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Littérature scientifique sur le sujet « Heterochiral complex »

Auteur : Grafiati

Publié le 21 décembre 2024

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Articles de revues sur le sujet "Heterochiral complex"

Kabza, Adam M., Brian E. Young, Nandini Kundu et Jonathan T. Sczepanski. « Heterochiral nucleic acid circuits ». Emerging Topics in Life Sciences 3, n^o 5 (28 août 2019) : 501–6. http://dx.doi.org/10.1042/etls20190102.

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The programmability of DNA/RNA-based molecular circuits provides numerous opportunities in the field of synthetic biology. However, the stability of nucleic acids remains a major concern when performing complex computations in biological environments. Our solution to this problem is l-(deoxy)ribose nucleic acids (l-DNA/RNA), which are mirror images (i.e. enantiomers) of natural d-nucleotides. l-oligonucleotides have the same physical and chemical properties as their natural counterparts, yet they are completely invisible to the stereospecific environment of biology. We recently reported a novel strand-displacement methodology for transferring sequence information between oligonucleotide enantiomers (which are incapable of base pairing with each other), enabling bio-orthogonal l-DNA/RNA circuits to be easily interfaced with living systems. In this perspective, we summarize these so-called ‘heterochiral’ circuits, provide a viewpoint on their potential applications in synthetic biology, and discuss key problems that must be solved before achieving the ultimate goal of the engineering complex and reliable functionality.

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Komiya, Naruyoshi, Takeharu Kageyama, Masaya Naito et Takeshi Naota. « A clothes-peg-shaped binucleartrans-bis(2-aminotroponato)palladium(II) complex bearing pentamethylene spacers ». Acta Crystallographica Section C Crystal Structure Communications 69, n^o 5 (23 avril 2013) : 503–5. http://dx.doi.org/10.1107/s0108270113004484.

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rac-Bis{μ-trans-2,2′-[pentane-1,5-diylbis(azanediyl)]ditroponato}dipalladium(II), [Pd2(C19H20N2O2)2], has been synthesized and fully characterized using single-crystal X-ray diffraction,1H NMR, FT–IR and mass spectroscopy. Thetranscoordination, vaulted structure andanticonformation have been unequivocally established from the X-ray diffraction studies. This is the first example of a bis(aminotroponato)palladium complex. In the crystalline state, the molecule has twofold symmetry and each molecular unit undergoes intermolecular offset π-stacking of the tropone rings to afford heterochiral interpenetrating dimers that are aligned in a lamellar manner with a herringbone packing motif.

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Bringmann, Gerhard, Doris Feineis, Ralph Brückner, Eva-Maria Peters et Karl Peters. « 2-Hexanoyl-1-tribromomethyl-1,2,3,4-tetrahydro-β-carboline : Crystal Structure Analysis of a Potent Inhibitor of Complex I of Mitochondrial Respiration ». Zeitschrift für Naturforschung B 55, n^o 1 (1 janvier 2000) : 94–99. http://dx.doi.org/10.1515/znb-2000-0115.

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The molecular structure of the title compound 2-hexanoyl-1-tribromomethyl-1,2,3,4-tetra-hydro-β-carboline (3), a potent inhibitor of complex I of the mammalian mitochondrial respiratory chain, has been studied by single-crystal X-ray diffraction analysis. In the crystal, two heterochiral molecules of 3 (i.e., one R- and one S-configured molecule each) were found to be connected with one other in pairs via two intermolecular hydrogen bonds [O(215) ··· H(212)′ and O(215)′ ··· H(212)] to form an overall achiral ‘dimeric’ subunit

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Jiao, Luyang, Mengying Du, Yameng Hou, Yuan Ma et Xianglei Kong. « Homochiral or Heterochiral : A Systematic Study of Threonine Clusters Using a FT ICR Mass Spectrometer ». Symmetry 14, n^o 1 (6 janvier 2022) : 86. http://dx.doi.org/10.3390/sym14010086.

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The strong chiral preferences of some magic clusters of amino acids have attracted continually increasing interests due to their unique structures, properties and possible roles in homochirogenesis. However, how chirality can influence the generation and stability of cluster ions in a wild range of cluster sizes is still unknown for most amino acids. In this study, the preference for threonine clusters to form homochiral and heterochiral complex ions has been investigated by electrospray ionization (ESI) mass spectrometry. Abundant cluster [Thrn+mH]m+ ions (7 ≤ n ≤ 78, 1 ≤ m ≤ 5) have been observed for both samples of enantiopure (100% L) and racemic (50:50 L:D) threonine solutions. Further analyses of the spectra show that the [Thr14+2H]2+ ion is characterized by its most outstanding homochiral preference, and [Thr7+H]+ and [Thr8+H]+ ions also clearly exhibit their homochiral preferences. Although most of the triply charged clusters (20 ≤ n ≤ 36) are characterized by heterochiral preferences, the quadruply charged [Thrn+4H]4+ ions (40 ≤ n ≤ 59) have no obvious chiral preference in general. On the other hand, a weak homochiral preference exists for most of the quintuply charged ions observed in the experiment.

