Littérature scientifique sur le sujet « Organic-Inorganic Hybrid Nanoporous Phosphates »

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Articles de revues sur le sujet "Organic-Inorganic Hybrid Nanoporous Phosphates"

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Cave, M. R., David Farrar et Adrian J. Wright. « Organic/Inorganic Hybrid Calcium Phosphate Biomaterials ». Key Engineering Materials 361-363 (novembre 2007) : 383–86. http://dx.doi.org/10.4028/www.scientific.net/kem.361-363.383.

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Calcium alkyl phosphates and their strontium and magnesium analogues were synthesised by the reaction of aqueous metal salts with a range of alkyl phosphates of varying chain length and were characterised by X-ray diffraction, thermogravimetric and FTIR analyses. These hybrid structures are based on alternating organic/metal phosphate regions and were found to exhibit a linear increase in interlayer separation upon increasing the length of the alkyl chain. Our analysis suggests a general formula for these phases of M(ROPO3).nH2O (where M = Ca, Sr, Mg and R = alkyl group), containing alkyl bilayers reminiscent of phospholipid bilayers found in biological membranes.
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Li, Ying, Han-Ying Li, Kai-Chi Chang, Hsiu-Mei Lin et Chih-Min Wang. « Recent developments in organic–inorganic hybrid metal phosphates and phosphites ». Dalton Transactions 50, no 29 (2021) : 10014–19. http://dx.doi.org/10.1039/d1dt01016f.

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This frontier article highlights recent advances in synthesis and characterization of organic–inorganic hybrid metal phosphates and phosphites. The synthetic strategies and structural stabilities of hybrid composites blended with stable crystalline compounds are presented.
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Stevens, N. S. M., et M. E. Rezac. « Nanoporous organic/inorganic hybrid materials produced from poly(dimethyl siloxane) ». Polymer 40, no 15 (juillet 1999) : 4289–98. http://dx.doi.org/10.1016/s0032-3861(98)00662-4.

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Forster, Paul M., et Anthony K. Cheetham. « Hybrid Inorganic–Organic Solids : An Emerging Class of Nanoporous Catalysts ». Topics in Catalysis 24, no 1-4 (octobre 2003) : 79–86. http://dx.doi.org/10.1023/b:toca.0000003079.39312.99.

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Kim, Jae Hoon, Jin Hee An, Young Soo La, Jin Su Jung, Han Mo Jeong, Suck Man Kim, Nam Gu Moon, Byung Wha Lee, Young Ho Yoon et Young Il Choi. « Inorganic–organic hybrid nanoporous materials as adsorbent to remove VOCs ». Journal of Industrial and Engineering Chemistry 14, no 2 (mars 2008) : 194–201. http://dx.doi.org/10.1016/j.jiec.2007.11.003.

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Tsuru, Toshinori, Hiroyasu Kondo, Tomohisa Yoshioka et Masashi Asaeda. « Permeation of nonaqueous solution through organic/inorganic hybrid nanoporous membranes ». AIChE Journal 50, no 5 (2004) : 1080–87. http://dx.doi.org/10.1002/aic.10092.

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Yang, Lan, Haruo Naruke et Toshihiro Yamase. « A novel organic/inorganic hybrid nanoporous material incorporating Keggin-type polyoxometalates ». Inorganic Chemistry Communications 6, no 8 (août 2003) : 1020–24. http://dx.doi.org/10.1016/s1387-7003(03)00172-2.

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Rao, Katabathini Narasimha, Lee D. Dingwall, Pratibha L. Gai, Adam F. Lee, Stewart J. Tavener, Nigel A. Young et Karen Wilson. « Synthesis and characterization of nanoporous phospho-tungstate organic–inorganic hybrid materials ». Journal of Materials Chemistry 18, no 8 (2008) : 868. http://dx.doi.org/10.1039/b715826b.

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Qawasmi, Y., P. Atanasova, T. Jahnke, Z. Burghard, A. Müller, L. Grassberger, R. Strey, J. Bill et T. Sottmann. « Synthesis of nanoporous organic/inorganic hybrid materials with adjustable pore size ». Colloid and Polymer Science 296, no 11 (14 septembre 2018) : 1805–16. http://dx.doi.org/10.1007/s00396-018-4402-z.

