Articles de revues sur le sujet « Thiodiethanol »

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1

Zhang, Yousheng, Suning Wang, Craig Bridges et John E. Greedan. « Co(II) and Mn(II) complexes of 2,2'-thiodiethanol : [CoII(2,2'-thiodiethanol)2Cl2] and [Mn(2,2'-thiodiethanol)Cl2]n ». Canadian Journal of Chemistry 78, no 10 (1 octobre 2000) : 1289–94. http://dx.doi.org/10.1139/v00-132.

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[Co(2,2'-thiodiethanol)2Cl2] (1) and [Mn(2,2'-thiodiethanol)Cl2]n (2), have been synthesized and characterized structurally. Compound 1 is a six-coordinate, mononuclear Co(II) complex. The mononuclear units in the crystal lattice of 1 are linked together through intermolecular hydrogen bonds between hydroxy and chloride groups to form a three-dimensional array. Compound 2 consists of six-coordinate Mn(II) units that are linked by covalently bound 2,2'-thiodiethanol and chloride ligands to form an alternating one-dimensional chain, which is further linked together by inter-chain hydrogen bonds to form a two-dimensional sheet. Antiferromagnetic exchange is present in compound 2.Key words: cobalt, manganese, 2,2'-thiodiethanol, structure, magnetism.
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Zhang, Yousheng, Suning Wang, Craig Bridges et John E. Greedan. « Co(II) and Mn(II) comple×es of 2,2'-thiodiethanol : [CoII(2,2'-thiodiethanol)2Cl2] and [Mn(2,2'-thiodiethanol)Cl2]n ». Canadian Journal of Chemistry 78, no 10 (2000) : 1289–94. http://dx.doi.org/10.1139/cjc-78-10-1289.

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Kangas, Michael, Adreanna Ernest, Rachel Lukowicz, Andres Mora, Anais Quossi, Marco Perez, Nathan Kyes et Andrea Holmes. « The Identification of Seven Chemical Warfare Mimics Using a Colorimetric Array ». Sensors 18, no 12 (6 décembre 2018) : 4291. http://dx.doi.org/10.3390/s18124291.

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Chemical warfare agents pose significant threats in the 21st century, especially for armed forces. A colorimetric detection array was developed to identify warfare mimics, including mustard gas and nerve agents. In total, 188 sensors were screened to determine the best sensor performance, in order to identify warfare mimics 2-chloro ethyl ethylsulfide, 2-2′-thiodiethanol, trifluoroacetic acid, methylphosphonic acid, dimethylphosphite, diethylcyanophosphonate, and diethyl (methylthiomethyl)phosphonate. The highest loadings in the principle component analysis (PCA) plots were used to identify the sensors that were most effective in analyzing the RGB data to classify the warfare mimics. The dataset was reduced to only twelve sensors, and PCA results gave comparable results as the large data did, demonstrating that only twelve sensors are needed to classify the warfare mimics.
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Lydon, John D., et Richard C. Thompson. « Reduction of peroxotitanium(IV) by iodide, thiodiethanol, thioxane, and thiourea in acidic solution ». Inorganic Chemistry 25, no 20 (septembre 1986) : 3694–97. http://dx.doi.org/10.1021/ic00240a035.

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Bossle, P. C., S. F. Hallowell, D. J. Reutter et E. W. Sarver. « Analysis of 2,2′-thiodiethanol in aqueous matrices by liquid chromatography with electrochemical detection ». Journal of Chromatography A 330 (janvier 1985) : 388–91. http://dx.doi.org/10.1016/s0021-9673(01)82000-8.

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Mohan, Hari, et J. P. Mittal. « Electron transfer reactions in aqueous solutions of 2,2′-thiodiethanol : A pulse radiolysis study ». International Journal of Radiation Applications and Instrumentation. Part C. Radiation Physics and Chemistry 38, no 1 (janvier 1991) : 45–50. http://dx.doi.org/10.1016/1359-0197(91)90043-2.

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Staudt, Thorsten, Marion C. Lang, Rebecca Medda, Johann Engelhardt et Stefan W. Hell. « 2,2′-Thiodiethanol : A new water soluble mounting medium for high resolution optical microscopy ». Microscopy Research and Technique 70, no 1 (2006) : 1–9. http://dx.doi.org/10.1002/jemt.20396.

