Bibliographies thématiques / Metal Coordination Chemistry

Littérature scientifique sur le sujet « Metal Coordination Chemistry »

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Publié le 7 septembre 2023

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Articles de revues sur le sujet "Metal Coordination Chemistry"

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Salzer, A. « Nomenclature of Organometallic Compounds of the Transition Elements (IUPAC Recommendations 1999) ». Pure and Applied Chemistry 71, no 8 (30 août 1999) : 1557–85. http://dx.doi.org/10.1351/pac199971081557.

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Organometallic compounds are defined as containing at least one metal-carbon bond between an organic molecule, ion, or radical and a metal. Organometallic nomenclature therefore usually combines the nomenclature of organic chemisty and that of coordination chemistry. Provisional rules outlining nomenclature for such compounds are found both in Nomenclature of Organic Chemistry, 1979 and in Nomenclature of Inorganic Chemistry, 1990This document describes the nomenclature for organometallic compounds of the transition elements, that is compounds with metal-carbon single bonds, metal-carbon multiple bonds as well as complexes with unsaturated molecules (metal-p-complexes).Organometallic compounds are considered to be produced by addition reactions and so they are named on an addition principle. The name therefore is built around the central metal atom name. Organic ligand names are derived according to the rules of organic chemistry with appropriate endings to indicate the different bonding modes. To designate the points of attachment of ligands in more complicated structures, the h, k, and m-notations are used. The final section deals with the abbreviated nomenclature for metallocenes and their derivatives.ContentsIntroduction Systems of Nomenclature2.1 Binary type nomenclature 2.2 Substitutive nomenlcature 2.3 Coordination nomenclature Coordination Nomenclature3.1 General definitions of coordination chemistry 3.2 Oxidation numbers and net charges 3.3 Formulae and names for coordination compounds Nomenclature for Organometallic Compounds of Transition Metals 4.1 Valence-electron-numbers and the 18-valence-electron-rule 4.2 Ligand names 4.2.1 Ligands coordinating by one metal-carbon single bond 4.2.2 Ligands coordinating by several metal-carbon single bonds 4.2.3 Ligands coordinating by metal-carbon multiple bonds 4.2.4 Complexes with unsaturated molecules or groups 4.3 Metallocene nomenclature
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Krezel, A., et W. Bal. « Coordination chemistry of glutathione. » Acta Biochimica Polonica 46, no 3 (30 septembre 1999) : 567–80. http://dx.doi.org/10.18388/abp.1999_4129.

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The metal ion coordination abilities of reduced and oxidized glutathione are reviewed. Reduced glutathione (GSH) is a very versatile ligand, forming stable complexes with both hard and soft metal ions. Several general binding modes of GSH are described. Soft metal ions coordinate exclusively or primarily through thiol sulfur. Hard ones prefer the amino acid-like moiety of the glutamic acid residue. Several transition metal ions can additionally coordinate to the peptide nitrogen of the gamma-Glu-Cys bond. Oxidized glutathione lacks the thiol function. Nevertheless, it proves to be a surprisingly efficient ligand for a range of metal ions, coordinating them primarily through the donors of the glutamic acid residue.
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de Carvalho, Antonio B., Maria A. M. A. de Maurera, José A. Nobrega, Clovis Peppe, Martyn A. Brown, Dennis G. Tuck, Marcelo Z. Hernandes, Elson Longo et Fabricio R. Sensato. « Coordination Chemistry of Br2InCH2Br : Coordination at the Metal Center ». Organometallics 18, no 1 (janvier 1999) : 99–105. http://dx.doi.org/10.1021/om980656p.

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Liu, Pengxin, Ruixuan Qin, Gang Fu et Nanfeng Zheng. « Surface Coordination Chemistry of Metal Nanomaterials ». Journal of the American Chemical Society 139, no 6 (26 janvier 2017) : 2122–31. http://dx.doi.org/10.1021/jacs.6b10978.

