Letteratura scientifica selezionata sul tema "Chiral ions pair"
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Articoli di riviste sul tema "Chiral ions pair":
Smith, Owen, Mihai V. Popescu, Madeleine J. Hindson, Robert S. Paton, Jonathan W. Burton e Martin D. Smith. "Control of stereogenic oxygen in a helically chiral oxonium ion". Nature 615, n. 7952 (15 marzo 2023): 430–35. http://dx.doi.org/10.1038/s41586-023-05719-z.
Mercea, Dan M., Michael G. Howlett, Adam D. Piascik, Daniel J. Scott, Alan Steven, Andrew E. Ashley e Matthew J. Fuchter. "Enantioselective reduction of N-alkyl ketimines with frustrated Lewis pair catalysis using chiral borenium ions". Chemical Communications 55, n. 49 (2019): 7077–80. http://dx.doi.org/10.1039/c9cc02900a.
Karlsson, Anders, e Olle Karlsson. "Chiral ion-pair chromatography on porous graphitized carbon using N-blocked dipeptides as counter ions". Journal of Chromatography A 905, n. 1-2 (gennaio 2001): 329–35. http://dx.doi.org/10.1016/s0021-9673(00)00986-9.
Sellmann, Dieter, Helge Friedrich e Falk Knoch. "Übergangsmetallkomplexe mit Schwefelliganden, XCIX. Bildung und Struktur von [Fe(′S4′)]4. Eine bemerkenswerte Tetramerisierung homochiraler[Fe(′S4′)]-Komplexfragmente (′S4′2- = 1,2-Bis(2-mercaptophenylthio)ethan(2-)) / Transition Metal Complexes with Sulfur Ligands, XCIX. Formation and Structure of [Fe(′S4′)]4. A Remarkable Tetramerization of Homochiral [Fe(′S4′)] Complex Fragments (′S4′2-= 1,2-Bis(2-mercaptophenylthio)ethane(2–))". Zeitschrift für Naturforschung B 48, n. 11 (1 novembre 1993): 1675–80. http://dx.doi.org/10.1515/znb-1993-1128.
Wang, Hai-Ping, Shao-Yun Yin, Mei Pan, Kai Wu, Ling Chen, Yi-Xuan Zhu e Ya-Jun Hou. "Circular dichroism enhancement by the coordination of different metal ions with a pair of chiral tripodal ligands". Inorganic Chemistry Communications 54 (aprile 2015): 92–95. http://dx.doi.org/10.1016/j.inoche.2015.02.013.
Tsunematsu, Hideaki, Hirohito Ikeda, Hiroshi Hanazono, Masanori Inagaki, Ryuichi Isobe, Ryuichi Higuchi, Yoshinobu Goto e Magobei Yamamoto. "Differentiation of a pair of diastereomeric tertiarybutoxycarbonylprolylproline ethyl esters by collision-induced dissociation of sodium adduct ions in electrospray ionization mass spectrometry and evidence for chiral recognition byab initio molecular orbital calculations". Journal of Mass Spectrometry 38, n. 2 (2003): 188–95. http://dx.doi.org/10.1002/jms.428.
BARSHAY, SAUL. "ARE NARROW POSITRON-ELECTRON LINES CREATED BY DECAY OF EXCITED VACUUM-LIKE SYSTEMS FORMED FROM A COHERENT PIONIC PHASE PRESENT IN HEAVY-ION COLLISIONS?" Modern Physics Letters A 07, n. 20 (28 giugno 1992): 1843–53. http://dx.doi.org/10.1142/s0217732392001555.
Tao, Kezheng, Qiang Li e Qingfeng Yan. "1D Tin(II)‐Based Chiral Hybrid Perovskite Single Crystals with Extremely Distorted Inorganic Chains for Second Harmonic Generation". Advanced Optical Materials, 17 febbraio 2024. http://dx.doi.org/10.1002/adom.202400018.
Si, Wei-Dan, Kai Sheng, Chengkai Zhang, Zhi Wang, Shan-Shan Zhang, Jian-Min Dou, Lei Feng, Zhi-Yong Gao, Chen-Ho Tung e Di Sun. "Bicarbonate insertion triggered self-assembly of chiral octa-gold nanoclusters into helical superstructures in the crystalline state". Chemical Science, 2022. http://dx.doi.org/10.1039/d2sc03463h.