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Wragg, David S., Gary B. Hix et Russell E. Morris. « Azamacrocycle-Containing Gallium Phosphates : A New Class of Inorganic−Organic Hybrid Material ». Journal of the American Chemical Society 120, no 27 (juillet 1998) : 6822–23. http://dx.doi.org/10.1021/ja9812305.

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Thèses sur le sujet "Organic-Inorganic Hybrid Nanoporous Phosphates"

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Chang, Yu-Tzu, et 張育慈. « Syntheses, Characterizations and Functional Properties of Nanoporous Frameworks of Organic-inorganic Hybrid Metal Phosphates and Phosphites ». Thesis, 2018. http://ndltd.ncl.edu.tw/handle/4ykmdd.

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Hsieh, Yuan-Hsin, et 謝沅芯. « Diamine Templated Zinc Phosphates and Organic/Inorganic Hybrid Zinc Phosphates ». Thesis, 2013. http://ndltd.ncl.edu.tw/handle/64880815315406426296.

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Chien, Chun-Chieh, et 簡君潔. « Organic-inorganic hybrid zinc phosphates : Green syntheses and functional properties ». Thesis, 2014. http://ndltd.ncl.edu.tw/handle/d6c3wu.

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Huang, Yu-Ting, et 黃玉廷. « Green Syntheses and Functionalities of Organic-Inorganic Hybrid Metal Phosphates ». Thesis, 2011. http://ndltd.ncl.edu.tw/handle/95220971014249763741.

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博士
國立清華大學
化學系
99
In this research, 18 compounds were synthesized by employing organic amine as template under hydrothermal conditions. They were classified into three systems: System A put emphasis on reduction of energy consumption and chemical recycling of waste PET. Reactions with the use of microwave as an energy source largely cut down the reaction time to 1% as compared to conventional heating time and successfully yielded three single-phased products of A1, A2 and A3. The compounds A2,A3 and A5 displayed 3D structures “seemingly the same “ but they are not exactly identical due to the common organic linkers of BDC moiety adopting different orientations with respect to the same inorganic framework. The results should overturn our conventional cognition on scaling up product by microwave synthesis. On the other hand, scraps of waste PET bottle were successfully employed in two reactions as potent reagents to produce new compound A5 and high-valued phosphor materials A6 with potential application to white-light LEDs, providing a brand new perspective to chemical recovery of waste PET. System B contains six layered zinc phosphates encapsulating organic supra molecules as guest species. Bearing intricate hydrogen-bonding patterns within each layer, the pseudo-neutral (H3tren)2[Zn3(PO4)4] sheets are highly adaptable to varied achiral organic monomers, making them transformed into different chiral supramolecular chains. As a result, the entire structures of B1-B4 were turned into chiral as well. Depending on the molecular size of guest monomers, the layer gap was able to pop up the most to 2.01 nm (B4). Furthermore, the zinc center could be doped with homo-valence transition metal ions. Incorporation of Co2+ ions into layers exerted strong influence on supramolecular guests’ arrangements while doping of Mn2+ ions created novel photoluminescence property-the inter-layer supramolecular guest became a good sensitizer for the emission of bright orange- (from B1-Mn) or pink- (from B4-Mn) light under UV excitation. System C involved the use of bola-type surfactant, the long chain amine-DADD, as organic template. In the synthesis additional bulky organic acid-BPDA was included together with (metal) phosphate to generate six layered materials. The compound of C3 is highly interesting as it not only was observed ultra-large inter layer gap of 2.2nm but also revealed intriguing green afterglow property. In the three systems, every structure was well-characterized and extended to the discussion on their syntheses, thermal properties, self-assembly of supramolecular guests and the mechanisms of luminescence. The study generated significant results with substantial novelty and made conceptual breakthroughs to the field of organic/inorganic hybrid metal phosphate materials.
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Chang, Ming-Chung, et 張銘中. « Hydrothermal Syntheses, Crystal Structures and Properties of Organic/Inorganic Hybrid Zinc Phosphates ». Thesis, 2006. http://ndltd.ncl.edu.tw/handle/80718313526872965091.

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Chen, Yen-Chieh, et 陳彥杰. « Synthesis and Properties of Inorganic-Organic Hybrid Frameworks of Metal Phosphates and Phosphites ». Thesis, 2016. http://ndltd.ncl.edu.tw/handle/53358385585200452645.

