Letteratura scientifica selezionata sul tema "Coordinative Polymerization"

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Articoli di riviste sul tema "Coordinative Polymerization":

1

Valente, Andreia, André Mortreux, Marc Visseaux e Philippe Zinck. "Coordinative Chain Transfer Polymerization". Chemical Reviews 113, n. 5 (7 febbraio 2013): 3836–57. http://dx.doi.org/10.1021/cr300289z.

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Stere, Cristina, Mihaela Iovu, Adrian Boborodea, Dan Sorin Vasilescu e Iosif Sorin Fazakas-Anca. "Anionic and ionic coordinative polymerization ofL-lactide". Polymers for Advanced Technologies 9, n. 6 (giugno 1998): 322–25. http://dx.doi.org/10.1002/(sici)1099-1581(199806)9:6<322::aid-pat783>3.0.co;2-n.

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Stere, Cristina, Mihaela-Corina Iovu, Horia Iovu, Adrian Boborodea, Dan Sorin Vasilescu e Simon James Read. "Anionic and ionic coordinative polymerization of ?-caprolactone". Polymers for Advanced Technologies 12, n. 5 (2001): 300–305. http://dx.doi.org/10.1002/pat.68.

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Del Rio, E., M. Galià, V. Cádiz, G. Lligadas e J. C. Ronda. "Polymerization of epoxidized vegetable oil derivatives: Ionic-coordinative polymerization of methylepoxyoleate". Journal of Polymer Science Part A: Polymer Chemistry 48, n. 22 (20 settembre 2010): 4995–5008. http://dx.doi.org/10.1002/pola.24297.

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Baulu, Nicolas, Marie-Noëlle Poradowski, Ludmilla Verrieux, Julien Thuilliez, François Jean-Baptiste-dit-Dominique, Lionel Perrin, Franck D'Agosto e Christophe Boisson. "Design of selective divalent chain transfer agents for coordinative chain transfer polymerization of ethylene and its copolymerization with butadiene". Polymer Chemistry 13, n. 14 (2022): 1970–77. http://dx.doi.org/10.1039/d2py00155a.

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WANG, Juan, Tingting YANG, Hui PENG e Shiyuan CHENG. "KINETICS OF THE COORDINATIVE CATALYTIC EMULSION POLYMERIZATION OF STYRENE". Acta Polymerica Sinica 011, n. 7 (21 luglio 2011): 718–23. http://dx.doi.org/10.3724/sp.j.1105.2011.10189.

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Ronda, Joan Carles, Angels Serra e Virginia Cádiz. "Coordinative polymerization of p-substituted phenyl glycidyl ethers, 2". Macromolecular Chemistry and Physics 198, n. 9 (settembre 1997): 2935–48. http://dx.doi.org/10.1002/macp.1997.021980922.

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8

Yu, Chao, Pengfei Zhang, Fei Gao, Shaowen Zhang e Xiaofang Li. "A displacement-type fluorescent probe reveals active species in the coordinative polymerization of olefins". Polymer Chemistry 9, n. 5 (2018): 603–10. http://dx.doi.org/10.1039/c7py01915g.

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Abstract (sommario):
The correct identification of active species is an important prerequisite to study the mechanism of coordinative polymerization of olefins, which can afford important theoretical guidance for the design and synthesis of new organometallic catalysts and high-performance polyolefin materials.
9

Park, Kyung Lee, Jun Won Baek, Seung Hyun Moon, Sung Moon Bae, Jong Chul Lee, Junseong Lee, Myong Sun Jeong e Bun Yeoul Lee. "Preparation of Pyridylamido Hafnium Complexes for Coordinative Chain Transfer Polymerization". Polymers 12, n. 5 (11 maggio 2020): 1100. http://dx.doi.org/10.3390/polym12051100.

