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1

Melnic, Elena, Victor Ch Kravtsov, Elena Lucenti та ін. "Regulation of π⋯π stacking interactions between triimidazole luminophores and comprehensive emission quenching by coordination to Cu(ii)". New Journal of Chemistry 45, № 20 (2021): 9040–52. http://dx.doi.org/10.1039/d1nj00909e.

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Hei, Ze-Huan, Gan-Lin Song, Chen-Yu Zhao, Wenhao Fan, and Mu-Hua Huang. "Supramolecular porous ionic network based on triazinonide and imidazolium: a template-free synthesis of meso-/macroporous organic materials via a one-pot reaction-assembly procedure." RSC Advances 6, no. 95 (2016): 92443–48. http://dx.doi.org/10.1039/c6ra20590a.

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A supramolecular porous ionic network (SPIN-1) was designed and prepared using a one-pot procedure, involving the quaternization of triimidazole triazine with cyanuric chloride followed by hydrolysis andin situassembly.
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Malpicci, Daniele, Clelia Giannini, Elena Lucenti, Alessandra Forni, Daniele Marinotto, and Elena Cariati. "Mono-, Di-, Tri-Pyrene Substituted Cyclic Triimidazole: A Family of Highly Emissive and RTP Chromophores." Photochem 1, no. 3 (2021): 477–87. http://dx.doi.org/10.3390/photochem1030031.

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The search of new organic emitters is receiving a strong motivation by the development of ORTP materials. In the present study we report on the preparation, optical and photophysical characterization, by both steady state and time resolved techniques, of two pyrene-functionalized cyclic triimidazole derivatives. Together with the already reported mono-substituted derivative, the di- and tri-substituted members of the family have revealed as intriguing emitters characterized by impressive quantum yields in solution and RTP properties in the solid state. In particular, phosphorescence lifetimes
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Previtali, Andrea, Elena Lucenti, Alessandra Forni, et al. "Solid State Room Temperature Dual Phosphorescence from 3-(2-Fluoropyridin-4-yl)triimidazo[1,2-a:1′,2′-c:1″,2″-e][1,3,5]triazine." Molecules 24, no. 14 (2019): 2552. http://dx.doi.org/10.3390/molecules24142552.

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Organic room temperature persistent luminescence is a fascinating but still largely unexplored phenomenon. Cyclic-triimidazole and its halogenated (Br, I) derivatives have recently revealed as intriguing phosphors characterized by multifaceted emissive behavior including room temperature ultralong phosphorescence (RTUP) associated with the presence of H-aggregates in their crystal structure. Here, we move towards a multicomponent system by incorporating a fluoropyridinic fragment on the cyclic-triimidazole scaffold. Such chromophore enhances the molecular properties resulting in a high photolu
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Malpicci, Daniele, Daniele Maver, Elisabetta Rosadoni та ін. "3-Ethynyltriimidazo[1,2-a:1′,2′-c:1″,2″-e][1,3,5]triazine Dual Short- and Long-Lived Emissions with Crystallization-Enhanced Feature: Role of Hydrogen Bonds and π-π Interactions". Molecules 29, № 9 (2024): 1967. http://dx.doi.org/10.3390/molecules29091967.

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Organic room temperature phosphorescent (ORTP) materials with stimuli-responsive, multicomponent emissive behaviour are extremely desirable for various applications. The derivative of cyclic triimidazole (TT) functionalized with an ethynyl group, TT-CCH, is isolated and investigated. The compound possesses crystallization-enhanced emission (CEE) comprising dual fluorescence and dual phosphorescence of both molecular and supramolecular origin with aggregation-induced components highly sensitive to grinding. The mechanisms involved in the emissions have been disclosed thanks to combined structur
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Schubert, David M., Daniel T. Natan, Duane C. Wilson, and Kenneth I. Hardcastle. "Facile Synthesis and Structures of Cyclic Triimidazole and Its Boric Acid Adduct." Crystal Growth & Design 11, no. 3 (2011): 843–50. http://dx.doi.org/10.1021/cg101489t.