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Thornton, Peter. « Advances in transition metal coordination chemistry ». Polyhedron 16, no 23 (septembre 1997) : 4189. http://dx.doi.org/10.1016/s0277-5387(97)81443-x.

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Hui, Joseph K. H., et Mark J. MacLachlan. « Metal-containing nanofibers via coordination chemistry ». Coordination Chemistry Reviews 254, no 19-20 (octobre 2010) : 2363–90. http://dx.doi.org/10.1016/j.ccr.2010.02.011.

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Bröring, Martin. « Coordination polymers built from metal tripyrrin units ». Journal of Porphyrins and Phthalocyanines 12, no 12 (décembre 2008) : 1242–49. http://dx.doi.org/10.1142/s1088424608000625.

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This account summarizes recent advances in the coordination chemistry of tripyrrins and related ligands with a special emphasis on the structural chemistry of coordination polymers with such ligands. The tripyrrin ligand is unique in supporting the formation of 1D- and 3D-supramolecular structures from pentacoordinate transition metal ions due to an effective blockage of their sixth coordination site. Linear coordination polymers have been observed with a multitude of bidentate and tridentate bridging ligands like trifluoroacetate, azide, thio- and selenocyanate, and higher order pseudohalides. Homo- and heterodimetallic species have been obtained by the use of cyanometallates and could be characterized structurally in two cases. Besides the covalent coordination bonds, several secondary interactions like hydrogen bonding and π-stacking were found to support these coordination polymers and are demonstrated to allow the preparation of species with functionalized inner surfaces.
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Maji, Tapas Kumar, et Susumu Kitagawa. « Chemistry of porous coordination polymers ». Pure and Applied Chemistry 79, no 12 (1 janvier 2007) : 2155–77. http://dx.doi.org/10.1351/pac200779122155.

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Remarkable advances in the recent development of porous compounds based upon coordination polymers have paved the way toward functional chemistry having potential applications such as gas storage, separation, and catalysis. From the synthetic point of view, the advantage is a designable framework, which can readily be constructed from building blocks, the so-called bottom-up assembly. Compared with conventional porous materials such as zeolites and activated carbons, porous inorganic-organic hybrid frameworks have higher potential for adsorption of small molecules because of their designability with respect to the coordination geometry around the central metal ion as well as size and probable multifunctionality of bridging organic ligands. Although rigidity and robustness of porous framework with different degree of adsorption are the most studied properties of metal-organic coordination frameworks, there are few studies on dynamic porous frameworks, which could open up a new dimension in materials chemistry.
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Zheng, Heping, Mahendra Chordia, David Cooper, Ivan Shabalin, Maksymilian Chruszcz, Peter Müller, George Sheldrick et Wladek Minor. « Check your metal - not every density blob is a water molecule ». Acta Crystallographica Section A Foundations and Advances 70, a1 (5 août 2014) : C1483. http://dx.doi.org/10.1107/s2053273314085167.

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Metals play vital roles in both the mechanism and architecture of biological macromolecules, and are the most frequently encountered ligands (i.e. non-solvent heterogeneous chemical atoms) in the determination of macromolecular crystal structures. However, metal coordinating environments in protein structures are not always easy to check in routine validation procedures, resulting in an abundance of misidentified and/or suboptimally modeled metal ions in the Protein Data Bank (PDB). We present a solution to identify these problems in three distinct yet related aspects: (1) coordination chemistry; (2) agreement of experimental B-factors and occupancy; and (3) the composition and motif of the metal binding environment. Due to additional strain introduced by macromolecular backbones, the patterns of coordination of metal binding sites in metal-containing macromolecules are more complex and diverse than those found in inorganic or organometallic chemistry. These complications make a comprehensive library of "permitted" coordination chemistry in protein structures less feasible, and the usage of global parameters such as the bond valence method more practical, in the determination and validation of metal binding environments. Although they are relatively infrequent, there are also cases where the experimental B-factor or occupancy of a metal ion suggests careful examination. We have developed a web-based tool called CheckMyMetal [1](http://csgid.org/csgid/metal_sites/) for the quick validation of metal binding sites. Moreover, the acquired knowledge of the composition and spatial arrangement (motif) of the coordinating atoms around the metal ion may also help in the modeling of metal binding sites in macromolecular structures. All of the studies described herein were performed using the NEIGHBORHOOD SQL database [2], which connects information about all modeled non-solvent heterogeneous chemical motifs in PDB structure by vectors describing all contacts to neighboring residues and atoms. NEIGHBORHOOD has broad applications for the validation and data mining of ligand binding environments in the PDB.
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Kaur, Gurpreet, et Richard Hartshorn. « Applications of Coordination Chemistry in Biological Systems ». Acta Crystallographica Section A Foundations and Advances 70, a1 (5 août 2014) : C1376. http://dx.doi.org/10.1107/s2053273314086239.