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Aoyagi, Yuka, Ryosuke Kawakami, Hisayuki Osanai, Terumasa Hibi et Tomomi Nemoto. « A Rapid Optical Clearing Protocol Using 2,2′-Thiodiethanol for Microscopic Observation of Fixed Mouse Brain ». PLOS ONE 10, no 1 (29 janvier 2015) : e0116280. http://dx.doi.org/10.1371/journal.pone.0116280.

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Kawashima, Hideki. « Production of [(2-Hydroxyethyl)thio] acetic Acid from Thiodiglycol (2,2′-Thiodiethanol) by Resting Cells ofCandida rugosaIFO 1364 ». Bioscience, Biotechnology, and Biochemistry 59, no 5 (janvier 1995) : 934–35. http://dx.doi.org/10.1271/bbb.59.934.

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Borowicz, Marcin, Joanna Paciorek-Sadowska, Jacek Lubczak et Bogusław Czupryński. « Biodegradable, Flame-Retardant, and Bio-Based Rigid Polyurethane/Polyisocyanurate Foams for Thermal Insulation Application ». Polymers 11, no 11 (5 novembre 2019) : 1816. http://dx.doi.org/10.3390/polym11111816.

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This article raised the issue of studies on the use of new bio-polyol based on white mustard seed oil and 2,2’-thiodiethanol (3-thiapentane-1,5-diol) for the synthesis of rigid polyurethane/polyisocyanurate (RPU/PIR) foams. For this purpose, new formulations of polyurethane materials were prepared. Formulations contained bio-polyol content from 0 to 0.4 chemical equivalents of hydroxyl groups. An industrial flame retardant, tri(2-chloro-1-methylethyl) phosphate (Antiblaze TCMP), was added to half of the formulations. Basic foaming process parameters and functional properties, such as apparent density, compressive strength, brittleness, absorbability and water absorption, aging resistance, thermal conductivity coefficient λ, structure of materials, and flammability were examined. The susceptibility of the foams to biodegradation in soil was also examined. The increase in the bio-polyol content caused a slight increase in processing times. Also, it was noted that the use of bio-polyol had a positive effect on the functional properties of obtained RPU/PIR foams. Foams modified by bio-polyol based on mustard seed oil showed lower apparent density, brittleness, compressive strength, and absorbability and water absorption, as well as thermal conductivity, compared to the reference (unmodified) foams. Furthermore, the obtained materials were more resistant to aging and more susceptible to biodegradation.
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MATSUMOTO, Satoshi, Kazutoshi IKENAGA et Hiroaki FUTIGAMI. « Studies on heterogeneous composite esters II. Composite ester plasticizers for poly(vinyl chloride) 2 composite esters consisting of 2,2'-thiodiethanol. » KOBUNSHI RONBUNSHU 48, no 1 (1991) : 19–24. http://dx.doi.org/10.1295/koron.48.19.

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Ferguson, George, Alan J. Lough, Christopher Glidewell et John Low. « The reaction of 2,2′-thiodiethanol with chloramine-T (sodium N-chlorotoluene-p-sulphonamide) : crystal and molecular structures of 2,2′-(p-tolylsulphonylimino-λ4-sulphanyl)diethanol monohydrate and 2,2′-sulphinyldiethanol ». J. Chem. Soc., Perkin Trans. 2, no 11 (1989) : 1685–90. http://dx.doi.org/10.1039/p29890001685.

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Dhammani, Anita, Rakesh Bohra et Ram C. Mehrotra. « Synthesis and characterization of some unique heterocyclic derivatives containing aluminium(III) atoms in 4- and 6-coordination states—3. Reaction of bis(β-diketonato) aluminium(III)-di-μ-isopropoxo di-isopropoxo aluminium(III) with 2-mercaptoethanol and 2,2′-thiodiethanol ». Polyhedron 15, no 4 (février 1996) : 733–37. http://dx.doi.org/10.1016/0277-5387(95)00276-x.

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Pope, Brandy E. Olin, Suzanne Dintzis, Elizabeth U. Parker, Rebeca Alvarez, Alexandra Alvarsson, Habib Rahbar et Nicholas Reder. « Abstract P6-04-18 : Rapid diagnosis of breast biopsies with open-top light-sheet microscopy ». Cancer Research 83, no 5_Supplement (1 mars 2023) : P6–04–18—P6–04–18. http://dx.doi.org/10.1158/1538-7445.sabcs22-p6-04-18.