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Melnic, Elena, Victor Kravtsov, Elena Lucenti, Elena Cariati, Alessandra Forni, and Marina Fonari. "Structural landscape of CuII coordination compounds with isomers and derivatives of cyclic triimidazole." Acta Crystallographica Section A Foundations and Advances 75, a2 (2019): e502-e502. http://dx.doi.org/10.1107/s2053273319090545.

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Malpicci, Daniele, Alessandra Forni, Elena Cariati, et al. "Crystallization-Enhanced Emission and Room-Temperature Phosphorescence of Cyclic Triimidazole-Monohexyl Thiophene Derivatives." Molecules 28, no. 1 (2022): 140. http://dx.doi.org/10.3390/molecules28010140.

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The development of organic room-temperature phosphorescent (ORTP) materials represents an active field of research due to their significant advantages with respect to their organometallic counterparts. Two cyclic triimidazole (TT) derivatives bearing one and three hexyl-thiophene moieties, TT-HThio and TT-(HThio)3, have been prepared and characterized. Both compounds display enhanced quantum yields in their crystalline form with respect to those in a solution state, revealing crystallization-enhanced emissive (CEE) behavior. Importantly, while single fluorescence is observed in solution, cryst
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Lucenti, Elena, Alessandra Forni, Chiara Botta, et al. "Cyclic Triimidazole Derivatives: Intriguing Examples of Multiple Emissions and Ultralong Phosphorescence at Room Temperature." Angewandte Chemie 129, no. 51 (2017): 16520–25. http://dx.doi.org/10.1002/ange.201710279.

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Lucenti, Elena, Alessandra Forni, Chiara Botta, et al. "Intrinsic and Extrinsic Heavy‐Atom Effects on the Multifaceted Emissive Behavior of Cyclic Triimidazole." Chemistry – A European Journal 25, no. 10 (2019): 2452–56. http://dx.doi.org/10.1002/chem.201804980.

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Lucenti, Elena, Alessandra Forni, Chiara Botta, et al. "Cyclic Triimidazole Derivatives: Intriguing Examples of Multiple Emissions and Ultralong Phosphorescence at Room Temperature." Angewandte Chemie International Edition 56, no. 51 (2017): 16302–7. http://dx.doi.org/10.1002/anie.201710279.

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12

Malpicci, Daniele, Delia Blasi, Daniele Marinotto, et al. "A Rare Structural Motif for a Luminescent Cu(I) Coordination Polymer with 3-(Pyridin-2-yl)triimidazotriazine." Crystals 13, no. 1 (2023): 149. http://dx.doi.org/10.3390/cryst13010149.

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The coordination ability of the pyridine derivative of cyclic triimidazole, namely 3-(pyridin-2-yl)triimidazotriazine (TT-Py) towards Cu(I) was explored. TT-Py is an appealing nitrogen-rich ligand characterized by the presence of three imidazole nitrogen atoms with trigonal symmetry and a pyridine moiety, available for coordination to metal ions. The multidentate nature of TT-Py allows to isolate, by reaction with CuI at room temperature, the one-dimensional coordination network [Cu2I2(TT-Py)]n (1). 1 is characterized by a rare structural network built-up by the combination in a 1:2 ratio of t
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Previtali, Andrea, Wei He, Alessandra Forni, et al. "Tunable Linear and Nonlinear Optical Properties from Room Temperature Phosphorescent Cyclic Triimidazole‐Pyrene Bio‐Probe." Chemistry – A European Journal 27, no. 67 (2021): 16690–700. http://dx.doi.org/10.1002/chem.202102839.

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Wang, Rong-Yan, Xiao Zhang, Qi-Sheng Huo, Jie-Hui Yu, and Ji-Qing Xu. "New discrete iodometallates with in situ generated triimidazole derivatives as countercations (Mn+ = Ag+, Pb2+, Bi3+)." RSC Advances 7, no. 31 (2017): 19073–80. http://dx.doi.org/10.1039/c6ra27510a.