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A novel 2,2′:6′,2″-terpyridine–picolylamine-based bridging ligand has been synthesized and fully characterized using a variety of analysis techniques including single crystal X-ray diffraction. As shown in figure (a), the ligand has both tridentate and bidentate metal binding sites available to coordinate with various metal ions. By varying the size of anions both dinuclear complexes and supramolecular assemblies have been produced. Addition of metal salts containing small anions like halides result in formation of Cu2L and Zn2L dinuclear complexes, figure (b), where one metal ion binds at each of the binding sites of the ligand. The metal ions in these complexes mimic active site of the hydrolytic enzymes and promote phosphatediester hydrolysis of model DNA/RNA compounds. Nearly ten times increase in the rate of hydrolysis of bis(p-nitrophenyl)phosphate (BNPP) is observed in comparison to the parent terpyridine and picolylamine complexes under physiological conditions. Larger anions like PF6-, ClO4-, SO42- , NO3- result in formation of Zn4L4 type squares via. head-to-head and tail-to-tail, HH-TT, (H=tridentate site, T=bidentate site) coordination of the ligand. The octahedrally bound Zn(II) ion between two tridentate sites can be replaced with Fe(II) to prepare Fe2Zn2L4 squares. A flat molecule of terephthalic acid was also deliberately encapsulated in the middle of the Fe2Zn2L4 square as shown in figure (c). The head-to-tail, HT, coordination of the ligand in case of Ni(II) results in formation of decanickel wheels, like [Ni10L10Cl4(H2O)6](Cl)15Br·~140H2O shown in figure (d). Due to the large structure of the molecule X-ray crystallographic studies rather have been quite challenging.
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Thèses sur le sujet "Metal Coordination Chemistry"

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Hannon, Michael John. « Metal ion control in oligopyridine coordination chemistry ». Thesis, University of Cambridge, 1993. https://www.repository.cam.ac.uk/handle/1810/272558.

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Arrowood, Kimberly Ann. « Combining cyclic peptides with metal coordination ». Thesis, Atlanta, Ga. : Georgia Institute of Technology, 2009. http://hdl.handle.net/1853/29700.

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Thesis (M.S.)--Chemistry and Biochemistry, Georgia Institute of Technology, 2009.
Committee Chair: Weck, Marcus; Committee Member: Collard, David; Committee Member: Kubanek, Julia. Part of the SMARTech Electronic Thesis and Dissertation Collection.
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Sze-To, Lap, et 司徒立. « The structural chemistry of coordination compounds containing d-block or f-block metals ». Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2010. http://hub.hku.hk/bib/B45204470.

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Lin, Xiang. « The supramolecular chemistry of metal-organic coordination oligomers and polymers ». Thesis, University of Nottingham, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.416395.

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Quirk, Jeffrey. « Coordination chemistry of selenoether macrocyclic ligands with transition metal ions ». Thesis, University of Southampton, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.242624.

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Näslund, Jan. « Solvated trivalent metal ions in solution : a coordination chemistry study / ». Uppsala : Swedish University of Agricultural Sciences, 2000. http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&doc_number=009419319&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA.

