Articles de revues : « UL-94 vertical »

1

Hoang, Quy Thi Dong, Cuong Ngoc Hoang, Anh Huynh Tram Pham, Vien Tri Thiem, Huong Ngoc Nhu Nguyen et Vy Thi Kim Trinh. « FLAME RETARDATION PERFORMANCES OF HALOGEN-FREE FLAME RETARDANT WHEN APPLIED TO UNSATURATED POLYESTER ». Science and Technology Development Journal 15, n^o 3 (30 septembre 2012) : 73–79. http://dx.doi.org/10.32508/stdj.v15i3.1819.

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In order to improve fire performance of polymeric materials, phosphorus flame retardants (FRs) were studied in an attempt to obtain UL-94 ratings for materials based on unsaturated polyester. The fire behaviors and thermal stability properties were evaluated using UL-94 vertical test and thermogravimetric analysis (TGA). The UL-94 test results show that V-1 rating is achieved. TGA and UL-94 results concluded that phosphorus FRs employed in this study works on both vapor phase and condensed phase, but the vapour phase is dominant mode of action. These suggested that the addition of FRs probably does affect on the char layer formed during combustion behavior and increase the flame retardant properties in the case of condensed phase mode of action. The efficiency of flame retardant of phosphorus also highly depends upon the phosphorus moieties generated during the decomposition which further converted to radical capturing species, and consequently quenching the flame in the case of gas phase mode of action. These FRs can be promising candidates that replace the halogen-based.

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Jin, Tian-Xiang, Xian-Yin Zhang, Yun-Feng Tao, Dan Wang, Feng Chen et Qiang Fu. « A novel biodegradable phosphorus-containing copolyester with preferable flame retardancy and mechanical properties ». RSC Advances 5, n^o 75 (2015) : 61364–70. http://dx.doi.org/10.1039/c5ra11390c.

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Zhang, Zhenya, Mingcheng Yang, Kunpeng Cai, Yang Chen, Shubo Liu, Wentao Liu et Jilin Liu. « Effect of the Flame Retardants and Glass Fiber on the Polyamide 66/Polyphenylene Oxide Composites ». Materials 15, n^o 3 (21 janvier 2022) : 813. http://dx.doi.org/10.3390/ma15030813.

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In this work, polyamide 66/polyphenylene oxide (PA66/PPO) composites, including the flame retardants 98 wt% aluminum diethylphosphinate + 2 wt% polydimethylsiloxane (P@Si), Al(OH)3-coated red phosphorus (RP*), and glass fiber (GF), were systematically studied, respectively. The limiting oxygen index (LOI), UL-94 vertical burning level, and thermal and mechanical properties of the PA66/PPO composites were characterized. The results showed that the P@Si and RP flame retardants both improved the LOI value and UL-94 vertical burning level of the PA66/PPO composites, and PA66/PPO composites passed to the UL-94 V-0 level when the contents of P@Si and RP* flame retardants were 16 wt% and 8 wt%. On the other hand, the mechanical properties of the PA66/PPO composites were reduced from a ductile to a brittle fracture mode. The addition of GF effectively made up for these defects and improved the mechanical properties of the PA66/PPO composites containing the P@Si and RP*, but it did not change the fracture mode. P@Si and RP* flame retardants improved the thermal decomposition of PA66/PPO/GF composites and reduced the maximum mass loss rates, showing that the PA66/PPO/GF composites containing the P@Si and RP* flame retardants could be used in higher-temperature fields.

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Pham, Linh Thi Thuy, Hien Thi Thu Nguyen et Quy Thi Dong Hoang. « Flame retardation performances of non-halogen flame retardant applied to composite PVC-wood flour ». Science and Technology Development Journal 18, n^o 4 (30 décembre 2015) : 16–22. http://dx.doi.org/10.32508/stdj.v18i4.905.

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In order to improve the fire performance of composite materials, halogen-free flame retardant (diamonium hydrogen phosphate- DAP) was studied in an attempt to obtain UL-94 ratings for composite PVC-wood flour (PVC-WF). The fire behaviors and thermal stability properties were evaluated using UL- 94 vertical test, LOI test and thermogravimetric analysis (TGA). The UL- 94 test results show that V-0 rating is achieved at 1.5 wt% of DAP loading. The incorporation of halogene-free flame retardant (FR) increases the flame retardant properties as well as the amounts of charred residues protecting the mixture from further degradation. This assertion can be accepted when observing that the char residual of PVC-WF/DAP mixture at 600 oC is much higher than that of neat PVC-WF. The char layer may limit the amount of fuel available and insulate the underlying composite material from the flame and, thus, inhibit further degradation. This FR is a promising candidate that could replace the halogenbased flame retardant.

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Liu, Sun, Yi Lun Tan, Si Chun Shao, Yin Yin Hui et Zhi Han Peng. « Synthesis and Characterization of a Novel Polyhydroxy Triazine Charring Agent and Properties of its Flame Retarded Polyproylene ». Advanced Materials Research 746 (août 2013) : 23–27. http://dx.doi.org/10.4028/www.scientific.net/amr.746.23.

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In this study, a novel polyhydroxy triazine charring agent (PT-CA) was synthesized through the solid-state reaction of triglycidyl isocyanurate (TGIC) and pentaerythritol. Meanwhile, the molecular structure of the chemical compound was determined by FTIR, elemental analysis and thermalgravimetric analysis (TG).Then it is combined with microencapsulated ammonium polyphosphate (MAPP) and melamine phosphate (MP) to impart flame retardance and dripping resistance for polypropylene (PP).The fire performance of treated PP was investigated by limiting oxygen index (LOI) and vertical burning test (UL-94).It has been found that the treated PP with the optimal flame retardant formulation of MAPP:MA:PTCA=18:6:6 (weight ratio, formulation 10) gives an LOI of 31.5 and UL-94 V-0 rating.

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Luo, Xing, Min He, Jian Bing Guo et Bin Wu. « Flame Retardancy and Mechanical Properties of Brominated Flame Retardant for Long Glass Fiber Reinforced Polypropylene Composites ». Advanced Materials Research 750-752 (août 2013) : 85–89. http://dx.doi.org/10.4028/www.scientific.net/amr.750-752.85.

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The effects of brominated flame retardant which composed of decabromodiphenyl ethane (DBDPE) and antimonous oxide (AO) on long glass fiber reinforced polypropylene (LGFPP) were investigated by means of limiting oxygen index (LOI), vertical burning (UL-94), thermogravimetry analysis (TGA), and mechanical properties. With the increase of DBDPE-AO content, the LOI values of DBDPE-AO/LGFPP composites increased from 21 to 27.6, and when the content of DBDPE-AO was 16wt%, the composites passed the V-0 rating in UL-94 testing. The experimental results showed that the brominated flame retardant improved flame retardancy of LGFPP, which was proved by the TGA testing. Whats more, the mechanical properties of composites even improved compared with pure LGFPP.

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Wang, Yong, et Jun Zhang. « Thermal stabilities of drops of burning thermoplastics under the UL 94 vertical test conditions ». Journal of Hazardous Materials 246-247 (février 2013) : 103–9. http://dx.doi.org/10.1016/j.jhazmat.2012.12.020.

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Yang, Hangfeng, Hangbo Yue, Xi Zhao, Minzimo Song, Jianwei Guo, Yihua Cui, Juan P. Fernández-Blázquez et De-Yi Wang. « Polycarbonate/Sulfonamide Composites with Ultralow Contents of Halogen-Free Flame Retardant and Desirable Compatibility ». Materials 13, n^o 17 (19 août 2020) : 3656. http://dx.doi.org/10.3390/ma13173656.

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A novel halogen-free flame retardant containing sulfonamide, 1,3,5,7-tetrakis (phenyl-4-sulfonamide) adamantane (FRSN) was synthesized and used for improving the flame retardancy of largely used polycarbonate (PC). The flame-retardant properties of the composites with incorporation of varied amounts of FRSN were analyzed by techniques including limited oxygen index, UL 94 vertical burning, and cone calorimeter tests. The new FR system with sulfur and nitrogen elements showed effective improvements in PC’s flame retardancy: the LOI value of the modified PC increased significantly, smoke emission suppressed, and UL 94 V-0 achieved. Typically, the composite with only 0.08 wt% of FRSN added (an ultralow content) can increase the limiting oxygen index (LOI) value to 33.7% and classified as UL 94 V-0 rating. Furthermore, the mechanical properties and SEM morphology indicated that the FRSN has very good compatibility with PC matrix, which, in turn, is beneficial to the property enhancement. Finally, the analysis of sample residues after burning tests showed that a high portion of char was formed, contributing to the PC burning protection. This synthesized flame retardant provides a new way of improving PC’s flame retardancy and its mechanical property.