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Lucenti, Elena, Elena Cariati, Andrea Previtali, et al. "Versatility of Cyclic Triimidazole to Assemble 1D, 2D, and 3D Cu(I) Halide Coordination Networks." Crystal Growth & Design 19, no. 3 (2019): 1567–75. http://dx.doi.org/10.1021/acs.cgd.8b01199.

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Kravtsov, Victor, Victor Bold, Diana Chisca, et al. "Crystallographic evidence for aggregation patterns of two cyclic triimidazole phosphors in ZnII and CdII complexes." Acta Crystallographica Section A Foundations and Advances 75, a2 (2019): e572-e572. http://dx.doi.org/10.1107/s2053273319089848.

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Cariati, Elena, Alessandra Forni, Elena Lucenti, et al. "Extrinsic Heavy Metal Atom Effect on the Solid‐State Room Temperature Phosphorescence of Cyclic Triimidazole." Chemistry – An Asian Journal 14, no. 6 (2019): 853–58. http://dx.doi.org/10.1002/asia.201801604.

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18

Giannini, Clelia, Alessandra Forni, Daniele Malpicci, et al. "Room Temperature Phosphorescence from Organic Materials: Unravelling the Emissive Behaviour of Chloro‐Substituted Derivatives of Cyclic Triimidazole." European Journal of Organic Chemistry 2021, no. 13 (2021): 2041–49. http://dx.doi.org/10.1002/ejoc.202100131.

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19

Lucenti, Elena, Alessandra Forni, Chiara Botta, et al. "The Effect of Bromo Substituents on the Multifaceted Emissive and Crystal-Packing Features of Cyclic Triimidazole Derivatives." ChemPhotoChem 2, no. 9 (2018): 801–5. http://dx.doi.org/10.1002/cptc.201800151.

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Forni, Alessandra, Elena Cariati, Lucia Carlucci, et al. "Interpreting the different emissive properties of cyclic triimidazole-based CuI and AgI coordination polymers: a QTAIM and IQA study." Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials 77, no. 6 (2021): 865–70. http://dx.doi.org/10.1107/s2052520621009707.

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A QTAIM and IQA investigation on model compounds of two isostructural AgI and CuI coordination polymers (CPs) based on cyclic triimidazole (L), i.e. the [MIL] n 1D double-stranded stair chain and the [MClL] n 3D network (M = Cu, Ag), has allowed light to be shed on the different emissive behaviour associated with the two metal ions. According to a previously reported investigation [Malpicci et al. (2021). Inorg. Chem. Front. 8, 1312–1323], AgI CPs showed both fluorescence and multiple ligand-centred room-temperature phosphorescences, whereas CuI CPs displayed non-thermally equilibrated halogen
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21

Adeyemo, Aderonke Ajibola, Sankarasekaran Shanmugaraju, Dipak Samanta, and Partha Sarathi Mukherjee. "Template-free coordination-driven self-assembly of discrete hexanuclear prismatic cages employing half-sandwich octahedral RuII2 acceptors and triimidazole donors." Inorganica Chimica Acta 440 (January 2016): 62–68. http://dx.doi.org/10.1016/j.ica.2015.10.029.

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22

Fonari, Marina S., Victor Ch Kravtsov, Victor Bold, et al. "Structural Landscape of Zn(II) and Cd(II) Coordination Compounds with Two Isomeric Triimidazole Luminophores: Impact of Crystal Packing Patterns on Emission Properties." Crystal Growth & Design 21, no. 7 (2021): 4184–200. http://dx.doi.org/10.1021/acs.cgd.1c00459.

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23

Samanta, Dipak, Sandip Mukherjee, Yogesh P. Patil, and Partha Sarathi Mukherjee. "Self-Assembled Pd6Open Cage with Triimidazole Walls and the Use of Its Confined Nanospace for Catalytic Knoevenagel- and Diels-Alder Reactions in Aqueous Medium." Chemistry - A European Journal 18, no. 39 (2012): 12322–29. http://dx.doi.org/10.1002/chem.201201679.