Li, Tianyu, Luyao Ding, Yihong Kang, Xin-Qi Hao, Yujing Guo, Linlin Shi e Mao-Ping Song. "The synthesis, characterization and application of the binol-cages of R-/S-enantiomers". Chemical Synthesis 3, n. 4 (31 ottobre 2023). http://dx.doi.org/10.20517/cs.2023.39.
Tesi sul tema "Chiral ions pair":
Saidah, Milane. "Synthèse énantiosélective de gamma-lactames possédant un centre tétrasubstitué". Electronic Thesis or Diss., Aix-Marseille, 2023. http://www.theses.fr/2023AIXM0034.
In view of the emergence of organocatalysts compounds as powerful tools for asymmetric catalysis, the development of processes involving chiral ion pairs has proven successful. Notably, Asymmetric Counterion-Directed Catalysis (ACDC) is well-known to be an efficient strategy for enantioselective reactions involving cationic species and enantiomerically pure counteranions. More specifically, cyclic N-acyliminium ions are key intermediates in the preparation of enantioenriched gamma-lactams. Based on the concept of ACDC, this work has focused on the construction of tetrasubstituted carbon centers via an organocatalyzed alpha-amidoalkylation reaction by chiral phosphoric acids from gamma-hydroxylactams
Claraz, Aurélie. "Nouvelles applications de paires d’ions coopératifs chirales en organocatalyse : réactions énantiosélectives de protonation, de déprotonation et d’aldolisation directes vinylogues". Thesis, Rouen, INSA, 2012. http://www.theses.fr/2012ISAM0015.
This work deals with the development of new asymetric organocatalyzed methodologies. More particularly we were focused on using "cooperative chiral ion pairs" having an ammonium moiety derived from cinchona alkaloids and an anionic moiety with nucleophilic properties able to activate a reagent.Firstly, we used an in situ generated chiral ammonium amide (from the combination of an aminosilane and a quininium aryloxide) as a Brønsted base in two distinct reactions. Initially, this strategy was applied to an organocatalyzed desymmetrization of prochiral ketones by enantioselective deprotonation. Despite modest enantiometric excesses, this report constitutes the first example of an enantioselective orgonacatalyc approach. Then, an anti-selective direct vinylogous asymmetric aldol reaction of (5H)-furan-2-ones was achieved in good yields and enantioselectivities up to 94%.Secondly, we described two new catalytic cycles for the enantioselective protonation of latent enolates. By means of cinchona alkaloids and hydrogenocarbonates, enantioenriched α-substituted ketones were obtained with good enantiometric excesses up to 93% starting from the corresponding enol trifluoacetates. Finally, the nucleophilic properties of our ammonium phenoxide catalysts prompted us to develop an enantioselective protonation reaction of silyl enol ethers in the presence of phenol as achiral proton source
Patwardhan, Neeraj Narendra. "Study of Synthesis, Reactions and Enantiomerization of Cα-Chiral Grignard Reagents". Diss., Virginia Tech, 2012. http://hdl.handle.net/10919/37814.
Ph. D.
Legros, Fabien. "Nouvelles applications de paires d'ions coopératifs chirales en organocatalyse : utilisations dans des réactions mettant en jeu l'acide de Meldrum et ses dérivés". Thesis, Normandie, 2017. http://www.theses.fr/2017NORMR026/document.
The work developed in this PhD thesis deals with the development of new asymmetric organocatalytic methodologies implying cooperative chiral ion pairing catalysis, by using chiral ammonium phenoxides as catalysts and Meldrum’s acid derivatives as substrates. First, we used the ability of Meldrum’s acid to generate acylketenes after cycloversion triggered by O-silylation thanks to a silylated probase in the presence of a chiral ammonium phenoxide. Such an approach was applied to the synthesis of β-lactones and β-lactames following a [2+2] cycloaddition reaction with aldehydes or imines respectively. Unfortunately, the desired products have never been observed. Then, we focused on disubstitued derivatives of Meldrum’s acids and their propensity to fragment after a nucleophilic addition of phenoxide. In a first part, we have developed a one-pot desymmetrization reaction of Meldrum’s acid derivatives to form dissymmetric malonates after an in-situ alkylation of the transient carboxylate. However, despite high isolated yields, only an unsatisfactory 21% ee could be reached. In a second part, we have developed an unprecedented sequence consisting of (1) a nucleophilic addition of phenol derivatives to Meldrum’s acid followed by (2) a fragmentation with loss of acetone, leading after (3) decaboxylation to the formation of an acyclic ketene acetal which is involved in (4) an enantioselective protonation reaction to provide a wide range of enantioenriched phenolic esters with moderate to excellent yield and up to 70% ee
上木, 佑介, e Yusuke UEKI. "Development of Ion-Pair Cooperative Asymmetric Catalyses of Chiral Tetraaminophosphonium Salts Possessing Organic Anions". Thesis, 2012. http://hdl.handle.net/2237/16460.