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Dai, Pei Bang, Lin Ying Yang, Ting Zheng, Chang Qin et Qi Chen Tang. « Flame Retardant Effect of a Modified Intumescent Flame Retardant on a Rigid Polyurethane Foam ». Key Engineering Materials 748 (août 2017) : 51–54. http://dx.doi.org/10.4028/www.scientific.net/kem.748.51.

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A rigid polyurethane (PU) flame retardant composite foam was prepared by the compounding of polyols and diisocyanates with a modified intumescent flame retardant (MIFR). The MIFR was based on the three components of intumescent flame retardant normally used and was modified in a surfactant TX-10 solution. The flame retardancy of the PU flame retardant composite foams were evaluated by using the limiting oxygen index (LOI), the UL-94 (vertical flame) test and scanning electron microscopy (SEM). When MIFR was fixed at 20.0 wt% in PU/MIFR composite foams, the MIFR could enhance the flame retardancy and pass V-0 rating of UL-94 test. The microstructures observed by SEM demonstrate that a suitable amount of MIFR can promote formation of compact intumescent charred layers in PU foams.

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Hu, Xiao Ping, Yu Yang Guo, Quan Min Xu, Hui Min Heng et Liang Jun Li. « Synthesis of a Novel Intumescent Flame Retardant Oligomer and its Application in ABS Copolymer ». Advanced Materials Research 391-392 (décembre 2011) : 204–8. http://dx.doi.org/10.4028/www.scientific.net/amr.391-392.204.

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A novel intumescent flame retardant oligomer containing phosphorous-nitrogen structure (PSPTR) was synthesized and characterized by Fourier Transform Infrared (FTIR) and Mass Spectrometry (MS). The thermal behavior of PSPTR was investigated by thermogravimetric analysis (TGA). The TGA data shows that PSPTR has a high initial temperature of thermal degradation and a high char residue of 41.18wt% at 700 . A novel intumescent ﬂame retardant (IFR) system, which is composed of PSPTR and novolac phenol (NP), was used to impart ﬂame retardancy of ABS. The combustion behaviors of the ABS/IFR composites were investigated by Limiting Oxygen Index (LOI) and UL-94 tests. When the content of IFR (PSPTR:NP=1:1 mass ratio) is 30 wt%, the LOI value of ABS/IFR reaches 28.2, and the vertical burning test reaches UL-94 V-1 rating.

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Zhang, Tie, Weishi Liu, Meixiao Wang, Ping Liu, Yonghong Pan et Dongfa Liu. « Synthesis of a boron/nitrogen-containing compound based on triazine and boronic acid and its flame retardant effect on epoxy resin ». High Performance Polymers 29, n^o 5 (25 mai 2016) : 513–23. http://dx.doi.org/10.1177/0954008316650929.

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With the aim of developing a novel organic flame retardant, an organic boronic acid derivative containing a triazine ring (2,4,6-tris(4-boronic-2-thiophene)-1,3,5-triazine (3TT-3BA)) was synthesized. The thermal properties of 3TT-3BA and its corresponding intermediate products were investigated by thermogravimetric analysis. The results show that 3TT-3BA has a high char yield (56.9%). The flame retardant properties of epoxy resin (EP) with 3TT-3BA were investigated by cone calorimeter, limiting oxygen index (LOI) test, and vertical burning test (UL 94). The LOI of EP with 20% 3TT-3BA is 31.2% and the UL 94 V-0 rating is achieved for EP with 20% 3TT-3BA. The flame retardant mechanism of 3TT-3BA in EP was investigated using TGA–Fourier transform infrared spectroscopy and scanning electron microscopy.

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Wang, Yong, Jun Zhang, Jinder Jow et Kenny Su. « Analysis and Modeling of Ignitability of Polymers in the UL-94 Vertical Burning Test Condition ». Journal of Fire Sciences 27, n^o 6 (30 juillet 2009) : 561–81. http://dx.doi.org/10.1177/0734904109099999.

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Kempel, Florian, Bernhard Schartel, Julio M. Marti, Kathryn M. Butler, Riccardo Rossi, Sergio R. Idelsohn, Eugenio Oñate et Anja Hofmann. « Modelling the vertical UL 94 test : competition and collaboration between melt dripping, gasification and combustion ». Fire and Materials 39, n^o 6 (24 juin 2014) : 570–84. http://dx.doi.org/10.1002/fam.2257.

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Tomiak, Florian, et Dietmar Drummer. « The Impact of β-Radiation Crosslinking on Flammability Properties of PA6 Modified by Commercially Available Flame-Retardant Additives ». Polymers 14, n^o 15 (3 août 2022) : 3168. http://dx.doi.org/10.3390/polym14153168.

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A comparative study was conducted investigating the influence of β-radiation crosslinking (β-RC) on the fire behavior of flame retardant-modified polyamide 6 (PA6). In order to provide a comprehensive overview, a variety of commercially available flame-retardant additives were investigated, exhibiting different flame retarding actions such as delusion, char formation, intumescence and flame poisoning. This study focused on the identification of differences in the influence of β-RC on fire behavior. Coupled thermal gravimetrical analysis (TGA) and Fourier transformation infrared spectroscopy (FTIR) were used to conduct changes within the decomposition processes. Dynamic thermal analysis (DTA) was used to identify structural stability limits and fire testing was conducted using the limiting oxygen index (LOI), vertical UL-94 and cone calorimeter testing. Crosslinking was found to substantially change the fire behavior observed, whereas the observed phenomena were exclusively physical for the given formulations studied: warpage, char residue destruction and anti-dripping. Despite these phenomena being observed for all β-RC formulations, the impact on fire resistivity properties were found to be very different. However, the overall fire protection properties measured in UL-94 fire tests were found to deteriorate for β-RC formulations. Only β-RC formulations based on PA6/EG were found to achieve a UL-94 V0 classification.

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Bachtiar, Erik Valentine, Katarzyna Kurkowiak, Libo Yan, Bohumil Kasal et Torsten Kolb. « Thermal Stability, Fire Performance, and Mechanical Properties of Natural Fibre Fabric-Reinforced Polymer Composites with Different Fire Retardants ». Polymers 11, n^o 4 (16 avril 2019) : 699. http://dx.doi.org/10.3390/polym11040699.

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In this study, ammonium polyphosphate (APP) and aluminum hydroxide (ALH) with different mass contents were used as fire retardants (FRs) on plant-based natural flax fabric-reinforced polymer (FFRP) composites. Thermogravimetric analysis (TGA), limited oxygen index (LOI), and the Underwriters Laboratories (UL)-94 horizontal and vertical tests were carried out for evaluating the effectiveness of these FR treatments. Flat-coupon tensile test was performed to evaluate the effects of FR treatment on the mechanical properties of the FFRP composites. For both fire retardants, the results showed that the temperature of the thermal decomposition and the LOI values of the composites increased as the FR content increases. Under the UL-94 vertical test, the FFRP composites with 20% and 30% APP (i.e., by mass content of epoxy polymer matrix) were self-extinguished within 30 and 10 s following the removal of the flame without any burning drops, respectively. However, the mechanical tensile tests showed that the APP treated FFRP composites reduced their elastic modulus and strength up to 24% and 18%, respectively. Scanning electronic microscopic (SEM) for morphology examination showed an effective coating of the flax fibres with the FRs, which improved the flame retardancy of the treated composites.

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Barbotko, S. L., M. M. Bochenkov, O. S. Volnyj, O. P. Korobeinichev et A. G. Shmakov. « STUDY OF THE EFFECT OF TWO TYPES OF FIRE RETARDANTS ON THE FLAMMABILITY OF EPOXY RESIN SAMPLES ». Proceedings of VIAM, n^o 4 (2021) : 132–40. http://dx.doi.org/10.18577/2307-6046-2021-0-4-132-140.