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Fossey, John S., Ryosuke Matsubara, Hiroshi Kiyohara et Shū Kobayashi. « Heterochiral Triangulo Nickel Complex as Evidence of a Large Positive Nonlinear Effect in Catalysis ». Inorganic Chemistry 47, n^o 3 (février 2008) : 781–83. http://dx.doi.org/10.1021/ic7017727.

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Roithová, Jana. « Diastereoisomeric proton-bound complexes of 1,5-diaza-cis-decalin in the gas phase ». Collection of Czechoslovak Chemical Communications 74, n^o 2 (2009) : 243–54. http://dx.doi.org/10.1135/cccc2008185.

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Diastereoisomeric proton-bound complexes of 1,5-diaza-cis-decalin (1) with butan-2-amine (2) are studied by means of the DFT calculations and mass spectrometry. The calculations reveal that 2 is bound via proton to only one nitrogen atom of the bicyclic base 1. The homochiral complex is favored by about 4 kJ/mol over the heterochiral complex. For a more loosely bound ion-pair complex [(1H)I(2H)]+ of the protonated bases 1 and 2 with an iodine counterion the energy difference drops to about 2 kJ/mol. Chiral effects in the formation of [(1)H(2)]+ are studied by the collision-induced dissociation of [(1H)I(2H)]+ generated by the electrospray ionization of the solution of [1·Cu(OH)I] and 2 in acetonitrile. The dominant fragmentation of [(1H)I(2H)]+ leads to 1·H+ and 2·HI, which is at small collision energies accompanied by the elimination of HI leading to the desired [(1)H(2)]+ ion. The chiral effect of 1.2 is determined in favor for the formation of the homochiral complex [(1)H(2)]+.

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Ragland, Beau, et Lianjun Wu. « Characteristic Analysis of Heterochiral TCP Muscle as a Extensile Actuator for Soft Robotics Applications ». Actuators 12, n^o 5 (28 avril 2023) : 189. http://dx.doi.org/10.3390/act12050189.

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A soft actuator is an essential component in a soft robot that enables it to perform complex movements by combining different fundamental motion modes. One type of soft actuator that has received significant attention is the twisted and coiled polymer artificial muscle (TCP actuator). Despite many recent advancements in TCP actuator research, its use as an extensile actuator is less common in the literature. This works introduces the concept of using TCP actuators as thermal-driven extensile actuators for robotics applications. The low-profile actuator can be easily fabricated to offer two unique deformation capabilities. Results from the characterization indicate that extensile actuators, made with various rod diameters and under different load conditions, display remarkable elongation deformation. Additionally, a proof-of-concept soft-earthworm robot was developed to showcase the potential application of the extensile actuator and to demonstrate the benefits of combining different types of motion modes.

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Matveevskaya, Vladislava, Dmitry Pavlov et Andrei Potapov. « Iridium(III) and Rhodium(III) Half-Sandwich Coordination Compounds with 11H-Indeno[1,2-b]quinoxalin-11-one Oxime : A Case of Spontaneous Resolution of Rh(III) Complex ». Inorganics 10, n^o 11 (25 octobre 2022) : 179. http://dx.doi.org/10.3390/inorganics10110179.

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Two half-sandwich iridium(III) and rhodium(III) complexes with 11H-indeno[1,2-b]quinoxalin-11-one oxime (IQ-1) ligand were prepared by the reaction of the proligand with [M(Cp*)Cl2]2 (M = Ir, Rh) dimers. The reaction between IQ-1 and [Ir(Cp*)Cl2]2 in methanol gave the complex [Ir(Cp*)(IQ-1)Cl] (1), which crystallized in a centrosymmetric space group as a true racemate. Whereas complex [Rh(Cp*)(IQ-1)Cl] (2) in the form of a racemic conglomerate was obtained by the reaction of [Rh(Cp*)Cl2]2 and IQ-1 in methanol. The crystal structures of complexes 1 and 2 (R and S enantiomers) were determined by X-ray diffraction analysis, and the structural features were compared in order to understand the structural factors leading to the spontaneous enantiomer resolution of the rhodium(III) complex. In the crystal packing of 1, intermolecular C–H···C contacts between a pair of enantiomers link the molecules into centrosymmetric dimers and lead to the formation of heterochiral crystals of 1. In contrast, the intramolecular contacts CH···Cl and CH···C in complex 2 bind all three ligands around the chiral Rh(III) metal center. In addition, a combination of intermolecular CH···O and CH···C contacts leads to the formation of a homochiral supramolecular structure. These interactions altogether reinforce the spontaneous resolution in complex 2.

