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1

Roselin, L. Selva, Ruey-Shin Juang, Chien-Te Hsieh, Suresh Sagadevan, Ahmad Umar, Rosilda Selvin et Hosameldin H. Hegazy. « Recent Advances and Perspectives of Carbon-Based Nanostructures as Anode Materials for Li-ion Batteries ». Materials 12, no 8 (15 avril 2019) : 1229. http://dx.doi.org/10.3390/ma12081229.

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Rechargeable batteries are attractive power storage equipment for a broad diversity of applications. Lithium-ion (Li-ion) batteries are widely used the superior rechargeable battery in portable electronics. The increasing needs in portable electronic devices require improved Li-ion batteries with excellent results over many discharge-recharge cycles. One important approach to ensure the electrodes’ integrity is by increasing the storage capacity of cathode and anode materials. This could be achieved using nanoscale-sized electrode materials. In the article, we review the recent advances and perspectives of carbon nanomaterials as anode material for Lithium-ion battery applications. The first section of the review presents the general introduction, industrial use, and working principles of Li-ion batteries. It also demonstrates the advantages and disadvantages of nanomaterials and challenges to utilize nanomaterials for Li-ion battery applications. The second section of the review describes the utilization of various carbon-based nanomaterials as anode materials for Li-ion battery applications. The last section presents the conclusion and future directions.
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Xue, J. S., J. R. Dahn et W. Xing. « Disordered carbon for rechargeable Li-ion battery ». Acta Crystallographica Section A Foundations of Crystallography 52, a1 (8 août 1996) : C412. http://dx.doi.org/10.1107/s0108767396083006.

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Goodenough, John B., et Kyu-Sung Park. « The Li-Ion Rechargeable Battery : A Perspective ». Journal of the American Chemical Society 135, no 4 (18 janvier 2013) : 1167–76. http://dx.doi.org/10.1021/ja3091438.

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Demir-Cakan, Rezan, Mathieu Morcrette, Jean-Bernard Leriche et Jean-Marie Tarascon. « An aqueous electrolyte rechargeable Li-ion/polysulfide battery ». J. Mater. Chem. A 2, no 24 (2014) : 9025–29. http://dx.doi.org/10.1039/c4ta01308e.

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In spite of great research efforts on Li–S batteries in aprotic organic electrolytes, there have been very few studies showing the potential application of this system in aqueous electrolyte. Herein, we explore this option and report on a cheaper and safer new aqueous system coupling a well-known cathode material in Li-ion batteries (i.e. LiMn2O4) with a dissolved polysulfide anode.
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Goodenough, John B. « How we made the Li-ion rechargeable battery ». Nature Electronics 1, no 3 (mars 2018) : 204. http://dx.doi.org/10.1038/s41928-018-0048-6.

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Siroya, Dharmik, et Preet Shah. « Lithium-Polymer Usb Rechargeable Battery ». International Journal for Research in Applied Science and Engineering Technology 10, no 8 (31 août 2022) : 190–94. http://dx.doi.org/10.22214/ijraset.2022.46140.

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Abstract: Interest in Rechargeable Batteries has risen drastically on account of environmental and energy concerns. The need for advancement in batteries has increased due to various applications in the field of science and technology. Therefore, rechargeable batteries were conceived and developed. Rechargeable batteries have high performance, high energy density, flexibility, light weight, better design and performance than non-rechargeable batteries. With increasing energy storage demands, calls for Li-ion rechargeable batteries. This paper focuses on technical concepts, brief ideas about the technology and progress in these rechargeable batteries. The rechargeable battery requires heavy industrial machinery for the manufacturing. The machines required are easily available in the market and the chemicals required for the battery are also easily available. The finished product requires only a single USB port for charging. All these alarming factors incline towards the development of rechargeable batteries, more crucially. The materials used in rechargeable batteries are environmentally-friendly and because of its multiple reusability, it contributes to minimal wastage
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Suhaimi, Lalu, Andy Tirta et Muhammad Hilmy Alfaruqi. « THEORETICAL INVESTIGATION OF DIVALENT ION INSERTION INTO TUNNEL-TYPE MANGANESE DIOXIDE POLYMORPH ». OISAA Journal of Indonesia Emas 3, no 1 (15 janvier 2020) : 1–4. http://dx.doi.org/10.52162/jie.2020.003.01.1.

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Rechargeable battery plays an important role to support the implementation of clean and renewable energy. In this aspect, post Li-ion battery, such as Zn-ion battery is receiving great attention due to its low cost and enviromentally friendly. Therefore, studies of electrode materials for Zn-ion battery are of paramount importance. In this contribution, we present theoretical investigation to explore the potential use of tunnel-type manganese dioxide for zinc storage material. Our calculation suggests the stability of the material for Zn-ion battery application.
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Kotaka, Hiroki, Hiroyoshi Momida et Tamio Oguchi. « Performance and reaction mechanisms of tin compounds as high-capacity negative electrodes of lithium and sodium ion batteries ». Materials Advances 3, no 6 (2022) : 2793–99. http://dx.doi.org/10.1039/d1ma00967b.

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Han, Liang, Feng Xiao et Shen Wang Wang. « The Study of Current and Voltage Needle for Li-Ion Battery Formation ». Advanced Materials Research 650 (janvier 2013) : 403–6. http://dx.doi.org/10.4028/www.scientific.net/amr.650.403.