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Mataka, Shuntaro, Takashi Irie, Youji Ikezaki, and Masashi Tashiro. "Preparation of Benzo-diimidazoles and Benzo-triimidazoles." Chemische Berichte 126, no. 8 (1993): 1819–22. http://dx.doi.org/10.1002/cber.19931260811.

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Magni, Mirko, Elena Lucenti, Andrea Previtali, Patrizia Romana Mussini, and Elena Cariati. "Electrochemistry of cyclic triimidazoles and their halo derivatives: A casebook for multiple equivalent centers and electrocatalysis." Electrochimica Acta 317 (September 2019): 272–80. http://dx.doi.org/10.1016/j.electacta.2019.05.146.

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Apen, Elizabeth, Paul G. Apen, Paul G. Rasmussen, and John L. Gland. "Characterization of Hexacarbonitrile-Triimidazo-Triazine (HTT) Using Experimental and Modeled Ultrasoft X-ray Absorption Spectra." Chemistry of Materials 6, no. 6 (1994): 831–35. http://dx.doi.org/10.1021/cm00042a022.

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Malpicci, Daniele, Stefano Di Ciolo, Elena Cariati, et al. "Role of molecular packing in RTP features of positional isomers: The case study of triimidazo-triazine functionalized with ethynyl pyridine moieties." Next Materials 7 (April 2025): 100440. https://doi.org/10.1016/j.nxmate.2024.100440.

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Shintoyo, Seira, Keishiro Murakami, Takeshi Fujinami, et al. "Crystal Field Splitting of the Ground State of Terbium(III) and Dysprosium(III) Complexes with a Triimidazolyl Tripod Ligand and an Acetate Determined by Magnetic Analysis and Luminescence." Inorganic Chemistry 53, no. 19 (2014): 10359–69. http://dx.doi.org/10.1021/ic501453h.

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Platella, Chiara, Stefano Di Ciolo, Andrea Criscuolo, et al. "Combining Cyclic Triimidazo Triazine Core With Ethynyl‐N‐Methyl‐Pyridinium Groups for Targeting G‐Quadruplex Structures." Archiv der Pharmazie 358, no. 7 (2025). https://doi.org/10.1002/ardp.70037.

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ABSTRACTThe synthesis and characterization of a mini‐library of cyclic triimidazo triazine (TT) derivatives functionalized with one, two, or three ethynyl‐N‐methyl‐pyridinium moieties are reported here. These compounds were designed with the aim of targeting cancer‐related DNA G‐quadruplex structures. The newly synthesized compounds were tested for their ability to bind G‐quadruplexes from both telomeric and oncogene promoter sequences using an affinity chromatography‐based assay, spectroscopic and electrophoretic techniques, as well as molecular docking analysis. The obtained results demonstr
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Cariati, Elena, Daniele Malpicci, Elena Lucenti, et al. "Ag(I) and Cu(I) cyclic-triimidazole coordination polymers: revealing different deactivation channels for multiple room temperature phosphorescences." Inorganic Chemistry Frontiers, 2020. http://dx.doi.org/10.1039/d0qi01377c.

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The remarkable emissive properties of cyclic triimidazole (TT), showing crystallization-induced emissive behavior and, in particular, room temperature phosphorescence (RTP), are here combined with its versatility in assembling coordination compounds. A...
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Malpicci, Daniele, Delia Blasi, Alessandra Forni, et al. "Layered Ag(I), Cd(II) and Cu(I) Luminescent Coordination Polymers Assembled through a Tri‐pyridyl Cyclic Triimidazole Ligand." European Journal of Inorganic Chemistry, April 24, 2024. http://dx.doi.org/10.1002/ejic.202400185.