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Kazemi, Zahra, Hadi Amiri Rudbari, Mehdi Sahihi, Valiollah Mirkhani, Majid Moghadam, Shahram Tangestaninejad, Iraj Mohammadpoor-Baltork et Abolghasem Abbasi Kajani. « New homochiral and heterochiral Mo(VI) complex from racemic ligand : Synthesis, X-ray structure, diastereomers separation and biological activities ». Polyhedron 170 (septembre 2019) : 70–85. http://dx.doi.org/10.1016/j.poly.2019.05.021.

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Řezanka, Tomáš, Andrea Palyzová, Milada Vítová, Tomáš Brányik, Markéta Kulišová et Jarošová Kolouchová Irena. « Structural Characterization of Mono- and Dimethylphosphatidylethanolamines from Various Organisms Using a Complex Analytical Strategy including Chiral Chromatography ». Symmetry 14, n^o 3 (19 mars 2022) : 616. http://dx.doi.org/10.3390/sym14030616.

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Two minor phospholipids, i.e., mono- and/or dimethylphosphatidylethanolamines, are widespread in many organisms, from bacteria to higher plants and animals. A molecular mixture of methyl-PE and dimethyl-PE was obtained from total lipids by liquid chromatography and further identified by mass spectrometry. Total methyl-PE and dimethyl-PE were cleaved by phospholipase C, and the resulting diacylglycerols, in the form of acetyl derivatives, were separated into alkyl-acyl, alkenyl-acyl, and diacylglycerols. Reversed-phase LC/MS allowed dozens of molecular species to be identified and further analyzed. This was performed on a chiral column, and identification by tandem positive ESI revealed that diacyl derivatives from all four bacteria were mixtures of both R and S enantiomers. The same applied to alkenyl-acyl derivatives of anaerobic bacteria. Analysis thus confirmed that some bacteria biosynthesize phospholipids having both sn-glycerol-3-phosphate and sn-glycerol-1-phosphate as precursors. These findings were further supported by data already published in GenBank. The use of chiral chromatography made it possible to prove that both enantiomers of glycerol phosphate of some molecular species of mono- and dimethylphosphatidylethanolamines are present. The result of the analysis can be interpreted that the cultured bacteria do not have homochiral membranes but, on the contrary, have an asymmetric, i.e., heterochiral membranes.

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Thèses sur le sujet "Heterochiral complex"

Dussart, Caitlyn. « Chiral self-recognition study of metallic complexes : towards coordination polymers ». Electronic Thesis or Diss., Strasbourg, 2024. http://www.theses.fr/2024STRAE006.

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Les assemblages polymériques métallo-supramoléculaires constituent une nouvelle classe de matériaux apparue au cours des dernières décennies. Ces matériaux présentent un large éventail de propriétés qui dépendent de la nature des métaux et des ligands ditopiques utilisés. La réversibilité des liaisons de coordination offre également un caractère dynamique au système qui peut répondre à un stimulus externe. En introduisant de la chiralité dans ces systèmes moléculaires, nous pouvons étudier la capacité de ces structures moléculaires à s’associer ou à se désolidariser pour former des espèces homochirales ou hétérochirales. Ce manuscrit se concentre sur la synthèse et la chimie de coordination de ligands chiraux avec une symétrie C2, tels que les bisoxazolines, les bisimidazolines et les dérivés du 1,2-diaminocyclohexane. La complexation de deux ligands sur un métal de transition donne formation à des complexes homoleptiques ML2 dans lesquels la chiralité des ligands et la géométrie de coordination sont des paramètres importants pour observer une auto-association ou une hétéro-association des ligands. Tous ces complexes ont été étudiés et caractérisés à l’état solide ou en solution et l’impact des groupements chiraux sur les ligands a également été analysée. Afin de convertir ces complexes en assemblages polymériques, des ligands ditopiques chiraux ont également été conçus, synthétisés et étudiés
Metallo-supramolecular polymeric assemblies are a new class of materials that have emerged in recent decades. These materials exhibit a wide range of properties depending on the nature of the metals and the ditopic ligands used. The reversibility of the coordination bonds also gives the system a dynamic character that can response to an external stimulus. By introducing chirality into these molecular systems, we can study the ability of these molecular structures to associate or disassociate to form homochiral or heterochiral species.This manuscript focuses on the synthesis and coordination chemistry of chiral ligands with C2-symmetry, i.e. bisoxazolines, bisimidazolines and derivates of 1,2-diamonocyclohexane. The complexation of two ligands to a transition metal gives rise to homoleptic ML2 complexes, in which the chirality of the ligands and the coordination geometry are important parameters for observing self-association or hetero-association of the ligands. All these complexes have been studied and characterized in the solid state or in solution and the influence of the chiral groups of the ligands has also been analysed. In order to convert these complexes into polymeric assemblies, chiral ditopic ligands have also been designed, synthesized and studied

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