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In recent years, the environmental and rechargeable Li-ion battery has become a hot spot in new energy technology field. The performance of Li-ion battery is in a large part affected by the advanced special equipment. The current and voltage needle is an important part in the special equipment. Based on the existing current and voltage needle, the paper designs a new current and voltage needle which is used for Li-ion battery formation. In this paper, we make a detailed analysis of mechanical structure and point out the superiority compared with the existing current and voltage needle. Cooperating with other formation equipment, it has achieved good economic benefits for the enterprise.
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Jihad, Ahmad, Affiano Akbar Nur Pratama, Salsabila Ainun Nisa, Shofirul Sholikhatun Nisa, Cornelius Satria Yudha et Agus Purwanto. « Resynthesis of NMC Type Cathode from Spent Lithium-Ion Batteries : A Review ». Materials Science Forum 1044 (27 août 2021) : 3–14. http://dx.doi.org/10.4028/www.scientific.net/msf.1044.3.

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Li-ion batteries are one of the most popular energy storage devices widely applied to various kinds of equipment, such as mobile phones, medical and military equipment, etc. Therefore, due to its numerous advantages, especially on the NMC type, there is a predictable yearly increase in Li-ion batteries' demand. However, even though it is rechargeable, Li-ion batteries also have a usage time limit, thereby increasing the amount of waste disposed of in the environment. Therefore, this study aims to determine the optimum conditions and the potential and challenges from the waste Li-ion battery recycling process, which consists of pretreatment, metal extraction, and product preparation. Data were obtained by studying the literature related to Li-ion battery waste's recycling process, which was then compiled into a review. The results showed that the most optimum recycling process of Li-ion batteries consists of metal extraction by a leaching process that utilizes H2SO4 and H2O2 as leaching and reducing agents, respectively. Furthermore, it was proceeding with the manufacturing of a new Li-ion battery.
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Matsuno, Shinsuke, Masanobu Nakayama et Masataka Wakihara. « Anode Material of CoMnSb for Rechargeable Li-Ion Battery ». Journal of The Electrochemical Society 155, no 1 (2008) : A61. http://dx.doi.org/10.1149/1.2804421.

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Eglitis, R. I., et G. Borstel. « Towards a practical rechargeable 5 V Li ion battery ». physica status solidi (a) 202, no 2 (janvier 2005) : R13—R15. http://dx.doi.org/10.1002/pssa.200409083.

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Goodenough, John B., et Kyu-Sung Park. « ChemInform Abstract : The Li-Ion Rechargeable Battery : A Perspective ». ChemInform 44, no 20 (25 avril 2013) : no. http://dx.doi.org/10.1002/chin.201320273.

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Park, Seungyoung, Ziyauddin Khan, Tae Joo Shin, Youngsik Kim et Hyunhyub Ko. « Rechargeable Na/Ni batteries based on the Ni(OH)2/NiOOH redox couple with high energy density and good cycling performance ». Journal of Materials Chemistry A 7, no 4 (2019) : 1564–73. http://dx.doi.org/10.1039/c8ta10830g.

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Guo, Ai Hong, Shuang Feng, Yun Ting Mi et Hong Zhi Li. « Synthesis and Electrochemical Properties of Rechargeable Battery Electrolyte Lithium Bis(heptafluoroisopropyl)tetrafluorophosphate ». Applied Mechanics and Materials 327 (juin 2013) : 128–31. http://dx.doi.org/10.4028/www.scientific.net/amm.327.128.

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Lithium-ion secondary cell has high energy density, stable and high working voltage, wide working temperature and long working term. It is a safe and clean energy resource without pollution. At present, Lithium Hexafluorophosphate is used as conducting electrolyte lithium salt in lithium-ion secondary batteries. But Lithium Hexafluorophosphate as conducting electrolyte lithium salt has some disadvantages such as hydrolysis and instability. Lithium Bis (heptafluoroisopropyl) t-etrafluorophosphate Li [(C3F7)2PF4] was received by simons process from diisopropylchlorophosphane in this paper. As electrolyte of Li ion secondary cell, Li [(C3F7)2PF4] had lower vapor pressure than LiPF6 in the solvent in the same temperature, comparable conductivity and oxidation stability in the same concentration in room temperature. It was worth mentioning that Li [(C3F7)2PF4] has excellent stability towards hydrolysis. The synthesis process is safe and easily controlled.
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16

Zhang, Zishuai, Yu Zhou, Qiang Ru, Ching-yuan Su, Linfeng Sun, Xianhua Hou et Fuming Chen. « An aqueous rechargeable dual-ion hybrid battery based on Zn//LiTi2(PO4)3 electrodes ». Sustainable Energy & ; Fuels 4, no 5 (2020) : 2448–52. http://dx.doi.org/10.1039/d0se00122h.

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A rechargeable dual-ion hybrid battery based on an aqueous Li+/Zn2+ electrolyte with Zn//LiTi2(PO4)3 electrodes was demonstrated to work effectively.
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Desai, Aamod V., Vanessa Pimenta, Cara King, David B. Cordes, Alexandra M. Z. Slawin, Russell E. Morris et A. Robert Armstrong. « Conversion of a microwave synthesized alkali-metal MOF to a carbonaceous anode for Li-ion batteries ». RSC Advances 10, no 23 (2020) : 13732–36. http://dx.doi.org/10.1039/d0ra01997f.