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The pyridylamido hafnium complex (I) discovered at Dow is a flagship catalyst among postmetallocenes, which are used in the polyolefin industry for PO-chain growth from a chain transfer agent, dialkylzinc. In the present work, with the aim to block a possible deactivation process in prototype compound I, the corresponding derivatives were prepared. A series of pyridylamido Hf complexes were prepared by replacing the 2,6-diisopropylphenylamido part in I with various 2,6-R2C6H3N-moieties (R = cycloheptyl, cyclohexyl, cyclopentyl, 3-pentyl, ethyl, or Ph) or by replacing 2-iPrC6H4C(H)- in I with the simple PhC(H)-moiety. The isopropyl substituent in the 2-iPrC6H4C(H)-moiety influences not only the geometry of the structures (revealed by X-ray crystallography), but also catalytic performance. In the complexes bearing the 2-iPrC6H4C(H)-moiety, the chelation framework forms a plane; however, this framework is distorted in the complexes containing the PhC(H)-moiety. The ability to incorporate α-olefin decreased upon replacing 2-iPrC6H4C(H)-with the PhC(H)-moiety. The complexes carrying the 2,6-di(cycloheptyl)phenylamido or 2,6-di(cyclohexyl)phenylamido moiety (replacing the 2,6-diisopropylphenylamido part in I) showed somewhat higher activity with greater longevity than did prototype catalyst I.
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Wang, Feng, Heng Liu, YanMing Hu e XueQuan Zhang. "Lanthanide complexes mediated coordinative chain transfer polymerization of conjugated dienes". Science China Technological Sciences 61, n. 9 (31 luglio 2018): 1286–94. http://dx.doi.org/10.1007/s11431-018-9256-6.

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Tesi sul tema "Coordinative Polymerization":

1

Zhang, Wei. "Living coordinative chain transfer polymerization of 1-alkenes". College Park, Md. : University of Maryland, 2008. http://hdl.handle.net/1903/8897.

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Abstract (sommario):
Thesis (Ph. D.)--University of Maryland, College Park, 2008.
Thesis research directed by: Dept. of Chemistry and Biochemistry. Title from t.p. of PDF. Includes bibliographical references. Published by UMI Dissertation Services, Ann Arbor, Mich. Also available in paper.
2

Valente, Andreia. "Lanthanide based coordinative chain transfer polymerization for architecture control in (co)polymers and ruthenium catalyzed ring-opening polymerization : two aspects of atom economy in polymerization catalysis". Thesis, Lille 1, 2010. http://www.theses.fr/2010LIL10061.

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Le nouveau complexe Cp*La(BH4)2(THF)2 a été utilisé en combinaison avec des alkyles magnésiens et aluminiques pour la (co)polymérisation coordinative par transfert de chaîne (CCTP) du styrène et de l’isoprène. En développant ce concept nous avons obtenu la première croissance de chaîne catalysée du styrène et de l’isoprène avec contrôle de la microstructure. L’application de la CCTP à la copolymérisation statistique est une voie nouvelle et originale pour le contrôle de la composition de copolymères.Par ailleurs, une étude mécanistique a été réalisée pour la polymérisation de l’ ε-caprolactone avec des dérivés cationiques de ruthénium [(η5-C5H5)Ru(η6-arène substitué)][PF6]. Nous avons montré que la polymérisation a lieu selon un mécanisme de type monomère activé avec transfert aux alcools, avec modification de l’hapticité du ligand arène
A newly synthesized Cp*La(BH4)2(THF)2 complex in combination with magnesium or aluminum alkyls was used for the coordinative chain transfer (co)polymerization (CCTP) of styrene and isoprene. Using this concept, we have accomplished the first catalyzed chain growth like reaction of styrene and isoprene, with control of the microstructure. The application of CCTP to statistical copolymerization represents a new and original approach to tune the composition of copolymers. In addition, a mechanistic study of the ring-opening polymerization of ε-caprolactone by [(η5-C5H5)Ru(η6-substituted arene)][PF6] complexes shows that the polymerization proceeds via an activated monomer mechanism by transfer to the alcohol with a change of hapticity of the arene ligand
3

Hashmi, Obaid Hasan. "Engineering of iron-based polymerization catalysts : towards the design of original multi-structured thermoplastic (co) polymers". Electronic Thesis or Diss., Université de Lille (2018-2021), 2021. http://www.theses.fr/2021LILUR022.