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Abstract Intro: Detection of breast cancer is achieved through a diagnostic work-up that involves specialized breast imaging, image-guided biopsy, and pathological assessment. Pathology results typically require ~ 3 business days before a diagnosis is rendered, creating avoidable anxiety in women presenting with a breast abnormality. We describe a solution to deliver a rapid preliminary diagnosis within 30 minutes of biopsy. This rapid preliminary diagnosis has the potential to reduce anxiety, streamline patient care workflows, and reduce healthcare costs. Methods: Fresh 14 gauge breast biopsies in normal saline were received directly from the breast imaging clinic and immediately stained using the nuclear marker SYBR Gold (Invitrogen) and pan-protein marker Atto 655 NHS Ester (Sigma) prepared in dimethyl sulfoxide, washed, and cleared for imaging at a refractive index of 1.46 using 2,2’-Thiodiethanol (Sigma). The full process requires approximately 14 minutes for staining and clearing. After staining, we placed the biopsy in a custom-built specimen holder and imaged a 100-micron cross section along the full length of the biopsy using our custom open-top light-sheet microscope. Images were subsequently converted computationally to a standard hematoxylin and eosin (H&E) color format using Fiji and Aivia (Leica) software and were ready for evaluation by a pathologist on the same day they were collected. Results: Using the protocol above, we demonstrated the ability to stain, clear, image, and visualize needle core biopsies within 30 minutes of receiving the tissue sample. Processing the data and converting to the H&E color palette required additional time, often requiring 60-90 minutes, surpassing the overall 30 minute turnaround time goal. The images contained identifiable stroma, epithelial cells, immune cells, and duct structures to a depth of 100 microns. Discussion: We describe a method to obtain a microscopic image for preliminary diagnosis within 30 minutes of receipt of tissue. The quality of the images produced by the method shows promise for preliminary diagnosis. Additional optimization is needed in sample preparation and data processing to meet the 30 minute turnaround time requirement. This optimization can be achieved by parallelization of the data processing on a cluster or cloud to reduce the time by an order of magnitude, which is currently under investigation by our team. The imaging and data processing will also be accelerated by multi-resolution imaging, which will decrease the time of imaging and dataset size for processing. A diagnostic study, comparing the preliminary light-sheet-based diagnosis to the final formalin fixed paraffin embedded (FFPE) pathology, is underway. Citation Format: Brandy E. Olin Pope, Suzanne Dintzis, Elizabeth U. Parker, Rebeca Alvarez, Alexandra Alvarsson, Habib Rahbar, Nicholas Reder. Rapid diagnosis of breast biopsies with open-top light-sheet microscopy [abstract]. In: Proceedings of the 2022 San Antonio Breast Cancer Symposium; 2022 Dec 6-10; San Antonio, TX. Philadelphia (PA): AACR; Cancer Res 2023;83(5 Suppl):Abstract nr P6-04-18.
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Maity, Dilip K., et Hari Mohan. « Electron transfer reactions of 2,2′-thiodiethanoic acid in aqueous solutions : a pulse radiolysis study ». J. Chem. Soc., Perkin Trans. 2, no 11 (1993) : 2229–33. http://dx.doi.org/10.1039/p29930002229.

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LYDON, J. D., et R. C. THOMPSON. « ChemInform Abstract : Reduction of Peroxotitanium(IV) by Iodide, Thiodiethanol, Thioxane, and Thiourea in Acidic Solution. » ChemInform 18, no 4 (27 janvier 1987). http://dx.doi.org/10.1002/chin.198704029.

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Shan, Qing-Hong, Xin-Ya Qin, Nan Zhou, Chuan Huang, Yu Wang, Peng Chen et Jiang-Ning Zhou. « A method for ultrafast tissue clearing that preserves fluorescence for multimodal and longitudinal brain imaging ». BMC Biology 20, no 1 (29 mars 2022). http://dx.doi.org/10.1186/s12915-022-01275-6.