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碩士
國立中央大學
化學學系
104
Two series of metal phosphate and phosphites structural, A and B, were shown as follows:(DA1)Zn2(Lcis)(HPO4)2 (A1)、(DA1)Zn2(Ltrans)(HPO4)2 (A2)、Zn3(L)0.5(DA2)(HDA2)(HPO3)2 (B1) and Co3(L)0.5(DA2)(HDA2)(HPO3)2 (B2). A1 and A2 were synthesized with the same reactants under the mild hydrothermal conditions. B1 and B2 had a similar structure with different metal center (B1 for Zn and B2 for Co). All of these structures were determined by single-crystal X-ray diffraction. Purity determined by PXRD, EA, XRF and EDX.   A1 and A2 are similar structure. BDC(L) bonded to Zn center with two different phases (cis and trans coordinate with metal). This is the first time we find in OMPO (organic-metallophosphate). By soaking A1 and A2 in Na+ solution, we found that DA1 were partially replaced by Na+ ion and ethanol. By the results of Element Analysis、Thermogravimetry Analysis and FTIR, we determined the new structure :(DA1)0.5Na(C2H5OH)0.5Zn2(L)(HPO4)2. A1 and A2 had no luminescence properties. However, by soaking Eu3+ and Tb3+ ions solution, A1-Eu/Tb and A2-Eu/Tb had luminescence properties (green light for A1/A2-Tb and red light for A1/A2-Eu).   Soaking in Cu(NO3)2, powder color of B1 would turn white to blue by exchanging Cu ion for only an hour. B1 was also a good sensor for Cu2+ ion. The metal center of B2 was Co, which showed good magnetism. Determined by SQUID, B2 has paramagnetism in high temperature and antiferromagnetism in low temperature.
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Chang, Wen-Ming, et 張文明. « Hydrothermal Syntheses, Crystal Structures and Properties of Organic/Inorganic Hybrid Gallium and Mixed-Metal Phosphates ». Thesis, 2004. http://ndltd.ncl.edu.tw/handle/6m6n94.

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Jiang, Yau-Chen, et 江耀誠. « Hydrothermal Syntheses, Crystal Structures and Properties of Organic/Inorganic Hybrid Transition Metal Phosphates and Arsenates ». Thesis, 2003. http://ndltd.ncl.edu.tw/handle/16750372538422297570.

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Wu, Wei-Chang, et 吳韋昌. « Hydrothermal Syntheses, Crystal Structures and Properties of Organic/Inorganic Hybrid Zinc Phosphates and Zinc Phosphites ». Thesis, 2007. http://ndltd.ncl.edu.tw/handle/70115945311908853914.

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Chen, Chun Yu, et 陳君毓. « Hydrothermal Syntheses,Crystal Structures and Properties of Organic /Inorganic Hybrid Transition Metal Zinc and Uranium Phosphates ». Thesis, 2005. http://ndltd.ncl.edu.tw/handle/49975276749700218368.

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Chapitres de livres sur le sujet "Organic-Inorganic Hybrid Nanoporous Phosphates"

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Brunei, D., P. Sutra et F. Fajula. « New Chiral Hybrid Organic-Inorganic Mesoporous Materials for Enantioselective Epoxidation. » Dans Nanoporous Materials II, Proceedings of the 2nd Conference on Access in Nanoporous Materials, 773–80. Elsevier, 2000. http://dx.doi.org/10.1016/s0167-2991(00)80282-7.

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Inagaki, S., S. Guan, Y. Fukushima, T. Ohsuna et O. Terasaki. « Novel ordered mesoporous materials with hybrid organic-inorganic network in the frameworks ». Dans Nanoporous Materials II, Proceedings of the 2nd Conference on Access in Nanoporous Materials, 155–62. Elsevier, 2000. http://dx.doi.org/10.1016/s0167-2991(00)80209-8.

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Thangavel Vijayakumar, Chinnaswamy, Saravanamuthu Siva Kaylasa Sundari, Mahendran Arunjunai Raj et Syed Mohammed Shamim Rishwana. « Application of Metal-Organic Framework as Reactive Filler in Bisphenol-A-Based High-Temperature Thermosets ». Dans Recent Developments in Nanofibers Research [Working Title]. IntechOpen, 2022. http://dx.doi.org/10.5772/intechopen.107871.