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An alkali-metal MOF is prepared using microwave-assisted synthesis, which is converted into a carbonaceous solid at low energy costs. The MOF-derived solid functions as a promising anode for Li-ion rechargeable battery (LIB).
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18

Nguyen, O., E. Courtin, F. Sauvage, N. Krins, C. Sanchez et C. Laberty-Robert. « Shedding light on the light-driven lithium ion de-insertion reaction : towards the design of a photo-rechargeable battery ». Journal of Materials Chemistry A 5, no 12 (2017) : 5927–33. http://dx.doi.org/10.1039/c7ta00493a.

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Tian, Yangyang, Chong Lin, Zhenggong Wang et Jian Jin. « Polymer of intrinsic microporosity-based macroporous membrane with high thermal stability as a Li-ion battery separator ». RSC Advances 9, no 37 (2019) : 21539–43. http://dx.doi.org/10.1039/c9ra02308a.

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Tudoroiu, Roxana-Elena, Mohammed Zaheeruddin, Nicolae Tudoroiu et Sorin-Mihai Radu. « SOC Estimation of a Rechargeable Li-Ion Battery Used in Fuel Cell Hybrid Electric Vehicles—Comparative Study of Accuracy and Robustness Performance Based on Statistical Criteria. Part II : SOC Estimators ». Batteries 6, no 3 (14 août 2020) : 41. http://dx.doi.org/10.3390/batteries6030041.

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The purpose of this paper is to analyze the accuracy of three state of charge (SOC) estimators of a rechargeable Li-ion SAFT battery based on two accurate Li-ion battery models, namely a linear RC equivalent electrical circuit (ECM) and a nonlinear Simscape generic model, developed in Part 1. The battery SOC of both Li-ion battery models is estimated using a linearized adaptive extended Kalman filter (AEKF), a nonlinear adaptive unscented Kalman filter (AUKF) and a nonlinear and non-Gaussian particle filter estimator (PFE). The result of MATLAB simulations shows the efficiency of all three SOC estimators, especially AEKF, followed in order of decreasing performance by AUKF and PFE. Besides, this result reveals a slight superiority of the SOC estimation accuracy when using the Simscape model for SOC estimator design. Overall, the performance of all three SOC estimators in terms of accuracy, convergence of response speed and robustness is excellent and is comparable to state of the art SOC estimation methods.
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Fleischauer, M. D., T. D. Hatchard, A. Bonakdarpour et J. R. Dahn. « Combinatorial investigations of advanced Li-ion rechargeable battery electrode materials ». Measurement Science and Technology 16, no 1 (18 décembre 2004) : 212–20. http://dx.doi.org/10.1088/0957-0233/16/1/028.

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Chang, Hao-Hsun, Tseng-Hsiang Ho et Yu-Sheng Su. « Graphene-Enhanced Battery Components in Rechargeable Lithium-Ion and Lithium Metal Batteries ». C 7, no 3 (16 septembre 2021) : 65. http://dx.doi.org/10.3390/c7030065.

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Stepping into the 21st century, “graphene fever” swept the world due to the discovery of graphene, made of single-layer carbon atoms with a hexagonal lattice. This wonder material displays impressive material properties, such as its electrical conductivity, thermal conductivity, and mechanical strength, and it also possesses unique optical and magnetic properties. Many researchers see graphene as a game changer for boosting the performance of various applications. Emerging consumer electronics and electric vehicle technologies require advanced battery systems to enhance their portability and driving range, respectively. Therefore, graphene seems to be a great candidate material for application in high-energy-density/high-power-density batteries. The “graphene battery”, combining two Nobel Prize-winning concepts, is also frequently mentioned in the news and articles all over the world. This review paper introduces how graphene can be adopted in Li-ion/Li metal battery components, the designs of graphene-enhanced battery materials, and the role of graphene in different battery applications.
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Eglitis, Roberts. « Ab initio calculations of Li2(Co, Mn)O8 solid solutions for rechargeable batteries ». International Journal of Modern Physics B 33, no 15 (20 juin 2019) : 1950151. http://dx.doi.org/10.1142/s0217979219501510.

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Current commercially available rechargeable Li-ion batteries, for example LiCoO2, are working mostly in the 4 V regime. One often suggested possibility to improve the effectivity of Li-ion batteries are the creation of the 5 V cathode materials. We performed quantum mechanical calculations on the average battery voltage for the Li2Co[Formula: see text]Mn[Formula: see text]O8 (x = 0, 1, 2, 3 and 4) cathode materials by means of the WIEN2k computer program package. The calculated average battery voltages for x = 0, 1, 2, 3 and 4 are equal to 3.95, 5, 4.47, 4.19 and 3.99 V. Our ab initio calculation results are compared with the available experimental data for x = 0, 1, 2 and 4 which are equal to 4, 5, 5 and 4 V. Thereby, for the Li2Co1Mn3O8 battery cathode material, our calculated average battery voltage around 5 V is in perfect agreement with the experimentally available battery voltage value of 5 Volt. Nevertheless, our calculated average battery voltage is underestimated (4.47 V) for the Li2Co2Mn2O8 cathode material, which also experimentally exhibits the 5 V voltage.
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Matsunami, M., T. Hashizume et A. Saiki. « Ion-Exchange Reaction Of A-Site In A2Ta2O6 Pyrochlore Crystal Structure ». Archives of Metallurgy and Materials 60, no 2 (1 juin 2015) : 941–44. http://dx.doi.org/10.1515/amm-2015-0234.