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Studies have been carried out to assess the effectiveness of fire retardants on the flammability of an epoxy composition – graphene and an organophosphorus compound DOPO-THPO. The concentrations of the added flame retardants were 2 and 4 % (mass). Flammability characteristics were determined using the method according to GOST 28157 (UL 94) with vertical and horizontal samples. It was found that the introduction of fire retardants reduces the flammability of the epoxy composition, but the introduction of even 4 % was insufficient to ensure self-extinguishing of the epoxy composition during vertical testing.

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Niu, Mingjun, Zhongzhou Zhang, Zizhen Wei et Wanjie Wang. « Effect of a Novel Flame Retardant on the Mechanical, Thermal and Combustion Properties of Poly(Lactic Acid) ». Polymers 12, n^o 10 (19 octobre 2020) : 2407. http://dx.doi.org/10.3390/polym12102407.

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Poly(lactic) acid (PLA) is one of the most promising biobased materials, but its inherent flammability limits its applications. A novel flame retardant hexa-(DOPO-hydroxymethylphenoxy-dihydroxybiphenyl)-cyclotriphosphazene (HABP-DOPO) for PLA was prepared by bonding 9,10-dihydro-9-oxy-10-phosphaphenanthrene-10-oxide (DOPO) to cyclotriphosphazene. The morphologies, mechanical properties, thermal stability and burning behaviors of PLA/HABP-DOPO blends were investigated using a scanning electron microscope (SEM), a universal mechanical testing machine, thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), limiting oxygen index (LOI), vertical burning (UL-94) and a cone calorimeter test (CCT). The LOI value reached 28.5% and UL-94 could pass V-0 for the PLA blend containing 25 wt% HABP-DOPO. A significant improvement in fire retardant performance was observed for PLA/HABP-DOPO blends. PLA/HABP-DOPO blends exhibited balanced mechanical properties. The flame retardant mechanism of PLA/HABP-DOPO blends was evaluated.

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Schreiber, H. « Vertical burning tests UL 94-V and IEC 249-1 (4.3.4) theoretical considerations and experimental results ». Makromolekulare Chemie. Macromolecular Symposia 74, n^o 1 (août 1993) : 349–57. http://dx.doi.org/10.1002/masy.19930740149.

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Qiao, Yihui, Yanbin Wang, Menghao Zou, Dehuan Xu, Yingtong Pan, Zhonglin Luo et Biaobing Wang. « One-Step Synthesis of Highly Efficient Oligo(phenylphosphonic Dihydroxypropyl Silicone Oil) Flame Retardant for Polycarbonate ». Polymers 11, n^o 12 (1 décembre 2019) : 1977. http://dx.doi.org/10.3390/polym11121977.

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A highly efficient flame retardant and smoke suppression oligomer, oligo(phenylphosphonic dihydroxypropyl silicone oil) (PPSO), was synthesized by a one-step reaction. The chemical structure of PPSO was confirmed by Fourier transform infrared (FTIR), 31P nuclear magnetic resonance (31P NMR), and 29Si nuclear magnetic resonance (29Si NMR). The flame-retardant effect of PPSO on the polycarbonate (PC) matrix was investigated by limiting oxygen index, UL-94 vertical burning test, and cone calorimetry, respectively. The results showed that PC/PPSO composites passed UL-94 V-0 rate testing with only 1.3 wt. % PPSO. Furthermore, the incorporation of PPSO can suppress the release of smoke. The flame-retardant mechanism was also investigated via thermogravimetric analysis-fourier transform infrared spectroscopy (TG-FTIR), field-emission scanning electronic microscopy (FE-SEM), X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy. From the result of pyrolysis gas and char residue, PPSO played a synergistic flame-retardant mechanism including the gas phase and the condensed phase.

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Li, Xiao Yan, Yan Chun Li, Chen Jie Shi, Si Si Cai, Xia Wang, Fan Fan et Ao Li. « Influence of Intumescent Flame Retardant on Flammability and Tensile Behavior of Oil-Extended SEBS ». Advanced Materials Research 749 (août 2013) : 65–70. http://dx.doi.org/10.4028/www.scientific.net/amr.749.65.

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A kind of intumescent flame retardant (IFR) were used for flame retarding of oil-extended hydrogenated styrene-butylenes-styrene (O-SEBS). The samples were systemically characterized by limited oxygen index (LOI), vertical burning test (UL-94), and scanning electron microscopy (SEM); Thermogravimetric (TG) analysis. The results showed that the IFR retardant can promote residual chars with multi-micro holes on the surface of SEBS to inhibit flame; with 45% IFR content, the LOI is 28.3 and flame retardant level is UL-94 classification of V-0, with no dripping. The morphological structures observed by SEM demonstrated that higher IFR content promote to form larger and compact films cover on bubbles of the intumescent char layer. The TG data revealed that the IFR could change the degradation behavior of the O-SEBS, enhance the thermal stability and increase the char residue, The tensile strength of all the O-SEBS/IFR blends had the tensile strength of more than 4MPa and the elongation of more than 850%.

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Cheng, Xi, Jianming Wu, Yulin Li, Chenguang Yao et Guisheng Yang. « SEBS-based thermoplastic elastomers containing aluminum hypophosphite and melamine cyanurate : Thermal degradation, flame retardancy, and mechanical properties ». Journal of Fire Sciences 37, n^o 2 (mars 2019) : 137–54. http://dx.doi.org/10.1177/0734904119830591.

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Aluminum hypophosphite combined with melamine cyanurate and poly(phenylene oxide) was applied to flame-retard TPE-S system (blends of SEBS and polyolefin). The flame-retardant properties of the TPE-S/AHP/MCA/PPO were investigated by LOI and vertical burning test (UL-94). The results indicated that TPE-S containing 16 wt% AHP, 20 wt% MCA, and 10 wt% PPO reached a V-0 rating in the UL-94 test, and its LOI value was 28.2%. It performed well in the cone calorimeter (reduction in peak heat release rate from 2001 to 494 kW m−2). Thermogravimetric-Fourier transform infrared spectroscopy tests showed that AHP and MCA acted in gaseous phase, while AHP and PPO helped to form char residue. The SEM graphs demonstrated that continuous and compact films cover bubbles of the char layer in TPE-S/AHP/MCA/PPO. The proposed flame-retardant mechanisms of such systems were summarized.

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Peng, Sha, Ming Zhou, Feiyan Liu, Chang Zhang, Xueqing Liu, Jiyan Liu, Liyong Zou et Jia Chen. « Flame-retardant polyvinyl alcohol membrane with high transparency based on a reactive phosphorus-containing compound ». Royal Society Open Science 4, n^o 8 (août 2017) : 170512. http://dx.doi.org/10.1098/rsos.170512.

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Flame-retardant polyvinyl alcohol (PVA) membranes with high transparency and flexibility were prepared by mixing an aqueous solution of a phosphorus-containing acrylic acid (AOPA) with PVA. The reaction between AOPA and PVA, the transparency, the crystallinity and the flexibility of the membrane were investigated with Fourier transform infrared spectrometry (FTIR), UV–vis light transmittance, X-ray diffraction and tensile tests, respectively. The limited oxygen index (LOI) and vertical flame (UL 94 VTM), microscale combustion calorimetry, thermogravimetric analysis (TGA) and TGA-FTIR were employed to evaluate the flame retardancy as well as to reveal the corresponding mechanisms. Results showed that PVA containing 30 wt% of AOPA can reach the UL 94 VTM V0 rating with an LOI of 27.3% and retain 95% of the original transparency of pure PVA. Adding AOPA reduces crystallinity of PVA, while the flexibility is increased. AOPA depresses the thermal degradation of PVA and promotes char formation during combustion. The proposed decomposition mechanism indicates that AOPA acts mainly in the condensed phase.

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Yang, Zheng, Xueting Chen, Shike Lu, Zhenhua Wang, Jiantong Li, Baoying Liu, Xiaomin Fang, Tao Ding et Yuanqing Xu. « Synergistic Flame Retardant Properties of Polyoxymethylene with Surface Modified Intumescent Flame Retardant and Calcium Carbonate ». Polymers 15, n^o 3 (20 janvier 2023) : 537. http://dx.doi.org/10.3390/polym15030537.

