Letteratura scientifica selezionata sul tema "Argilite du Callovo-Oxfordien (Cox)"
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Articoli di riviste sul tema "Argilite du Callovo-Oxfordien (Cox)":
Liu, Jiang-Feng, Yang Song, Frédéric Skoczylas e Jian Liu. "Gas migration through water-saturated bentonite–sand mixtures, COx argillite, and their interfaces". Canadian Geotechnical Journal 53, n. 1 (gennaio 2016): 60–71. http://dx.doi.org/10.1139/cgj-2014-0412.
Kleib, Joelle, Mouhamadou Amar, Georges Aouad, Xavier Bourbon, Mahfoud Benzerzour e Nor-Edine Abriak. "The Use of Callovo-Oxfordian Argillite as a Raw Material for Portland Cement Clinker Production". Buildings 12, n. 9 (10 settembre 2022): 1421. http://dx.doi.org/10.3390/buildings12091421.
Di Donna, Alice, Pascal Charrier, Simon Salager e Pierre Bésuelle. "Self-sealing capacity of argillite samples". E3S Web of Conferences 92 (2019): 03005. http://dx.doi.org/10.1051/e3sconf/20199203005.
Zhang, Xiang, Gilles Duveau e Jean-Baptiste Colliat. "Numerical prediction of gas migration properties in Callovo-Oxfordian (COx) argillite using morpho-mathematical operations". International Journal for Numerical and Analytical Methods in Geomechanics 42, n. 10 (6 aprile 2018): 1125–43. http://dx.doi.org/10.1002/nag.2776.
Lassin, Arnault, Nicolas Marty, Benoît Henry, Joachim Trémosa, Hélène Gailhanou, Benoît Madé, Scott Altmann e Eric C. Gaucher. "Equilibrium Partial Pressure of CO2 in the Callovo-Oxfordian Argillite as a Function of Relative Humidity". Procedia Earth and Planetary Science 7 (2013): 459–62. http://dx.doi.org/10.1016/j.proeps.2013.03.083.
Tesi sul tema "Argilite du Callovo-Oxfordien (Cox)":
Zhang, Wang. "Contribution à l'étude expérimentale du comportement mécanique des argilites du Callovo-Oxfordien : effets du chemin de chargement et de la température". Thesis, Université de Lille (2018-2021), 2021. https://pepite-depot.univ-lille.fr/ToutIDP/EDENGSYS/2021/2021LILUN037.pdf.
Callovo-Oxfordian (COx) claystone has been investigated for several decades in France in the context of geological disposal of radioactive waste. A large number of laboratory tests and in-situ experiments have been conducted for the characterization of short and long thermo-hydromechanical behavior as well as gas flow diffusion property of this clayey rock. However, some aspects still need further investigation, among others, effects of loading paths and temperature on short and long-term mechanical responses. This thesis brings a new contribution to previous works on these open aspects. It is composed of three parts.In the first part, the influence of the loading path on the short-term mechanical behavior of COx claystone is considered. Based on theoretical analysis of stress path around the underground cavity, two particular loading paths with two different values of Lode angle are selected, namely lateral decompression and axial extension under constant mean stress. A series of tests with different values of mean stress are performed. Unloading-reloading cycles are involved in the tests. The obtained results are then analyzed and the emphasis is put on the influences of loading path (Lode angle) on the failure strength and induced damage process.The second part is devoted to studying the thermal effect on the short-term mechanical behavior of COx claystone. For this purpose, a series of laboratory tests, with both loading paths (axial extension and lateral decompression) and different values of temperature are performed. Based on the obtained results, the effects of temperature on the elastic property and failure strength are discussed for the two loading paths.In the third part, we are interested in investigating the effect of loading paths and temperature on the long-term mechanical behavior of COx claystone. A series of creep tests are then performed under two loading paths and with different values of temperature. The obtained test results are analyzed and discussed by putting the emphasis on the influences of loading path and temperature on creep deformation kinetics
Maia, Flávia Marina Serafim. "Impact de l'élévation de la temperature jusqu'à 80ºC sur le comportement des radionucléides dans le callovo-oxfordien : application à l'uranium". Thesis, Ecole nationale supérieure Mines-Télécom Atlantique Bretagne Pays de la Loire, 2018. http://www.theses.fr/2018IMTA0078/document.