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Une série de ligands L1-L11 à base d'iminopyridine/iminoquinoline du type 11-[(Ar)N=C(R)]-R' (Ar = 2,6-Me2-C6H3 ou 2,6-iPr2-C6H3 ou 3,5-(CF3)2-C6H3 ou C6F5, R = H ou Me et R’ = 2-C6H5N ou 2-C6H4N-5-Me ou 2-C9H7N ou 8-C9H7N) et leurs complexes de fer (II) correspondants ont été développés. Les complexes ont été entièrement caractérisés, y compris par diffraction des rayons X pour les nouveaux complexes (6-11), et leurs applications catalytiques ont été étudiées pour la polymérisation coordonnée contrôlée de l'isoprène. La modulation des propriétés stériques et électroniques au sein de cette famille de ligands/complexes s'est avérée influencer la stéréosélectivité et l'activité de la polymérisation de l'isoprène après activation avec divers cocatalyseurs. Les catalyseurs obtenus ont produit des polyisoprènes avec une excellente conversion, une activité élevée et une variété de stéréo-/régio-régularités. Certains de ces catalyseurs ont également été évalués pour la polymérisation coordinative du styrène et ont montré une bonne activité pour la formation de polystyrènes syndiotactiques enrichis. Une autre méthodologie organométallique a été utilisée pour la synthèse de ligands d'aminopyridine (rac-L1H and rac-L2H) et de leurs complexes d'amides de fer correspondants 12 ((L1)2Fe), 13Py et 14Py (LnFe[N(SiMe3)2](Py)) pour leur application dans la (co)polymérisation par ouverture de cycle de L-lactide et ε-caprolactone où les complexes 13Py et 14Py se sont avérés efficaces
A series of iminopyridine-/iminoquinoline-based ligands L1-L11 of type 11-[(Ar)N=C(R)]-R’ (Ar = 2,6-Me2-C6H3 or 2,6-iPr2-C6H3 or 3,5-(CF3)2-C6H3 or C6F5, R = H or Me and R’ = 2-C6H5N or 2-C6H4N-5-Me or 2-C9H7N or 8-C9H7N) and their corresponding iron (II) complexes were developed. The complexes were fully characterized including by X-ray for new complexes (6-11) and their catalytic applications were investigated for the controlled coordinative polymerization of isoprene. The modulation of steric and electronic properties within this family of ligands/complexes has shown to influence the stereo-selectivity and activity of the polymerization of isoprene after activation with various cocatalysts. The resulting catalysts produced polyisoprenes with an excellent conversion, high activity and a variety of stereo-/regio-regularities. Some of these catalysts were also assessed for the coordinative polymerization of styrene and displayed good activity for the formation of syndiotactic enriched polystyrenes. Another organometallic methodology has been utilized for the synthesis of aminopyridine ligands (rac-L1H and rac-L2H) and their corresponding iron amide complexes 12 ((L1)2Fe), 13Py and 14Py (LnFe[N(SiMe3)2](Py)) for their application in the Ring-Opening (Co)polymerizaion of L-lactide and ε-caprolactone where the complexes 13Py and 14Py proved to be effective
4

Obenauf, Johannes [Verfasser], e Rhett [Akademischer Betreuer] Kempe. "Coordinative Chain-Transfer Polymerization of Ethylene with NCN-Ligand Stabilized Complexes of Titanium and Zirconium / Johannes Obenauf. Betreuer: Rhett Kempe". Bayreuth : Universität Bayreuth, 2015. http://d-nb.info/1075249414/34.

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Starks, Leonard J. "The polymerization of formaldehyde by coordination catalysis". Diss., Georgia Institute of Technology, 1993. http://hdl.handle.net/1853/28018.

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Tas, Huseyin. "Coordination Polymerization Of Cyclic Ethers By Metal Xanthates And Carbamates". Master's thesis, METU, 2003. http://etd.lib.metu.edu.tr/upload/1225028/index.pdf.