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Excellent thermoset monomers, bisphenol-A-based biscyanate ester (BADCy) and bispropargyl ether (BPEBPA), are synthesized and thermally cured to high-temperature thermosetting polymers. The nanoporous aluminum fumarate (Al_FA_A), an interesting Metal-Organic Framework (MOF), is synthesized in an eco-friendly manner and used as a reactive nanoparticle filler. The interaction of fumarate π bonds (trans -CH=CH-) in MOF with the reactive end functional groups (-O-C ≡ N) in cyanate ester (CE) and (-CH2-C ≡ CH) in bispropargyl (BP) ethers is focused in these hybrid nanocomposites. The % decrease in enthalpy of curing in the organic and the inorganic blends (~60% for CE and ~ 10% for BP) indicates the interaction exciting between the MOF and the organic component. The addition of the aluminum fumarate MOF increases the glass transition temperature of the polymers. The amount of heat released for every increase in 1°C during the temperature window of curing (ΔHc/TE-TS) of the neat BADCy resin is approximately 2.4 times higher than the blend (BADCy+Al_FA_A). But BPEBPA shows only a 1% higher temperature curing window compared to its blend with MOF. The metal hotspots present in the hybrid nanocomposites may be the reason for the decrease in the thermal stability, and the % char residue is noted at 700°C. The TG-FTIR studies are done to predict the gaseous products (CO2) evolved during thermal degradation.
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Tyoker Kukwa, Donald, et Maggie Chetty. « Microalgae : The Multifaceted Biomass of the 21st Century ». Dans Biomass [Working Title]. IntechOpen, 2020. http://dx.doi.org/10.5772/intechopen.94090.

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Microalgae are unicellular, eukaryotic organisms which possess unique qualities of replication, producing biomass as a precursor for biofuels, nutraceuticals, biofertilizer, and fine chemicals including hydrocarbons. Microalgae access nitrates and phosphates in wastewater from municipalities, industries, and agricultural processes to grow. Wastewater is, therefore, culture media for microalgae, and provides the needed nutrients, micronutrients, inorganic and organic pollutants to produce microalgae biomass. Suitable strains of microalgae cultivated under mesophilic conditions in wastewater with optimized hydrodynamics, hydraulic retention time (HRT), luminous intensity, and other co-factors produce biomass of high specific growth rate, high productivity, and with high density. The hydrodynamics are determined using a range of bioreactors from raceway ponds, photobioreactors to hybrid reactors. Carbon dioxide is used in the photosynthetic process, which offers different growth stimuli in the daytime and the night-time as the microalgae cultivation technique is navigated between autotrophy, heterotrophy, and mixotrophy resulting in microalgal lipids of different compositions.
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Tyoker Kukwa, Donald, et Maggie Chetty. « Microalgae : The Multifaceted Biomass of the 21st Century ». Dans Biotechnological Applications of Biomass. IntechOpen, 2021. http://dx.doi.org/10.5772/intechopen.94090.

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Microalgae are unicellular, eukaryotic organisms which possess unique qualities of replication, producing biomass as a precursor for biofuels, nutraceuticals, biofertilizer, and fine chemicals including hydrocarbons. Microalgae access nitrates and phosphates in wastewater from municipalities, industries, and agricultural processes to grow. Wastewater is, therefore, culture media for microalgae, and provides the needed nutrients, micronutrients, inorganic and organic pollutants to produce microalgae biomass. Suitable strains of microalgae cultivated under mesophilic conditions in wastewater with optimized hydrodynamics, hydraulic retention time (HRT), luminous intensity, and other co-factors produce biomass of high specific growth rate, high productivity, and with high density. The hydrodynamics are determined using a range of bioreactors from raceway ponds, photobioreactors to hybrid reactors. Carbon dioxide is used in the photosynthetic process, which offers different growth stimuli in the daytime and the night-time as the microalgae cultivation technique is navigated between autotrophy, heterotrophy, and mixotrophy resulting in microalgal lipids of different compositions.
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Actes de conférences sur le sujet "Organic-Inorganic Hybrid Nanoporous Phosphates"

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Wang, T., H. Okuda et S. W. Lee. « Methanol selective fibre-optic gas sensor with a nanoporous thin film of organic-inorganic hybrid multilayers ». Dans Fifth Asia Pacific Optical Sensors Conference, sous la direction de Byoungho Lee, Sang-Bae Lee et Yunjiang Rao. SPIE, 2015. http://dx.doi.org/10.1117/12.2183999.

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