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The versatility of a nitrogen rich pyridinic derivative of the cyclic triimidazole scaffold with C3 symmetry is here exploited to obtain three luminescent coordination polymers (CPs). By reaction of 3,7,11‐tri(pyridin‐4‐yl)triimidazo[1,2‐a:1',2'‐c:1'',2''‐e][1,3,5]triazine, (4py)3TT, with Ag(I), Cd(II) and Cu(I) salts, [Ag{(4‐py)3TT}(SO3CF3)]n∙½nCH2Cl2 (1), [Cd{(4‐py)3TT}(NO3)2(EtOH)]n (2) and [(Cu2I2)3{(4‐py)3TT}4]n·xn(H2O, EtOH) (3) are obtained. The trigonal symmetry of (4py)3TT results in 2D structures with hcb topology in 1 and 2 and a rare 3,4‐connected (3,4‐c) topology in 3. The multifa
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Formenti, Matteo, Delia Blasi, Elena Cariati, et al. "Pyrene-substituted cyclic triimidazole: An appealing and versatile luminescent scaffold for explosive detection." Dyes and Pigments, August 2022, 110637. http://dx.doi.org/10.1016/j.dyepig.2022.110637.

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Kaenzig, Cyrstal, Richard Hubbard, Mingzhu Zhang, Constance M. Harris, Thomas M. Harris, and Moses Lee. "SYNTHESIS OF A DEOXYGUANOSINE-2-AMINO ADDUCT OF A TRIIMIDAZOLE-CONTAINING TALLIMUSTINE ANALOG." Heterocyclic Communications 4, no. 6 (1998). http://dx.doi.org/10.1515/hc.1998.4.6.509.

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Malpicci, Daniele, Alessandra Forni, Chiara Botta, et al. "Stimuli responsive features of organic RTP materials: an intriguing carbazole‐cyclic triimidazole derivative." Chemistry – A European Journal, April 21, 2023. http://dx.doi.org/10.1002/chem.202300930.

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Malpicci, Daniele, Alessandra Forni, Chiara Botta, et al. "Dual fluorescence and RTP features of carbazole-cyclic triimidazole derivatives: The fluorophores’ connectivity does matter." Dyes and Pigments, March 2023, 111274. http://dx.doi.org/10.1016/j.dyepig.2023.111274.

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Cariati, Elena Maria, Daniele Malpicci, Alessandra Forni, et al. "Excitation Dependent Multiemissive Behaviour of Triimidazole Carboxylic Acid anti‐Kasha Luminophore and its Mononuclear Metal Complexes." European Journal of Inorganic Chemistry, October 22, 2024. http://dx.doi.org/10.1002/ejic.202400338.

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Materials based on small molecules characterized by multi‐component short and long‐lived emissive behaviour are extremely desirable for various applications. The derivative of cyclic triimidazole (TT) functionalized with a carboxylic group, namely TT‐COOH, is isolated, investigated and used as coordinative ligand to obtain a series of isomorphous mononuclear complexes of general formula [M(TT‐COO)2(H2O)2] (M = Mn(II), Co(II), Ni(II), Cu(II), Zn(II) and Cd(II)). Crystals of TT‐COOH display aggregation induced enhanced emission (AIEE) comprising dual fluorescence and dual phosphorescence of mole
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Forni, Alessandra, Daniele Malpicci, Daniele Maver, Elena Lucenti, and Elena Cariati. "The intriguing case of cyclic triimidazole: an emerging scaffold for the preparation of multiemissive, bio-medical and hybrid inorganic-organic materials." Journal of Materials Chemistry C, 2025. https://doi.org/10.1039/d4tc04766d.

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Among organic small molecules characterized by multifaceted behaviour, triimidazo[1,2-a:1′,2′-c:1″,2″-e][1,3,5]triazine, TT, having a triazinic central ring with three annelated imidazoles, represents a fascinating but still underinvestigated scaffold endowed with intriguing luminescent...
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Malpicci, Daniele, Silvia Rosa Araneo, Serena Arnaboldi, et al. "Electrochemical insight on the nitrogen-rich, weakly aromatic cyclic triimidazole multifunctional system expanded with pyridine or thiophene terminals." Electrochimica Acta, August 2023, 143117. http://dx.doi.org/10.1016/j.electacta.2023.143117.