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Zinc xanthates are active catalysts in stereoregular polymerization of propylene oxide and markedly more stable than that of known classical stereoregular catalysts. But steric control of zinc xanthates is weaker. To find more effective catalyst systems the isopropyl xanthates of Cu, Pb, Ni, Fe, Al and Sn are investigated and only copper (Cu(isoPr)Xt) and tin (Sn(isoPr)Xt) isopropyl xanthates were appeared to be active, but Cu(isoPr)Xt yielded only low molecular weight product. Therefore Sn(isoPr)Xt system was investigated in detail in polymerization of propylene oxide (PO). Polymerization of PO with this catalyst produced two contrasting polymers
high molar mass, crystalline (K-polymer) and low molar mass (D-polymer). Formation of double bonds in D-polymer was thought to be due to as an anionic process. Polymerization reactions were studied by changing polymerization conditions and reacting catalyst with predetermined amount of water. It&
#8217
s found that Sn(isoPr)Xt have considerably low efficiency than that of Zn(isoPr)Xt catalyst. The yield linearly increases by increasing catalyst concentration. The propagation is competed by termination or transfer process hence overall activation energy is negative. Some mechanistic features of this system was also discussed. The catalytical activity of carbamates in this field has also been reported, without any information about catalytical efficiency and stereoregularity of the process. Therefore zinc diethyl dithiocarbamate was also studied and found as an active catalyst in stereoregular polymerization but it showed weaker efficiency in the PO polymerization than that of Zn(isoPr)Xt catalyst (about 12 times weaker).
7

Mochizuki, Shuto. "Controlled radical polymerization in designed porous materials". Kyoto University, 2019. http://hdl.handle.net/2433/242535.

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Noack, Cassandra, e n/a. "Studies in Coordination Chemistry". Griffith University. School of Science, 2003. http://www4.gu.edu.au:8080/adt-root/public/adt-QGU20031030.145610.

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The research reported in this thesis was carried out in Brisbane, Australia and Calgary, Canada. The aim of the research conducted in Brisbane was to prepare a series of copper(I) and ruthenium(II) based complexes incorporating a hemilabile phosphine ligand and to determine whether or not these compounds possessed catalytic activity. The history, uses, properties and recent work incorporating hemilabile phosphine ligands is discussed in detail as well as the application of hemilabile ligands to atom transfer radical polymerization (ATRP) and the usefulness of the 'windscreen wiper' action of these ligands in polymerization. The literature synthesis and characterization of four hemilabile phosphine ligands is reported with modifications. The (2-chlorophenyl)diphenylphosphine ligand was prepared via a Grignard reaction giving a 11% yield. The (2-bromophenyl) diphenylphosphine ligand was prepared by reaction of 2-bromoiodobenzene with Ph2PSiMe3 in the presence of a palladium catalyst (MeCN)2PdCl2 which yielded 50% product. The 1-chloro-2-diphenylphosphinoethane ligand was prepared following the generation of a lithium diphenylphosphide which was added to 1,2-dichloroethane to give a 43% yield of product. The (2-benzoic-acid)diphenylphosphine ligand was prepared by hydrolysis of (2-methyl-ester-phenyl)diphenylphosphine. Following acidification of the methyl ester phosphine with HCl, the desired product was isolated in 88% yield. The synthesis and characterization of a series of copper(I) based complexes incorporating the prepared phosphine ligands involved reaction in CH3CN of the appropriate ligand with copper halides as starting material. Solution state 31P NMR and mass spectrometry were used to study many of these complexes in the solution state, whilst microanalysis, 31P CP MAS NMR and single crystal X-ray diffraction studies were used to study their solid state properties. The complexes of the type bis(2-halophenyl)diphenylphosphine copper halide were found to be three coordinate with non-chelating ligands and to be isostructural with the previously studied bis(2-methylphenyl)diphenylphosphine copper halide complexes. The synthesis and characterization of ruthenium(II) based complexes incorporating hemilabile phosphine ligands involved reaction of the appropriate ligands in MeOH with RuCl3.3H2O or RuCl2(DMSO)4 as the ruthenium source. Modes of characterization included solution state 31P NMR, mass spectrometry, microanalysis and single crystal X-ray diffraction studies. All ruthenium(II) based complexes were found to incorporate the hemilabile ligands in a chelating mode resulting in 6 coordinate structures. The preliminary polymerization testing of MMA in the presence of the copper(I) and ruthenium(II) based complexes has been reported. All complexes successfully polymerized the monomer and the resulting polyMMA showed polydispersity values ranging from moderate (3.1) to very high (6.7). Chapter 7 discusses research conducted over a 6 month period at the University of Calgary, Canada under an International Resident Fellowship award. This work involved the synthesis and characterization of scandium(III) and yttrium(III) based complexes incorporating a chelating amido-imine ligand, as potential olefin polymerization catalysts.
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Noack, Cassandra. "Studies in Coordination Chemistry". Thesis, Griffith University, 2003. http://hdl.handle.net/10072/366798.