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Abstract Na+ or K+ ion rechargeable battery is started to garner attention recently in Place of Li+ ion cell. It is important that A+ site ion can move in and out the positive-electrode materials. When K2Ta2O6 powder had a pyrochlore structure was only dipped into NaOH aqueous solution at room temperature, Na2Ta2O6 was obtained. K2Ta2O6 was fabricated from a tantalum sheet by a hydrothermal synthesize with KOH aqueous solution. When Na2Ta2O6 was dipped into KOH aqueous solution, K2Ta2O6 was obtained again. If KTaO3 had a perovskite structure was dipped, Ion-exchange was not observed by XRD. Because a lattice constant of pyrochlore structure of K-Ta-O system is bigger than perovskite, K+ or Na+ ion could shinny through and exchange between Ta5+ and O2− ion site in a pyrochlore structure. K+ or Na+ ion exchange of A2Ta2O6 pyrochlore had reversibility. Therefore, A2Ta2O6 had a pyrochlore structure can be expected such as Na+ ion rechargeable battery element.
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Ye, Hui, Zhi Fang, Prabhakar Tamirisa, Gaurav Jain et Erik Scott. « (Digital Presentation) Thermal Acceleration Model for the Capacity Fade of a Rechargeable Li Ion Battery and Its Validation with 10+ Years of Testing Data ». ECS Meeting Abstracts MA2022-01, no 2 (7 juillet 2022) : 388. http://dx.doi.org/10.1149/ma2022-012388mtgabs.

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Rechargeable Li ion batteries have become not only a major power source for consumer electronics, but also a critical power source for high demanding applications like electrical vehicles, portable military devices and medical devices. Medtronic, one of the leading medical device companies has developed a breakthrough rechargeable Li ion battery technology-OverdriveTM to power implantable neurostimulators such as Intellis and Interstim Micro. OverdriveTM batteries have exceptional stable performance and fast charging capability. Figure 1 shows design verification test of capacity stability under two different discharge rate, C/24 and C/168; charging rate are 2C for both groups. As shown in Figure 1, there is virtually no capacity fade under C/168 discharge rate cycling and only a few percent capacity loss under C/24 rate cycling for more than 10 years of testing at 37oC. It is crucial to have a good acceleration testing model to design a rechargeable battery with reliable performance over 10 years of service and to ensure robust design with foreseeing battery material replacement over time. In the early development stage, we established a thermal acceleration capacity fade model for our OverdriveTM battery based on 2 years of testing as shown in Figure 2. Figure 2 shows capacity fade of Overdrive battery cycling at different temperatures up to 10 years. The trend of additional 8 years of data is consistent with model prediction. This presentation will highlight the performance characteristics of the OverdriveTM battery technology and provide the technical details of thermal acceleration capacity fade model. In addition, we will present how the model has been applied to understand the degradation mechanism of OverdriveTM battery and to improve the battery chemistry. Figure 1
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Hoang, Tuan K. A., Longyan Li, Jian Zhi, The Nam Long Doan, Wenhan Dong, Xiaoxiao Huang, Junhong Ma, Yahong Xie, Menglei Chang et P. Chen. « A True Non-Newtonian Electrolyte for Rechargeable Hybrid Aqueous Battery ». Batteries 8, no 7 (13 juillet 2022) : 71. http://dx.doi.org/10.3390/batteries8070071.

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The rechargeable aqueous hybrid battery is a unique system in which the Li-ion mechanism dominates the cathode while the first-order metal reaction of stripping/depositing regulates the anode. This battery inherits the advantages of the low-cost anode while possessing the capability of the Li-ion cathode. One of the major challenges is to design a proper electrolyte to nourish such strengths and alleviate the downsides, because two different mechanisms are functioning separately at the node–electrolyte and the cathode–electrolyte interfaces. In this work, we design a non-Newtonian electrolyte which offers many advantages for a Zn/LiMn2O4 battery. The corrosion is kept low while almost non-dendritic zinc deposition is confirmed by chronoamperometry and ex situ microscopy. The gel strength and gelling duration of such non-Newtonian electrolytes can be controlled. The ionic conductivity of such gels can reach 60 mS⋅cm−1. The battery exhibits reduced self-discharge, 6–10% higher specific discharge capacity than the aqueous reference battery, high rate capability, nearly 80% capacity retention after 1000 cycles, and about 100 mAh⋅g−1 of specific discharge capacity at cycle No. 1000th. Negligible amorphization on the cathode surface and no passivation on the anode surface are observed after 1000 cycles, evidenced by X-ray diffraction and scanning electron microscopy on the post-run battery electrodes.
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Wang, Yuhang, Yehua Wang, Jing Tang, Yongyao Xia et Gengfeng Zheng. « Aqueous Li-ion cells with superior cycling performance using multi-channeled polyaniline/Fe2O3 nanotube anodes ». J. Mater. Chem. A 2, no 47 (2014) : 20177–81. http://dx.doi.org/10.1039/c4ta04465g.