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Abstract Background Tissue-clearing techniques have recently been developed to make tissues transparent for three-dimensional (3D) imaging at different scales, including single-cell resolution. However, current tissue-clearing workflows have several disadvantages, including complex protocols, time-consuming application, and fluorescence quenching. Additionally, they can be used mainly for clearing larger-volume samples, preventing wide and easy applicability in conventional experimental approaches. In this study, we aimed to develop a versatile, fast, and convenient method for clearing thin and semi-thick samples, which can be used for three-dimensional imaging of experimental or even clinical samples. Results We developed an alkaline solution (AKS) containing a combination of 2,2′-thiodiethanol (TDE), DMSO, D-sorbitol, and Tris for tissue clearing, as the alkaline environment is suitable for maintaining the fluorescence of most commonly used fluorescence protein GFP and its variants, and tested its clearing effect on samples from mice and human brains. We assessed the clearing speed, the preservation of fluorescence protein and dyes, and the imaging depth and quality. The results showed that AKS treatment rapidly cleared 300-μm-thick brain slices and 1-mm-thick slices from different organs within 5 min and 1 h, respectively. Moreover, AKS was compatible with a variety of fluorescence proteins and dyes. Most importantly, AKS enhanced the fluorescence of YFP, in contrast to the majority of existing tissue-clearing methods which reduce the fluorescence intensity of fluorescent proteins. Using AKS, we performed long-time high-resolution imaging of weak fluorescent protein-labelled tissues, long-distance fibre tracking, larger-scale 3D imaging and cell counting of the entire brain area, neural circuit tracing, 3D neuromorphic reconstruction, and 3D histopathology imaging. Conclusions AKS can be used for simple and rapid clearing of samples from mice and human brains and is widely compatible with a variety of fluorescent dyes. Therefore, AKS has great potential to be used as a broad tissue-clearing reagent for biological optical imaging, especially for time-sensitive experiments.
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Bekkouche, Bo M. B., Helena K. M. Fritz, Elisa Rigosi et David C. O'Carroll. « Comparison of Transparency and Shrinkage During Clearing of Insect Brains Using Media With Tunable Refractive Index ». Frontiers in Neuroanatomy 14 (20 novembre 2020). http://dx.doi.org/10.3389/fnana.2020.599282.

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Improvement of imaging quality has the potential to visualize previously unseen building blocks of the brain and is therefore one of the great challenges in neuroscience. Rapid development of new tissue clearing techniques in recent years have attempted to solve imaging compromises in thick brain samples, particularly for high resolution optical microscopy, where the clearing medium needs to match the high refractive index of the objective immersion medium. These problems are exacerbated in insect tissue, where numerous (initially air-filled) tracheal tubes branching throughout the brain increase the scattering of light. To date, surprisingly few studies have systematically quantified the benefits of such clearing methods using objective transparency and tissue shrinkage measurements. In this study we compare a traditional and widely used insect clearing medium, methyl salicylate combined with permanent mounting in Permount (“MS/P”) with several more recently applied clearing media that offer tunable refractive index (n): 2,2′-thiodiethanol (TDE), “SeeDB2” (in variants SeeDB2S and SeeDB2G matched to oil and glycerol immersion, n = 1.52 and 1.47, respectively) and Rapiclear (also with n = 1.52 and 1.47). We measured transparency and tissue shrinkage by comparing freshly dissected brains with cleared brains from dipteran flies, with or without addition of vacuum or ethanol pre-treatments (dehydration and rehydration) to evacuate air from the tracheal system. The results show that ethanol pre-treatment is very effective for improving transparency, regardless of the subsequent clearing medium, while vacuum treatment offers little measurable benefit. Ethanol pre-treated SeeDB2G and Rapiclear brains show much less shrinkage than using the traditional MS/P method. Furthermore, at lower refractive index, closer to that of glycerol immersion, these recently developed media offer outstanding transparency compared to TDE and MS/P. Rapiclear protocols were less laborious compared to SeeDB2, but both offer sufficient transparency and refractive index tunability to permit super-resolution imaging of local volumes in whole mount brains from large insects, and even light-sheet microscopy. Although long-term permanency of Rapiclear stored samples remains to be established, our samples still showed good preservation of fluorescence after storage for more than a year at room temperature.
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FERGUSON, G., A. J. LOUGH, C. GLIDEWELL et J. LOW. « ChemInform Abstract : The Reaction of 2,2′-Thiodiethanol with Chloramine-T (Sodium N-Chlorotoluene-p-sulfonamide) : Crystal and Molecular Structures of 2,2′-(p-Tolylsulfonylimino-λ4-sulfanyl)diethanol Monohydrate (I) and 2,2′-Sulfinyldiethanol (II). » ChemInform 21, no 10 (6 mars 1990). http://dx.doi.org/10.1002/chin.199010039.

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