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Hall, Christopher. « The coordination of alkanes to transition metal fragments ». Thesis, University of York, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.331939.

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Parrott, Suzanne J. « The coordination chemistry of hydrazide and diazenide complexes of rhenium ». Thesis, University of Essex, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.315728.

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Ogilvie, Stephen Hudson. « Coordination Frameworks : Host-Guest Chemistry and Structural Dynamics ». Thesis, The University of Sydney, 2015. http://hdl.handle.net/2123/15897.

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This thesis investigates the host-guest chemistry and structural dynamics in three families of coordination frameworks – Prussian blue analogues (PBAs), zeolitic imidazolate frameworks (ZIFs), and lanthanoid metal-organic frameworks (MOFs). This was primarily achieved using in situ gas-loading neutron powder diffraction (NPD) to examine various guests in the pore space of these materials. Each of these frameworks contain structural motifs that have previously been identified as influential in the uptake of gases. Gas-loaded NPD of the PBA Fe¬3[Co(CN)6]2 revealed two CO2 adsorption sites, both of which interact with the coordinatively-unsaturated Fe(II) sites. A linear relationship was also observed between the material's thermal expansion behaviour when dosed with increasing amounts of CO2, suggesting the potential for controlled thermal expansion properties. NPD analysis of gas-loaded Co(nIm)2-RHO has revealed five adsorption sites each when this material was dosed with CO2 or D2. Host-guest interactions at CO2 and D¬2 adsorption sites are observed to be predominantly driven by electrostatic interactions with the nitro functional group of the 2 nitroimidazolate bridging ligand. Analysis of CO2-loaded NPD data for Co(mIm)2-SOD revealed only a single CO2 adsorption site that accounted for ca. 17% of the total amount of CO2 dosed. This comparison has helped to confirm the necessity of having ligands with strong charge polarisation in order to achieve guest interaction and crystallographic ordering. NPD analysis of gas-loaded Y(btc) has revealed multiple adsorption sites with dosed with CO2, CD4, and O2. These host-guest adsorption sites typically occur between the guest molecule and the carboxylate functional groups of the bridging ligand. Despite the presence of bare metal sites, only the O2 guest is seen to interact weakly. This has been attributed to the contraction in O-Y-O coordination angles upon desolvation of the host material.
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Higginson, Joshua J. « Synthesis and coordination chemistry of ditopic ligands capable of coordinating metal ions and interacting with anions ». Thesis, University of Huddersfield, 2015. http://eprints.hud.ac.uk/id/eprint/26444/.