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Romanenko, Konstantin, et Alexej Jerschow. « Distortion-free inside-out imaging for rapid diagnostics of rechargeable Li-ion cells ». Proceedings of the National Academy of Sciences 116, no 38 (30 août 2019) : 18783–89. http://dx.doi.org/10.1073/pnas.1906976116.

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Safety risks associated with modern high energy-dense rechargeable cells highlight the need for advanced battery screening technologies. A common rechargeable cell exposed to a uniform magnetic field creates a characteristic field perturbation due to the inherent magnetism of electrochemical materials. The perturbation pattern depends on the design, state of charge, accumulated mechanical defects, and manufacturing flaws of the device. The quantification of the induced magnetic field with MRI provides a basis for noninvasive battery diagnostics. MRI distortions and rapid signal decay are the main challenges associated with strongly magnetic components present in most commercial cells. These can be avoided by using Single-Point Ramped Imaging with T1 enhancement (SPRITE). The method is immune to image artifacts arising from strong background gradients and eddy currents. Due to its superior image quality, SPRITE is highly sensitive to defects and the state of charge distribution in commercial Li-ion cells.
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Ni, Jie, Qiang Feng Xiao, YiKE Lei, YongKang Han, YingChuan Zhang, Zhen Geng et Cunman Zhang. « (Digital Presentation) A Polymeric/Inorganic Composite Coatings on the Separator for High-Energy Lithium Metal Battery ». ECS Meeting Abstracts MA2022-02, no 3 (9 octobre 2022) : 196. http://dx.doi.org/10.1149/ma2022-023196mtgabs.

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Lithium metal (Li) is a highly promising anode for next-generation rechargeable due to its high specific capacity (3,860 mA/g) and low negative electrochemical potential (-3.040 V vs. the standard hydrogen electrode). However, the issues such as high reactivity with electrolyte, infinite volume expansion, and uneven Li plating/stripping, cause low Coulombic efficiency, unstable growth of the solid-electrolyte interphase (SEI), and lithium dendrites. SEI plays an important role in the stabilization of lithium metal anodes in rechargeable batteries. Here we report a polymeric inorganic composite coatings (PICC) on the Celgard separator to regulate the Li-ion transport during charge/discharge of the battery. Such coatings enable uniformly deposition of Li, form a stable SEI film and in turn improve the electrochemical performance of the rechargeable batteries. Firstly, poly(vinylidene fluoride) (PVDF) and Li6.03La3Zr1.75Nb0.25Al0.24O12 (LLZO) were mixed at a mass ratio of 1:2, 1:1 and 1:2 in DMF, respectively. Afterwards the mixtures were coated onto the Celgard separator using doctor blades. In the carbonate-based electrolyte, the cycle life of Li‖Cu batteries with coating (PVDF:LLZO=1:2) increases from 30 cycles for uncoated batteries to 120 cycles of and a high Coulomb Efficiency of 96% is achieved. Moreover, when a high mass loading of 15 mg/cm2 NCM811 is chosen as cathodes, the Li‖NCM811 batteries using the PICC exhibit decent rate and cycling performance. After 100 cycles, the capacity retention at 0.2C of 94% is obtained, and the specific capacity is still 191 mAh/g. These results indicate that PICC can improve the electrochemical performance of Li anodes for high-energy rechargeable lithium metal batteries.
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Sung, Geon-Kyu, et Cheol-Min Park. « Puckered-layer-structured germanium monosulfide for superior rechargeable Li-ion battery anodes ». Journal of Materials Chemistry A 5, no 12 (2017) : 5685–89. http://dx.doi.org/10.1039/c7ta00358g.

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Puckered-layer-structured germanium monosulfide (GeS) and corresponding amorphous-carbon-decorated nanocomposites (GeS–C) were synthesized and used to fabricate Li-ion battery anodes which displayed remarkable reversible capacity above 1050 mA h g−1after 100 cycles.
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Li, Yao Yao, Yin Hu et Cheng Tao Yang. « Regulating Li<sup>+</sup> ; Transfer and Solvation Structure via Metal-Organic Framework for Stable Li Anode ». Key Engineering Materials 939 (25 janvier 2023) : 123–27. http://dx.doi.org/10.4028/p-in7u78.

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Lithium metal batteries (LMBs) possess large application potential for advanced rechargeable batteries due to the high energy density (> 500 Wh kg−1) and alternative cathode materials. Random Li dendrite growth caused by uneven Li+ distribution and local ion depletion near surface of Li anode induces battery failure with inferior long-term stability. Therefore, regulation of ion distribution near anode surface is essential to realize dendrite-free and uniform Li deposition. Herein, a metal-organic framework (MOF), i.e., ZIF-8, is applied to regulate Li+ solvation structure via unsaturated metal-ion sites to achieve uniform Li+ distribution and Li deposition. A stable cycling performance over 800 h for Li symmetrical cell at 3 mA cm−2 and 3 mAh cm−2 without short circuit is realized. The facilitated Li+ solvation via the adsorption effect of metal-ion sites on anions is demonstrated, which further enhances the uniform Li+ distribution near Li anode surface. This work demonstrates an effective strategy for regulating ion coordination and Li+ distribution to stabilize Li anode via MOF-based materials.
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Kondori, Alireza, Mohammadreza Esmaeilirad, Ahmad Mosen Harzandi, Rachid Amine, Mahmoud Tamadoni Saray, Lei Yu, Tongchao Liu et al. « A room temperature rechargeable Li 2 O-based lithium-air battery enabled by a solid electrolyte ». Science 379, no 6631 (3 février 2023) : 499–505. http://dx.doi.org/10.1126/science.abq1347.