Shie, Ying-ying, e 謝瑩瑩. "Enantioseparation of Acids by Partial Filling Technique of Capillary Electrophoretic Chromatography with π-Acid Derived Quinidine as Chiral Ion-Pair Reagent". Thesis, 2004. http://ndltd.ncl.edu.tw/handle/01261368607598987489.
朝陽科技大學
應用化學系碩士班
92
The potential of 3,5-dinitrobenzoyl quinidine as chiral selector added to a non-aqueous background buffer for the capillary electrophoretic separation of the enantiomers of N-derivatized amino acids and non-steroidal anti-inflammatory drugs are evaluated. Separation is based on chiral analytes of R or S of negatively charged and positively charged quinidine-derived chiral selector to form temporary ion-pair, because of different molecular interactions and mobiling. As a result, the differences in the overall migration of analytes can be achievd. To suppress one problems associated with the high UV absorption of the chiral selector and thus the high detecting background in the ‘total filling technique’, the ‘partial filling technique’ has been adopted. Several parameters including selector filling time and length of selector zone, selector concentration, type of non-aqueous background electrolyte and length of column have been evaluated. Optimun experimental conditions were found with a electrolyte made of 80 mM acetic acid, 20 mM triethylamine and 150 mM 3,5-dinitrobenzoyl quinidine in an EtOH-MeOH (60:40, v/v), and at voltage of –30kV. Under these conditions, (R) and (S) enantiomers of 3,5-dinitrobenzoyl leucine could be separated with α=1.10, Rs=5.16. (R) and (S) enantiomers of ketoprofen could be separated with α=1.06, Rs=1.13. Similar resolution, and efficiencies were observed for other analytes. 3,5-dinitrobenzoyl quinidine as chiral selector can be utilized to separate several kinds of compound induding aromatic π acid, aromatic π base and ascorbic acid.
Capitoli di libri sul tema "Chiral ions pair":
Buese, Mark A., e Thieo E. Hogen-Esch. "Stereoelective Anionic Polymerization of Chiral Vinyl Monomers Via Interconverting Ion Pair Epimers". In Recent Advances in Anionic Polymerization, 231–47. Dordrecht: Springer Netherlands, 1987. http://dx.doi.org/10.1007/978-94-009-3175-6_16.
de Biasi, V., M. B. Evans e W. J. Lough. "A Note on Chiral Ion-Pair Chromatography of Novel Basic Antihypertensive Agents". In Recent Advances in Chiral Separations, 93–96. New York, NY: Springer US, 1991. http://dx.doi.org/10.1007/978-1-4684-8282-9_13.
Rueping, M., e E. Sugiono. "New Developments in Enantioselective Brønsted Acid Catalysis: Chiral Ion Pair Catalysis and Beyond". In Ernst Schering Foundation Symposium Proceedings, 301–50. Berlin, Heidelberg: Springer Berlin Heidelberg, 2008. http://dx.doi.org/10.1007/2789_2008_085.
Gaskell, R. M., e B. Crooks. "A Note on Analytical and Preparative Chiral Resolution of Some Aminoalcohols by Ion-Pair High-Performance Liquid Chromatography". In Chiral Separations, 65–70. Boston, MA: Springer US, 1988. http://dx.doi.org/10.1007/978-1-4615-6634-2_8.
Ali, Imran, e Hassan Y. Aboul-Enein. "Speciation of Metal Ions by Ion-Pair, Micellar Electrokinetic, Size Exclusion, Chiral, Capillary Electro-, and Supercritical Fluid Chromatographic Methods". In Instrumental Methods in Metal Ion Speciation, 243–61. CRC Press, 2006. http://dx.doi.org/10.1201/9781420019407-8.
"Speciation of Metal Ions by Ion-Pair, Micellar Electrokinetic, Size Exclusion, Chiral, Capillary Electro-, and Supercritical Fluid Chromatographic Methods". In Instrumental Methods in Metal Ion Speciation, 243–61. CRC Press, 2006. http://dx.doi.org/10.1201/9781420019407.ch8.
Heldin, E. "CHIRAL SEPARATIONS | Ion-Pair Chromatography". In Encyclopedia of Separation Science, 2358–69. Elsevier, 2000. http://dx.doi.org/10.1016/b0-12-226770-2/03151-3.