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The aim of this research was to synthesise a series of novel organic multidentate ligands which contain N-donor domains for the coordination of metal ions and amide or amine hydrogen atoms which are capable of interaction with anions. It was envisaged that incorporation of these two binding units would produce a system where the metal ions would control the ability of the ligand to interact with anions or vice versa. Ligand 1 contains a tetradentate N-donor domain formed by a central bipyridine, two thaizole units and two amide units attached in the 4,4’-position of the bipyridine unit. Reaction of this with divalent metal ions results in a mono-nuclear complex where the metal is bound by the N-donor atoms and the amides interact with a variety of anions. Reaction with monovalent metal ions results in the formation of a dinuclear double helicate with the metal again coordinated by the N-donor domains and the anions interacting with the amide hydrogen atoms. This results in a polymeric assembly in the solid state. Ligand 2 contains an identical tetradentate domain comprised of the same N-donor units; however the single amides in the 4,4’-position have been removed and a diamide attached in the 3,3’-position of the bipyridine unit. Reaction of [L2 with divalent cations results in a similar mono-nuclear species. The metal centre is coordinated by the N-donor atoms and one of the acetyl units from two adjoining ligands with the counter ions undergoing interactions with the diamide hydrogen atoms. Coordination of the same ligand with a monovalent cation resulted in a di-nuclear double helicate, each metal centre is fulfilled by the N-donor atoms of the ligand strand and the hydrogen atoms of the diamide units interact with anions. This too results in a polymeric assembly in the solid state. Ligands 3 and 4 contain the iso-structural tetradentate N-donor domain seen in [L1] and [L2] but their functionality in the 3,3’-position differ. Ligand 3 contains a urea group while ligand 4 has a single amide group attatched to an indole unit. Coordination of [L3] and a divalent metal ion results in the formation of a mono-nuclear species with the metal ion bound by the central bipyridine and the N-donor of two thaizole units. Furthermore each of the urea groups in the 3,3’-position undergo favourable interactions with the perchlorate counter ions. A solid state structure of Ligand 4 was only successful with a monovalent cation resulting in the formation of a dinuclear double stranded species. Each metal centre exhibits a distorted trigonal planar geometry through coordination with a pyridine and thiazole ring of one strand and a single thiazole ring of another. The indole and amide of each ligand strand undergo two sets of interactions; anion interactions through the amide and indole hydrogen atoms as well as complementary intermolecular interactions between the indole N···H units of one ligand and the carbonyl C···O units of another complex. Both [L3] and [L4] exhibit long range order through favourable anion-NH interactions however [L4] also displays complimentary indole/acetyl interactions to develop a larger aggregate species. In all these cases the resultant complex is independent upon which anion is used. However, this is not the case with ligand 5. Reaction of [L5] with Cu(BF4)2 or Cu(ClO4)2 gave a dinuclear double helicate with a cleft within the helicate assembly in which an anion is bound. However, reaction of this with half an equivalent of either sulphate (SO4 2-) or dihydrogen phosphate (H2PO4 -) results in the formation of a different dinuclear double helicate whereby the cleft is occupied by either a dihydrogen phosphate or sulphate anion which bridges the metal centres. Further addition of sulphate results in no change of the ESI-MS indicating the dinuclear double helicate persist however addition of one equivalent of di-hydrogen phosphate leads to the formation of a pentanuclear circular helicate. Each metal centre is coordinated by the pyridine and thiazole units of two different ligand strands and a single Cu···O interaction from one of the dihydrogen phosphates. The inclusion of three dihydrogen phosphates into the centre of the assembly as well as a series of phosphate-ligand and phosphate-phosphate interactions leads to the dimerization of the structure with another set of phosphates from a second assembly. Further reaction of this dinuclear species with one equivalent of (Bu4N)NO3 resulted in the formation of a hexanuclear circular meso-helicate (or mesocate). In this structure each Ndonor domain of a thiazole and pyridine ring coordinate two different Cu2+ metal centres. Each metal centre exhibits a distorted octahedral arrangement with two ligand strands completing 4 of its 6 coordination sites, the remaining sites are occupied by two O-donors of a nitrate anion. In addition an amine of each ligand strand points into the centre of the complex creating a cavity capable of hosting two nitrate anions. Ligand 6 is made up of the same bis-bidentate donors as ligand 5 with the addition of a nitrogen atom into the central phenyl spacer. On reaction of [L6] with a divalent metal ion (e.g. Cu(II)) a simple mono-nuclear structure is observed. Although a mono-nuclear assembly is expected, it is interesting that even a simple change in the ligand strand can have a dramatic affect on the self-assembly process. When a central 1,3-phenylene spacer is employed (i.e. [L5]) a dinuclear double helicate is formed, however, when a 1,3-pyridine unit is contained within the ligand strand (i.e. [L6]) a simple mono-nuclear species is produced.
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Livres sur le sujet "Metal Coordination Chemistry"

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Basolo, Fred. Coordination chemistry. 2e éd. [England] : Science Reviews, 1986.

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C, Johnson Ronald, dir. Coordination chemistry. 2e éd. Northwood : Science Reviews, 1986.

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Chi-Ming, Che, et Yam Vivian W. W, dir. Advances in transition metal coordination chemistry. Greenwich, Co : Jai Press, 1996.