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A lithium-air battery based on lithium oxide (Li 2 O) formation can theoretically deliver an energy density that is comparable to that of gasoline. Lithium oxide formation involves a four-electron reaction that is more difficult to achieve than the one- and two-electron reaction processes that result in lithium superoxide (LiO 2 ) and lithium peroxide (Li 2 O 2 ), respectively. By using a composite polymer electrolyte based on Li 10 GeP 2 S 12 nanoparticles embedded in a modified polyethylene oxide polymer matrix, we found that Li 2 O is the main product in a room temperature solid-state lithium-air battery. The battery is rechargeable for 1000 cycles with a low polarization gap and can operate at high rates. The four-electron reaction is enabled by a mixed ion–electron-conducting discharge product and its interface with air.
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Yun, Young Jun, Jin Kyu Kim, Ji Young Ju, Sanjith Unithrattil, Sun Sook Lee, Yongku Kang, Ha-Kyun Jung, Jin-Seong Park, Won Bin Im et Sungho Choi. « A morphology, porosity and surface conductive layer optimized MnCo2O4 microsphere for compatible superior Li+ ion/air rechargeable battery electrode materials ». Dalton Transactions 45, no 12 (2016) : 5064–70. http://dx.doi.org/10.1039/c5dt04975j.

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Widiyandari, H., A. Purwanto et S. A. Widyanto. « Polyvinilidine fluoride (PVDF) nanofiber membrane for Li-ion rechargeable battery separator ». Journal of Physics : Conference Series 817 (10 avril 2017) : 012013. http://dx.doi.org/10.1088/1742-6596/817/1/012013.

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Reddy, Ch V. Subba, J. Wei, Z. Quan-Yao, D. Zhi-Rong, Chen Wen, Sun-il Mho et Rajamohan R. Kalluru. « Cathodic performance of (V2O5+PEG) nanobelts for Li ion rechargeable battery ». Journal of Power Sources 166, no 1 (mars 2007) : 244–49. http://dx.doi.org/10.1016/j.jpowsour.2007.01.010.

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Morris, R. Scott, Brian G. Dixon, Thomas Gennett, Ryne Raffaelle et Michael J. Heben. « High-energy, rechargeable Li-ion battery based on carbon nanotube technology ». Journal of Power Sources 138, no 1-2 (novembre 2004) : 277–80. http://dx.doi.org/10.1016/j.jpowsour.2004.06.014.

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Azmi, Bustam M., Tatsumi Ishihara, Hiroyasu Nishiguchi et Yusaku Takita. « LiVOPO4 as a new cathode materials for Li-ion rechargeable battery ». Journal of Power Sources 146, no 1-2 (août 2005) : 525–28. http://dx.doi.org/10.1016/j.jpowsour.2005.03.101.

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Gandoman, Foad H., Adel El-Shahat, Zuhair M. Alaas, Ziad M. Ali, Maitane Berecibar et Shady H. E. Abdel Aleem. « Understanding Voltage Behavior of Lithium-Ion Batteries in Electric Vehicles Applications ». Batteries 8, no 10 (20 septembre 2022) : 130. http://dx.doi.org/10.3390/batteries8100130.

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Electric vehicle (EV) markets have evolved. In this regard, rechargeable batteries such as lithium-ion (Li-ion) batteries become critical in EV applications. However, the nonlinear features of Li-ion batteries make their performance over their lifetime, reliability, and control more difficult. In this regard, the battery management system (BMS) is crucial for monitoring, handling, and improving the lifespan and reliability of this type of battery from cell to pack levels, particularly in EV applications. Accordingly, the BMS should control and monitor the voltage, current, and temperature of the battery system during the lifespan of the battery. In this article, the BMS definition, state of health (SoH) and state of charge (SoC) methods, and battery fault detection methods were investigated as crucial aspects of the control strategy of Li-ion batteries for assessing and improving the reliability of the system. Moreover, for a clear understanding of the voltage behavior of the battery, the open-circuit voltage (OCV) at three ambient temperatures, 10 °C, 25 °C, and 45 °C, and three different SoC levels, 80%, 50%, and 20%, were investigated. The results obtained showed that altering the ambient temperature impacts the OCV variations of the battery. For instance, by increasing the temperature, the voltage fluctuation at 45 °C at low SoC of 50% and 20% was more significant than in the other conditions. In contrast, the rate of the OCV at different SoC in low and high temperatures was more stable.
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Jeong, Goojin, Hansu Kim, Jong Hwan Park, Jaehwan Jeon, Xing Jin, Juhye Song, Bo-Ram Kim, Min-Sik Park, Ji Man Kim et Young-Jun Kim. « Nanotechnology enabled rechargeable Li–SO2 batteries : another approach towards post-lithium-ion battery systems ». Energy & ; Environmental Science 8, no 11 (2015) : 3173–80. http://dx.doi.org/10.1039/c5ee01659b.