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Ammonium polyphosphate (APP) was successfully modified by a titanate coupling agent which was compounded with benzoxazine (BOZ) and melamine (ME) to become a new type of intumescent flame retardant (Ti-IFR). Ti-IFR and CaCO3 as synergists were utilized to modify polyoxymethylene (POM), and the flame-retardant properties and mechanism of the composites were analyzed by vertical combustion (UL-94), limiting oxygen index (LOI), TG-IR, and cone calorimeter (Cone), etc. The results show that Ti-IFR can enhance the gas phase flame retardant effect, while CaCO3 further strengthens the barrier effect in the condensed phase. When they were used together, they can exert their performance, respectively, at the same time showing excellent synergistic effect. The FR-POM composite with 29% Ti-IFR and 1% CaCO3 can pass the UL-94 V0 level. The LOI reaches 58.2%, the average heat release (Av HRR) is reduced by 81.1% and the total heat release (THR) is decreased by 35.3%.

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Linh, Pham Thi Thuy, et Hoang Thi Dong Quy. « Thermoplastic polyurethane flame retardant using phosphorus/phosphorus-nitrogen compounds ». Science and Technology Development Journal - Natural Sciences 2, n^o 1 (6 janvier 2019) : 91–95. http://dx.doi.org/10.32508/stdjns.v2i1.680.

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In order to improve fire performance of thermoplastic polyurethane (TPU) material, halogen-free flame retardants (triphenylphosphate- TPP and diamonium hydrogen phosphate-DAP) were studied in an attempt to obtain UL-94V ratings. The fire behaviors and thermal stability properties were evaluated using UL-94 vertical test and thermogravimetric analysis (TGA). The UL- 94V results showed that V-0 ratings were achieved at 5 wt% of DAP or 7.5 wt% loading of TPP. The incorporation of these flame retardant (FR) increases the flame retardant properties as well as the amounts of charred residues protecting the mixture from further degradation. This assertion could be accepted when observing that the char residual of TPU/DAP mixture at 500–600oC was much higher than that of neat TPU. The char layer limited the amount of fuel available and insulate the underlying composite material from the flame and, thus, make further degradation more difficult. The mechanism of flame retardants was also discussed in this study.

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Liu, Nian, Na Wang, Lingtong Li, Weidi He, Jianbing Guo, Xiaolang Chen, Kun Zhang et Hong Wu. « Modified expandable graphite as an effective flame retardant for LLDPE/EVA composites filled with Mg(OH)2/Al(OH)3 ». Journal of Thermoplastic Composite Materials 33, n^o 7 (24 février 2019) : 938–55. http://dx.doi.org/10.1177/0892705718815539.

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The flammability, thermal properties, and synergistic effects of modified expandable graphite (MEG) with magnesium hydroxide (MH) and aluminum hydroxide (ATH) on the linear low-density polyethylene/ethylene vinyl acetate (LLDPE/EVA) blends are investigated by Underwriters Laboratories-94 (UL-94) vertical combustion test, limiting oxygen index (LOI), thermogravimetric analysis (TGA), cone calorimeter test (CCT), and scanning electron microscopy (SEM). The results show that the MEG improves the flame-retardant efficiency of LLDPE/EVA blends. The addition of MEG apparently improves the LOI values and the UL-94 rating of LLDPE/EVA composites. The data obtained from the CCT show that the heat release rate (HRR), the total heat release (THR), and the gas production rate of composites with MEG decrease remarkably with increasing the content of MEG. When 10 phr of MEG is added, the char residues of LEMEG10 increase to 38.2% from 2.7% of LLDPE/EVA. The results of SEM and CCT present that MEG can improve the quality of char layers. The rate of char formation is enhanced also due to the existence of MEG, which plays an important role to improve the flame retardancy of the LLDPE/EVA composites.

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Zhang, Qing, Huiyuan Liu, Junxia Guan, Xiaochun Yang et Baojing Luo. « Synergistic Flame Retardancy of Phosphatized Sesbania Gum/Ammonium Polyphosphate on Polylactic Acid ». Molecules 27, n^o 15 (25 juillet 2022) : 4748. http://dx.doi.org/10.3390/molecules27154748.

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Phosphating sesbania gum (DESG) was obtained by modifying sesbania gum (SG) with 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) and endic anhydride (EA). The structure of DESG was determined using Fourier transform infrared (FTIR) spectroscopy and nuclear magnetic resonance spectroscopy (1H-NMR). Flame-retardant polylactic acid (PLA) composites were prepared by melt-blending PLA with DESG, which acted as a carbon source, and ammonium polyphosphate (APP), which acted as an acid source and a gas source. The flame retardancy of the PLA composite was investigated using vertical combustion (UL-94), the limiting oxygen index (LOI) and the cone calorimeter (CONE) test. Thermal properties and morphology were characterized via thermogravimetric analysis (TGA) and field emission scanning electron microscopy (FESEM), respectively. Experimental results indicated that when the mass ratio of DESG/APP was equal to 12/8 the LOI value was 32.2%; a vertical burning test (UL-94) V-0 rating was achieved. Meanwhile, the sample showed a lowest total heat release (THR) value of 52.7 MJ/m2, which is a 32.5% reduction compared to that of neat PLA. Using FESEM, the uniform distribution of DESG and APP in the PLA matrix was observed. The synergistic effect of DESG and APP effectively enhanced the flame retardancy of PLA. Additionally, the synergistic mechanism of DESG and APP in PLA was proposed.

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Meng, Lingyu, Xiangrui Li, Mingli Liu, Chunfeng Li, Lipeng Meng et Sen Hou. « Modified Ammonium Polyphosphate and Its Application in Polypropylene Resins ». Coatings 12, n^o 11 (13 novembre 2022) : 1738. http://dx.doi.org/10.3390/coatings12111738.

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Herein, a simple and environment-friendly method of coupling agent treatment of APP (ammonium polyphosphate) is provided and an optimum process of modification via coupling agent is identified. The effects of coupling agent type, dosage, modification time, and modification temperature on the modification of ammonium polyphosphate (APP) were investigated using an orthogonal experimental design. The modified ammonium polyphosphate (KAPP) was characterized under optimal process conditions using Fourier Transform Infrared (FT-IR), X-ray Diffraction (XRD), Thermogravimetry (TG), and Scanning Electron Microscope (SEM) analysis. The treatment greatly improved the water solubility, dispersibility, and thermal stability of KAPP; and the application of KAPP in polypropylene (PP) was investigated. The flexural properties, thermal stability, and flame retardancy were studied using mechanical testing, thermogravimetric analysis, oxygen index, and UL-94 vertical combustion. The results show that the KAPP-added polypropylene composites have better bending properties when compared with the APP-added PP composites. SEM analysis suggests that the surface of KAPP became smoother and flat; dispersion was better, compatibility with the PP matrix was improved, and there were no prominent voids and gaps in the cross-section. A different degree of improvement in flame retardancy was also observed as per the LOI and vertical combustion results, wherein the PP composites prepared by adding 20% KAPP achieved the LOI of 27.6% and passed the UL-94 test with V-0 rating.

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Kheyrabadi, Rasool, Hossein Rahmani et S. Heydar Mahmoudi Najafi. « Flame-retardant halogen-free polymers using phosphorylated hexaglycidyl epoxy resin ». High Performance Polymers 30, n^o 2 (6 février 2017) : 202–10. http://dx.doi.org/10.1177/0954008316688759.

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Flame-retardant halogen-free epoxy resin, containing phosphorus and nitrogen atoms in the main chain, was synthesized through the curing of tris(3-(bis(oxiran-2-ylmethyl)amino)phenyl)phosphine oxide (HGE, hexaglycidyl epoxy monomer), starting from tris(3-aminophenyl) phosphine oxide (TAPO) and epichlorohydrin. The molecular structure of HGE with molecular weight 660 was confirmed using Fourier transform infrared, nuclear magnetic resonance, and liquid chromatography–mass spectrometry techniques. Epoxy equivalent weight determined by titration method was 120. The thermal curing behavior of the HGE/TAPO was investigated by differential scanning calorimetry. An intense exotherm due to curing reaction was observed in the temperature range from 123°C to 215°C. The HGE cured with TAPO, 4,4′-diaminodiphenylsulfone (DDS), and 1,5-diaminonaphthalene (DAN) and the thermal behaviors were studied by thermogravimetric analysis. The flame retardancy properties of the HGE/TAPO, DDS, and DAN were evaluated by vertical burning test (UL-94 V). The high performance cured epoxy resins showed high thermal stability and UL-94 V-0 flame retardancy rating.