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A, Herrmann W., Astruc D, Okuda J et Zybill Ch, dir. Transition metall [sic] coordination chemistry. Berlin : Springer-Verlag, 1992.

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5

1933-, Huang Chun-Hui, dir. Rare earth coordination chemistry : Fundamentals and applications. Hoboken, N.J : Wiley, 2010.

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1934-, Veillard A., North Atlantic Treaty Organization. Scientific Affairs Division. et Société de chimie physique. International Meeting, dir. Quantum chemistry : The challenge of transition metals and coordination chemistry. Dordrecht : D. Reidel Pub. Co., 1986.

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van Koten, Gerard, et Robert A. Gossage, dir. The Privileged Pincer-Metal Platform : Coordination Chemistry & ; Applications. Cham : Springer International Publishing, 2016. http://dx.doi.org/10.1007/978-3-319-22927-0.

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Organotransition metal chemistry : From bonding to catalysis. Sausalito, Calif : University Science Books, 2010.

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Yamaguchi, Ryohei. Ligand platforms in homogenous catalytic reactions with metals : Practice and applications for green organic transformations. Hoboken, New Jersey : Wiley, 2015.

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M, Neĭman K., et Zhidomirov G. M, dir. Kvantovai͡a︡ khimii͡a︡ i spektroskopii͡a︡ vysokovozbuzhdennykh sostoi͡a︡niĭ : Koordinat͡s︡ionnye soedinenii͡a︡ perekhodnykh metallov. Novosibirsk : "Nauka," Sibirskoe otd-nie, 1990.

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Chapitres de livres sur le sujet "Metal Coordination Chemistry"

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Weber, Birgit. « Metal-Metal Bond ». Dans Coordination Chemistry, 139–53. Berlin, Heidelberg : Springer Berlin Heidelberg, 2023. http://dx.doi.org/10.1007/978-3-662-66441-4_9.

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Weber, Birgit. « Luminescence of Metal Complexes ». Dans Coordination Chemistry, 199–214. Berlin, Heidelberg : Springer Berlin Heidelberg, 2023. http://dx.doi.org/10.1007/978-3-662-66441-4_11.

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Rashvandi, Zahra, Fereshteh Rasouli Asl et Fatemeh Ganjali. « Coordination Chemistry of MOFs ». Dans Physicochemical Aspects of Metal-Organic Frameworks, 181–96. Cham : Springer International Publishing, 2023. http://dx.doi.org/10.1007/978-3-031-18675-2_12.

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Palmer, Joshua H. « Transition Metal Corrole Coordination Chemistry ». Dans Molecular Electronic Structures of Transition Metal Complexes I, 49–89. Berlin, Heidelberg : Springer Berlin Heidelberg, 2011. http://dx.doi.org/10.1007/430_2011_52.

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Hall, Michael B. « Multiple Metal-Metal and Metal-Carbon Bonds ». Dans Quantum Chemistry : The Challenge of Transition Metals and Coordination Chemistry, 391–401. Dordrecht : Springer Netherlands, 1986. http://dx.doi.org/10.1007/978-94-009-4656-9_28.

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Sato, Sota, et Makoto Fujita. « Metal-Organic Caged Assemblies ». Dans Coordination Chemistry in Protein Cages, 351–74. Hoboken, NJ, USA : John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118571811.ch14.

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Dzhardimalieva, Gulzhian I., et Igor E. Uflyand. « Coordination Polymers Containing Metal Chelate Units ». Dans Chemistry of Polymeric Metal Chelates, 633–759. Cham : Springer International Publishing, 2018. http://dx.doi.org/10.1007/978-3-319-56024-3_6.

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Lippert, B. « Metal-Nucleobase Chemistry : Coordination, Reactivity, and Base Pairing ». Dans Bioinorganic Chemistry, 179–99. Dordrecht : Springer Netherlands, 1995. http://dx.doi.org/10.1007/978-94-011-0255-1_15.