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Kravtsov, Victor, Victor Bold, Diana Chisca, et al. "Crystallographic evidence for aggregation patterns of two cyclic triimidazole phosphors in ZnII and CdII complexes." July 2, 2020. https://doi.org/10.1107/s2053273319089848.

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Malpicci, Daniele, Daniele Maver, Daniela Maggioni, et al. "2-pyridine cyclic triimidazole as chelating and bridging ligand in mono- and hexanuclear Re(I) complexes with emissive properties in solution and in the solid state." New Journal of Chemistry, 2023. http://dx.doi.org/10.1039/d3nj02823b.

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Two luminescent Re(I) complexes, namely the mononuclear fac-[ReCl(CO)3(TT-Py)] (1) and the hexanuclear [{Re(μ-Cl)(CO)3(μ-TT-Py)}{Re2(μ-Cl)2(CO)6}]2 (2), have been isolated in high yields by one-pot reaction between [ReCl(CO)5] and different amounts of nitrogen...
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Malpicci, Daniele, Stefano Andolina, Stefano Di Ciolo, et al. "Cyclic Triimidazoles as Stabilizers for Gene Promoter and Human Telomeric DNA G‐Quadruplexes." European Journal of Organic Chemistry, August 8, 2022. http://dx.doi.org/10.1002/ejoc.202200718.

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Rosadoni, Elisabetta, Lorenzo Ballerini, Antonio Del Vecchio, and Fabio Bellina. "Synthesis of 3‐Aryl Substituted Triimidazotriazines via Regioselective Direct Arylation." Asian Journal of Organic Chemistry, April 2, 2024. http://dx.doi.org/10.1002/ajoc.202400082.

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A general and convenient selective direct arylation of the 3‐position of triimidazo[1,2‐a:1’,2’‐c:1’’,2’’‐e][1,3,5]triazine (1) with (hetero)aryl halides in DMA was successfully achieved in the presence of K2CO3 as the base and a catalyst precursor consisting of Pd(OAc)2 and P(2‐furyl)3. Electron‐poor and ‐rich (hetero)aryl moieties, including the strongly deactivated and sterically encumbered 2,4,6‐trimethoxyphenyl unit, are well tolerated in the electrophilic partner. The data obtained in this synthetic study support a reaction mechanism involving an electrophilic attack of an arylpalladium‐
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Ahsan, Aisha, Xing Wang, Rejaul Sk, et al. "Self-Assembly of N-Rich Triimidazoles on Ag(111): Mixing the Pleasures and Pains of Epitaxy and Strain." Journal of Physical Chemistry C, November 17, 2023. http://dx.doi.org/10.1021/acs.jpcc.3c03325.

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Li, Huixue, Lingling Lv, Kun Yuan, Sujuan Pan, and Zhifeng Li. "Understanding H-aggregates crystallization induced emissive behavior: insights from theory." Scientific Reports 13, no. 1 (2023). http://dx.doi.org/10.1038/s41598-023-39605-5.

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AbstractWe conducted a theoretical investigation into how the molecular stacking effect impacts the photophysical properties in solid phases. Our findings indicated that in the aggregated state, the out-of-plane distorted vibration and imidazole ring stretching vibration of triimidazo-[1,3,5] triazinethe are significantly suppressed, which decreased the Huang-Rhys factor and the corresponding reorganization energy of the photophysical process, as a result, this restricted intramolecular motions and dissipation pathways of excess energy in the excited state, therefore, aggregation induced enhan
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Di Micco, Simone, Clelia Giannini, Andrea Previtali, Elena Lucenti, and Giuseppe Bifulco. "Chemical shift assignment of mono- and di-bromo triimidazo[1,2-a :1',2'-c :1”,2”-e ][1,3,5] triazine derivatives by DFT/NMR integrated approach." Magnetic Resonance in Chemistry, November 13, 2018. http://dx.doi.org/10.1002/mrc.4804.

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