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Senthilkumar, Sri Harini, Brindha Ramasubramanian, Rayavarapu Prasada Rao, Vijila Chellappan et Seeram Ramakrishna. « Advances in Electrospun Materials and Methods for Li-Ion Batteries ». Polymers 15, no 7 (24 mars 2023) : 1622. http://dx.doi.org/10.3390/polym15071622.

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Electronic devices commonly use rechargeable Li-ion batteries due to their potency, manufacturing effectiveness, and affordability. Electrospinning technology offers nanofibers with improved mechanical strength, quick ion transport, and ease of production, which makes it an attractive alternative to traditional methods. This review covers recent morphology-varied nanofibers and examines emerging nanofiber manufacturing methods and materials for battery tech advancement. The electrospinning technique can be used to generate nanofibers for battery separators, the electrodes with the advent of flame-resistant core-shell nanofibers. This review also identifies potential applications for recycled waste and biomass materials to increase the sustainability of the electrospinning process. Overall, this review provides insights into current developments in electrospinning for batteries and highlights the commercialization potential of the field.
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Choi, Seung Ho, Seung Jong Lee, Hye Jin Kim, Seung Bin Park et Jang Wook Choi. « Li2O–B2O3–GeO2 glass as a high performance anode material for rechargeable lithium-ion batteries ». Journal of Materials Chemistry A 6, no 16 (2018) : 6860–66. http://dx.doi.org/10.1039/c8ta00934a.

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Li2O–B2O3–GeO2 glass is demonstrated as a promising lithium-ion battery anode because the glass phase facilitates lithium ion conduction while buffering the volume expansion of the active material.
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42

Kumar, Harish, Sundar Rajan et Ashok K. Shukla. « Development of Lithium-ion Batteries from Micro-Structured to Nanostructured Materials : Its Issues and Challenges ». Science Progress 95, no 3 (septembre 2012) : 283–314. http://dx.doi.org/10.3184/003685012x13421145651372.

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Lithium-ion batteries are the systems of choice, offering high energy density, flexibility, lightness in weight, design and longer lifespan than comparable battery technologies. A brief historical review is given of the development of Li-ion rechargeable batteries, highlighting the ongoing research strategies, and highlighting the challenges regarding synthesis, characterization, electrochemical performance and safety of these systems. This work is primarily focused on development of Li-ion batteries from micro-structured to nanostructured materials and some of the critical issues namely, electrode preparation, synthesis, and electrochemical characterization. The purpose of this review is to act as a reference for future work in this area.
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Lee, Joo Hyeong, Chong S. Yoon, Jang-Yeon Hwang, Sung-Jin Kim, Filippo Maglia, Peter Lamp, Seung-Taek Myung et Yang-Kook Sun. « High-energy-density lithium-ion battery using a carbon-nanotube–Si composite anode and a compositionally graded Li[Ni0.85Co0.05Mn0.10]O2 cathode ». Energy & ; Environmental Science 9, no 6 (2016) : 2152–58. http://dx.doi.org/10.1039/c6ee01134a.

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Kirubakaran, Kiran Preethi, Senthil Chenrayan, Lakshmanan Kumaresan, Kavibharathy Kasiviswanathan et Kumaran Vediappan. « Sensitive mode investigations of lithium-ion cells with tavorite-type LiVXO4F (X = B, Si) as cathodes with stable cycling in low temperature operations ». Applied Physics Letters 121, no 13 (26 septembre 2022) : 133903. http://dx.doi.org/10.1063/5.0101447.

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Li-ion battery cathodes appear to be a significant factor affecting the total amount of energy delivered and the cost of the battery systems. LiVXO4F (X = B, Si), a polyanionic-based tavorite structure, is investigated as a cathode for Li-ion batteries and its capability to endure in sensitive mode operations, i.e., at temperatures of approximately 55 and −10 °C. Due to the near-freezing point at the atomic level and the absence of kinetic energy, a battery system operating at a lower temperature is theoretically expected to perform inferior. On the contrary, Vanadium boron oxyfluoride (VBF) has better electrochemical properties because of its tightly packed covalent bond, which produced structural stability at low temperature activities. This intriguing feature appears to hold promise for its use in advanced rechargeable battery systems in low-temperature areas and cold storage devices. This might pave the path for future energy storage and conversion devices to use neoteric tavorite structured electrodes.
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Demir-Cakan, Rezan, Mathieu Morcrette et Jean-Marie Tarascon. « Use of ion-selective polymer membranes for an aqueous electrolyte rechargeable Li-ion–polysulphide battery ». Journal of Materials Chemistry A 3, no 6 (2015) : 2869–75. http://dx.doi.org/10.1039/c4ta05756b.

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An aqueous electrolyte Li-ion–polysulphide batteries by replacing the ceramic membrane with an ion-selective polymer membrane is developed. A 1.5 V average voltage together with a stable cycling profile over 200 cycles at high current density regimes are easily achieved.
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Chang, Zheng, Xujiong Wang, Yaqiong Yang, Jie Gao, Minxia Li, Lili Liu et Yuping Wu. « Rechargeable Li//Br battery : a promising platform for post lithium ion batteries ». J. Mater. Chem. A 2, no 45 (2014) : 19444–50. http://dx.doi.org/10.1039/c4ta04419c.