The aim of this study was to understand and quantify the behaviour of U(VI) on the Callovo-Oxfordian(COx) clay which is envisioned to host high-level radioactive waste in France. The temperature effect up to 80°C on this behaviour was particularly studied. The first part of the work focussed on the thermodynamic properties of the calcium uranyl carbonate aqueous complexes which govern U(VI) speciation in solution. They were measured indirectly by sorption-based methodologies under controlled pCO₂ and pH. The results indicate that the temperature does not favour the formation of CaUO₂(CO₃)₃²⁻ (log₁₀ βº₁₁₃ = 27,3 ± 0,3 ; ΔrHº = -27,4 ± 8 kJ/mol) and does not affect the formation of Ca₂UO₂(CO₃)₃(aq)(log₁₀ βº₂₁₃ = 29,7 ± 0,3 ; ΔrHº = 0 ± 2 kJ/mol). A bottom-up approach with the published “2SPNE SC/CE”model was used for describing the sorption processes, with the assumption that the clay fraction of the COx (Illite, andI/S) governs U(VI) sorption.The model was successfully applied to reproduce a wealth of experimental data obtained with illite, the COₓ clay fractionand the COₓ clay rock as a function of key parameters (pH, pCO2, [U(VI)], [Ca]) at 20 °C. The sorption on COₓ conditions is mainly governed by the sorption of U(VI)-CO3 complexes and a new sorption constant is proposed for illite. An increase in temperature to 80 °C leads to an in-crease of U(VI) retention on COx. This increase is ac-companiedby a change of both pCO₂ and pH. The sorption model developed at 20 °C, together with the thermodynamic parameters describing U(VI) speciation in solution, can explain this increase but without obtaining a good agreement with the experiment. The model is improved by considering ΔrHº values for sur-face complexation reactions obtained for the U(VI))/illite system
Zhang, Yuhao. "Etude expérimentale et modélisation du comportement poromécanique d'une roche argileuse". Electronic Thesis or Diss., Université de Lille (2022-....), 2023. https://pepite-depot.univ-lille.fr/ToutIDP/EDENGSYS/2023/2023ULILN061.pdf.
This work has been carried out in the context of studies for the geological disposal of radioactive waste. The main objective is to complete previous works on the characterization of poromechanical behavior of the Callovo-Oxfordian (COx) clay, which is envisaged as the geological barrier in France. The work is composed of two parts.In the first part, an experimental study is carried out. Laboratory tests on saturated samples are carried out to estimate Biot's coefficient under hydrostatic compression on the one hand, and its evolution during deviatoric loading on the other. Tests were then conducted under undrained conditions. Two loading paths were considered: triaxial compression with constant confining pressure and axial extension with constant mean stress. In particular, we studied the variation in pore pressure as a function of deviatoric loading and its influence on the material's resistance to fracture.The second part is devoted to numerical modelling. A new plasticity criterion is proposed, taking into account the effect of the Lode angle. The validity of the effective Terzaghi stress in the plastic deformation and fracture criterion is studied. Based on this criterion, a plastic model is formulated. The associated parameters are identified. The proposed model is used to simulate several series of laboratory tests
Sun, Yufeng. "Time-dependent hydromechanical behaviour of callovo-oxfordian claystone by anatytical and multiscale numerical methods". Electronic Thesis or Diss., Vaulx-en-Velin, École nationale des travaux publics de l’État, 2023. http://www.theses.fr/2023ENTP0009.
