Bibliographies thématiques / Multidentate ligand systems

Littérature scientifique sur le sujet « Multidentate ligand systems »

Auteur : Grafiati
Publié le 18 mai 2024

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Articles de revues sur le sujet "Multidentate ligand systems"

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Kuzu, Istemi, Ivo Krummenacher, Jens Meyer, Felix Armbruster et Frank Breher. « Multidentate ligand systems featuring dual functionality ». Dalton Transactions, no 43 (2008) : 5836. http://dx.doi.org/10.1039/b808347a.

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Wang, Ya Zhen, Chuan Feng Yang et Jie Chen. « Advances of Chromium(III)-Based Catalysts with Multidentate Heteroatomic Ligands for 1-Hexene Production ». Advanced Materials Research 317-319 (août 2011) : 1797–800. http://dx.doi.org/10.4028/www.scientific.net/amr.317-319.1797.

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According to the various multidentate heteroatomic ligands(based oxygen,nitrogen, phosphorus,mixed N and P,mixed N and S donors, composition, activity and overall selectivity to 1-hexene of chromium-based trimerization catalysts were reviewed. Commercial application foreground of these catalyst systems was also expected.It was found that effect of ligand structure on activity and selectivity for ethylene trimerization was the most predominant.The PNP （(Ph2P)2N(cyclopentyl)）ligands were prepared using inexpensive reagents and gave the corresponding complexes in high yields.Due to the inexpensive ligands coupled with low MAO （methyl aluminum oxide）requirements and high activity and selectivity of these systems, this has positive implication for a commercial process to 1-hexene.
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Harmjanz, Michael, Ingmar M. Piglosiewicz, Brian L. Scott et Carol J. Burns. « Generation of Spirotricyclic Site-Differentiated Cyclotriphosphazenes : A Solvent-Free Approach to Multidentate N/O Donor Ligand Systems ». Inorganic Chemistry 43, no 2 (janvier 2004) : 642–50. http://dx.doi.org/10.1021/ic034990b.

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Gorshkov, Nikolay I., Andrey Yu Murko, Irina I. Gavrilova, Marina A. Bezrukova, Albert I. Kipper, Valerii D. Krasikov et Evgenii F. Panarin. « Synthesis of Water-Soluble Copolymers of N-vinylpyrrolidone with N-vinyldithiocarbamate as Multidentate Polymeric Chelation Systems and Their Complexes with Indium and Gallium ». Molecules 25, no 20 (14 octobre 2020) : 4681. http://dx.doi.org/10.3390/molecules25204681.

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Dithiocarbamate (DTC) derivatives of N-vinylpyrrolidone-N-vinylamine (VP–VA) copolymers were synthesized via reaction between the copolymers and carbon disulfide in alkaline medium; molecular masses of the products were 12 and 29 kDa; the VP:VDTC ratios were 94:6 and 83:17 mol.%. Complexation between the obtained DTC derivatives and metal ions (indium and gallium) was investigated. It was demonstrated that metal–DTC ligand complexes with 1:3 ratio between components were formed. Gallium metal–polymer complexes (MPC) were unstable in solution. Individual indium MPC were isolated and characterized by spectral and chromatographic methods. Unlike similar gallium MPC, they appeared to be stable in histidine challenge reaction.
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Song, Bin, Glen S. Kurokawa, Shuang Liu et Chris Orvig. « Proton- and lanthanide-coordinating properties of the tetraaza macrocycle (EDDA-KA)2 in aqueous solution ». Canadian Journal of Chemistry 79, no 5-6 (1 mai 2001) : 1058–67. http://dx.doi.org/10.1139/v00-179.

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The new potentially multidentate ligand (EDDA-KA)2 has been prepared and its acid-base properties determined. Its coordination properties with three lanthanide ions (La3+, Gd3+, and Lu3+) and Fe3+ have been studied in aqueous solution (I = 0.16 M NaCl, 25°C) by potentiometric pH, spectrophotometric, and 1H NMR titrations. In total, eight pKa values could be determined by these diverse methods. From the 1H NMR titrations, all the deprotonation steps could be determined and assigned (in groups). Strong hydrogen bonding among two nitrogen atoms and one oxygen atom on the pyrone ring was observed, and the corresponding pKa values were estimated to be 13.2 and 14.0. By comparison with similar systems, an equilibrium constant for the formation of the hydrogen bond was estimated, KI = 104.4. Eight stability constants in total were determined for various protonation states of the La3+ and Gd3+ complexes, but for Lu3+ only the last four constants were obtained. The species distribution diagram showed that [M(EDDA-KA)2-4H]2- predominated in the range 5 [Formula: see text] pH [Formula: see text] 9 and [M(EDDA-KA)2-6H]4- predominated in the region 9 [Formula: see text] pH [Formula: see text] 11. In the former complex, two strong hydrogen bonds anchored the macrocycle and Ln3+ was coordinated with the four carboxylate groups; in the latter, the two hydrogen bonding protons were absent and the metal ion might also bind to the nitrogens on the macrocycle. The stability of Gd3+-(EDDA-KA)2 is lower than the analogous Gd3+ complexes of DOTA, DTPA, and DTPA-BMA.Key words: acidity constants, stability constants, La3+, Gd3+, Lu3+, Fe3+, amino carboxylate chelator.
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Motekaitis, R. J., et A. E. Martell. « METAL ION SPECIATION IN COMPLEX MULTICOMPONENT SYSTEMS. SIX METAL IONS AND FIVE MULTIDENTATE LIGANDS ». Journal of Coordination Chemistry 14, no 1 (mai 1985) : 49–55. http://dx.doi.org/10.1080/00958978508080677.