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Castillo-Martínez, Diego Hilario, Adolfo Josué Rodríguez-Rodríguez, Adrian Soto, Alberto Berrueta, David Tomás Vargas-Requena, Ignacio R. Matias, Pablo Sanchis, Alfredo Ursúa et Wenceslao Eduardo Rodríguez-Rodríguez. « Design and On-Field Validation of an Embedded System for Monitoring Second-Life Electric Vehicle Lithium-Ion Batteries ». Sensors 22, no 17 (24 août 2022) : 6376. http://dx.doi.org/10.3390/s22176376.

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In the last few years, the growing demand for electric vehicles (EVs) in the transportation sector has contributed to the increased use of electric rechargeable batteries. At present, lithium-ion (Li-ion) batteries are the most commonly used in electric vehicles. Although once their storage capacity has dropped to below 80–70% it is no longer possible to use these batteries in EVs, it is feasible to use them in second-life applications as stationary energy storage systems. The purpose of this study is to present an embedded system that allows a Nissan® LEAF Li-ion battery to communicate with an Ingecon® Sun Storage 1Play inverter, for control and monitoring purposes. The prototype was developed using an Arduino® microcontroller and a graphical user interface (GUI) on LabVIEW®. The experimental tests have allowed us to determine the feasibility of using Li-ion battery packs (BPs) coming from the automotive sector with an inverter with no need for a prior disassembly and rebuilding process. Furthermore, this research presents a programming and hardware methodology for the development of the embedded systems focused on second-life electric vehicle Li-ion batteries. One second-life battery pack coming from a Nissan® Leaf and aged under real driving conditions was integrated into a residential microgrid serving as an energy storage system (ESS).
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Kim, Minjeong, Jahun Koo, Minjeong Kang, Juah Song et Chunjoong Kim. « Research Trend in Rock Salt Structured High Entropy Cathode ». Ceramist 25, no 1 (31 mars 2022) : 90–103. http://dx.doi.org/10.31613/ceramist.2022.25.1.06.

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Development of lithium-ion rechargeable batteries with high energy storage capability are required in timely manner. Recently, it has been experimentally and computationally proven that oxides with the disordered rock salt structure can be charged and discharged in the Li-ion battery system. In particular, the high entropy disordered rock salt cathode has unique structure property, where both Li-ion and transition metal are randomly located on the cation sites. Such disordering in metal sites can migrate the Li-ion in a percolating way albeit with sluggish kinetics. Therefore, the high entropy disordered rock salt structure has attracted great attention due to its high energy density and stable structure. In this paper, we introduce a simple and effective strategy in the selection of transition metals for high entropy cathodes to achieve desired electrochemical properties.
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Tang, Shuai, Xiang Li, Qianqian Fan, Xiuqing Zhang, Dan-Yang Wang, Wei Guo et Yongzhu Fu. « Review—Advances in Rechargeable Li-S Full Cells ». Journal of The Electrochemical Society 169, no 4 (1 avril 2022) : 040525. http://dx.doi.org/10.1149/1945-7111/ac638c.

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Lithium sulfur (Li-S) batteries with the high theoretical specific energy of 2600 Wh kg−1 are a promising candidate at the era of the post lithium-ion batteries. In most studies, lithium metal anode is used. To advance the Li-S battery towards practical application, Li-S full cells with low or non-Li metal anode need to be developed. Herein, the latest advances of the Li-S full cells are mainly categorized according to the initial state of the S cathode, i.e., sulfur (S) and lithium sulfide (Li2S). In each part, the challenges and strategies are thoroughly reviewed for the cells with different anodes, such as carbon, silicon, other alloys and metallic Li. The cycling performance comparisons of state-of-the-art Li-S full cells are also included. To achieve the high real energy density for practical applications, the Li-S full cells have to use low excess lithiated graphite, lithiated alloys, or metallic Li as the anodes. Meanwhile, the lean electrolyte is also important to further improve the practical energy density. The review is expected to supply a comprehensive guide to design Li-S full cells.
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Kim, Junghwan, Kihwan Kwon, Kwanghyun Kim, Seungmin Han, Patrick Joohyun Kim et Junghyun Choi. « Size Effect of a Piezoelectric Material as a Separator Coating Layer for Suppressing Dendritic Li Growth in Li Metal Batteries ». Nanomaterials 13, no 1 (24 décembre 2022) : 90. http://dx.doi.org/10.3390/nano13010090.

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Li metal has been intensively investigated as a next-generation rechargeable battery anode. However, its practical application as the anode material is hindered by the deposition of dendritic Li. To suppress dendritic Li growth, introducing a modified separator is considered an effective strategy since it promotes a uniform Li ion flux and strengthens thermal and mechanical stability. Herein, we present a strategy for the surface modification of separator, which involves coating the separator with a piezoelectric material (PM). The PM-coated separator shows higher thermal resistance than the pristine separator, and its modified surface properties enable the homogeneous regulation of the Li-ion flux when the separator is punctured by Li dendrite. Furthermore, PM was synthesized in different solvents via solvothermal method to explore the size effect. This strategy would be helpful to overcome the intrinsic Li metal anode problems.
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