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Lv, Wenyan, Jun Lv, Cunbing Zhu, Ye Zhang, Yongli Cheng, Linghong Zeng, Lu Wang et Changrong Liao. « Thermal Stabilities and Flame Retardancy of Polyamide 66 Prepared by In Situ Loading of Amino-Functionalized Polyphosphazene Microspheres ». Polymers 15, n^o 1 (31 décembre 2022) : 218. http://dx.doi.org/10.3390/polym15010218.

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The flame-retardant polyamide 66 composites (FR-PA66) were prepared by in situ loading of amino-functionalized polyphosphazene microspheres (HCNP), which were synthesized in the laboratory and confirmed by a Fourier transform infrared spectrometer (FTIR), scanning electron microscope (SEM), and transmission electron microscope (TEM). The thermal stabilities and flame retardancy of FR-PA66 were measured using thermogravimetric analysis (TGA), a thermogravimetric infrared instrument (TG-IR), the limiting oxygen index (LOI), the horizontal and vertical combustion method (UL-94), and a cone calorimeter. The results illustrate that the volatile matter of FR-PA66 mainly contains carbon dioxide, methane4, and water vapor under heating, accompanied by the char residue raising to 14.1 wt% at 600 °C and the value of the LOI and UL-94 rating reaching 30% and V-0, respectively. Moreover, the addition of HCNP decreases the peak of the heat release rate (pHRR), total heat release (THR), mass loss (ML), and total smoke release (TSR) of FR-PA66 to 373.7 kW/m2, 106.7 MJ/m2, 92.5 wt%, and 944.8 m2/m2, respectively, verifying a significant improvement in the flame retardancy of PA66.

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Zhou, Xuan, Feng Jiang, Zhiyu Hu, Faqun Wu, Ming Gao, Zhihua Chai, Yan Wang, Xiaoyu Gu et Yanxia Wang. « Study on the Flame Retardancy of Rigid Polyurethane Foam with Phytic Acid-Functionalized Graphene Oxide ». Molecules 28, n^o 17 (27 août 2023) : 6267. http://dx.doi.org/10.3390/molecules28176267.

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A rigid polyurethane foam (RPUF) composite was prepared by compounding phytic acid (PA)-functionalized Graphite oxide (PA-GO) with flame-retardant poly (Ammonium phosphate) (APP) and expandable graphite (EG). The effects of PA-GO on the thermal, flame-retardant, and mechanical properties of RPUF were studied using a thermogravimetric analyzer, a limiting oxygen index (LOI) tester, a UL-94 vertical combustion tester, a cone calorimeter, scanning electron microscopy, and a universal tensile testing machine. The results indicated that there was a significant synergistic flame-retardant effect between PA-GO and the intumescent flame retardants (IFR) in the RPUF matrix. Compared with RPUF-1, the addition of 0.3 wt% PA-GO could increase LOI from 25.7% to 26.5%, increase UL-94 rating from V-2 to V-0, and reduce the peak heat release rate (PHRR) and total heat release rate (THR) by 28.5% and 22.2%, respectively. Moreover, the amount of residual char increased from 22.2 wt% to 24.6 wt%, and the char layer was continuous and dense, with almost no holes. Meanwhile, the loss of mechanical properties was apparently lightened.

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Luo, Xing, Min He, Jian Bing Guo, Kai Zhou Zhang et Bin Wu. « An Efficiently Brominated Flame Retardant Composed of Decabromodiphenyl Oxide and Antimonous Oxide for Long Glass Fiber Reinforced Polypropylene ». Advanced Materials Research 734-737 (août 2013) : 2240–43. http://dx.doi.org/10.4028/www.scientific.net/amr.734-737.2240.

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An efficiently brominated flame retardant which composed of decabromodiphenyl oxide (DB) and antimonous oxide (AO) was used to flame retardant for long glass fiber reinforced polypropylene (LGFPP). In order to investigate the thermal stability, flame retardancy and mechanical property of DB-AO/LGFPP composites used by thermogravimetric analysis (TGA), limiting oxygen index (LOI), vertical burning (UL-94) and mechanical property tests. The results showed that brominated flame retardant improved flame retardancy of LGFPP efficiently can be proved by TGA, and had less affected on mechanical properties.

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Li, Liang, et Zaisheng Cai. « Flame-Retardant Performance of Transparent and Tensile-Strength-Enhanced Epoxy Resins ». Polymers 12, n^o 2 (4 février 2020) : 317. http://dx.doi.org/10.3390/polym12020317.

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In this study, a flame-retardant additive with 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) groups denoted DSD was successfully synthesized from DOPO, 4,4′-diaminodiphenyl sulfone (DDS), and salicylaldehyde. The chemical structure of DSD was characterized by FTIR–ATR, NMR, and elemental analysis. DSD was used as an amine curing agent, and the transparent, tensile strength-enhanced epoxy resins named EP–DSD were prepared via thermal curing reactions among the diglycidyl ether of bisphenol A (DGEBA), 4,4′-diaminodiphenylmethane (DDM), and DSD. The flame-retardancy of composites was studied by the limiting oxygen index (LOI) and UL-94 test. The LOI values of EP–DSD composites increased from 30.7% for a content of 3 wt % to 35.4% for a content of 9 wt %. When the content of DSD reached 6 wt %, a V-0 rating under the UL-94 vertical test was achieved. SEM photographs of char residues after the UL-94 test indicate that an intumescent and tight char layer with a porous structure inside was formed. The TGA results revealed that EP–DSD thermosets decomposed ahead of time. The graphitization degree of the residual chars was also investigated by laser Raman spectroscopy. The measurement of tensile strength at breaking point shows that the loading of DSD increases the tensile strength of epoxy thermosets. Py-GC/MS analysis shows the presence of phosphorus fragments released during EP–DSD thermal decomposition, which could act as free radical inhibitors in the gas phase. Owing to the promotion of the formation of intumescent and compact char residues in the condensed phase and nonflammable phosphorus fragments formed from the decomposition of DOPO groups, EP–DSD composites displayed obvious flame-retardancy.

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Shi, Xuejun, Baoting Wei, Yongjun Han, Xiangxiang Du et Guoxu He. « Epoxy/melamine polyphosphate modified silicon carbide composites : Thermal conductivity and flame retardancy analyses ». e-Polymers 22, n^o 1 (1 janvier 2022) : 742–51. http://dx.doi.org/10.1515/epoly-2022-0070.

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Abstract Silicon carbide (SiC) was modified by melamine polyphosphate (MPP)-modified silicone to form SiC-MPP, then incorporated into epoxy resin (EP) for developing thermally resistant composites, which showed thermal conductivity and flame retardancy performance. The EP/SiC-MPP composites were prepared by blending and cured under 60°C for 2 h and 150°C for 8 h. The grafting degree of SiC-MPP was analyzed using Fourier transform Infrared, scanning electron microscope, and thermogravimetric measurements. The flame retardancy of the EP/SiC-MPP composites was studied by UL-94 vertical combustion and cone calorimetry test. The results showed that for EP/SiC-MPP containing 20 wt%, the UL-94 was case V1. Also compared to pure epoxy, the peak heat release rate (PHRR) of composites was reduced from 800 to 304 kW·m−2. The thermal conductivity of EP/SiC-M20 composites was 0.53 W·m−1·K−1, almost 2.5-fold higher than pure epoxy (0.21 W·m−1·K−1). The as-prepared EP/SiC-MPP composites exhibited enhanced flame retardancy and thermal conductivity. Based on analyses performed, these composites took credit-related applications.

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Geng, Junming, Jianyu Qin et Jiyu He. « Preparation of Intercalated Organic Montmorillonite DOPO-MMT by Melting Method and Its Effect on Flame Retardancy to Epoxy Resin ». Polymers 13, n^o 20 (12 octobre 2021) : 3496. http://dx.doi.org/10.3390/polym13203496.