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Abstract (sommario):
The research reported in this thesis was carried out in Brisbane, Australia and Calgary, Canada. The aim of the research conducted in Brisbane was to prepare a series of copper(I) and ruthenium(II) based complexes incorporating a hemilabile phosphine ligand and to determine whether or not these compounds possessed catalytic activity. The history, uses, properties and recent work incorporating hemilabile phosphine ligands is discussed in detail as well as the application of hemilabile ligands to atom transfer radical polymerization (ATRP) and the usefulness of the 'windscreen wiper' action of these ligands in polymerization. The literature synthesis and characterization of four hemilabile phosphine ligands is reported with modifications. The (2-chlorophenyl)diphenylphosphine ligand was prepared via a Grignard reaction giving a 11% yield. The (2-bromophenyl) diphenylphosphine ligand was prepared by reaction of 2-bromoiodobenzene with Ph2PSiMe3 in the presence of a palladium catalyst (MeCN)2PdCl2 which yielded 50% product. The 1-chloro-2-diphenylphosphinoethane ligand was prepared following the generation of a lithium diphenylphosphide which was added to 1,2-dichloroethane to give a 43% yield of product. The (2-benzoic-acid)diphenylphosphine ligand was prepared by hydrolysis of (2-methyl-ester-phenyl)diphenylphosphine. Following acidification of the methyl ester phosphine with HCl, the desired product was isolated in 88% yield. The synthesis and characterization of a series of copper(I) based complexes incorporating the prepared phosphine ligands involved reaction in CH3CN of the appropriate ligand with copper halides as starting material. Solution state 31P NMR and mass spectrometry were used to study many of these complexes in the solution state, whilst microanalysis, 31P CP MAS NMR and single crystal X-ray diffraction studies were used to study their solid state properties. The complexes of the type bis(2-halophenyl)diphenylphosphine copper halide were found to be three coordinate with non-chelating ligands and to be isostructural with the previously studied bis(2-methylphenyl)diphenylphosphine copper halide complexes. The synthesis and characterization of ruthenium(II) based complexes incorporating hemilabile phosphine ligands involved reaction of the appropriate ligands in MeOH with RuCl3.3H2O or RuCl2(DMSO)4 as the ruthenium source. Modes of characterization included solution state 31P NMR, mass spectrometry, microanalysis and single crystal X-ray diffraction studies. All ruthenium(II) based complexes were found to incorporate the hemilabile ligands in a chelating mode resulting in 6 coordinate structures. The preliminary polymerization testing of MMA in the presence of the copper(I) and ruthenium(II) based complexes has been reported. All complexes successfully polymerized the monomer and the resulting polyMMA showed polydispersity values ranging from moderate (3.1) to very high (6.7). Chapter 7 discusses research conducted over a 6 month period at the University of Calgary, Canada under an International Resident Fellowship award. This work involved the synthesis and characterization of scandium(III) and yttrium(III) based complexes incorporating a chelating amido-imine ligand, as potential olefin polymerization catalysts.
Thesis (PhD Doctorate)
Doctor of Philosophy (PhD)
School of Science
Faculty of Science
Full Text
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Groeneman, Ryan H. "Investigating the inclusion chemistry of multi-dimensional coordiation polymers /". free to MU campus, to others for purchase, 2000. http://wwwlib.umi.com/cr/mo/fullcit?p9999289.

