorsing is gedoen op alledaagse produkte en is hoofsaaklik gefokus op die produkte wat die basis van die voedselpiramide uitmaak. Daar is bevind dat verskeulde allergene voorkom in produkte waar dit nie verwag word nie, en soms selfs nie op die voedseletikette verklaar word nie. Die twee-weeksiklusspyskaart van die melk-allergiese kind is kwantitatief ge-evalueer vir toereikendheid van die dieet vir kinders tussen die ouderdomme sewe tot tien jaar op die Foodfinder TM 2 - sagteware program. Die makro- en mikronutriente wat volgens 'n nasionale opname in 1999 as problematiese «67% van die RDA) vir kinders in die ouderdomsgroep een tot nege, uitgewys is, is geneem en die voedingstowwe is ook teen die Werêld Gesondheidsorganisasie (WHO) se dieetdoelwitte getoets. AI die nutriënte was voldoende volgens die analise, behalwe kalsium en Vitamen D. Supplementasie word aanbeveel vir dié twee nutriënte. Die sensoriese aanvaarbaarheid van die spyskaartitems in die siklusspyskaart is nie getoets nie. Verskeie aspekte wat vorendag gekom het, benodig verdere navorsing. 'n Groot behoefte aan die ontwikkeling van opvoedkundige programme, wat die huishoudings met voedsel-allergiese kinders ondersteun, bestaan. Die identifikasie van verskuilde allergene en die ontwikkeling van 'n beproefte sensoriese toetsmodel vir voedsel-allergiese kinders is potensiële gebiede wat dringend verder nagevors behoort te word.
Tsang, Bo-yee, e 曾寶怡. "Food intake, resting metabolic rate and diet-induced thermogenesis of young Chinese females in the luteal and follicular phases of themenstrual cycle". Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1998. http://hub.hku.hk/bib/B31219998.
Testo completoRothe, Hannes [Verfasser]. "Educational Service Improvement Cycle : Ein Vorgehen zur Analyse von Nutzungsdaten für die kontinuierliche Weiterentwicklung webbasierter Lernservices / Hannes Rothe". Berlin : Freie Universität Berlin, 2016. http://d-nb.info/1081077816/34.
Testo completoMeinel, Dominik [Verfasser]. "Die Kraft-Wärme-Kopplung auf Basis von zweistufigen Organic Rankine Cycles / Dominik Meinel". München : Verlag Dr. Hut, 2020. http://d-nb.info/1219476668/34.
Testo completoGibert, Fabien. "Télédétection du CO2 atmosphérique par Lidar DIAL Doppler Hétérodyne à 2 microns". Phd thesis, Ecole Polytechnique X, 2005. http://pastel.archives-ouvertes.fr/pastel-00001903.
Testo completoClaasen, Clinton Jared. "Die stil avontuur an evaluation of Hendrik Hofmeyr's song-cycle with an emphasis on the poetry of Elisabeth Eybers". Master's thesis, University of Cape Town, 2012. http://hdl.handle.net/11427/10233.
Testo completoForty-six opuses in Hofmeyr's oeuvre are either inspired by or set to Afrikaans texts. This is indicative of his love for the language and of the culture in which he feels most comfortable. Of these works, the Afrikaans song is the most predominant genre which spans his entire compositional career. However, only one cycle, Alleenstryd, has been the subject of extensive academic evaluation (Roos, 2000; May, 2003; Cupido, 2010). For the purposes of this dissertation, I have decided to investigate Die stil avontuur, a cycle based on seven poems by Elisabeth Eybers. Die stil avontuur, commissioned by Lina Spies in celebration of Eybers' ninetieth birthday traces, like Robert Schumann's Frauenlieben und -leben, the life of a woman from the first meeting of her beloved to his death. My motivation for selecting this cycle as the subject for my study, besides considering it a high-point in both Hofmeyr's oeuvre and South African song, is one of identifying a number of correlations between Eybers and Hofmeyr. Both being recipients of international awards for their respective arts, they also both left their birth country in self-imposed exile. Another aspect common to both artists is their struggle to reconcile aspects of their upbringing with their arts.