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An intercalated organic montmorillonite DOPO-MMT was prepared through the melting method using 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) as a modifier. Epoxy resin (EP) composites were prepared with DOPO-MMT, DOPO, MMT, and the physical mixtures of DOPO+MMT as flame retardants. The microstructure of the flame retardants and EP samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The flame retardant properties, thermal stability, and residual char structure of the EPs were studied by the limited oxygen index (LOI) test, the UL-94 vertical burning test, thermogravimetric analysis (TGA), the differential scanning calorimeter (DSC) test, the cone calorimeter (CONE) test as well as other characterization methods. The results showed that the intercalated organic montmorillonite DOPO-MMT can be successfully prepared by the melting method and that the MMT is evenly dispersed in the EP/DOPO-MMT composite in the form of nanosheets. The EP/DOPO-MMT nanocomposites showed the optimal flame retardancy (LOI, UL-94, PHRR, etc.) among the EPs with DOPO, MMT, and the physical mixture of DOPO+MMT. The flame-retardant grade of the material reached V-0.

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Wang, Peilong, Xianling Fu, Yongchun Kan, Xin Wang et Yuan Hu. « Two high-efficient DOPO-based phosphonamidate flame retardants for transparent epoxy resin ». High Performance Polymers 31, n^o 3 (8 mars 2018) : 249–60. http://dx.doi.org/10.1177/0954008318762037.

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In this work, two kinds of 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO)-based phosphonamidate flame retardants named 4,4′-diamino-diphenyl methane (DDM)-DOPO and morpholine (MPL)-DOPO are successfully synthesized by the classic Atherton–Todd reaction, and their chemical structures are characterized by Fourier transform infrared spectroscopy (FTIR) and nuclear magnetic resonance (NMR). Epoxy composites containing DDM-DOPO or MPL-DOPO are prepared, which still retain relatively high transparency compared with pure epoxy resin (EP). Its fire behavior is studied in terms of vertical burning test (UL-94), limiting oxygen index (LOI), and cone calorimeter tests. The LOI values can achieve 30% and UL-94 test past V-0 rating for DDM-DOPO-modified epoxy composites with 0.25 wt% phosphorus content. The cone calorimeter results indicate that the modified epoxy composites can release less heat and smoke compared with pure EP. Also, thermal degradation behavior and flame-retardant mechanism of epoxy composites are investigated by thermogravimetric analysis and thermogravimetric analysis/infrared spectrometry. The results indicate that two DOPO-based phosphonamidates show a significant gaseous-phase effect on reducing the release of combustible volatiles.

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Zhao, Qianqiong, Congyan Chen, Ruilan Fan, Yong Yuan, Yalin Xing et Xiao Ma. « Halogen-free flame-retardant rigid polyurethane foam with a nitrogen–phosphorus flame retardant ». Journal of Fire Sciences 35, n^o 2 (3 février 2017) : 99–117. http://dx.doi.org/10.1177/0734904116684363.

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A halogen-free flame retardant containing nitrogen and phosphorus, 2-[anilino-(6-oxobenzo[c][2,1]benzoxaphosphinin-6-yl)methyl]phenol (PDOP), has been synthesized by reaction of benzo[c][2,1]benzoxaphosphinine-6-oxide (DOPO) with 2-( N-phenyliminomethyl)phenol. Halogen-free flame-retardant rigid polyurethane foams (RPUF-PDOP) were prepared using PDOP as a flame retardant. The flammability was investigated using limiting oxygen index, a vertical burning test (UL-94), and a cone calorimeter. When PDOP (10 wt%) as flame retardant was added to RPUF (RPUF-PDOP10%), the limiting oxygen index value was increased from 18% to 27%, and a UL-94 V-0 rating was achieved; meanwhile, the peak heat release rate, total heat release, and the average mass-loss rates of RPUF-PDOP10% were reduced from 246 to 207 kW m−2, from 26.9 to 21.0 MJ/m2, and from 0.043 to 0.033 g/s, respectively. Especially, the initial decomposition temperature of RPUF-PDOP10% was decreased from 228°C to 209°C. The final residual char from decomposition of RPUF-PDOP10% was significantly increased up to 35.6%. The addition of PDOP did not markedly decrease the mechanical properties of the resulting flame-retardant RPUFs.

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Kim, Woojung, et Dong Quy Hoang Thi. « Organo-phosphorus flame retardants when applied to acrylonitrile-butadiene-styrene copolymer ». Science and Technology Development Journal - Natural Sciences 1, n^o 6 (7 décembre 2018) : 192–96. http://dx.doi.org/10.32508/stdjns.v1i6.629.

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In order to find an effective halogen-free flame retardant for acrylonitrile-butadienestyrene copolymer (ABS), organo-phosphorus compounds were studied and their flame retarding performances were determined by UL 94 vertical test. It is found that the flame retardancy strongly depends on phosphorus (P) content of organophosphorus compounds. Only the mixture of ABS with 2-(6-oxido-6Hdibenz< c,e><1,2>oxaphosphorin-6-yl) methyl diethyl phosphinate (ODOPM-DE), which has the highest P content, i.e., 17.68 % gives V-0 rating for the 70/30 composition.

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Jin, Xiaodong, Suping Cui, Shibing Sun, Jun Sun et Sheng Zhang. « The Preparation and Characterization of Polylactic Acid Composites with Chitin-Based Intumescent Flame Retardants ». Polymers 13, n^o 20 (13 octobre 2021) : 3513. http://dx.doi.org/10.3390/polym13203513.

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In this work, a novel intumescent flame retardant (IFR) system was fabricated by the introduction of chitin as a green charring agent, ammonium polyphosphate (APP) as the acid source, and melamine (MEL) as the gas source. The obtained chitin-based IFR was then incorporated into a polylactic acid (PLA) matrix using melt compounding. The fire resistance of PLA/chitin composites was investigated via the limiting oxygen index (LOI), UL-94 vertical burning, and cone calorimeter (CONE) tests. The results demonstrated that the combination of 10%APP, 5%chitin and 5%MEL could result in a 26.0% LOI, a V-0 rating after UL and a 51.2% reduction in the peak heat release rate during the CONE test. Based on the mechanism analysis from both the morphology and the chemical structure of the char, it was suggested that chitin was a promising candidate as a charring agent for chitin reacted with APP and MEL with the formation of an intumescent layer on the surface.

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Zhao, Wei, et Bin Li. « Effect of a Novel Phosphorus and Silicon System on Flame Retardancy and Thermal Degradation of PC ». Advanced Materials Research 430-432 (janvier 2012) : 3–6. http://dx.doi.org/10.4028/www.scientific.net/amr.430-432.3.

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The novel phosphine was used with a silicon resin to impart flame resistancy to polycarbonate. Combustion behaviors and thermal degradation properties of flame retardancy PC have been assayed by limiting oxygen index, vertical burning test and thermogravimetric analysis. Dynamic rheological of FR-PC was also examined. Flame retardant consisted of 80 wt.% PPPO and 20 wt.% silicon resin possesses excellent flame retardancy for PC. LOI value of FR-PC is 33.0% and passes UL-94 V-0 rating. SEM revealed that the char yield as well as char properties have direct effects on the flame retardancy.

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Tomiak, Florian, Kevin Schneider, Angelina Schoeffel, Klaus Rathberger et Dietmar Drummer. « Expandable Graphite as a Multifunctional Flame-Retarding Additive for Highly Filled Thermal Conductive Polymer Formulations ». Polymers 14, n^o 8 (15 avril 2022) : 1613. http://dx.doi.org/10.3390/polym14081613.

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Expandable graphite (EG) and graphite (G) were assessed as multifunctional additives improving both flame retardancy and thermal conductivity in highly filled, thermal conductive polymeric materials based on polyamide 6 (PA6). Fire testing was conducted using modern UL-94, LOI and cone calorimeter test setups. It is demonstrated that thermal conductivity can significantly influence the time to ignition, although offering little fire resistance once ignited even in highly filled systems. Thus, for PA6 formulations containing solely 70 wt.% G, the peak heat release rate (pHRR) measured in cone calorimeter tests was 193 kW/m², whereas PA6 formulations containing 20 wt.% EG/50 wt.% G did not exhibit a measurable heat development. Particular attention was paid to effect separation between thermal conductivity and residue formation. Good thermal conductivity properties are proven to be particularly effective in test scenarios where the heat impact is comparatively low and the testing environment provides good heat dissipation and convective cooling possibilities. For candle-like ignition scenarios (e.g., LOI), filling levels of >50 wt.% (G or EG/G) are shown to be sufficient to suppress ignition exclusively by thermal conductivity. V0 classifications in UL-94 vertical burning tests were achieved for PA6 formulations containing ≥70 wt.% G, ≥25 wt.% EG and ≥20 wt.% EG/25 wt.% G.