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Libri sul tema "Coordinative Polymerization":

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S, Abd-El-Aziz Alaa, a cura di. Metal-coordination polymers. Hoboken, N.J: Wiley, 2005.

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Kuran, Witold. Principles of coordination polymerisation: Heterogeneous and homogeneous catalysis in polymer chemistry-polymerisation of hydrocarbon, heterocyclic, and heterounsaturated monomers. Chicthester [i.e. Chichester], England: John Wiley, 2001.

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Hong, Mao-Chun. Design and construction of coordination polymers. Hoboken, N.J: Wiley, 2009.

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Drǎguţan, V. Olefin metathesis and ring-opening polymerization of cyclo-olefins. 2a ed. Bucureşti: Editura Academiei, 1985.

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Batten, Stuart R. Coordination polymers: Design, analysis and application. Cambridge, UK: Royal Society of Chemistry, 2009.

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Nail, Fatkullin, a cura di. NMR, 3D analysis, photopolymerization. Berlin: Springer, 2004.

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K, Bregg Robert, a cura di. Current topics in polymer research. Hauppauge, N.Y: Nova Science Publishers, 2005.

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Price, Charles C. Coordination Polymerization. Springer, 2011.

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Price, Charles C. Coordination Polymerization. Springer, 2013.

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Sun, Hong-Bo, Kohtaro Osakada, Satoshi Kawata, Daisuke Takeuchi e Rainer Kimmich. NMR/Coordination Polymerization/Photopolymerization. Springer, 2004.

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Capitoli di libri sul tema "Coordinative Polymerization":

1

Gooch, Jan W. "Coordination Polymerization". In Encyclopedic Dictionary of Polymers, 171. New York, NY: Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-6247-8_2904.

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Koltzenburg, Sebastian, Michael Maskos e Oskar Nuyken. "Coordination Polymerization". In Polymer Chemistry, 293–319. Berlin, Heidelberg: Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-49279-6_11.

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Soares, João B. P., e Odilia Pérez. "Coordination Polymerization". In Handbook of Polymer Synthesis, Characterization, and Processing, 85–104. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118480793.ch5.

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Elias, Hans-Georg. "Coordination Polymerization". In Macromolecules, 269–308. D-69451 Weinheim, Germany: Wiley-VCH Verlag GmbH, 2014. http://dx.doi.org/10.1002/9783527627219.ch9.

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Su, Wei-Fang. "Coordination Polymerization". In Lecture Notes in Chemistry, 219–32. Berlin, Heidelberg: Springer Berlin Heidelberg, 2013. http://dx.doi.org/10.1007/978-3-642-38730-2_9.

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Koltzenburg, Sebastian, Michael Maskos e Oskar Nuyken. "Coordination Polymerization". In Polymer Chemistry, 295–324. Berlin, Heidelberg: Springer Berlin Heidelberg, 2023. http://dx.doi.org/10.1007/978-3-662-64929-9_11.

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Mishra, Munmaya, e Biao Duan. "Coordination Polymerization". In The Essential Handbook of Polymer Terms and Attributes, 38–40. Boca Raton: CRC Press, 2024. http://dx.doi.org/10.1201/9781003161318-37.

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Visseaux, Marc, Thomas Chenal e Philippe Zinck. "Coordinative Chain Transfer Polymerization and Copolymerization by Means of Rare Earth Organometallic Catalysts for the Synthesis of Tailor-Made Polymers". In Advances in Organometallic Chemistry and Catalysis, 343–58. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118742952.ch27.

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Nakayama, Yuushou, e Takeshi Shiono. "Coordination Polymerization (Olefin and Diene)". In Encyclopedia of Polymeric Nanomaterials, 1–6. Berlin, Heidelberg: Springer Berlin Heidelberg, 2014. http://dx.doi.org/10.1007/978-3-642-36199-9_179-1.

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Nakayama, Yuushou, e Takeshi Shiono. "Coordination Polymerization (Olefin and Diene)". In Encyclopedia of Polymeric Nanomaterials, 469–74. Berlin, Heidelberg: Springer Berlin Heidelberg, 2015. http://dx.doi.org/10.1007/978-3-642-29648-2_179.

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