Tsang, Bo-yee. "Food intake, resting metabolic rate and diet-induced thermogenesis of young Chinese females in the luteal and follicular phases of the menstrual cycle /". Hong Kong : University of Hong Kong, 1998. http://sunzi.lib.hku.hk/hkuto/record.jsp?B19324224.
Testo completoSmati, Hossem Edine. "Physical forcing of zooplankton in the upper oligotrophic ocean off Bermuda (northwestern Atlantic) and New Caledonia (southwestern Pacific) from acoustics and net measurements". Thesis, Aix-Marseille, 2015. http://www.theses.fr/2015AIXM4073.
Testo completoPhysical forcing drives the space and time discontinuity (patchiness) of plankton in the ocean. The thesis was focused on the role of these forcing on the zooplankton, studied using both acoustic and traditional methods with net sampling. The study was based on two examples. The first one concerns the northwestern Sargasso Sea where high resolution time-series data on 0-200m macrozooplankton abundance and distribution off Bermuda was estimated from volume backscattering strength (Sv) measured with a 153-Khz ADCP. Three types of eddies were identified: a productive cyclonic eddy, the periphery of a mode water eddy, and the periphery of an anticyclonic eddy. Sv values increased during passage of theses eddies, with a more pronounced increase associated with the edge of the cyclonic and the anticyclonic eddies, suggesting a significant biological response to localized upwelling in the high velocity boundary of these eddies. In the second example, spatial and temporal distribution of zooplankton off New Caledonia was studied during two multidisciplinary cruises in 2011. Zooplankton variability was assessed using net sampling together with acoustic measurements (shipborne ADCP, scientific echosounder and TAPS). Higher amplitudes of diel vertical migration (DVM) of zooplankton were associated with higher abundance of large zooplankton and cold waters to the south of the study area, while lower DVM amplitudes in the north were associated with warmer waters and higher abundance of small organisms. These acoustic measurements clearly evidenced the role of physical forcing, particularly mesoscale features, in shaping zooplankton space and time distribution
Deleens, Raynald. "Contribution au développement de nouvelles carbofonctionnalisations d'alcènes, préparation de polycycles aminofonctionnalisés en jonction de cycles et synthèse d'un disélénure chiral de symétrie C2". Rouen, 2002. http://www.theses.fr/2002ROUES062.
Testo completoThis work deals with the optimisation of new strategies for the synthesis of functionalised polycycles. In the first part, the study of a new methodology of alkenes carbofunctionalisation, based on the interaction between an episelenonium ion and a non activated silane, was examined. A strategy for the synthesis of bicyclic skeleton with a nitrogen atom at the junction is then described. It is based on the utilisation of nitroacetylene synthetic equivalents in a sequential double cycloaddition reaction. Hyperbaric conditions give access to expected adducts in good yields, and good regio and stereoselectivity. The optimisation of a new method to introduce a double bond in the cycloadduct, using carbenoid, yields cyclic nitroalkenes that could be involved in a second Diels-Alder reaction. An asymmetric version of the reactions described in these two parts is possible. Thus, the conception and the synthesis of a new chiral inductor, parenting a C2 symmetry, from proline, are described
Laquièvre, Aurélie. "Mécanismes élémentaires de plasticité des systèmes polymères amorphes : influence de la modification de la structure macromoléculaire par la chimie « Click »". Thesis, Lille 1, 2012. http://www.theses.fr/2012LIL10124/document.