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Beltrán-Ramírez, F. I., L. F. Ramos-deValle, E. Ramírez-Vargas, S. Sánchez-Valdes, A. B. Espinoza-Martínez, J. G. Martínez-Colunga, O. S. Rodríguez-Fernandez, E. N. Cabrera-Alvarez et M. L. López-Quintanilla. « Effect of Nanometric Metallic Hydroxides on the Flame Retardant Properties of HDPE Composites ». Journal of Nanomaterials 2014 (2014) : 1–11. http://dx.doi.org/10.1155/2014/969184.

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The effect of nanometric magnesium and aluminum hydroxides on the flame retardancy of high density polyethylene was studied. Additionally, the effect of maleic anhydride grafted polyethylene (PEgMA) and methyl acrylate grafted polyethylene (EMA) compatibilizers, on the tensile properties, was also studied. Morphological characterization of nanocomposites was carried out by means of scanning transmission electron microscopy (STEM). Flame retardant properties of nanocomposites were evaluated by the UL-94 horizontal and vertical tests as well as by cone calorimeter tests. Thermal degradation behavior was analyzed with a thermogravimetric analyzer (TGA). Tensile tests were carried out according to ASTM D 638-03 in an Instron 4301 tensile testing machine. From STEM images, a good dispersion of flame retardants (MH and ATH) in the polymer matrix was observed, which was reflected in the flame retardant properties. Results showed that the combination of nanometric MH and ATH produced excellent flame retardant properties, achieving a classification of V0 in the UL-94-V test and producing the lowest peak of heat release rate (PHRR) and the lowest total heat released (THR) in the cone calorimeter test. Finally, the addition of compatibilizer, especially PEgMA, resulted in much better tensile properties as compared to the noncompatibilized composition, maintaining the flame retardant properties.

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Lai, Xuejun, Jiedong Qiu, Hongqiang Li, Xingrong Zeng, Shuang Tang, Ye Chen et Zhen Chen. « Flame-Retardant and Thermal Degradation Mechanism of Caged Phosphate Charring Agent with Melamine Pyrophosphate for Polypropylene ». International Journal of Polymer Science 2015 (2015) : 1–11. http://dx.doi.org/10.1155/2015/360274.

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An efficient caged phosphate charring agent named PEPA was synthesized and combined with melamine pyrophosphate (MPP) to flame-retard polypropylene (PP). The effects of MPP/PEPA on the flame retardancy and thermal degradation of PP were investigated by limiting oxygen index (LOI), vertical burning test (UL-94), cone calorimetric test (CCT), and thermogravimetric analysis (TGA). It was found that PEPA showed an outstanding synergistic effect with MPP in flame retardant PP. When the content of PEPA was 13.3 wt% and MPP was 6.7 wt%, the LOI value of the flame retardant PP was 33.0% and the UL-94 test was classed as a V-0 rating. Meanwhile, the peak heat release rate (PHRR), average heat release rate (AV-HRR), and average mass loss rate (AV-MLR) of the mixture were significantly reduced. The flame-retardant and thermal degradation mechanism of MPP/PEPA was investigated by TGA, Fourier transform infrared spectroscopy (FTIR), TG-FTIR, and scanning electron microscopy-energy dispersive X-ray spectrometry (SEM-EDXS). It revealed that MPP/PEPA could generate the triazine oligomer and phosphorus-containing compound radicals which changed the thermal degradation behavior of PP. Meanwhile, a compact and thermostable intumescent char was formed and covered on the matrix surface to prevent PP from degrading and burning.

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Dong, Yanmao, et Zhiyang Shen. « Synthesis of PMM and Synergistic Flame Retardant Effect with Ammonium polyphosphate ». Journal of Physics : Conference Series 2713, n^o 1 (1 février 2024) : 012021. http://dx.doi.org/10.1088/1742-6596/2713/1/012021.

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Abstract A novel flame retardant poly {[(2-Methyl-acrylic acid 2-(dimethoxyphosphoryloxy)-ethyl ester]-co-[2-Methyl-acrylic acid 2-(trimethoxysiloxy)-ethyl ester]} (PMM) containing dimethoxyphosphoryloxy and trimethoxysiloxy groups in side chains was synthesized. The structure of PMM was characterized by Fourier transform infrared spectroscopy (FTIR), nuclear magnetic resonance (1H NMR), and the thermal performance of PMM was characterized by thermal gravimetric analysis (TGA) and differential scanning calorimetry (DSC). The effect of PMM on polypropylene’s flame retardancy and thermal behaviors was investigated by limited oxygen index (LOI), vertical burning test (UL-94), and TG tests. The experimental results indicate that the addition of PMM helps to improve the flame retardancy and thermal stability of PP. When the addition of PMM and APP in PC was 15% and 20%, the LOI value of PC reached 28.4%, and the UL-94 test rating reached V-0 level. The charred structure observed by scanning electron microscopy (SEM) indicated that the char surface for PP/APP/PMM system holds an intumescent char structure compared to neat PP, and the synergy exists in the composites. The PMM slightly decreased the tensile property in terms of strength but increased the elongation at break for PP composites.

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S, Sakthivel, Magibalan S, Jeyaprakasam S et Venkatraman J. « Improving Fire Resistance in E-Vehicles : A Study on MPP-Enhanced S-Glass/Phenolic Hybrid Composites ». E3S Web of Conferences 529 (2024) : 02001. http://dx.doi.org/10.1051/e3sconf/202452902001.

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The automotive industry has benefited greatly from the advancements in fireproof, high-strength fiber-reinforced polymer matrix composites during the last several decades. S-Glass/Phenolic hybrid composites made by hydraulic compression molding are the subject of this investigation into the effects of Melamine Polyphosphate (MPP) on their thermal and fire performance. In addition to studying the morphology of the samples, researchers analyzed the thermal and fire performances of hybrid laminates made with neat laminates and varying compositions of MPP (ranging from 3% to 15% by weight). Tests included UL 94, limiting oxygen index (LOI), and the impacts of accelerated heat ageing on the behavior of the hybrid specimens. The results demonstrated that specimens filled with higher MPP performed better in a fire compared to neat samples. According to the results in UL 94 horizontal burning test and vertical burning test, specimens filled with 12 and 15 wt. % MPP demonstrated a reduced flame spreading rate and fulfilled the V-0 criteria. Simultaneously, the energy absorption capacity of hybrid configurations is severely limited by heat ageing, due to its temperature and duration dependent. The research proved that the suggested S-Glass / Phenolic / Melamine Polyphosphate hybrid composites were suitable for creating environmentally friendly electric vehicle battery housings and fire-resistant automotive parts.

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Wang, Ning Ping, Hai Shan Tang, Lang Ping Xia, Si Chun Shao, Jie Zhu et Zhi Han Peng. « Synthesis and Characterization of Triazine-Based Charring Agent and its Application in Flame Retarded Polypropylene ». Advanced Materials Research 1033-1034 (octobre 2014) : 623–26. http://dx.doi.org/10.4028/www.scientific.net/amr.1033-1034.623.

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In this study, N,N-(2,4-diamino-1,3,5-triazinyl) diethylenetriamine were synthesized by cyanuric chloride, diethylenetriamine and ammonia with a novel process in three steps, and it can be used as charring agent in intumescent flame retardant. Its chemical structures were characterized by Fourier-transform infrared spectroscopy (FT-IR) and elemental analysis. Meanwhile, the TGA results showed that triazine-based charring agent had good thermostability. Furthermore, the fire performancce of composites blended by the flame retardant and polypropylene was investigated by vertical burning test. The results revealed good fire retardancy that flame retardant polypropylene with 5.1wt% charring agent, 2.8wt% anti-dripping and 20.1wt% APP, was reached UL-94 V-0 rating.