In the context of radioactive waste repository, the time-dependent hydromechanical behaviour of the Callovo-Oxfordian (COx) claystone is investigated to ensure the safety conditions required for long-term repository of radioactive wastes.The first two parts of the study are based on the phenomenological approach carried out directly at the macroscale. Firstly, a quasi-analytical model for the hydromechanical behaviour of a deep spherical cavity excavated in a dilatant poro-viscoplastic rock mass is presented, considering three stages of a simplified life cycle: excavation, free convergence and post-closure. Subsequently, the sensitive and probability analyses are carried out using the finite element code Cast3M toinvestigate the time-dependent extent of the Excavation Damaged Zone (EDZ) which refers to a region characterized by significant and mainly irreversible changes in geochemical and hydromechanical properties. In the following, a multiscale numerical approach is employed to investigate its creep and damage behaviour under mechanical condition. Firstly, a micromechanics-based model within the finite element square (FE2) framework is developed to model the short-term and long-term behaviours of saturated COx claystone. For the viscous behaviour, two microscale mechanisms have been introduced: the viscoplasticity of the clay aggregates and the viscoelasticity of their contacts. Then, the creep model of COx claystones developed at small scale is applied to model the large-scale creep behaviour at laboratory and gallery scales. From simulation results of laboratory scale, a clear three-stage creep process is reproduced, including the primary creep stage, second creep stage and tertiary creep stage. At the gallery scale, the long-term effect of viscosity on the gallery convergences, the evolution of EDZ, and the long-term drainage and pore pressure around a gallery are investigated. Finally, the above developed double-scale creep model used to simulate saturated cracked medium is extend to partial saturated case to study the interaction between rock and the atmosphere occurs through air circulation within underground galleries. The emphasis is to study the effect of the gallery air ventilation on hydromechanical behaviour of host rock. The model predictions reproduce the drainage and desaturation kinetics of undisturbed and damaged rock
Scholtus, Nicolas. "Altération pédogénétique des argilites du Callovo-Oxfordien soumises à la végétalisation". Vandoeuvre-les-Nancy, INPL, 2003. http://www.theses.fr/2003INPL056N.
Menaceur, Hamza. "Comportement thermo-hydro-mécanique et microstructure de l'argilite du Callovo-Oxfordien". Thesis, Paris Est, 2014. http://www.theses.fr/2014PEST1167/document.
The development of nuclear energy in recent years requires safe solutions for the storage of radioactive waste. A solution proposed for high activity radioactive waste is the storage indeep low permeability geological formations such as claystones. In this perspective, Andra, the French agency for the management of radioactive wastes, supported investigations on theshort and long term behaviour of the Callovo-Oxfordian (COx) claystone, considered as apotential host rock in France. In this framework, a microscopic and macroscopic experimental study on the thermo-hydro-mechanical behaviour of COx claystone was carried out. In this work, a microstructure investigation of the water retention properties of the Cox claystone was performed. The water retention properties were determined by controlling suction through the vapour phase, with also the monitoring of volume changes and changes indegree of saturation as a function of suction along the drying and wetting paths. The study was completed by a microstructure investigation based on the use of mercury intrusion porosimetry on freeze-dried specimens. It was observed that the concepts governing the hydration of smectites appeared useful to better understand the effects of changes in water content and suction on the microstructure of COx claystone. In a second step, the compression-swelling behaviour of the COx claystone was related to micro structure features by performing high pressure oedometer compression tests and byrunning mercury intrusion porosimetry tests and scanning electron microscope observationson specimens submitted to compression and stress release. The results obtained showed that the potential of swelling was linked to the density of cracks generated during compression. The thermo-mechanical behaviour of fully saturated COx claystone specimens was investigated from shear and drained heating tests using a hollow cylinder triaxial device specially developed for low permeability materials. The shear tests at 25°C evidenced lowershear strength on specimens with higher porosity. The preliminary results obtained at 80°Cevidenced a more ductile response, with slightly smaller shear strength and little changes of the elastic parameters at elevated temperature. Drained isotropic heating tests confirmed thecontracting volumetric plastic behaviour of the COx argillite, similar to normally consolidated clays. The effect of thermal pressurisation of the pore water on a specimen with a pre-existingshear plan was investigated. The results showed that undrained heating under shear stress decreased the effective stress, bringing back the sheared specimen to failure. The self-sealing properties of COx claystone at 25 and 80°C were investigated by conducting steady state permeability tests on sheared specimens at various stages. The results showed that the overall permeability of the sheared specimen at 25 and 80°C was comparable to that before shearing, confirming the good self-sealing properties of COx claystone
Bregoin, Stéphanie. "Variabilité spatiale et temporelle des caractéristiques du Callovo-Oxfordien de Meuse/Haute-Marne". Paris, ENMP, 2003. http://www.theses.fr/2003ENMP1297.