Testo completoThe main objectives of this work were the elaborate new reversible crosslinked materials and to get a better understanding of their physical and mechanical properties. Two strategies have been investigated to prepare such materials. The first one consisted in applying to well-defined furan functionalized side-chain copolymers the Diels-Alder (DA) / retroDiels-Alder reactions. The second approach was based on the high reactivity of azlactone units embedding in well-defined copolymer chains toward primary amines. The controlled radical polymerization has been exploited in order to provide an effective way for the control synthesis of the well-defined side-chain functionalized copolymers. Then, various crosslinked materials have been prepared using the DA reaction and characterized to determine their glass transition temperature and their swelling ratio. The study of their thermal and viscoelastic properties highlighted the deep impact of the crosslinking. Then, their reversible and mechanical behaviors were investigated and we observed a correlation between the plastic deformation mechanisms and the induced structural evolution. Concerning the azlactone based copolymer, we have shown that this new polymeric platform could be efficiently modified by various primary amines, affording new materials with interesting properties (fluorescence, electroactive,…). The ring-opening reactions of azlactone functionalized copolymers were fully characterized proving the quantitative character of this reaction. Endly, crosslinked materials have been also elaborated by treating the azlactone copolymer with a diamino component
Espinosa, Rodriguez Edgar. "Préparation de polyéthylènes portant des fonctions réactives en extrémité de chaînes et leur utilisation en tant qu’agents de couplage pour la conception de matériaux originaux à base de polyéthylène". Thesis, Lyon 1, 2011. http://www.theses.fr/2011LYO10292/document.
Testo completoPolyethylene (PE) is a polymer of great importance in our everyday life due to its unique thermal and mechanical properties. However, it suffers from lack of reactivity that prevents to introduce it into more complexed architectures the final properties of which would benefit from these unique features. The modification of end-functionalized polymers through orthogonal and efficient coupling reactions is a powerful and widely used tool for the design of various macromolecular architectures. In today’s polymer science the copper catalyzed azide-alkyne cycloaddition (CuAAC) is the most frequently used « click » reaction. Another efficient coupling method is the hetero Diels-Alder (HDA) reaction between a diene end-functionalized polymer and the electron deficient dithioester end-group of a polymer synthesized by reversible addition fragmentation chain transfer (RAFT) polymerization. Our first aim was to fin and optimize the best ethylene catalytic polymerization system that would allow to produce PE with different molar masses and end functional groups. In a second step, we tried to introduce polyethylene segments in macromolecular architectures by taking advantage of the best attributes of the aforementioned coupling reactions
Vergnerie, Cédric. "La théorie des caractéristiques dans les Vorlesungen über die Theorie der algebraischen Gleichungen de Kronecker : la fin du cycle d’idées sturmiennes ?" Thesis, Sorbonne Paris Cité, 2017. http://www.theses.fr/2017USPCC238/document.
Testo completoIn her book Corps et Modèles, Hourya Sinaceur presented Kronecker’s theory of characteristics as the end of a “cycle of Sturmian ideas”, making it a step in history of the algebraization of Sturm’s theorem. However, this theory is often also introduced as the starting point of some of the early works of topology of the very end of the nineteenth century. In this PhD thesis, I will describe how these two stories are connected in Kronecker’s theory. To achieve this, I used material which has seldom been discussed before : the manuscripts of the courses that Kronecker gave at the University of Berlin between 1872 and 1891 on the Theory of algebraic equations. I begin with the presentation of these manuscripts, their contents and their writing contexts. I then look more closely at Kronecker’s rework of the theorem of Sturm and show that the theory of characteristics is not only an algebraic extension of this theorem but also that it is transformed in order to provide some of the analytic tools that Poincaré will use for the construction of his Analysis Situs. The exposition of the theory of characteristics in his courses is an opportunity for Kronecker to take up three of the four demonstrations from Gauss of the fundamental theorem of algebra, and I will show how, in Kronecker’s practice, the very notion of root is questioned
Ouellet, Luc. "Synthèse rapide de 14ß-hydroxystéroïdes via la réaction de Diels-Alder transannulaire ayant le cycle à aromatique et fonctionnalise en C17 et C18". Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1996. http://www.collectionscanada.ca/obj/s4/f2/dsk3/ftp04/mq21808.pdf.
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