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Shiu, Bing-Chiuan, Kunlin Wu, Ching-Wen Lou, Qi Lin et Jia-Horng Lin. « Synthesis of a Compound Phosphorus-Nitrogen Intumescent Flame Retardant for Applications to Raw Lacquer ». Polymers 13, n^o 17 (25 août 2021) : 2858. http://dx.doi.org/10.3390/polym13172858.

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Raw lacquer (RL) is a natural polymer compound with highly promising applications; however, its inflammable attribute restricts the industrial applications. In this study, melamine is used to formulate tri (1-melamine-2-propanol) phosphate (FR-1), after which it is synthesized with ammonium phosphate (FR-2) and diatomite to form a compound phosphorus-nitrogen intumescent flame retardant (IFR). Next, IFR is used as the filling agent that then cross-links with RL, and as such RL/IFR membranes are formed after the curing. The limiting oxygen index (LOI) measurement, the vertical combustion test (UL-94), the microshape calorimetric analysis (CCT), and the thermal gravimetric analysis (TGA) are conducted to examine the combustion resistance and thermal stability of the membranes. Fourier transform infrared spectroscopy (FT-IR) and electron scanning microscope (SEM) are performed to separately characterize the structure and compatibility; the mechanical properties of the membranes are also evaluated. The vertical combustion test results confirm that with 30 wt% of IFR, RL/IFR membranes acquire 12.3% higher LOI and a vertically combustion of V-0 level. The TGA indicates that RL/IFR membranes demonstrate a greater adhesion level, a higher rigidity, and better luster than pure RL membranes.

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Aldalbahi, Ali, Bander S. AlOtaibi, Badr M. Thamer et Ayman El-Faham. « Synthesis of New S-Triazine Bishydrazino and Bishydrazido-Based Polymers and Their Application in Flame-Retardant Polypropylene Composites ». Polymers 14, n^o 4 (17 février 2022) : 784. http://dx.doi.org/10.3390/polym14040784.

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In this study six new s-triazine bishydrazino and bishydrazido-based polymers were synthesized via condensation of bishydrazino s-triazine derivatives with terephthaldehyde or via nucleophilic substitution of dichloro-s-triazine derivatives with terephthalic acid hydrazide. The synthesized polymers were characterized by different techniques. The new polymers displayed good thermal behavior with great values in terms of limited oxygen indexed (LOI) 27.50%, 30.12% for polymers 5b,c (bishydrazino-s-triazine based polymers) and 27.23%, 29.86%, 30.85% for polymers 7a–c (bishydrazido-s-triazine based polymers) at 800 °C. Based on the LOI values, these polymers could be classified as flame retardant and self-extinguishing materials. The thermal results also revealed that the type of substituent groups on the triazine core has a considerable impact on their thermal behavior. Accordingly, the prepared polymers were mixed with ammonium polyphosphate (APP) in different proportions to form an intumescent flame-retardant (IFRs) system and were introduced into polypropylene (PP) to improve the flame-retardancy of the composites. The best results were obtained with a mass ratio of APP: 5a–c or 7a–c of 2:1, according to the vertical burning study (UL-94). In addition, the presence of 25% “weight ratio” of IFR in the composite showed great impact and passed UL-94 V-0 and V-1 tests.

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Yan, Wei, Jie Yu, Mingqiu Zhang, Lijuan Long, Tao Wang, Shuhao Qin et Weijiang Huang. « Novel flame retardancy effect of phenethyl-bridged DOPO derivative on epoxy resin ». High Performance Polymers 30, n^o 6 (3 juillet 2017) : 667–76. http://dx.doi.org/10.1177/0954008317716525.

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A series of flame-retardant epoxy resins (EPs) containing either phenethyl-bridged 9 or 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide derivative (bisDOPO) were prepared. The flame-retardant properties of bisDOPO on EP composites were characterized by the limiting oxygen index (LOI), the UL-94 vertical burning, and the cone calorimeter test (CCT).The LOI of the EP/bisDOPO composites increased from 21.8% to 38.0%, and the hybrids with the 10 wt% bisDOPO obtained a V-0 rating in the UL94 vertical burning test. The char residue following the CCT showed intumescent structures with continuous and compact surfaces that can effectively suppress the spread of the flame and extinguish the fire. This was confirmed through both visual observation and scanning electron microscopy (SEM) measurements. The flame-retardant mechanism was studied by Fourier transform infrared spectroscope (FTIR), thermogravimetric analysis/infrared spectrometry, SEM/energy-dispersive X-ray, and pyrolysis-gas chromatography/mass spectrometry. Overall, bisDOPO was an effective flame retardant with potential applications within EP.

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Zhao, Chunxia, Zhangmei Sun, Jixuan Wei, Yuntao Li, Dong Xiang, Yuanpeng Wu et Yusheng Que. « A Phosphorous-Containing Bio-Based Furfurylamine Type Benzoxazine and Its Application in Bisphenol-A Type Benzoxazine Resins : Preparation, Thermal Properties and Flammability ». Polymers 14, n^o 8 (14 avril 2022) : 1597. http://dx.doi.org/10.3390/polym14081597.

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Polybenzoxazine (PBa) composites based on phosphorous-containing bio-based furfurylamine type benzoxazines (D-fu) and bisphenol-A type benzoxazines (Ba) were developed for flame retardation. The structure of D-fu was analyzed by Fourier transform infrared (FTIR) spectroscopy and 1H-NMR spectroscopy. The curing temperature of Ba/D-fu mixtures was systematically studied by differential scanning calorimetry (DSC). Thermogravimetric analysis (TGA) demonstrated the excellent char formation ability of the PBa composites with the addition of phosphorous-containing D-fu. The flame retardancy of the PBa composite materials was tested by the limited oxygen index (LOI), vertical burning test (UL-94) and cone calorimeter (CONE). The LOI and UL-94 level of PBa/PD-fu-5% reached 34 and V0 rate, respectively. Notably, the incorporation of 5% D-fu into PBa led to a decrease of 21.9% at the peak of the heat-release rate and a mass-loss reduction of 8.0%. Moreover, the fire performance index increased, which demonstrated that the introduction of D-fu can diminish fire occurrence. The role of D-fu in the condensed and gas phases for the fire-resistant mechanism of the PBa matrix was supported by SEM-EDS and TGA/infrared spectrometry (TG-FTIR), respectively. Dynamic mechanical analysis (DMA) revealed that the Tg of PBa flame-retardant composites was around 230 °C. Therefore, PBa composites are promising fire-retardant polymers that can be applied as high-performance functional materials.

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Wang, Fang, Wenbo Shi, Yuliang Mai et Bing Liao. « Effect of Thermal Conductive Fillers on the Flame Retardancy, Thermal Conductivity, and Thermal Behavior of Flame-Retardant and Thermal Conductive Polyamide 6 ». Materials 12, n^o 24 (9 décembre 2019) : 4114. http://dx.doi.org/10.3390/ma12244114.

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In this work, polyamide 6 (PA6) composites with improved flame retardancy and thermal conductivity were prepared with different thermal conductive fillers (TC fillers) such as aluminum nitride (AlN) and boron nitride (BN) in a PA6 matrix with aluminum diethylphosphinate (AlPi) as a fire retardant. The resultant halogen-free flame retardant (HFFR) and thermal conductive (TC) PA6 (HFFR-TC-PA6) were investigated in detail with a mechanical property test, a limiting oxygen index (LOI), the vertical burning test (UL-94), a cone calorimeter, a thermal gravimetric analysis (TGA) and differential scanning calorimetry (DSC). The morphology of the impact fracture surface and char residue of the composites were analyzed by scanning electron microscopy (SEM). It was found that the thermal conductivity of the HFFR-TC-PA6 composite increased with the amount of TC fillers. The TC fillers exerted a positive effect for flame retardant PA6. For example, the HFFR-TC-PA6 composites with the thickness of 1.6 mm successfully passed the UL-94 V-0 rating with an LOI of more than 29% when the loading amount of AlN-550RFS, BN-SW08 and BN-NW04 was 30 wt%. The morphological structures of the char residues revealed that TC fillers formed a highly integrated char layer surface (without holes) during the combustion process, as compared to that of flame retardant PA6/AlPi composites. In addition, the thermal stability and crystallization behavior of the composites were studied.

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