Durce, Delphine. "Interactions et transfert de macromolécules organiques et de colloïdes dans l'argile nanoporeuse du Callovo-Oxfordien". Nantes, 2011. http://www.theses.fr/2011NANT2008.
Low permeability Callovo-Oxfordian clay rock is under consideration as a possible host rock for long-term disposal of radioactive waste in a deep geological repository. Radionuclides move slowly in the Callovo-Oxfordian rock but complexation with colloidal species or organic macromolecules, naturally present in the pore solution or generated by storage, may enhance their migration. These colloidal and organic species can be retained by the clay through chemical interactions or physical immobilization (filtration). To increase the understanding of their mobility, batch and transport experiments (percolation) were performed on crushed and whole rock samples using Se(0) colloids and the following organic acids: succinic acid (118Da), citric acid (192Da) and polymaleic acid (1900Da). Adsorption studies on Se(0) colloids show the retention of this species on the clay. However, the properties of these colloids are masked by the presence of the protein required for the stabilization of the suspension. Adsorption studies on organic acids highlight the retention of these species (between 2. 2. 10-3 and 4. 20. 10-2 mol/kg of rock) which is strongly irreversible and which depends on the Ca2+ ion concentrations in solution and on the capacity of organic acids to complex with this ion. Percolation experiments performed on succinic and polymaleic acids show that despite their size, these molecules are mobile in the pore water of the compact rock. Filtration was not observed. Interactions rock/organic molecule were similar to those identified on a crushed rock
Mohajerani, Mehrdokht. "Etude expérimentale du comportement thermo-hydro-mécanique de l'argilite du Callovo-Oxfordien". Phd thesis, Université Paris-Est, 2011. http://pastel.archives-ouvertes.fr/pastel-00647890.
He, Zheng. "Quelques contributions à la modélisation micromécanique de l’argilite du Callovo-Oxfordien". Thesis, Lille 1, 2012. http://www.theses.fr/2012LIL10166/document.
This work focuses on the development of micromechanical modeling tools to study the behavior of the Callovo-Oxfordian argillite. This geomaterial is modeled as a porous heterogeneous medium at three distinct spatial scales. The microscopic scale reveals the heterogeneity of the clay phase on which the morphological model synthesized as a porous polycrystal was based. Numerical predictions of the elastoplastic and transversely isotropic clay phase considering mechanical interactions between the crystals are performed by using an incremental approach. Then, a poroelastic model for saturated granular materials with imperfect interface effects is proposed. On the basis of this poroelastic model and the nonlinear homogenization, we showcase the impact of the cohesive Mohr-Coulomb imperfect interfaces on the strength criterion of granular geomaterials. Finally, we propose a complete model for the prediction of the strength of Callovo-Oxfordian argillite under the assumption that the clay matrix is a porous material with the solid phase described by a perfectly plastic Drucker-Prager criterion. It is important to note that the explored failure mechanism includes the possibility of a strain concentration at the (rigid) inclusion-matrix interface. This model is analyzed in detail and its predictions appear quite convincing