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Müller, Achim, et Dieter Rehder. « Molecular Metal Oxides in Protein Cages/Cavities ». Dans Coordination Chemistry in Protein Cages, 25–42. Hoboken, NJ, USA : John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118571811.ch2.

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Berry, Ginger M., Michael E. Bothwell, Beatriz G. Bravo, George J. Cali, John E. Harris, Thomas Mebrahtu, Susan L. Michelhaugh, Jose F. Rodriguez et Manuel P. Soriaga. « Surface Coordination/Organometallic Chemistry of Monometal and Bimetallic Electrocatalysts ». Dans Metal-Metal Bonds and Clusters in Chemistry and Catalysis, 316–17. Boston, MA : Springer US, 1990. http://dx.doi.org/10.1007/978-1-4899-2492-6_26.

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Actes de conférences sur le sujet "Metal Coordination Chemistry"

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Gildenast, Hans, Franziska Busse et Ulli Englert. « Competition of the Donor Atoms - Coordination Chemistry of a O,P,N tritopic Ligand - Complexes, Supramolecules and Metal-Organic Frameworks ». Dans The 2nd International Online Conference on Crystals. Basel, Switzerland : MDPI, 2020. http://dx.doi.org/10.3390/iocc_2020-07321.

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Kostić, Marina, Vera Divac et Sven Mangelinckx. « SYNTHESIS AND CHARACTERIZATION OF PALLADIUM (II)–2- (AZIDOMETHYL)CYCLOPROPANE-1,1-DICARBOXYLIC ACID COMPLEX ». Dans 1st INTERNATIONAL Conference on Chemo and BioInformatics. Institute for Information Technologies, University of Kragujevac, 2021. http://dx.doi.org/10.46793/iccbi21.297k.

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The discovery that palladium complexes possess a wide range of biological activities (from antitumor, -viral, -malarial, -fungal to antimicrobial activities) encourages further research in this scientific field. Herein we describe the synthesis and characterization of a novel palladium (II) complex, using [Pd(dien)Cl]Cl and 2-(azidomethyl)cyclopropane-1,1-dicarboxylic acid (azmcpda) as a ligand. [Pd(dien)Cl]Cl was selected as a starting material taking into consideration its importance as a model for the investigation of the substitution reactions in coordination chemistry and a deeper understanding of the biological activities of some structurally similar compounds. The ligand compound was synthesized by the procedure described in the literature. It is noteworthy to mention that 2- (azidomethyl)cyclopropane-1,1-dicarboxylic acid presents the precursor for the synthesis of 2- (aminomethyl)cyclopropane-1,1-dicarboxylic acid, as an example of the constrained γ-amino dicarboxylic acids. The synthesis was achieved by the conversion of the ligand compound into the corresponding sodium dicarboxylate salt and subsequent treatment with [Pd(dien)Cl]Cl (pH maintained between 6-7). The IR and NMR spectra, as well as elemental analysis have confirmed that the Na[Pd(dien)(azmcpda)]. H2O species was formed and that coordination of the ligand compound to the metal ion was established through carboxylate oxygen donor atom.
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Blair, Sharon L., C. W. Chu, Ralph R. Dammel et Ross H. Hill. « Use of complex coordination chemistry for the deposition of inorganic materials : spin on metals and photoresist-free lithography ». Dans Microlithography '97, sous la direction de Regine G. Tarascon-Auriol. SPIE, 1997. http://dx.doi.org/10.1117/12.275884.

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Rapports d'organisations sur le sujet "Metal Coordination Chemistry"

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Neu, Mary Patricia. Coordination chemistry of two heavy metals : I, Ligand preferences in lead(II) complexation, toward the development of therapeutic agents for lead poisoning : II, Plutonium solubility and speciation relevant to the environment. Office of Scientific and Technical Information (OSTI), novembre 1993. http://dx.doi.org/10.2172/10107977.

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