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Belikov, Кonstantin, Ekateryna Bryleva, Zinaida Bunina, Victoria Varchenko, Anna Andryushchenko, Ilias Shcherbakov, Vitaliy Kalchenko, Andriy Drapailo, Alexander Zontov et Larysa Zontova. « SOLID PHASE EXTRACTANTS BASED ON POROUS POLYMERS IMPREGNATED WITH MULTIDENTATE CHELATING LIGANDS FOR ACTINIDE AND LANTHANIDE REMOVAL ». Science and Innovation 17, no 2 (27 avril 2021) : 64–71. http://dx.doi.org/10.15407/scine17.02.064.

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Introduction. Treatment and disposal of radioactive wastes as well as monitoring of radioactive isotope content in environmental objects are actual tasks in the developed world. Lanthanide and transuranium element removal from spent nuclear fuel of nuclear power plants allows decreasing waste amount to be dumped and diminishing the risk of environmental pollution by radionuclides. Problem Statement. Considering extreme radiotoxicity of transuranium elements and tight standards restricting their activity in air and water, there is an urgent need to develop accurate and highly sensitive methods for pollution control. Purpose. Development of solid phase extractants (SPEs) based on porous polymers impregnated with multidentate chelating ligands for lanthanide, uranium and transuranium element removal from aqueous solutions. Materials and Methods. The materials used are porous divinylbenzene polymers of POROLAS brand and styrene-divinylbenzene copolymers from Smoly SE (Kamianske); multidentate chelating ligands of actinides and lanthanides such as N,N,N´,N´-tetra-n-octyl-oxapentane-1,5-diamide (TODGA) and carbamoyl phosphine oxides (CMPO); sorbent from TrisKem (France) based on TRU Resin (Eichrom Industries, Inc.). The research techniques are inductively coupled plasma atomic emission spectrometry, IR spectroscopy, scanning electron spectroscopy, spectrofluorimetry. Results. The solid-phase extractants (SPEs) for actinide and lanthanide removal from aqueous solutions have been synthesized by impregnation of porous polymeric POROLAS matrices and TODGA, CMPO-(PhOct) and CMPO-(Ph2). Sorption kinetics has been studied and capacity values for the different sorbents have been estimated. Extractive columns for uranium and europium concentration have been manufactured. Conclusions. SPEs studied demonstrate a high efficiency in removing uranium and europium from aqueous solutions. Due to their characteristics obtained materials may be used for preconcentration of target ions in radioecologycal monitoring procedures.
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Hołyńska, Małgorzata, Rodolphe Clérac et Mathieu Rouzières. « Lanthanide Complexes with Multidentate Oxime Ligands as Single-Molecule Magnets and Atmospheric Carbon Dioxide Fixation Systems ». Chemistry - A European Journal 21, no 38 (31 juillet 2015) : 13321–29. http://dx.doi.org/10.1002/chem.201501824.

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Stepniak-Biniakiewicz, Danuta, Baohe Chen et Edward Deutsch. « A new, general synthetic route to multidentate N,S ligands for use in technetium-99m radiopharmaceuticals. Preparation of diamido disulfur, diamino dithiol, and tripodal N3S3 prototypes. Comparative biodistributions of [99mTcVO-DADS]- analogs which contain 5,5,5- and 5,7,5-membered chelate ring systems ». Journal of Medicinal Chemistry 35, no 2 (janvier 1992) : 274–79. http://dx.doi.org/10.1021/jm00080a011.

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Kuzu, Istemi, Ivo Krummenacher, Jens Meyer, Felix Armbruster et Frank Breher. « ChemInform Abstract : Multidentate Ligand Systems Featuring Dual Functionality ». ChemInform 40, no 10 (10 mars 2009). http://dx.doi.org/10.1002/chin.200910226.

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Thèses sur le sujet "Multidentate ligand systems"

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Mitra, Amritaa. « Multidentate ligand systems : metal binding and applications ». Thesis, University of North Bengal, 2017. http://ir.nbu.ac.in/handle/123456789/2627.

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Stollberg, Peter. « Synthesis and Characterization of Polydentate C3 Symmetric Ligand Systems in Metal Coordination ». Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2018. http://hdl.handle.net/21.11130/00-1735-0000-0003-C119-7.

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Chapitres de livres sur le sujet "Multidentate ligand systems"

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K. Joshi, Kaushal. « Chemistry with Schiff Bases of Pyridine Derivatives : Their Potential as Bioactive Ligands and Chemosensors ». Dans Chemistry with Pyridine Derivatives [Working Title]. IntechOpen, 2022. http://dx.doi.org/10.5772/intechopen.106749.

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Pyridine is a valuable nitrogen based heterocyclic compound which is present not only in large number of naturally occurring bioactive compounds, but widely used in drug designing and development in pharmaceuticals as well as a precursor to agrochemicals and chemical-based industries. Pyridine derivatives bearing either formyl or amino group undergo Schiff base condensation reaction with appropriate substrate and under optimum conditions resulting in Schiff base as product which behave as a flexible and multidentate bioactive ligand. These Schiff bases are of great interest in medicinal chemistry as they can exhibit physiological effects similar to pyridoxal-amino acid systems which are considered to be very important in numerous metabolic reactions. They possess an interesting range of bioactivities including antibacterial, antiviral, antitubercular, antifungal, antioxidant, anticonvulsants, antidepressant, anti-inflammatory, antihypertensive, anticancer activity etc. and considered as a versatile pharmacophore group. Further, several pyridine-based Schiff bases show very strong binding abilities towards the various cations and anions with unique photophysical properties which can be used in ion recognition and they are extensively used in development of chemosensors for qualitative and quantitative detection of selective or specific ions in various kinds of environmental and biological media. These chapter insights the bioactivity and ion recognition ability of Schiff bases derived from pyridine derivatives.
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